JP2003165857A - Elastic member and image formation apparatus - Google Patents

Elastic member and image formation apparatus

Info

Publication number
JP2003165857A
JP2003165857A JP2001365713A JP2001365713A JP2003165857A JP 2003165857 A JP2003165857 A JP 2003165857A JP 2001365713 A JP2001365713 A JP 2001365713A JP 2001365713 A JP2001365713 A JP 2001365713A JP 2003165857 A JP2003165857 A JP 2003165857A
Authority
JP
Japan
Prior art keywords
elastic member
elastic
elastic body
developer
fluorine compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001365713A
Other languages
Japanese (ja)
Inventor
Manabu Yakushiji
薬師寺  学
Yukihiro Kusano
行弘 草野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Priority to JP2001365713A priority Critical patent/JP2003165857A/en
Publication of JP2003165857A publication Critical patent/JP2003165857A/en
Pending legal-status Critical Current

Links

Abstract

<P>PROBLEM TO BE SOLVED: To obtain an elastic member provided with an elastic body which does not occur toner fixation and can supply a stable image for a long period of time, and to provide an electrophotographic apparatus using the elastic member. <P>SOLUTION: This elastic member is obtained by chemically bonding a fluorine compound to the surface of an elastic body by plasma treatment under atmospheric pressure. This electrophotographic apparatus is incorporated with the elastic member provided with the elastic body as a charged member, development solution supply body, development solution carrier, transfer member, development solution control blade, intermediate transfer member, etc. <P>COPYRIGHT: (C)2003,JPO

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、弾性体に関するも
ので、主に電子写真装置の部材である、帯電部材、現像
剤供給体、現像剤担持体、転写部材、現像剤量規制ブレ
ード、中間転写部材等に用いられる弾性体と、この弾性
体を装着して成る電子写真装置に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an elastic body, which is mainly a member of an electrophotographic apparatus, such as a charging member, a developer supply member, a developer carrying member, a transfer member, a developer amount regulating blade, and an intermediate member. The present invention relates to an elastic body used for a transfer member and the like, and an electrophotographic apparatus equipped with this elastic body.

【0002】[0002]

【従来の技術】従来、複写機、ファクシミリ、プリンタ
ー等の電子写真方式あるいは静電記録方式の画像形成装
置においては、例として図1に示す様に、まず、帯電部
材1を画像形成部材2に当接させ、この被帯電体との間
に電圧を印加することにより画像形成部材2を帯電させ
る。この画像形成部材2上にレーザー光を用いて画像を
書き込むことにより静電潜像を形成する。一方、現像剤
供給体3より現像剤担持体4に対して現像剤5が供給さ
れ、次に現像剤担持体4が回転することにより矢印方向
に運ばれた現像剤5が、現像剤担持体4と圧接する形で
配置された現像剤量規制ブレ−ド6との間を通過するこ
とで現像剤担持体4上の現像剤5が適正な厚さに規制さ
れ、同時に現像剤量規制ブレ−ド6と現像剤5との摩擦
帯電により現像剤5に適正な電荷が帯電され、さらに、
現像剤担持体4に対して当接あるいは一定の距離をもっ
て配置された画像形成部材2上の静電潜像に現像剤5が
付着することにより、現像が行われる。その後、転写部
材7を用いて画像形成部材2上の現像剤5を紙面8に転
写し、その後加熱・定着することにより紙面への印刷が
行われる。
2. Description of the Related Art Conventionally, in an electrophotographic type or electrostatic recording type image forming apparatus such as a copying machine, a facsimile or a printer, as shown by way of example in FIG. The image forming member 2 is charged by bringing them into contact with each other and applying a voltage to the member to be charged. An electrostatic latent image is formed by writing an image on the image forming member 2 using laser light. On the other hand, the developer 5 is supplied from the developer supply body 3 to the developer carrying body 4, and the developer 5 carried in the arrow direction by the rotation of the developer carrying body 4 is the developer carrying body. 4 and the developer amount regulation blade 6 arranged in pressure contact with each other, the developer 5 on the developer carrier 4 is regulated to an appropriate thickness, and at the same time, the developer amount regulation blade 6 is regulated. By the frictional charging between the developer 6 and the developer 5, the developer 5 is appropriately charged, and
Development is carried out by adhering the developer 5 to the electrostatic latent image on the image forming member 2 which is in contact with the developer carrying member 4 or is arranged at a certain distance. After that, the developer 5 on the image forming member 2 is transferred onto the paper surface 8 by using the transfer member 7, and then heating and fixing are performed to perform printing on the paper surface.

【0003】このような、帯電部材、現像剤供給体、現
像剤担持体、転写部材、現像剤量規制ブレード等の部材
には、いずれもゴム・ウレタンなどの弾性体が用いられ
るが、長期間使用し続けるためには、表面にトナーが付
着・凝固するいわゆるトナー固着が発生しにくいことが
必要である。一般に、トナーの固着を低減する方法とし
ては、上記部材上にフッ素樹脂等の低付着性・低摩擦性
の塗膜層を形成する方法や、フッ素やシリコーンを含有
する低分子量の離型剤を部材に添加する方法が採られて
いる。
An elastic body such as rubber or urethane is used for all members such as the charging member, the developer supplying member, the developer carrying member, the transferring member, and the developer amount controlling blade, but for a long period of time. In order to continue the use, it is necessary that the so-called toner adhesion, in which the toner adheres and solidifies on the surface, does not easily occur. Generally, as a method for reducing toner sticking, a method of forming a low-adhesion / low-friction coating layer such as a fluororesin on the above member, or a low-molecular weight release agent containing fluorine or silicone is used. The method of adding to a member is adopted.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、弾性体
が発泡体の場合は塗膜が塗布できず、またフッ素樹脂で
形成した塗膜は非常に脆いため、長期間の使用で塗膜が
割れる等の問題を抱えている。一方、上記離型剤を部材
に添加した場合、長期間の使用によって離型剤が表面に
ブリードアウトし、紙面や感光体を汚染し画像の劣化を
引き起こすという問題を抱えている。本発明は、上記実
情に鑑みて鋭意検討されたものであり、トナー固着が発
生せず、長期間に渡って安定した画像を供給し得る弾性
体と、上記弾性体を用いた電子写真装置を提供すること
を目的とする。
However, when the elastic body is a foam, the coating film cannot be applied, and since the coating film formed of the fluororesin is very brittle, the coating film may crack after a long period of use. Have a problem. On the other hand, when the above-mentioned release agent is added to a member, there is a problem that the release agent bleeds out on the surface due to long-term use and contaminates the surface of the paper and the photoconductor to cause image deterioration. The present invention has been earnestly studied in view of the above circumstances, and an elastic body capable of supplying a stable image for a long period of time without toner sticking, and an electrophotographic apparatus using the elastic body. The purpose is to provide.

【0005】[0005]

【課題を解決するための手段】本発明者らは、上記目的
を達成するために鋭意検討を重ねた結果、大気圧プラズ
マ処理により弾性体の表面にフッ素化合物を化学的に結
合することによってトナー固着が低減することを見出
し、本発明に到った。
DISCLOSURE OF THE INVENTION As a result of intensive studies to achieve the above object, the inventors of the present invention have found that a toner is obtained by chemically bonding a fluorine compound to the surface of an elastic body by atmospheric pressure plasma treatment. The inventors have found that sticking is reduced and have reached the present invention.

【0006】[0006]

【発明の実施の形態】以下、本発明について詳細に説明
する。本発明の弾性体は、プリンター、複写機、ファク
シミリなどの電子写真装置に装着される、帯電部材、現
像剤供給体、現像剤担持体、転写部材、現像剤量規制ブ
レード、中間転写部材等の部材に用いられるもので、特
にその形状が限定されるものではなく、ロール状、プレ
ート状、ブロック状、ベルト状、ドラム状などの各種形
状のものが用途に応じて適宜選択される。例えば、帯電
部材、現像剤供給体、現像剤担持体、転写部剤等の部材
にはロール形状が適当であり、例えば図2(a)に示す
ように、金属あるいはプラスチック製のシャフト9と、
このシャフト9の外周に形成された弾性体からなる弾性
層10とを備えた構造や、図2(b)に示すように、弾
性層10の外側に保護層11を備えた構造を例示するこ
とが出来る。
BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below. The elastic body of the present invention is used as a charging member, a developer supplying body, a developer carrying body, a transfer member, a developer amount regulating blade, an intermediate transfer member, etc., which is mounted on an electrophotographic apparatus such as a printer, a copying machine, a facsimile machine. It is used for a member, and its shape is not particularly limited, and various shapes such as a roll shape, a plate shape, a block shape, a belt shape, and a drum shape are appropriately selected according to the application. For example, a roll shape is suitable for members such as a charging member, a developer supply member, a developer carrying member, and a transfer part agent. For example, as shown in FIG. 2A, a shaft 9 made of metal or plastic,
A structure including an elastic layer 10 formed of an elastic body formed on the outer periphery of the shaft 9 and a structure including a protective layer 11 outside the elastic layer 10 as shown in FIG. Can be done.

【0007】また、現像剤量規制ブレード等の部材には
プレート形状が適当であり、図3(a)に例示する様
に、金属あるいは樹脂からなる支持部材12aの少なく
とも現像剤担持体と当接する表面に弾性体層13aを形
成したものが挙げられる。支持部材12a表面に弾性体
層13aを形成する手段としては、一般には塗布、一体
成形、あるいは予めシ−ト状に成形され、適当な形状に
裁断された弾性体を支持部材12aに接着するなどの方
法が採られている。支持部材12aと弾性体層13aと
の間には、必要に応じて接着剤層を設けても良い。ま
た、図3(b)に例示する様に、金属あるいは樹脂から
なる支持部材12bの先端の現像剤担持体と当接する位
置に弾性体13bを形成したものも挙げられる。支持部
材12b表面に弾性体層13bを形成する手段としては
一体成形などの方法が採られている。支持部材12bと
弾性体層13bとの間には、必要に応じて接着剤層を設
けても良い。
Further, a plate shape is suitable for a member such as a developer amount controlling blade, and as shown in FIG. 3A, it abuts at least the developer carrying member of the supporting member 12a made of metal or resin. The thing which formed the elastic body layer 13a on the surface is mentioned. As means for forming the elastic layer 13a on the surface of the supporting member 12a, generally, an elastic body which is applied, integrally molded, or preliminarily formed into a sheet shape and cut into an appropriate shape is adhered to the supporting member 12a. The method of is adopted. An adhesive layer may be provided between the support member 12a and the elastic layer 13a, if necessary. Further, as illustrated in FIG. 3B, the elastic member 13b may be formed at the position of the tip of the supporting member 12b made of metal or resin and in contact with the developer carrying member. As a means for forming the elastic layer 13b on the surface of the supporting member 12b, a method such as integral molding is adopted. An adhesive layer may be provided between the support member 12b and the elastic layer 13b, if necessary.

【0008】本発明の弾性体を形成する弾性層として
は、特に制限はないが、例示すると、イソプレンゴム、
ブタジエンゴム、スチレン・ブタジエンゴム、アクリロ
ニトリル・ブタジエンゴム、クロロプレンゴム、エチレ
ン・プロピレンゴム、エチレン・プロピレンタ−ポリマ
−、ブチルゴム、アクリルゴム、クロルスルフォン化ポ
リエチレン、シリコ−ンゴム、フッ素ゴム、ポリエ−テ
ルゴム、エピクロルヒドリンゴム、ウレタンゴム等のゴ
ム材料や、ポリウレタン、ポリスチレン・ポリブタジエ
ンブロック重合体、ポリオレフィン、ポリエチレン、塩
素化ポリエチレン、エチレン・酢酸ビニル共重合体等の
エラストマ−が挙げられる。これらは、単独で用いても
2種以上組み合わせても良いが、特に、ウレタン、シリ
コーンゴム、エチレン・プロピレンゴムが好ましい。ま
た、硬度を低下させるために弾性層は発泡体としても良
く、この場合、密度は0.1〜0.9g/cm3 が適当
である。
The elastic layer forming the elastic body of the present invention is not particularly limited, but for example, isoprene rubber,
Butadiene rubber, styrene / butadiene rubber, acrylonitrile / butadiene rubber, chloroprene rubber, ethylene / propylene rubber, ethylene / propylene terpolymer, butyl rubber, acrylic rubber, chlorosulfonated polyethylene, silicone rubber, fluororubber, polyether rubber, Examples thereof include rubber materials such as epichlorohydrin rubber and urethane rubber, and elastomers such as polyurethane, polystyrene / polybutadiene block polymer, polyolefin, polyethylene, chlorinated polyethylene, and ethylene / vinyl acetate copolymer. These may be used alone or in combination of two or more, but urethane, silicone rubber and ethylene / propylene rubber are particularly preferable. Further, in order to reduce the hardness, the elastic layer may be a foam, and in this case, the density is suitably 0.1 to 0.9 g / cm 3 .

【0009】また、本発明の弾性体を帯電部材、現像剤
供給体、現像剤担持体、転写部材等の半導電性が要求さ
れる部材に用いる場合には、その要求に合わせて体積抵
抗を102 〜1014Ωcmに調整することが必要であ
り、そのために導電材が添加される。用いられる導電材
に特に制限はないが、例えばカーボンブラック、金属、
金属酸化物等の電子導電性物質や4級アンモニウム塩等
のイオン導電性物質などが挙げられる。更に例示する
と、電子導電性物質ではケッチェンブラック、アセチレ
ンブラック等の導電性カーボン、SAF、ISAF、H
AF、FEF、GPF、SRF、FT、MTなどのゴム
用カーボン、酸化処理を施したインク用カーボン、熱分
解カーボン、天然グラファイト等のカーボンブラック、
アンチモンドープの酸化錫、酸化チタン、酸化亜鉛等の
金属酸化物、ニッケル、銅、銀、ゲルマニウム等の金属
などが挙げられる。
When the elastic body of the present invention is used for a member requiring semiconductivity such as a charging member, a developer supplying member, a developer carrying member and a transfer member, the volume resistance is adjusted to meet the demand. It is necessary to adjust to 10 2 to 10 14 Ωcm, and a conductive material is added for that purpose. The conductive material used is not particularly limited, for example, carbon black, metal,
Examples thereof include electronic conductive substances such as metal oxides and ionic conductive substances such as quaternary ammonium salts. To further exemplify, electron conductive materials include conductive carbon such as Ketjen black and acetylene black, SAF, ISAF, and H.
Carbon for rubber such as AF, FEF, GPF, SRF, FT, MT, carbon for ink subjected to oxidation treatment, pyrolytic carbon, carbon black such as natural graphite,
Examples thereof include metal oxides such as antimony-doped tin oxide, titanium oxide and zinc oxide, and metals such as nickel, copper, silver and germanium.

【0010】また、イオン導電性物質としては、テトラ
エチルアンモニウム、テトラブチルアンモニウム、ドデ
シルトリメチルアンモニウム(例えばラウリルトリメチ
ルアンモニウム)、ヘキサデシルトリメチルアンモニウ
ム、オクタデシリルトリメチルアンモニウム(例えばス
テアリルトリメチルアンモニウム)、ベンジルトリメチ
ルアンモニウム、変性脂肪酸ジメチルエチルアンモニウ
ムなどの過塩素酸塩、塩素酸塩、塩酸塩、臭素酸塩、ヨ
ウ素酸塩、ホウフッ化水素酸塩、硫酸塩、エチル硫酸
塩、カルボン酸塩、スルホン酸塩などのアンモニウム
塩、リチウム、ナトリウム、カリウム、カルシウム、マ
グネシウムなどのアルカリ金属やアルカリ土類金属の過
塩素酸塩、塩素酸塩、塩酸塩、臭素酸塩、ヨウ素酸塩、
ホウフッ化水素酸塩、トリフルオロメチル硫酸塩、スル
ホン酸塩などが挙げられる。これらの導電材は、単独で
用いても、2種以上組み合わせて用いてもよい。その添
加量は特に制限はなく、弾性体に要求される体積抵抗に
応じて決定すればよい。更に、弾性体には、必要に応じ
てシリカ、炭酸カルシウムなどの充填剤、オイル等の可
塑剤、架橋促進剤、架橋遅延剤、老化防止剤、着色剤な
どを適宜配合しても良い。
Further, as the ion conductive material, tetraethylammonium, tetrabutylammonium, dodecyltrimethylammonium (eg lauryltrimethylammonium), hexadecyltrimethylammonium, octadesilyltrimethylammonium (eg stearyltrimethylammonium), benzyltrimethylammonium, Modified fatty acid Perchlorate such as dimethylethylammonium, chlorate, hydrochloride, bromate, iodate, borofluoride, sulfate, ethylsulfate, carboxylate, sulfonate and ammonium Perchlorates, chlorates, hydrochlorides, bromates, iodates of salts, alkali metals and alkaline earth metals such as lithium, sodium, potassium, calcium, magnesium, etc.
Examples thereof include borofluoride, trifluoromethyl sulfate, and sulfonate. These conductive materials may be used alone or in combination of two or more. The amount added is not particularly limited and may be determined according to the volume resistance required for the elastic body. Further, if necessary, a filler such as silica or calcium carbonate, a plasticizer such as oil, a crosslinking accelerator, a crosslinking retarder, an antiaging agent, a colorant and the like may be appropriately added to the elastic body.

【0011】現像剤量規制ブレード等の部材における、
支持部材12a,12bを形成する金属としては、鉄、
銅、洋白、ステンレス、リン青銅などが挙げられ、樹脂
としては、ポリエチレン、ポリプロピレン、ポリスチレ
ン、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリウレタ
ン、ポリアミド、ポリアセタ−ル、ポリカ−ボネ−ト、
ポリエチレンテレフタレ−ト、ポリイミド、ポリアミド
イミド、ポリエステル、フェノ−ル樹脂、メラミン樹
脂、シリコン樹脂、エポキシ樹脂、アクリル樹脂、メタ
クリル樹脂、尿素樹脂等の合成樹脂が挙げられる。ま
た、前記弾性層から汚染物質がブリードアウトし、紙面
や画像形成部材を汚染し画像の劣化を引き起こす恐れが
ある場合は、それを防ぐために、弾性層上に保護層を形
成しても良い。保護層を形成する材料は、特に限定され
ないが、表面に柔軟性、平滑性を付与し得るものが好適
に用いられる。具体的には、ポリエステル樹脂、アクリ
ル樹脂、ウレタン樹脂、アクリルウレタン樹脂、ナイロ
ン樹脂、エポキシ樹脂、ポリビニルアセタール樹脂、塩
化ビニリデン樹脂、フッ素樹脂、シリコーン樹脂等が挙
げられる。更に、この保護層にも、必要に応じて、前記
導電材や架橋剤、増粘剤などの適宜な添加剤を必要に応
じて適量添加することができる。
In a member such as a developer amount control blade,
As the metal forming the support members 12a and 12b, iron,
Copper, nickel silver, stainless steel, phosphor bronze and the like can be mentioned, and as the resin, polyethylene, polypropylene, polystyrene, polyvinyl chloride, polyvinylidene chloride, polyurethane, polyamide, polyacetal, polycarbonate,
Examples thereof include synthetic resins such as polyethylene terephthalate, polyimide, polyamide imide, polyester, phenol resin, melamine resin, silicone resin, epoxy resin, acrylic resin, methacrylic resin and urea resin. Further, in the case where contaminants bleed out from the elastic layer to contaminate the surface of the paper or the image forming member and cause image deterioration, a protective layer may be formed on the elastic layer in order to prevent it. The material forming the protective layer is not particularly limited, but a material that can impart flexibility and smoothness to the surface is preferably used. Specific examples thereof include polyester resin, acrylic resin, urethane resin, acrylic urethane resin, nylon resin, epoxy resin, polyvinyl acetal resin, vinylidene chloride resin, fluorine resin, and silicone resin. Further, if necessary, an appropriate amount of the conductive material, the cross-linking agent, the thickener, and the like may be added to the protective layer.

【0012】本発明における、大気圧プラズマ処理によ
ってフッ素化合物を弾性体表面に化学的に結合させる方
法は、弾性体を処理室内に配置し、フッ素化合物を処理
室内に導入して処理室内に大気圧グロープラズマを発生
させる方法であり、弾性体表面に発生したラジカルと、
フッ素化合物のラジカルが結合し、弾性体表面にフッ素
化合物を導入できる。かかる大気圧でグロープラズマを
得る方法としては、例えば特開昭62−235339号
等で提案された方法を採用することが出来る。大気圧プ
ラズマ法は、大気圧付近の圧力で行われるため、大型の
真空装置を必要とせず、また、水分やガスの可塑剤等を
多く含む基材にも良好に対応し得、しかも処理時の発熱
もほとんど生じることがない。このため、低融点の基材
にも適応可能であるといった長所を有する上、局所的な
処理が可能で、基材の所望の部分のみを処理することが
容易に出来るという特徴も有する。プラズマの発生方法
としては、プラズマを発生し、かつこれにより弾性体表
面をフッ素化できる方法であればいかなる方法であって
も良いが、具体的には、内部電極方式による直流グロー
放電や低周波放電、内部電極方式または外部電極方式ま
たはコイル形方式による高周波放電、導波管型方式によ
るマイクロ波放電や電子サイクロトロン共鳴放電などが
挙げられる。また、フッ素化合物としては、プラズマ処
理後に表面をフッ素化出来る、言い換えれば、プラズマ
処理時にフッ素化合物のラジカルを発生するような化合
物であればいかなるものであっても使用できる。
In the method of chemically bonding the fluorine compound to the surface of the elastic body by the atmospheric pressure plasma treatment in the present invention, the elastic body is placed in the processing chamber, the fluorine compound is introduced into the processing chamber, and the atmospheric pressure is introduced into the processing chamber. It is a method of generating glow plasma, with radicals generated on the surface of the elastic body,
Radicals of the fluorine compound can bond to introduce the fluorine compound to the surface of the elastic body. As a method of obtaining glow plasma at such atmospheric pressure, for example, the method proposed in JP-A-62-235339 can be adopted. Since the atmospheric pressure plasma method is carried out at a pressure near the atmospheric pressure, it does not require a large vacuum device, and can be applied well to substrates containing a large amount of water or gas plasticizers. Almost no heat generation occurs. Therefore, it has an advantage that it can be applied to a base material having a low melting point, and also has a feature that local processing is possible and only a desired portion of the base material can be easily processed. The plasma may be generated by any method as long as plasma is generated and the surface of the elastic body can be fluorinated by the plasma. Specifically, direct current glow discharge or low frequency by the internal electrode method may be used. Examples include discharge, high frequency discharge by an internal electrode system, external electrode system or coil system, microwave discharge by a waveguide system and electron cyclotron resonance discharge. Further, as the fluorine compound, any compound can be used as long as it can fluorinate the surface after plasma treatment, in other words, a compound that generates radicals of the fluorine compound during plasma treatment.

【0013】上記フッ素化合物が処理室内温度や常温下
において気体状である場合には、これをそのまま処理室
内へ流入することができ、また液体状である場合には、
蒸気圧が比較的高ければその蒸気をそのまま流入しても
よいし、その液体を不活性ガスなどの希釈ガスでバブリ
ングして流入してもよい。一方、気体状でなくしかも蒸
気圧が比較的低い場合には、加熱することにより、気体
状または蒸気圧が高い状態にして用いることが出来る
が、処理の簡便性・安全性から、CHF3 、CH
2 2 、CH3 F、CF4 、SF6 、C3 6 、C4
8 等のフッ素化合物ガスが用いられるが、C3 6 の中
でもヘキサフルオロプロピレンが、また、C4 8 のな
かでもオクタフルオロシクロブタンが好適に用いられ
る。また、これらのフッ素化合物ガスは、そのまま用い
ても良いが、放電の持続性、安定性、経済性等の観点か
ら、必要に応じて、ヘリウム、アルゴン、ネオンなどの
不活性ガス、あるいは、窒素、水素、酸素などのガスの
1種を単独でまたは2種以上の混合ガスで希釈すること
も有効である。
When the above-mentioned fluorine compound is used in the temperature of the processing chamber or at room temperature
If it is gaseous in the process chamber, leave it as it is.
If it is in liquid form,
If the vapor pressure is relatively high,
The liquid is bubbled with a diluent gas such as an inert gas.
You may inflow and inflow. On the other hand, it is not gaseous and is steamed.
When the atmospheric pressure is relatively low, it can be heated
Can be used in a state of high pressure or high vapor pressure
However, due to the ease and safety of processing, CHF3, CH
2F2, CH3F, CFFour, SF6, C3F6, CFourF
8Fluorine compound gas such as3F6in
But hexafluoropropylene, CFourF 8No
In particular, octafluorocyclobutane is preferably used
It Also, these fluorine compound gases are used as they are.
It is OK, but from the viewpoint of discharge sustainability, stability, economic efficiency, etc.
, Helium, argon, neon, etc.
Of inert gas or gases such as nitrogen, hydrogen and oxygen
Diluting one kind alone or with a mixture of two or more kinds
Is also effective.

【0014】本発明にかかるプラズマ処理は、前記方法
によりプラズマ放電領域が形成される処理室内に被処理
物を収容し、この処理室内に上記フッ素化合物ガスや必
要に応じて同時に希釈ガスを連続的に供給することによ
り実施することが出来る。本発明において、プラズマ処
理を行う場合、処理室内へフッ素化合物ガスあるいはフ
ッ素化合物ガスと希釈ガスを供給して行うことが出来
る。なお、本発明の弾性体は、プリンター、複写機、フ
ァクシミリなどの電子写真装置に用いられる帯電部材、
現像剤供給体、現像剤担持体、転写部材、現像剤量規制
ブレード、中間転写部材等の部材に用いられる。
In the plasma treatment according to the present invention, an object to be treated is housed in a treatment chamber in which a plasma discharge region is formed by the above method, and the fluorine compound gas and, if necessary, a dilution gas are continuously fed into the treatment chamber. Can be implemented by supplying In the present invention, the plasma treatment can be performed by supplying a fluorine compound gas or a fluorine compound gas and a diluent gas into the treatment chamber. The elastic body of the present invention is a charging member used in an electrophotographic apparatus such as a printer, a copying machine, and a facsimile.
It is used as a member such as a developer supply member, a developer carrying member, a transfer member, a developer amount regulating blade, and an intermediate transfer member.

【0015】[0015]

【実施例】以下に、実施例及び比較例を示し、本発明を
具体的に説明するが、本発明は下記に限定されるもので
はない。
EXAMPLES The present invention will be specifically described below by showing Examples and Comparative Examples, but the present invention is not limited to the following.

【0016】実施例1 下記の配合1のウレタンエラストマ−原料を混合機で攪
拌混合し、金属シャフトを配置した金型に注型し、90
℃で6時間硬化した後研磨し、上記金属シャフトの外周
に長さ20cm、肉厚0.3cmの半導電性弾性体を形
成したローラ状の半導電性部材Aを作成した。この半導
電性部材Aの動摩擦係数μは、1.03であった。 (配合1) サンニックスGR5000(ポリエーテル系ポリオー
ル:三洋化成製:)60g PTG1000SN(ポリテトラメチレングリコール:
保土ヶ谷化学製)40g ルプラネートMB301(MDI系イソシアネート:B
ASF・イノアック製)22g ネオスタンU−100(錫触媒:日東化成製)0.00
4g デンカブラック(カーボンブラック:電気化学工業製)
2g
Example 1 Urethane elastomer raw materials of the following formulation 1 were mixed by stirring with a mixer and poured into a mold having a metal shaft, and 90
After being hardened at 0 ° C. for 6 hours, it was polished to prepare a roller-shaped semiconductive member A in which a semiconductive elastic body having a length of 20 cm and a thickness of 0.3 cm was formed on the outer circumference of the metal shaft. The dynamic friction coefficient μ of the semiconductive member A was 1.03. (Compound 1) Sannix GR5000 (polyether-based polyol: manufactured by Sanyo Kasei Co., Ltd.) 60 g PTG1000SN (polytetramethylene glycol:
Hodogaya Chemical Co., Ltd.) 40g Ruplanate MB301 (MDI isocyanate: B
ASF / Inoac) 22g Neostan U-100 (tin catalyst: Nitto Kasei) 0.00
4g Denka Black (Carbon Black: manufactured by Denki Kagaku Kogyo)
2 g

【0017】この半導電性部材Aを、図4に示した内部
電極型高周波プラズマ放電装置を用いて、下記の条件で
処理し、弾性体の表面にフッ素化合物を結合した。 フッ素ガス:C3 6 不活性ガス:He 放電周波数:5kHz 処理時間:60sec なお、図4中14は処理室、15はフッ素ガスと希釈ガ
ス供給管で、供給管15よりフッ素ガスを処理室内へ供
給すると共に、電極16a,16b間にプラズマ電源1
7よりプラズマ領域を形成させるとラジカルが発生し、
電極16a,16b間の被処理物18表面にフッ素化合
物が結合する。なお、19はガス排出管である。この処
理をして得られた半導電性部材A−Fの動摩擦係数μ
は、0.58であった。
The semiconductive member A was treated under the following conditions using the internal electrode type high frequency plasma discharge device shown in FIG. 4 to bond a fluorine compound to the surface of the elastic body. Fluorine gas: C 3 F 6 inert gas: He Discharge frequency: 5 kHz Processing time: 60 sec In addition, in FIG. 4, 14 is a processing chamber, 15 is a fluorine gas and dilution gas supply pipe, and fluorine gas is supplied from the supply pipe 15 to the processing chamber. To the plasma power source 1 between the electrodes 16a and 16b.
When a plasma region is formed from 7, radicals are generated,
A fluorine compound is bonded to the surface of the object 18 to be processed between the electrodes 16a and 16b. In addition, 19 is a gas discharge pipe. The coefficient of dynamic friction μ of the semiconductive members AF obtained by this treatment
Was 0.58.

【0018】この半導電性部材A−Fを、現像剤担持体
として、図1に示す様な電子写真装置に組み込んでプリ
ンターに装着し、常温常湿条件(22℃、50%RH)
にて連続印刷試験を行ったところ、5000枚まで良好
な画像が得られた。また連続印刷試験終了後に半導電性
部材A−Fを取り外し、表面を1000倍の顕微鏡にて
観察した結果、トナー固着は見られなかった。
The semiconductive members AF were incorporated as a developer carrying member into an electrophotographic apparatus as shown in FIG. 1 and mounted in a printer, and the conditions were room temperature and normal humidity (22 ° C., 50% RH).
When a continuous printing test was carried out at, good images were obtained up to 5,000 sheets. After the continuous printing test was completed, the semiconductive members AF were removed, and the surface was observed with a microscope of 1000 times. As a result, toner adhesion was not observed.

【0019】実施例2 下記の配合2のウレタン原料を混合機で攪拌混合し、金
属シャフトを配置した金型に注型し、90℃で6時間硬
化した後研磨し、上記金属シャフトの外周に長さ20c
m、肉厚0.3cmの半導電性発泡体を形成したローラ
状の半導電性部材Bを作成した。この半導電性部材Bの
動摩擦係数μは、1.50であった。 (配合2) サンニックスGR5000(ポリエーテル系ポリオー
ル:三洋化成製:)60g PTG1000SN(ポリテトラメチレングリコール:
保土ヶ谷化学製)40g ルプラネートMB301(MDI系イソシアネート:B
ASF・イノアック製)22g SF2941F(整泡剤:東レ・ダウコーニング・シリ
コーン製)4g ネオスタンU−100(錫触媒:日東化成製)0.00
8g デンカブラック(カーボンブラック:電気化学工業製)
2g
Example 2 Urethane raw materials having the following formulation 2 were mixed by stirring with a mixer, cast into a mold in which a metal shaft is placed, cured at 90 ° C. for 6 hours, and then polished, and the outer circumference of the metal shaft was obtained. Length 20c
A roller-shaped semi-conductive member B having a m-thickness of 0.3 cm and formed with a semi-conductive foam was prepared. The dynamic friction coefficient μ of this semiconductive member B was 1.50. (Formulation 2) Sannix GR5000 (polyether polyol: Sanyo Kasei Co., Ltd.) 60 g PTG1000SN (polytetramethylene glycol:
Hodogaya Chemical Co., Ltd.) 40g Ruplanate MB301 (MDI isocyanate: B
ASF / Inoac) 22g SF2941F (foam stabilizer: Toray Dow Corning Silicone) 4g Neostan U-100 (tin catalyst: Nitto Kasei) 0.00
8g Denka Black (Carbon Black: manufactured by Denki Kagaku Kogyo)
2 g

【0020】この半導電性部材Bを、実施例1と同様の
条件で大気圧プラズマ処理し、表面にフッ素化合物を結
合した。この処理をして得られた半導電性部材B−Fの
動摩擦係数μは、0.79であった。この半導電性部材
B−Fを、転写部材として、図1に示すような電子写真
装置に組み込んでプリンターに装着し、常温常湿条件
(22℃、50%RH)にて連続印刷試験を行ったとこ
ろ、10000枚まで良好な画像が得られた。また連続
印刷試験終了後に半導電性部材B−Fを取り外し、表面
を1000倍の顕微鏡にて観察した結果、トナー固着は
見られなかった。
This semiconductive member B was subjected to atmospheric pressure plasma treatment under the same conditions as in Example 1 to bond a fluorine compound on the surface. The dynamic friction coefficient μ of the semiconductive member BF obtained by this treatment was 0.79. This semi-conductive member BF was incorporated as a transfer member into an electrophotographic apparatus as shown in FIG. 1 and mounted in a printer, and a continuous print test was conducted under normal temperature and normal humidity conditions (22 ° C., 50% RH). As a result, good images were obtained up to 10,000 sheets. Further, as a result of removing the semiconductive members BF after the continuous printing test and observing the surface with a microscope of 1000 times, toner adhesion was not observed.

【0021】実施例3 下記の配合3のウレタンエラストマ−原料を混合し、片
面を鏡面加工した金属モ−ルドに注型、加熱硬化して
1.5mm厚のシ−ト状の弾性体を得た。得られたシ−
トを所定の大きさに裁断した後、両面テ−プを用いて支
持部材に接着することにより図3(a)に示す様な形状
の半導電性部材Cを得た。この半導電性部材Cの動摩擦
係数μは、1.41であった。 (配合3) コロネ−ト4387(ポリエステル系プレポリマ−:日
本ポリウレタン製)93.55g ニッポラン4038(低分子量ポリオ−ル:日本ポリウ
レタン製)5.95g ネオスタンU−100(錫触媒:日東化成製)0.00
2g
Example 3 A urethane elastomer raw material having the following formulation 3 was mixed, cast into a metal mold having one surface mirror-finished, and heat-cured to obtain a sheet-like elastic body having a thickness of 1.5 mm. It was The obtained sea
The sheet was cut into a predetermined size and then adhered to a supporting member using a double-sided tape to obtain a semiconductive member C having a shape as shown in FIG. 3 (a). The dynamic friction coefficient μ of this semiconductive member C was 1.41. (Compound 3) Colonate 4387 (polyester type prepolymer: made by Nippon Polyurethane) 93.55 g Nipporan 4038 (low molecular weight polyol: made by Nippon Polyurethane) 5.95 g Neostan U-100 (tin catalyst: made by Nitto Kasei) 0 .00
2 g

【0022】この半導電性部材Cを、実施例1と同様の
条件で大気圧プラズマ処理し、表面にフッ素化合物を結
合した。この処理をして得られた半導電性部材C−Fの
動摩擦係数μは、0.74であった。この半導電性部材
C−Fを、現像剤量規制ブレードとして、図1に示すよ
うな電子写真装置に組み込んでプリンターに装着し、常
温常湿条件(22℃、50%RH)にて連続印刷試験を
行ったところ、5000枚まで良好な画像が得られた。
また連続印刷試験終了後に半導電性部材C−F(現像剤
量規制ブレ−ド)を取り外し、表面を1000倍の顕微
鏡にて観察した結果、トナー固着は見られなかった。
This semiconductive member C was subjected to atmospheric pressure plasma treatment under the same conditions as in Example 1 to bond a fluorine compound on the surface. The dynamic friction coefficient μ of the semiconductive member C-F obtained by this treatment was 0.74. This semi-conductive member C-F was incorporated into an electrophotographic apparatus as shown in FIG. 1 as a developer amount control blade and mounted in a printer, and continuously printed under normal temperature and normal humidity conditions (22 ° C., 50% RH). When the test was conducted, good images were obtained up to 5000 sheets.
Further, as a result of removing the semi-conductive member C-F (developer amount controlling blade) after the completion of the continuous printing test and observing the surface with a microscope of 1000 times, no toner adhesion was observed.

【0023】実施例4 実施例1と同様に作成した半導電性弾性体上に、下記の
配合4の塗料をディッピング法により塗布することによ
り、厚さ5.0μmの導電性塗膜を形成したローラ状の
半導電性部材Dを形成した。この半導電性部材Dの動摩
擦係数μは、1.60であった。 (配合4) EAU65B(アクリルウレタン樹脂:亜細亜工業製)
50g デンカブラック(カーボンブラック:電気化学工業製)
2g 2−ブタノン(溶剤)150g
Example 4 A semi-conductive elastic body prepared in the same manner as in Example 1 was coated with a paint of the following formulation 4 by a dipping method to form a conductive coating film having a thickness of 5.0 μm. A roller-shaped semiconductive member D was formed. The dynamic friction coefficient μ of this semiconductive member D was 1.60. (Compound 4) EAU65B (acrylic urethane resin: manufactured by Asia Industrial Co., Ltd.)
50g Denka Black (Carbon Black: manufactured by Denki Kagaku Kogyo)
2g 2-butanone (solvent) 150g

【0024】この半導電性部材Dを、実施例1と同様に
表1に示した条件で大気圧プラズマ処理し、表面にフッ
素化合物を結合した。この処理をして得られた半導電性
部材D−Fの動摩擦係数μは、0.88であった。この
半導電性部材D−Fを、帯電部材として、図1に示すよ
うな電子写真装置に組み込んでプリンターに装着し、常
温常湿条件(22℃、50%RH)にて連続印刷試験を
行ったところ、5000枚まで良好な画像が得られた。
また連続印刷試験終了後に半導電性部材D−Fを取り外
し、表面を1000倍の顕微鏡にて観察した結果、トナ
ー固着は見られなかった。
This semiconductive member D was subjected to atmospheric pressure plasma treatment under the conditions shown in Table 1 in the same manner as in Example 1 to bond a fluorine compound on the surface. The dynamic friction coefficient μ of the semiconductive member DF obtained by this treatment was 0.88. The semi-conductive member DF as a charging member was incorporated into an electrophotographic apparatus as shown in FIG. 1 and mounted in a printer, and a continuous print test was conducted under normal temperature and normal humidity conditions (22 ° C., 50% RH). As a result, good images were obtained up to 5000 sheets.
Further, as a result of removing the semi-conductive member DF after the continuous printing test and observing the surface with a microscope of 1000 times, toner adhesion was not observed.

【0025】比較例1 実施例1における半導電性部材Aを、大気圧プラズマ処
理を行わないで、現像剤担持体として、図1に示すよう
な電子写真装置に組み込んでプリンターに装着し、常温
常湿条件(22℃、50%RH)にて連続印刷試験を行
ったところ、3000枚で画像上に斑点状の不良が見ら
れ、表面を1000倍の顕微鏡にて観察した結果、トナ
ー固着が見られた。
Comparative Example 1 The semiconductive member A in Example 1 was mounted as a developer carrying member in an electrophotographic apparatus as shown in FIG. When a continuous printing test was performed under normal humidity conditions (22 ° C., 50% RH), spot-like defects were observed on the image on 3,000 sheets, and the surface was observed with a microscope of 1000 times, as a result, toner adhesion was found. I was seen.

【0026】比較例2 実施例2における半導電性部材Bを、大気圧プラズマ処
理を行わないで、転写部材として、図1に示すような電
子写真装置に組み込んでプリンターに装着し、常温常湿
条件(22℃、50%RH)にて連続印刷試験を行った
ところ、6000枚で画像上に斑点状の不良が見られ、
表面を1000倍の顕微鏡にて観察した結果、トナー固
着が見られた。
COMPARATIVE EXAMPLE 2 The semiconductive member B in Example 2 was incorporated into an electrophotographic apparatus as shown in FIG. 1 as a transfer member without being subjected to atmospheric pressure plasma treatment, and was mounted in a printer and kept at normal temperature and normal humidity. When a continuous printing test was performed under the conditions (22 ° C., 50% RH), spot-like defects were observed on the image on 6000 sheets,
As a result of observing the surface with a microscope of 1000 times, toner adhesion was found.

【0027】比較例3 実施例3における半導電性部材Cを、大気圧プラズマ処
理を行わないで、現像剤量規制ブレードとして、図1に
示すような電子写真装置に組み込んでプリンターに装着
し、常温常湿条件(22℃、50%RH)にて連続印刷
試験を行ったところ、3000枚で画像上に筋状の不良
が見られ、表面を1000倍の顕微鏡にて観察した結
果、トナー固着が見られた。
Comparative Example 3 The semiconductive member C in Example 3 was incorporated into an electrophotographic apparatus as shown in FIG. 1 as a developer amount control blade without performing atmospheric pressure plasma treatment, and mounted in a printer. When a continuous printing test was performed under normal temperature and normal humidity conditions (22 ° C, 50% RH), streaky defects were observed on the image on 3,000 sheets, and the surface was observed with a microscope of 1000 times. It was observed.

【0028】比較例4 実施例4における半導電性部材Dを、大気圧プラズマ処
理を行わないで、帯電部材として、図1に示すような電
子写真装置に組み込んでプリンターに装着し、常温常湿
条件(22℃、50%RH)にて連続印刷試験を行った
ところ、3000枚で画像上に斑点状の不良が見られ、
表面を1000倍の顕微鏡にて観察した結果、トナー固
着が見られた。
COMPARATIVE EXAMPLE 4 The semiconductive member D in Example 4 was not subjected to atmospheric pressure plasma treatment, but was incorporated into an electrophotographic apparatus as shown in FIG. When a continuous printing test was performed under the conditions (22 ° C., 50% RH), spot-like defects were observed on the image after 3000 sheets,
As a result of observing the surface with a microscope of 1000 times, toner adhesion was found.

【0029】実施例5 下記の配合5を二軸混練機によって溶融混練し、得られ
た混練物を押出し成形することにより、内径24.5c
m、厚さ100μm、幅25cmの寸法を有する半導電
性エンドレスベルトを得た。この半導電性エンドレスベ
ルトEの動摩擦係数μは、1.20であった。 (配合5) セビアンV510(アクリロニトリル−ブタジエン−ス
チレン樹脂:ダイセルポリマー製) 1000g デンカブラック(カーボンブラック:電気化学工業製)
300g この半導電性エンドレスベルトEを、実施例1と同様の
条件で大気圧プラズマ処理し、表面にフッ素化合物を結
合した。この処理をして得られた半導電性エンドレスベ
ルトE−Fの動摩擦係数μは、0.86であった。この
半導電性エンドレスベルトE−Fを、中間転写ベルトと
して、プリンターに装着し、常温常湿条件(22℃、5
0%RH)にて連続印刷試験を行ったところ、5000
枚まで良好な画像が得られた。また連続印刷試験終了後
に半導電性エンドレスベルトE−Fを取り外し、表面を
1000倍の顕微鏡にて観察した結果、トナー固着は見
られなかった。
Example 5 The following compound 5 was melt-kneaded by a twin-screw kneader and the resulting kneaded product was extruded to give an inner diameter of 24.5c.
A semiconductive endless belt having dimensions of m, thickness of 100 μm and width of 25 cm was obtained. The dynamic friction coefficient μ of this semiconductive endless belt E was 1.20. (Compound 5) Sebian V510 (acrylonitrile-butadiene-styrene resin: manufactured by Daicel Polymer) 1000 g Denka black (carbon black: manufactured by Denki Kagaku Kogyo)
300 g This semiconductive endless belt E was subjected to atmospheric pressure plasma treatment under the same conditions as in Example 1 to bond a fluorine compound on the surface. The dynamic friction coefficient μ of the semi-conductive endless belt EF obtained by this treatment was 0.86. This semi-conductive endless belt EF was mounted on a printer as an intermediate transfer belt, and was subjected to normal temperature and normal humidity conditions (22 ° C., 5
When a continuous print test was performed at 0% RH, 5000
Good images were obtained up to the number of sheets. After the end of the continuous printing test, the semi-conductive endless belt EF was removed and the surface was observed with a microscope of 1000 times. As a result, toner adhesion was not observed.

【0030】比校例5 実施例5における半導電性エンドレスベルトEを、大気
圧プラズマ処理を行わないで、中間転写ベルトとして、
プリンターに装着し、常温常湿条件 (22℃、50%R
H)にて連続印刷試験を行ったところ、3000枚で画
像上に斑点状の不良が見られ、表面を1000倍の顕微
鏡にて観察した結果、トナー固着が見られた。
Comparative Example 5 The semiconductive endless belt E in Example 5 was used as an intermediate transfer belt without performing atmospheric pressure plasma treatment.
Mounted on a printer and kept at room temperature and humidity (22 ° C, 50% R
When a continuous printing test was conducted under H), spotted defects were observed on the image on 3000 sheets, and toner adhesion was observed as a result of observing the surface with a microscope of 1000 times.

【発明の効果】本発明の弾性体は、複写機、ファクシミ
リ、プリンター等における電子写真プロセスに用いた場
合、トナー固着が発生せず、長期間に渡って安定した画
像を供給し得る弾性体を提供出来る。
The elastic body of the present invention is an elastic body capable of supplying a stable image for a long period of time without toner sticking when used in an electrophotographic process in a copying machine, a facsimile, a printer or the like. Can be provided.

【図面の簡単な説明】[Brief description of drawings]

【図1】 画像形成装置の概略図を示す。FIG. 1 shows a schematic view of an image forming apparatus.

【図2】 ローラ状部材の断面図を示す。FIG. 2 shows a cross-sectional view of a roller-shaped member.

【図3】 現像剤量規制部材の断面図を示す。FIG. 3 is a cross-sectional view of a developer amount regulating member.

【図4】 大気圧プラズマ処理装置の概略図を示す。FIG. 4 shows a schematic view of an atmospheric pressure plasma processing apparatus.

【符号の説明】[Explanation of symbols]

1:帯電部材 2:画像形成部材 3:現像剤供給体 4:現像剤担持体 5:現像剤 6:現像剤量規制ブレード 7:転写部材 8:紙面 9:シャフト 10:弾性層 11:保護層 12a,12b:支持部材 13a,13b:弾性体 14:処理室 15:ガス供給管 16a、16b:電極 17:電源 18:被処理物 19:ガス排出管 1: charging member 2: Image forming member 3: Developer supply body 4: developer carrier 5: developer 6: Developer amount control blade 7: Transfer member 8: Space 9: Shaft 10: Elastic layer 11: Protective layer 12a, 12b: support members 13a, 13b: elastic body 14: Processing room 15: Gas supply pipe 16a, 16b: electrodes 17: Power supply 18: Object to be processed 19: Gas exhaust pipe

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) G03G 15/08 501 G03G 15/08 501D 504 504B 15/16 15/16 // C08L 23:16 C08L 23:16 75:04 75:04 83:04 83:04 Fターム(参考) 2H071 BA42 BA43 DA06 DA08 DA09 2H077 AC04 AD06 AD13 FA12 FA16 FA22 FA27 GA03 2H200 FA02 FA13 HA02 HB12 HB22 HB45 HB46 HB47 JA02 JA25 JA26 JA27 JC03 JC13 JC15 JC16 JC17 LC06 MA03 MA14 MA17 MA20 MB04 MC05 4F073 AA30 AA32 BA09 BA28 BA33 BB08 CA01 CA02 DA05 EA04 FA06 ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) G03G 15/08 501 501 G03G 15/08 501D 504 504B 15/16 15/16 // C08L 23:16 C08L 23: 16 75:04 75:04 83:04 83:04 F-term (reference) 2H071 BA42 BA43 DA06 DA08 DA09 2H077 AC04 AD06 AD13 FA12 FA16 FA22 FA27 GA03 2H200 FA02 FA13 HA02 HB12 HB22 HB45 HB46 HB47 JA02 JA25 JA26 JA27 JC03 JC13 JC15 JC JC17 LC06 MA03 MA14 MA17 MA20 MB04 MC05 4F073 AA30 AA32 BA09 BA28 BA33 BB08 CA01 CA02 DA05 EA04 FA06

Claims (10)

【特許請求の範囲】[Claims] 【請求項1】 大気圧プラズマ処理によって、フッ素化
合物を表面に化学的に結合させた弾性体を具備すること
を特徴とする弾性部材。
1. An elastic member comprising an elastic body in which a fluorine compound is chemically bonded to the surface by atmospheric pressure plasma treatment.
【請求項2】 上記弾性体が、ウレタン、シリコーンゴ
ム及びエチレン・プロピレンゴムのいずれか1種又はこ
れらを2種以上混合したもので構成されることを特徴と
する請求項1に記載の弾性部材。
2. The elastic member according to claim 1, wherein the elastic body is composed of any one of urethane, silicone rubber, and ethylene / propylene rubber, or a mixture of two or more thereof. .
【請求項3】 大気圧プラズマ処理が、弾性体を処理室
内に配置し、フッ素化合物ガス又はフッ素化合物ガスと
希釈ガスを処理室内に導入して処理室内に大気圧グロー
プラズマを発生させる方法であることを特徴とする請求
項1又は2に記載の弾性部材。
3. The atmospheric pressure plasma treatment is a method in which an elastic body is arranged in a treatment chamber and a fluorine compound gas or a fluorine compound gas and a diluent gas are introduced into the treatment chamber to generate atmospheric pressure glow plasma. The elastic member according to claim 1 or 2, characterized in that.
【請求項4】 フッ素化合物がヘキサフルオロプロピレ
ン又はオクタフルオロシクロブタンであることを特徴と
する請求項3に記載の弾性部材。
4. The elastic member according to claim 3, wherein the fluorine compound is hexafluoropropylene or octafluorocyclobutane.
【請求項5】 上記弾性部材が現像剤担持体である請求
項1〜4の何れかに記載の弾性部材。
5. The elastic member according to claim 1, wherein the elastic member is a developer carrying member.
【請求項6】 上記弾性部材が現像剤量規制ブレードで
ある請求項1〜4の何れかに記載の弾性部材。
6. The elastic member according to claim 1, wherein the elastic member is a developer amount regulating blade.
【請求項7】 上記弾性部材が転写部材である請求項1
〜4の何れかに記載の弾性部材。
7. The elastic member is a transfer member.
The elastic member according to any one of to 4.
【請求項8】 上記弾性部材が帯電部材である請求項1
〜4の何れかに記載の弾性部材。
8. The elastic member is a charging member.
The elastic member according to any one of to 4.
【請求項9】 上記弾性部材が中間転写部材である請求
項1〜4の何れかに記載の弾性部材。
9. The elastic member according to claim 1, wherein the elastic member is an intermediate transfer member.
【請求項10】 上記請求項1〜9のいずれかに記載の
弾性部材を具備した画像形成装置。
10. An image forming apparatus comprising the elastic member according to claim 1.
JP2001365713A 2001-11-30 2001-11-30 Elastic member and image formation apparatus Pending JP2003165857A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001365713A JP2003165857A (en) 2001-11-30 2001-11-30 Elastic member and image formation apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001365713A JP2003165857A (en) 2001-11-30 2001-11-30 Elastic member and image formation apparatus

Publications (1)

Publication Number Publication Date
JP2003165857A true JP2003165857A (en) 2003-06-10

Family

ID=19175704

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001365713A Pending JP2003165857A (en) 2001-11-30 2001-11-30 Elastic member and image formation apparatus

Country Status (1)

Country Link
JP (1) JP2003165857A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006129543A1 (en) * 2005-06-01 2006-12-07 Konica Minolta Business Technologies, Inc. Intermediate transfer body, device and method for producing intermediate transfer body, and image forming apparatus
JP2009002995A (en) * 2007-06-19 2009-01-08 Konica Minolta Business Technologies Inc Electrophotographic charging brush and image forming apparatus
US8163456B2 (en) 2008-04-11 2012-04-24 Konica Minolta Business Technologies, Inc. Image forming method and image forming apparatus
US8295747B2 (en) 2007-05-25 2012-10-23 Konica Minolta Business Technologies, Inc. Intermediate transfer member for use in electrophotographic image forming apparatus
JP2015212763A (en) * 2014-05-02 2015-11-26 住友ゴム工業株式会社 Semiconductive roller
CN108987573A (en) * 2017-06-05 2018-12-11 Tcl集团股份有限公司 The transfer method of quantum dot film

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006129543A1 (en) * 2005-06-01 2006-12-07 Konica Minolta Business Technologies, Inc. Intermediate transfer body, device and method for producing intermediate transfer body, and image forming apparatus
US8236396B2 (en) 2005-06-01 2012-08-07 Konica Minolta Business Technologies, Inc. Intermediate transfer member, manufacturing apparatus of intermediate transfer member, manufacturing method of intermediate transfer member and image forming apparatus
US8295747B2 (en) 2007-05-25 2012-10-23 Konica Minolta Business Technologies, Inc. Intermediate transfer member for use in electrophotographic image forming apparatus
JP2009002995A (en) * 2007-06-19 2009-01-08 Konica Minolta Business Technologies Inc Electrophotographic charging brush and image forming apparatus
US8163456B2 (en) 2008-04-11 2012-04-24 Konica Minolta Business Technologies, Inc. Image forming method and image forming apparatus
JP2015212763A (en) * 2014-05-02 2015-11-26 住友ゴム工業株式会社 Semiconductive roller
CN108987573A (en) * 2017-06-05 2018-12-11 Tcl集团股份有限公司 The transfer method of quantum dot film

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