JP2003182213A - Inkjet recording element - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an inkjet recording element with improved Dmax density and light stability when printed with a water-soluble dye and to provide a method for printing using the element. <P>SOLUTION: The inkjet recording element has a substrate carrying (a) a base layer comprising a polymer binder, a polymer mordant and a stabilizer having formula (1) and (b) an overcoat layer comprising a polymer UV absorbing material in the described order thereon and an overcoat layer comprising a polymer UV absorbing material in the described order. <P>COPYRIGHT: (C)2003,JPO

Description

DETAILED DESCRIPTION OF THE INVENTION [0001] [0001] The present invention relates to a method using a water-soluble dye.
Dmax density and light stability when printed with
Inkjet recording element having
Related to the printing method used. [0002] 2. Description of the Related Art Ink jet printing uses digital signals.
Ink droplets adhere to the image recording element pixel by pixel in response to
Is a non-impact method of producing an image by
You. By controlling the deposition of ink droplets on the image recording element,
The methods that can be used to produce the desired image are
Various. One known as continuous inkjet
The method comprises charging a continuous stream of droplets to form an image recording element.
Not used for image formation while image-deflecting on the surface of
The captured droplets are captured and returned to the ink reservoir. Drop-on
-Another known as demand-based inkjet
Method requires individual ink droplets on the image recording element
Injected according to the desired image. Drop-O
Control the ejection of ink droplets in on-demand printing
Common methods include piezoelectric transducers and thermal bubble
Is included. Industrial inkjet printers
From labeling to desktop documents and pictorial image formation
Extensive use across the market ranging from time printing to end
There is a way. [0003] In various ink jet printers
The inks used are either dye-based or pigment-based
Can be classified. Dyes are molecular
Is a colorant that is dispersed or solvated in water. The dispersion medium is
It may be liquid or solid at the temperature. general
The dispersion medium used for water is water or water and an organic co-solvent.
It is a mixture. Each individual dye molecule is a molecule of the dispersion medium
Surrounded by In dye-based inks,
No particles can be observed under the microscope. Most
Recently, many technologies in dye-based inkjet ink
Despite the progress, these inks
Drawbacks such as low optical density and poor light fastness
To have. When water is used as the dispersion medium,
Inks also generally suffer from poor waterfastness
You. [0004] Ink jet recording elements are generally low
At least one ink-receiving layer or image-forming layer
Comprising a supporting support. This ink receiving layer
Is a polymer layer that swells and absorbs ink,
Even with a porous layer that sucks ink by capillary action
Good. [0005] By printing on the ink jet recording element,
Inkjet prints are subject to environmental degradation.
It's easy. They are smearing by water, color flow
And is particularly vulnerable to aggregation and photobleaching.
For example, since inkjet dyes are water-soluble,
When the ink comes into contact with the imaged receptor,
The materials may move from their location in the image layer.
Highly swellable hydrophilic layers are desirable for drying
If it takes too long to reduce the printing speed
May dissolve if left in contact with water,
The printed image will be destroyed. The porous layer is for ink
Faster vehicle absorption, but poor gloss, severe
Photobleaching or fading induced by atmospheric ozone
In many cases. US Pat. No. 4,926,190 describes a recording material.
And the use of ultraviolet absorbers. But
These materials include that they are not polymers, but rather layers.
Question in that they may have a tendency to
There is a title. US Pat. No. 5,384,235 discloses silver halide
Use of polymeric UV absorbers in color photographic elements
I do. However, this patent specification does not cover these materials.
May not be used in inkjet recording elements.
Not disclosed at all. US Pat. No. 6,045,917 discloses an inkjet printer.
Use of a cationic mordant in the image recording layer
About. However, as shown below, this element
The image formed in the image receiving layer has light stability.
There is a problem in that it is inadequate. US Patent Application Publication No. 09 / 611,123 (2000
(Filed on June 6, 2008) is an ink jet printer for improving light stability.
The use of stabilizers in the jet receptor.
However, it is formed in the image receiving layer of this element.
It would be desirable to improve the light stability of the resulting image. [0010] [Patent Document 1] U.S. Pat. No. 4,926,190 [Patent Document 2] US Patent No. 5,384,235 [Patent Document 3] US Patent No. 6,045,917 [Patent Document 4] US Patent Application Publication No. 09 / 611,123 [0011] SUMMARY OF THE INVENTION The object of the present invention is
Improved Dmax density when printed with a neutral dye
And ink-jet recording element having light stability
It is to be. [0012] Another object of the present invention is to provide the above-described element.
The purpose is to provide a printing method to be used. [0013] SUMMARY OF THE INVENTION These and other objects are provided.
My goal is, a) a polymeric binder, a polymeric mordant, and
formula: [0014] Embedded image A stabilizer having the formula:
R is independently substituted or unsubstituted 1-7 carbon atoms
Alkyl or alkoxy group having an atom, 6 to 10
Phenyl group having 6 carbon atoms, 6-10 carbon atoms
A phenoxy group having 1 to 8 carbon atoms
Represents a rubonamide group, or two or more R groups
And n may be 1 to 3 to form a ring structure.
4 and L contains at least one carbon atom
Is a linking group, and M⁺ Is a monovalent cation
Is the sum of the carbon atoms in all R and L combined
The number is at least three and at least one R is
A base layer comprising a stabilizer, which is a alkoxy group;
Bini b) Overcoat comprising polymeric UV absorbing material
Layers, comprising a support carrying the layers in the order described.
The present invention relates to an ink jet recording element comprising
Achieved. Due to the above recording elements, excellent Dmax density and excellent
And light stability has been found to be provided. Another aspect of the present invention is a A) Inkjet printer responding to digital data signal
The process of preparing a linter, B) The above-mentioned printer is provided with the above-mentioned ink jet recording element.
Loading the, C) water, a humectant, and a water-soluble dye
For loading an inkjet ink composition comprising
About D) The ink jet in response to the digital data signal
Printing on the above overcoat layer using inkjet ink
And an inkjet printing method. [0018] DETAILED DESCRIPTION OF THE INVENTION Used in printing elements of the present invention.
Ink jet ink composition,
Having a functional group (for example, a sulfo group or a carboxylic acid group)
Any water-soluble dye, such as
it can. This anionic water-soluble dye is applied to COLOR INDEX
Any acid dye, direct dye,
Alternatively, it may be a reactive dye, but is not limited to these.
It is not specified. Also, U.S. Patent No. 5,482,545
As disclosed in the specification, metallized azo dyes
And non-metallized azo dyes may be used. Even if you use
Another good dye is EP-A-802246-A1.
And JP-A-09 / 202043.
In a preferred embodiment, used in the method of the invention
Water-soluble dye that may be used in the composition
Are metallized azo dyes, non-metallized azo dyes, xanthene dyes
Pigment, metallophthalocyanine dye, or sulfur dye.
You. Further, a mixture of these dyes may be used. Book
Examples of dyes that may be used in the invention are as follows:
is there. [0019] Embedded image[0020] Embedded image The above-mentioned dyes are effective for the intended use,
Any amount may be used. Generally, inkjet
0.2 to 5% by mass of the ink composition, preferably 0.3 to 3% by mass
Good results have been obtained when the dye is present in an amount of
I have. Further, a mixture of dyes may be used. In a preferred embodiment of the present invention,
UV-absorbing materials should not contain the following repeating units:
You. [0023] Embedded image In the above formula, R₁ Is H or CH_Three Represents
R_Two Is H, halogen, alkoxy, or 1-8
Represents a linear or branched alkyl group having carbon atoms
Then R_Three Is H, Cl, alkoxy, or 1-4
Represents an alkyl group having a carbon atom, and X represents COO, C
Represents ONH, or aryl, and Y is 2-10
Or an alkylene group having a carbon atom of_Two )_n O
Where n is 1-4. [0025] The polymer ultraviolet absorbing agent useful in the present invention.
Specific examples of the repeating unit include the following. [0026] Embedded image[0027] [Table 1] The UV absorber described in Table I above
Yield repeat units overlap in the presence of two or more comonomers.
They can also be combined. For example, ethyl acrylate mono
And acrylamide-2,2'-dimethylpropanesulfone
The combination with an acid monomer is repeated
It can also be copolymerized with the position UV-1. In the present invention
Specific examples of useful polymeric UV absorbing materials are summarized below.
You. UVL-1: poly- (UV-1) -co-acrylic acid
Ethyl-co-2-sulfo-1,1-dimethylethylacrylamide
Sodium salt (molar ratio = 1: 1: 0.05) UVL-2: Poly- (UV-2) -co-ethyl acrylate-co-2-
Sulfo-1,1-dimethylethylacrylamide, sodium
Salt (molar ratio = 1: 1: 0.05) UVL-3: poly- (UV-3) -co-butyl acrylate-co-2-
Sulfo-1,1-dimethylethylacrylamide, sodium
Salt (molar ratio = 1: 2: 0.05) The polymer ultraviolet absorber used in the present invention
The collected material is 0.05 ~ 4.0g / m^Two, Preferably 0.20 to 1.5 g / m^Two
Can be used in quantities. In the present invention, any polymer mordant
Can also be used. In a preferred embodiment, the mordant
The agent may be a cationic protonated amine-containing polymer or
Polymers containing quaternary ammonium groups,
Is also good. Examples of these mordants include poly 1-vinyl imida
Sol, poly 4-vinyl pyridine, poly (styrene-co-salt
N-benzyl-N, N-dimethyl-N-vinylbenzylammonium
-Co-divinylbenzene) (molar ratio = 49:49:
2), polychlorinated N, N, N-tributyl-N-vinylbenzyla
Ammonium, polychlorinated N, N-dimethyl-N-benzyl-N-bi
Nylbenzylammonium, poly (styrene-co-chlorinated N,
N, N-trimethyl-N-vinylbenzylammonium)
1: 1), poly (N, N, N-trimethyl chloride-N-vinyl chloride)
Rubenzylammonium-co-divinylbenzene) (mol
Ratio = 87: 13), polychlorinated N, N-dimethyl-N-octadecyl
-N-vinylbenzylammonium, poly (styrene-co-1
-Vinylimidazole-co-3-hydroxyethyl chloride -1-
(Vinyl imidazolium) (molar ratio = 5: 4: 1), poly
 (Styrene-co-1-vinylimidazole-co-3-benzide chloride
1-vinylimidazolium) (molar ratio = 5: 4:
1), poly (styrene-co-1-vinylimidazole-co-salt)
3-hydroxyethyl-1-vinylimidazolium)
Ratio = 2: 2: 1), poly (styrene-co-4-vinylpyri)
Gin-co-1-hydroxyethyl chloride-4-vinylpyridinium
) (Molar ratio = 5: 4: 1), polychlorinated diallyldimethyl
Ruammonium, and chitosan. The polymeric mordant used in the present invention
Is 0.2 ~ 16g / m^Two, Preferably 0.4 to 8 g / m^TwoUsed in quantity
can do. In a preferred embodiment of the present invention,
L in the above formula for the agent is at least one
Contains a methylene group. In another preferred embodiment
Wherein the stabilizer comprises at least two alkoxy groups
It contains. In yet another embodiment, the above
The total number of carbon atoms in the combined R and L is at least
There are three. Stability that can be used in the present invention
Examples of the agent are as follows. [0034] Embedded image [0035] [Table 2] For clarity, stabilizers S-1 to S-4
And the structures of S-9 are depicted below. [0037] Embedded imageAn alkyl group or the like is added to the benzene ring of the above stabilizer.
And an electron donating substituent such as an alkoxy group.
Efficiency and photoinduced dye quenching
Efficiency as a color stabilizer may be increased. general
One measure of electron donating properties used in
(Eg, "Exploring Q
SAR, Hydrophobic, Electronic and Steric Constant
s ", C. Hansch, A. Leo and D. Hoekman, American Che
mical Society, 1995). Electronic
Donor groups generally have a negative Hammett sigma value. Book
In a preferred embodiment of the present invention, the Hammett's σ
The sum of the values is less than -0.10 (based on the bonding position of L)
). [0039] The stabilizer of the present invention comprises the ink jet of the present invention.
0.04 to 1.6 g / m^Two, Preferably 0.08
~ 0.8g / m^TwoIs applied. Binder used in the base layer
Is preferably a hydrophilic polymer. The present invention
Examples of useful hydrophilic polymers include polyvinyl alcohol.
, Polyvinylpyrrolidone, polyethyloxazolyl
, Poly-N-vinylacetamide, non-deionized Type IV
Bone gelatin or deionized Type IV bone gelatin, acidified
Ossein gelatin, pork skin gelatin, acetylated gelatin
, Phthalated gelatin, oxidized gelatin, chitosan, poly
Alkylene oxide, sulfonated polyester, partially
Poly (vinyl acetate / vinyl alcohol)
), Polyacrylic acid, poly 1-vinyl pyrrolidone, poly
Sodium styrene sulfonate, poly (2-acrylamide
De-2-methanesulfonic acid), polyacrylamide,
Include mixtures thereof. In a preferred embodiment of the present invention
The binder is gelatin or polyvinyl alcohol.
Call. The hydrophilic polymer is used in an amount of 0.1 to
30g / m^Two, Preferably 0.2 to 16 g / m^TwoEven if present in the amount
Good. Mass ratio of polymer mordant to binder
Is 1:99 to 8: 2, preferably 1: 9 to 4: 6
You. Further, the binder in the base layer
Latex polymer particles and / or inorganic oxidation in
Particles to increase the porosity of the layer and increase the drying time.
May be improved. Preferably, the latex polymer
The particles and / or inorganic oxide particles may be cationic or
Is neutral. Preferably, the latex polymer particles
The child is porous. Examples of inorganic oxide particles include sulfuric acid burrs.
Um, calcium carbonate, clay, silica, or aluminum
Mina, or a mixture thereof. In that case,
The mass% of the fine particles in the image receiving layer is 70 to 98%, preferably
Or 80-95%. By the addition of organic or inorganic acids or bases
Thus, an aqueous ink composition used with the element of the present invention
May be adjusted. Useful inks are used
Depending on the type of dye used, it has a preferred pH of 2 to 10.
It may be. Typical inorganic acids include hydrochloric acid, phosphorus
Acids, and sulfuric acid. Typical organic acids include meta
Sulfonic acid, acetic acid, and lactic acid. Typical
Inorganic bases include hydroxides and carbonates of alkali metals.
included. Typical organic bases include ammonia, trie
Tanolamine and tetramethylethylenediamine
Is included. If the ink dries or the print head
To help prevent clumping in the orifice,
Ink jet compositions used with the elements of the present invention
Use a wetting agent. Of wetting agents that can be used
Examples include polyhydric alcohols (eg, ethylene glycol,
Diethylene glycol, triethylene glycol, pro
Pyrene glycol, tetraethylene glycol, polyether
Tylene glycol, glycerol, 2-methyl-2,4-pen
Tandiol, 1,2,6-hexanetriol, and thiol
Glycols), low derived from alkylene glycols
Mono- or diethers of lower alkyls (e.g.
Monomethyl ether or monoethyl ethylene glycol
Monomethyl ether of diether glycol and diethylene glycol
Or monoethyl ether, propylene glycol
Monomethyl ether or monoethyl ether, triet
Monomethyl ether or monoethyl ethylene glycol
Diether, dimethyl ether of diethylene glycol
Or diethyl ether, and diethylene glycol
Monobutyl ether), nitrogen-containing cyclic compounds (for example,
Loridone, N-methyl-2-pyrrolidone, and 1,3-dimethyl
Le-2-imidazolidinone) and sulfur-containing compounds (eg
For example, dimethyl sulfoxide and tetramethylene sulfoxide
) Is included. Preferred for the composition used in the present invention.
Preferred wetting agents are diethylene glycol, glycerol
Or diethylene glycol monobutyl ether
is there. Paper whose receiving substrate is highly sized
Especially when used with the elements of the invention.
Add a water-miscible organic solvent to a water-soluble ink
It may help penetrate the substrate. Examples of such solvents
Include alcohols (eg, methyl alcohol, ethyl alcohol)
Alcohol, n-propyl alcohol, isopropyl alcohol
, N-butyl alcohol, s-butyl alcohol, t-butyl alcohol
Tyl alcohol, isobutyl alcohol, furfurylua
Alcohol and tetrahydrofurfuryl alcohol
Ketone or keto alcohol (eg, acetone,
Methyl ethyl ketone, and diacetone alcohol),
Ethers such as tetrahydrofuran and dioxa
), And esters (eg, ethyl lactate,
And propylene carbonate). Surface tension of ink by adding surfactant
May be adjusted to an appropriate level. The surfactant is ani
On, cationic, zwitterionic, or nonionic
It may be. The compositions used with the elements of the present invention
Add a herbicide and add microorganisms (e.g.
Growth of bacteria, fungi, etc.). In the present invention
Preferred biocides for ink compositions used in
Proxel (trademark) GXL having a degree of 0.0001 to 0.5% by mass (Zeneca
Specialties Co.). A typical a used with the elements of the present invention
The ink composition comprises, for example, the following components:
It may be. Coloring agent (0.05-5 mass%), water (20-95 quality)
%), Wetting agent (5-70% by mass), water-miscible auxiliary solvent
(2-20% by mass), surfactant (0.1-10% by mass), killing
Raw agent (0.05-5 mass%) and pH adjuster (0.1-10
mass%). Ink jets used with the elements of the present invention
May optionally be present in the ink composition.
Additives include thickeners, conductivity enhancers, kogation
Antiseptics, desiccants, and defoamers. Ink jets used with elements of the present invention
Ink to the print of the inkjet printer.
Ink droplets from multiple nozzles or orifices
Liquid ink in a controlled manner by jetting
Ink jet printing where droplets are applied to an ink receiving layer substrate
It may be used in printing. The image used in the element of the present invention
The image recording layer contributes to the non-blocking properties of the image recording layer
Matting agent for controlling the stain resistance of the image recording layer
(Eg, titanium dioxide, zinc oxide, silica,
Beads (such as cross-linked polymethyl methacrylate beads)
Or polystyrene beads)), surfactants (eg non-a
On-hydrocarbon or fluorinated hydrocarbon surfactants or
Cationic surfactants (eg quaternary ammonium
Salt)), fluorescent dye, pH adjuster, defoamer, lubricant, preservative
Agents, viscosity modifiers, dye fixing agents, waterproofing agents, dispersants, ultraviolet rays
Absorbent, fungicide, mordant, antistatic agent, antioxidant, firefly
Contains various known additives including photo brighteners
You can also. If desired, harden the ink receiving layer.
A film agent may be added. For the ink jet recording element of the present invention
The support can be paper, resin-coated paper, polyester, or fine
Porous materials (eg, PPG In of Pittsburgh, Pennsylvania)
Under the trade name Teslin ™ by dustries, Inc.
Polyethylene polymer containing materials sold), Tyv
ek ™ synthetic paper (DuPont Corp.) and OPPalyte (trademark)
Mark) Film (Mobil Chemical Co.) and US Patent No.
 No. 5,244,861.
Commonly used in inkjet receivers, such as films
It can be any of those. For opaque supports
Are plain paper, coated paper, synthetic paper, photographic printing paper support,
Melt-extruded coated paper, and laminated paper (eg, biaxially oriented support
Laminate). Biaxially oriented support laminates are
Nos. 5,853,965, 5,866,282, 5,874,205,
5,888,643, 5,888,681, 5,888,683,
And 5,888,714. this
These biaxially oriented supports include paper-based and paper-based strips.
Biaxially oriented polyolefin sheet laminated on one or both sides
(Generally polypropylene). On transparent support
Refers to glass, cellulose derivatives (eg, cellulose
Stele, cellulose triacetate, cellulose diacetate, acetate acetate
Cellulose ropionate, cellulose acetate butyrate), polye
Stell (eg polyethylene terephthalate, polyethylene
Lennaphthalate, poly-1,4-cyclohexanedimethylene
Terephthalate, polybutylene terephthalate, and
And their copolymers), polyimides, polyamides,
Carbonate, polystyrene, polyolefin (e.g.
Polyethylene or polypropylene), polysulfo
Polyacrylate, polyetherimide, and
These mixtures are included. In the papers listed above, high quality
Paper (for example, photographic printing paper) to low-quality paper (for
Paper). The support used in the present invention is preferably 50 to
 Has a thickness of 500 μm, preferably 75-300 μm
Is also good. If desired, antioxidants, antistatics,
Plasticizers and other known additives can be introduced into the support
Good. In a preferred embodiment, paper is used. Improved adhesion of image recording layer to support
Before applying the image recording layer, the surface of the support
May be subjected to a corona discharge treatment. Furthermore, halogenated phenols or moieties
-Hydrolyzed vinyl chloride-vinyl acetate copolymer
Applying an undercoat layer such as a layer formed from the surface of the support
Thus, the adhesiveness of the image recording layer can be enhanced. Undercoat
If using a layer, its thickness (ie dry coating thickness)
Should be less than 2 μm. The image recording layer is not effective for the intended use
It may be present in a shift amount. Generally, 2 to 60 g / m^Two,
Preferably 6 to 40 g / m^Two(2-50 μm, preferably 6-40
(equivalent to dry thickness of μm)
Good results are obtained in some cases. The overcoat layer is suitable for the intended use.
It may be present in any effective amount. In general, 1.1 ~
10.7g / m^Two, Preferably 1.6 to 5.4 g / m^Two(1.0 ~ 10μm,
Preferably equivalent to a dry thickness of 1.5 to 5 μm).
-Good results are obtained when a bar coat layer is present.
You. The following example illustrates the utility of the present invention.
You. [0060] EXAMPLES The following polymers were mordanted in an image receiving layer.
Used as an agent. MP-1: Poly (N-vinylbenzyl chloride-N, N, N-trime
(Tylammonium-co-divinylbenzene) (approx. 90/10
% (US Patent No. 6,045,917) MP-2: poly (styrene-co-N-vinylbenzyl chloride-
(N, N, N-trimethylammonium-co-divinylbenzene)
(About 49/49/2 mol%) (US Patent No. 6,045,917) [0061]Synthesis of UVL-1 260 g deionized water, 2.26 g 20% sodium N-methyl
-N-oleoyl taurate (surfactant Igepon
 T-77 ™) and 26 g of acetone were mechanically stirred.
500mL equipped with stirrer, nitrogen inlet, and condenser
Mix in a four neck round bottom flask. Keep the flask at 80 ° C
In a constant temperature bath and purge with nitrogen for 30 minutes.
Heated. The monomer solution contained 6.46 g of 2- (2'-hydroxy-
5-methacrylyloxyethylphenyl) -2H-benzotri
Azole (0.02 mol), 2.00 g of ethyl acrylate (0.
02 mol), 0.23 g of 2-sulfo-1,1-dimethylethylac
Lilamide, sodium salt (0.001 mol), and 130
mL of N, N-dimethylformamide
Was. The supplemental feed solution contains 0.9 g of Igepon T-77 ™
(20%), 1.8 g sodium persulfate, and 20 g
Manufactured from ionic water. 3.91 g of 5% potassium persulfate
Added to the reactor and stirred for 3 minutes. This monomer and
Pump solution of auxiliary feed into reactor over 4 hours
Transported. The polymerization lasted 8 hours. Cool the latex,
Filtered and dialyzed overnight against distilled water. Next, this latte
By the Amicon Ultrafiltration unit
Concentrated to the desired concentration. [0062]Synthesis of UVL-3 UVL-3 is 6.86 g of 2- (2-hydroxy-4-m-vinyl)
Benzyloxyphenyl) benzotriazole and 2
-(2-hydroxy-4-p-vinylbenzyloxyphenyl)
Benzotriazole (60:40) (0.02 mol), 5.12 g
Butyl acrylate (0.04 mol), 0.23 g of 2-sulfo-1,
1-dimethylethylacrylamide, sodium salt (0.0
01 mol), and 130 mL of N, N-dimethylformamide
Except that the mixture was used as a monomer solution,
Prepared by the same method. [0063]Example 1: Light in a gelatin based coating
Stability Preparation of water-soluble anionic dye ink composition I-1 Ink I-1 containing Dye1 as defined above
With the dye concentrate (3.1%) in 6%
Len glycol (Aldrich Chemical Co.) and glycer
Roll (Acros Co.) wetting agent, 0.003% by weight biocide
(Proxcel GXL ™ biocide (Zeneca Specialitie
s)), and 0.05% by weight of a surfactant (Surfynol 465)
(Trademark) (Air Products Co.))
Prepared by mixing with water. The concentration of the dye is determined by the absorption spectrum of the solution.
When the final ink is diluted 1: 1000 based on
Selected to produce a transmission optical density of approximately 1.0
Was. [0065]Water-soluble anionic dye ink composition I-2
Preparation of Dye2 specified above (Reactive Red 31, CAS-12237
-00-2) contains 100 g of commercially available ink I-2.
Ink with 0.5 g Surfynol 465 ™ surfactant (Air
Products Inc.)
ajet ™ Magenta Ink (Lyson Inc.)
And [0066]Preparation of Control Ink Recording Element C-1 Composite of polyethylene resin coated photographic grade paper support
The material side was subjected to corona discharge treatment before coating. Control A
The ink recording element was coated from distilled water on the paper support described above.
0.86g / m^TwoMordant polymer MP-2, 7.75 g / m^Twoof
Gelatin, and 0.09 g / m^TwoS-100 polystyrene beads
(12 μm) (ACE Chemical Co.)
And [0067]The ink recording elements E-1 to E-2 of the present invention
Preparation The recording elements E-1 to E-2 of the present invention include two layers.
Become. The base layer was applied from distilled water, 0.86 g / m^Twoof
Mordant polymer MP-2, 7.43 g / m^TwoGelatin, 0.09g /
m^TwoS-100 polystyrene beads (12μm) (ACE Chemica
l Co.), and 0.33 g / m^TwoS-1 (E-1) or S-
2 (E-2). Next, 0.61 g / m^TwoUVL-
1, 1.51 g / m^TwoOf gelatin, and 0.02 g / m^TwoOlin 10G
Overcoat a mixture of (trademark) surfactant from distilled water
Was. [0069]The ink recording elements E-3 to E-4 of the present invention
Preparation The recording elements E-3 to E-4 of the present invention comprise an overcoat layer
But 0.67g / m^TwoUVL-2 and 1.51 g / m^TwoBlended with gelatin
Except that the compound of the above E-1 and
And E-2. [0070]printing Elements E-1 to E-4 and control element C-1 have
200 using a commercial ink I-1 and I-2 (trademark)
Mark) Printed using a printer. After printing all
The image was dried overnight at room temperature and X-Rite 820 ™
Use a densitometer to measure the concentration at all stages
did. In step 11 for I-1 and I-2
The Dmax concentration was recorded in Table II below. Next, the above image was converted to 50 klux, 5400 °
K, 2 weeks for high-intensity daylight fading test at about 25% RH
Attached between. Status A closest to 1.0
Compare the blue and green reflection densities before and after
% Of the yellow ink (I) of each receiver element.
-1) and magenta ink (I-2)
Was. These results can be found in Table II below.
it can. [0072] [Table 3] The above results indicate that the recording elements E-1 to E-1 of the present invention were used.
-4, compared to the control standard recording element C-1,
Higher Dmax density and density retention after photobleaching
(%). [0074]Example 2: Stabilizer and UV overcoat
Coating and stabilizer containing only or UV
Light with coating containing only overcoat
Stability contrast Preparation of Control Ink Recording Elements C-2 to C-3 Control ink recording elements C-2 to C-3 were prepared from distilled water.
0.86g / m applied^TwoMordant polymer MP-2, 7.43
g / m^TwoGelatin, 0.09g / m^TwoS-100 polystyrene beads
(12 μm) (ACE Chemical Co.), and 0.33 g / m^TwoS-
1 (C-2) or S-2 (C-3)
It became. [0075]Preparation of Control Ink Recording Element C-4 Control ink recording element C-4 was prepared as described above.
0.61 g / m^TwoUVL-1, 1.51 g / m^TwoZelatin
And 0.02 g / m^TwoOf Olin 10G ™ surfactant
The compound was prepared by overcoating from distilled water. [0076]Preparation of Control Ink Recording Element C-5 Control ink recording element C-5 was replaced with UVL-1.
0.67g / m^TwoC-4 except that UVL-2 was used.
Was prepared in the same manner as described above. [0077]printing Using 1-1 and 1-2, as described in Example 1
Elements E-1 to E-4 and control elements C-1 to C
-5 was printed. These results are shown in Table III below.
Can be found. [0078] [Table 4]The above results indicate that the recording elements E-1 to E-1 of the present invention were used.
-4 compared to Control Recording Elements C-1 to C-5:
After high intensity daylight fade, higher Dmax density and density preservation
This indicates that the ownership rate (%) has occurred. This is cheap
Use a combination of fixing agent and UV overcoat
By using any of these materials individually
, Which results in superior performance. [0080]Example 3: Light stability in PVA coating
sex Preparation of Control Ink Recording Elements C-6 to C-7 Control ink recording elements C-6 to C-7 were prepared from distilled water.
1.19g / m applied^TwoMordant polymer MP-2, 9.13
g / m^TwoGH-17 (C-6, Gohsenol (trademark)
Mark), 86.5-89.0% hydrolysis, 27-33 cps) or KH-
17 (C-7, Gohsenol ™, 78.5-81.5% water
Solution, 32-38 cps) Polyvinyl alcohol (Nippon Gohse
i) any of 0.43g / m^TwoS-2, and 0.05 g / m^TwoO
lin shall consist of a mixture of 10G ™ surfactants
Was. [0081]The ink recording elements E-5 to E-6 of the present invention
Preparation The recording elements E-5 to E-6 of the present invention may be replaced with gelatin.
UVL-1 and GH-17 (E-5) or KH-17 (E-
Coating C-6 and C-7 using the mixture with 6)
Was prepared in the same manner as in the above E-2, except that [0082]printing Using 1-2, as described in Example 1, element E-5
~ E-6 and control elements C-6 ~ C-7
Was. These results can be found in Table IV below.
it can. [0083] [Table 5] The above results indicate that the recording elements E-5 to E of the present invention were used.
-6 compared to control recording elements C-6 and C-7
Higher density and density retention after high-intensity daylight fading
Rate (%). [0085]Example 4 Preparation of sets I-3 to I-5 of water-soluble anionic dye inks Yellow inkjet ink I-3 has a dye
 Direct Yellow 132 (Dye1, Projet Yellow 1G above)
(Trademark), Zeneca Specialities, 10% aqueous solution)
Prepared using standard formulations. Magenta ink I
-4 is the above-mentioned Dye3 (for details, see US Pat.
No. 01,161).
Prepared using the standard formulation. Cyan ink jet
Twink I-5 is a direct dye 199 (top)
See Dye4. Duasyn T manufactured by Clariant Corp.
urquoise Blue FRL-SF ™, 10% aqueous solution)
Prepared using the standard formulation. Standard formulations used in these inks
Is 2-pyrrolidinone (3%), triethylene glycol
(5%), glycerin (4%), Dowanol DB (2.5
%), And Surfynol 465 ™ (0.5%).
About I-4, triethanolamine (0.25%)
Was added. The dye concentration in each ink is determined by the solution absorption.
Based on the yield spectrum, the final ink is 1: 1000
When diluted, it produces a transmission optical density of approximately 1.0.
I chose. The percentage of each dye used is shown in the table below.
Summarize in V. [0087] [Table 6][0088]printing Elements E-5 to E-6 and the reference element C-6 of Example 3
C-7, Lex using the above-mentioned inks I-3 to I-5
mark Using a Z51 ™ Inkjet Printer
Printed. After printing, dry all images overnight at room temperature.
Let dry and use an X-Rite820 ™ densitometer to
In the step, the concentration was measured. Then these images
At 50 kilolux, 5400 ° K, approximately 25% RH
The illuminance daylight fading test was subjected to two weeks. 50%
Single color (yellow, magenta, and shear)
Color) and two color combinations (red, green, and blue) and
Status A for a combination of three colors (natural colors)
Compare the reflection densities before and after fading, and save the density for each.
Retention (%) was recorded. These results are shown in Table VI below.
Can be found in VIII. [0089] [Table 7] [0090] [Table 8] [0091] [Table 9] The above results indicate that the recording elements E-5 to E of the present invention were used.
-6 compared to control recording elements C-6 and C-7
High-light daylight fading in all color combinations
Later showed that a higher concentration retention rate (%) occurred
I have. [0093] Another preferred embodiment of the present invention is defined by the claims.
In relation, it is described next. [1] a) Polymer Binder, Polymer Medium
Dyes, and the formula: [0095] Embedded image A stabilizer having the formula:
R is independently substituted or unsubstituted 1-7 carbon atoms
Alkyl or alkoxy group having an atom, 6 to 10
Phenyl group having 6 carbon atoms, 6-10 carbon atoms
A phenoxy group having 1 to 8 carbon atoms
Represents a rubonamide group, or two or more R groups
And n may be 1 to 3 to form a ring structure.
4 and L contains at least one carbon atom
Is a linking group, and M⁺ Is a monovalent cation
Is the sum of the carbon atoms in all R and L combined
The number is at least three and at least one R is
A base layer comprising a stabilizer, which is a alkoxy group;
Bini b) Overcoat comprising polymeric UV absorbing material
Layers, comprising a support carrying the layers in the order described.
An inkjet recording element consisting of [2] The polymer ultraviolet absorbing material is as follows:
Comprising the repeating unit below, [0098] Embedded imageIn the above formula, R₁ Is H or CH_Three Represents
R_Two Is H, halogen, alkoxy, or 1-8
Represents a linear or branched alkyl group having carbon atoms
Then R_Three Is H, Cl, alkoxy, or 1-4
Represents an alkyl group having a carbon atom, and X represents COO, C
Represents ONH, or aryl, and Y is 2-10
Or an alkylene group having a carbon atom of_Two )_m O
Wherein m is 1 to 4;
Elementary. [3] R₁ Is CH_Three And R_Two Is H
Represents, R_Three Represents H, X represents COO, and Y represents
CH_Two CH_Two The element according to [2], wherein [4] R₁ Represents H, R_Two Represents H
Then R_Three Represents Cl, X represents COO, and Y represents
CH_Two CH_Two CH_Two The element according to [2], wherein [5] The polymer binder is hydrophilic.
An element according to [1]. [6] When the hydrophilic polymer is a polyvinyl
The alcohol according to [5], which is alcohol or gelatin.
Elementary. [7] The polymer UV-absorbing material is used in an amount of 0.1.
05-4.0g / m^TwoThe element of [1], which is present in an amount of [8] The polymer mordant is 0.2 to 16 g /
m^TwoThe element of [1], which is present in an amount of [9] The overcoat layer is hydrophilic.
The essential substance according to [1], which contains a polymer binder.
Elementary. [10] A) In response to a digital data signal
The process of preparing an inkjet printer that answers B) The printer according to [1],
Loading the recording element, C) water, a humectant, and a water-soluble dye
For loading an inkjet ink composition comprising
About D) the ink jet in response to the digital data signal;
Printing on the overcoat layer using inkjet ink
And an inkjet printing method.

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Claims (1)

Claims: 1. A) a polymeric binder, a polymeric mordant,
And the following formula: Wherein each R is independently a substituted or unsubstituted alkyl or alkoxy group having 1 to 7 carbon atoms,
Represents a phenyl group having 6 to 10 carbon atoms, a phenoxy group having 6 to 10 carbon atoms, a carbonamido group having 1 to 8 carbon atoms, or two or more R groups together. May be linked to form a ring structure, n is 1-4, L is a linking group containing at least one carbon atom, and M ⁺ is a monovalent cation A base layer comprising a stabilizer, wherein the total number of carbon atoms in the sum of all R and L is at least 3 and at least one R is an alkoxy group; An ink jet recording element comprising a support carrying in the order described an overcoat layer comprising a molecular ultraviolet absorbing material.