JP2004196598A - Smoking apparatus - Google Patents

Smoking apparatus Download PDF

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Publication number
JP2004196598A
JP2004196598A JP2002367496A JP2002367496A JP2004196598A JP 2004196598 A JP2004196598 A JP 2004196598A JP 2002367496 A JP2002367496 A JP 2002367496A JP 2002367496 A JP2002367496 A JP 2002367496A JP 2004196598 A JP2004196598 A JP 2004196598A
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Japan
Prior art keywords
gas
smoking
smoked
temperature
heating
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Pending
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JP2002367496A
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JP2004196598A5 (en
Inventor
Zuiko Iwatsuki
瑞光 岩月
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IWAFUKU CERAMICS KK
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IWAFUKU CERAMICS KK
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Priority to JP2002367496A priority Critical patent/JP2004196598A/en
Publication of JP2004196598A publication Critical patent/JP2004196598A/en
Publication of JP2004196598A5 publication Critical patent/JP2004196598A5/ja
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Abstract

<P>PROBLEM TO BE SOLVED: To eliminate bad states, due to such as attached carbon or rust on the surface of a smoked ceramic product, easily brought about by the change in the external environment. <P>SOLUTION: The smoking apparatus has heating/warmth-keeping means 13, 14 used for heating/warmth-keeping feed pipes 2, 3 and installed around the feed pipes 2, 3, which feed a smoking gas, a diluted smoking gas, and their mixture to the inside of smoking boxes 1, 1a, or the like. The apparatus is used for smoking a base surface. In the apparatus, a fed gas at a low temperature is heated; a smoking gas is heated so as not to be thermally decomposed; and when the diluted gas is being heated, its temperature does not lower and it is heated until just before being fed into the boxes 1a or the like. Therefore, the inside temperature of the smoking boxes 1, 1a, or the like during the smoking treatment can be maintained in a temperature range suitable for smoking. <P>COPYRIGHT: (C)2004,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
本発明は、例えば燻瓦の様な、表面に炭素皮膜を形成した燻し窯業製品用の燻化装置に関する。
【0002】
【従来の技術】
従来、上記の様な燻化装置にあっては、所定形状に成形、乾燥及び焼成された素地を燻化ボックス内に収容した後、該燻化ボックス内を密閉し空気を遮断した状態で素地を約900〜1000度程度に灼熱しながら、燻化ボックス内を最適温度域に維持しつつ、プロパン、ブタン等の燻化ガスを、CO2 、N2 等の不活性ガス(本願明細書中、稀釈ガスと称する。)で稀釈して燻化ボックス内に所定時間供給して燻化処理を行って、還元雰囲気下で素地の表面に炭素質皮膜を形成し、その後に炭素質皮膜を酸化させない温度(約450度)まで、上記稀釈ガスを供給しながら密閉状態を維持して冷却することで、表面に銀色の炭素質皮膜が形成された燻し窯業製品となる(例えば、特許文献1参照)。
上記工程中、素地を高温で所定時間以上燻化すると、素地表面の一部に、刷毛でも除去出来ない「付着炭素」が発生してしまい、又素地中の鉄分で焼成工程中に十分に酸化されずに残った鉄分、或いは酸化された鉄分が還元雰囲気下で還元された鉄分が水分に接触すると、表面に茶褐色の斑点状の「サビ」が発生してしまう。尚、付着炭素発生の防止策としては、燻化処理時に燻化ガスを稀釈ガスにより稀釈して使用し、サビ発生の防止策としては、焼成時に素地中の鉄分を完全に酸化し、燻化処理時に燻化ガスを稀釈ガスにより稀釈して使用することで、酸化鉄分の還元反応を抑止せねばならない(例えば、非特許文献1参照)。
【0003】
【特許文献1】
特開2000−203927号公報(第2頁)
【非特許文献1】
田中 稔、「粘土瓦ハンドブック」、扶報堂出版株式会社、1980年11月25日、p328−331、p341−353、p355−357
【0004】
【発明が解決しようとする課題】
しかし、燻化ガスは主に工場外部にボンベ内に液化ガスとして充填され、気化器により気化させた後、送給配管の工場外部分を通って工場内部側へ送られ、他方稀釈ガスは、N2 発生器により大気中から取り出したN2 や、ボンベ内に気体として充填されたCO2 を、必要に応じて送給配管の工場外部分を通して工場内部側へ送ることから、特に冬期にあっては、送給過程において燻化ガス及び稀釈ガスの温度が低下してしまうなど、燻化処理時の燻化ボックス内温度が時期により大きく異なってしまうため、どちらかの設定条件のままで通年燻化処理を行うと、燻化に必要な時間に対し過不足が発生して、「付着炭素」のある製品になったり、「サビ」が発生し易い製品になってしまうなど、解決せねばならない課題があった。
【0005】
【課題を解決するための手段】
本発明は、上記従来技術に基づく、外部環境の変化により燻し窯業製品の表面に付着炭素、サビ等の不具合が発生し易い課題に鑑み、燻化ガス、該燻化ガスの稀釈ガス及び両者の混合ガスの燻化ボックス内への送給パイプの外側に、該送給パイプの加熱・保温手段を設けた燻化装置で素地を燻化処理することで、低温状態の供給ガスを加熱するが、燻化ガスは熱分解しない程度に加熱し、稀釈ガスが加熱されている場合にはその温度の低下を防止し、而もその加熱・保温は燻化ボックス内への供給寸前まで行われることによって、燻化処理時の燻化ボックス内温度を、燻化に適した温度帯に維持可能にする様にして、上記課題を解決する。
【0006】
【発明の実施の形態】
以下本発明の一実施例を図面に基づいて説明する。
図1は、本発明に係る燻化装置の正面概略図であり、図2は、加熱・保温手段の断面図であり、製品素地を収容する複数台の燻化ボックス1、1a…に2本の送給パイプ2、3を、該送給パイプ2、3からの分岐管4、4a…、5、5a…同志を合流させて燻化ボックス1、1a…接続している。他方送給パイプ2、3の下流側を燻化ガス及び該燻化ガスの稀釈ガスの供給部6、7に接続して、燻化ガス及び該燻化ガスの稀釈ガスを送給パイプ2、3内及び分岐管4、4a…、5、5a…内を通して燻化ボックス1、1a…内に供給可能とし、両方のガスを同時に供給する際には、両者が混合される様に成っている。
又、分岐管4、4a…、5、5a…の下流側に流量調整部8、8a…、9、9a…を設けて、燻化ガス及び稀釈ガスの供給量を調節可能としている。
又、燻化ガスの供給部6は、ボンベ10内に燻化ガスの液化ガスを充填すると共に、供給部6の出口部位に気化器11を設け、他方稀釈ガスの供給部7は、大気中からN2 を取り出すN2 発生器であったり、気体状のCO2 を充填したボンベとし、稀釈ガス送給パイプ3の上流側に稀釈ガスの加熱器12を設けている。
【0007】
送給パイプ2、3の外側に、該送給パイプ2、3内の燻化ガス及び稀釈ガスの加熱・保温手段13、14として、高温スチームを通す複数本のパイプ15、15a …、16、16a …を、送給パイプ2、3の上流側より最下流側へ沿わせる様に配置すると共に、パイプ15、15a …、16、16a …の上流側を同じボイラー17に接続し、ボイラー17からの高温スチームをパイプ15、15a …、16、16a …内を通すことで、送給パイプ2、3内の燻化ガス及び稀釈ガスを加熱・保温する様にしている。又、各パイプ15、15a …、16、16a …にあっては、送給パイプ2、3に対し略平行に配置したり、蛇行状又は螺旋状に配置している。
図2に示す様に、上記パイプ15、15a …、16、16a …を配置した送給パイプ2、3の外側に断熱材18、19を設けている。
【0008】
尚、上記実施例にあっては、2本の送給パイプ2、3を有しているが、かかる形態に限定せず、例えば、図示しないが、燻化ガス送給パイプ及び稀釈ガス送給パイプを混合器を介して混合ガス送給パイプに合流させ、該混合ガス送給パイプからの分岐管を燻化ボックス1、1a…接続し、混合ガス送給パイプに加熱・保温手段を配置するなど、要するに素地を収容する燻化ボックスに接続した、燻化ガス、該燻化ガスの稀釈ガス及び両者の混合ガスなどの燻化ボックス内への供給ガスの送給パイプの外周部に、該送給パイプに沿わせる様に加熱・保温手段を設け、該加熱・保温手段により送給ガスの加熱・保温を燻化ボックス内への供給寸前まで行える様に成っていれば良い。
又、上記実施例における加熱・保温手段13、14にあっては、高温スチームを利用しているが、図示しないが、パイプ15、15a …、16、16a …内に液状の熱媒体を通す様にしたり、或いは、送給パイプ2、3に沿わせる様に配置した、シースヒーターの様な電熱ヒーターであっても良い。
【0009】
次に本発明に係る燻化装置の作用について説明する。
従来技術と同様に、所定形状に成形、乾燥及び焼成された素地を燻化ボックス1、1a…内に収容した後、該燻化ボックス1、1a…内を密閉し空気を遮断した状態で素地を約900〜1000度程度に灼熱しながら、燻化ボックス1、1a…内を最適温度域に維持しつつ、プロパン、ブタン等の燻化ガスを、CO2 、N2 等の稀釈ガスで稀釈して燻化ボックス1、1a…内に所定時間供給して燻化処理を行って、還元雰囲気下で素地の表面に炭素質皮膜を形成し、その後に炭素質皮膜を酸化させない温度(約450度)まで、上記稀釈ガスを供給しながら密閉状態を維持して冷却することで、表面に銀色の炭素質皮膜が形成された燻し窯業製品となるが、燻化処理時に、加熱・保温手段13、14におけるパイプ15、15a …、16、16a …内を高温スチームを通すことで、加熱器12により加熱された稀釈ガスの温度低下が無く、低温状態の燻化ガスを熱分解しない程度に加熱昇温させ、その後稀釈ガス及び燻化ガスを合流、混合して燻化ボックス1、1a…内に供給する様にしている。
尚、上記燻化処理は、全ての燻化ボックス1、1a…で同時に行ったり、1台毎又は任意台数毎に行う様にし、実際には流量調整部8、8a…、9、9a…による分岐管4、4a…、5、5a…の開閉操作により行う様にしている。
【0010】
【発明の効果】
要するに本発明は、素地を収容する燻化ボックス1、1a…に接続した、燻化ガス、該燻化ガスの稀釈ガス及び両者の混合ガスなどの燻化ボックス1、1a…内への供給ガスの送給パイプ2、3の外側に、該送給パイプ2、3の加熱・保温手段13、14を設けたので、送給パイプ2、3内を通ってきた供給ガスが低温状態であれば、加熱・保温手段13、14により加熱昇温させることが出来、加熱された供給ガスも加熱・保温手段13、14によりその温度を維持することが出来、而もその加熱・保温は燻化ボックス1、1a…内への供給寸前まで行われることから、外部環境の変化による供給ガスの温度変化を極めて小さく抑えることが出来るため、燻化処理時の燻化ボックス1、1a…の内部温度を、燻化に適した温度帯に維持することが出来、よって常に品質の変わらぬ良質の燻し窯業製品を製造することが出来る等その実用的効果甚だ大である。
【図面の簡単な説明】
【図1】本発明に係る燻化装置の正面概略図である。
【図2】加熱・保温手段の断面図である。
【符号の説明】
1、1a… 燻化ボックス
2、3 送給パイプ
13、14 加熱・保温手段
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a smoker for smoking ceramic products having a carbon film formed on the surface, such as a smoker.
[0002]
[Prior art]
Conventionally, in the above-described smoking apparatus, after the green body molded, dried and fired into a predetermined shape is accommodated in a smoking box, the inside of the smoking box is sealed and the air is shut off in a state where the air is shut off. While the inside of the smoking box is kept in the optimum temperature range while burning the gas to about 900 to 1000 degrees, an inert gas such as CO 2 , N 2, etc. (in the specification of the present application) , Diluted gas) and supplied into a smoking box for a predetermined time to perform a smoking treatment, form a carbonaceous film on the surface of the substrate under a reducing atmosphere, and then oxidize the carbonaceous film. By cooling while maintaining the sealed state while supplying the above-mentioned diluent gas to a temperature (about 450 ° C.), a smoked ceramic product having a silvery carbonaceous film formed on the surface is obtained (for example, see Patent Document 1). ).
During the above process, if the substrate is smoked at a high temperature for a predetermined time or more, "adhered carbon" which cannot be removed even with a brush is generated on a part of the substrate surface, and the iron in the substrate sufficiently oxidizes during the firing process. If the remaining iron or oxidized iron is reduced in a reducing atmosphere and the iron comes into contact with moisture, brown spot-like “rust” is generated on the surface. As a measure to prevent the generation of deposited carbon, the smoked gas is diluted with a diluting gas during the smoke treatment, and the rust is prevented by completely oxidizing the iron in the base material during firing and smoking. The reduction reaction of iron oxide must be suppressed by diluting the smoked gas with the diluent gas during the treatment (for example, see Non-Patent Document 1).
[0003]
[Patent Document 1]
JP-A-2000-203927 (page 2)
[Non-patent document 1]
Minoru Tanaka, “Clay Roof Handbook”, Bupodo Publishing Co., Ltd., November 25, 1980, p328-331, p341-353, p355-357
[0004]
[Problems to be solved by the invention]
However, the smoked gas is mainly filled as a liquefied gas in a cylinder outside the factory, and after being vaporized by a vaporizer, is sent to the inside of the factory through the outside of the factory of the feed pipe, while the diluted gas is N 2 and taken out from the atmosphere with N 2 generator, a CO 2 filled as a gas into the cylinder, from sending to the factory interior side through plant extracellular portion of feed pipes if necessary, in particular a winter For example, the temperature inside the smoking box during the smoking process varies greatly depending on the season, such as the temperature of the smoked gas and dilution gas dropping during the feeding process. If the smoking process is performed, the time required for smoking will be too short or too long, resulting in a product with "adhered carbon" or a product that tends to generate "rust". There was a task that had to be done.
[0005]
[Means for Solving the Problems]
The present invention is based on the above-described conventional technology, and in view of the problem that defects such as carbon and rust are easily generated on the surface of a smoked ceramic product due to a change in the external environment, a smoked gas, a diluted gas of the smoked gas, and a mixture of both The supply gas in a low temperature state is heated by subjecting the base material to a smoking process provided with a heating and heat retaining means for the supply pipe on the outside of the supply pipe for feeding the mixed gas into the smoking box. The smoked gas is heated to the extent that it does not thermally decompose, and if the diluted gas is heated, its temperature is prevented from dropping, and the heating and heat keeping should be performed just before it is supplied to the smoked box. Thus, the above-mentioned problem is solved by making it possible to maintain the temperature in the smoking box during the smoking process in a temperature zone suitable for smoking.
[0006]
BEST MODE FOR CARRYING OUT THE INVENTION
An embodiment of the present invention will be described below with reference to the drawings.
FIG. 1 is a schematic front view of a smoking apparatus according to the present invention, and FIG. 2 is a cross-sectional view of a heating / insulating means, in which a plurality of smoking boxes 1, 1a,. , 5a,... From the supply pipes 2, 3 are joined together and connected to the smoking boxes 1, 1a,. On the other hand, the downstream side of the supply pipes 2 and 3 is connected to the supply sections 6 and 7 for the smoked gas and the diluted gas of the smoked gas, and the smoked gas and the diluted gas of the smoked gas are supplied to the supply pipe 2 and 3 and the branch pipes 4, 4a ... 5, 5a ... can be supplied into the smoker boxes 1, 1a ..., and when both gases are supplied at the same time, both are mixed. .
, 9, 9a, etc. are provided downstream of the branch pipes 4, 4a, 5, 5a, so that the supply amounts of the smoked gas and the dilution gas can be adjusted.
The supply section 6 for the smoked gas fills the cylinder 10 with the liquefied gas of the smoked gas, and a vaporizer 11 is provided at the outlet of the supply section 6, while the supply section 7 for the diluted gas is provided in the atmosphere. or a N 2 generator retrieve the N 2 from the cylinder filled with gaseous CO 2, is provided with a heater 12 dilution gas on the upstream side of the dilution gas feed pipe 3.
[0007]
A plurality of pipes 15, 15a..., 16, through which high-temperature steam is passed outside the feed pipes 2 and 3 as heating and keeping means 13 and 14 for the smoked gas and the diluted gas in the feed pipes 2 and 3 16a are arranged so as to extend from the upstream side of the feed pipes 2 and 3 to the most downstream side, and the upstream sides of the pipes 15, 15a ..., 16, 16a ... are connected to the same boiler 17 and , 16, 16a... Are passed through the pipes 15, 15a..., 16, 16a. The pipes 15, 15a ..., 16, 16a ... are arranged substantially parallel to the feed pipes 2, 3 or in a meandering or spiral manner.
As shown in FIG. 2, heat insulating materials 18, 19 are provided outside the feed pipes 2, 3 in which the pipes 15, 15a..., 16, 16a.
[0008]
In the above embodiment, two feed pipes 2 and 3 are provided. However, the present invention is not limited to this. For example, although not shown, a smoked gas feed pipe and a diluted gas feed pipe are provided. The pipe is joined to the mixed gas supply pipe via the mixer, the branch pipe from the mixed gas supply pipe is connected to the smoking box 1, 1a,..., And the heating / heating means is arranged in the mixed gas supply pipe. In other words, the outer peripheral portion of a supply pipe for supplying gas into the smoking box, such as a smoked gas, a diluted gas of the smoked gas, and a mixed gas of both, connected to a smoked box containing the base material, It is sufficient that a heating and heat retaining means is provided along the feed pipe, and the heating and heat retaining means can heat and keep the supplied gas to just before the supply into the smoking box.
In the above-mentioned embodiment, the heating and heat retaining means 13 and 14 use high-temperature steam. Although not shown, a liquid heat medium is passed through the pipes 15, 15a..., 16, 16a. Alternatively, an electric heater such as a sheath heater disposed along the feed pipes 2 and 3 may be used.
[0009]
Next, the operation of the smoking apparatus according to the present invention will be described.
In the same manner as in the prior art, the green body molded, dried and fired into a predetermined shape is accommodated in the smoking boxes 1, 1a..., And the air is shut off in the smoking boxes 1, 1a. while burning to approximately 900-1000 degrees while maintaining the optimum temperature range the Ibushika box 1, 1a ... within, propane, Ibushika gas such as butane, diluted with dilution gas such as CO 2, N 2 Are supplied into the smoking boxes 1, 1a for a predetermined period of time to perform a smoking process, to form a carbonaceous film on the surface of the substrate under a reducing atmosphere, and then to a temperature at which the carbonaceous film is not oxidized (about 450 ° C). By cooling while maintaining the sealed state while supplying the above-mentioned dilution gas, the product becomes a smoked ceramics product having a silvery carbonaceous film formed on the surface. , 14, high temperature steam through pipes 15, 15a ..., 16, 16a ... Then, the temperature of the diluted gas heated by the heater 12 does not decrease, and the temperature of the diluted gas in the low-temperature state is increased by heating to such an extent that it does not thermally decompose, and then the diluted gas and the smoked gas are combined, mixed and smoked. Supply in boxes 1, 1a ...
The above-mentioned smoking process is performed simultaneously in all the smoking boxes 1, 1a,..., Or one by one or an arbitrary number. Actually, the flow rate adjusting units 8, 8a,. The opening and closing operations of the branch pipes 4, 4a,.
[0010]
【The invention's effect】
In short, the present invention relates to the supply of gas to the inside of the smoking boxes 1, 1a, etc., connected to the smoking boxes 1, 1a,. Are provided outside the supply pipes 2 and 3 for heating and warming the supply pipes 2 and 3 so that if the supply gas passing through the supply pipes 2 and 3 is in a low temperature state, The heating and heating means 13 and 14 can be heated to raise the temperature, and the heated supply gas can be maintained at the same temperature by the heating and keeping means 13 and 14, and the heating and keeping the heat is a smoking box. 1, 1a ..., just before the supply to the inside, the temperature change of the supply gas due to the change of the external environment can be kept extremely small, so the internal temperature of the smoking box 1, 1a ... , Can be maintained in the temperature range suitable for smoking, so always quality Is large, such as very its practical effect can be produced ceramic products fumigation of high-quality unchanging.
[Brief description of the drawings]
FIG. 1 is a schematic front view of a smoking apparatus according to the present invention.
FIG. 2 is a cross-sectional view of a heating / heating means.
[Explanation of symbols]
1, 1a ... Smoked box 2, 3 Feeding pipe
13, 14 Heating / warming means

Claims (1)

素地を収容する燻化ボックスに接続した、燻化ガス、該燻化ガスの稀釈ガス及び両者の混合ガスなどの燻化ボックス内への供給ガスの送給パイプの外側に、該送給パイプの加熱・保温手段を設けたことを特徴とする燻化装置。Outside the supply pipe of the supply gas into the smoking box, such as the smoked gas, the dilution gas of the smoked gas and the mixed gas of both, connected to the smoked box containing the substrate, A smoker comprising a heating and heat retaining means.
JP2002367496A 2002-12-19 2002-12-19 Smoking apparatus Pending JP2004196598A (en)

Priority Applications (1)

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JP2002367496A JP2004196598A (en) 2002-12-19 2002-12-19 Smoking apparatus

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JP2002367496A JP2004196598A (en) 2002-12-19 2002-12-19 Smoking apparatus

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JP2004196598A true JP2004196598A (en) 2004-07-15
JP2004196598A5 JP2004196598A5 (en) 2006-02-09

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1621296A1 (en) 2004-07-29 2006-02-01 Fanuc Ltd Transfer robot system comprising a manipulator and a temporary container depository moving synchronously with the manipulator

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1621296A1 (en) 2004-07-29 2006-02-01 Fanuc Ltd Transfer robot system comprising a manipulator and a temporary container depository moving synchronously with the manipulator

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