JP2003284515A - Emulsifying composition for boiling rice - Google Patents

Emulsifying composition for boiling rice

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Publication number
JP2003284515A
JP2003284515A JP2002097776A JP2002097776A JP2003284515A JP 2003284515 A JP2003284515 A JP 2003284515A JP 2002097776 A JP2002097776 A JP 2002097776A JP 2002097776 A JP2002097776 A JP 2002097776A JP 2003284515 A JP2003284515 A JP 2003284515A
Authority
JP
Japan
Prior art keywords
mass
rice
content
lecithin
cooking rice
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2002097776A
Other languages
Japanese (ja)
Inventor
Keiichi Oyama
慶一 大山
Yoichi Watanabe
洋一 渡辺
Yuko Yamaguchi
優子 山口
Koji Tsuchikawa
浩司 土川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nisshin Oillio Ltd
Original Assignee
Nisshin Oillio Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nisshin Oillio Ltd filed Critical Nisshin Oillio Ltd
Priority to JP2002097776A priority Critical patent/JP2003284515A/en
Publication of JP2003284515A publication Critical patent/JP2003284515A/en
Pending legal-status Critical Current

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Abstract

<P>PROBLEM TO BE SOLVED: To provide an emulsifying composition for boiling rice having a function equal to that of a conventional emulsifying composition for boiling rice, and preventing flavor deterioration of rice derived from edible oil and fat to be used as the raw material and lowering of palate feeling by preventing transpiration of water content while lowering the adhesion of rice grains after being boiled, and hardly making the boiled rice get cold. <P>SOLUTION: This emulsifying composition contains lecithin having 40-100 mass% of oleic acid and 0-20 mass% of saturated fatty acid each in the whole constituent fatty acid of an acetone-insoluble matter. <P>COPYRIGHT: (C)2004,JPO

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は従来からの炊飯油の
有する釜離れやほぐれ性の改善等の機能を有するととも
に、原料として使用する食用油脂の風味による米飯の風
味低下を防止し、米飯が冷めても良好な食感を保ち、さ
らに米飯が冷めにくい炊飯用乳化組成物に関する。
TECHNICAL FIELD [0001] The present invention has functions such as removal of a kettle and loosening property of conventional cooking oil, and prevents deterioration of the flavor of cooked rice due to the flavor of edible oil and fat used as a raw material. The present invention relates to an emulsified composition for cooking, which keeps a good texture even when cooled and is hard to cool cooked rice.

【0002】[0002]

【従来の技術】近年、加工食品製造においては一層の作
業性・生産性の向上、製品の品質の向上が求められてい
る。これは米飯を利用した製品にもあてはまり、米飯の
風味の向上、炊飯後の釜離れの向上、機械への付着性低
下、米粒同士の接着低減、湯に浸したときの油浮き低減
等が求められている。これらの改善策として食用油脂又
は食用油脂に乳化剤を添加する方法(特開昭56−68
366号公報、特開平2−142443号公報、特開平
3−175938号公報、特開平3−175940号公
報)が提案されていたが、炊飯時に直接食用油脂を添加
する方法では油脂は水に十分分散せず、炊飯後に米粒表
面に食用油脂が均一に付着しないため、釜離れの改善、
米の付着防止において十分な効果を得ることができなか
った。また、一部に多量に付着した油脂が米飯の風味を
損なったり、お茶漬けをした時に油浮きが生じてくる等
の問題があった。
2. Description of the Related Art In recent years, in the production of processed foods, further improvement in workability / productivity and product quality have been demanded. This also applies to products that use cooked rice, and it is necessary to improve the flavor of cooked rice, improve the separation of the pot after cooking rice, reduce the adhesion to machines, reduce the adhesion of rice grains, and reduce the oil floating when immersed in hot water. Has been. As a countermeasure for these problems, a method of adding an edible oil or fat or an emulsifier to the edible oil or fat (JP-A-56-68)
No. 366, JP-A-2-142443, JP-A-3-175938, and JP-A-3-175940) have been proposed, but in the method of directly adding edible oil and fat when cooking rice, the oil and fat are sufficient for water. Since it does not disperse and the edible oils and fats do not adhere evenly to the surface of rice grains after cooking rice, it improves the separation from the pot
It was not possible to obtain a sufficient effect in preventing the adhesion of rice. In addition, there are problems that a large amount of oil and fat attached to a part of the rice impairs the flavor of cooked rice, or oil floats when rice is pickled.

【0003】近年、これらの問題を解決する方法とし
て、レシチン、ポリグリセリン脂肪酸エステル等の乳化
剤を用いて食用油脂を乳化し、炊飯時に添加する方法
(特開平1−262762号公報、特開平4−1794
51号公報、特開平5−316971号公報、特開平8
−140601号公報)等が提案されてきた。乳化物を
使用することにより油脂が米飯に均一にコーティングさ
れるため、油脂そのものを添加するより付着性、油浮き
の面で良好な効果を示すが、炊飯後の風味に関しては、
乳化物の原料である食用油脂が大きく影響するため、満
足できるものではなかった。また、ほぐれ性・付着性が
改善されているがために米粒同士も分離しやすくなり、
米飯の表面が乾燥しやすくなる。米飯の表面が乾燥する
と食感が低下したり、米飯からの水分の蒸散とともに米
飯の蒸発熱を奪われるため、米飯が冷めやすくなるとい
う問題も生じていた。
In recent years, as a method for solving these problems, a method of emulsifying edible fats and oils by using an emulsifier such as lecithin and polyglycerin fatty acid ester and adding them during rice cooking (JP-A-1-262762 and JP-A-4-26276). 1794
51, JP-A-5-316971, JP-A-8
No. 140601) has been proposed. Since the oil and fat are uniformly coated on the cooked rice by using the emulsion, the adhesiveness is better than the addition of the oil and fat itself, and it shows a good effect in terms of oil floating, but regarding the flavor after cooking,
It was not satisfactory because the edible oil and fat, which is the raw material of the emulsion, has a great influence. In addition, because the loosening and adhesion are improved, rice grains can be easily separated,
The surface of cooked rice becomes easy to dry. When the surface of cooked rice is dried, the texture of the cooked rice is deteriorated, and the heat of evaporation of the cooked rice is removed along with the evaporation of water from the cooked rice, which makes it easier to cool the cooked rice.

【0004】[0004]

【発明が解決しようとする課題】本発明の目的はこれま
での炊飯用乳化組成物と同等な機能を有した上で、原料
として使用する食用油脂の風味による米飯の風味低下を
防止し、米粒の付着性を低下させたまま水分の蒸散を防
いで食感の低下を防止するとともに、米飯を冷めにくく
することができる炊飯用乳化組成物を提供することであ
る。
DISCLOSURE OF THE INVENTION The object of the present invention is to have a function equivalent to that of the conventional emulsified composition for cooking rice, to prevent the flavor of cooked rice from being deteriorated by the flavor of the edible oil and fat used as a raw material, and It is an object of the present invention to provide an emulsified composition for cooking rice, which prevents evaporation of water while reducing the adhesiveness of the rice to prevent deterioration of texture and makes it difficult to cool cooked rice.

【0005】[0005]

【課題を解決するための手段】以上の問題を解決すべく
鋭意開発を行った結果、アセトン不溶物の全構成脂肪酸
中のオレイン酸含量が40〜100質量%、かつ、アセ
トン不溶物の全構成脂肪酸中の飽和脂肪酸含量が0〜2
0%質量であるレシチンを乳化剤とした乳化組成物に多
大な効果があることを発見した。すなわち、本発明は、
アセトン不溶物の全構成脂肪酸中のオレイン酸含量が4
0〜100質量%、かつ、アセトン不溶物の全構成脂肪
酸中の飽和脂肪酸含量が0〜20%質量であるレシチン
を含有する炊飯用乳化組成物を提供する。また本発明
は、アセトン不溶物の全構成脂肪酸中の多価不飽和脂肪
酸含量が0〜50質量%であるレシチンを含有する炊飯
用乳化組成物を提供する。さらに、本発明は、前記炊飯
用乳化組成物がO/W型乳化物である炊飯用乳化組成物
を提供する。
[Means for Solving the Problems] As a result of earnestly developing to solve the above problems, the oleic acid content in all constituent fatty acids of the acetone insoluble matter is 40 to 100% by mass, and the total composition of the acetone insoluble matter is Saturated fatty acid content of fatty acid is 0-2
It was discovered that an emulsified composition using 0% mass lecithin as an emulsifier has a great effect. That is, the present invention is
The oleic acid content in all the constituent fatty acids of the acetone insoluble matter is 4
An emulsified composition for cooking rice containing 0 to 100% by mass and lecithin having a saturated fatty acid content of 0 to 20% by mass in the total constituent fatty acids of an acetone insoluble matter. The present invention also provides an emulsion composition for cooking rice containing lecithin having a polyunsaturated fatty acid content of 0 to 50% by mass in the total constituent fatty acids of the acetone insoluble matter. Furthermore, the present invention provides an emulsion composition for cooking rice, wherein the emulsion composition for cooking rice is an O / W type emulsion.

【0006】本発明は、前記レシチン中のホスファチジ
ルコリンの含量が15〜100質量%である炊飯用乳化
組成物を提供する。また、本発明は、前記レシチンのア
セトン不溶物含量が30〜100質量%である炊飯用乳
化組成物を提供する。さらに、本発明は、前記アセトン
不溶物中のホスファチジルコリン含量が25〜100質
量%である炊飯用乳化組成物を提供する。
The present invention provides an emulsified composition for cooking rice, wherein the content of phosphatidylcholine in the lecithin is 15 to 100% by mass. The present invention also provides an emulsified composition for cooking rice, wherein the content of acetone insoluble matter in the lecithin is 30 to 100% by mass. Furthermore, the present invention provides an emulsified composition for cooking rice, wherein the phosphatidylcholine content in the acetone insoluble matter is 25 to 100% by mass.

【0007】本発明は、前記レシチン、食用油脂、多価
アルコール、エタノール、水を含有する炊飯用乳化組成
物を提供する。また、本発明は、前記炊飯用乳化組成物
の多価アルコール含量が、固形分含量として、多価アル
コール、エタノール、水からなる水相中の60〜100
質量%である炊飯用乳化組成物を提供する。さらに、本
発明は、炊飯用乳化組成物全体に対してレシチン(アセ
トン不溶物として)含量が0.1〜3質量%、食用油脂
含量が30〜40質量%、多価アルコール(固形分とし
て)含量が35〜55質量%、エタノール含量が0.5
〜2質量%、水含量10〜25質量%である炊飯用乳化
組成物を提供する。さらにまた、本発明は、茶抽出物を
0.05〜3質量%を含有する炊飯用乳化組成物を提供
する。
The present invention provides an emulsified composition for cooking rice containing the above lecithin, edible oil and fat, polyhydric alcohol, ethanol and water. Further, in the present invention, the polyhydric alcohol content of the rice cooking emulsion composition is, as a solid content, 60 to 100 in a water phase comprising polyhydric alcohol, ethanol and water.
Provided is an emulsified composition for cooking rice, which is mass%. Further, the present invention has a lecithin (as acetone insoluble matter) content of 0.1 to 3% by mass, an edible oil and fat content of 30 to 40% by mass, and a polyhydric alcohol (as solid content) with respect to the whole emulsion composition for cooking rice. Content of 35-55% by mass, ethanol content of 0.5
Provided is an emulsified composition for cooking rice having a content of ˜2 mass% and a water content of 10 to 25 mass%. Furthermore, the present invention provides an emulsified composition for cooking rice containing 0.05 to 3% by mass of a tea extract.

【0008】[0008]

【発明の実施の形態】以下、本発明について詳細に説明
する。本発明に用いるレシチンとはホスファチジルコリ
ンだけを指すのではなく、アシルグリセリド型リン脂質
を含む混合脂質を指し、形態としては、ペースト、粉末
状、顆粒状等がある。アシルグリセリド型リン脂質とし
ては、例えば、ホスファチジルコリン、ホスファチジル
エタノールアミン、ホスファチジルイノシトール、ホス
ファチジルセリン、ホスファチジン酸等が挙げられ、ま
た、酵素処理や化学反応により加水分解されたモノアシ
ルグリセリド型ホスファチジルコリン、モノアシルグリ
セリド型ホスファチジルエタノールアミン、モノアシル
グリセリド型ホスファチジルイノシトール、モノアシル
グリセリド型ホスファチジルセリン、モノアシルグリセ
リド型ホスファチジン酸等のいわゆるリゾレシチンも含
む。
BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below. The lecithin used in the present invention does not refer only to phosphatidylcholine, but refers to a mixed lipid containing an acylglyceride-type phospholipid, and forms include paste, powder, and granules. Examples of the acylglyceride-type phospholipid include phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, phosphatidylserine, phosphatidic acid and the like, and monoacylglyceride-type phosphatidylcholine and monoacylglyceride hydrolyzed by enzymatic treatment or chemical reaction. Also included are so-called lysolecithins such as type phosphatidylethanolamine, monoacylglyceride type phosphatidylinositol, monoacylglyceride type phosphatidylserine, and monoacylglyceride type phosphatidic acid.

【0009】本発明に用いるレシチンには、天然由来レ
シチン、それを酵素処理又は酵素分解したレシチン、水
素添加処理したレシチン、合成レシチン等各種レシチン
を用いることができる。天然由来のレシチンとしては、
例えば大豆、菜種、トウモロコシ、綿実、落花生、亜麻
仁、ゴマ、紅花、オリーブ、ひまわり、米、グレープ、
アボガド、ヤシ、卵黄、牛脳等由来のレシチンが挙げら
れる。それら天然由来レシチンを酵素処理又は化学的処
理によりエステル交換することで、アセトン不溶物の構
成脂肪酸組成を調整したレシチンを用いても良い。本発
明においては、アセトン不溶物中のホスファチジルコリ
ン含量が高濃度になるとともに入手が容易であるという
点で、植物由来レシチンを含水エタノールで抽出して得
られるものであって、アセトン不溶物の全構成脂肪酸中
のオレイン酸含量が40〜100質量%、かつ、アセト
ン不溶物の全構成脂肪酸中の飽和脂肪酸含量が0〜20
%質量であるレシチンを用いるのが最も好ましい。
As the lecithin used in the present invention, various types of lecithin such as naturally-occurring lecithin, lecithin enzymatically treated or enzymatically decomposed, lecithin hydrogenated, and synthetic lecithin can be used. As naturally-derived lecithin,
For example, soybean, rapeseed, corn, cottonseed, peanut, flaxseed, sesame, safflower, olive, sunflower, rice, grape,
Examples include lecithin derived from avocado, palm, egg yolk, bovine brain and the like. You may use the lecithin which adjusted the constituent fatty acid composition of an acetone insoluble matter by transesterifying these naturally derived lecithins by an enzymatic treatment or a chemical treatment. In the present invention, the phosphatidylcholine content in the acetone insoluble matter is high in concentration and easily available, and is obtained by extracting plant-derived lecithin with hydrous ethanol, and the entire composition of the acetone insoluble matter is obtained. Oleic acid content in fatty acid is 40 to 100% by mass, and saturated fatty acid content in all constituent fatty acids of acetone insoluble matter is 0 to 20.
It is most preferred to use lecithin which is% mass.

【0010】レシチンのエタノール抽出法は特別な方法
を用いる必要は無く、既知の方法で行えばよい。例え
ば、次のような方法が開示できるが、これに限定される
ものではない。レシチンに対し5倍量の90(V/V)
%含水エタノールを加え、45℃、30分間攪拌を行
う。10℃まで冷却して30分間静置後、デカンテーシ
ョンで上層を分離する。この操作をもう一度行い、得ら
れた上層部のエタノールを真空下留去することにより、
エタノール抽出レシチンが得られる。
It is not necessary to use a special method for extracting lecithin with ethanol, and a known method may be used. For example, the following method can be disclosed, but the method is not limited to this. 90 (V / V) of 5 times the amount of lecithin
% Hydrous ethanol is added, and the mixture is stirred at 45 ° C. for 30 minutes. After cooling to 10 ° C. and leaving still for 30 minutes, the upper layer is separated by decantation. This operation is performed once again, and the obtained upper layer ethanol is distilled off under vacuum,
Ethanol extracted lecithin is obtained.

【0011】本発明においてアセトン不溶物とは、アセ
トンによりレシチンから中性脂質等を除去したアセトン
に不溶の物質であり、おおよそのリン脂質含量を表して
いる。レシチン中のアセトン不溶物の含量は、好ましく
は30〜100質量%で、さらに好ましくは40〜10
0質量%である。レシチン中のアセトン不溶物の含量が
30質量%未満であると、レシチンの乳化組成物への配
合量を多くしなけばならず、米飯の食感に悪影響を与え
る。
In the present invention, the acetone-insoluble substance is a substance insoluble in acetone obtained by removing neutral lipids and the like from lecithin with acetone, and represents an approximate phospholipid content. The content of acetone insoluble matter in lecithin is preferably 30 to 100% by mass, more preferably 40 to 10%.
It is 0 mass%. When the content of the acetone insoluble matter in lecithin is less than 30% by mass, the amount of lecithin to be added to the emulsion composition must be increased, which adversely affects the texture of cooked rice.

【0012】レシチンのアセトン不溶物含量は、例えば
次のようにして求められる。試料2gをビーカーに計り
とり、氷冷したリン脂質飽和アセトン溶液300ミリリ
ットルを加え、十分攪拌して30分放置する。上澄み液
を質量既知のガラス濾過器で吸引ろ過し、さらに氷冷し
たリン脂質飽和アセトン溶液30ミリリットルで3回不
溶物を洗浄して、不溶物の全量をガラス濾過器に移し入
れる。ガラス濾過器に氷冷したリン脂質飽和アセトン溶
液を満たし、吸引した後、減圧下で乾燥させ、質量を測
定する。(不溶物の質量/試料採取量)×100がアセ
トン不溶物(質量%)となる。
The acetone insoluble matter content of lecithin can be determined, for example, as follows. 2 g of the sample is weighed in a beaker, 300 ml of ice-cooled phospholipid-saturated acetone solution is added, sufficiently stirred and left for 30 minutes. The supernatant is suction filtered with a glass filter of known mass, and the insoluble matter is washed three times with 30 ml of ice-cooled phospholipid-saturated acetone solution, and the entire amount of the insoluble matter is transferred to the glass filter. A glass filter is filled with ice-cooled phospholipid-saturated acetone solution, suctioned, and then dried under reduced pressure, and the mass is measured. (Mass of insoluble matter / sampled amount) × 100 is acetone insoluble matter (mass%).

【0013】本発明に用いるレシチン中のアセトン不溶
物は、その全構成脂肪酸組成中のオレイン酸含量が好ま
しくは40〜100質量%、さらに好ましくは50〜1
00質量%で、かつ、アセトン不溶物の全構成脂肪酸中
の飽和脂肪酸含量が0〜20質量%、さらに好ましくは
0〜15質量%である。アセトン不溶物の全構成脂肪酸
中のリノール酸、リノレン酸等の多価不飽和脂肪酸含量
が0〜50質量%であることが好ましく、更に好ましく
は0〜40質量%である。オレイン酸が40質量%未満
であると、乳化組成物の乳化安定性及び風味に悪影響を
及ぼす。また、飽和脂肪酸が20質量%より多いと乳化
粒子の界面が固くなるため、米飯の食感が堅くなった
り、パサついたものとなる。なお多価不飽和脂肪酸が5
0質量%より多いと乳化安定性及び風味に悪影響を及ぼ
す。さらにはレシチン中のアセトン不溶物の全構成脂肪
酸中のオレイン酸含量が40質量%未満であって、か
つ、アセトン不溶物の全構成脂肪酸中の飽和脂肪酸含量
が20質量%より多い場合は、乳化組成物の原料である
食用油脂が米飯の風味を損なってしまうばかりでなく、
炊飯後の米粒も乾燥しやすく冷めやすいものとなってし
まう。アセトン不溶物中の脂肪酸含量は、アセトン不溶
物中の脂肪酸部分をメチルエステル化し、ガスクロマト
グラフ装置により分析を行う方法が一般的である。
The acetone-insoluble matter in lecithin used in the present invention has an oleic acid content of 40 to 100% by mass, preferably 50 to 1%, in the total fatty acid composition.
The content of saturated fatty acid in the total constituent fatty acids of the acetone insoluble matter is 0 to 20% by mass, and more preferably 0 to 15% by mass. The content of polyunsaturated fatty acids such as linoleic acid and linolenic acid in all the constituent fatty acids of the acetone-insoluble matter is preferably 0 to 50% by mass, more preferably 0 to 40% by mass. When the oleic acid content is less than 40% by mass, the emulsion stability and flavor of the emulsion composition are adversely affected. Further, when the saturated fatty acid content is more than 20% by mass, the interface of the emulsified particles becomes hard, so that the cooked rice has a hard texture or becomes dull. The polyunsaturated fatty acid is 5
When it is more than 0% by mass, the emulsion stability and the flavor are adversely affected. Furthermore, when the oleic acid content in all the constituent fatty acids of the acetone insoluble matter in lecithin is less than 40% by mass and the saturated fatty acid content in all the constituent fatty acids of the acetone insoluble is more than 20% by mass, emulsification Not only does the cooking oil and fat, which is the raw material of the composition, impair the flavor of cooked rice,
After cooking rice, the rice grains also tend to dry and cool easily. Regarding the fatty acid content in the acetone insoluble matter, a method is generally used in which the fatty acid portion in the acetone insoluble matter is methyl esterified and analyzed by a gas chromatograph.

【0014】本発明に用いるレシチンは、ホスファチジ
ルコリン含量が好ましくは15〜100質量%、より好
ましくは25〜80質量%である。ホスファチジルコリ
ン含量が20質量%未満であると乳化安定性に劣るとと
もに、油浮き等が生じ米飯の風味に悪影響を及ぼす。ホ
スファチジルコリン含量が多いほどO/W型の乳化では
好ましいが、80質量%より多いものは、製造コストが
高価になりあまり実用的ではない。また、アセトン不溶
物中のホスファチジルコリン含量が25〜100質量
%、より好ましくは25〜80質量%のものが好まし
い。
The lecithin used in the present invention has a phosphatidylcholine content of preferably 15 to 100% by mass, more preferably 25 to 80% by mass. If the phosphatidylcholine content is less than 20% by mass, the emulsion stability will be poor, and oil floating will occur, which will adversely affect the flavor of cooked rice. The higher the phosphatidylcholine content is, the more preferable it is for the O / W type emulsification, but the higher phosphatidylcholine content is not very practical because the production cost is high. The content of phosphatidylcholine in the acetone insoluble matter is preferably 25 to 100% by mass, more preferably 25 to 80% by mass.

【0015】本発明の炊飯用乳化組成物中の前記レシチ
ン含量は、アセトン不溶物として0.05〜5質量%、
さらに好ましくは0.1〜3質量%である。0.05質
量%未満であると、十分な乳化能や炊飯米のほぐれ等の
各種効果が得られず、また、5質量%より多い場合は乳
化組成物の粘度が高くなるため使用時のハンドリング性
が低下したり、レシチンの風味が強く出てきてしまい米
飯の風味低下を招く。
The lecithin content of the emulsion composition for cooking rice of the present invention is 0.05 to 5% by mass as an acetone insoluble matter.
More preferably, it is 0.1 to 3 mass%. When it is less than 0.05% by mass, various effects such as sufficient emulsifying ability and loosening of cooked rice cannot be obtained, and when it is more than 5% by mass, the viscosity of the emulsified composition becomes high, so handling at the time of use And the lecithin flavor becomes stronger and the cooked rice flavor is reduced.

【0016】次に、本発明の炊飯用乳化組成物について
説明する。本発明の炊飯用乳化組成物の乳化形態は、O
/W型、W/O型、O/W/O型、W/O/W型等のい
ずれでも良いが、乳化組成物原料として配合する食用油
脂の量が少なくて済み、炊飯時の水に容易に分散して炊
飯への使用が容易であるO/W型乳化形態が最も好まし
い。
Next, the emulsion composition for cooking rice of the present invention will be described. The emulsified form of the emulsion composition for cooking rice of the present invention is O
It may be any of the following types: / W type, W / O type, O / W / O type, W / O / W type, etc., but the amount of edible oil / fat mixed as a raw material for the emulsified composition is small, and it is suitable for water when cooking The O / W type emulsified form, which is easily dispersed and easily used for cooking rice, is most preferable.

【0017】本発明の炊飯用乳化組成物は、前記レシチ
ン、食用油脂、多価アルコール、エタノール、水を含有
する乳化組成物が好ましい。
The rice cooking emulsion composition of the present invention is preferably an emulsion composition containing the above lecithin, edible oil and fat, polyhydric alcohol, ethanol and water.

【0018】炊飯用乳化組成物に用いる食用油脂とは、
植物油脂、動物油脂、又は合成油脂のことであって、こ
れらの2種以上のものを混合して得られる油脂も含む。
植物油脂としては、大豆油、菜種油、トウモロコシ油、
オリーブ油、ヤシ油、米ぬか油、米油、サフラワー油、
綿実油、ひまわり油、小麦胚芽油、パーム油、落花生
油、亜麻仁油、ごま油等が挙げられる。動物油脂として
は、牛脂、豚脂、魚油等が挙げられる。合成油脂として
は、グリセリンと脂肪酸とをエステル結合させることに
より得られた合成トリグリセライド、トリグリセライド
どうしやトリグリセライドを脂肪酸エチルエステル、脂
肪酸メチルエステル等の単鎖アルコール脂肪酸エステル
とエステル交換することにより得られるエステル交換油
脂、水素添加処理により得られた水添油脂等がある。本
発明の炊飯用乳化組成物に用いる食用油脂としては、離
形性、風味、乳化組成物の粘度という点から中鎖脂肪酸
トリグリセリドを使用するのが最も好ましい。本発明の
炊飯用乳化組成物中の食用油脂の含量は、好ましくは2
0〜50質量%、さらに好ましくは30〜40質量%で
ある。20質量%未満であると、米への添加量を多くし
なけば離型性等の効果が得られず、また、50質量%よ
り多いと乳化組成物の粘度が高くなり、製造及び使用面
で適切ではない。
The edible oil and fat used in the emulsion composition for cooking rice is
It is a vegetable oil, an animal oil, or a synthetic oil, and includes an oil obtained by mixing two or more of these.
Vegetable fats and oils include soybean oil, rapeseed oil, corn oil,
Olive oil, coconut oil, rice bran oil, rice oil, safflower oil,
Examples include cottonseed oil, sunflower oil, wheat germ oil, palm oil, peanut oil, linseed oil, sesame oil and the like. Animal fats and oils include beef tallow, lard, fish oil and the like. As the synthetic fats and oils, transesterification obtained by transesterifying a synthetic triglyceride obtained by ester-bonding glycerin with a fatty acid, triglyceride or triglyceride with a single-chain alcohol fatty acid ester such as fatty acid ethyl ester or fatty acid methyl ester Examples include fats and oils, hydrogenated fats and oils obtained by hydrogenation treatment. As the edible oil and fat used in the emulsified composition for cooking rice of the present invention, it is most preferable to use a medium-chain fatty acid triglyceride from the viewpoint of releasability, flavor and viscosity of the emulsified composition. The content of edible oil / fat in the emulsion composition for cooking rice of the present invention is preferably 2
It is 0 to 50% by mass, more preferably 30 to 40% by mass. If it is less than 20% by mass, effects such as releasability cannot be obtained unless the amount added to rice is increased, and if it is more than 50% by mass, the viscosity of the emulsified composition becomes high, and the production and usage Is not appropriate.

【0019】炊飯用乳化組成物に用いる多価アルコール
とは、水酸基を2個以上有するアルコールのことであっ
て、例えば、ショ糖、グリセリン、ポリグリセリン、ソ
ルビトール、還元澱粉糖化物等が挙げられる。これらは
数%から数10%の水を含んでいる場合があるため、炊
飯用乳化組成物中の含量は、固形分として好ましくは3
0〜70質量%、さらに好ましくは35〜55質量%で
ある。30質量%未満であると、乳化安定性が悪くな
り、また、70質量%より多いと乳化組成物の粘度が高
くなり、製造及び使用面で適切ではない。
The polyhydric alcohol used in the emulsion composition for cooking rice is an alcohol having two or more hydroxyl groups, and examples thereof include sucrose, glycerin, polyglycerin, sorbitol, reduced starch saccharified products and the like. Since these may contain water of several% to several tens%, the content in the emulsion composition for cooking rice is preferably 3 as solid content.
It is 0 to 70% by mass, more preferably 35 to 55% by mass. If it is less than 30% by mass, the emulsion stability will be poor, and if it is more than 70% by mass, the viscosity of the emulsified composition will be high, which is not suitable in terms of production and use.

【0020】炊飯用乳化組成物のエタノールの含有量
は、好ましくは0.3〜3質量%、さらに好ましくは
0.5〜2質量%である。これにより、乳化組成物の衛
生性が向上する。
The content of ethanol in the emulsion composition for cooking rice is preferably 0.3 to 3% by mass, more preferably 0.5 to 2% by mass. This improves the hygiene of the emulsified composition.

【0021】炊飯用乳化組成物の水の含有量は、好まし
くは0.5〜30質量%、さらに好ましくは10〜25
質量%である。炊飯用乳化組成物中の水の含有量は、ア
マミール(東和化成工業株式会社製)やソルビットL−
70(東和化成工業株式会社製)のように30質量%の
水を含む原料のように水を多く含む原料を使用するとき
は、その水も考慮して含有させる。炊飯用乳化組成物の
水の含有量が0.5質量%未満であると、乳化が困難に
なり、また、30質量%より多いと乳化組成物の粘度が
著しく低下し、乳化安定性が低下するからである。
The water content of the emulsion composition for cooking rice is preferably 0.5 to 30% by mass, more preferably 10 to 25.
It is% by mass. The content of water in the emulsified composition for cooking rice is Amamiru (manufactured by Towa Kasei Kogyo Co., Ltd.) or Solbit L-
When a raw material containing a large amount of water such as 70 (manufactured by Towa Kasei Kogyo Co., Ltd.) containing 30% by mass of water is used, the water is also taken into consideration. If the water content of the emulsified composition for cooking rice is less than 0.5% by mass, emulsification becomes difficult, and if it exceeds 30% by mass, the viscosity of the emulsified composition is remarkably reduced and the emulsion stability is deteriorated. Because it does.

【0022】炊飯用乳化組成物の多価アルコールの含有
量は、多価アルコール、エタノール、水からなる水相中
の固形分として60〜100質量%であることが好まし
い。60質量%未満であると、水分活性が上昇すること
により、衛生性が低下し好ましくない。
The polyhydric alcohol content of the emulsion composition for cooking rice is preferably 60 to 100% by mass as the solid content in the aqueous phase consisting of the polyhydric alcohol, ethanol and water. If it is less than 60% by mass, the water activity is increased, which lowers hygiene and is not preferable.

【0023】さらに、本発明の炊飯用乳化油脂組成物に
は、必要に応じてポリグリセリン脂肪酸エステル、モノ
グリセリン脂肪酸エステル、ショ糖脂肪酸エステル等の
乳化剤、ビタミンE、ビタミンC等の酸化防止剤、茶抽
出物等の天然抽出物、各種ビタミン、ミネラル等の栄養
強化剤、調味料、蛋白分解物、酵素、色素、香料等を添
加することができる。特に茶抽出物を加えることによ
り、乳化組成物原料による米飯の風味を低下することを
より防止することが可能となる。
Furthermore, in the emulsified oil and fat composition for cooking rice of the present invention, emulsifiers such as polyglycerin fatty acid ester, monoglycerin fatty acid ester and sucrose fatty acid ester, antioxidants such as vitamin E and vitamin C, if necessary, Natural extracts such as tea extracts, nutritional enhancers such as various vitamins and minerals, seasonings, proteolytic products, enzymes, pigments, flavors and the like can be added. In particular, by adding the tea extract, it is possible to further prevent the flavor of cooked rice from being deteriorated by the raw material of the emulsion composition.

【0024】本発明に用いる茶抽出物とは、茶の葉を含
水エタノールや熱水で抽出し精製したものであり、ポリ
フェノール化合物(カテキン類)を含む。デキストリン
やグリセリン等で製剤化したものも用いることができ、
サンフード(三共株式会社製)、サンフェノン(太陽化
学株式会社製)、サンカトール(太陽化学株式会社
製)、ポリフェノン(三井農林株式会社製)等が挙げら
れる。炊飯用乳化組成物の茶抽出物の含有量は、好まし
くは0.05〜3質量%、さらに好ましくは0.1〜
0.5質量%である。0.05質量%未満であると、米
飯への風味に対し効果が顕れず、また、3質量%より多
いと乳化安定性が低下するからである。
The tea extract used in the present invention is a tea leaf extracted with water-containing ethanol or hot water and purified, and contains a polyphenol compound (catechins). Formulated with dextrin or glycerin can also be used,
Examples include sun hood (manufactured by Sankyo Co., Ltd.), sun phenone (manufactured by Taiyo Kagaku Co., Ltd.), sankatol (manufactured by Taiyo Kagaku Co., Ltd.), polyphenon (manufactured by Mitsui Norin Co., Ltd.) and the like. The content of the tea extract in the emulsion composition for cooking rice is preferably 0.05 to 3% by mass, and more preferably 0.1 to 3.
It is 0.5% by mass. If it is less than 0.05% by mass, the effect on the flavor of cooked rice will not be manifested, and if it is more than 3% by mass, the emulsion stability will decrease.

【0025】本発明の炊飯用乳化組成物の製造方法は、
特に限定されるものではなく、通常広く実施される製造
方法を用いることができる。以下にO/W型での本発明
の炊飯用乳化組成物の製造方法の例を示す。アセトン不
溶物の全構成脂肪酸中のオレイン酸含量が40〜100
質量%、かつ、アセトン不溶物の全構成脂肪酸中の飽和
脂肪酸含量が0〜20%質量であるレシチンを、50℃
〜70℃に加熱させた多価アルコール、エタノール、水
等を含有する水相に均一に分散させた後、ホモミキサー
等で攪拌しながら食用油脂を徐々に滴下し予備乳化を行
う。この予備乳化組成物を高圧ホモジナイザ−等を用い
て数μm以下の粒子径となるように均質化処理すること
により、本発明の炊飯用乳化組成物を得る。必要であれ
ば均質化の後、殺菌を行っても良い。
The method for producing the emulsion composition for cooking rice of the present invention is as follows:
It is not particularly limited, and a manufacturing method that is generally widely used can be used. The following is an example of a method for producing the emulsion composition for cooking rice of the present invention in an O / W type. The oleic acid content in all the constituent fatty acids of the acetone insoluble matter is 40 to 100
Mass%, lecithin having a saturated fatty acid content of 0 to 20% by mass in all constituent fatty acids of the acetone-insoluble matter is treated at 50 ° C.
After being uniformly dispersed in an aqueous phase containing polyhydric alcohol, ethanol, water, etc. heated to ˜70 ° C., edible oils and fats are gradually dropped while stirring with a homomixer or the like to carry out preliminary emulsification. The pre-emulsified composition is homogenized with a high pressure homogenizer or the like so that the particle size is several μm or less, to obtain the emulsified composition for cooking rice of the present invention. If necessary, sterilization may be performed after homogenization.

【0026】本発明の炊飯用乳化組成物の使用方法とし
て、次の方法が例示できる。炊飯容器に洗米した米と水
を加え、そこへ本発明の炊飯用乳化組成物を添加する
か、先に乳化組成物を炊飯容器に入れてから、洗米と水
を加え炊飯を開始する。炊飯を開始する前に洗米と水と
乳化組成物を混合しておくことで、乳化組成物がより均
一に分散し、高い効果が得られようになる。
The following method can be exemplified as a method for using the emulsion composition for cooking rice of the present invention. Washed rice and water are added to a rice cooking container, and the emulsion composition for rice cooking of the present invention is added thereto, or the emulsified composition is first put in a rice cooking container, and then rice is washed and water is added to start rice cooking. By mixing washed rice, water and the emulsified composition before starting rice cooking, the emulsified composition is more uniformly dispersed and a high effect can be obtained.

【0027】本発明の炊飯用乳化組成物の炊飯時の使用
量は、米(固形分)に対して0.01〜3質量%が好ま
しく、より好ましくは0.05〜2質量%である。添加
量が0.01質量%より少ないと添加効果が十分に得ら
れず、3質量%以上添加した場合は更なる効果は期待で
きないばかりか、米飯の風味に悪影響を及ぼす可能性が
ある。
The amount of the emulsion composition of the present invention used for cooking rice is preferably 0.01 to 3% by mass, and more preferably 0.05 to 2% by mass with respect to rice (solid content). If the addition amount is less than 0.01% by mass, the effect of addition is not sufficiently obtained, and if 3% by mass or more is added, no further effect can be expected, and the flavor of cooked rice may be adversely affected.

【0028】[0028]

【実施例】以下本発明を更に詳細に説明するが、本発明
はこれらの実施例に限定されるものではない。
The present invention will be described in more detail below, but the present invention is not limited to these examples.

【0029】実施例1 低エルシン酸菜種を溶剤抽出して得た粗油を常法により
脱ガム処理し遠心分離して油さいを得た。薄膜乾燥機で
脱水後、得られた粗レシチンに対し95(V/V)%含
水エタノール6倍量を加えて、10分間40℃で攪拌し
た。1時間静置後、上層をデカンテーションで分離し、
この操作を2回繰り返した。分離した上層部のエタノー
ルをエバポレーターで留去し さらに減圧下40℃にて
乾燥を行い低エルシン酸菜種レシチンを得た。このレシ
チンのアセトン不溶物は56質量%、アセトン不溶物中
の構成脂肪酸はパルミチン酸8質量%、ステアリン酸2
質量%、オレイン酸62質量%、リノール酸22質量
%、リノレン酸6質量%(内飽和脂肪酸10質量%)で
あり、レシチン中のホスファチジルコリン含量は34質
量%であった。このレシチンを用いて表1の配合で以下
の方法により乳化組成物を調製した。水相として、レシ
チン、ソルビトール、エタノールを均一に混合し、水
相、油相をそれぞれ65℃に加温した。水相をホモミキ
サー6000rpmで攪拌ながら、水相の中に油相を徐
々に滴下した。完全に油相を水相に投入した後、引き続
いて、ホモミキサー6000rpmで20分間攪拌を行
った。予備乳化後、高圧ホモジナイザー200kg/c
、3パスで均質化し乳化組成物を得た。得られた乳
化組成物を米(固形分)に対して1質量%添加し炊飯を
行った。
Example 1 A crude oil obtained by solvent-extracting low erucic acid rapeseed was degummed by a conventional method and centrifuged to obtain an oil syrup. After dehydration with a thin film drier, 6 times amount of 95 (V / V)% water-containing ethanol was added to the obtained crude lecithin, and the mixture was stirred at 40 ° C. for 10 minutes. After standing for 1 hour, the upper layer is separated by decantation,
This operation was repeated twice. The separated upper layer ethanol was distilled off by an evaporator and further dried at 40 ° C. under reduced pressure to obtain low erucic acid rapeseed lecithin. Acetone insoluble matter of this lecithin is 56% by mass, constituent fatty acids in the acetone insoluble matter are palmitic acid 8% by mass, stearic acid 2
% By mass, oleic acid by 62% by mass, linoleic acid by 22% by mass, linolenic acid by 6% by mass (internal saturated fatty acid by 10% by mass), and the phosphatidylcholine content in lecithin was 34% by mass. Using this lecithin, an emulsion composition was prepared according to the formulation shown in Table 1 by the following method. As the aqueous phase, lecithin, sorbitol, and ethanol were uniformly mixed, and the aqueous phase and the oil phase were each heated to 65 ° C. The oil phase was gradually dropped into the water phase while stirring the water phase at 6000 rpm with a homomixer. After the oil phase was completely added to the water phase, the mixture was subsequently stirred at 6000 rpm for homomixer for 20 minutes. After pre-emulsification, high pressure homogenizer 200kg / c
It was homogenized with m 2 and 3 passes to obtain an emulsified composition. The obtained emulsified composition was added to the rice (solid content) in an amount of 1% by mass to cook rice.

【0030】実施例2 実施例1のレシチンを用い、食用油として大豆白絞油の
かわりに脂肪酸組成がカプリル酸:カプリン酸=6:4
の中鎖脂肪酸トリグリセライドを用いて表1の配合で、
実施例1と同様な方法により乳化組成物を調整し、得ら
れた乳化組成物を米(固形分)に対して1質量%添加し
炊飯を行った。
Example 2 Using the lecithin of Example 1, the fatty acid composition was caprylic acid: capric acid = 6: 4 instead of soybean white squeezing oil as the edible oil.
Using the medium chain fatty acid triglyceride in the formulation of Table 1,
An emulsified composition was prepared by the same method as in Example 1, and 1 mass% of the obtained emulsified composition was added to rice (solid content) to cook rice.

【0031】実施例3 実施例1のレシチンを用い、食用油として大豆白絞油の
かわりに脂肪酸組成がカプリル酸:カプリン酸=6:4
の中鎖脂肪酸トリグリセライドを用い、また天然抽出物
として茶抽出物も加え、表1の配合で実施例1と同様な
方法により乳化組成物を調製し、得られた乳化組成物を
米(固形分)に対して1質量%添加し炊飯を行った。
Example 3 The lecithin of Example 1 was used, and the fatty acid composition was caprylic acid: capric acid = 6: 4 instead of soybean white squeezing oil as the edible oil.
A medium-chain fatty acid triglyceride was used, and a tea extract was also added as a natural extract, and an emulsion composition was prepared in the same manner as in Example 1 with the composition shown in Table 1, and the obtained emulsion composition was mixed with rice (solid content). ) Was added and 1% by mass was added to cook rice.

【0032】実施例4 ひまわり種子を溶剤抽出して得た粗油を常法により脱ガ
ム処理し遠心分離して油さいを得た。薄膜乾燥機で脱水
後、得られた粗レシチンに対し10倍量の5℃のアセト
ンを加えて30分間攪拌し、静置後アセトン層をデカン
テーションで分別した。この操作をさらに2回繰り返し
た。沈殿物に残存するアセトンを減圧乾燥で除去した
後、乾燥物に対しヘキサン:エタノール=8:2の溶媒
を質量比で4倍量加え、10%パラジウム−炭素触媒を
レシチンに対し0.05質量%加え、水素圧力1KP
a、液温40℃で1時間水素添加を行った。触媒ろ過及
び溶剤除去を行い、微水添ひまわりレシチンを得た。こ
のレシチンのアセトン不溶物は97質量%、アセトン不
溶物中の構成脂肪酸はパルミチン酸14質量%、ステア
リン酸5質量%、オレイン酸44質量%、リノール酸3
7質量%(内飽和脂肪酸19質量%)、レシチン中のホ
スファチジルコリン含量は43質量%であった。このレ
シチンを用いて表1の配合で、実施例1と同様な方法に
より乳化組成物を調製し、得られた乳化組成物を米(固
形分)に対して1質量%添加し炊飯を行った。
Example 4 Crude oil obtained by solvent-extracting sunflower seeds was degummed by a conventional method and centrifuged to obtain an oil syrup. After dehydration with a thin film drier, 10 times the amount of acetone at 5 ° C. was added to the obtained crude lecithin and the mixture was stirred for 30 minutes. After standing, the acetone layer was separated by decantation. This operation was repeated twice more. After removing the acetone remaining in the precipitate by drying under reduced pressure, a solvent of hexane: ethanol = 8: 2 was added to the dried product in a four-fold amount by mass ratio, and 10% palladium-carbon catalyst was added to 0.05 mass of lecithin. %, Hydrogen pressure 1KP
Hydrogen was added at a liquid temperature of 40 ° C. for 1 hour. Catalyst filtration and solvent removal were performed to obtain slightly hydrogenated sunflower lecithin. Acetone insoluble matter of this lecithin is 97% by mass, and constituent fatty acids in the acetone insoluble matter are 14% by mass of palmitic acid, 5% by mass of stearic acid, 44% by mass of oleic acid, and 3 of linoleic acid.
The amount of phosphatidylcholine in the lecithin was 7% by mass (internal saturated fatty acid: 19% by mass) and 43% by mass. Using this lecithin, with the formulation shown in Table 1, an emulsified composition was prepared in the same manner as in Example 1, and 1 mass% of the obtained emulsified composition was added to rice (solid content) to cook rice. .

【0033】[0033]

【表1】 [Table 1]

【0034】比較例1 高純度粉末大豆レシチン(日清製油株式会社製、ベイシ
スLP−20)は、アセトン不溶物98質量%、アセト
ン不溶物中の構成脂肪酸がパルミチン酸19質量%、ス
テアリン酸5質量%、オレイン酸14質量%、リノール
酸56質量%、リノレン酸6質量%(内飽和脂肪酸24
質量%)、レシチン中のホスファチジルコリン含量31
質量%であった。このレシチンを用いて表2の配合で、
実施例1と同様な方法により乳化組成物を調製し、得ら
れた乳化組成物を米(固形分)に対して1質量%添加し
炊飯を行った。
Comparative Example 1 High-purity soybean lecithin (manufactured by Nisshin Oil Co., Ltd., Basis LP-20) contained 98% by mass of acetone insoluble matter, 19% by mass of palmitic acid in the acetone insoluble matter and 5% of stearic acid. Mass%, oleic acid 14 mass%, linoleic acid 56 mass%, linolenic acid 6 mass% (internal saturated fatty acid 24
Mass%), phosphatidylcholine content in lecithin 31
It was mass%. Using this lecithin in the formulation of Table 2,
An emulsified composition was prepared by the same method as in Example 1, and 1% by mass of the obtained emulsified composition was added to rice (solid content) to cook rice.

【0035】比較例2 アルコール抽出大豆レシチン(日清製油株式会社製、ベ
イシスLG−40)は、アセトン不溶物57質量%、ア
セトン不溶物中の構成脂肪酸がパルミチン酸22質量
%、ステアリン酸5質量%、オレイン酸11質量%、リ
ノール酸58質量%、リノレン酸4質量%(内飽和脂肪
酸27質量%)、レシチン中のホスファチジルコリン含
量38質量%であった。このレシチンを用いて表2の配
合で、実施例1と同様な方法により乳化組成物を調製
し、得られた乳化組成物を米(固形分)に対して1質量
%添加し炊飯を行った。
Comparative Example 2 Alcohol-extracted soybean lecithin (manufactured by Nisshin Oil Co., Ltd., Basis LG-40) has an acetone insoluble matter of 57% by mass, a constituent fatty acid in the acetone insoluble matter of 22% by mass palmitic acid, and 5% by mass of stearic acid. %, Oleic acid 11% by mass, linoleic acid 58% by mass, linolenic acid 4% by mass (internal saturated fatty acid 27% by mass), and the content of phosphatidylcholine in lecithin was 38% by mass. Using this lecithin, with the formulation shown in Table 2, an emulsified composition was prepared in the same manner as in Example 1, and 1 mass% of the obtained emulsified composition was added to rice (solid content) to cook rice. .

【0036】比較例3 比較例1のレシチンを用い、食用油として大豆白絞油の
かわりに脂肪酸組成がカプリル酸:カプリン酸=6:4
の中鎖脂肪酸トリグリセライドを用い、また天然抽出物
として茶抽出物も加え、表2の配合で、実施例1と同様
な方法により乳化組成物を調製し、この乳化組成物を米
(固形分)に対して1質量%添加し炊飯を行った。
Comparative Example 3 The lecithin of Comparative Example 1 was used, and the fatty acid composition was caprylic acid: capric acid = 6: 4 instead of soybean white squeezing oil as the edible oil.
A medium-chain fatty acid triglyceride was used, and a tea extract was also added as a natural extract, and an emulsion composition was prepared in the same manner as in Example 1 according to the formulation shown in Table 2, and the emulsion composition was mixed with rice (solid content). 1% by mass was added to and cooked rice.

【0037】比較例4 乾燥卵黄に5倍量のクロロホルム:メタノール=1:1
の溶媒を加え、30分間20℃で攪拌した後、30分間
静置後、デカンテーションで上層を分離した。分離した
上層の溶媒をエバポレーターで分離し、得られた油分に
対し10倍量の5℃のアセトンを加え、静置後、アセト
ン層をデカンテーションで分別した。この操作をさらに
2回繰り返した。沈殿物に残存するアセトンを減圧乾燥
で除去した後、乾燥物に対し残存するアセトンを減圧乾
燥し卵黄レシチンを得た。このレシチンのアセトン不溶
物は96質量%、アセトン不溶物中の構成脂肪酸はパル
ミチン酸27質量%、ステアリン酸9質量%、オレイン
酸44質量%、リノール酸10質量%、その他10質量
%(内飽和脂肪酸36質量%)、レシチン中のホスファ
チジルコリン含量は71質量%であった。このレシチン
を用いて表2の配合で、実施例1と同様な方法により乳
化組成物を調製し、得られた乳化組成物を米(固形分)
に対して1質量%添加し炊飯を行った。
Comparative Example 4 Dried egg yolk with 5 volumes of chloroform: methanol = 1: 1
The solvent was added, the mixture was stirred for 30 minutes at 20 ° C., allowed to stand for 30 minutes, and then the upper layer was separated by decantation. The separated upper layer solvent was separated by an evaporator, 10 times amount of acetone at 5 ° C. was added to the obtained oil, and the mixture was left standing and then the acetone layer was separated by decantation. This operation was repeated twice more. After removing the acetone remaining in the precipitate by drying under reduced pressure, the remaining acetone was dried under reduced pressure in the dried product to obtain egg yolk lecithin. Acetone insoluble matter of this lecithin is 96% by mass, constituent fatty acids in the acetone insoluble matter are 27% by mass of palmitic acid, 9% by mass of stearic acid, 44% by mass of oleic acid, 10% by mass of linoleic acid, and 10% by mass of others (internal saturation). The fatty acid (36% by mass) and the phosphatidylcholine content in lecithin were 71% by mass. Using this lecithin, with the formulation shown in Table 2, an emulsion composition was prepared in the same manner as in Example 1, and the obtained emulsion composition was treated with rice (solid content).
1% by mass was added to and cooked rice.

【0038】比較例5 ひまわり種子を溶剤抽出して得た粗油を常法により脱ガ
ム処理し遠心分離して油さいを得た。薄膜乾燥機で脱水
後、得られた粗レシチンに対し10倍量の5℃のアセト
ンを加えて30分間攪拌し、静置後アセトン層をデカン
テーションで分別した。この操作をさらに2回繰り返し
た。沈殿物に残存するアセトンを減圧乾燥で除去し、ひ
まわりレシチンを得た。このレシチンのアセトン不溶物
は97質量%、アセトン不溶物中の構成脂肪酸はパルミ
チン酸13質量%、ステアリン酸5質量%、オレイン酸
19質量%、リノール酸63質量%、リノレン酸2質量
%(内飽和脂肪酸18質量%)、レシチン中のホスファ
チジルコリン含量は43質量%であった。このレシチン
を用いて表2の配合で、実施例1と同様な方法により乳
化組成物を調製し、この乳化組成物を米(固形分)に対
して1質量%添加し炊飯を行った。
Comparative Example 5 A crude oil obtained by solvent-extracting sunflower seeds was degummed by a conventional method and centrifuged to obtain an oil syrup. After dehydration with a thin film drier, 10 times the amount of acetone at 5 ° C. was added to the obtained crude lecithin and the mixture was stirred for 30 minutes. After standing, the acetone layer was separated by decantation. This operation was repeated twice more. Acetone remaining in the precipitate was removed by vacuum drying to obtain sunflower lecithin. Acetone insoluble matter of this lecithin is 97% by mass, and constituent fatty acids in the acetone insoluble matter are 13% by mass of palmitic acid, 5% by mass of stearic acid, 19% by mass of oleic acid, 63% by mass of linoleic acid and 2% by mass of linolenic acid. The saturated fatty acid content was 18% by mass) and the content of phosphatidylcholine in lecithin was 43% by mass. Using this lecithin, with the formulation shown in Table 2, an emulsified composition was prepared in the same manner as in Example 1, and 1% by mass of this emulsified composition was added to rice (solid content) to cook rice.

【0039】[0039]

【表2】 [Table 2]

【0040】実施例1〜4、比較例1〜5で炊いた米飯
を下記方法にて評価を実施した。 米飯の風味 米飯100gをビーカーにとり、パネラー10名にて各
米飯の風味を比較し、「良い」を5点、「やや良い」を
4点、「普通」を3点、「やや悪い」を2点、「悪い」
を1点で採点し、10名の平均点で評価した。 米飯の食感 米飯を20分間室温で放置後、パネラー10名にて各米
飯の食感を比較し、「良い」を5点、「やや良い」を4
点、「普通」を3点、「やや悪い」を2点、「悪い」を
1点で採点し、10名の平均点で評価た。 米飯のさめにくさ 冷凍した米飯100gをビーカーにとり、電子レンジで
2分間加熱した。直後から15分後まで5分ごとに中心
温度を測定した。
The cooked rice cooked in Examples 1 to 4 and Comparative Examples 1 to 5 was evaluated by the following method. Flavor of cooked rice Take 100 g of cooked rice in a beaker, and compare the flavors of each cooked rice with 10 panelists. 5 points are "good", 4 points are "somewhat good", 3 points are "normal" and 2 points are "somewhat bad". Point, "bad"
Was scored at 1 point and evaluated by the average score of 10 people. Texture of cooked rice After leaving cooked rice for 20 minutes at room temperature, 10 panelists compared the texture of each cooked rice, 5 points were "good" and 4 points were "somewhat good"
The average score of 10 people was evaluated by scoring points, "ordinary" with 3 points, "slightly bad" with 2 points, and "bad" with 1 point. 100 g of frozen cooked rice was placed in a beaker and heated in a microwave oven for 2 minutes. The core temperature was measured every 5 minutes from immediately after to 15 minutes later.

【0041】[0041]

【表3】 [Table 3]

【0042】表3から分かるように、実施例1〜4の炊
飯用乳化組成物を使用することにより、風味、食感とも
良好の米飯が得られた。特に食用油脂として中鎖脂肪酸
トリグリセライドを用いたものが良好であり、茶抽出物
を加えたものは更に良好な風味であった。比較例1〜5
においてはパネラーから「米飯に異臭を感じる」、「パ
サついていると感じられた」というコメントがあった。
米飯のほぐれ性や付着性については実施例1〜4及び比
較例1〜5で殆ど差はみられなかった。
As can be seen from Table 3, cooked rice having good flavor and texture was obtained by using the emulsion compositions for cooking rice of Examples 1 to 4. Particularly, the one using medium-chain fatty acid triglyceride as the edible oil and fat was good, and the one containing the tea extract had an even better flavor. Comparative Examples 1-5
There was a comment from a panelist that "I felt a strange odor in cooked rice" and "I felt it was dry."
About the loosening property and the adhesive property of cooked rice, there was hardly any difference between Examples 1 to 4 and Comparative Examples 1 to 5.

【0043】[0043]

【表4】 [Table 4]

【0044】表4から分かるように実施例1〜4の炊飯
用乳化組成物は、比較例1〜5の炊飯用乳化組成物と比
較して、加熱直後の温度はほぼ同様であったが、あきら
かに冷めにくいことが確認された。
As can be seen from Table 4, the temperature of the emulsion compositions for cooking rice of Examples 1 to 4 was almost the same as that of the emulsion compositions for cooking rice of Comparative Examples 1 to 5, although the temperature immediately after heating was almost the same. It was clearly confirmed that it was difficult to cool.

【0045】[0045]

【発明の効果】以上説明したように本発明の乳化組成物
は、これまでの炊飯用乳化組成物と同等な機能を有した
上で、原料として使用する食用油脂の風味による米飯の
風味低下を防止する。また炊飯後の米粒の付着性を低下
させたまま水分の蒸散を防いで食感の低下を防止すると
ともに、米飯を冷めにくくすることができる。
As described above, the emulsified composition of the present invention has a function equivalent to that of conventional emulsified compositions for cooking rice, and further reduces the flavor of cooked rice due to the flavor of the edible oil and fat used as a raw material. To prevent. In addition, it is possible to prevent evaporation of water while reducing the adhesion of rice grains after cooking rice to prevent the texture from being deteriorated, and to make it difficult to cool the cooked rice.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 土川 浩司 神奈川県横浜市磯子区新森町1番地 日清 製油株式会社横浜磯子事業場内 Fターム(参考) 4B023 LC05 LC08 LE11 LK03 LK05 LK12 LP11    ─────────────────────────────────────────────────── ─── Continued front page    (72) Inventor Koji Tsuchikawa             Nisshin, No. 1 Shinmorimachi, Isogo Ward, Yokohama City, Kanagawa Prefecture             Refinery Co., Ltd.Yokohama Isogo Plant F term (reference) 4B023 LC05 LC08 LE11 LK03 LK05                       LK12 LP11

Claims (10)

【特許請求の範囲】[Claims] 【請求項1】 アセトン不溶物の全構成脂肪酸中のオレ
イン酸含量が40〜100質量%、かつ、アセトン不溶
物の全構成脂肪酸中の飽和脂肪酸含量が0〜20%質量
であるレシチンを含有することを特徴とする炊飯用乳化
組成物。
1. Lecithin having an oleic acid content of 40 to 100% by mass in the total constituent fatty acids of the acetone insoluble matter and a saturated fatty acid content of 0 to 20% by mass in the total constituent fatty acids of the acetone insoluble matter. An emulsified composition for cooking rice, which is characterized in that
【請求項2】 アセトン不溶物の全構成脂肪酸中の多価
不飽和脂肪酸含量が0〜50質量%であるレシチンを含
有することを特徴とする請求項1記載の炊飯用乳化組成
物。
2. The emulsified composition for cooking rice according to claim 1, further comprising lecithin having a polyunsaturated fatty acid content of 0 to 50% by mass in all constituent fatty acids of the acetone insoluble matter.
【請求項3】 前記炊飯用乳化組成物がO/W型乳化物
であることを特徴とする請求項1又は2に記載の炊飯用
乳化組成物。
3. The emulsion composition for cooking rice according to claim 1, wherein the emulsion composition for cooking rice is an O / W type emulsion.
【請求項4】 前記レシチン中のホスファチジルコリン
の含量が15〜100質量%であることを特徴とする請
求項1〜3に記載の炊飯用乳化組成物。
4. The emulsified composition for cooking rice according to claim 1, wherein the content of phosphatidylcholine in the lecithin is 15 to 100% by mass.
【請求項5】 前記レシチンのアセトン不溶物含量が3
0〜100質量%であることを特徴とする請求項1〜4
に記載の炊飯用乳化組成物。
5. The content of acetone insoluble matter in the lecithin is 3
It is 0-100 mass%, It is characterized by the above-mentioned.
The emulsified composition for cooking rice as described in.
【請求項6】 前記アセトン不溶物中のホスファチジル
コリン含量が25〜100質量%であることを特徴とす
る請求項1〜5に記載の炊飯用乳化組成物。
6. The emulsified composition for cooking rice according to claim 1, wherein the content of phosphatidylcholine in the acetone insoluble matter is 25 to 100% by mass.
【請求項7】 前記炊飯用乳化組成物が、前記レシチ
ン、食用油脂、多価アルコール、エタノール、水を含有
するものであることを特徴とする請求項1〜6に記載の
炊飯用乳化組成物。
7. The emulsion composition for cooking rice according to claim 1, wherein the emulsion composition for cooking rice contains the lecithin, edible oil and fat, polyhydric alcohol, ethanol, and water. .
【請求項8】 前記炊飯用乳化組成物の多価アルコー
ル、エタノール、水を含有する水相中の多価アルコール
含量が、固形分として60〜100質量%であることを
特徴とする請求項1〜7に記載の炊飯用乳化組成物。
8. The polyhydric alcohol content of the polyhydric alcohol, ethanol, and water-containing aqueous phase of the rice cooking emulsion composition is 60 to 100% by mass as a solid content. The emulsified composition for cooking rice according to any one of claims 1 to 7.
【請求項9】 炊飯用乳化組成物全体に対して、レシチ
ン(アセトン不溶物として)含量が0.1〜3質量%、
食用油脂含量が30〜40質量%、多価アルコール(固
形分として)含量が35〜55質量%、エタノール含量
が0.5〜2質量%、水含量10〜25質量%であるこ
とを特徴とする請求項1〜8に記載の炊飯用乳化組成
物。
9. The lecithin (as acetone insoluble matter) content is 0.1 to 3 mass% with respect to the entire emulsion composition for cooking rice.
The edible oil and fat content is 30 to 40% by mass, the polyhydric alcohol (as solid content) content is 35 to 55% by mass, the ethanol content is 0.5 to 2% by mass, and the water content is 10 to 25% by mass. The emulsified composition for cooking rice according to claim 1.
【請求項10】 前記炊飯用乳化組成物が、茶抽出物を
0.05〜3質量%を含有するものであることを特徴と
する請求項1〜9に記載の炊飯用乳化組成物。
10. The emulsion composition for cooking rice according to claim 1, wherein the emulsion composition for cooking rice contains 0.05 to 3% by mass of a tea extract.
JP2002097776A 2002-03-29 2002-03-29 Emulsifying composition for boiling rice Pending JP2003284515A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013051916A (en) * 2011-09-02 2013-03-21 Kao Corp Additive for cooked rice
JP2016195558A (en) * 2015-04-03 2016-11-24 株式会社J−オイルミルズ Animal feed raw material and its use
CN108260677A (en) * 2017-01-04 2018-07-10 日清奥利友集团株式会社 The manufacturing method cooked with fat or oil composition, meal class and meal class
JP2019058086A (en) * 2017-09-25 2019-04-18 日清オイリオグループ株式会社 Fat composition for cooked rice
JPWO2022114126A1 (en) * 2020-11-30 2022-06-02

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04271748A (en) * 1991-02-27 1992-09-28 Nisshin Oil Mills Ltd:The Oil and fat composition
JPH07147914A (en) * 1993-12-01 1995-06-13 Nippon Oil & Fats Co Ltd Loosening agent for processed cereals
JPH07274859A (en) * 1994-04-01 1995-10-24 Nisshin Oil Mills Ltd:The Fats and oils composition for cooking boiled rice
JP2000093098A (en) * 1998-09-28 2000-04-04 Dai Ichi Kogyo Seiyaku Co Ltd Emulsifying agent composition for cooked rice and cooking of rice using the same
JP2001017098A (en) * 1999-07-01 2001-01-23 Kanemasu Ikedaen:Kk Tea for cooked rice, cooked rice and method for preparing cooked rice

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04271748A (en) * 1991-02-27 1992-09-28 Nisshin Oil Mills Ltd:The Oil and fat composition
JPH07147914A (en) * 1993-12-01 1995-06-13 Nippon Oil & Fats Co Ltd Loosening agent for processed cereals
JPH07274859A (en) * 1994-04-01 1995-10-24 Nisshin Oil Mills Ltd:The Fats and oils composition for cooking boiled rice
JP2000093098A (en) * 1998-09-28 2000-04-04 Dai Ichi Kogyo Seiyaku Co Ltd Emulsifying agent composition for cooked rice and cooking of rice using the same
JP2001017098A (en) * 1999-07-01 2001-01-23 Kanemasu Ikedaen:Kk Tea for cooked rice, cooked rice and method for preparing cooked rice

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013051916A (en) * 2011-09-02 2013-03-21 Kao Corp Additive for cooked rice
JP2016195558A (en) * 2015-04-03 2016-11-24 株式会社J−オイルミルズ Animal feed raw material and its use
CN108260677A (en) * 2017-01-04 2018-07-10 日清奥利友集团株式会社 The manufacturing method cooked with fat or oil composition, meal class and meal class
JP2018108052A (en) * 2017-01-04 2018-07-12 日清オイリオグループ株式会社 Fat composition for rice cooking, rice, and method for producing rice
JP2019058086A (en) * 2017-09-25 2019-04-18 日清オイリオグループ株式会社 Fat composition for cooked rice
JP7254439B2 (en) 2017-09-25 2023-04-10 日清オイリオグループ株式会社 Fat and oil composition for cooking rice
JPWO2022114126A1 (en) * 2020-11-30 2022-06-02
WO2022114126A1 (en) * 2020-11-30 2022-06-02 キユーピー株式会社 Cooked-rice improver and method for producing cooked rice
JP7175432B2 (en) 2020-11-30 2022-11-18 キユーピー株式会社 Cooked rice improver and method for producing cooked rice

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