JP2003275544A - Spiral type membrane element and manufacturing method therefor - Google Patents

Spiral type membrane element and manufacturing method therefor

Info

Publication number
JP2003275544A
JP2003275544A JP2002080477A JP2002080477A JP2003275544A JP 2003275544 A JP2003275544 A JP 2003275544A JP 2002080477 A JP2002080477 A JP 2002080477A JP 2002080477 A JP2002080477 A JP 2002080477A JP 2003275544 A JP2003275544 A JP 2003275544A
Authority
JP
Japan
Prior art keywords
hollow tube
membrane
permeation
flow path
elastic body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2002080477A
Other languages
Japanese (ja)
Other versions
JP4070002B2 (en
Inventor
Katsumi Ishii
勝視 石井
Shinichi Jizo
眞一 地蔵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nitto Denko Corp
Original Assignee
Nitto Denko Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nitto Denko Corp filed Critical Nitto Denko Corp
Priority to JP2002080477A priority Critical patent/JP4070002B2/en
Publication of JP2003275544A publication Critical patent/JP2003275544A/en
Application granted granted Critical
Publication of JP4070002B2 publication Critical patent/JP4070002B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

<P>PROBLEM TO BE SOLVED: To provide a spiral type membrane element in which the deviation of a membrane and a flow path material is easily prevented, the workability of fixing the flow path material is excellent and the insertion work of the membrane and the flow path material is facilitated, and the manufacturing method. <P>SOLUTION: In the spiral type membrane element, a laminated body for which a supply side flow path material 2 is interposed on the supply side of an opposing membrane 1 and a transmission side flow path material 4 is interposed on the transmission side of the opposing membrane 1 is wound around a perforated hollow pipe 5 in a spiral shape and sealing structures A1 and A2 for not directly communicating a supply side flow path and a transmission side flow path are provided. The sealing part A2 around the hollow pipe 5 of the sealing structures is composed by interposing an elastic body 6 between the hollow pipe 5 and the membrane 1. <P>COPYRIGHT: (C)2003,JPO

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、種々の流体(液体
あるいは気体)中に存在する特定成分を分離する分離操
作、または液体への気体溶解もしくは液体からの気体放
散といった気液接触操作などに用いられるスパイラル型
膜エレメント及びその製造方法に関する。詳しくは中空
管の周囲の膜との間の封止部の改良に関するものであ
る。
TECHNICAL FIELD The present invention relates to a separation operation for separating a specific component existing in various fluids (liquid or gas), or a gas-liquid contact operation such as gas dissolution into a liquid or gas release from a liquid. The present invention relates to a spiral wound type membrane element and a method for producing the same. More specifically, it relates to an improvement in the sealing portion between the hollow tube and the surrounding membrane.

【0002】[0002]

【従来の技術】従来のスパイラル型膜エレメントは、2
枚の膜の透過側に透過側流路材を介在させて袋状に3辺
を封止した1組みの積層体(膜リーフ)を有孔の中空管
に接続し、接続した積層体を供給側流路材を介在させつ
つスパイラル状に巻回した構造が知られていた。また、
透過側の流路長を短くすべく、複数組みの積層体(膜リ
ーフ)を用いたものも知られている。
2. Description of the Related Art The conventional spiral wound type membrane element has two
A set of laminated bodies (membrane leaves) in which three sides are sealed in a bag shape with a permeation side flow path material interposed on the permeation side of a single membrane is connected to a perforated hollow tube, and the connected lamination is A structure has been known in which a supply-side flow path material is interposed and spirally wound. Also,
It is also known to use a plurality of laminated bodies (membrane leaves) in order to shorten the flow path length on the permeation side.

【0003】後者の基本構造としては、対向する膜の供
給側に供給側流路材を介在させ、対向する膜の透過側に
透過側流路材を介在させた積層体を有孔の中空管にスパ
イラル状に巻回してあり、供給側流路と透過側流路とが
直接連通しないための封止構造を備えるものが一般的で
ある。より具体的には、供給側流路材を膜の分離層側に
挟み込んだ二つ折り膜リーフ及びこれに隣接する透過側
流路材とからなる膜素材群の単数あるいは複数の積層体
を、有孔の中空管の周りに巻き付けたものが既に公知で
ある(例えば米国特許3,417,870号等)。
As the latter basic structure, a laminated body having a supply side channel material on the supply side of the opposing membrane and a permeation side channel material on the permeation side of the opposing membrane is used as a perforated hollow body. It is generally wound around a pipe in a spiral shape, and is generally provided with a sealing structure for preventing direct communication between the supply-side flow passage and the permeation-side flow passage. More specifically, a single or a plurality of laminates of a membrane material group consisting of a bi-folded membrane leaf sandwiching the supply side channel material on the separation layer side of the membrane and a permeation side channel material adjacent thereto are provided. It is already known to wind a hollow tube around a hole (for example, US Pat. No. 3,417,870).

【0004】このようなスパイラル型膜エレメントにお
いて、上記の封止構造として図5に示すような中空管5
の周囲の封止部Bが重要となる。即ち、積層体を中空管
5の周りに巻回すると、膜1と中空管5との間に隙間
(三角巣等)が生じるため、巻回後の工程で当該隙間部
分にエポキシ樹脂、ウレタン樹脂等の接着剤を塗布し
て、硬化等させることで封止部Bを形成する必要があっ
た。
In such a spiral wound type membrane element, the hollow tube 5 as shown in FIG.
The sealing portion B around is important. That is, when the laminated body is wound around the hollow tube 5, a gap (triangular nest or the like) is formed between the membrane 1 and the hollow tube 5, so that an epoxy resin, It is necessary to form the sealing portion B by applying an adhesive such as urethane resin and curing the same.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、このよ
うな従来のスパイラル型膜エレメントの製造方法では、
次のような種々の問題があった。即ち、(1)流動性の
接着剤を塗布するための塗布工程が必要になり、作業工
程が増える、生産効率が低下する、(2)塗布した接着
剤が完全硬化するまでに数十時間要するため、次の工程
に進むのに長い待ち時間が必要になる、(3)空隙部分
の表面だけの塗布であり、シール性の確保という面では
信頼性が薄い、などの問題がある。なお、シール性の低
下は、分離膜の性能上、透過液の汚染や阻止率の低下な
どを生じさせる。
However, in such a conventional method for producing a spiral wound type membrane element,
There were various problems as follows. That is, (1) a coating step for coating a fluid adhesive is required, which increases the number of working steps, reduces production efficiency, and (2) requires several tens of hours until the coated adhesive is completely cured. Therefore, there is a problem that a long waiting time is required to proceed to the next step, (3) the coating is applied only to the surface of the void portion, and reliability is low in terms of ensuring the sealing property. The decrease in the sealing property causes the permeated liquid to be contaminated and the rejection rate to be decreased due to the performance of the separation membrane.

【0006】そこで、本発明の目的は、中空管の周囲の
封止部を形成するための接着剤の塗布工程や硬化の待ち
時間を不要にでき、しかも膜と中空管との間の封止部の
シール性が良好なスパイラル型膜エレメント、及びその
製造方法を提供することにある。
[0006] Therefore, an object of the present invention is to eliminate the need for an adhesive application step for forming a sealing portion around the hollow tube and a waiting time for curing, and moreover, between the membrane and the hollow tube. It is an object of the present invention to provide a spiral wound type membrane element having a good sealing property at a sealing portion, and a method for manufacturing the same.

【0007】[0007]

【課題を解決するための手段】上記目的は、下記の如き
本発明により達成できる。即ち、本発明のスパイラル型
膜エレメントは、対向する膜の供給側に供給側流路材を
介在させ、対向する膜の透過側に透過側流路材を介在さ
せた積層体を有孔の中空管にスパイラル状に巻回してあ
り、供給側流路と透過側流路とが直接連通しないための
封止構造を備えるスパイラル型膜エレメントにおいて、
前記封止構造のうち前記中空管の周囲の封止部が、その
中空管と前記膜との間に弾性体を介在してなることを特
徴とする。
The above object can be achieved by the present invention as described below. That is, the spiral wound type membrane element of the present invention has a laminated body in which a supply-side channel material is interposed on the supply side of the opposing membrane and a permeation-side channel material is interposed on the permeate side of the opposing membrane. In a spiral wound type membrane element, which is spirally wound around an empty tube, and has a sealing structure for the supply side flow passage and the permeation side flow passage not directly communicating with each other,
In the sealing structure, a sealing portion around the hollow tube is characterized in that an elastic body is interposed between the hollow tube and the membrane.

【0008】上記において、前記弾性体が熱可塑性樹脂
の発泡体を含むことが好ましい。
In the above, it is preferable that the elastic body includes a foamed body of a thermoplastic resin.

【0009】一方、本発明のスパイラル型膜エレメント
の製造方法は、有孔の中空管の周囲の封止部を形成する
位置に弾性体を配置する工程と、対向する膜の供給側に
供給側流路材を対向する膜の透過側に透過側流路材を各
々介在させた積層体を形成する工程と、この積層体を前
記中空管に巻回する工程と、その中空管と前記膜との間
で前記弾性体を配置させて中空管の周囲に封止部を形成
する工程と、供給側流路と透過側流路とが直接連通しな
いためのその他の封止構造を形成する工程とを有するこ
とを特徴とする。ここで、その他の封止構造を形成する
工程とは、膜同士などの各部材間の封止を行う工程を指
し、この工程は複数に分けて行ってもよく、各工程は何
れの段階で行ってもよい。
On the other hand, in the method for manufacturing a spiral wound type membrane element of the present invention, a step of arranging an elastic body at a position forming a sealing portion around a perforated hollow tube and a step of supplying the opposite side to a supply side of the membrane are provided. A step of forming a laminate in which the permeate side channel materials are respectively interposed on the permeate sides of the membranes facing the side channel materials, a step of winding the laminate around the hollow tube, and the hollow tube A step of forming the sealing portion around the hollow tube by arranging the elastic body between the membrane and another sealing structure for preventing the supply-side channel and the permeation-side channel from directly communicating with each other. And a forming step. Here, the step of forming another sealing structure refers to a step of sealing between respective members such as films, and this step may be divided into a plurality of steps. You can go.

【0010】上記において、前記弾性体を配置する際
に、熱可塑性樹脂の発泡体を基材とする粘着テープを前
記中空管の周囲に巻回することが好ましい。
In the above, when disposing the elastic body, it is preferable to wind an adhesive tape having a foamed body of a thermoplastic resin as a base material around the hollow tube.

【0011】[作用効果]本発明のスパイラル型膜エレ
メントによると、中空管の周囲の封止部が中空管と膜と
の間に弾性体を介在してなるため、当該封止部を形成す
るための接着剤の塗布工程や硬化の待ち時間を不要にす
ることができる。また、弾性体を配置してあるため、適
度な変形が生じ、中空管と膜との間の間隙を小さくして
封止部のシール性を高めることができる。更に、中空管
と膜との間に弾性体を介在させるため、弾性体の面積を
大きくしてシール面積を大きくすることで、封止部のシ
ール性を高めることができる。
[Operation and Effect] According to the spiral wound type membrane element of the present invention, since the sealing portion around the hollow tube has the elastic body interposed between the hollow tube and the membrane, the sealing portion can be It is possible to eliminate the step of applying the adhesive for forming and the waiting time for curing. Further, since the elastic body is arranged, appropriate deformation occurs, and the gap between the hollow tube and the membrane can be reduced to improve the sealing property of the sealing portion. Further, since the elastic body is interposed between the hollow tube and the membrane, the sealing property of the sealing portion can be improved by increasing the area of the elastic body and increasing the sealing area.

【0012】また、前記弾性体が熱可塑性樹脂の発泡体
を含む場合、発泡体のため変形を大きくして、中空管と
膜との間の間隙をより小さくすることで、封止によるシ
ール性を更に高めることができる。
When the elastic body contains a thermoplastic resin foam, deformation is increased due to the foam, and the gap between the hollow tube and the membrane is made smaller, thereby sealing by sealing. The sex can be further enhanced.

【0013】一方、本発明の製造方法によると、中空管
の周囲の封止部を形成する位置に弾性体を配置して中空
管の周囲の封止部を形成するため、当該封止部を形成す
るための接着剤の塗布工程や硬化の待ち時間を不要にす
ることができる。また、弾性体を用いているため、適度
な変形が生じ、中空管と膜との間の間隙を小さくして封
止部のシール性を高めることができる。更に、予め中空
管の周囲に弾性体を配置するため、弾性体の面積を大き
くしてシール面積を大きくすることで、シール性を高め
ることができる。
On the other hand, according to the manufacturing method of the present invention, since the elastic body is arranged at the position where the sealing portion around the hollow tube is formed to form the sealing portion around the hollow tube, the sealing is performed. It is possible to eliminate the step of applying the adhesive for forming the portion and the waiting time for curing. Further, since the elastic body is used, appropriate deformation occurs, and the gap between the hollow tube and the membrane can be reduced to improve the sealing property of the sealing portion. Furthermore, since the elastic body is previously arranged around the hollow tube, the sealing property can be improved by increasing the area of the elastic body and increasing the sealing area.

【0014】また、前記弾性体を配置する際に、熱可塑
性樹脂の発泡体を基材とする粘着テープを前記中空管の
周囲に巻回する場合、粘着テープを用いるため巻回する
だけで中空管の周囲に弾性体を容易に配置することがで
き、その基材が発泡体のため変形を大きくして、中空管
と膜との間の間隙をより小さくすることで、封止による
シール性を更に高めることができる。
When arranging the elastic body, when an adhesive tape having a foamed body of a thermoplastic resin as a base material is wound around the hollow tube, the adhesive tape is used. The elastic body can be easily placed around the hollow tube, and its base material is foam, so the deformation is increased and the gap between the hollow tube and the membrane is made smaller, thereby sealing. It is possible to further enhance the sealing property.

【0015】[0015]

【発明の実施の形態】以下、本発明の実施の形態につい
て、図面を参照しながら説明する。図1(a)〜図3
(b)は、本発明のスパイラル型膜エレメントの製造方
法の一例を模式的に示す工程図である。まず、本発明の
製造方法について説明する。
BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of the present invention will be described below with reference to the drawings. 1 (a) to 3
(B) is a process drawing which shows typically an example of the manufacturing method of the spiral type membrane element of this invention. First, the manufacturing method of the present invention will be described.

【0016】本発明の製造方法は、図1(a)に示すよ
うに、有孔の中空管5の周囲の封止部A2を形成する位
置に弾性体6を配置する工程を有する。封止部A2の形
成位置は、膜1の幅に応じて決定され、膜1の両端が配
置される位置の付近となる。
As shown in FIG. 1 (a), the manufacturing method of the present invention has a step of disposing the elastic body 6 at the position where the sealing portion A2 is formed around the perforated hollow tube 5. The formation position of the sealing portion A2 is determined according to the width of the film 1, and is near the position where both ends of the film 1 are arranged.

【0017】中空管5としては、従来公知のものが何れ
も使用でき、例えば金属、繊維強化プラスチック、プラ
スチックまたはセラミックスなどからなる、有孔の中空
管であればよい。孔5aの形状、大きさ、位置、個数な
ども膜種類などに応じて、従来公知のものがいずれも採
用できる。但し、弾性体6との接着性を高める上で、繊
維強化プラスチック、プラスチックが好ましい。
As the hollow tube 5, any conventionally known tube can be used, for example, a hollow tube made of metal, fiber reinforced plastic, plastic, ceramics or the like and having a hole. Regarding the shape, size, position, number, etc. of the holes 5a, any conventionally known one can be adopted depending on the kind of the film. However, in order to improve the adhesiveness with the elastic body 6, fiber reinforced plastic or plastic is preferable.

【0018】弾性体6を構成する材料としては、熱可塑
性エラストマー、熱可塑性樹脂、もしくは熱硬化性樹脂
の部分硬化物、ゴムの部分架橋物、又はそれらの発泡体
などが挙げられるが、熱可塑性樹脂の発泡体を含むもの
が好ましい。特に、熱可塑性樹脂の発泡体を基材とする
粘着テープ(両面テープを含む)を用いて、中空管5の
周囲にそれを巻回することで、弾性体6を配置するのが
好ましい。 粘着テープを用いる場合、10〜500K
Paの圧力で1〜数十回分巻付けるのが好ましい。ま
た、粘着テープの粘着剤としては、アクリル系、ゴム
系、シリコーン系の粘着剤などが何れも使用できるが、
アクリル系粘着剤が好ましい。
Examples of the material constituting the elastic body 6 include a thermoplastic elastomer, a thermoplastic resin, or a partially cured product of a thermosetting resin, a partially crosslinked product of rubber, or a foam thereof, and the like. Those containing a resin foam are preferred. In particular, it is preferable to arrange the elastic body 6 by winding it around the hollow tube 5 using an adhesive tape (including a double-sided tape) having a thermoplastic resin foam as a base material. 10 to 500K when using adhesive tape
It is preferable to wind at a pressure of Pa for 1 to several tens of times. As the adhesive for the adhesive tape, any of acrylic, rubber, and silicone adhesives can be used.
Acrylic adhesives are preferred.

【0019】弾性体6の厚みは、0.01〜20mmが
好ましく、0.1〜10mmがより好ましい。弾性体6
の厚みが小さすぎると、中空管と膜との間の間隙を小さ
くする効果が少なくなる傾向があり、厚みが大きすぎる
と、弾性体6の変形が大きくなり、有効膜面積の減少や
膜の変形などが生じる傾向がある。
The thickness of the elastic body 6 is preferably 0.01 to 20 mm, more preferably 0.1 to 10 mm. Elastic body 6
If the thickness is too small, the effect of reducing the gap between the hollow tube and the membrane tends to be reduced, and if the thickness is too large, the elastic body 6 is deformed significantly, and the effective membrane area is reduced or the membrane is reduced. Deformation tends to occur.

【0020】弾性体6を配置する幅は、5〜100mm
が好ましく、10〜50mmがより好ましい。弾性体6
の幅が小さすぎると、シール性が不十分となる傾向があ
り、弾性体6の幅が大きすぎると、透過側流路が狭くな
り、また有効膜面積の減少する傾向がある。
The width for disposing the elastic body 6 is 5 to 100 mm.
Is preferable, and 10-50 mm is more preferable. Elastic body 6
If the width is too small, the sealing property tends to be insufficient, and if the width of the elastic body 6 is too large, the permeate side flow channel tends to be narrow, and the effective membrane area tends to decrease.

【0021】本発明の製造方法は、図1(b)に示すよ
うに、対向する膜1の供給側に供給側流路材2を対向す
る膜の透過側に透過側流路材4を各々介在させた積層体
S2を形成する工程を有する。本実施形態では、複数の
透過側流路材4の一端部を多孔シート10に所定間隔で
固着し、固着された透過側流路材4の間に膜1及び供給
側流路材2を挿入して積層体S2を形成する例を示す。
In the manufacturing method of the present invention, as shown in FIG. 1 (b), the supply side channel material 2 is provided on the supply side of the opposing membrane 1 and the permeation side channel material 4 is provided on the permeation side of the opposing membrane. There is a step of forming the interposed laminated body S2. In this embodiment, one ends of a plurality of permeate-side channel members 4 are fixed to the porous sheet 10 at predetermined intervals, and the membrane 1 and the supply-side channel member 2 are inserted between the fixed permeate-side channel members 4. An example of forming the laminated body S2 is shown.

【0022】本発明に用いられる膜1は、透過に一定以
上の圧力損失を有する多孔質膜又は非多孔質膜であれば
よく、具体的には、精密濾過膜、限外濾過膜、ナノ濾過
膜、逆浸透膜、イオン交換膜、気体分離膜、透析膜、な
どが挙げられる。膜の材質としては、ポリプロピレン、
ポリエチレン等のポリオレフィン、ポリスルホン、ポリ
エーテルスルホン、ポリスチレン、ポリアクリロニトリ
ル、酢酸セルロース、ポリアミド、ポリイミド、フッ素
樹脂等の高分子膜を用いることができる。
The membrane 1 used in the present invention may be a porous membrane or a non-porous membrane having a pressure loss of a certain level or more in permeation, and specifically, it is a microfiltration membrane, an ultrafiltration membrane or a nanofiltration. Membranes, reverse osmosis membranes, ion exchange membranes, gas separation membranes, dialysis membranes and the like can be mentioned. The material of the film is polypropylene,
Polymer films such as polyolefin such as polyethylene, polysulfone, polyether sulfone, polystyrene, polyacrylonitrile, cellulose acetate, polyamide, polyimide, fluororesin, etc. can be used.

【0023】供給側流路材2としては、スパイラル型膜
エレメントとして従来公知の供給側流路材が何れも使用
でき、ネット、メッシュ、線材織物、繊維織物、不織
布、溝付きシート、波形シートなど何れでもよい。ま
た、その材質もポリプロピレン、ポリエチレン、ポリエ
チレンテレフタレート(PET)、ポリアミド等の樹脂
の他、天然高分子、ゴム、金属など何れでもよい。但
し、分離操作等の際に流路材からの溶出が問題となる場
合、それを考慮して材質を選択するのが好ましい。
As the supply side flow path member 2, any conventionally known supply side flow path material as a spiral wound type membrane element can be used, such as a net, a mesh, a wire woven fabric, a fiber woven fabric, a non-woven fabric, a grooved sheet and a corrugated sheet. Either may be used. Further, the material thereof may be a resin such as polypropylene, polyethylene, polyethylene terephthalate (PET), polyamide, etc., as well as a natural polymer, rubber or metal. However, when elution from the flow path material poses a problem during the separation operation or the like, it is preferable to select the material in consideration of it.

【0024】供給側流路材2の厚みは0.3mm以上2
mm以下であることが好ましく、供給側流路材2の厚み
方向における空隙率は10%以上95%以下であること
が好ましい。また、供給側流路材2がネット状である場
合、そのピッチが0.5mm以上10mm以下であるこ
とが好ましい。
The thickness of the flow path member 2 on the supply side is 0.3 mm or more 2
It is preferable that the flow path member 2 has a porosity of 10% or more and 95% or less in the thickness direction. When the supply-side flow path member 2 has a net shape, its pitch is preferably 0.5 mm or more and 10 mm or less.

【0025】透過側流路材4としては、スパイラル型膜
エレメントとして従来公知の透過側流路材が何れも使用
でき、ネット、メッシュ、線材織物、繊維織物、不織
布、溝付きシート、波形シートなど何れでもよい。ま
た、その材質もポリプロピレン、ポリエチレン、ポリエ
チレンテレフタレート(PET)、ポリアミド、エポキ
シ、ウレタン等の樹脂の他、天然高分子、ゴム、金属な
ど何れでもよい。但し、分離操作等の際に流路材からの
溶出が問題となる場合、それを考慮して材質を選択する
のが好ましい。
As the permeation-side channel material 4, any permeation-side channel material conventionally known as a spiral wound type membrane element can be used, and a net, a mesh, a wire woven fabric, a fiber woven fabric, a non-woven fabric, a grooved sheet, a corrugated sheet, etc. Either may be used. Further, the material thereof may be any resin such as polypropylene, polyethylene, polyethylene terephthalate (PET), polyamide, epoxy, urethane, etc., as well as natural polymer, rubber or metal. However, when elution from the flow path material poses a problem during the separation operation or the like, it is preferable to select the material in consideration of it.

【0026】透過側流路材4の厚みは0.1mm以上2
mm以下であることが好ましく、透過側流路材4の厚み
方向における空隙率は10%以上80%以下であること
が好ましい。また、透過側流路材4がネット状である場
合、そのピッチが0.3mm以上5mm以下であること
が好ましい。
The thickness of the permeate side flow path member 4 is 0.1 mm or more 2
It is preferably mm or less, and the porosity in the thickness direction of the permeation-side channel member 4 is preferably 10% or more and 80% or less. When the permeation-side flow path member 4 has a net shape, the pitch is preferably 0.3 mm or more and 5 mm or less.

【0027】多孔シート10としては、流体の透過があ
る程度生じるものであれば何れでもよく、透過側流路材
4のうち、この条件を満足するものが何れも使用でき
る。好ましい多孔シート10の形態としては、ネット、
メッシュ、線材織物などが挙げられる。多孔シート10
の開口率又は空孔率は10〜80%が好ましく、40〜
80%がより好ましい。
The perforated sheet 10 may be any one as long as it allows fluid to permeate to some extent, and any of the permeation side flow path members 4 that satisfies this condition can be used. A preferable form of the porous sheet 10 is a net,
Examples include mesh and woven wire material. Perforated sheet 10
The aperture ratio or porosity of 10 to 80% is preferable,
80% is more preferable.

【0028】固着の方法としては、熱融着や超音波融着
の他、接着剤による接着、粘着テープ、熱融着材による
接着、縫合やステープル等による機械的な連結など何れ
でもよい。また、固着の際には、重ね代を設けてもよ
い。
As the method of fixing, in addition to heat fusion or ultrasonic fusion, adhesion by an adhesive, adhesion by an adhesive tape, a heat fusion material, or mechanical connection by suture or staple may be used. In addition, an overlapping margin may be provided when fixing.

【0029】固着の部位としては、少なくとも流路材の
一端部が固着されていればよいが、流路材の一辺(エレ
メントとしての中心側端辺)の略全長にわたって固着す
るのが、膜等のずれを確実に防止する上で好ましい。
It is sufficient that at least one end portion of the flow path member is fixed as the fixing portion, but it is fixed over substantially the entire length of one side of the flow path material (end side on the center side as an element) such as a membrane. It is preferable for surely preventing the deviation.

【0030】各々の流路材を多孔シート10に固着する
際の間隔としては、等間隔でなくとも膜等の配置の仕方
で修正することができるが、略等間隔とするのが好まし
い。略等間隔とする場合、中空管5の外周長を固着する
流路材の数で除した間隔とするのが好ましい。
The intervals at which the respective flow path members are fixed to the porous sheet 10 may be modified by the arrangement of the membrane or the like, but it is preferable that the intervals be substantially equal. When the intervals are substantially equal, it is preferable that the outer peripheral length of the hollow tube 5 is divided by the number of flow path members to be fixed.

【0031】上記のように、事前に中空管5に流路材を
固着することにより、等間隔の融着等が非常に簡易にな
り確実に出来るようになる。また、中空管5に透過側流
路材を直接超音波にて融着する手段が既に知られている
が、この方式だと高音による人体への影響や中心管5の
有孔部の融着不足及び円周上での融着が困難であり等間
隔にならない等の問題が発生していたが、この点の問題
も本方式で解決できる。
As described above, by fixing the flow path material to the hollow tube 5 in advance, fusion at equal intervals can be made very simple and reliable. Also, there is already known a means for directly welding the permeation-side flow path material to the hollow tube 5 by ultrasonic waves. With this method, the influence of high sound on the human body and the fusion of the perforated portion of the central tube 5 are known. Problems such as insufficient adhesion and difficulty in fusion bonding on the circumference and uneven spacing have occurred, but this problem can also be solved by this method.

【0032】本実施形態では、図1(b)に示すよう
に、多孔シート10を部分的に中空管5に固着しておく
が、この工程は、多孔シート10などを中空管5に巻回
するまでに行えばよい。例えば、流路材を多孔シート1
0に固着する前又は直後、あるいは多孔シート10など
を中空管5に巻回する直前などである。なお、多孔シー
ト10の固着工程は、多孔シート10の滑りがない場合
など、必ずしも必要な工程ではない。
In this embodiment, as shown in FIG. 1B, the porous sheet 10 is partially fixed to the hollow tube 5. In this process, the porous sheet 10 and the like are attached to the hollow tube 5. All you have to do is to wind it. For example, the channel material is used as the porous sheet 1.
Before or immediately after fixing to 0, or immediately before winding the porous sheet 10 or the like around the hollow tube 5. The step of fixing the porous sheet 10 is not always necessary, such as when the porous sheet 10 does not slip.

【0033】多孔シート10を中空管5に固着する方法
としては、熱融着や超音波融着の他、接着剤による接
着、粘着テープ、両面テープ、熱融着材による接着、機
械的な固着など何れでもよい。固着の部位としては、少
なくとも多孔シート10が部分的に固着されていればよ
いが、多孔シート10の端辺の略全長にわたって固着す
るのが、巻回工程を良好に行う上で好ましい。
As the method of fixing the porous sheet 10 to the hollow tube 5, in addition to heat fusion or ultrasonic fusion, adhesion with an adhesive, adhesive tape, double-sided tape, adhesion with a heat fusion material, mechanical It may be fixed or otherwise. As a fixing portion, at least the porous sheet 10 may be partially fixed, but it is preferable to fix the porous sheet 10 over substantially the entire length of the end side of the porous sheet 10 in order to favorably perform the winding step.

【0034】本実施形態では、膜1及び他方の流路材で
ある供給側流路材2を挿入する際に、交互に折り返した
連続膜を使用し、連続膜の供給側に予め供給側流路材2
を介在させた積層物S1を準備しておく例を示す。この
ような積層物S1は、例えば図2(a)〜図3(b)に
示す工程図のようにして作製することができる。
In this embodiment, when inserting the membrane 1 and the flow channel material 2 on the other side, which is the flow channel material of the other side, continuous membranes that are alternately folded back are used, and the flow on the feed side of the continuous membrane is preliminarily provided. Road material 2
An example in which the laminate S1 with the intervening is prepared is shown. Such a layered product S1 can be produced, for example, as shown in the process diagrams of FIGS. 2 (a) to 3 (b).

【0035】まず、図2(a)に示すように、膜1の両
端のシール性を高めるために、連続膜である膜1の両端
を部分的に熱融着(緻密化)して融着部1aを形成す
る。例えば、幅900〜1016mmの連続膜(具体的
には日東電工(株)製759HRの924mm幅の膜な
ど)の場合、それをロールから繰り出しながら、両端か
ら30mmの領域のうち、30mm以下の幅で熱融着
(ヒートシール、超音波ウェルダーなど)を連続的に行
う。図示した例では、両端から10mm位置より内側に
幅5mmの融着部1aを設けている。
First, as shown in FIG. 2 (a), in order to enhance the sealing property of both ends of the film 1, both ends of the film 1 which is a continuous film are partially heat-bonded (densified) and then fused. The part 1a is formed. For example, in the case of a continuous film having a width of 900 to 1016 mm (specifically, a film having a width of 924 mm of 759HR manufactured by Nitto Denko Corporation, etc.), while unrolling it from a roll, a width of 30 mm or less in a region of 30 mm from both ends. To continuously perform heat fusion (heat sealing, ultrasonic welder, etc.). In the illustrated example, the fused portion 1a having a width of 5 mm is provided on the inner side from the positions of 10 mm from both ends.

【0036】次に、図2(b)に示すように、融着部1
aの上の透過側に、両端から5〜30mm幅の熱融着テ
ープ11(例えば20mm幅)を10kPa以上の圧力
でシワが入らないように貼りつける。熱融着テープ11
は、熱融着性の基材テープに粘着剤層を設けたもの等で
あり、粘着剤層を設けていないものでもよい。
Next, as shown in FIG. 2B, the fused portion 1
A heat-sealing tape 11 (for example, 20 mm width) having a width of 5 to 30 mm from both ends is attached to the permeation side above a so that wrinkles do not occur at a pressure of 10 kPa or more. Heat fusion tape 11
Is, for example, a heat-fusible base tape provided with an adhesive layer, and may not be provided with an adhesive layer.

【0037】次に、図2(c)に示すように、供給側の
膜面に等間隔で、補強用の粘着テープ12(例えば、日
東電工(株)製PETテープNo.31B、50mm
幅)の20〜50mm幅を、長さ方向に500〜150
0mmの等間隔(具体的には750mm)で幅方向にシ
ワの入らないように貼り付ける。これは連続で折りたた
んだときの山折り側、谷折り側になる部分である。
Next, as shown in FIG. 2 (c), the reinforcing adhesive tape 12 (for example, PET tape No. 31B, 50 mm manufactured by Nitto Denko Corporation) is equidistantly provided on the film surface on the supply side.
Width) 20-50 mm width in the length direction 500-150
It is attached at equal intervals of 0 mm (specifically, 750 mm) so that there are no wrinkles in the width direction. This is the portion on the mountain fold side and the valley fold side when continuously folded.

【0038】次に、図3(a)に示すように、幅900
〜1016mm(具体的には924mm)のPP製の供
給側流路材2を500〜1500mm(具体的には75
0mm)に切断しておき、粘着テープ12を貼り付けた
ところに交互に供給側流路材2を固定していく。固定方
法については、熱融着、ステープル、テープ、樹脂など
あるが超音波ウェルダーが好ましい。
Next, as shown in FIG. 3A, a width 900
10-16 mm (specifically 924 mm) made of PP supply side flow path member 2 is 500-1500 mm (specifically 75 mm)
It is cut to 0 mm) and the supply side flow path material 2 is alternately fixed to the place where the adhesive tape 12 is attached. As a fixing method, there are heat fusion, staple, tape, resin and the like, but an ultrasonic welder is preferable.

【0039】次に、図3(b)に示すように、供給側流
路材2を固定した粘着テープ12の部分のほぼ中央部分
を供給側流路材2が内側になるように折り曲げる。それ
を設定リーフ分(例えば32リーフ)折り曲げて、積層
物S1とする。この時、供給側流路材2を取りつけてな
いほうは折り曲げていない状態となる。続いて、折目部
の強度アップのために40〜150℃、10〜500k
Paのエアー圧力で熱プレスを1〜120秒間行うのが
好ましい。
Next, as shown in FIG. 3 (b), the approximately central portion of the adhesive tape 12 to which the supply-side flow path member 2 is fixed is bent so that the supply-side flow path member 2 is on the inside. It is bent by a set leaf (for example, 32 leaves) to form a laminate S1. At this time, the one in which the supply-side flow path member 2 is not attached is in a non-bent state. Subsequently, 40-150 ° C, 10-500k for increasing the strength of the folds
It is preferable to perform hot pressing with an air pressure of Pa for 1 to 120 seconds.

【0040】この積層物S1を、図1(b)のように多
孔シート10に固着された透過側流路材4の間に挿入す
るには、例えば各々の透過側流路材4とリーフとを、載
置面の両側から1枚づつ交互に重ねていけばよく、この
工程は自動化することも可能である。また、図3(b)
に示すような折り曲げ工程を行う際に、透過側流路材4
を順次介在させていく方法も可能である。本発明ではこ
のように、積層物S1や流路材を固着した多孔シート1
0を予め準備しておくことにより、生産性の面でも非常
に効率がよくなる。
To insert this laminate S1 between the permeation side flow path members 4 fixed to the porous sheet 10 as shown in FIG. 1 (b), for example, each permeation side flow path member 4 and leaves are formed. It suffices to alternately superpose them one by one from both sides of the mounting surface, and this process can be automated. In addition, FIG.
When performing the bending process as shown in FIG.
It is also possible to intervene in sequence. In the present invention, as described above, the porous sheet 1 to which the laminate S1 and the channel material are fixed
By preparing 0 in advance, the efficiency becomes very efficient in terms of productivity.

【0041】図2〜図3で例示した工程に対応する中空
管5としては、例えば変性ポリフェニレンエーテル(P
PE)樹脂製φ38mm、1016mmの中空管が用い
られ、多孔シート10としては、幅800〜1016m
mのPET製の透過側流路材を500〜2000mm
(具体的には1750mm)に切断したものなどが使用
できる。透過側流路材4としては、500〜1500m
mの透過側流路材が使用できる。
As the hollow tube 5 corresponding to the steps illustrated in FIGS. 2 to 3, for example, modified polyphenylene ether (P
PE) A resin-made φ38 mm, 1016 mm hollow tube is used, and the porous sheet 10 has a width of 800 to 1016 m.
m permeation side flow path material made of PET is 500 to 2000 mm
Those specifically cut to 1750 mm can be used. As the permeation side flow path member 4, 500 to 1500 m
m channel material on the permeate side can be used.

【0042】本実施形態では、積層物S1を挿入して積
層体S2とした後に、供給側流路と透過側流路とが直接
連通しないための封止構造を形成する工程を行う例を示
す。この例では、前記の熱融着テープ11を利用して、
対向する膜1の透過側に透過側流路材4を介在させた状
態で膜1の両端部を封止すると共に、膜1の両端部と多
孔シート10との近接部を固着する。前者の封止により
両端封止部A1が形成される。その際、膜1の両端部を
順次リーフ数の分だけ封止していき、その封止後に多孔
シート10との近接部を固着してもよい。
In the present embodiment, an example of performing a step of forming a sealing structure for preventing direct communication between the supply-side flow passage and the permeation-side flow passage after inserting the laminate S1 into the laminate S2 will be described. . In this example, using the above heat-sealing tape 11,
Both ends of the membrane 1 are sealed while the permeation side flow path member 4 is interposed on the permeation side of the opposing membrane 1, and the both ends of the membrane 1 and the proximity portion of the porous sheet 10 are fixed. The former sealing forms the both-end sealing portion A1. At that time, both ends of the membrane 1 may be sequentially sealed by the number of leaves, and after the sealing, the portion close to the porous sheet 10 may be fixed.

【0043】当該封止の方法については、熱融着テープ
11を用いた熱融着や超音波融着の他、接着剤による接
着、粘着テープ、両面テープ、熱融着材による接着など
何れでもよい。
Regarding the sealing method, in addition to heat fusion using the heat fusion tape 11 and ultrasonic fusion, adhesion with an adhesive, adhesive tape, double-sided tape, adhesion with a heat fusion material, etc. may be used. Good.

【0044】本発明の製造方法は、図1(c)に示すよ
うに、積層体S2を前記中空管5に巻回する工程を有す
る。本実施形態では、積層体S2及び多孔シート10を
同時に巻回する例を示したが、予め多孔シート10を巻
回してから、積層体S2を巻回してもよい。
The manufacturing method of the present invention has a step of winding the laminated body S2 around the hollow tube 5, as shown in FIG. 1 (c). In the present embodiment, the example in which the laminated body S2 and the porous sheet 10 are wound at the same time has been described, but the laminated body S2 may be wound after the porous sheet 10 is wound in advance.

【0045】巻回は、巻付用のチャックに中空管5をセ
ットし、このチャックをある一定の速度とテンションで
巻き上げればよい。また、ある一定の速度で巻き上げた
後にロールにて荷重方式にて巻き上げる方式で行うこと
も可能であるが、前者の方法が好ましい。その際、中心
部のテンションは膜1の幅1000mmあたり50〜7
00Nで行うのが好ましい。
For winding, the hollow tube 5 may be set on a winding chuck and the chuck may be wound at a constant speed and tension. It is also possible to wind the roll at a certain speed and then roll it by a load system, but the former method is preferable. At that time, the tension of the central part is 50 to 7 per 1000 mm width of the film 1.
It is preferably performed at 00N.

【0046】本発明の製造方法は、中空管5と膜1との
間で弾性体6を融着させて中空管5の周囲に封止部A2
を形成する工程と、供給側流路と透過側流路とが直接連
通しないためのその他の封止構造を形成する工程とを有
する。後者の工程としては、前述した両端封止部A1の
形成工程や、連続膜を使用せずに複数のリーフを使用す
る場合における膜1の外側端辺の封止工程が挙げられ
る。
According to the manufacturing method of the present invention, the elastic member 6 is fused between the hollow tube 5 and the membrane 1 so that the sealing portion A2 is provided around the hollow tube 5.
And a step of forming another sealing structure for preventing the supply-side flow passage and the permeation-side flow passage from directly communicating with each other. Examples of the latter step include the above-described step of forming the both-end sealing portion A1 and the step of sealing the outer edge of the film 1 when using a plurality of leaves without using a continuous film.

【0047】弾性体6の接着は、加熱融着、超音波融
着、両者の併用、粘着剤、接着剤などにより行うことが
できる。
The elastic body 6 can be adhered by heat fusion, ultrasonic fusion, a combination of the two, a pressure sensitive adhesive, an adhesive or the like.

【0048】本発明では、巻回の後に、熱融着等した封
止部分の残留応力を除去するために、適当な温度で熱処
理したり、あるいは前記巻回工程を熱融着等が離反しな
い温度で加熱等しながら行ってもよい。また、以上の工
程の後に、膜1の外周面にネット等の外周部流路材を巻
回してもよく、外周面の封止、粘着テープの巻回などを
行ってもよい。
In the present invention, after winding, heat treatment is carried out at an appropriate temperature in order to remove the residual stress of the sealed portion that has been heat-sealed, or the winding step does not separate from the heat-sealing. You may perform it, heating at temperature. After the above steps, an outer peripheral flow path material such as a net may be wound around the outer peripheral surface of the membrane 1, sealing of the outer peripheral surface, winding of an adhesive tape, or the like may be performed.

【0049】一方、本発明のスパイラル型膜エレメント
は、以上のような製造方法によって好適に製造し得るも
のである。即ち、本発明のスパイラル型膜エレメント
は、図4に示すように、対向する膜1の供給側に供給側
流路材2を介在させ、対向する膜1の透過側に透過側流
路材4を介在させた積層体を有孔の中空管5にスパイラ
ル状に巻回してあり、供給側流路と透過側流路とが直接
連通しないための封止構造を備え、前記封止構造のうち
前記中空管5の周囲の封止部A2が、その中空管5と前
記膜1との間に弾性体6を介在してなることを特徴とす
る。
On the other hand, the spiral wound type membrane element of the present invention can be preferably manufactured by the above manufacturing method. That is, in the spiral wound type membrane element of the present invention, as shown in FIG. 4, the supply-side channel material 2 is interposed between the opposing membranes 1 on the supply side, and the permeation-side channel material 4 is disposed on the permeate side of the opposing membrane 1. The laminated body having the interposing member is spirally wound around the hollow tube 5 having a hole, and is provided with a sealing structure for preventing direct communication between the supply side flow passage and the permeation side flow passage. The sealing portion A2 around the hollow tube 5 is characterized in that an elastic body 6 is interposed between the hollow tube 5 and the membrane 1.

【0050】膜1、供給側流路材2、透過側流路材4、
中空管5、弾性体6及びそれらの結合関係、並びに封止
構造については、先に述べた通りである。なお、本発明
のスパイラル型膜エレメントは、モジュール化された後
又は直接に分離装置等に組み込まれ、前述した膜の種類
に応じた用途に使用することができる。
Membrane 1, supply-side channel material 2, permeate-side channel material 4,
The hollow tube 5, the elastic body 6 and their coupling relationship, and the sealing structure are as described above. In addition, the spiral wound type membrane element of the present invention can be used after being modularized or directly incorporated into a separation device or the like, and used according to the type of the above-mentioned membrane.

【0051】[他の実施形態] (1)前述の実施形態では、多孔シートに透過側流路材
を所定間隔で固着し、その透過側流路材の間に膜及び供
給側流路材を挿入して積層体を形成する例を示したが、
本発明は多孔シートを用いずに実施することができる。
その場合、例えば透過側流路材を弾性体に固着又は仮固
着した後、その間に膜及び供給側流路材を挿入して膜
(膜に貼着したテープを含む)を弾性体に固着又は仮固
着してから積層体を巻回させればよい。
[Other Embodiments] (1) In the above-described embodiment, the permeation-side channel material is fixed to the porous sheet at a predetermined interval, and the membrane and the supply-side channel material are provided between the permeation-side channel materials. Although an example of inserting and forming a laminated body has been shown,
The present invention can be carried out without using a porous sheet.
In that case, for example, after the permeation-side channel material is fixed or temporarily fixed to the elastic body, the membrane and the supply-side channel material are inserted between them to fix the membrane (including the tape adhered to the membrane) to the elastic body. The laminated body may be wound after being temporarily fixed.

【0052】(2)前述の実施形態では、弾性体を配置
する際に粘着テープを中空管の周囲に巻回する例を示し
たが、粘着テープの代わりに、O型スリーブ又はC型ス
リーブを外嵌したり、弾性体を一定厚みで中空管の周囲
に塗布して固化させたり、あるいは多孔シート側に弾性
体層を形成してもよい。
(2) In the above embodiment, an example was shown in which the adhesive tape was wound around the hollow tube when the elastic body was placed. However, instead of the adhesive tape, an O-type sleeve or a C-type sleeve is used. May be externally fitted, an elastic body may be applied to the periphery of the hollow tube with a constant thickness to be solidified, or an elastic body layer may be formed on the porous sheet side.

【0053】(3)前述の実施形態では、中空管を透過
側の流路とすべく、透過側流路材を多孔シートに固着す
る例を示したが、濃度分極によるケークの形成等が問題
とならない場合など、中空管を供給側の流路とすべく、
供給側流路材を多孔シートに固着してもよい。
(3) In the above-described embodiment, an example is shown in which the permeation-side channel material is fixed to the perforated sheet so that the hollow tube serves as the permeation-side channel. When there is no problem, to make the hollow tube the flow path on the supply side,
The supply-side channel material may be fixed to the porous sheet.

【0054】(4)前述の実施形態では、交互に折り返
した連続膜の供給側に予め供給側流路材を介在させた積
層物を準備しておき、これを透過側流路材の間に挿入す
る例を示したが、まず連続膜を透過側流路材の間に挿入
した後、続いて連続膜の間に供給側流路材を挿入しても
よい。
(4) In the above-described embodiment, a laminate having a supply-side channel material interposed in advance on the supply side of the alternately folded back continuous film is prepared, and this is provided between the permeation-side channel materials. Although the example of insertion is shown, first, the continuous membrane may be inserted between the permeation side channel materials, and then the supply side channel material may be inserted between the continuous membranes.

【0055】(5)前述の実施形態では、膜の両端封止
部を形成(封止)した後に、多孔シート等を中空管に巻
回する例を示したが、多孔シート等を中空管に巻回した
後に又は巻回しながら、膜の両端部を順次リーフ数の分
だけ封止していき、その封止後に多孔シートとの近接部
を封止するなどしてもよい。
(5) In the above-described embodiment, an example in which the porous sheet or the like is wound around the hollow tube after forming (sealing) both ends of the membrane is shown. After or while being wound around the tube, both ends of the membrane may be sequentially sealed by the number of leaves, and after the sealing, the vicinity of the porous sheet may be sealed.

【0056】[0056]

【実施例】以下、本発明の構成と効果を具体的に示す実
施例等について説明する。
EXAMPLES Examples and the like specifically showing the constitution and effects of the present invention will be described below.

【0057】実施例1 本発明の効果の確認のために、図1〜図3に示す製造方
法に従って、次のようにして本発明のスパイラル型膜エ
レメントを製造し、シール性を評価した。即ち、変性P
PE樹脂製φ38mm、1016mmの中空管の封止部
を形成する位置に下記の発泡テープを10KPaの圧力
で10回分巻付けて弾性体を配置した。
Example 1 In order to confirm the effects of the present invention, the spiral wound type membrane element of the present invention was manufactured as follows according to the manufacturing method shown in FIGS. 1 to 3, and the sealing property was evaluated. That is, modified P
The foamed tape described below was wound 10 times at a pressure of 10 KPa at a position where a sealing portion of a hollow tube made of PE resin and having a diameter of 38 mm and 1016 mm was formed, and an elastic body was arranged.

【0058】構造:粘着剤(アクリル系)、基材(独立
気泡ポリエチレンフォーム)、厚み0.33mm、引張
強さ:35.6kg/cm2 、伸び率:411%、密度
0.55g/cm3 、基材フォーム層の発泡倍率:5.
0倍、圧縮硬さ:30〜90kPa、せん断接着力:
7.5〜8.5kg/cm2 、180°剥離接着力:1
000〜1400g/25mm。
Structure: Adhesive (acrylic), substrate (closed-cell polyethylene foam), thickness 0.33 mm, tensile strength: 35.6 kg / cm 2 , elongation: 411%, density 0.55 g / cm 3. Foaming ratio of the base foam layer: 5.
0 times, compression hardness: 30 to 90 kPa, shear adhesive strength:
7.5-8.5 kg / cm 2 , 180 ° peeling adhesive strength: 1
000-1400 g / 25 mm.

【0059】更に多孔シートとしてPET製の透過側流
路材(繊維織布タイプ、長さ1750mm)、透過側流
路材としてPET製の透過側流路材(繊維織布タイプ、
長さ750mm)、膜として日東電工(株)製759H
R(924mm幅、連続膜)、供給側流路材としてPP
製の供給側流路材(ネットタイプ、長さ750mm)、
熱融着テープとして20mm幅の日東電工(株)製,M
−5213SSを用いた。
Further, the permeation side channel material made of PET (fiber woven type, length 1750 mm) is used as the porous sheet, and the permeation side channel material made of PET (fiber woven type, is used as the permeation side channel material.
750 mm in length, 759H made by Nitto Denko Corporation as a film
R (924 mm width, continuous film), PP as the flow path material on the supply side
Supply side flow path material (net type, length 750 mm),
20 mm width as a heat-sealing tape manufactured by Nitto Denko Corporation, M
-5213SS was used.

【0060】また、膜の両端部の封止は通常通り行い、
巻回時の中空管付近のテンションは、400Nとし、そ
の後温度110℃で1.5時間加熱することにより、封
止部を融着させた。気密保持検査を行い補修樹脂無しで
シール性を確保できた。このシール性の確認は透過側か
ら49KPaの圧縮エアーでの漏れ、エレメントを真空
状態にし−530mmHg→−480mmHgまでの保
持時間測定にて漏れの無いことを確認した。
Further, the both ends of the film are sealed as usual,
The tension in the vicinity of the hollow tube at the time of winding was set to 400 N, and then the sealing portion was fused by heating at a temperature of 110 ° C. for 1.5 hours. An airtightness retention inspection was performed, and the sealability could be secured without repair resin. This sealability was confirmed by leaking from the permeate side with compressed air of 49 KPa, and measuring the holding time from -530 mmHg to -480 mmHg with the element in a vacuum state, and it was confirmed that there was no leak.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明のスパイラル型膜エレメントの製造方法
の一例を模式的に示す工程図
FIG. 1 is a process chart schematically showing an example of a method for producing a spiral wound type membrane element of the present invention.

【図2】図1に示す工程の一部を更に詳細に示す工程図FIG. 2 is a process diagram showing in more detail a part of the process shown in FIG.

【図3】図1に示す工程の一部を更に詳細に示す工程図FIG. 3 is a process chart showing in more detail a part of the process shown in FIG.

【図4】本発明のスパイラル型膜エレメントの一例を示
す部分破断した側面図
FIG. 4 is a partially cutaway side view showing an example of the spiral wound type membrane element of the present invention.

【図5】従来のスパイラル型膜エレメントの一例を示す
部分破断した側面図
FIG. 5 is a partially cutaway side view showing an example of a conventional spiral wound type membrane element.

【符号の説明】[Explanation of symbols]

1 膜 2 供給側流路材 4 透過側流路材 5 中空管 6 弾性体 10 多孔シート A1 両端封止部(封止構造) A2 内周封止部(封止構造) 1 membrane 2 Flow path side material 4 Permeation side flow path material 5 hollow tubes 6 elastic body 10 Perforated sheet A1 Both ends sealing part (sealing structure) A2 Inner circumference sealing part (sealing structure)

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4D006 GA02 GA03 GA06 GA07 GA32 HA61 HA62 JA05A JA05C JA06A JA06C JA19A JA19Z JB04 JB05 JB07 MC18 MC22 MC23 MC28 MC35 MC39 MC45 MC54 MC62 PB70 PC80    ─────────────────────────────────────────────────── ─── Continued front page    F-term (reference) 4D006 GA02 GA03 GA06 GA07 GA32                       HA61 HA62 JA05A JA05C                       JA06A JA06C JA19A JA19Z                       JB04 JB05 JB07 MC18 MC22                       MC23 MC28 MC35 MC39 MC45                       MC54 MC62 PB70 PC80

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 対向する膜の供給側に供給側流路材を介
在させ、対向する膜の透過側に透過側流路材を介在させ
た積層体を有孔の中空管にスパイラル状に巻回してあ
り、供給側流路と透過側流路とが直接連通しないための
封止構造を備えるスパイラル型膜エレメントにおいて、
前記封止構造のうち前記中空管の周囲の封止部が、その
中空管と前記膜との間に弾性体を介在してなることを特
徴とするスパイラル型膜エレメント。
1. A laminated body in which a supply-side channel material is interposed on the supply side of opposed membranes and a permeation-side channel material is interposed on the permeation side of opposed membranes in a spiral shape in a hollow tube having a hole. In a spiral wound type membrane element having a sealing structure that is wound and the supply side flow passage and the permeation side flow passage do not directly communicate with each other,
A spiral wound type membrane element, wherein a sealing portion around the hollow tube in the sealing structure has an elastic body interposed between the hollow tube and the membrane.
【請求項2】 前記弾性体が熱可塑性樹脂の発泡体を含
む請求項1記載のスパイラル型膜エレメント。
2. The spiral wound type membrane element according to claim 1, wherein the elastic body includes a foamed body of a thermoplastic resin.
【請求項3】 有孔の中空管の周囲の封止部を形成する
位置に弾性体を配置する工程と、対向する膜の供給側に
供給側流路材を対向する膜の透過側に透過側流路材を各
々介在させた積層体を形成する工程と、この積層体を前
記中空管に巻回する工程と、その中空管と前記膜との間
で前記弾性体を配置させて中空管の周囲に封止部を形成
する工程と、供給側流路と透過側流路とが直接連通しな
いためのその他の封止構造を形成する工程とを有するス
パイラル型膜エレメントの製造方法。
3. A step of disposing an elastic body at a position where a sealing portion is formed around a perforated hollow tube, and a supply-side channel material is provided on the supply side of the opposing membrane on the permeation side of the opposing membrane. A step of forming a laminated body in which each of the permeation side flow path members is interposed, a step of winding the laminated body around the hollow tube, and arranging the elastic body between the hollow tube and the membrane. Of a spiral wound type membrane element having a step of forming a sealing portion around a hollow tube by forming a hollow tube and a step of forming another sealing structure for preventing direct communication between the supply-side flow passage and the permeation-side flow passage. Method.
【請求項4】 前記弾性体を配置する際に、熱可塑性樹
脂の発泡体を基材とする粘着テープを前記中空管の周囲
に巻回する請求項3記載のスパイラル型膜エレメントの
製造方法。
4. The method for producing a spiral wound type membrane element according to claim 3, wherein an adhesive tape having a thermoplastic resin foam as a base material is wound around the hollow tube when the elastic body is arranged. .
JP2002080477A 2002-03-22 2002-03-22 Spiral type membrane element and manufacturing method thereof Expired - Fee Related JP4070002B2 (en)

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JP4070002B2 JP4070002B2 (en) 2008-04-02

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006326376A (en) * 2005-05-23 2006-12-07 Nitto Denko Corp Spiral type separation membrane element and its production method
WO2012043553A1 (en) * 2010-09-30 2012-04-05 日東電工株式会社 Separation membrane element and fluid collecting tube for separation membrane element
CN103662381A (en) * 2012-09-26 2014-03-26 刘俊杰 Vane placing device
KR20170112599A (en) * 2016-03-31 2017-10-12 도레이케미칼 주식회사 perforated flux pipe manufacturing apparatus
CN108671754A (en) * 2013-11-11 2018-10-19 Rts雷歇姆技术服务有限责任公司 By the method and apparatus of membrane filtration and separation flow media
CN115253692A (en) * 2022-06-22 2022-11-01 沃顿科技股份有限公司 Membrane element, production method of membrane element and roll-type membrane module

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006326376A (en) * 2005-05-23 2006-12-07 Nitto Denko Corp Spiral type separation membrane element and its production method
JP4485410B2 (en) * 2005-05-23 2010-06-23 日東電工株式会社 Spiral type separation membrane element and manufacturing method thereof
WO2012043553A1 (en) * 2010-09-30 2012-04-05 日東電工株式会社 Separation membrane element and fluid collecting tube for separation membrane element
KR101483382B1 (en) 2010-09-30 2015-01-14 닛토덴코 가부시키가이샤 Separation membrane element and fluid collecting tube for separation membrane element
CN103662381A (en) * 2012-09-26 2014-03-26 刘俊杰 Vane placing device
CN108671754A (en) * 2013-11-11 2018-10-19 Rts雷歇姆技术服务有限责任公司 By the method and apparatus of membrane filtration and separation flow media
KR20170112599A (en) * 2016-03-31 2017-10-12 도레이케미칼 주식회사 perforated flux pipe manufacturing apparatus
KR102462035B1 (en) * 2016-03-31 2022-11-01 도레이첨단소재 주식회사 perforated flux pipe manufacturing apparatus
CN115253692A (en) * 2022-06-22 2022-11-01 沃顿科技股份有限公司 Membrane element, production method of membrane element and roll-type membrane module
CN115253692B (en) * 2022-06-22 2023-12-01 沃顿科技股份有限公司 Membrane element, production method of membrane element and rolled membrane assembly

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