JP2003335940A - Resin composition for sliding member and sliding member - Google Patents

Resin composition for sliding member and sliding member

Info

Publication number
JP2003335940A
JP2003335940A JP2002147206A JP2002147206A JP2003335940A JP 2003335940 A JP2003335940 A JP 2003335940A JP 2002147206 A JP2002147206 A JP 2002147206A JP 2002147206 A JP2002147206 A JP 2002147206A JP 2003335940 A JP2003335940 A JP 2003335940A
Authority
JP
Japan
Prior art keywords
weight
resin
sliding member
polyethylene
resin composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2002147206A
Other languages
Japanese (ja)
Other versions
JP4201528B2 (en
Inventor
Kazuo Hirai
一夫 平井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oiles Industry Co Ltd
Original Assignee
Oiles Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oiles Industry Co Ltd filed Critical Oiles Industry Co Ltd
Priority to JP2002147206A priority Critical patent/JP4201528B2/en
Publication of JP2003335940A publication Critical patent/JP2003335940A/en
Application granted granted Critical
Publication of JP4201528B2 publication Critical patent/JP4201528B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a resin composition which exhibits excellent frictional abrasion characteristics, when a soft metal such as an aluminum alloy is used as a counter material, and is used for sliding members, and to provide a sliding member. <P>SOLUTION: This resin composition for sliding members comprises 0.5 to 30 wt.% of polyethylene resin, 1 to 15 wt.% of a hydrocarbon-based wax, 0.1 to 5 wt.% of an inorganic whisker having a Moh's hardness of 2 to 4, and the remainder of a polyamide resin. <P>COPYRIGHT: (C)2004,JPO

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明が属する技術分野】本発明は、摺動部材用樹脂組
成物に関し、詳しくは、アルミニウム合金などの軟質金
属を摺動相手材として使用した場合において、とくに優
れた摩擦摩耗特性を発揮する摺動部材用樹脂組成物およ
び摺動部材に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a resin composition for sliding members, and more particularly, to a sliding member that exhibits particularly excellent friction and wear characteristics when a soft metal such as an aluminum alloy is used as a sliding mating member. The present invention relates to a resin composition for a moving member and a sliding member.

【0002】[0002]

【従来の技術】従来より、ポリアミド樹脂、ポリアセタ
ール樹脂などの熱可塑性合成樹脂は、機械的強度、耐摩
耗性に優れるため、軸受、歯車などの機械要素として広
く使用されている。しかしながら、これらの合成樹脂は
樹脂単独では充分な摩擦摩耗特性が得られないため、こ
れらの樹脂に黒鉛、二硫化モリブデン、四ふっ化エチレ
ン樹脂などの固体潤滑剤、鉱油やロウなどの潤滑油剤を
含有したり、ポリエチレン樹脂などの低摩擦性を有する
他の合成樹脂を配合したりして摩擦摩耗特性の向上を図
っている。
2. Description of the Related Art Conventionally, thermoplastic synthetic resins such as polyamide resins and polyacetal resins have been widely used as mechanical elements such as bearings and gears because of their excellent mechanical strength and wear resistance. However, since these synthetic resins cannot obtain sufficient friction and wear properties by themselves, a solid lubricant such as graphite, molybdenum disulfide, ethylene tetrafluoride resin, or a lubricant such as mineral oil or wax is added to these resins. It is included or blended with another synthetic resin having low friction such as polyethylene resin to improve the friction and wear characteristics.

【0003】例えば、ポリエチレン樹脂を配合した樹脂
組成物として、ポリアミド樹脂、ポリアセタール樹脂、
ポリエステル樹脂およびポリカーボネート樹脂から選ば
れる熱可塑性樹脂70〜98重量%と、超高分子量ポリ
エチレン樹脂粉末2〜30重量%とを溶融混練してなる
熱可塑性樹脂組成物が知られている(特公昭63−65
232号公報)。
For example, as a resin composition containing a polyethylene resin, a polyamide resin, a polyacetal resin,
There is known a thermoplastic resin composition obtained by melt-kneading 70 to 98% by weight of a thermoplastic resin selected from polyester resins and polycarbonate resins and 2 to 30% by weight of ultrahigh molecular weight polyethylene resin powder (Japanese Patent Publication No. 63-63). -65
No. 232).

【0004】一方、合成樹脂製の摺動部材に限らず、軸
受などの摺動部材においては、相手材、例えば軸の材
質、表面性状なども優れた摩擦摩耗特性を得るためには
重要な要素となる。近年の複写機などOA機器の発達に
ともない、軽量化が要求される機械装置、機器類におい
ては、摺動相手材としてアルミニウム合金の使用が不可
欠とされており、アルミニウム合金を相手材とした場合
においても、良好な摩擦摩耗特性が要求される。
On the other hand, not only sliding members made of synthetic resin but also sliding members such as bearings are important factors for obtaining excellent friction and wear characteristics in mating materials such as shaft materials and surface properties. Becomes With the development of office automation equipment such as copying machines in recent years, it is indispensable to use an aluminum alloy as a sliding mating material in mechanical devices and equipment that require weight reduction. Also in this, good friction and wear characteristics are required.

【0005】上述した特公昭63−65232号公報に
開示された熱可塑性樹脂組成物からなる摺動部材は、ア
ルミニウム合金を相手材とする摺動においては、摩擦係
数が高く、摩耗量も大きいという問題があり、上記の要
求を満たしているとは言い難いものである。
The sliding member made of the thermoplastic resin composition disclosed in Japanese Patent Publication No. 63-65232 described above has a high friction coefficient and a large amount of wear when sliding with an aluminum alloy as a mating member. There are problems and it is hard to say that the above requirements are met.

【0006】[0006]

【発明が解決しようとする課題】本発明は上記の実情に
鑑みなされたもので、その目的は、アルミニウム合金な
どの軟質金属を相手材とする場合において、優れた摩擦
摩耗特性を発揮する摺動部材用樹脂組成物および摺動部
材を提供することにある。
SUMMARY OF THE INVENTION The present invention has been made in view of the above circumstances, and an object thereof is to provide sliding that exhibits excellent friction and wear characteristics when a soft metal such as an aluminum alloy is used as a mating material. To provide a resin composition for a member and a sliding member.

【0007】[0007]

【課題を解決するための手段】本発明者は、上記目的を
達成するべく鋭意研究を重ねた結果、ポリアミド樹脂を
主成分とし、これに一定割合のポリエチレン樹脂、炭化
水素系ワックスおよびモース硬度2〜4の無機ウィスカ
を配合した樹脂組成物、あるいはこれら成分にさらにフ
ェノキシ樹脂を配合した樹脂組成物からなる摺動部材
が、上記目的を達成し得るとの知見を得た。
Means for Solving the Problems As a result of intensive studies aimed at achieving the above object, the present inventor has found that a polyamide resin is a main component and a certain proportion of the polyethylene resin, hydrocarbon wax and Mohs hardness 2 It has been found that a sliding member made of a resin composition containing inorganic whiskers (4) to (4) or a resin composition containing these components further mixed with a phenoxy resin can achieve the above object.

【0008】本発明は上記知見に基づき完成されたもの
であり、本発明によれば、上記目的は、ポリエチレン樹
脂0.5〜30重量%と炭化水素系ワックス1〜15重
量%とモース硬度2〜4の無機ウィスカ0.1〜5重量
%と残部ポリアミド樹脂とからなる摺動部材用樹脂組成
物によって達成される。
The present invention has been completed based on the above findings. According to the present invention, the above objects are 0.5 to 30% by weight of a polyethylene resin, 1 to 15% by weight of a hydrocarbon wax, and a Mohs hardness of 2. It is achieved by a resin composition for a sliding member, which comprises 0.1 to 5% by weight of inorganic whiskers of -4 and the balance polyamide resin.

【0009】また、本発明によれば、上記目的は、ポリ
エチレン樹脂0.5〜30重量%と炭化水素系ワックス
1〜15重量%とモース硬度2〜4の無機ウィスカ0.
1〜5重量%とフェノキシ樹脂3〜25重量%と残部ポ
リアミド樹脂とからなる摺動部材用樹脂組成物によって
も達成される。
Further, according to the present invention, the above objects are 0.5 to 30% by weight of a polyethylene resin, 1 to 15% by weight of a hydrocarbon wax, and 0.5.
It is also achieved by a resin composition for a sliding member, which comprises 1 to 5% by weight, a phenoxy resin 3 to 25% by weight, and the balance polyamide resin.

【0010】さらに、本発明によれば、上記目的は、こ
れら摺動部材用樹脂組成物を成形してなる摺動部材によ
っても達成される。
Furthermore, according to the present invention, the above object can be achieved by a sliding member formed by molding these resin compositions for sliding members.

【0011】[0011]

【発明の実施の形態】以下、本発明を説明する。先ず、
摺動部材用樹脂組成物について説明する。本発明の摺動
部材用樹脂組成物においては、主成分としてポリアミド
樹脂を使用し、配合成分としてポリエチレン樹脂、炭化
水素系ワックスおよびモース硬度2〜4の無機ウィス
カ、あるいはこれら配合成分にさらにフェノキシ樹脂を
使用する。
BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described below. First,
The resin composition for sliding members will be described. In the resin composition for a sliding member of the present invention, a polyamide resin is used as a main component, and a polyethylene resin, a hydrocarbon wax and an inorganic whisker having a Mohs hardness of 2 to 4 as a blending component, or a phenoxy resin as a blending component. To use.

【0012】主成分をなすポリアミド樹脂は、脂肪族ポ
リアミド樹脂であり、具体的には、ナイロン6、ナイロ
ン66、ナイロン610、ナイロン11、ナイロン12
等が挙げられ、これらの一種もしくは二種が選択されて
使用される。
The polyamide resin as the main component is an aliphatic polyamide resin, and specifically, nylon 6, nylon 66, nylon 610, nylon 11, nylon 12
And the like, and one or two of these are selected and used.

【0013】本発明で使用するポリエチレン樹脂として
は、低密度ポリエチレン樹脂、直鎖状低密度ポリエチレ
ン樹脂、中密度ポリエチレン樹脂、高密度ポリエチレン
樹脂が挙げられる。また、超高分子量ポリエチレン樹
脂、超高分子量ポリエチレン成分と低分子量ポリエチレ
ン成分とからなる高分子量ポリエチレン樹脂も使用でき
る。
The polyethylene resin used in the present invention includes low density polyethylene resin, linear low density polyethylene resin, medium density polyethylene resin and high density polyethylene resin. Further, an ultra high molecular weight polyethylene resin or a high molecular weight polyethylene resin composed of an ultra high molecular weight polyethylene component and a low molecular weight polyethylene component can also be used.

【0014】また、エチレンと少量の他のα−オレフィ
ン、例えばプロピレン、1−ブテン、1−ヘキセン、1
−オクテン、4−メチル−1−ペンテン等との共重合体
も使用できる。さらに、前記エチレン単独重合体または
共重合体が、不飽和カルボン酸、その誘導体またはビニ
ル系重合体などにより変性されたポリエチレン樹脂も使
用できる。この変性ポリエチレン樹脂は、ポリアミド樹
脂との親和性を向上させる。
Also, ethylene and small amounts of other α-olefins such as propylene, 1-butene, 1-hexene, 1
A copolymer with -octene, 4-methyl-1-pentene and the like can also be used. Furthermore, a polyethylene resin obtained by modifying the ethylene homopolymer or copolymer with an unsaturated carboxylic acid, a derivative thereof, a vinyl polymer, or the like can also be used. This modified polyethylene resin improves the affinity with the polyamide resin.

【0015】上記の不飽和カルボン酸としては、アクリ
ル酸、メタクリル酸、マレイン酸、フマル酸、テトラヒ
ドロフタル酸、イタコン酸、シトラコン酸、クロトン
酸、エンドシス−ビシクロ[2,2,1]ヘプト−5−
エン−2,3−ジカルボン酸(ナジック酸)等が挙げら
れる。また、不飽和カルボン酸の誘導体としては、塩化
マレニル、マレイミド、アクリル酸アミド、メタクリル
酸アミド、グリシジルメタクリレート、無水マレイン
酸、無水シトラコン酸、マレイン酸モノメチル、マレイ
ン酸ジメチル、グリシジルマレエート等が挙げられる。
これらの不飽和カルボン酸またはその誘導体は、単独で
または組合わせて使用される。とくに、不飽和ジカルボ
ン酸またはその酸無水物が好ましく、マレイン酸、ナジ
ック酸またはこれらの酸無水物がより好ましい。
As the above-mentioned unsaturated carboxylic acid, acrylic acid, methacrylic acid, maleic acid, fumaric acid, tetrahydrophthalic acid, itaconic acid, citraconic acid, crotonic acid, endocis-bicyclo [2,2,1] hept-5 −
Examples thereof include ene-2,3-dicarboxylic acid (nadic acid). Examples of unsaturated carboxylic acid derivatives include maleenyl chloride, maleimide, acrylic acid amide, methacrylic acid amide, glycidyl methacrylate, maleic anhydride, citraconic anhydride, monomethyl maleate, dimethyl maleate, and glycidyl maleate. .
These unsaturated carboxylic acids or their derivatives are used alone or in combination. In particular, unsaturated dicarboxylic acids or acid anhydrides thereof are preferable, and maleic acid, nadic acid or acid anhydrides thereof are more preferable.

【0016】ポリエチレン樹脂をカルボン酸またはその
誘導体で変性する方法としては、不飽和カルボン酸また
はその誘導体から選ばれるグラフトモノマーをポリエチ
レン樹脂にグラフト重合する方法が挙げられる。グラフ
ト重合する方法としては、従来公知の方法が採用でき
る。例えば、ポリエチレン樹脂を溶融し、グラフトモノ
マーを添加してグラフト重合する方法あるいはポリエチ
レン樹脂を溶媒に溶解し、グラフトモノマーを添加して
グラフト重合する方法である。このとき、ラジカル開始
剤を併用するのが好ましい。グラフトモノマーの添加割
合としては、ポリエチレン樹脂100重量部に対して
0.01〜10重量部が好ましい。
Examples of the method for modifying the polyethylene resin with a carboxylic acid or its derivative include a method of graft-polymerizing a graft monomer selected from an unsaturated carboxylic acid or its derivative onto a polyethylene resin. As a method of graft polymerization, a conventionally known method can be adopted. For example, there is a method of melting polyethylene resin and adding a graft monomer to carry out graft polymerization, or a method of dissolving polyethylene resin in a solvent and adding a graft monomer to carry out graft polymerization. At this time, it is preferable to use a radical initiator together. The addition ratio of the graft monomer is preferably 0.01 to 10 parts by weight with respect to 100 parts by weight of the polyethylene resin.

【0017】ビニル系重合体としては、ポリスチレン、
ポリメチルメタクリレート、アクリロニトリル−スチレ
ン共重合体などが挙げられる。
As the vinyl polymer, polystyrene,
Examples thereof include polymethyl methacrylate and acrylonitrile-styrene copolymer.

【0018】ポリエチレン樹脂をビニル系重合体で変性
する方法としては、ポリエチレン樹脂の懸濁水溶液に、
スチレン等のビニル単量体、ベンゾイルペルオキシド等
のラジカル重合開始剤およびt−ブチルペルオキシメタ
クリロイロキシエチルカーボネート等の有機過酸化物含
有ビニルモノマーからなる溶液を添加して、ラジカル重
合開始剤、有機過酸化物含有ビニルモノマーおよびビニ
ル単量体をポリエチレン樹脂に含浸させた後、ポリエチ
レン樹脂中でビニル単量体と有機過酸化物含有ビニルモ
ノマーとを重合して有機ペルオキシド基含有ビニル系重
合体を生成し、得られた樹脂組成物を、または、この樹
脂組成物にポリエチレン樹脂を加えたものを溶融混練す
ることによって、ビニル系重合体がグラフトしたポリエ
チレン樹脂を得る方法が挙げられる。ビニル系重合体で
変性されたポリエチレン樹脂中のビニル系重合体の含有
割合は、10〜60重量%が好ましい。
As a method of modifying the polyethylene resin with a vinyl polymer, a suspension of the polyethylene resin in an aqueous solution is used.
A solution of a vinyl monomer such as styrene, a radical polymerization initiator such as benzoyl peroxide, and an organic peroxide-containing vinyl monomer such as t-butylperoxymethacryloyloxyethyl carbonate is added to the radical polymerization initiator and the organic peroxide. After the oxide-containing vinyl monomer and the vinyl monomer are impregnated in the polyethylene resin, the vinyl monomer and the organic peroxide-containing vinyl monomer are polymerized in the polyethylene resin to produce an organic peroxide group-containing vinyl polymer. Then, the obtained resin composition or a product obtained by adding a polyethylene resin to this resin composition is melt-kneaded to obtain a polyethylene resin grafted with a vinyl polymer. The content ratio of the vinyl polymer in the polyethylene resin modified with the vinyl polymer is preferably 10 to 60% by weight.

【0019】上記のようなビニル系共重合体がグラフト
したポリエチレン樹脂の市販品としては、日本油脂製の
「モディパー(商品名)」が挙げられる。
Commercially available products of the polyethylene resin grafted with the vinyl-based copolymer as described above include "MODIPER (trade name)" manufactured by NOF Corporation.

【0020】上述したポリエチレン樹脂は、ポリアミド
樹脂とのポリマーアロイの形態で配合されるのが好まし
い。このポリマーアロイとしては、ポリエチレン樹脂2
0〜50重量%とポリアミド樹脂80〜50重量%から
なる。
The polyethylene resin described above is preferably blended in the form of a polymer alloy with a polyamide resin. This polymer alloy includes polyethylene resin 2
It is composed of 0 to 50% by weight and 80 to 50% by weight of polyamide resin.

【0021】主成分をなすポリアミド樹脂に、上記ポリ
エチレン樹脂を配合することにより成形性を向上させ
る。また、摺動部材の摩擦係数を低下させ、相手材に対
するアタック性を緩和し、かつなじみ性を向上させる。
ポリエチレン樹脂の配合量は通常0.5〜30重量%、
好ましくは5〜25重量%、さらに好ましくは10〜2
0重量%である。ポリエチレン樹脂の配合量が0.5重
量%未満の場合は、上記した効果が発揮されず、また配
合量が30重量%を超える場合は、耐摩耗性を低下させ
るとともに摺動部材としての強度を低下させる。
Moldability is improved by blending the above-mentioned polyethylene resin with the polyamide resin as the main component. Further, the friction coefficient of the sliding member is lowered, the attacking property with respect to the mating material is alleviated, and the conformability is improved.
The content of the polyethylene resin is usually 0.5 to 30% by weight,
Preferably 5 to 25% by weight, more preferably 10 to 2
It is 0% by weight. If the content of the polyethylene resin is less than 0.5% by weight, the above effects are not exhibited, and if the content of the polyethylene resin exceeds 30% by weight, the abrasion resistance is reduced and the strength as a sliding member is reduced. Lower.

【0022】本発明で使用する炭化水素系ワックスとし
ては、パラフィンワックス、ポリエチレンワックス、マ
イクロクリスタリンワックスが挙げられる。
Examples of the hydrocarbon wax used in the present invention include paraffin wax, polyethylene wax, and microcrystalline wax.

【0023】これらの炭化水素系ワックスは、摺動部材
の低摩擦性に寄与するとともに相手材の損傷を著しく低
減させるものである。炭化水素系ワックスの配合量は通
常1〜15重量%、好ましくは3〜10重量%、さらに
好ましくは5〜7重量%である。炭化水素系ワックスの
配合量が1重量%未満の場合は、低摩擦性に充分寄与せ
ず、また配合量が15重量%を超えると成形性を著しく
低下させるとともに摺動部材としての強度を低下させ
る。
These hydrocarbon waxes contribute to the low friction of the sliding member and significantly reduce the damage of the mating member. The content of the hydrocarbon wax is usually 1 to 15% by weight, preferably 3 to 10% by weight, more preferably 5 to 7% by weight. If the blending amount of the hydrocarbon wax is less than 1% by weight, it does not sufficiently contribute to the low friction property, and if the blending amount exceeds 15% by weight, the formability is remarkably lowered and the strength as a sliding member is lowered. Let

【0024】本発明で使用するモース硬度2〜4の無機
ウィスカとしては、硫酸カルシウムウィスカ、チタン酸
カリウムウィスカ、酸化亜鉛ウィスカ、硫酸マグネシウ
ムウィスカを挙げることができ、具体的には、硫酸カル
シウムウィスカとしては大日精化工業社製の「フランク
リンファイバーA−30(商品名):モース硬度2〜
3」、チタン酸カリウムウィスカとしては大塚化学社製
の「ティスモN(商品名):モース硬度4」あるいは川
鉄鉱業社製の「タイブレック(商品名):モース硬度
4」、酸化亜鉛ウィスカとしては松下アムテック社製の
「パナテトラ(商品名):モース硬度4」、硫酸マグネ
シウムウィスカとしては宇部興産社製の「モスハイジ
(商品名):モース硬度2.5」を挙げることができ
る。
Examples of the inorganic whiskers having a Mohs hardness of 2 to 4 used in the present invention include calcium sulfate whiskers, potassium titanate whiskers, zinc oxide whiskers, and magnesium sulfate whiskers. Specifically, calcium sulfate whiskers are used. Is a "Franklin Fiber A-30 (trade name): Mohs hardness 2" manufactured by Dainichi Seika Kogyo Co., Ltd.
3 ", potassium titanate whiskers" Tismo N (trade name): Mohs hardness 4 "manufactured by Otsuka Chemical Co., Ltd. or" Tybreck (trade name): Mohs hardness 4 "manufactured by Kawatetsu Mining Co., Ltd., and zinc oxide whiskers "Panatetra (trade name): Mohs hardness 4" manufactured by Matsushita Amtec Co., Ltd., and "Moss Heidi (trade name): Mohs hardness 2.5" manufactured by Ube Industries, Ltd. can be mentioned as the magnesium sulfate whiskers.

【0025】これらウィスカは、上記ポリアミド樹脂、
ポリエチレン樹脂および炭化水素系ワックスからなる組
成物に配合されることにより、組成物の耐摩耗性を著し
く向上させる。ウィスカの繊維長さは10〜100μm
であり、組成物中への一様な分散を行わせるためには、
その繊維長さは50μm前後のものが好ましい。
These whiskers are composed of the above polyamide resin,
By being mixed with a composition comprising a polyethylene resin and a hydrocarbon wax, the abrasion resistance of the composition is significantly improved. Fiber length of whiskers is 10-100 μm
In order to achieve uniform dispersion in the composition,
The fiber length is preferably about 50 μm.

【0026】そして、これらウィスカの配合量は、0.
1〜5重量%、好ましくは1〜3重量%である。配合量
が0.1重量%より少ないと組成物の耐摩耗性に効果が
発揮されず、また5重量%を超えて配合すると、耐摩耗
性を向上させる反面、相手材を損傷させるという欠点が
現れる。
The amount of these whiskers blended is 0.
It is 1 to 5% by weight, preferably 1 to 3% by weight. If the blending amount is less than 0.1% by weight, no effect is exerted on the wear resistance of the composition. If the blending amount exceeds 5% by weight, the wear resistance is improved, but the drawback is that the mating material is damaged. appear.

【0027】本発明においては、上述した成分組成から
なる摺動部材用樹脂組成物に、さらに一定割合のフェノ
キシ樹脂を配合することができる。本発明で使用するフ
ェノキシ樹脂は、ビスフェノールAとエピクロルヒドリ
ンの縮合によって得られる線状ポリマーで、次の構造式
を有している。
In the present invention, a phenoxy resin can be further compounded in a fixed ratio to the resin composition for sliding members having the above-mentioned component composition. The phenoxy resin used in the present invention is a linear polymer obtained by condensation of bisphenol A and epichlorohydrin, and has the following structural formula.

【0028】[0028]

【化1】 [Chemical 1]

【0029】このフェノキシ樹脂は、上記ポリアミド樹
脂、ポリエチレン樹脂、炭化水素系ワックスおよび炭酸
塩に所定の割合で配合されることにより、摺動部材の耐
摩耗性を向上させる。そして、その配合量は3〜25重
量%、好ましくは5〜20重量%が適当である。このフ
ェノキシ樹脂の配合量が3重量%未満では、摺動部材の
耐摩耗性の向上に充分な効果が得られず、また25重量
%を超えて配合すると、相手材との摺動において相手材
表面を損傷させる虞があるのと、摺動部材としての機械
的強度を低下させる。
This phenoxy resin improves the wear resistance of the sliding member by being mixed with the above-mentioned polyamide resin, polyethylene resin, hydrocarbon wax and carbonate at a predetermined ratio. And, the blending amount is 3 to 25% by weight, preferably 5 to 20% by weight. If the compounding amount of this phenoxy resin is less than 3% by weight, a sufficient effect cannot be obtained for improving the wear resistance of the sliding member, and if it exceeds 25% by weight, it will slide against the mating material. There is a risk of damaging the surface and the mechanical strength of the sliding member is reduced.

【0030】本発明の摺動部材用樹脂組成物は、定法に
従い、上述の各成分の所定量をヘンシェルミキサー、ス
ーパーミキサー、ボールミル、タンブラーミキサー等の
混合機によって混合することによって得られる。また、
上記のポリマーアロイは各成分を所定の割合で溶融混練
して得ることができる。
The resin composition for a sliding member of the present invention can be obtained by a known method by mixing predetermined amounts of the above-mentioned components with a mixer such as a Henschel mixer, a super mixer, a ball mill or a tumbler mixer. Also,
The above polymer alloy can be obtained by melt-kneading each component at a predetermined ratio.

【0031】つぎに、本発明の摺動部材について説明す
る。本発明の摺動部材は、前述の摺動部材用樹脂組成物
を成形して得られる。摺動部材用樹脂組成物の成形は、
直接に射出成形機または押出成形機により成形する方
法、摺動部材用樹脂組成物から得られたペレットを射出
成形機または押出成形機により成形する方法のいずれで
あってもよい。
Next, the sliding member of the present invention will be described. The sliding member of the present invention is obtained by molding the resin composition for sliding members described above. Molding of the resin composition for sliding members,
It may be either a method of directly molding by an injection molding machine or an extrusion molding machine, or a method of molding pellets obtained from the resin composition for a sliding member by an injection molding machine or an extrusion molding machine.

【0032】本発明の摺動部材は、アルミニウム合金な
どの軟質金属を摺動相手材とした場合において、とくに
摩擦摩耗特性に優れ、事務・情報機器、電装機器、家電
機器などのすべり軸受、すべり軸受装置、シール材など
の摺動接触する摺動部材として使用される。
The sliding member of the present invention is particularly excellent in friction and wear characteristics when a soft metal such as an aluminum alloy is used as a sliding mating material, and it is a plain bearing or a sliding bearing for office / information equipment, electrical equipment, household appliances and the like. It is used as a sliding member that makes sliding contact with bearings and seals.

【0033】以下、実施例により本発明を詳細に説明す
るが、本発明は、その要旨を超えない限り、以下の実施
例に限定されるものではない。実施例および比較例で使
用したポリアミド樹脂およびポリエチレン樹脂を下記表
1に示す。
Hereinafter, the present invention will be described in detail with reference to Examples, but the present invention is not limited to the following Examples unless the gist thereof is exceeded. The polyamide resins and polyethylene resins used in Examples and Comparative Examples are shown in Table 1 below.

【0034】[0034]

【表1】<ポリアミド樹脂> A−1:ナイロン6〔宇部興産社製「宇部ナイロンP1
011F(商品名)」〕 A−2:ナイロン66〔東レ社製「アミランCM300
1N(商品名)」〕 <ポリエチレン樹脂> B−1:無水マレイン酸をグラフトさせた変性ポリエチ
レン樹脂〔三井化学社製高分子量ポリエチレン樹脂「リ
ュブマーL5000(商品名)」100重量部、無水マ
レイン酸1重量部、ベンゾイルペルオキシド0.1重量
部を混合し、押出機で溶融混練して得た。〕 B−2:高密度ポリエチレン樹脂〔三井化学社製「ハイ
ゼックス2100JP(商品名)」〕 B−3:低密度ポリエチレン樹脂にポリスチレンをグラ
フトさせた変性ポリエチレン樹脂(低密度ポリエチレン
70重量%/ポリスチレン30重量%)〔日本油脂社製
「モディパーA1100(商品名)」〕 <無機ウィスカ> C−1:硫酸カルシウムウィスカ〔大日精化工業社製の
「フランクリンファイバーA−30(商品名):モース
硬度2〜3」〕 C−2:チタン酸カリウムウィスカ〔大塚化学社製の
「ティスモN(商品名):モース硬度4」〕 C−3:硫酸マグネシウムウィスカ〔宇部興産社製の
「モスハイジ(商品名):モース硬度2.5」〕 C−4:酸化亜鉛ウィスカ〔松下アムテック社製の「パ
ナテトラ(商品名):モース硬度4」〕 <フェノキシ樹脂> 東都化成社製「フェノトートYP−50P(商品名)」
[Table 1] <Polyamide resin> A-1: Nylon 6 [Ube Nylon P1 manufactured by Ube Industries, Ltd.
011F (trade name) ”] A-2: Nylon 66 [Amylan CM300 manufactured by Toray Industries, Inc.
1N (trade name) "] <Polyethylene resin> B-1: Modified polyethylene resin grafted with maleic anhydride [100 parts by weight of high molecular weight polyethylene resin" LUBMER L5000 (trade name) "manufactured by Mitsui Chemicals, Inc., maleic anhydride 1 Parts by weight and 0.1 parts by weight of benzoyl peroxide were mixed, and melt-kneaded with an extruder to obtain. B-2: High-density polyethylene resin [“HIZEX 2100JP (trade name)” manufactured by Mitsui Chemicals, Inc.] B-3: Modified polyethylene resin obtained by grafting polystyrene onto low-density polyethylene resin (low-density polyethylene 70% by weight / polystyrene 30) % By weight) [“MODIPA A1100 (trade name) manufactured by NOF CORPORATION”] <Inorganic whiskers> C-1: calcium sulfate whisker [“Franklin fiber A-30 (trade name) manufactured by Dainichiseika Kogyo KK: Mohs hardness 2”] ~ 3 "] C-2: Potassium titanate whisker [" Tismo N (trade name): Mohs hardness 4 "manufactured by Otsuka Chemical Co., Ltd.] C-3: Magnesium sulfate whisker [" Mosheiji (trade name) manufactured by Ube Industries ") : Mohs hardness 2.5 "] C-4: Zinc oxide whiskers [" Panatetra (trade name) manufactured by Matsushita Amtec Co., Ltd .: Mohs hardness " 4 "] <phenoxy resin>" Phenotote YP-50P (trade name) "manufactured by Tohto Kasei Co., Ltd.

【0035】実施例1 ポリアミド樹脂(A−1)97.5重量%、変性ポリエ
チレン樹脂(B−1)0.5重量%、炭化水素系ワック
スとしてパラフィンワックス1重量%および無機ウィス
カとして硫酸カルシウムウィスカ(C−1)1重量%を
混合して混合物を作製した後、この混合物を押出機で溶
融混練し、ポリアミド樹脂97.5重量%、ポリエチレ
ン樹脂0.5重量%、パラフィンワックス1重量%およ
び硫酸カルシウムウィスカ1重量%からなるペレットを
作製した。次いで、これらのペレットを射出成形機のホ
ッパーに投入し、成形して内径10mm、外径14m
m、長さ10mmの円筒状試験片(摺動部材)を作製し
た。
[0035]Example 1 Polyamide resin (A-1) 97.5% by weight, modified polyester
0.5% by weight of ethylene resin (B-1), hydrocarbon-based wack
Paraffin wax 1% by weight and inorganic whistle
1% by weight of calcium sulfate whisker (C-1) as a mosquito
After mixing to make a mixture, melt the mixture in an extruder.
Melt-kneaded, polyamide resin 97.5% by weight, polyethylene
Resin 0.5 wt%, paraffin wax 1 wt% and
Pellets composed of 1% by weight of calcium sulfate whisker
It was made. These pellets are then placed on the injection molding machine.
Put into the top and mold to form an inner diameter of 10 mm and an outer diameter of 14 m.
A cylindrical test piece (sliding member) of m and 10 mm in length was prepared.
It was

【0036】実施例2 ポリアミド樹脂(A−1)80重量部および変性ポリエ
チレン樹脂(B−1)20重量部を押出機で溶融混練し
て、ポリアミド樹脂80重量%、ポリエチレン樹脂20
重量%からなるペレットを作製した(以下「ポリマーア
ロイA」という。)。次いで、ポリアミド樹脂(A−
1)69.5重量%、得られたポリマーアロイA25重
量%、炭化水素系ワックスとしてポリエチレンワックス
5重量%、および無機ウィスカとしてチタン酸カリウム
ウィスカ(C−2)0.5重量%を混合して混合物を作
製した後、この混合物を押出機で溶融混練し、ポリアミ
ド樹脂89.5重量%、ポリエチレン樹脂5重量%、ポ
リエチレンワックス5重量%およびチタン酸カリウムウ
ィスカ0.5重量%からなるペレットを作製した。次い
で、前記実施例1と同様に成形して内径10mm、外径
14mm、長さ10mmの円筒状試験片(摺動部材)を
作製した。
[0036]Example 2 80 parts by weight of polyamide resin (A-1) and modified polyester
20 parts by weight of ethylene resin (B-1) was melt-kneaded with an extruder.
80% by weight of polyamide resin, 20 of polyethylene resin
Pellets composed of weight% were prepared (hereinafter referred to as “polymer
Roy A ”. ). Then, a polyamide resin (A-
1) 69.5% by weight, 25 weight of the obtained polymer alloy A
%, Polyethylene wax as hydrocarbon wax
5% by weight and potassium titanate as an inorganic whisker
Make a mixture by mixing 0.5% by weight of whiskers (C-2).
After manufacturing, this mixture is melt-kneaded in an extruder and
Resin 89.5% by weight, polyethylene resin 5% by weight,
5% by weight of polyethylene wax and potassium titanate
Pellets consisting of 0.5% by weight of whiskers were prepared. Next
Then, the inner diameter is 10 mm and the outer diameter is the same as in the first embodiment.
14mm, 10mm long cylindrical test piece (sliding member)
It was made.

【0037】実施例3〜5 ポリアミド樹脂(A−1)41〜42重量%、前記実施
例2で使用したポリマーアロイA50重量%、炭化水素
系ワックスとしてポリエチレンワックス7重量%、およ
び無機ウィスカとして酸化亜鉛ウィスカ(C−4)1〜
2重量%を混合してそれぞれ混合物を作製した後、これ
らの混合物を押出機で溶融混練し、(1)ポリアミド樹
脂82重量%、ポリエチレン樹脂10重量%、ポリエチ
レンワックス7重量%および酸化亜鉛ウィスカ1重量%
からなるペレットを、(2)ポリアミド樹脂81.5重
量%、ポリエチレン樹脂10重量%、ポリエチレンワッ
クス7重量%および酸化亜鉛ウィスカ1.5重量%から
なるペレットを、(c)ポリアミド樹脂81重量%、ポ
リエチレン樹脂10重量%、ポリエチレンワックス7重
量%および酸化亜鉛ウィスカ2重量%からなるペレット
をそれぞれ作製した。次いで、前記実施例1と同様に成
形して内径10mm、外径14mm、長さ10mmの円
筒状試験片(摺動部材)を作製した。
[0037]Examples 3-5 Polyamide resin (A-1) 41 to 42% by weight, the above implementation
50% by weight of polymer alloy A used in Example 2, hydrocarbon
Polyethylene wax 7% by weight as a system wax, and
And zinc oxide whiskers (C-4) 1 as inorganic whiskers
After mixing 2% by weight to make a mixture,
The mixture is melt-kneaded with an extruder, and (1) polyamide resin
82% by weight of fat, 10% by weight of polyethylene resin, polyethylene
7% by weight len wax and 1% by weight zinc oxide whisker
Pellet consisting of (2) polyamide resin 81.5 weight
% Polyethylene resin 10% by weight polyethylene polyethylene
From 7% by weight and 1.5% by weight of zinc oxide whiskers
The pellets obtained from (c) polyamide resin 81% by weight
Polyethylene resin 10% by weight, polyethylene wax 7 layers
% And 2% by weight zinc oxide whiskers
Were produced respectively. Then, the same procedure as in Example 1 was performed.
A circle with an inner diameter of 10 mm, an outer diameter of 14 mm, and a length of 10 mm
A cylindrical test piece (sliding member) was produced.

【0038】実施例6 ポリアミド樹脂(A−1)50重量部および変性ポリエ
チレン樹脂(B−1)50重量部を押出機で溶融混練し
て、ポリアミド樹脂50重量%、ポリエチレン樹脂50
重量%からなるペレットを作製した(以下「ポリマーア
ロイB」という。)。次いで、ポリアミド樹脂(A−
1)52重量%、得られたポリマーアロイB40重量
%、炭化水素系ワックスとしてマイクロクリスタリンワ
ックス7重量%およびウィスカとして硫酸マグネシウム
ウィスカ(C−3)1重量%、を混合して混合物を作製
した後、この混合物を押出機で溶融混練し、ポリアミド
樹脂72重量%、ポリエチレン樹脂20重量%、マイク
ロクリスタリンワックス7重量%および硫酸マグネシウ
ムウィスカ1重量%からなるペレットを作製した。次い
で、前記実施例1と同様に成形して内径10mm、外径
14mm、長さ10mmの円筒状試験片(摺動部材)を
作製した。
[0038]Example 6 50 parts by weight of polyamide resin (A-1) and modified polyester
50 parts by weight of ethylene resin (B-1) was melt-kneaded with an extruder.
Polyamide resin 50% by weight, polyethylene resin 50
Pellets composed of weight% were prepared (hereinafter referred to as “polymer
Roy B ”. ). Then, a polyamide resin (A-
1) 52 wt%, 40 wt% of the obtained polymer alloy B
%, Microcrystalline wax as hydrocarbon wax
X 7% by weight and magnesium sulphate as whiskers
Whiskers (C-3) 1% by weight are mixed to prepare a mixture.
After that, this mixture is melt-kneaded in an extruder to obtain polyamide
72% by weight resin, 20% by weight polyethylene resin, Mike
7% by weight locrystalline wax and magnesium sulfate
Pellets composed of 1% by weight of muwhisker were prepared. Next
Then, the inner diameter is 10 mm and the outer diameter is the same as in the first embodiment.
14mm, 10mm long cylindrical test piece (sliding member)
It was made.

【0039】実施例7 ポリアミド樹脂(A−1)31重量%、前記実施例6で
使用したポリマーアロイB60重量%、炭化水素系ワッ
クスとしてポリエチレンワックス7重量%および無機ウ
ィスカとして酸化亜鉛ウィスカ(C−4)2重量%を混
合して混合物を作製した後、この混合物を押出機で溶融
混練し、ポリアミド樹脂61重量%、ポリエチレン樹脂
30重量%、ポリエチレンワックス7重量%および酸化
亜鉛ウィスカ2重量%からなるペレットを作製した。次
いで、前記実施例1と同様に成形して内径10mm、外
径14mm、長さ10mmの円筒状試験片(摺動部材)
を作製した。
[0039]Example 7 31% by weight of polyamide resin (A-1), in Example 6
Polymer alloy B used 60% by weight, hydrocarbon type w
Polyethylene wax 7% by weight and inorganic wax
2% by weight of zinc oxide whisker (C-4) was mixed as a whisker.
After mixing to make a mixture, melt the mixture in an extruder
Kneaded, polyamide resin 61% by weight, polyethylene resin
30% by weight, polyethylene wax 7% by weight and oxidation
Pellets consisting of 2% by weight of zinc whiskers were prepared. Next
In the same manner as in Example 1, the inner diameter was 10 mm, and the outer diameter was 10 mm.
Cylindrical test piece with 14 mm diameter and 10 mm length (sliding member)
Was produced.

【0040】実施例8〜9 ポリアミド樹脂(A−2)81〜82重量%、ポリエチ
レン樹脂(B−2)10重量%、炭化水素系ワックスと
してポリエチレンワックス7重量%および無機ウィスカ
として硫酸カルシウムウィスカ(C−1)1〜2重量%
を混合して混合物をそれぞれ作製した後、これらの混合
物を押出機で溶融混練してペレットをそれぞれ作製し
た。次いで、前記実施例1と同様に成形して各成分組成
からなる内径10mm、外径14mm、長さ10mmの
円筒状試験片(摺動部材)を作製した。
[0040]Examples 8-9 Polyamide resin (A-2) 81-82% by weight, polyethylene
Ren resin (B-2) 10% by weight, hydrocarbon wax
Polyethylene wax 7% by weight and inorganic whiskers
As calcium sulfate whisker (C-1) 1-2% by weight
After mixing to make each mixture,
Melt kneading the product with an extruder to produce pellets
It was Then, each component composition is obtained by molding in the same manner as in Example 1.
With an inner diameter of 10 mm, an outer diameter of 14 mm, and a length of 10 mm
A cylindrical test piece (sliding member) was produced.

【0041】実施例10〜11 ポリアミド樹脂(A−2)81〜82重量%、変性ポリ
エチレン樹脂(B−3)10重量%、炭化水素系ワック
スとしてポリエチレンワックス7重量%および無機ウィ
スカとして硫酸マグネシウムウィスカ(C−3)1〜2
重量%を混合して混合物をそれぞれ作製した後、これら
の混合物を押出機で溶融混練してペレットをそれぞれ作
製した。次いで、前記実施例1と同様に成形して各成分
組成からなる内径10mm、外径14mm、長さ10m
mの円筒状試験片(摺動部材)を作製した。
[0041]Examples 10-11 Polyamide resin (A-2) 81-82% by weight, modified poly
Ethylene resin (B-3) 10% by weight, hydrocarbon-based wack
Polyethylene wax 7% by weight and inorganic wax
Magnesium sulfate whiskers (C-3) 1-2 as ska
After mixing each of the weight% to make a mixture,
The mixture is melt-kneaded with an extruder to produce pellets.
Made Then, each component was molded by molding in the same manner as in Example 1.
Inner diameter 10 mm, outer diameter 14 mm, length 10 m consisting of composition
A cylindrical test piece (sliding member) of m was produced.

【0042】実施例12〜14 ポリアミド樹脂(A−1)21.5〜36.5重量%、
ポリマーアロイA50重量%、炭化水素系ワックスとし
てポリエチレンワックス7重量%、無機ウィスカとして
酸化亜鉛ウィスカ(C−4)1.5重量%およびフェノ
キシ樹脂5〜20重量%を混合してそれぞれ混合物を作
製した後、これらの混合物を押出機で溶融混練し、
(1)ポリアミド樹脂76.5重量%、ポリエチレン樹
脂10重量%、ポリエチレンワックス7重量%、酸化亜
鉛ウィスカ1.5重量およびフェノキシ樹脂5重量%か
らなるペレットを、(2)ポリアミド樹脂71.5重量
%、ポリエチレン樹脂10重量%、ポリエチレンワック
ス7重量%、酸化亜鉛ウィスカ1.5重量%およびフェ
ノキシ樹脂10重量%からなるペレットを、(3)ポリ
アミド樹脂61.5重量%、ポリエチレン樹脂10重量
%、ポリエチレンワックス7重量%、酸化亜鉛ウィスカ
1.5重量%およびフェノキシ樹脂20重量%からなる
ペレットをそれぞれ作製した。次いで、前記実施例1と
同様に成形して各成分組成からなる内径10mm、外径
14mm、長さ10mmの円筒状試験片(摺動部材)を
作製した。
[0042]Examples 12-14 Polyamide resin (A-1) 21.5 to 36.5% by weight,
50% by weight of polymer alloy A, hydrocarbon wax
Polyethylene wax 7% by weight, as an inorganic whisker
1.5% by weight of zinc oxide whiskers (C-4) and pheno
Mix 5 to 20% by weight of xy resin to make a mixture.
After manufacturing, melt and knead these mixtures with an extruder,
(1) Polyamide resin 76.5% by weight, polyethylene resin
Fat 10% by weight, polyethylene wax 7% by weight, suboxide
1.5% by weight of lead whiskers and 5% by weight of phenoxy resin
(2) 71.5 weight of polyamide resin
%, Polyethylene resin 10% by weight, polyethylene wack
7% by weight, zinc oxide whiskers 1.5% by weight and Fe
Pellets consisting of 10% by weight of nox resin were added to (3) poly
Amide resin 61.5% by weight, polyethylene resin 10% by weight
%, Polyethylene wax 7% by weight, zinc oxide whiskers
Consists of 1.5% by weight and 20% by weight of phenoxy resin
Each pellet was made. Then, as in Example 1 above.
Molded in the same way, consisting of each component composition, inner diameter 10 mm, outer diameter
14mm, 10mm long cylindrical test piece (sliding member)
It was made.

【0043】比較例1 ポリマーアロイAを成形して内径内径10mm、外径1
4mm、長さ10mmの円筒状試験片(摺動部材)を作
製した。
[0043]Comparative Example 1 Polymer alloy A is molded to have an inner diameter of 10 mm and an outer diameter of 1
Create a cylindrical test piece (sliding member) with a length of 4 mm and a length of 10 mm
Made

【0044】比較例2 ポリアミド樹脂(A−1)95重量%および炭化水素系
ワックスとしてポリエチレンワックス5重量%を混合し
て混合物を作製した後、この混合物を押出機で溶融混練
し、ポリアミド樹脂95重量%、ポリエチレンワックス
5重量%からなるペレットを作製した。次いで、このペ
レットを射出成形機のホッパーに投入し、成形して内径
10mm、外径14mm、長さ10mmの円筒状試験片
(摺動部材)を作製した。
[0044]Comparative example 2 Polyamide resin (A-1) 95% by weight and hydrocarbon type
Mix 5% by weight of polyethylene wax as wax
After making a mixture, melt-kneading this mixture with an extruder
95% by weight of polyamide resin, polyethylene wax
A pellet consisting of 5% by weight was produced. Then this
Inside the hopper of the injection molding machine
Cylindrical test piece with 10 mm, outer diameter 14 mm, and length 10 mm
(Sliding member) was produced.

【0045】上述した実施例1〜14および比較例1〜
2で作製した円筒状試験片について、表2に示す試験条
件でジャーナル試験を行なった。その試験結果を表3〜
5に示す。摩擦係数については、試験開始から安定時に
移行した段階での摩擦係数を示し、摩耗量については、
試験終了後の円筒状試験片(摺動部材)の寸法変化量で
示した。また、試験後の相手材表面の損傷度の評価を、
損傷が認められないものを○印にて、損傷が認められる
ものを×印にて表示した。
Examples 1 to 14 and Comparative Examples 1 to 1 described above
A journal test was performed on the cylindrical test piece prepared in 2 under the test conditions shown in Table 2. The test results are shown in Table 3 ~
5 shows. Regarding the friction coefficient, it shows the friction coefficient at the stage when the test started and became stable, and regarding the wear amount,
The amount of dimensional change of the cylindrical test piece (sliding member) after the test is shown. Also, after the test, evaluate the degree of damage on the surface of the mating material,
Those with no damage are shown with a circle, and those with a damage are shown with x.

【0046】[0046]

【表2】<ジャーナル試験> すべり速度 20m/min 荷重 5kgf 相手材 アルミニウム合金(A5052) 試験時間 24hr 潤滑 無潤滑 (以下余白)[Table 2] <Journal test> Sliding speed 20m / min Load 5kgf Counterpart material Aluminum alloy (A5052) Test time 24hr Lubrication Non-lubrication (Below margin)

【0047】[0047]

【表3】 (以下余白)[Table 3] (Below margin)

【0048】[0048]

【表4】 (以下余白)[Table 4] (Below margin)

【0049】[0049]

【表5】 [Table 5]

【0050】以上の結果から、本発明のポリエチレン樹
脂と炭化水素系ワックスと無機ウィスカと残部ポリアミ
ド樹脂からなる樹脂組成物、あるいはこれらの成分にさ
らにフェノキシ樹脂を配合してなる樹脂組成物を成形し
てなる摺動部材はいずれも良好な摩擦摩耗特性を示し
た。また、試験後の相手材表面には何らの損傷も認めら
れなかった。一方、比較例1の樹脂組成物を成形してな
る摺動部材は、摩擦係数が高く、摩耗量も多く、摩擦摩
耗特性に劣るものであり、相手材表面に引掻き傷のよう
な損傷(摩耗痕)が認められ、本発明の目的を達成する
ものではなかった。さらに、比較例2の樹脂組成物を成
形してなる摺動部材は、相手材との摺動において、相手
材表面に損傷等を与えることなく低い摩擦係数を示した
が、摩耗量が多く本発明の目的を達成するものではなか
った。
From the above results, a resin composition of the present invention comprising a polyethylene resin, a hydrocarbon wax, an inorganic whisker and the balance polyamide resin, or a resin composition obtained by further mixing these components with a phenoxy resin was molded. All of the sliding members thus obtained exhibited good friction and wear characteristics. Further, no damage was observed on the surface of the mating material after the test. On the other hand, the sliding member formed by molding the resin composition of Comparative Example 1 has a high coefficient of friction, a large amount of wear, and inferior friction and wear characteristics, and damage (wear) such as scratches on the surface of the mating member. Traces) were not observed and did not achieve the object of the present invention. Further, the sliding member formed by molding the resin composition of Comparative Example 2 showed a low coefficient of friction in sliding with the mating material without damaging the surface of the mating material, but the amount of wear was large. It did not achieve the object of the invention.

【0051】[0051]

【発明の効果】以上説明した本発明によれば、アルミニ
ウム合金などの軟質金属を相手材とした場合において、
優れた摩擦摩耗特性を発揮する摺動部材用樹脂組成物お
よび摺動部材が提供される。
According to the present invention described above, when a soft metal such as an aluminum alloy is used as a mating material,
Provided are a resin composition for a sliding member and a sliding member that exhibit excellent friction and wear characteristics.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C08L 23:04 C08L 91:06 91:06) ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) C08L 23:04 C08L 91:06 91:06)

Claims (7)

【特許請求の範囲】[Claims] 【請求項1】 ポリエチレン樹脂0.5〜30重量%と
炭化水素系ワックス1〜15重量%とモース硬度2〜4
の無機ウィスカ0.1〜5重量%と残部ポリアミド樹脂
とからなることを特徴とする摺動部材用樹脂組成物。
1. Polyethylene resin 0.5 to 30% by weight, hydrocarbon wax 1 to 15% by weight, and Mohs hardness 2 to 4
2. A resin composition for a sliding member, characterized by comprising 0.1 to 5% by weight of the inorganic whiskers and the balance polyamide resin.
【請求項2】 フェノキシ樹脂3〜25重量%をさらに
含む請求項1に記載の摺動部材用樹脂組成物。
2. The resin composition for a sliding member according to claim 1, further comprising 3 to 25% by weight of a phenoxy resin.
【請求項3】 ポリエチレン樹脂はポリアミド樹脂との
ポリマーアロイからなる請求項1又は2に記載の摺動部
材用樹脂組成物。
3. The resin composition for a sliding member according to claim 1, wherein the polyethylene resin is a polymer alloy with a polyamide resin.
【請求項4】 ポリエチレン樹脂とポリアミド樹脂との
ポリマーアロイは、ポリエチレン樹脂20〜50重量%
とポリアミド樹脂80〜50重量%とからなる請求項3
に記載の摺動部材用樹脂組成物。
4. The polymer alloy of polyethylene resin and polyamide resin is 20 to 50% by weight of polyethylene resin.
And 50 to 50% by weight of polyamide resin.
The resin composition for a sliding member as described in 1.
【請求項5】 炭化水素系ワックスは、パラフィンワッ
クス、ポリエチレンワックス、マイクロクリスタリンワ
ックスから選択される請求項1から4のいずれか一項に
記載の摺動部材用樹脂組成物。
5. The resin composition for a sliding member according to claim 1, wherein the hydrocarbon wax is selected from paraffin wax, polyethylene wax, and microcrystalline wax.
【請求項6】 モース硬度2〜4の無機ウィスカは、硫
酸カルシウムウィスカ、チタン酸カリウムウィスカ、酸
化亜鉛ウィスカ、硫酸マグネシウムウィスカから選択さ
れる請求項1から5のいずれか一項に記載の摺動部材用
樹脂組成物。
6. The sliding according to any one of claims 1 to 5, wherein the inorganic whiskers having a Mohs hardness of 2 to 4 are selected from calcium sulfate whiskers, potassium titanate whiskers, zinc oxide whiskers, and magnesium sulfate whiskers. Resin composition for members.
【請求項7】 請求項1から6のいずれか一項に記載の
摺動部材用樹脂組成物を成形してなることを特徴とする
摺動部材。
7. A sliding member formed by molding the resin composition for a sliding member according to claim 1. Description:
JP2002147206A 2002-05-22 2002-05-22 Resin composition for sliding member and sliding member Expired - Lifetime JP4201528B2 (en)

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Country Link
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010023930A1 (en) 2008-08-30 2010-03-04 オイレス工業株式会社 Resin composition for slide member, slide member, and bearing device for hatch cover
JP2015124056A (en) * 2013-12-26 2015-07-06 ツバキ山久チエイン株式会社 Slide member for conveyance chain
JP2016117848A (en) * 2014-12-22 2016-06-30 日油株式会社 Polyamide resin composition and resin molded article
JP2016117842A (en) * 2014-12-22 2016-06-30 日油株式会社 Polyamide resin composition and resin molded article thereof
JP2019124356A (en) * 2018-01-17 2019-07-25 Ntn株式会社 Slide bearing, bearing device and image formation device
CN110078448A (en) * 2019-05-15 2019-08-02 宁波西立混凝土有限公司 A kind of cracking resistance early strength concrete and preparation method thereof
CN113061297A (en) * 2021-03-11 2021-07-02 四川省金路树脂有限公司 Polyethylene resin composition for hot water pipeline and preparation method thereof
WO2023182491A1 (en) * 2022-03-24 2023-09-28 旭化成株式会社 Polyamide resin composition

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010023930A1 (en) 2008-08-30 2010-03-04 オイレス工業株式会社 Resin composition for slide member, slide member, and bearing device for hatch cover
JP2015124056A (en) * 2013-12-26 2015-07-06 ツバキ山久チエイン株式会社 Slide member for conveyance chain
JP2016117848A (en) * 2014-12-22 2016-06-30 日油株式会社 Polyamide resin composition and resin molded article
JP2016117842A (en) * 2014-12-22 2016-06-30 日油株式会社 Polyamide resin composition and resin molded article thereof
JP2019124356A (en) * 2018-01-17 2019-07-25 Ntn株式会社 Slide bearing, bearing device and image formation device
JP7332299B2 (en) 2018-01-17 2023-08-23 Ntn株式会社 Plain bearing, bearing device, and image forming device
CN110078448A (en) * 2019-05-15 2019-08-02 宁波西立混凝土有限公司 A kind of cracking resistance early strength concrete and preparation method thereof
CN110078448B (en) * 2019-05-15 2021-07-30 宁波西立混凝土有限公司 Anti-cracking early-strength concrete and preparation method thereof
CN113061297A (en) * 2021-03-11 2021-07-02 四川省金路树脂有限公司 Polyethylene resin composition for hot water pipeline and preparation method thereof
CN113061297B (en) * 2021-03-11 2022-10-14 四川省金路树脂有限公司 Polyethylene resin composition for hot water pipeline and preparation method thereof
WO2023182491A1 (en) * 2022-03-24 2023-09-28 旭化成株式会社 Polyamide resin composition

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