JP2004223346A - Adsorbent for residual agrochemical in crop and soil - Google Patents
Adsorbent for residual agrochemical in crop and soil Download PDFInfo
- Publication number
- JP2004223346A JP2004223346A JP2003011882A JP2003011882A JP2004223346A JP 2004223346 A JP2004223346 A JP 2004223346A JP 2003011882 A JP2003011882 A JP 2003011882A JP 2003011882 A JP2003011882 A JP 2003011882A JP 2004223346 A JP2004223346 A JP 2004223346A
- Authority
- JP
- Japan
- Prior art keywords
- adsorbent
- agrochemical
- soil
- residual
- agricultural crops
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Abstract
Description
【0001】
【発明が属する技術分野】
本発明は農作物の残留農薬除去剤に関する。
【0002】
【従来の技術】
従来の農作物の残留農薬を取り除く方法は水での洗浄や拭き取りであった。
【0003】
【発明が解決しようとする課題】
従来の水での洗浄や拭き取りでは農作物の微細な残留農薬を効率的に除去することが出来ないこと。
【0004】
【課題を解決するための手段】
上記課題を解決するため、散布もしくは塗布することの可能な、水和性もしくは水溶性を有する農薬を吸着するに適した微細な気孔を持つ吸着剤に農薬成分を吸着させ、農薬を無効化する残留農薬吸着剤を提供する。
【0005】
【発明実施の形態】
活性炭やゼオライトに水和性もしくは水溶性をもたせた吸着剤を農薬残留のある農作物に散布もしくは塗布することで吸着剤が農作物に付着している微細な残留農薬成分を気孔内部に吸着し、農薬化合物の化学的作用を無効化する。
【0006】
【実施例】
平成14年11月14日、「みかん」をトップジンM水和剤(チオファネートメチル50%、日本曹達株式会社製造)6gを水2リットルに希釈した溶液(濃度約0.15%)に5秒間つけてから取りだし1kgづつ2つに分け、平成14年11月19日、竹炭フロアブル剤(竹炭20重量%)を10倍に希釈した溶液を試液A(濃度約1.8%)とし、前述のチオファネートメチルにつけたみかんをそれぞれ、水に5秒間つけたものを検体1、試液Aに5秒間つけたものを検体2とする。
【0007】
【発明の効果】
残留農薬の濃度分析は平成14年11月26日に株式会社住化分析センターに依頼した。平成14年12月12日、残留農薬分析結果によると、検体1のチオファネートメチル測定値1.33mg/kg、検体2のチオファネートメチル測定値0.64mg/kgであり、検体1に比べ検体2は残留農薬濃度が約52%減少した。なお分析・試験方法はHPLC法(蛍光)である。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a pesticide residue remover for agricultural products.
[0002]
[Prior art]
Conventional methods for removing pesticide residues from crops have been washing and wiping with water.
[0003]
[Problems to be solved by the invention]
Conventional cleaning and wiping with water cannot efficiently remove fine pesticide residues from crops.
[0004]
[Means for Solving the Problems]
In order to solve the above-mentioned problem, a pesticide component is adsorbed on an adsorbent having fine pores that can be sprayed or applied and is suitable for adsorbing a water-soluble or water-soluble pesticide, thereby invalidating the pesticide. Provide pesticide residue adsorbent.
[0005]
DETAILED DESCRIPTION OF THE INVENTION
By spraying or applying a hydrated or water-soluble adsorbent to activated carbon or zeolite to crops with pesticide residues, the adsorbent adsorbs fine residual pesticide components adhering to the crops into the pores, Negate the chemical action of the compound.
[0006]
【Example】
On November 14, 2002, “Mikan” was applied to a solution (concentration: about 0.15%) prepared by diluting 6 g of Topzin M wettable powder (thiophanate methyl 50%, manufactured by Nippon Soda Co., Ltd.) in 2 liters of water for 5 seconds. Then, on November 19, 2002, a solution obtained by diluting a bamboo charcoal flowable agent (bamboo charcoal 20% by weight) 10-fold was used as a test solution A (concentration: about 1.8%), and attached to the above-mentioned thiophanate methyl. The tangerines immersed in water for 5 seconds are referred to as sample 1, and the tangerines immersed in test solution A for 5 seconds are referred to as sample 2.
[0007]
【The invention's effect】
Analysis of residual pesticide concentration was requested to Sumika Chemical Analysis Service, Ltd. on November 26, 2002. According to the analysis results of the residual pesticide on December 12, 2002, the measured value of thiophanate methyl of sample 1 was 1.33 mg / kg, and the measured value of thiophanate methyl of sample 2 was 0.64 mg / kg. The concentration was reduced by about 52%. The analysis and test method is an HPLC method (fluorescence).
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003011882A JP2004223346A (en) | 2003-01-21 | 2003-01-21 | Adsorbent for residual agrochemical in crop and soil |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003011882A JP2004223346A (en) | 2003-01-21 | 2003-01-21 | Adsorbent for residual agrochemical in crop and soil |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2004223346A true JP2004223346A (en) | 2004-08-12 |
Family
ID=32900655
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003011882A Withdrawn JP2004223346A (en) | 2003-01-21 | 2003-01-21 | Adsorbent for residual agrochemical in crop and soil |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2004223346A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010116434A (en) * | 2008-11-11 | 2010-05-27 | Takasago Internatl Corp | Method for producing purified essential oil |
WO2011092840A1 (en) * | 2010-01-29 | 2011-08-04 | 小川香料株式会社 | Method for manufacturing polymethoxyflavones that are highly stable over time and have reduced residual pesticide levels |
-
2003
- 2003-01-21 JP JP2003011882A patent/JP2004223346A/en not_active Withdrawn
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010116434A (en) * | 2008-11-11 | 2010-05-27 | Takasago Internatl Corp | Method for producing purified essential oil |
US9580668B2 (en) | 2008-11-11 | 2017-02-28 | Takasago International Corporation | Process for producing purified essential oil |
WO2011092840A1 (en) * | 2010-01-29 | 2011-08-04 | 小川香料株式会社 | Method for manufacturing polymethoxyflavones that are highly stable over time and have reduced residual pesticide levels |
US8945646B2 (en) | 2010-01-29 | 2015-02-03 | Ogawa & Co., Ltd. | Method for manufacturing polymethoxyflavones that are highly stable over time and have reduced residual pesticide levels |
JP5701779B2 (en) * | 2010-01-29 | 2015-04-15 | 小川香料株式会社 | Process for producing polymethoxyflavones with excellent temporal stability and reduced amount of residual agricultural chemicals |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
A300 | Withdrawal of application because of no request for examination |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 20060404 |