JP2004035473A - Foam aerosol composition for hair treatment, and hair treatment method - Google Patents
Foam aerosol composition for hair treatment, and hair treatment method Download PDFInfo
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- JP2004035473A JP2004035473A JP2002194811A JP2002194811A JP2004035473A JP 2004035473 A JP2004035473 A JP 2004035473A JP 2002194811 A JP2002194811 A JP 2002194811A JP 2002194811 A JP2002194811 A JP 2002194811A JP 2004035473 A JP2004035473 A JP 2004035473A
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- hair
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- hair treatment
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Abstract
Description
【0001】
【発明の属する技術分野】
本発明は、毛髪の整髪状態を保持する毛髪処理用泡沫エアゾール組成物および毛髪処理方法に関するものである。
【0002】
【従来の技術および発明が解決しようとする課題】
従来、整髪の際には薬事法に定められているチオグリコール酸塩、システイン、システイン塩酸塩、アセチルシステイン、亜硫酸塩類などの還元剤を主剤とする1剤と、臭素酸塩、過硼酸塩、過酸化水素水などの酸化剤を主剤とする2剤とから成る二浴式のものがある。そして整髪の際には、毛髪を所定のロッドに巻き、カールした状態に保持し、還元剤を主剤とする1剤を塗布して毛髪の成分であるシスチンの結合を開裂して10〜15分経過した後に、酸化剤を主剤とする2剤を塗布して再結合させることによりパーマネント・ウエーブの整髪が得られる。
【0003】
一方、前記還元剤を主剤とする一浴式のものは、前記1剤を塗布した後に洗髪し、所望の髪型にブローして毛髪に浸透した前記還元剤の自然酸化により開裂したシスチンを再結合させることにより整髪するものである。そしてこのような一浴式のものとして、前記還元剤と整髪用の高分子化合物とを含有する毛髪処理用組成物も提案されている(特開2000−143452号公報参照)。
【0004】
しかしながら、従来の二浴式や一浴式の前記還元剤を主剤とする1剤は液状であり、毛髪に塗布する際に必要部分以外に流れたり飛び散る虞があるという問題があった。また、前記還元剤によりしっかりした整髪力を得るためにはアルカリ度やpHを高めなければならず、その結果毛髪にダメージを与える傾向があった。
【0005】
本発明の目的は、毛髪に塗布する際に必要部分以外に流れたり飛び散る虞がなく、しかも毛髪にダメージを与えずにしっかりした整髪力を得ることができる毛髪処理用泡沫エアゾール組成物および毛髪処理方法を提供することにある。
【0006】
【課題を解決するための手段】
本発明者らは上記の目的を達成するために鋭意検討した結果、パーマ液の還元剤としてシステアミン塩酸塩を使用することにより、従来の前記還元剤と異なり弱酸性ないし弱アルカリ性の領域で強いウエーブ(カール)力を保持することを見出すとともに、毛髪処理用組成物それ自体を泡沫化することにより上記目的を達成することができることを見出し、本発明を完成するに至った。
【0007】
すなわち本発明の毛髪処理用泡沫エアゾール組成物は、システアミン塩酸塩、界面活性剤、整髪用の高分子化合物および噴射剤を含有することを特徴とするものである。
【0008】
本発明によれば、前記毛髪処理用泡沫エアゾール組成物を塗布して毛髪の成分であるシスチンの結合を開裂させ、10〜15分経過した後に、酸化剤を主剤とする2剤を塗布して再結合させることにより所望の整髪が得られる。
【0009】
また本発明によれば、前記毛髪処理用泡沫エアゾール組成物を通常の整髪と同様に塗布して所望の髪型に整髪することにより、整髪用の高分子化合物により髪型が保持され、この保持された状態でシステアミン塩酸塩により毛髪中のシスチン結合を一旦開裂させ、所定時間経過することにより整髪された状態で自然酸化によりシスチンが再結合し、洗髪によりシステアミン塩酸塩および整髪用の高分子化合物を洗い流しても、所望の髪型に整髪される。
【0010】
さらに本発明によれば、毛髪処理用泡沫エアゾール組成物を塗布しシスチン結合を開裂させ洗髪し、所望の髪型にブローした後自然酸化により開裂したシスチンを再結合させることにより所望のカールを得たり、癖毛を所望のストレートヘアにすることができる。
【0011】
【発明の実施の形態】
本発明の毛髪処理用泡沫エアゾール組成物の性状は弱酸性ないし弱アルカリ性であることが望ましく、弱酸性ないし弱アルカリ性のpHに設定することにより毛髪にダメージを与えることなくシステアミン塩酸塩の反応性を保つことができる。なお、弱酸性ないし弱アルカリ性のpH調整剤としてはアンモニア水、アミノアルコール、塩基性アミノ酸、炭酸ナトリウム、水酸化カリウムなどのアルカリ調整剤を用いることが可能であり、任意の量を添加することができる。
【0012】
本発明の毛髪処理用泡沫エアゾール組成物において、システアミン塩酸塩は組成物全体の0.1〜20.0重量%の割合で配合することが望ましい。その理由はシステアミン塩酸塩の配合量が組成物全体の0.1重量%未満であると還元力が弱く所望の整髪が得られない虞があり、逆に20.0重量%を超えると毛髪にダメージを与える虞があるからである。
【0013】
本発明の毛髪処理用泡沫エアゾール組成物において泡沫化するための界面活性剤としては、非イオン界面活性剤、アニオン界面活性剤、カチオン界面活性剤または両性界面活性剤を任意に選択して使用することができる。また、噴射剤としてフロン、液化石油ガス、ジメチルエーテル、窒素、炭酸ガス、ヘリウムおよびアルゴンのうち少なくとも1種を配合することができる。
【0014】
前記の界面活性剤の配合量は組成物全体の0.05〜5重量%とすることが望ましい。その理由は組成物全体の0.05重量%未満では泡沫状態が悪く、すぐに液状化してしまう虞があり、逆に5重量%を超えると泡沫の保持時間が長すぎて毛髪への速やかな浸透が得られない虞があるからである。
【0015】
本発明の毛髪処理用泡沫エアゾール組成物においては、整髪状態の保持を行いながら還元後の自然酸化により所望のウエーブ(カール)を得ることを目的として整髪用の高分子化合物を配合するが、そのような高分子化合物としてはカール保持率の高いものであることが望ましい。その理由はカール保持率が低いと毛髪の保持力が低下し、反応が終了するまでに髪型が崩れ、所望の整髪が得られない虞があるからである。望ましい整髪用の高分子化合物としては、例えば、アクリル酸系高分子化合物、メタクリル酸系高分子化合物、ビニルピロリドン系高分子化合物、酢酸ビニル系高分子化合物などを挙げることができる。
【0016】
【実施例】
本発明の毛髪処理用泡沫エアゾール組成物の具体的な配合例(実施例1〜3)を比較例とともに表1に示す。なお配合割合は重量%である。
【0017】
【表1】
【0018】
表1に示す実施例1〜実施例3の毛髪処理用泡沫エアゾール組成物は弱酸性ないし弱アルカリ性で所望の還元効果が得られるので、アルカリ度やpHを高くする必要がないため毛髪にダメージを与えることが少ない。
【0019】
次に、表1に示す実施例1〜実施例3の毛髪処理用泡沫エアゾール組成物の具体的な使用方法について説明する。
使用方法1
毛髪を所定のロッドに巻きながら整髪を実施し、次いで実施例1の毛髪処理用泡沫エアゾール組成物を塗布しながら、あるいはカールまたはストレートにした状態に塗布して毛髪の成分であるシスチンの結合を開裂して10〜15分経過した後に、酸化剤を主剤とする2剤を塗布してシスチンを再結合させることにより完了する。この反応はドライヤー等の加熱により促進される。
【0020】
使用方法2
毛髪に実施例2の毛髪処理用泡沫エアゾール組成物を塗布しシスチン結合を開裂して10〜15分経過した後に洗髪し、所望の髪型にブローし自然酸化により開裂したシスチン結合を再結合させることにより完了する。
【0021】
使用方法3
整髪の際、実施例3の毛髪処理用泡沫エアゾール組成物を毛髪に通常の整髪と同様に塗布して所望の髪型に整髪することにより、整髪用の高分子化合物により髪型が保持され、この保持された状態でシステアミン塩酸塩により毛髪の成分であるシスチンの結合を一旦開裂し、所定時間経過することにより整髪された状態で自然酸化によりシスチンが再結合し、洗髪により洗い流して所望の髪型に整髪される。この反応はドライヤー等の加熱により促進される。
【0022】
【発明の効果】
本発明の毛髪処理用泡沫エアゾール組成物は泡沫であるため、毛髪に塗布する際に必要部分以外に流れたり飛び散ることがなく、所望の部分だけに塗布することができる。例えば毛髪の必要部分に直接または手に取り塗布することができる。
【0023】
すなわち前述したように、毛髪をカールまたはストレートにした状態に本発明の毛髪処理用泡沫エアゾール組成物を塗布して毛髪の成分であるシスチンの結合を開裂して10〜15分経過した後に、酸化剤を主剤とする2剤を塗布してシスチンを再結合させることにより整髪することができる。
【0024】
また毛髪に通常の整髪と同様に本発明の毛髪処理用泡沫エアゾール組成物を塗布して所望の髪型に整髪することにより、整髪用の高分子化合物により髪型が保持され、この保持された状態でシステアミン塩酸塩により毛髪中のシスチンの結合を一旦開裂し、所定時間経過することにより整髪された状態で自然酸化によりシスチンが再結合し、洗髪により洗い流して所望の髪型に整髪することができる。
【0025】
さらに本発明の毛髪処理用泡沫エアゾール組成物を塗布しシスチン結合を開裂させ洗髪し、所望の髪型にブローした後自然酸化により開裂したシスチンを再結合させることにより所望のカールを得たり、癖毛を所望のストレートヘアにすることができる。[0001]
TECHNICAL FIELD OF THE INVENTION
TECHNICAL FIELD The present invention relates to a foam aerosol composition for hair treatment and a hair treatment method for maintaining a hair styling condition.
[0002]
2. Description of the Related Art
Conventionally, in the case of hair styling, one agent mainly containing a reducing agent such as thioglycolate, cysteine, cysteine hydrochloride, acetylcysteine, sulfites and the like, which are prescribed in the Pharmaceutical Affairs Law, bromate, perborate, There is a two-bath type comprising two agents mainly containing an oxidizing agent such as aqueous hydrogen peroxide. Then, at the time of hair styling, the hair is wound around a predetermined rod, kept in a curled state, and one agent containing a reducing agent as a main agent is applied to cleave the bond of cystine, which is a component of the hair, for 10 to 15 minutes. After the lapse of time, a permanent wave hair styling can be obtained by applying and recombining two agents mainly composed of an oxidizing agent.
[0003]
On the other hand, the one-bath type containing the reducing agent as a main component is used for washing the hair after applying the one agent, blowing into a desired hairstyle, and recombining cystine cleaved by natural oxidation of the reducing agent penetrated into hair. By doing so, the hair is adjusted. As such a one-bath type, a hair treatment composition containing the reducing agent and a hairdressing polymer compound has also been proposed (see JP-A-2000-143452).
[0004]
However, the conventional two-bath or single-bath one-agent containing the reducing agent as a main component is in a liquid state, and has a problem that when applied to hair, there is a possibility that the agent may flow or scatter at portions other than the necessary portions. Further, in order to obtain a firm hair styling effect by the reducing agent, the alkalinity and pH must be increased, and as a result, the hair tends to be damaged.
[0005]
SUMMARY OF THE INVENTION An object of the present invention is to provide a hair treatment foam aerosol composition and a hair treatment, which have no risk of flowing or splattering on portions other than necessary portions when applied to hair, and which can obtain a firm hair styling power without damaging the hair. It is to provide a method.
[0006]
[Means for Solving the Problems]
The present inventors have conducted intensive studies to achieve the above object, and as a result, by using cysteamine hydrochloride as a reducing agent for the perm solution, unlike the conventional reducing agent, a strong wave in a weakly acidic or weakly alkaline region was obtained. The present inventors have found that the above-mentioned object can be achieved by foaming the hair treatment composition itself while finding that the (curl) force is maintained, and have completed the present invention.
[0007]
That is, the foam aerosol composition for hair treatment of the present invention is characterized by containing cysteamine hydrochloride, a surfactant, a hairdressing polymer compound and a propellant.
[0008]
According to the present invention, the hair treatment foam aerosol composition is applied to cleave the bond of cystine, which is a component of hair, and after 10 to 15 minutes, two agents mainly containing an oxidizing agent are applied. Recombination gives the desired hair styling.
[0009]
Further, according to the present invention, the hair treatment foam aerosol composition is applied in the same manner as ordinary hair styling, and the hair is shaped into a desired hair style. In this state, cystine bonds in the hair are once cleaved by cysteamine hydrochloride, and after a predetermined time has passed, the cystine is recombined by natural oxidation in a state where the hair has been trimmed, and the cysteamine hydrochloride and the high molecular weight compound are washed out by washing the hair. Even so, the hair is adjusted to the desired hairstyle.
[0010]
Furthermore, according to the present invention, a desired curl can be obtained by applying a foam aerosol composition for hair treatment, breaking cystine bonds, washing the hair, blowing into a desired hairstyle, and then rebonding the cystine cleaved by natural oxidation. , The desired hair can be made into a desired straight hair.
[0011]
BEST MODE FOR CARRYING OUT THE INVENTION
The properties of the foam aerosol composition for hair treatment of the present invention are desirably weakly acidic to weakly alkaline, and by setting the pH to a weakly acidic to weakly alkaline pH, the reactivity of cysteamine hydrochloride can be reduced without damaging the hair. Can be kept. In addition, as a weakly acidic to weakly alkaline pH adjuster, it is possible to use an alkali adjuster such as aqueous ammonia, amino alcohol, basic amino acid, sodium carbonate, and potassium hydroxide, and any amount may be added. it can.
[0012]
In the foam aerosol composition for hair treatment of the present invention, cysteamine hydrochloride is desirably blended in a proportion of 0.1 to 20.0% by weight of the whole composition. The reason for this is that if the amount of cysteamine hydrochloride is less than 0.1% by weight of the whole composition, the reducing power is so weak that a desired hair styling may not be obtained. This is because there is a risk of causing damage.
[0013]
As the surfactant for foaming in the foam aerosol composition for treating hair of the present invention, a nonionic surfactant, an anionic surfactant, a cationic surfactant or an amphoteric surfactant is arbitrarily selected and used. be able to. Further, at least one of Freon, liquefied petroleum gas, dimethyl ether, nitrogen, carbon dioxide, helium and argon can be blended as a propellant.
[0014]
The amount of the surfactant is desirably 0.05 to 5% by weight of the whole composition. The reason is that if the content is less than 0.05% by weight of the whole composition, the foam state is poor and there is a risk of liquefaction immediately. If the content is more than 5% by weight, the retention time of the foam is too long, and the composition is quickly applied to the hair. This is because there is a possibility that the permeation cannot be obtained.
[0015]
In the foam aerosol composition for hair treatment of the present invention, a high molecular compound for hair styling is blended for the purpose of obtaining a desired wave (curl) by natural oxidation after reduction while maintaining the hair styling state. It is desirable that such a polymer compound has a high curl retention. The reason is that if the curl retention is low, the hair holding power is reduced, and the hairstyle is broken before the reaction is completed, so that there is a possibility that a desired hair styling cannot be obtained. Desirable hairdressing polymer compounds include, for example, acrylic acid-based polymer compounds, methacrylic acid-based polymer compounds, vinylpyrrolidone-based polymer compounds, and vinyl acetate-based polymer compounds.
[0016]
【Example】
Table 1 shows specific formulation examples (Examples 1 to 3) of the foam aerosol composition for hair treatment of the present invention together with comparative examples. The mixing ratio is% by weight.
[0017]
[Table 1]
[0018]
The foaming aerosol compositions for hair treatment of Examples 1 to 3 shown in Table 1 are weakly acidic or weakly alkaline, and a desired reducing effect can be obtained. Therefore, it is not necessary to increase the alkalinity or pH, so that the hair is damaged. Little to give.
[0019]
Next, a specific method for using the foam aerosol compositions for hair treatment of Examples 1 to 3 shown in Table 1 will be described.
Usage 1
Hair styling is performed while winding the hair around a predetermined rod, and then applying the foam aerosol composition for hair treatment of Example 1 or applying it in a curled or straightened state to bind cystine, a component of hair. After 10 to 15 minutes have passed since the cleavage, the procedure is completed by applying two agents containing an oxidizing agent as a main component and recombining cystine. This reaction is promoted by heating with a drier or the like.
[0020]
Usage 2
Applying the foam aerosol composition for hair treatment of Example 2 to the hair, cleave the cystine bond after 10 to 15 minutes elapse, wash the hair, blow it into a desired hairstyle, and rejoin the cystine bond cleaved by natural oxidation. To complete.
[0021]
Usage 3
At the time of hair styling, the foam aerosol composition for hair treatment of Example 3 is applied to the hair in the same manner as ordinary hair styling, and the hair is shaped into a desired hair style. The cystine, which is a component of the hair, is once cleaved by cysteamine hydrochloride in a conditioned state, and after a predetermined time has passed, the cystine is recombined by natural oxidation in a state where the hair has been trimmed, and is rinsed off by washing the hair to form a desired hairstyle. Is done. This reaction is promoted by heating with a drier or the like.
[0022]
【The invention's effect】
Since the foam aerosol composition for hair treatment of the present invention is a foam, it can be applied only to a desired portion without flowing or scattering to a portion other than a necessary portion when applied to hair. For example, it can be applied directly or by hand to the required part of the hair.
[0023]
That is, as described above, after the hair is curled or straightened, the foam aerosol composition for hair treatment of the present invention is applied to cleave the bond of cystine, which is a component of the hair, and after 10 to 15 minutes have passed, oxidation is performed. Hair can be adjusted by applying two agents, each of which is a main agent, and recombining cystine.
[0024]
Further, the hair treatment foam aerosol composition of the present invention is applied to the hair in the same manner as ordinary hair styling, and the hair is shaped into a desired hair style, whereby the hair styling polymer compound holds the hair style, and in this held state, The cystine bond in the hair is once cleaved by cysteamine hydrochloride, and after a predetermined time has passed, the cystine is recombined by natural oxidation in a state where the hair has been trimmed, and the hair can be washed and washed to obtain a desired hairstyle.
[0025]
Further, the foam aerosol composition for hair treatment of the present invention is applied, the cystine bond is cleaved and the hair is washed. To the desired straight hair.
Claims (8)
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JP2006131597A (en) * | 2004-11-09 | 2006-05-25 | Hisamitsu Pharmaceut Co Inc | Aerosol composition |
JP2006312587A (en) * | 2005-05-06 | 2006-11-16 | Atsushi Hamamoto | Permanent wave solution for hair |
JP2014105176A (en) * | 2012-11-27 | 2014-06-09 | L'oreal Sa | Method for treating keratin fiber |
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JP2005290003A (en) * | 2004-04-02 | 2005-10-20 | L'oreal Sa | Treatment method for hair fiber and use thereof |
JP2006131597A (en) * | 2004-11-09 | 2006-05-25 | Hisamitsu Pharmaceut Co Inc | Aerosol composition |
JP2006312587A (en) * | 2005-05-06 | 2006-11-16 | Atsushi Hamamoto | Permanent wave solution for hair |
JP2014105176A (en) * | 2012-11-27 | 2014-06-09 | L'oreal Sa | Method for treating keratin fiber |
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