JP2004067886A - Building for petrochemical industry - Google Patents

Building for petrochemical industry Download PDF

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Publication number
JP2004067886A
JP2004067886A JP2002229798A JP2002229798A JP2004067886A JP 2004067886 A JP2004067886 A JP 2004067886A JP 2002229798 A JP2002229798 A JP 2002229798A JP 2002229798 A JP2002229798 A JP 2002229798A JP 2004067886 A JP2004067886 A JP 2004067886A
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JP
Japan
Prior art keywords
building
photocatalyst
oil
plant
box
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Granted
Application number
JP2002229798A
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Japanese (ja)
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JP4562164B2 (en
Inventor
Akinori Ito
伊東 昭典
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BLEST KK
Blest Co Ltd
Original Assignee
BLEST KK
Blest Co Ltd
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Priority to JP2002229798A priority Critical patent/JP4562164B2/en
Publication of JP2004067886A publication Critical patent/JP2004067886A/en
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Publication of JP4562164B2 publication Critical patent/JP4562164B2/en
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Abstract

<P>PROBLEM TO BE SOLVED: To impart activities against hydrogen chloride gas, malodor and dioxins to a building for petrochemical industry. <P>SOLUTION: The building for the petrochemical industry is treated with a photocatalyst by forming a film of the photocatalyst on a ventilating fan 3 of the building housing a petrochemical plant by thermal spraying, treating a drop curtain 12 hung from a ceiling with the photocatalyst, installing a dioxins-decomposing cylinder 30 in the tip of a smoke stack of a hot air blower, laying photocatalytic tiles 11 on a floor face of the building, installing a photocatalytic box 4 in the side wall 2b of the building, or optionally coating a photocatalyst on the inner wall of the building. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、プラスチックを油化して油を採集する油化プラントの建屋に関する。
【0002】
【従来技術及び発明が解決しようとする課題】
現在、廃棄プラスチックを油化する大型油化プラントが日本に3ヶ所程存在し、小型油化プラントも現在開発されている。これらの油化プラントでは、塩化ビニールを処理した場合、塩化水素ガス、ダイオキシン等の有毒ガスが発生するので、これらについての対策が必要であるが、現在のところこれらについての対策が不十分であった。
【0003】
【課題を解決するための手段】
そこで、本発明は、小型油化プラントを収納する建屋を光触媒処理したことを特徴とする。
【0004】
この光触媒処理としては、光触媒を付着した換気栓を使用したり、天井から光触媒を付着した垂れ膜を設けたり、煙突先端に光触媒筒を設けたり、床面に光触媒タイルを敷設したり、壁面に光触媒箱を設けたりする。
これによって、建屋内の空気の脱臭を行ったり、ダイオキシン等の有害ガスを分解する。
【0005】
【実施形態】
以下、図面を参照して本発明の実施形態について説明する。
【0006】
図1において、小型の油化プラント本体1が建屋2内に収納され、この油化プラント1は、廃プラ等のプラスチックを元の石油として採集するためのものであり、例えば、縦10m、横5m、高さ5mくらいの小型である、前記建屋2は屋根2aと側壁2bと床面2cとからなっている。前記屋根2aの頂点には所定間隔で建屋の縦方向に複数の換気栓3が設けられ、建屋の側壁2bには光触媒箱4が設けられている。
【0007】
前記油化プラント本体1は、図2に示すようにホッパー5を有し、このホッパー5にコンベアCを介して破砕機7によって1〜2m角に破砕されたプラスチックが供給され、前記破砕機6には、コンベアC2によって原料プラスチックが投入される。
前記破砕機6近傍には、入口8から運び込まれた原料プラスチックが載置される載置場10が設けられている。この載置場10は廃プラを処理する場合、悪臭を放つことがあるが、この悪臭を脱臭するために少なくとも載置場10の近傍の床面には、光触媒タイル11が敷設されている。この光触媒タイル11は、タイルの上面に溶射により酸化チタン、酸化アルミニウム等の細粒からなる光触媒層を形成したものであり、脱臭効果が大きい。なお床面全体に光触媒タイルを敷設してもよい。
【0008】
前記建屋2の屋根2aからは図1に示すように建屋内に垂れ膜12、…12が所定間隔で垂れ下がり、この垂れ膜12はプラスチックの繊維からなる不織布から形成され、この不織布には溶射により光触媒が付着されている。この垂れ幕12は、光触媒が付着できるものであればその材質は問わず、金属板でも木板でもよい。
油化プラントにおいて、塩素が入っている塩化ビニールを処理する場合には、塩化水素ガスとダイオキシンが発生するおそれがあるのでその対策が必須となる。塩化水素ガスは、図2のホッパー5の近傍に設けられる脱塩素装置近傍に発生して漏洩するおそれがあるので、その近傍の建屋側壁床面近くには排気ファン13、…13が設けられ、万が一漏洩した場合に備えている。なお、塩化水素ガスは空気より重いので床面近くに滞溜し、これを排出するために排気ファン13は床面近傍に設けられている。
【0009】
前記換気栓3は、図3に示すように、筒体20中に回転ファン21を備え、前記筒体20の上面は、屋根板22によってカバーされる。前記回転ファン21は羽根23、22を備え、この羽根23は軸24に付設され、この軸24はモータ25によって回転され,この軸24の上下端部は、放射状に配置された支持フレーム26によって支えられている。建屋内の空気は排出換気栓の場合は、矢印Aのように流れ、吸引換気栓の場合には逆方向に流れる。なお、換気栓3は複数個設けられ、その一部は排出換気栓であり、残りは吸入換気栓として構成されてもよい。
【0010】
なお、換気栓3の内面全体には、溶射により光触媒が付着され、とくに回転ファン21の羽根23に光触媒が付着されていると、羽根23が回転して空気への接触面積が大きくなり、これにより光触媒の効果が著しく増大する。また、筒体20には、高電圧発生装置(トランス)27が接続され、換気栓3が電気的に絶縁状体で屋根に設置されていることにより、換気栓3全体が電場雰囲気となり、これにより光触媒が励起され、光触媒の効果が更に著しく増大する。
【0011】
油化プラントの熱源供給をする熱風発生器から伸びる煙突28の先端には、図4に示すようにダイオキシン分解筒30が設けられ、この分解筒30は建屋2の側壁上部に支持された本体ケーシング31と、この本体ケーシング31内に千鳥状に配設された邪魔板32、32…32とからなり、入口33から入った燃焼ガスは邪魔板32に当たりながら出口34から大気中に排出される。なお、前記本体ケーシング31の内壁および邪魔板32には溶射により光触媒層が形成され、前記本体ケーシング31には、高電圧発生装置35が接続され、これによりダイオキシン分解筒30内が電場雰囲気とされ、光触媒のダイオキシン分解能力が向上する。なお、前記分解筒30は、煙突28とは絶縁体36を介して接続されるとともに建屋2の側壁26に絶縁体37を介して支持されることにより電気的に絶縁されている。
【0012】
前記建屋の側壁2bの適宜位置に取り付けられる光触媒箱4は、図5に示すように箱体40を有し、この箱体40の下面には吸気口41が形成され、その上面にはファン42が設けられている。前記箱体40の内部にはガイド板43、43が立設され、箱体40の裏面は建屋の側壁2bに設けた換気口44に面している。前記箱体40の外壁および内壁更には、ガイド板41、ファン42には溶射又は塗料による光触媒層が形成され、必要に応じて高電圧発生装置を設置して電場雰囲気を形成してもよい。この光触媒箱4においては、ファン42の回転により、その下面より吸引された建屋内の空気は光触媒により脱臭され、一部ダイオキシンも分解されている。
【0013】
なお、建屋2の側壁2b面には、塗料による光触媒層が形成されてもよい。
【0014】
【発明の効果】
本発明は、以上のように構成されているので、油化プラントの建屋内に誤って、塩化水素ガス、ダイオキシンが発生してもそれらを分解でき、悪臭を迅速に脱臭できるという効果を奏する。
【図面の簡単な説明】
【図1】本発明の建屋の概略構成図である。
【図2】本発明の概略平面図である。
【図3】本発明に係る換気栓の概略構成図である。
【図4】本発明に係るダイオキシン分解装置の概略構成図である。
【図5】本発明に係る光触媒箱の斜視図である。
【符号の説明】
1…油化プラント本体
2…建屋
3…換気栓
4…光触媒箱
6…破砕機
12…垂れ幕
30…ダイオキシン分解筒
[0001]
TECHNICAL FIELD OF THE INVENTION
TECHNICAL FIELD The present invention relates to a building of an oil conversion plant for collecting oil by converting plastic into oil.
[0002]
2. Prior Art and Problems to be Solved by the Invention
At present, there are about three large oil plants in Japan that convert waste plastic into oil, and small oil plants are currently being developed. In these oil plants, when vinyl chloride is treated, toxic gases such as hydrogen chloride gas and dioxin are generated, so it is necessary to take countermeasures.However, at present these measures are insufficient. Was.
[0003]
[Means for Solving the Problems]
Therefore, the present invention is characterized in that a building accommodating a small-sized oil conversion plant is subjected to photocatalytic treatment.
[0004]
For this photocatalytic treatment, use a ventilation plug with a photocatalyst attached, provide a hanging film with a photocatalyst attached from the ceiling, install a photocatalyst tube at the end of the chimney, lay a photocatalytic tile on the floor, For example, a photocatalyst box is provided.
This deodorizes the air in the building and decomposes harmful gases such as dioxin.
[0005]
Embodiment
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
[0006]
In FIG. 1, a small oil conversion plant main body 1 is housed in a building 2, and this oil conversion plant 1 is for collecting plastic such as waste plastic as original oil, and is, for example, 10 m long and 10 m wide. The building 2 having a small size of about 5 m and a height of about 5 m comprises a roof 2a, side walls 2b, and a floor 2c. At the apex of the roof 2a, a plurality of ventilation plugs 3 are provided at predetermined intervals in the vertical direction of the building, and a photocatalyst box 4 is provided on the side wall 2b of the building.
[0007]
The oiling plant main body 1 has a hopper 5 as shown in FIG. 2, and the crusher 7 supplies plastic crushed to a square of 1 to 2 m by a crusher 7 via a conveyor C. , Raw material plastic is charged by the conveyor C2.
In the vicinity of the crusher 6, there is provided a loading place 10 on which the raw material plastic carried from the inlet 8 is placed. When the waste plastic is treated, the loading place 10 may emit a bad smell. To remove the bad smell, at least a photocatalytic tile 11 is laid on the floor near the loading place 10. The photocatalyst tile 11 has a photocatalyst layer formed of fine particles such as titanium oxide and aluminum oxide formed on the upper surface of the tile by thermal spraying, and has a large deodorizing effect. Note that a photocatalytic tile may be laid on the entire floor.
[0008]
As shown in FIG. 1, drooping films 12,... 12 hang down at predetermined intervals from the roof 2a of the building 2, and the dripping film 12 is formed of a non-woven fabric made of plastic fibers. Photocatalyst is attached. The material of the hanging curtain 12 is not limited as long as the photocatalyst can be attached thereto, and may be a metal plate or a wooden plate.
When treating vinyl chloride containing chlorine in an oil conversion plant, there is a risk that hydrogen chloride gas and dioxin will be generated, so measures must be taken. Since hydrogen chloride gas may be generated near the dechlorination device provided near the hopper 5 in FIG. 2 and leaked, exhaust fans 13,... 13 are provided near the floor of the building side wall in the vicinity thereof. Be prepared in case of a leak. Since hydrogen chloride gas is heavier than air, it stays near the floor, and an exhaust fan 13 is provided near the floor to discharge the gas.
[0009]
As shown in FIG. 3, the ventilation plug 3 includes a rotating fan 21 in a cylindrical body 20, and an upper surface of the cylindrical body 20 is covered by a roof plate 22. The rotary fan 21 includes blades 23, 22. The blades 23 are attached to a shaft 24, the shaft 24 is rotated by a motor 25, and upper and lower ends of the shaft 24 are supported by radially arranged support frames 26. Supported. The air in the building flows as indicated by an arrow A in the case of the discharge vent plug, and flows in the opposite direction in the case of the suction vent plug. Note that a plurality of ventilation plugs 3 may be provided, some of which may be configured as exhaust ventilation plugs, and the other may be configured as suction ventilation plugs.
[0010]
A photocatalyst is attached to the entire inner surface of the ventilation plug 3 by thermal spraying. In particular, when the photocatalyst is attached to the blades 23 of the rotary fan 21, the blades 23 rotate to increase the contact area with air, This significantly increases the effect of the photocatalyst. Further, a high-voltage generator (transformer) 27 is connected to the cylinder 20, and the ventilation plug 3 is electrically insulated and installed on the roof, so that the entire ventilation plug 3 has an electric field atmosphere. This excites the photocatalyst, and the effect of the photocatalyst is further remarkably increased.
[0011]
As shown in FIG. 4, a dioxin decomposition tube 30 is provided at the tip of a chimney 28 extending from a hot air generator for supplying a heat source of the oil conversion plant, and this decomposition tube 30 is a main body casing supported on the upper side wall of the building 2. 32 are arranged in a zigzag pattern in the main body casing 31, and the combustion gas entering through the inlet 33 is discharged into the atmosphere from the outlet 34 while hitting the baffle plate 32. A photocatalytic layer is formed on the inner wall and the baffle plate 32 of the main body casing 31 by thermal spraying, and a high voltage generator 35 is connected to the main body casing 31 so that the inside of the dioxin decomposition tube 30 is set to an electric field atmosphere. In addition, the dioxin decomposition ability of the photocatalyst is improved. The disassembly tube 30 is electrically insulated by being connected to the chimney 28 via an insulator 36 and supported by the side wall 26 of the building 2 via an insulator 37.
[0012]
The photocatalyst box 4 attached to an appropriate position on the side wall 2b of the building has a box 40 as shown in FIG. 5, and a suction port 41 is formed on the lower surface of the box 40 and a fan 42 is formed on the upper surface thereof. Is provided. Guide plates 43, 43 are erected inside the box 40, and the back surface of the box 40 faces a ventilation port 44 provided in the side wall 2b of the building. The outer and inner walls of the box 40, and the guide plate 41 and the fan 42 may be provided with a photocatalyst layer formed by thermal spraying or paint, and a high voltage generator may be provided as necessary to form an electric field atmosphere. In the photocatalyst box 4, the air inside the building sucked from the lower surface by the rotation of the fan 42 is deodorized by the photocatalyst, and dioxin is partially decomposed.
[0013]
Note that a photocatalyst layer made of a paint may be formed on the side wall 2 b of the building 2.
[0014]
【The invention's effect】
ADVANTAGE OF THE INVENTION Since this invention is comprised as mentioned above, even if hydrogen chloride gas and dioxin generate | occur | produce erroneously in the building of an oil conversion plant, they can decompose | disassemble, and it has the effect that a bad smell can be quickly deodorized.
[Brief description of the drawings]
FIG. 1 is a schematic configuration diagram of a building of the present invention.
FIG. 2 is a schematic plan view of the present invention.
FIG. 3 is a schematic configuration diagram of a ventilation plug according to the present invention.
FIG. 4 is a schematic configuration diagram of a dioxin decomposition apparatus according to the present invention.
FIG. 5 is a perspective view of a photocatalyst box according to the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Oil conversion plant main body 2 ... Building 3 ... Ventilation plug 4 ... Photocatalyst box 6 ... Crusher 12 ... Hanging curtain 30 ... Dioxin decomposition cylinder

Claims (6)

油化プラントを収納する建屋において、前記建屋は脱臭、ダイオキシン対策として光触媒処理がなされていることを特徴とする油化プラントの建屋。A building for storing an oil conversion plant, wherein the building has been subjected to photocatalytic treatment as a measure against deodorization and dioxin. 前記光触媒処理は、建屋の換気栓に光触媒の溶射被膜を施してなることを特徴とする請求項1記載の油化プラントの建屋。The said photocatalyst processing is performed by applying the thermal spray coating of a photocatalyst to the ventilation plug of a building, The building of the oil-forming plant of Claim 1 characterized by the above-mentioned. 前記光触媒処理は、建屋の天井から垂らした垂れ膜に光触媒を施してなることを特徴とする請求項1又は2に記載の油化プラントの建屋。The said photocatalyst process is performed by applying a photocatalyst to the dripping film | membrane dripped from the ceiling of the building, The building of the oil-forming plant of Claim 1 or 2 characterized by the above-mentioned. 前記光触媒処理は、温風発生器の燃焼ガスを外部に排出する煙突先端に光触媒筒を付着せしめてなることを特徴とする請求項1乃至3のいずれかに記載の油化プラントの建屋。The building according to any one of claims 1 to 3, wherein the photocatalyst treatment is performed by attaching a photocatalyst tube to a tip of a chimney for discharging a combustion gas of the hot air generator to the outside. 前記光触媒処理は、建屋の床面に溶射光触媒が付着されたタイルを敷設してなることを特徴とする請求項1乃至4のいずれかに記載の油化プラントの建屋。The building of an oil-forming plant according to any one of claims 1 to 4, wherein the photocatalyst treatment is performed by laying a tile having a sprayed photocatalyst attached to a floor surface of the building. 前記光触媒処理は、建屋の壁面に光触媒箱を設置せしめてなり、この光触媒箱はその中を建屋内の空気を通過せしめて光触媒に接触させることを特徴とする請求項1乃至5のいずれかに記載の油化プラントの建屋。6. The photocatalyst treatment according to claim 1, wherein a photocatalyst box is installed on a wall surface of the building, and the photocatalyst box allows air in the building to pass therethrough to contact the photocatalyst. The building of the oil plant described.
JP2002229798A 2002-08-07 2002-08-07 Oil refinery building Expired - Fee Related JP4562164B2 (en)

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JP4562164B2 JP4562164B2 (en) 2010-10-13

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005259640A (en) * 2004-03-15 2005-09-22 Matsushita Electric Ind Co Ltd Fuel cell system

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0957112A (en) * 1995-08-18 1997-03-04 Nippon Muki Co Ltd Photocatalytic reaction apparatus and cartridge therefor
JP2000303662A (en) * 1999-04-20 2000-10-31 Almetax Mfg Co Ltd Atmosphere cleaning type ceramic external facing material
JP2001286731A (en) * 2000-02-04 2001-10-16 Masahiro Abe Method for treating injurious substance contained in exhaust gas as global environment conservation countermeasures, waste disposal method and rational economic system for cycle-oriented society
JP2001343109A (en) * 2000-06-02 2001-12-14 Km Kenkyusho:Kk Apparatus for pyrolytic treatment
JP2002059178A (en) * 2000-08-22 2002-02-26 Meiji Rice Delica Kk Food factory
JP2002085978A (en) * 2000-09-14 2002-03-26 Toto Ltd Photocatalytic member

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0957112A (en) * 1995-08-18 1997-03-04 Nippon Muki Co Ltd Photocatalytic reaction apparatus and cartridge therefor
JP2000303662A (en) * 1999-04-20 2000-10-31 Almetax Mfg Co Ltd Atmosphere cleaning type ceramic external facing material
JP2001286731A (en) * 2000-02-04 2001-10-16 Masahiro Abe Method for treating injurious substance contained in exhaust gas as global environment conservation countermeasures, waste disposal method and rational economic system for cycle-oriented society
JP2001343109A (en) * 2000-06-02 2001-12-14 Km Kenkyusho:Kk Apparatus for pyrolytic treatment
JP2002059178A (en) * 2000-08-22 2002-02-26 Meiji Rice Delica Kk Food factory
JP2002085978A (en) * 2000-09-14 2002-03-26 Toto Ltd Photocatalytic member

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005259640A (en) * 2004-03-15 2005-09-22 Matsushita Electric Ind Co Ltd Fuel cell system

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