JP2003113363A - Composition for decomposing carbonyl compound and method for decomposition of carbonyl compound - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a composition for the decomposition of a carbonyl compound capable of quickly decomposing toxic carbonyl compounds such as toxic formaldehyde in high decomposition ratio with a simple procedure and provide a method for the decomposition of the carbonyl compounds. SOLUTION: The composition for the decomposition of a carbonyl compound is composed of a compound of formula [I] (the definitions of R1 to R6 and (m) are described in the specification) for the decomposition of carbonyl compound and a sugar. The composition decomposes harmful aldehyde compounds and ketone compounds by reacting with the compounds.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a composition for decomposing harmful substances, particularly carbonyl compounds such as aldehyde compounds and ketone compounds, and a method for decomposing carbonyl compounds. More particularly, the present invention relates to a decomposition treatment of a harmful substance, particularly a carbonyl compound such as an aldehyde compound and a ketone compound, which uses a natural compound that is friendly to the environment and the human body, and an analysis method for confirming the decomposition.

[0002]

2. Description of the Related Art Decomposition and removal of carbonyl compounds such as aldehyde compounds and ketone compounds are known in synthetic organic chemistry by many methods such as conversion into carboxylic acid and ester by oxidation, or conversion into alcohol. Has been. However, at present, little is known about an effective method for decomposing and removing carbonyl compounds such as harmful aldehyde compounds and ketone compounds which are causative substances of sick house syndrome, which has been a problem in recent years. Some attempts have been made to solve the sick house syndrome by such carbonyl compounds such as harmful aldehyde compounds and ketone compounds. However, most of them are removal by decomposition or adsorption of formalin, but the removal rate is at most about 50%,
It requires a long time of 24-72 hours. Further, in the report that the removal rate is improved, it takes more than 140 hours (JP-A-10-251565, JP-A-10-121740, JP-A-10-104740).
-152964, JP-A-10-119495). Therefore, it is required to develop a method for decomposing or adsorbing harmful aldehyde compounds and ketone compounds including formalin in a short time and with a high removal rate.

[0003]

Therefore, the inventor of the present invention
We have studied earnestly to find compounds that can decompose carbonyl compounds such as formalin and other harmful aldehyde compounds and ketone compounds in a short period of time and with a high removal rate as naturally occurring harmless compounds for humans and animals. . As a result, it was surprisingly found that many naturally occurring amino acids, alcohol compounds, polyalcohol compounds and the like decompose harmful aldehydes such as formalin and harmful ketones such as acetone with a high removal rate. did. Furthermore, the present invention has been completed by finding out that amine compounds and polyamine compounds, amino alcohol compounds and sugars having similar chemical structures have similar effects.

[0004]

SUMMARY OF THE INVENTION Therefore, the present invention provides a composition for decomposing carbonyl compounds, which can decompose carbonyl compounds such as formalin and other harmful aldehyde compounds and ketone compounds in a short time and with a high removal rate. The main purpose is to provide goods. Another main object of the present invention is to provide a carbonyl compound decomposing method capable of decomposing harmful aldehyde compounds such as formalin and carbonyl compounds such as ketone compounds in a short time and at a high removal rate. Also,
Another object of the present invention is to suppress the generation of harmful carbonyl compounds by decomposing harmful aldehyde compounds such as formalin and carbonyl compounds such as ketone compounds, and particularly to prevent the occurrence of house-sick syndrome. To aim. Another object of the present invention is to provide a carbonyl compound decomposition analysis method for confirming carbonyl compound decomposition.

In order to achieve the above object, the present invention provides
Provided is a composition for decomposing a carbonyl compound, which can decompose a harmful aldehyde compound such as formalin and a carbonyl compound such as a ketone compound in a short time with a high removal rate. That is, the composition for decomposing a carbonyl compound according to the present invention comprises a compound for decomposing a carbonyl compound represented by the following general formula [I] and / or a saccharide, and the composition for decomposing a carbonyl compound is
The carbonyl compound can be decomposed by applying it to the carbonyl compound represented by the following general formula [II] contained in the object to be treated. Further, as a preferred embodiment according to the present invention, the carbonyl compound decomposing compound according to the present invention represented by the following general formula [I] is:
An amino acid represented by the following general formula [III], a general formula [I
Examples thereof include amino alcohol compounds represented by V], alcohol compounds or polyalcohol compounds represented by general formula [V], or amine compounds or polyamine compounds represented by general formula [VI]. These compounds are
It is possible to decompose harmful aldehyde compounds such as formalin and carbonyl compounds such as ketone compounds in a short time and with a high removal rate.

Furthermore, the carbonyl compound decomposing compound according to the present invention represented by the following general formula [I] may contain the following saccharides. Examples of such saccharides include D-
Glucose, galactose, xylose, monosaccharides such as D-fructose, disaccharides such as sucrose, maltose and lactose, trisaccharides such as raffinose, tetrasaccharides such as statioose, dextrin, cyclodextrin, dextran, amylose, soluble starch, cellulose, Examples thereof include polysaccharides such as agarose, alginic acid, hyaluronic acid and pectic acid, and sugar-related compounds such as L-ascorbic acid. By using such a saccharide together with the carbonyl compound decomposing compound, a carbonyl compound represented by the following general formula [II] is obtained:
It can be decomposed in a short time and with a high removal rate.

In another embodiment of the present invention, a carbonyl compound decomposing compound of the present invention represented by the following general formula [I] and / or a carbonyl compound decomposing composition containing a saccharide as a main component is used. Provided is a method for decomposing a carbonyl compound represented by the following general formula [II], which can decompose a carbonyl compound in a short period of time with a high removal rate. As a preferred embodiment according to the present invention, the carbonyl compound decomposing compound according to the present invention represented by the following general formula [I] is represented by the following general formula [III] amino acids and general formula [IV]. By using an amino alcohol compound, an alcohol compound or a polyalcohol compound represented by the general formula [V], or an amine compound or a polyamine compound represented by the general formula [VI], harmful substances such as formalin can be obtained. Provided is a carbonyl compound decomposing method capable of decomposing a carbonyl compound such as an aldehyde compound and a ketone compound in a short time and with a high removal rate.

Further, according to the carbonyl compound decomposing method of the present invention, the carbonyl compound decomposing compound of the present invention represented by the following general formula [I], that is, amino acids of the following general formula [III] , An amino alcohol compound represented by the general formula [IV], an alcohol compound or a polyalcohol compound represented by the general formula [V], or an amine compound or a polyamine compound represented by the general formula [VI] Can be applied to the object to be treated in liquid or gas form by coating, spraying, or adsorbing to a fibrous base material. Therefore, the method according to the present invention is capable of decomposing harmful aldehyde compounds such as formalin and carbonyl compounds such as ketone compounds in a short period of time with a high removal rate, and maintaining such effects.

In another embodiment of the present invention, a carbonyl compound decomposing compound represented by the following general formula [I] and / or a carbonyl compound decomposing composition containing a saccharide as a main component is used. By providing a method for decomposing a carbonyl compound represented by the following general formula [II], it is possible to easily analyze the decomposition of the carbonyl compound with a detector tube. This analysis method makes it possible to easily and quickly confirm the decomposition of the carbonyl compound represented by the following general formula [II].

[0010]

BEST MODE FOR CARRYING OUT THE INVENTION The composition for decomposing a carbonyl compound used in the present invention contains a compound decomposing a carbonyl compound and / or transparent as a main component. The carbonyl compound decomposing compound has the general formula [I]:

[0011]

[Chemical 13]

[In the formula, R1 is a hydrogen atom, an aldehyde group, a hydroxyacetyl group, an unsubstituted or substituted C _1-
C ₈ alkyl group, an unsubstituted or substituted _C 3 -C ₇ cycloalkyl group, unsubstituted or substituted _C 7 _{-C 11} aralkyl group, an unsubstituted or substituted _C 6 _{-C 10} ants - group, unsubstituted or substituted _{C 1} means -C ₅ carboxylic acid group or a heterocyclic group, R2 is a hydrogen atom, an unsubstituted or substituted _C 1 -C ₈ alkyl group, an unsubstituted or substituted _C 3 -C ₇
It means a cycloalkyl group, an unsubstituted or substituted C ₆ -C ₁₀ aryl group or an unsubstituted or substituted C ₇ -C ₁₁ aralkyl group, and R 3 is a hydroxy group, an amino group or a —NHR 9 group (in the formula, R 9 Represents a hydrogen atom, a single bond or a C ₁ -C ₃ alkylene group, and may combine with R 1a to form a cyclic structure), and R 4 represents a hydrogen atom, an aldehyde group, unsubstituted or substituted. C ₁ -C ₈ alkyl group, an unsubstituted or substituted _C 3 -C ₇ cycloalkyl group, unsubstituted or substituted _C 6 _{-C 10} ants - group, unsubstituted or substituted _C 7 _{-C 11} aralkyl group, a carboxyl group, means a hydroxyacetyl group or keto group, R5 is a hydrogen atom, an unsubstituted or substituted C ₁ -
C ₈ alkyl group, an unsubstituted or substituted _C 3 -C ₇ cycloalkyl group, unsubstituted or substituted _C 6 _{-C 10} ants - means Le group or an unsubstituted or substituted _C 7 _{-C 11} aralkyl group, R6 is Means a hydroxy group or an amino group, and m means 0 or an integer from 1 to 20}
It is represented by.

In the present specification, n is normal, i is iso, sec is secondary or secondary, and t is
Alternatively, tert represents tertiary or tertiary, Me represents methyl, Et represents ethyl, Bu represents butyl, and Ph represents phenyl.

Among the substituents R1 in the above general formula [I], the unsubstituted or substituted C ₁ -C ₈ alkyl group is a monovalent straight chain having 1 to 8 carbon atoms which may have a substituent. It means a chain or branched saturated aliphatic hydrocarbon group,
For example, methyl, ethyl, n-propyl, i-propyl,
n-butyl, i-butyl, sec-butyl, tert-butyl, n
-Pentyl, n-hexyl, n-heptyl, n-octyl and the like. Here, examples of the substituent include hydroxy, amino, carbamoyl, formyl, mercapto, guanidino, alkyl (eg, methyl, ethyl, propyl or isopropyl) thio and the like. Further, one or a plurality of these substituents may be present, and when a plurality of these substituents are present, the types thereof may be the same or different. That is, examples of the substituted C ₁ -C ₈ alkyl group include a hydroxyalkyl group, an aminoalkyl group, a carbamoylalkyl group, a formylalkyl group, a mercaptoalkyl group, a guanidinoalkyl group, and an alkylthioalkyl group. More specifically, examples of the hydroxyalkyl group include hydroxymethyl, 1-hydroxyethyl, 2-hydroxyethyl, 3-hydroxypropyl and 2
-Hydroxy-2-methylpropyl and the like can be mentioned.
Examples of aminoalkyl groups include aminomethyl, 2
-Aminoethyl, 3-aminopropyl, 4-aminobutyl, 4-amino-3-hydroxybutyl and the like can be mentioned. Further, as the carbamoylalkyl group, for example,
Examples thereof include carbamoylmethyl, carbamoylethyl, carbamoylaminomethyl, carbamoylaminopropyl, 2-carbamoylpropenyl, N-ethylcarbamoylethyl, N- (1-cyanoethyl) carbamoylethylki. Examples of the formylalkyl group include formylmethyl, formylethyl and the like. Further, examples of the mercaptoalkyl group include mercaptomethyl, 1-mercaptoethyl, 2-mercaptoethyl and the like. Further, examples of the formylalkyl group include formylmethyl, formylethyl, formylpropyl and the like. Further, examples of the guanidinoalkyl group include guanidinomethyl, 2-guanidinoethyl, 3-guanidinopropyl, 4-guanidinobutyl, 2-guanidinooxyethyl, 3-guanidino-2-hydroxypropyl, and 4-guanidino-2-hydroxy. Butyl and the like can be mentioned. Furthermore, examples of the alkylthioalkyl group include methylthiomethyl, methylthioethyl, ethylthiomethyl, ethylthioethyl, methylthiopropyl, methylthioisopropyl, propylthiomethyl, isopropylthiomethyl and the like.

[0015] Among the substituents R1 in the formula [I], unsubstituted or substituted C ₃ -C ₇ cycloalkyl groups can have 3 to be carbon atoms which may have a substituent group 7
A monovalent cyclic saturated aliphatic hydrocarbon group, for example,
Examples thereof include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl and cycloheptyl groups. Here, examples of the substituent include hydroxy, amino, and lower alkyl groups such as methyl and ethyl. Further, one or a plurality of these substituents may be present, and when a plurality of these substituents are present, the types thereof may be the same or different.

Further, in the substituent R1 in the general formula [I],
Of which, unsubstituted or substituted C₆-C₁₀The aryl group is
6 to 10 carbon atoms which may have a substituent
Means a monovalent aromatic hydrocarbon group. Also, as a substituent
Examples include hydroxy, chloro, bromo and iodo.
Such as a halogen atom, etc., and these substituents
May exist one or more, and
If there are several, even if they are of the same type, they are different
May be. Such unsubstituted or substituted C₆ -C₁₀
Examples of the aryl group include phenyl, o-tolyl, m
-Tolyl, p-tolyl, 2,3-dimethylphenyl, 2,4-
Dimethylphenyl, 2,5-dimethylphenyl, 2,6-dimeme
Tylphenyl, 3,4-dimethylphenyl, 3,5-dimethyl
Phenyl, 2,3,4-trimethylphenyl, 2,3,5-trimethyl
Tylphenyl, 2,3,6-trimethylphenyl, 3,4,5-to
Limethylphenyl, 3,4,6-trimethylphenyl, 2,4,6
-Trimethylphenyl, α-naphthyl, β-naphthyl,
3,5-dibromo-4-hydroxyphenyl, 3-hydroxy
Examples thereof include carbonyl phenyl.

Further, the substituent R in the above general formula [I] is
Among them, the unsubstituted or substituted C ₇ -C ₁₁ aralkyl group is an unsubstituted or substituted aryl group having 6 or 10 carbon atoms and a non-substituted or unsubstituted C ₇ -C ₁₁ aralkyl group having 1 to 5 carbon atoms. It means a monovalent linear or branched saturated aliphatic hydrocarbon group which is a substituted or substituted alkyl group. Examples of such an unsubstituted or substituted C ₇ -C ₁₁ aralkyl group include benzyl, o-methylbenzyl, m-methylbenzyl, p-methylbenzyl, phenethyl, o-methylphenethyl, m-methylphenethyl, p-methylphenethyl. , Phenylpropyl, o-methylphenylpropyl, m-methylphenylpropyl, p-methylphenylpropyl, phenylbutyl, α-naphthylmethyl, β-naphthylmethyl, p-hydroxybenzyl, 3,4-dihydroxybenzyl, 3,5 -Diodo-4-hydroxybenzyl, 3-hydroxycarbonylbenzyl, 4-hydroxy-3-hydroxycarbonylbenzyl and the like can be mentioned.

Among the substituents R1 represented by the above general formula [I], the unsubstituted or substituted C ₁ -C ₅ carboxylic acid group is, for example, a carboxyl group, an acetic acid group, a propionic acid group or a butyric acid group. , 2-methylpropionic acid group, methacrylic acid group, valeric acid group, ketocarboxylic acid group and the like. These carboxylic acid groups may have a suitable substituent.

Further, among the substituents R1 represented by the above general formula [I], examples of the unsubstituted or substituted heterocyclic group include 3-indolemethyl, 4-imidazolemethyl and N-methyl. -4-Imidazolmethyl, 4- (2-aminopyrimidine) methyl, 1-pyrazolmethyl group and the like can be mentioned. These carboxylic acid groups are halogen atoms,
It may have a suitable substituent such as a hydroxy group, an amino group and a lower alkyl group such as methyl.

Examples of the substituent R2 in the above general formula [I], a hydrogen atom, an unsubstituted or substituted _C 1 -C ₈ alkyl group, an unsubstituted or substituted _C 3 -C ₇ cycloalkyl group, unsubstituted or substituted _{C 6} -C ₁₀ ants - Le group or an unsubstituted or substituted _C 7 _{-C 1 1} aralkyl group. Each of these substituents has the same meaning as above.

The substituent R3 in the above general formula [I] is a hydrogen atom, a hydroxy group, an amino group or a group NH.
R9 is mentioned. Here, R9 represents a single bond, methylene, ethylene, means C ₁ -C ₃ alkylene group such as propylene, may be formed N-containing heterocyclic group bonded to R1. When R9 is combined with R1 to form a heterocyclic structure, the cyclic structure may be a 3-membered ring, a 4-membered ring, a 5-membered ring or a 6-membered ring. Examples of such a cyclic group include a pyrrolidine ring, a piperidine ring,
Examples thereof include an aziridine ring and an azetidine ring.

Further, the substituent R in the above general formula [I] is
4 is a hydrogen atom, an aldehyde group, an unsubstituted or substituted C
₁ -C ₈ alkyl group, an unsubstituted or substituted _C 3 -C ₇ cycloalkyl group, unsubstituted or substituted _C 6 _{-C 10} ants - group, unsubstituted or substituted _C 7 _{-C 11} aralkyl group, a carboxyl group, keto It means an acid group or a hydroxyacetyl group. Among the above substituents R4, unsubstituted or substituted _C 1 -C ₈ alkyl group, an unsubstituted or substituted _C 3 -C ₇ cycloalkyl group, unsubstituted or substituted _C 6 _{-C 10} ants - Le group and unsubstituted or substituted C ₇
The -C ₁₁ aralkyl group may have the same meaning as the above substituent R1.

Further, the substituent R in the above general formula [I] is
5 is a hydrogen atom, unsubstituted or substituted C₁-C₈
Alkyl group, unsubstituted or substituted C_Three-C₇Cycloal
Kill group, unsubstituted or substituted C₆-C₁₀Allyl
Or unsubstituted or substituted C₇ -C₁₁Means aralkyl group
Taste, these substituents R5 have the same meaning as the above substituent R1.
May have a taste.

The carbonyl compound decomposing compound represented by the above general formula [I] according to the present invention will be described more specifically. That is, the carbonyl compound-decomposing compound [I] is represented by the amino acids represented by the following general formula [III], the amino alcohol compound represented by the following general formula [IV], and the following general formula [V]. And an amine compound and a polyamine compound represented by the following general formula [VI].

One form of the carbonyl compound decomposing compound according to the present invention represented by the above general formula [I] is represented by the general formula [II
I]:

[0026]

[Chemical 14]

(In the formula, R 1a represents a hydrogen atom, an unsubstituted or substituted C ₁ -C ₈ alkyl group, an unsubstituted or substituted C ₃
-C ₇ cycloalkyl group, unsubstituted or substituted C ₆ -C
_{1 0} ant - group, means an unsubstituted or substituted _C 7 _{-C 11} aralkyl group or an unsubstituted or substituted _C 1 -C ₅ carboxylic acid group, R9a represents a hydrogen atom, a single bond or a _{C 1} -
Means C ₃ alkylene group, and a amino compound represented by the combined means may also be) to form a cyclic structure with R1a). Further, in these amino acids, when stereoisomers exist, such stereoisomers,
For example, L-form, D-form and dl-form are also included.

In the above general formula [III], represented by R1a
Unsubstituted or substituted C₁-C₈ The alkyl group is
Have the same meaning. That is, non-substituted C₁-C₈Alkyl
Examples of the group include, for example, methyl, ethyl, n-propyl
Ropil, i-propyl, n-butyl, i-butyl, sec-bu
Tyl, tert-butyl, n-pentyl, n-hexyl, n-
Examples include heptyl and n-octyl. Also replace
C₁-C₈Examples of the alkyl group include, for example, hydr
Roxymethyl, 1-hydroxyethyl, 2-hydroxyethyl
Chill, 3-hydroxypropyl, 2-hydroxy-2-me
Hydroxyalkyl group such as tylpropyl, aminomethyl
2-aminoethyl, 3-aminopropyl, 4-amino
Amino such as butyl and 4-amino-3-hydroxybutyl
Alkyl group, carbamoylmethyl, carbamoylethyl
Carbamoylal, such as carbamoylaminomethyl
Kill group, mercaptomethyl, 1-mercaptoethyl, 2-
Mercaptoalkyl groups such as mercaptoethyl, 2-g
Anidinoethyl, 3-guanidinopropyl, 4-guanidi
Nobutyl, 2-guanidinooxyethyl, 3-guanidino
2-hydroxypropyl, 4-guanidino-2-hydro
Guanidinoalkyl groups such as x-butyl, methylthiome
Chill, methylthioethyl, ethylthiomethyl, ethylthio
Oethyl, methylthiopropyl, methylthioisopropyl
R, propylthiomethyl, isopropylthiomethyl, etc.
And an alkylthioalkyl group of

In the above general formula [III], represented by R1a
Unsubstituted or substituted C_Three-C₇ A cycloalkyl group
It has the same meaning as above. That is, the non-substituted C_Three-C
₇Examples of the cycloalkyl group include cyclopropyl group.
L, cyclobutyl, cyclopentyl, cyclohexyl,
Cycloheptyl and the like, as the substituent,
For example, hydroxy, amino, eg methyl, ethyl
And lower alkyl groups such as Therefore,
Substitution C_Three-C₇Examples of cycloalkyl groups include, for example,
Droxycyclopropyl, hydroxycyclobutyl, hi
Droxycyclopentyl, aminocyclopropyl, ami
Nocyclobutyl, methylcyclopentyl, methylcyclo
Propyl, ethylcyclobutyl, ethylcyclopentyl
, Methylcyclohexyl, methylcycloheptyl, etc.
Is mentioned.

In the above general formula [III], the unsubstituted or substituted C ₆ -C ₁₀ aryl group represented by R 1a has the same meaning as described above. That is, the C ₆ -C ₁₀ ant-
Examples of the radical group include, for example, phenyl, o-tolyl, m-tolyl, p-tolyl, 2,3-dimethylphenyl,
2,4-dimethylphenyl, 2,5-dimethylphenyl, 2,6
-Dimethylphenyl, 3,4-dimethylphenyl, 3,5-dimethylphenyl, 2,3,4-trimethylphenyl, 2,3,5-
Trimethylphenyl, 2,3,6-trimethylphenyl, 3,
4,5-trimethylphenyl, 3,4,6-trimethylphenyl, 2,4,6-trimethylphenyl, α-naphthyl, β-
Naphthyl, 3,5-dibromo-4-hydroxyphenyl, 3
-Hydroxycarbonylphenyl and the like.

[0031] In the above general formula [III], unsubstituted or substituted _C 7 _{-C 1 1} aralkyl group represented by R1a has the same meaning as above. That is, examples of the C ₇ -C ₁₁ aralkyl group include benzyl, o-methylbenzyl, m-methylbenzyl, p-methylbenzyl, phenethyl, o-methylphenethyl, m-methylphenethyl, p.
-Methylphenethyl, phenylpropyl, o-methylphenylpropyl, m-methylphenylpropyl, p-methylphenylpropyl, phenylbutyl, α-naphthylmethyl, β-naphthylmethyl, p-hydroxybenzyl,
3,4-dihydroxybenzyl, 3,5-diode-4-hydroxybenzyl, 3-hydroxycarbonylbenzyl, 4
-Hydroxy-3-hydroxycarbonylbenzyl and the like can be mentioned.

In the above general formula [III], the unsubstituted or substituted C ₁ -C ₅ carboxylic acid group represented by R 1a has the same meaning as described above. That is, examples of the C ₁ -C ₅ carboxylic acid group include a carboxyl group, an acetic acid group, a propionic acid group, a butyric acid group, a 2-methylpropionic acid group, a methacrylic acid group, a valeric acid group, and a ketocarboxylic acid group. To be

Further, in the above general formula [III], R9a
Has the same meaning as the above substituent R9. That is, R9a
Means a single bond or a C ₁ -C ₃ alkylene group such as methylene, ethylene or propylene, which is bonded to R 1a to form a 3-membered, 4-membered, 5-membered or 6-membered N-containing heterocyclic group. May be formed. Examples of the N-containing heterocyclic group include a pyrrolidine ring, a piperidine ring, an aziridine ring, and an azetidine ring.

Examples of the amino acids represented by the above general formula [III] include glycine and alanine (L or D).
Or dl), α-aminobutyric acid (L or D or d
l), valine (L or D or dl), norvaline (L or D or dl), leucine (L or D)
Or dl), isoleucine (L or D or d
l), alloisoleucine (L or D or dl),
Norleucine (L or D or dl), 2- (methylenecyclopropyl) glycine (L or D or d
l), serine (L or D or dl), threonine (L or D or dl), alosreonine (L or D or dl), δ-hydroxynorvaline (L or D or dl), γ-hydroxyleucine (L) Or D or dl), aspartic acid (L or D
Or dl), glutamic acid (L or D or d
l), α-aminoadipic acid (L or D or d
l), (L or D or dl), γ-methylglutamic acid (L or D or dl), γ-methyleneglutamic acid (L or D or dl), α-aminopimelic acid (L or D or dl), asparagine (L)
Or D or dl), glutamine (L or D or dl), lysine (L or D or dl), δ-
Hydroxylysine (L or D or dl), citrulline (L or D or dl), arginine (L or D or dl), cysteine (L or D or dl), homocysteine (L or D or dl),
Methionine (L or D or dl), phenylglycine (L or D or dl), phenylalanine (L or D or dl), tyrosine (L or D)
Or dl), 3-hydroxytyrosine (L or D
Or dl), 3-carboxyphenylglycine (L or D or dl), 3-carboxyphenylalanine (L or D or dl), tryptophan (L or D or dl), histidine (L or D or dl), proline (L). Or D or dl), 4-
Hydroxyproline (L or D or dl), pipecolic acid (L or D or dl), 4-aminopipecolic acid (L or D or dl), azetidine-2
-Carboxylic acids (L or D or dl) and the like.

Another embodiment of the carbonyl compound decomposing compound of the present invention represented by the above general formula [I] is represented by the general formula [IV]:

[0036]

[Chemical 15]

(In the formula, R 1b is a hydrogen atom, an unsubstituted or substituted C ₁ -C ₈ alkyl group, an unsubstituted or substituted C ₃
-C ₇ cycloalkyl group, unsubstituted or substituted C ₆ -C
_{1 0} ant - group, means an unsubstituted or substituted _C 7 _{-C 11} aralkyl group or an unsubstituted or substituted _C 1 -C ₅ carboxylic acid group, R9b is hydrogen atom, a single bond or a _{C 1} -
And a le compound - means C ₃ alkylene group, an amino alcohol represented by the combined means may also be) to form a cyclic structure and R1b). Further, in these amino alcohol compounds, when stereoisomers are present, such stereoisomers, for example, R isomer, S isomer and d
The 1-form is also included.

Of the substituent R1b represented by the above general formula [IV]
Of which, unsubstituted or substituted C₁-C₈ Alkyl group, non-positioned
Substitution or substitution C_Three-C₇Cycloalkyl group, also unsubstituted
Or replace C₆-C₁₀Aryl group, unsubstituted or substituted
Conversion C₇-C₁₁Aralkyl groups and unsubstituted or substituted
C₁-C₅The carboxylic acid group is the same as the substituent R1a
It may have meaning. That is, the substituent R1b is
Are, for example, hydrogen atom, methyl, ethyl, n-propy
Ru, i-propyl, n-butyl, i-butyl, sec-butyl
, Tert-butyl, n-pentyl, n-hexyl, n-hexyl
Butyl, n-octyl, hydroxymethyl, 1-hydroxy
Ciethyl, 2-hydroxyethyl, 3-hydroxypropyi
And hydroxy such as 2-hydroxy-2-methylpropyl
Cyalkyl, carbamoylmethyl, carbamoylethyl
L, carbamoylaminomethyl, carbamoylaminop
Ropyr, 2-carbamoylpropenyl, N-ethylcarba
Moylethyl, N- (1-cyanoethyl) carbamoylethyl
Such as carbamoylalkyl, aminomethyl, 2-a
Minoethyl, 3-aminopropyl, 4-aminobutyl, 4
-Amino-3-hydroxybutyl and other aminoalkyls
Le, guanidinomethyl, 2-guanidinoethyl, 3-guar
Nidinopropyl, 4-guanidinobutyl, 2-guanidino
Oxyethyl, 3-guanidino-2-hydroxypropyi
, 4-guanidino-2-hydroxybutyl, etc.
Dinoalkyl, mercaptomethyl, 1-mercaptoethyl
Mercaptoalkyl such as 2-mercaptoethyl,
Methylthiomethyl, methylthioethyl, ethylthiomethy
L, ethylthioethyl, methylthiopropyl, methylthio
O-isopropyl, propylthiomethyl, isopropylthio
C such as lower alkylthioalkyl such as omethyl₁−
C₈Alkyl group, cyclopropyl, cyclobutyl, shik
C such as lopentyl, cyclohexyl and cycloheptyl
_Three-C₇Cycloalkyl group, phenyl, o-tolyl, m-
Tolyl, p-tolyl, 2,3-dimethylphenyl, 2,4-di
Methylphenyl, 2,5-dimethylphenyl, 2,6-dimethyl
Ruphenyl, 3,4-dimethylphenyl, 3,5-dimethylphenyl
Phenyl, 2,3,4-trimethylphenyl, 2,3,5-trimethyl
Ruphenyl, 2,3,6-trimethylphenyl, 3,4,5-tri
Methylphenyl, 3,4,6-trimethylphenyl, 2,4,6-
Trimethylphenyl, α-naphthyl, β-naphthyl, 3,
5-dibromo-4-hydroxyphenyl, 3-hydroxy
C such as carbonylphenyl group₆-C₁₀Aryl group,
Benzyl, o-methylbenzyl, m-methylbenzyl, p
-Methylbenzyl, phenethyl, o-methylphenethyl
L, m-methylphenethyl, p-methylphenethyl, fe
Nylpropyl, o-methylphenylpropyl, m-methyl
Phenylpropyl, p-methylphenylpropyl, fe
Nylbutyl, α-naphthylmethyl, β-naphthylmethy
P-hydroxybenzyl, 3,4-dihydroxyben
Zil, 3,5-diiodo-4-hydroxybenzyl, 3-hi
Droxycarbonylbenzyl, 4-hydroxy-3-hydr
C such as Roxycarbonylbenzyl₇-C₁₁Aralchi
Group, carboxyl, acetic acid group, propionic acid group, butyric acid
Group, 2-methylpropionic acid group, methacrylic acid group, Yoshikusa
C such as acid group₁-C₅Carboxylic acid group, 3-indoleme
Cyl, 4-imidazole methyl, N-methyl-4-imidazole
Zolemethyl, 4- (2-aminopyrimidine) methyl, 1-
Examples include heterocyclic groups such as pyrazolmethyl group
It

The substituent R9b is the same as the substituent R9a.
May have the same meaning as. That is, the substituent R
9b may form a hydrogen atom or an N-containing heterocyclic group consisting of a 3- to 6-membered ring integrally bonded to the substituent R1b. Examples of the N-containing heterocyclic group include aziridine ring, azetidine ring, pyrrolidine ring, piperidine ring and the like.

Examples of the amino alcohol compound represented by the above general formula [IV] include 2-aminoethanol,
2-Methylaminoethanol, 2-aminopropanol (R, S or dl), 2-aminobutanol (R, S
Or dl), valinol (R, S or dl), norvalinol (R, S or dl), leucinol (R,
S or dl), isoleucinol ((2S, 3S),
(2S, 3R), (2R, 3S), (2R, 3R) or dl), alloisoleucine ((2S, 3S),
(2S, 3R), (2R, 3S), (2R, 3R) or dl), norleucinol (R, S or dl), 2
-Amino-1,3-propanediol (R, S or d
l), 2-amino-1,3-butanediol ((2S,
3S), (2S, 3R), (2R, 3S), (2R, 3
R) or dl), (R, S or dl), 2-amino-1,4-butanediol (R, S or dl),
(R, S or dl), (R, S or dl), 2-amino-1,5-pentanediol (R, S or d
l), 2-amino-1,6-hexanediol (R, S
Or dl), 2,6-diamino-1-hexanol (R, S or dl), 2-amino-5-guadinino-
1-pentanol (R, S or dl), 2-amino-
3-mercapto-1-propanol (R, S or d
1), 2-amino-2-phenylethanol (R, S or dl), 2-amino-3-phenylpropanol (R, S or dl), 2-amino-3- (4-hydroxy) ) Phenyl-1-propanol (R, S or d
l), 2-amino-3-indole propanol (R,
S or dl), 2-amino-4-imidazole propanol (R, S or dl), prolinol (R, S or dl), piperidine-2-methanol (R, S or dl), etc. Is mentioned.

Another form of the carbonyl compound decomposing compound according to the present invention represented by the above general formula [I] is represented by the general formula [V]:

[0042]

[Chemical 16]

(In the formula, R1c is a hydrogen atom, an aldehyde
Group, unsubstituted or substituted C₁-C₈ Alkyl group, unsubstituted
Or substitution C_Three-C₇Cycloalkyl group, unsubstituted
Kuha substitution C₆-C₁₀Aryl group, unsubstituted or substituted
C₇-C₁₁Aralkyl group, carboxyl group, ketocar
R2a means a boric acid group or a hydroxyacetyl group.
Is a hydrogen atom, unsubstituted or substituted C₁-C₈Alkyl
Group, unsubstituted or substituted C_Three-C₇Cycloalkyl group,
Unsubstituted or substituted C₆-C₁₀ Aryl group or non-positioned
Substitution or substitution C₇-C₁₁R means an aralkyl group, R
4a is a hydrogen atom, an aldehyde group, an unsubstituted or substituted C
₁-C₈Alkyl group, unsubstituted or substituted C_Three-C₇Shi
Chloroalkyl group, unsubstituted or substituted C₆-C₁₀Ants
-R group, unsubstituted or substituted C₇-C₁₁Aralkyl
Groups, carboxyl groups, ketocarboxylic acid groups or hydroxy groups
A acetyl group, R5a is a hydrogen atom,
Kuha substitution C₁-C₈Alkyl group, unsubstituted or substituted C
_Three-C₇Cycloalkyl group, unsubstituted or substituted C₆−
C₁₀ Aryl group or unsubstituted or substituted C₇-C
₁₁Means an aralkyl group, and ma is 0 or 1 to 2
(Meaning an integer of up to 0)
And a polyalcohol compound. Well
In addition, these alcohol compounds and polyalcohols
If stereoisomers are present in the compound,
Isomers are also included.

More specifically, when ma is 0, the carbonyl compound-decomposing compound becomes an alcohol compound, while when ma means an integer of 1 to 20, the carbonyl compound-decomposing compound is decomposed. Compound is polyalco
It becomes a compound.

Of the substituent R1c represented by the above general formula [V]
Of which, unsubstituted or substituted C₁-C₈Alkyl group, non-positioned
Substitution or substitution C_Three-C₇Cycloalkyl group, also unsubstituted
Or replace C₆-C₁₀Aryl group and unsubstituted or
Is the substitution C₇-C₁₁The aralkyl group is a substituent R1a
Each may have the same meaning. That is, the substituent R1c
Are, for example, hydrogen atom, hydroxymethyl group,
Tocarboxylic acid, formylmethyl group, aldehyde group, hydr
Roxyacetyl group, carboxyl group, methyl, ethyl,
n-propyl, i-propyl, n-butyl, i-butyl, se
c-butyl, tert-butyl, n-pentyl, n-hexyl
C such as ru, n-heptyl, n-octyl group₁-C₈Al
Kill group, cyclopropyl, cyclobutyl, cyclopentyl
C such as le, cyclohexyl and cycloheptyl_Three-C₇
Cycloalkyl group, phenyl, o-tolyl, m-tolyl,
p-tolyl, 2,3-dimethylphenyl, 2,4-dimethylphenyl
Phenyl, 2,5-dimethylphenyl, 2,6-dimethylphenyl
L, 3,4-dimethylphenyl, 3,5-dimethylphenyl,
2,3,4-trimethylphenyl, 2,3,5-trimethylphenyl
2,3,6-trimethylphenyl, 3,4,5-trimethylphenyl
Phenyl, 3,4,6-trimethylphenyl, 2,4,6-trimethyl
C such as ruphenyl, α-naphthyl, β-naphthyl₆−
C₁₀Aryl group, benzyl, o-methylbenzyl, m-
Methylbenzyl, p-methylbenzyl, phenethyl, o-
Methylphenethyl, m-methylphenethyl, p-methylphen
Enetyl, phenylpropyl, o-methylphenylpro
Pill, m-methylphenylpropyl, p-methylphenyl
Propyl, phenylbutyl, α-naphthylmethyl, β-
C such as naphthylmethyl₇-C₁₁ Aralkyl groups, etc.
Can be mentioned.

Among the above substituents R2a, R4a and R5a, an unsubstituted or substituted C ₁ -C ₈ alkyl group, an unsubstituted or substituted C ₃ -C ₇ cycloalkyl group, an unsubstituted or substituted C ₆ -C ₁₀ The aryl group and the unsubstituted or substituted C ₇ -C ₁₁ aralkyl group are the substituents R2 and R4.
And R5 may have the same meaning. That is, the substituent R2a, among R4a and R5a, the unsubstituted or substituted _C 1 -C ₈ alkyl group, an unsubstituted or substituted _C 3 -C ₇ cycloalkyl group, unsubstituted or substituted _C 6 _{-C 10} ants - Group and unsubstituted or substituted C
Examples of the _7- C ₁₁ aralkyl group include methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, sec-butyl, tert-butyl, n-pentyl, n-hexyl, n-heptyl. , _C 1 -C _8, such as n- octyl
Alkyl groups, C _3-, such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl and cycloheptyl
C ₇ cycloalkyl group, phenyl, o- tolyl, m- tolyl, p- tolyl, 2,3-dimethylphenyl, 2,4-dimethylphenyl, 2,5-dimethylphenyl, 2,6-dimethylphenyl, 3, 4-dimethylphenyl, 3,5-dimethylphenyl, 2,3,4-trimethylphenyl, 2,3,5-trimethylphenyl, 2,3,6-trimethylphenyl, 3,4,5-trimethylphenyl, 3, C such as 4,6-trimethylphenyl, 2,4,6-trimethylphenyl, α-naphthyl and β-naphthyl
₆ -C ₁₀ ants - group, benzyl, o- methylbenzyl, m- methylbenzyl, p- methylbenzyl, phenethyl, o- methylphenethyl, m- methylphenethyl, p-
Examples thereof include C ₇ -C ₁₁ aralkyl groups such as methylphenethyl, phenylpropyl, o-methylphenylpropyl, m-methylphenylpropyl, p-methylphenylpropyl, phenylbutyl, α-naphthylmethyl and β-naphthylmethyl.

Examples of the alcohol compound and the polyalcohol compound represented by the above general formula [V] are, for example, methanol, ethanol, n-propanol, i-propanol and benzyl alcohol. Le, α-phenethyl alcohol
(R, S or dl), β-phenethyl alcohol,
Ethylene glycol, 1,2-propylene glycol,
Glycerin, erythritol, lipitol, arabite
(D, L or dl), mannitol (D, L or dl), sorbitol (D, L or dl), dulcitol, boremitole (D, L or dl), β-sedoheptite (D, L or dl), Perseitol (D, L or dl) and the like.

Another form of the carbonyl compound decomposing compound according to the present invention represented by the above general formula [I] is represented by the general formula [VI]:

[0049]

[Chemical 17]

(In the formula, R1d represents a hydrogen atom, an aldehyde
Group, unsubstituted or substituted C₁-C₈ Alkyl group, unsubstituted
Or substitution C_Three-C₇Cycloalkyl group, unsubstituted
Kuha substitution C₆-C₁₀Aryl group, unsubstituted or substituted
C₇-C₁₁Aralkyl group, carboxyl group or hydr
Means a roxyacetyl group, R2b is a hydrogen atom, unsubstituted
Or substitution C₁-C₈Alkyl group, unsubstituted or substituted
Conversion C_Three-C₇Cycloalkyl group, unsubstituted or substituted C
₆-C₁₀ Aryl group or unsubstituted or substituted C₇−
C₁₁Means an aralkyl group, R4b is a hydrogen atom,
Dehydrate group, unsubstituted or substituted C₁-C₈An alkyl group,
Unsubstituted or substituted C_Three-C₇Cycloalkyl group, non-substituted
Substitution or substitution C₆-C₁₀Aryl group, unsubstituted or
Is the substitution C₇-C₁₁Aralkyl group, carboxyl group or
Means a hydroxyacetyl group, R5b is a hydrogen atom,
Unsubstituted or substituted C₁-C₈Alkyl group, unsubstituted
Kuha substitution C_Three-C₇Cycloalkyl group, unsubstituted or
Substitution C₆-C₁₀ Aryl group or unsubstituted or substituted
C₇-C₁₁Means an aralkyl group, and mb is 0 or
Amination represented by (meaning an integer of 1 to 20)
It is composed of a compound and a polyamine compound. Well
In addition, these amine compounds and polyamine compounds
And the stereoisomer exists, such stereoisomer
Is also included.

More specifically, when mb is 0, the carbonyl compound-decomposing compound becomes an amine compound, while when mb means an integer of 1 to 20, the carbonyl compound-decomposing compound is It becomes a polyamine compound.

The substituent R1d represented by the above general formula [VI]
Of which, unsubstituted or substituted C₁-C₈Alkyl group, non-positioned
Substitution or substitution C_Three-C₇Cycloalkyl group, also unsubstituted
Or replace C₆-C₁₀Aryl group and unsubstituted or
Is the substitution C₇-C₁₁The aralkyl group is a substituent R1a
Each may have the same meaning. That is, the above substituents
Examples of R1d include a hydrogen atom, an aldehyde group, and a hydride.
Roxyacetyl group, carboxyl group, methyl, ethyl,
n-propyl, i-propyl, n-butyl, i-butyl, se
c-butyl, tert-butyl, n-pentyl, n-hexyl
C such as le, n-heptyl, n-octyl₁-C₈Archi
Group, cyclopropyl, cyclobutyl, cyclopentyl
C such as le, cyclohexyl and cycloheptyl_Three -C₇
Cycloalkyl group, phenyl, o-tolyl, m-tolyl,
p-tolyl, 2,3-dimethylphenyl, 2,4-dimethylphenyl
Phenyl, 2,5-dimethylphenyl, 2,6-dimethylphenyl
L, 3,4-dimethylphenyl, 3,5-dimethylphenyl,
2,3,4-trimethylphenyl, 2,3,5-trimethylphenyl
2,3,6-trimethylphenyl, 3,4,5-trimethylphenyl
Phenyl, 3,4,6-trimethylphenyl, 2,4,6-trimethyl
C such as ruphenyl, α-naphthyl, β-naphthyl group₆
-C₁₀Aryl group, benzyl, o-methylbenzyl, m
-Methylbenzyl, p-methylbenzyl, phenethyl, o
-Methylphenethyl, m-methylphenethyl, p-methyl
Phenethyl, phenylpropyl, o-methylphenylp
Ropyr, m-methylphenylpropyl, p-methylpheny
Rupropyl, phenylbutyl, α-naphthylmethyl, β
-C such as naphthylmethyl₇-C₁₁Aralkyl group, etc.
Is mentioned.

Among the above substituents R2b, R4b and R5b, an unsubstituted or substituted C ₁ -C ₈ alkyl group, an unsubstituted or substituted C ₃ -C ₇ cycloalkyl group, an unsubstituted or substituted C ₆ -C ₁₀ The aryl group and the unsubstituted or substituted C ₇ -C ₁₁ aralkyl group are the substituents R2 and R4.
And R5 may have the same meaning. That is, the substituent R2b, among R4b and R5b, the unsubstituted or substituted _C 1 -C ₈ alkyl group, an unsubstituted or substituted _C 3 -C ₇ cycloalkyl group, unsubstituted or substituted _C 6 _{-C 10} ants - Group and unsubstituted or substituted C
Examples of the _7- C ₁₁ aralkyl group include methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, sec-butyl, tert-butyl, n-pentyl, n-hexyl, n-heptyl. , _C 1 -C _8, such as n- octyl
Alkyl groups, C _3-, such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl and cycloheptyl
C ₇ cycloalkyl group, phenyl, o- tolyl, m- tolyl, p- tolyl, 2,3-dimethylphenyl, 2,4-dimethylphenyl, 2,5-dimethylphenyl, 2,6-dimethylphenyl, 3, 4-dimethylphenyl, 3,5-dimethylphenyl, 2,3,4-trimethylphenyl, 2,3,5-trimethylphenyl, 2,3,6-trimethylphenyl, 3,4,5-trimethylphenyl, 3, C such as 4,6-trimethylphenyl, 2,4,6-trimethylphenyl, α-naphthyl and β-naphthyl
₆ -C ₁₀ ants - group, benzyl, o- methylbenzyl, m- methylbenzyl, p- methylbenzyl, phenethyl, o- methylphenethyl, m- methylphenethyl, p-
Examples thereof include C ₇ -C ₁₁ aralkyl groups such as methylphenethyl, phenylpropyl, o-methylphenylpropyl, m-methylphenylpropyl, p-methylphenylpropyl, phenylbutyl, α-naphthylmethyl and β-naphthylmethyl.

Examples of the amine compound and polyamine compound represented by the above general formula [VI] include methylamine, ethylamine, n-propylamine, i-propylamine, benzylamine, α-phenethylamine (R,
S or dl), β-phenethylamine, ethylenediamine, 1,2-propylenediamine (R, S or d)
l), 3-phenyl-1,2-propylenediamine (R, S or dl), 1,2,3-propanetriamine, 1,2,3,4-butanetetraamine (2R, 3R
Or 2S, 3S or 2R, 3S or dl), 1,
2,3,4,5-pentanepentaamine (optically active form or racemic form or meso form), 1,2,3,4,5,6
-Hexanehexamine (optically active substance or racemic form or meso form) and the like.

The carbonyl compound decomposing composition according to the present invention contains the carbonyl compound decomposing compound represented by the general formula [I] and / or the saccharide.
As described above, the saccharides are composed of monosaccharides, disaccharides, trisaccharides, tetrasaccharides, polysaccharides and sugar-related compounds. In the above saccharides, examples of monosaccharides include D-glucose, galactose, xylose and D-
Fructose, D-erythrose, D-threose, arabinose, D-ribose, D-ribulose, xylulose, D-mannose, L-sorbose, D-glucuronic acid, D-gluconic acid, D-glucosamine, D-galactosamine, D -Mannosamine, D-glyceraldehyde, etc .; as disaccharides, for example, sucrose, maltose, lactose, cellobiose, agarobiose, isomaltose, xylobiose, gentiobiose, kojibiose, sophorose, taranose, trehalose, nigerose, hyalobiuronic acid, melibiose, lamina. Ribiose, rutinose, primberose, vicyanose, etc .; as trisaccharides, for example, gentianose, cellotriose, maltotriose, planteose, melezitose, la The tetrasaccharides, e.g., stachyose, lacto -N- tetraose like; Inosu and panose Polysaccharides, for example, dextrin, cyclodextrin, dextran, amylose,
Amylopectin, soluble starch, potato starch, corn starch, cellulose, agarose,
Alavan, alginic acid, inulin, galactan, xylan, chitin, glycogen, glucomannan, chondroitin, chondroitin-4-sulfate, chondroitin-6-sulfate, hyaluronic acid, pectic acid,
Mannan, lichenan, levan, etc .; Examples of sugar-related compounds include L-ascorbic acid, L-dehydroascorbic acid, etc. These sugars are light, water,
It is thermally stable and has the advantage of being extremely easy to handle in operation.

The carbonyl compound decomposed by the composition for decomposing a carbonyl compound according to the present invention having the above-mentioned constitution has the general formula [II]:

[0057]

[Chemical 18]

(In the formula, R7 is a hydrogen atom or an aldehyde.
Group, unsubstituted or substituted C₁-C₈Alkyl group, unsubstituted
Or substitution C_Three-C₇Cycloalkyl group, unsubstituted
Kuha substitution C₇-C₁₁Aralkyl group, unsubstituted or substituted
Conversion C₆-C₁₀Aryl group, carboxy group, lower alk
Group, hydroxyacetyl group or lower alkyl group
R8 means a hydrogen atom, an aldehyde
Group, unsubstituted or substituted C₁-C₈Alkyl group, unsubstituted
Or substitution C_Three-C₇Cycloalkyl group, unsubstituted
Kuha substitution C₇-C₁₁Aralkyl group, unsubstituted or substituted
Conversion C₆-C₁₀Aryl group, carboxy group, lower alk
Group, hydroxyacetyl group or C₁-C_Four
It means a lower alkyl ester group, and R7 and R8 are
C to start_Two-C₉Means an alkylene group and is linked to each other.
Combined with each other may form an alicyclic group)
it can. The carbonyl represented by the above general formula [II]
When R8 is a hydrogen atom, the compound is converted to an aldehyde.
And R8 is other than a hydrogen atom.
When it is a substituent, it is generically called a ketone compound.

Of the substituents R7 and R8 in the above-mentioned general formula [II], the unsubstituted or substituted C ₁ -C ₈ alkyl group has 1 to 8 carbon atoms which may have a substituent. It means a valent linear or branched saturated aliphatic hydrocarbon group. Examples of such an unsubstituted or substituted C ₁ -C ₈ alkyl group include methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, sec-butyl, tert-butyl, n-pentyl, n. Hydroxyalkyl groups such as hexyl, n-heptyl, n-octyl, hydroxymethyl, 1-hydroxyethyl, 2-hydroxyethyl, 3-hydroxypropyl, 2-hydroxy-2-methylpropyl; aminomethyl, 2-aminoethyl , 3-aminopropyl, 4-aminobutyl, 4-amino-3-hydroxybutyl and other aminoalkyl groups; carbamoylmethyl, carbamoylethyl, carbamoylaminomethyl, carbamoylaminopropyl, 2-carbamoylpropenyl and other carbamoylalkyl groups; Formylalkyl group such as formylmethyl; mercaptome Le, 1-
Mercaptoalkyl groups such as mercaptoethyl and 2-mercaptoethyl; guanidinoalkyl groups such as guanidinomethyl, 2-guanidinoethyl, 3-guanidinopropyl and 4-guanidinobutyl; lower alkylthioalkyl such as methylthiomethyl, methylthioethyl and ethylthiomethyl Groups and the like.

[0060] Among the substituents R7 and R8 in the above general formula [II], unsubstituted or substituted C ₃ -C ₇ cycloalkyl group, a good number of carbon atoms which may have a substituent group 3
To 7 monovalent cyclic saturated aliphatic hydrocarbon groups,
For example, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl group and the like can be mentioned. Here, examples of the substituent include hydroxy, amino, and lower alkyl groups such as methyl and ethyl. Further, one or a plurality of these substituents may be present, and when a plurality of these substituents are present, the types thereof may be the same or different.

Further, the substituent R in the above general formula [II] is
Of 7 and R8, unsubstituted or substituted _C 6 _{-C 10}
The aryl group means a monovalent aromatic hydrocarbon group having 6 to 10 carbon atoms which may have a substituent. Further, as the substituent, for example, hydroxy, chloro,
Examples thereof include halogen atoms such as bromo and iodo, and these substituents may be present in one or a plurality of groups, and when a plurality of these substituents are present, the types thereof may be the same or different. May be. Examples of such an unsubstituted or substituted C ₆ -C ₁₀ aryl group include phenyl,
o-tolyl, m-tolyl, p-tolyl, 2,3-dimethylphenyl, 2,4-dimethylphenyl, 2,5-dimethylphenyl, 2,6-dimethylphenyl, 3,4-dimethylphenyl,
3,5-dimethylphenyl, 2,3,4-trimethylphenyl,
2,3,5-trimethylphenyl, 2,3,6-trimethylphenyl, 3,4,5-trimethylphenyl, 3,4,6-trimethylphenyl, 2,4,6-trimethylphenyl, α-naphthyl,
Examples include β-naphthyl, 3,5-dibromo-4-hydroxyphenyl, 3-hydroxycarbonylphenyl and the like.

Further, the substituent R in the above general formula [II] is
Of 7 and R8, unsubstituted or substituted _C 7 _{-C 11}
The aralkyl group is a monovalent linear group which is an unsubstituted or substituted aryl group having 6 or 10 carbon atoms and an unsubstituted or substituted alkyl group having 1 to 5 carbon atoms. Alternatively, it means a branched saturated aliphatic hydrocarbon group. Examples of such an unsubstituted or substituted C ₇ -C ₁₁ aralkyl group include benzyl, o-methylbenzyl, m-methylbenzyl, p-methylbenzyl, phenethyl, o-methylphenethyl, m-methylphenethyl, p-
Methylphenethyl, phenylpropyl, o-methylphenylpropyl, m-methylphenylpropyl, p-methylphenylpropyl, phenylbutyl, α-naphthylmethyl, β-naphthylmethyl, p-hydroxybenzyl, 3,
4-dihydroxybenzyl, 3,5-diode-4-hydroxybenzyl, 3-hydroxycarbonylbenzyl, 4-
Hydroxy-3-hydroxycarbonylbenzyl and the like can be mentioned.

Further, the substituent R in the above general formula [II] is
Examples of the C ₁ -C ₄ lower alkyl ester group among 7 and R8 include methyl ester, ethyl ester and the like. The alicyclic group formed by combining R7 and R8 is a cyclic group consisting of a 3-membered ring to a 10-membered ring, and examples thereof include cyclopropanone, cyclobutanone, cyclopentanone, cyclohexanone, cyclohepta Examples thereof include non-, cyclooctanone, cyclononone and cyclodecanone.

In the method for decomposing a carbonyl compound which is another embodiment of the present invention, the composition for decomposing a carbonyl compound, which comprises the above-mentioned carbonyl compound-decomposing compound [I] and / or the above saccharide as a main component, ], And can be decomposed. More specifically, the method for decomposing a carbonyl compound according to the present invention is
The amino acid [III], the amino alcohol compound [IV], the alcohol compound or the poly alcohol compound [V], or the amine compound and the polyamine compound [VI] and / or the saccharide as a main component. The composition for decomposing a carbonyl compound is applied to the carbonyl compound [II].

As described above, the carbonyl compound-decomposing compound [I] and / or the saccharide-decomposing composition containing the saccharide as a main component is used in various forms depending on the shape of the object to be treated. can do. For example, when the composition for decomposing a carbonyl compound is used in the form of an aqueous solution, the composition for decomposing a carbonyl compound can be dissolved in water or another appropriate solvent and applied to the object to be treated. . Also, various methods can be adopted as the application method for the object to be treated, and, for example, methods such as coating, spraying and dipping can be adopted depending on the object to be treated. Further, the composition for decomposing a carbonyl compound can also be used, for example, with a paint or the like. In that case, the composition for decomposing the carbonyl compound may be mixed with a paint,
Alternatively, it can be used by applying or spraying the applied coating material. Furthermore, the composition for decomposing a carbonyl compound can also be used by being adsorbed on, for example, a fibrous base material such as wallpaper. This application method is particularly effective when the carbonyl compound is a causative substance of sick house syndrome.

More specifically, the method for decomposing a carbonyl compound according to the present invention comprises the above amino acids [III], the above amino alcohol compound [IV], the above alcohol compound [V], and the above poly alcohol compound. [V], the above amine compound [VI] and / or the above polyamine compound [VI]
And / or in combination with a composition for decomposing a carbonyl compound containing the above saccharide as a main component, the aldehyde compound [II] (when R8 is a hydrogen atom in the general formula [II]) or the ketone compound [II] (above General formula [II]
In the case where R8 is a substituent other than a hydrogen atom),
It can be decomposed by reacting in water or an organic solvent.

When the above aldehyde compound [II] or ketone compound [II] is vaporized, the above amino acids [III], the above amino alcohol compound [IV], the above alcohol compound [V], and the above poly alcohol. -A solid layer of the compound [V], the amine compound [VI] and / or the polyamine compound [VI] and a saccharide, for example,
It can also be decomposed by passing through a thin layer or a column layer.

Further, the vaporized aldehyde compound [II] or ketone compound [II] is converted into the above amino acids [III], the above amino alcohol compound [IV], the above alcohol compound [V], and the above poly alcohol. -A compound [V], the above amine compound [VI] and / or the above polyamine compound [VI] and / or a carbonyl compound-decomposing composition containing a saccharide as a main component, for example,
It can also be decomposed by absorbing or adsorbing it on a fibrous base material such as Japanese paper, western paper, cotton and the like, and passing the base material such as the fibrous base material.

Next, the decomposition experiment method and analysis method of the harmful carbonyl compound [II], that is, the harmful aldehyde compound and the harmful ketone compound will be described. The harmful carbonyl compound [II] can be decomposed by reacting with the carbonyl compound decomposing compound [I] and / or a carbonyl compound decomposing composition containing a saccharide as a main component in water or an organic solvent. That is, in detail, the harmful aldehyde compound and ketone compound [II] include the amino acids [III], the amino alcohol compound [IV], the alcohol compound [V], and the polyalcohol compound [II]. V], the above-mentioned amine compound [VI] and / or the above-mentioned polyamine compound [VI] and / or a saccharide-based composition for decomposing a carbonyl compound as a main component, for decomposition.

Further, the vaporized carbonyl compound [I
[I], that is, an aldehyde compound and a ketone compound, and a compound for decomposing a carbonyl compound [I], that is, the above amino acids [III], and the above amino alcohol compound [I
V], the above-mentioned alcohol compound [V], the above-mentioned polyalcohol compound [V], the above-mentioned amine compound [VI] and / or the above-mentioned polyamine compound [VI] and / or the above-mentioned saccharide for decomposing carbonyl compounds It can be decomposed by passing through a solid layer of the composition, eg a thin layer or a column layer.

Further, the vaporized carbonyl compound [I
[I], that is, an aldehyde compound and a ketone compound, and a compound for decomposing a carbonyl compound [I], that is, the above amino acids [III], and the above amino alcohol compound [I
V], the above-mentioned alcohol compound [V], the above-mentioned polyalcohol compound [V], the above-mentioned amine compound [VI] and / or the above-mentioned polyamine compound [VI] and / or the above-mentioned saccharide for decomposing a carbonyl compound The composition as a base material,
For example, it can be decomposed by being absorbed or adsorbed on a fibrous base material such as Japanese paper, Western paper, cotton and the like, and passing through the fibrous layer.

Furthermore, the composition for decomposing a carbonyl compound according to the present invention comprises the above-mentioned carbonyl compound [II], that is, formalin, which is a causative substance of sick house syndrome among the above-mentioned aldehyde compounds and ketone compounds,
It can also be applied to walls, floors, ceilings, furniture, plywood and pillars where harmful chemical substances such as acetone and ethyl methyl ketone are generated. The composition for decomposing a carbonyl compound according to the present invention, that is, the amino acids [III] constituting the carbonyl compound decomposing compound [I], the amino alcohol compound [IV], the alcohol compound [V], the above Polyalcohol compound [V], the above amine compound [VI] and / or the above polyamine compound [V
I] and / or the composition for decomposing a carbonyl compound containing the above saccharide as a main component is dissolved in a suitable non-toxic solvent such as water or ethanol, a mixed solution of water and ethanol, or a paint. When sprayed or applied to the objects to be processed such as walls, floors, ceilings, furniture, plywood and pillars, the harmful substances such as formalin, acetone and ethyl methyl ketone generated from the objects to be processed are mixed. It can decompose various chemical substances.

Further, the carbonyl compound decomposing compound [I]
Constituting the amino acid [III], the amino alcohol compound [IV], the alcohol compound [V], the polyalcohol compound [V], the amine compound [VI]
And / or the above polyamine compound [VI] and / or
Alternatively, the composition for decomposing a carbonyl compound containing the above-mentioned saccharide as a main component is applied to a fibrous base material such as paper, fiber, cotton or the like in Kyushu or the like, and treated on walls, floors, ceilings, furniture, plywood, columns, etc. By sticking to an object, harmful chemical substances such as formalin, acetone and ethyl methyl ketone generated from the object to be treated can be decomposed.

The detector tube method can be used as an analytical method for confirming the decomposition of the aldehyde compound and the ketone compound decomposed by the carbonyl compound decomposition method according to the present invention. By this detector tube method, the main test (when carbonyl compound decomposing compound [I] of the present invention, that is, [III] to [VI] and / or saccharide is used) and blank test (decomposition of carbonyl compound according to the present invention) By performing the compound [I], that is, [III] to [VI] and / or the case where no saccharide is used), the decomposition removal rate of the aldehyde compound and the ketone compound can be determined. The decomposition removal rate is calculated by the following calculation formula. Decomposition / removal rate (%) = [100−main test value (ppm) / blank test value (ppm) × 100]

[0075]

EFFECT OF THE INVENTION By using the composition for decomposing a carbonyl compound according to the present invention, a harmful aldehyde compound and a ketone compound [II] can be decomposed in a short time with a high decomposition rate and a simple operation. In particular, it is effective for decomposing harmful chemical substances such as formalin and acetone generated from walls, floors, ceilings, furniture, plywood and pillars of new houses and condominiums. That is, it was found that the method for decomposing and removing formalin according to the present invention has an overwhelmingly high decomposition rate and a remarkably short time, as compared with the conventional method for decomposing and removing formalin, and thus is extremely effective. Further, the analysis regarding the decomposition of such harmful chemical substances can be performed by a simple operation using the detector tube method.

[0076]

EXAMPLES The present invention will be described in more detail by way of examples. Example 1: Decomposition experiment and analysis of formaldehyde in aqueous solution (main test) A carbonyl compound decomposing compound [III], [IV], [V] or [VI] or saccharide was added to 7.5 ml of 40% formalin aqueous solution (1 mmol). (1.2-5 mmol) A few ml of aqueous solution was added, and the mixture was stirred for 5 minutes. After standing for 10 minutes, measure the concentration (ppm) of formalin generated using a detector tube (1 minute, 1 minute
(00 ml suction). (Blank test) To 7.5 ml of 40% formalin aqueous solution (1 mmol), several ml of the same amount of water used in this test was added and stirred for 5 minutes. Ten
Concentration of formalin generated using detector tube after standing for 3 minutes
(ppm) was measured (100 ml suction for 1 minute). From the results of this experiment, the composition for decomposing carbonyl compounds [I]
Was found to exhibit high degradability of formaldehyde in an extremely short time. The results are shown in Table 1.

Table 1: Decomposition of formaldehyde in aqueous solution (Formaldehyde: 1 mmol; measured at 120 ° C)

Example 2: Decomposition experiment and analysis of formaldehyde by passing through solid layer (main test) 1 ml of 40% formalin aqueous solution (0.13 mmol) was gently put in a 500 ml bottle and the lid was closed. After 2 minutes, gently remove the lid to remove the carbonyl compound decomposing compound [III], [I
V], [V] or [VI] and sugars (1.23 to 2.46 mm
The column filled with ol) was firmly installed, and the concentration (ppm) of formalin generated through the column was measured using a detector tube (1 minute, 100 ml suction). (Blank test) 40% formalin aqueous solution (0.13 mmol) 1 ml
Gently placed in a 500 ml bottle and capped. After 2 minutes, gently remove the lid, firmly install the column not filled with the composition for decomposing carbonyl compounds, and measure the concentration (ppm) of formalin generated through this using a detector tube (1 minute, 100 ml suction )did. From the results of this experiment, it was found that the composition for decomposing a carbonyl compound almost instantly decomposes formaldehyde. The results are shown in Table 2.

Table 2: Decomposition of formaldehyde by passage through the solid layer (All measured at 20 ° C)

Example 3: Decomposition experiment and analysis of acetone by passage through solid layer (main test) 1 ml of acetone (13.6 mmol) was gently put into a 500 ml bottle and the lid was closed. After 1 minute, gently remove the lid,
A column packed with the composition for decomposing a carbonyl compound (2.46 mmol) was firmly installed, and the concentration (ppm) of acetone generated therethrough was measured using a detector tube (1.5 minutes, 100 ml suction was performed twice). (Blank test) 1 ml of acetone (13.6 mmol) was gently put into a 500 ml bottle and the lid was closed. After 1 minute, gently remove the lid,
A column not packed with the composition for decomposing carbonyl compounds was installed firmly, and the concentration (ppm) of acetone generated through this was measured using a detector tube (1.5 minutes, 100
ml was sucked twice). From the results of the experiment, it was found that the composition for decomposing a carbonyl compound instantly decomposes acetone well. The results are shown in Table 3.

Table 3: Decomposition of acetone by passage through the solid layer (All measured at 20 ° C)

Example 4: Decomposition experiment and analysis of formaldehyde by passage through fiber layer (main test) 1% of 40% formalin aqueous solution (0.13 mmol)
Gently placed in a 500 ml bottle and capped. After 2 minutes, gently remove the lid to remove the carbonyl compound decomposition composition (2.46 mm
ol) adsorbed absorbent cotton (the composition for decomposing carbonyl compounds was dissolved in an appropriate solvent, and this solution was absorbed by absorbent cotton and dried) was firmly installed and the concentration of formalin generated through this column was fixed. (ppm) was measured using a detector tube (100 ml suction for 1 minute). (Blank test) 1 ml of 40% formalin aqueous solution (0.13 mmol) was gently put into a 500 ml bottle and the lid was closed. After 2 minutes, gently remove the lid and install the column packed with normal absorbent cotton firmly, and the concentration of formalin (ppm) generated through this column
Was measured using a detector tube (100 ml suction for 1 minute). From the results of this experiment, it was found that the composition for decomposing a carbonyl compound instantly decomposes formaldehyde at a high decomposition rate. The results are shown in Table 4.

Table 4: Decomposition of formaldehyde by passage through the fiber layer (All measured at 20 ° C)

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁷ Identification code FI theme code (reference) C07C 49/08 C07C 49/08 Z G01N 31/00 G01N 31/00 V 31/22 121 31/22 121B F Term (reference) 2E191 BA11 BC05 BD11 2G042 AA01 BD04 BD08 BD09 BD10 BD12 CA01 CB01 DA08 FA11 4H006 AA05 AC13

Claims (15)

[Claims] 1. General formula [I]: {Wherein, R1 is a hydrogen atom, an aldehyde group, hydroxyacetyl group, an unsubstituted or substituted _C 1 -C ₈ alkyl group, an unsubstituted or substituted _C 3 -C ₇ cycloalkyl group,
Unsubstituted or substituted _C 7 _{-C 11} aralkyl group, an unsubstituted or substituted _C 6 _{-C 10} ants - group, means an unsubstituted or substituted _C 1 -C ₅ carboxylic acid group or heterocyclic group, and R2, Hydrogen atom, unsubstituted or substituted C ₁ -C ₈ alkyl group, unsubstituted or substituted C ₃ -C ₇ cycloalkyl group, unsubstituted or substituted C ₆ -C ₁₀ aryl group or unsubstituted or substituted C ₇ -C means ₁₁ aralkyl group, R3 is hydroxy group, an amino group or a -NHR9 group (wherein, R9 represents a hydrogen atom, means a single bond or _C 1 -C ₃ alkylene group, a heterocyclic bonded to R1a R4 represents a hydrogen atom, an aldehyde group, an unsubstituted or substituted C ₁ -C ₈ alkyl group, an unsubstituted or substituted C ₃ -C ₇
Cycloalkyl group, an unsubstituted or substituted _C 6 _{-C 10} ants - group, unsubstituted or substituted _C 7 _{-C 11} aralkyl group means a carboxyl group, hydroxyacetyl group, or keto group, R5 is a hydrogen atom, Unsubstituted or substituted C ₁ -C ₈ alkyl group, unsubstituted or substituted C ₃ -C ₇ cycloalkyl group, unsubstituted or substituted C ₆ -C ₁₀ aryl group or unsubstituted or substituted C ₇ -C ₁₁ aralkyl group R6 represents a hydroxy group or an amino group, m represents 0 or an integer from 1 to 20}, and a carbonyl compound decomposing compound and / or a carbonyl compound containing a saccharide as a main component A composition for decomposition, which has the general formula [II]: (Wherein, R7 is a hydrogen atom, an aldehyde group, hydroxyacetyl group, an alkyl ester group, a carboxyl group, hydroxyacetyl group, a lower alkyl ester group, an unsubstituted or substituted C ₁ -C ₈ alkyl group, an unsubstituted or substituted C _3- C ₇ cycloalkyl group, unsubstituted or substituted C ₆
-C ₁₀ ants - Le group or an unsubstituted or substituted _C 7 -C
Means ₁₁ aralkyl group, R8 is an aldehyde group, hydroxyacetyl group, a lower alkyl ester group, a carboxyl group, an unsubstituted or substituted _C 1 -C ₈ alkyl group, an unsubstituted or substituted _C 3 -C
₇ cycloalkyl group, unsubstituted or substituted C ₆ -C ₁₀
A carbonyl compound capable of decomposing a carbonyl compound represented by an aryl group or an unsubstituted or substituted C ₇ -C ₁₁ aralkyl group, and R 7 and R 8 may combine with each other to form a cyclic group. A composition for decomposing a carbonyl compound, which is a composition for decomposing a compound. 2. Decomposition of a carbonyl compound according to claim 1.
In the composition for use, the carbonyl compound decomposing compound
(I) is represented by the general formula (III): [Chemical 3] {In the formula, R1a is a hydrogen atom, unsubstituted or substituted C₁−
C₈Alkyl group, unsubstituted or substituted C_Three-C₇Cyclo
Alkyl group, unsubstituted or substituted C₆-C_{1 0}Aleil
Group, unsubstituted or substituted C₇-C₁₁Aralkyl group, non-
Substitution or substitution C₁-C₅Carboxylic acid group or heterocycle
Means formula group, R9a is a hydrogen atom, a single bond or C₁-C_ThreeAlkylene
A group, which may combine with R1a to form a cyclic structure
Amino acids represented by}. General formula [IV]: [Chemical 4] (In the formula, R 1b is a hydrogen atom, unsubstituted or substituted C₁−
C₈Alkyl group, unsubstituted or substituted C_Three-C₇Cyclo
Alkyl group, unsubstituted or substituted C₆-C_{1 0}Aleil
Group, unsubstituted or substituted C₇-C₁₁Aralkyl group, non-
Substitution or substitution C₁-C₅Carboxylic acid group or heterocycle
Means formula group, R9b is a hydrogen atom, a single bond or C₁-C_ThreeAlkylene
A group, which may combine with R1a to form a cyclic structure
An amino alcohol compound represented by General formula [V]: [Chemical 5] (In the formula, R1c is a hydrogen atom, an aldehyde group, or an unsubstituted
Kuha substitution C₁-C₈ Alkyl group, unsubstituted or substituted C
_Three-C₇Cycloalkyl group, unsubstituted or substituted C₆−
C₁₀Aryl group, unsubstituted or substituted C₇-C₁₁A
Ralalkyl group, carboxyl group, ketocarboxylic acid group or
Means a hydroxyacetyl group, R2a is a hydrogen atom, unsubstituted or substituted C₁-C₈Al
Kill group, unsubstituted or substituted C_Three-C₇Cycloalkyl
Group, unsubstituted or substituted C₆-C₁₀ Aryl group or
Unsubstituted or substituted C₇-C₁₁Means aralkyl group
Then R4a is a hydrogen atom, an aldehyde group, unsubstituted or substituted
C₁-C₈Alkyl group, unsubstituted or substituted C_Three-C₇
Cycloalkyl group, unsubstituted or substituted C₆-C₁₀A
Ryl group, unsubstituted or substituted C₇-C₁₁Aralkyl
Groups, carboxyl groups, ketocarboxylic acid groups or hydroxy groups
Means a acetyl group, R5a is a hydrogen atom, unsubstituted or substituted C₁-C₈Al
Kill group, unsubstituted or substituted C_Three-C₇Cycloalkyl
Group, unsubstituted or substituted C₆-C₁₀ Aryl group or
Unsubstituted or substituted C₇-C₁₁Means aralkyl group
Then ma means 0 or an integer from 1 to 20)
Represented alcohol compound or polyalcohol compound
Thing; or General formula [VI]: [Chemical 6] (In the formula, R1d is a hydrogen atom, an aldehyde group, or an unsubstituted
Kuha substitution C₁-C₈ Alkyl group, unsubstituted or substituted C
_Three-C₇Cycloalkyl group, unsubstituted or substituted C₆−
C₁₀Aryl group, unsubstituted or substituted C₇-C₁₁A
Ralalkyl group, carboxyl group or hydroxyacetyl
Means radical, R2b is a hydrogen atom, unsubstituted or substituted C₁-C₈Al
Kill group, unsubstituted or substituted C_Three-C₇Cycloalkyl
Group, unsubstituted or substituted C₆-C₁₀ Aryl group or
Unsubstituted or substituted C₇-C₁₁Means aralkyl group
Then R4b is a hydrogen atom, an aldehyde group, unsubstituted or substituted
C₁-C₈Alkyl group, unsubstituted or substituted C_Three-C₇
Cycloalkyl group, unsubstituted or substituted C₆-C₁₀A
Ryl group, unsubstituted or substituted C₇-C₁₁Aralkyl
Group, carboxyl group or hydroxyacetyl group
Then R5b is a hydrogen atom, unsubstituted or substituted C₁-C₈Al
Kill group, unsubstituted or substituted C_Three-C₇Cycloalkyl
Group, unsubstituted or substituted C₆-C₁₀ Aryl group or
Unsubstituted or substituted C₇-C₁₁Means aralkyl group
Then mb means 0 or an integer from 1 to 20)
Is an amine compound or polyamine compound represented
And a composition for decomposing a carbonyl compound. 3. The composition for decomposing a carbonyl compound according to claim 1, wherein the saccharide is D-glucose, galactose, xylose, D-fructose, D-erythrose, D-threose, arabinose, D-ribose, D-ribulose, xylulose, D-mannose,
L-sorbose, D-glucuronic acid, D-gluconic acid,
Monosaccharides such as D-glucosamine, D-galactosamine, D-mannosamine, D-glyceraldehyde, sucrose, maltose, lactose, cellobiose, agarobiose, isomaltose, xylobiose, gentiobiose, kojibiose, sophorose, taranose,
Disaccharides such as trehalose, nigerose, hyalobiuronic acid, melibiose, laminaribiose, rutinose, primberose, vicyanose, and trisaccharides such as gentianose, cellotriose, maltotriose, planteose, melezitose, raffinose, panose, statioose, lacto-N- Tetraose and other tetrasaccharides, dextrin, cyclodextrin, dextran, amylose, amylopectin, soluble starch, potato starch, corn starch, cellulose, agarose, araban, alginic acid, inulin, galactan,
Polysaccharides such as xylan, chitin, glycogen, glucomannan, chondroitin, chondroitin-4-sulfate, chondroitin-6-sulfate, hyaluronic acid, pectic acid, mannan, lichenan, levan or L-ascorbic acid, L-dehydroascorbic acid, etc. A composition for decomposing a carbonyl compound, which is a sugar-related compound. 4. General formula [I]: {Wherein, R1 is a hydrogen atom, an aldehyde group, hydroxyacetyl group, an unsubstituted or substituted _C 1 -C ₈ alkyl group, an unsubstituted or substituted _C 3 -C ₇ cycloalkyl group,
Unsubstituted or substituted _C 7 _{-C 11} aralkyl group, an unsubstituted or substituted _C 6 _{-C 10} ants - group, means an unsubstituted or substituted _C 1 -C ₅ carboxylic acid group or heterocyclic group, and R2, Hydrogen atom, unsubstituted or substituted C ₁ -C ₈ alkyl group, unsubstituted or substituted C ₃ -C ₇ cycloalkyl group, unsubstituted or substituted C ₆ -C ₁₀ aryl group or unsubstituted or substituted C ₇ -C ₁₁ means an aralkyl group, R3 is hydroxy group, an amino group or a -NHR9 group (wherein, R9 represents a hydrogen atom, means a single bond or _C 1 -C ₃ alkylene group, a cyclic structure in combination with R1a R4 is a hydrogen atom, an aldehyde group, an unsubstituted or substituted C ₁ -C ₈ alkyl group, an unsubstituted or substituted C ₃ -C ₇
Cycloalkyl group, an unsubstituted or substituted _C 6 _{-C 10} ants - group, unsubstituted or substituted _C 7 _{-C 11} aralkyl group means a carboxyl group, hydroxyacetyl group, or keto group, R5 is a hydrogen atom, unsubstituted or substituted _C 1 -C ₈ alkyl group, an unsubstituted or substituted _C 3 -C ₇ cycloalkyl group, unsubstituted or substituted _C 6 _{-C 10} ants - Le group or an unsubstituted or substituted _C 7 _{-C 11} aralkyl group R6 represents a hydroxy group or an amino group, m represents 0 or an integer from 1 to 20}, and a carbonyl compound decomposing compound and / or a carbonyl compound containing a saccharide as a main component By using the composition for decomposition, the compound of the general formula [II]: (Wherein, R7 is a hydrogen atom, an aldehyde group, hydroxyacetyl group, an alkyl ester group, a carboxyl group, hydroxyacetyl group, a lower alkyl ester group, an unsubstituted or substituted C ₁ -C ₈ alkyl group, an unsubstituted or substituted C _3- C ₇ cycloalkyl group, unsubstituted or substituted C ₆
-C ₁₀ ants - Le group or an unsubstituted or substituted _C 7 -C
Means ₁₁ aralkyl group, R8 is an aldehyde group, hydroxyacetyl group, a lower alkyl ester group, a carboxyl group, an unsubstituted or substituted _C 1 -C ₈ alkyl group, an unsubstituted or substituted _C 3 -C
₇ cycloalkyl group, unsubstituted or substituted C ₆ -C ₁₀
It means an aryl group or an unsubstituted or substituted C ₇ -C ₁₁ aralkyl group, and R 7 and R 8 are combined to form a 3-membered ring, 4
Member ring, 5 member ring, 6 member ring, 7 member ring, 8 member ring, 9 member ring or
A method for decomposing a carbonyl compound, which comprises decomposing a carbonyl compound represented by the formula (10-membered ring may be formed). 5. Decomposition of a carbonyl compound according to claim 4.
In the method, the carbonyl compound decomposing compound (I)
Has the general formula (III): [Chemical 9] {In the formula, R1a is a hydrogen atom, unsubstituted or substituted C₁−
C₈Alkyl group, unsubstituted or substituted C_Three-C₇Cyclo
Alkyl group, unsubstituted or substituted C₆-C_{1 0}Aleil
Group, unsubstituted or substituted C₇-C₁₁Aralkyl group, non-
Substitution or substitution C₁-C₅Carboxylic acid group or heterocycle
Means formula group, R9a is a hydrogen atom, a single bond or C₁-C_ThreeAlkylene
A group, which may combine with R1a to form a cyclic structure
Amino acids represented by}. General formula [IV]: [Chemical 10] (In the formula, R 1b is a hydrogen atom, unsubstituted or substituted C₁−
C₈Alkyl group, unsubstituted or substituted C_Three-C₇Cyclo
Alkyl group, unsubstituted or substituted C₆-C_{1 0}Aleil
Group, unsubstituted or substituted C₇-C₁₁Aralkyl group, non-
Substitution or substitution C₁-C₅Carboxylic acid group or heterocycle
Means formula group, R9b is a hydrogen atom, a single bond or C₁-C_ThreeAlkylene
A group, which may combine with R1a to form a cyclic structure
An amino alcohol compound represented by General formula [V]: [Chemical 11] (In the formula, R1c is a hydrogen atom, an aldehyde group, or an unsubstituted
Kuha substitution C₁-C₈ Alkyl group, unsubstituted or substituted C
_Three-C₇Cycloalkyl group, unsubstituted or substituted C₆−
C₁₀Aryl group, unsubstituted or substituted C₇-C₁₁A
Ralalkyl group, carboxyl group, ketocarboxylic acid group or
Means a hydroxyacetyl group, R2a is a hydrogen atom, unsubstituted or substituted C₁-C₈Al
Kill group, unsubstituted or substituted C_Three-C₇Cycloalkyl
Group, unsubstituted or substituted C₆-C₁₀ Aryl group or
Unsubstituted or substituted C₇-C₁₁Means aralkyl group
Then R4a is a hydrogen atom, an aldehyde group, unsubstituted or substituted
C₁-C₈Alkyl group, unsubstituted or substituted C_Three-C₇
Cycloalkyl group, unsubstituted or substituted C₆-C₁₀A
Ryl group, unsubstituted or substituted C₇-C₁₁Aralkyl
Groups, carboxyl groups, ketocarboxylic acid groups or hydroxy groups
Means a acetyl group, R5a is a hydrogen atom, unsubstituted or substituted C₁-C₈Al
Kill group, unsubstituted or substituted C_Three-C₇Cycloalkyl
Group, unsubstituted or substituted C₆-C₁₀ Aryl group or
Unsubstituted or substituted C₇-C₁₁Means aralkyl group
Then ma means 0 or an integer from 1 to 20)
Represented alcohol compound or polyalcohol compound
Thing; or General formula [VI]: [Chemical 12] (In the formula, R1d is a hydrogen atom, an aldehyde group, or an unsubstituted
Kuha substitution C₁-C₈ Alkyl group, unsubstituted or substituted C
_Three-C₇Cycloalkyl group, unsubstituted or substituted C₆−
C₁₀Aryl group, unsubstituted or substituted C₇-C₁₁A
Ralalkyl group, carboxyl group or hydroxyacetyl
Means radical, R2b is a hydrogen atom, unsubstituted or substituted C₁-C₈Al
Kill group, unsubstituted or substituted C_Three-C₇Cycloalkyl
Group, unsubstituted or substituted C₆-C₁₀ Aryl group or
Unsubstituted or substituted C₇-C₁₁Means aralkyl group
Then R4b is a hydrogen atom, an aldehyde group, unsubstituted or substituted
C₁-C₈Alkyl group, unsubstituted or substituted C_Three-C₇
Cycloalkyl group, unsubstituted or substituted C₆-C₁₀A
Ryl group, unsubstituted or substituted C₇-C₁₁Aralkyl
Group, carboxyl group or hydroxyacetyl group
Then R5b is a hydrogen atom, unsubstituted or substituted C₁-C₈Al
Kill group, unsubstituted or substituted C_Three-C₇Cycloalkyl
Group, unsubstituted or substituted C₆-C₁₀ Aryl group or
Unsubstituted or substituted C₇-C₁₁Means aralkyl group
Then mb means 0 or an integer from 1 to 20)
Is an amine compound or polyamine compound represented
A method for decomposing a carbonyl compound, which comprises: 6. The method for decomposing a carbonyl compound according to claim 4 or 5, wherein the saccharide is D-glucose,
Galactose, xylose, D-fructose, D-erythrose, D-threose, arabinose, D-ribose, D-ribulose, xylulose, D-mannose, L-sorbose, D-glucuronic acid, D-gluconic acid, D-glucosamine. , Monosaccharides such as D-galactosamine, D-mannosamine, D-glyceraldehyde, etc., sucrose, maltose, lactose, cellobiose, agarobiose, isomaltose, xylobiose, gentiobiose, kojibiose, sophorose, taranose, trehalose, nigerose, hyalobiuronic acid, melobiose. , Disaccharides such as laminaribiose, rutinose, primberose, vicyanose, gentianose,
Cellotriose, maltotriose, planteose,
Trisaccharides such as melezitose, raffinose, panose,
Tetrasaccharides such as stathose, lacto-N-tetraose, dextrin, cyclodextrin, dextran, amylose, amylopectin, soluble starch, potato starch, corn starch, cellulose, agarose, araban, alginic acid, inulin, galactan, xylan, chitin, glycogen, glycogen, Glucomanan, chondroitin, chondroitin-4-sulfate, chondroitin-6-sulfate, hyaluronic acid, pectic acid, polysaccharides such as mannan, lichenan, levan or sugar-related compounds such as L-ascorbic acid, L-dehydroascorbic acid A method for decomposing a carbonyl compound, comprising: 7. The method for decomposing a carbonyl compound according to claim 4, wherein the compound decomposing the carbonyl compound represented by the general formula [I] and / or
Alternatively, a composition for decomposing a carbonyl compound containing a saccharide as a main component is applied to the carbonyl compound represented by the general formula [II] to decompose the carbonyl compound represented by the general formula [II]. A method for decomposing a carbonyl compound, comprising: 8. The method for decomposing a carbonyl compound according to claim 7, wherein the compound decomposing the carbonyl compound is an amino acid represented by the general formula [III] or the general formula [I
V], an amino alcohol compound represented by the general formula [V], an alcohol compound or a polyalcohol compound represented by the general formula [V], or an alcohol compound or a polyalcohol represented by the general formula [VI]. And a carbonyl compound decomposing method. 9. The method for decomposing a carbonyl compound according to claim 7 or 8, wherein the compound decomposing the carbonyl compound represented by the general formula [I], the amino acid represented by the general formula [III], or the general formula An amino alcohol compound represented by [IV], an alcohol compound or polyalcohol compound represented by the general formula [V], or an alcohol compound or polyalcohol represented by the general formula [VI]. A carbonyl compound and / or a composition for decomposing a carbonyl compound having a saccharide as a main component is applied to an object to be treated containing the carbonyl compound represented by the general formula [II]. Disassembly method. 10. The method for decomposing a carbonyl compound according to claim 9, wherein the object to be treated is an object or place where a causative substance of sick house syndrome is being generated, such as a house or furniture, or is applied to such object or place. A method for decomposing a carbonyl compound, characterized in that it is a substance or product to be treated. 11. The method for decomposing a carbonyl compound according to claim 9 or 10, wherein the composition for decomposing a carbonyl compound containing the carbonyl compound-decomposing compound and / or the saccharide as a main component is in a liquid state with respect to the object to be treated. Alternatively, a method for decomposing a carbonyl compound, which is applied in a gaseous state. 12. The method for decomposing a carbonyl compound according to claim 11, wherein the composition for decomposing a carbonyl compound containing the carbonyl compound decomposing compound and / or the saccharide as a main component is applied or sprayed to the object to be treated. Or a method of decomposing a carbonyl compound, which is applied by being adsorbed on a fibrous base material. 13. The method for decomposing a carbonyl compound according to claim 4, wherein the carbonyl compound represented by the general formula [II] is represented by the general formula [I] in a vaporized state. A method for decomposing a carbonyl compound, which comprises passing through a composition for decomposing a carbonyl compound containing the compound for decomposing a carbonyl compound and / or the saccharide or a base material composed of the composition for decomposing a carbonyl compound to decompose the compound. 14. The method for decomposing a carbonyl compound according to claim 13, wherein the carbonyl compound decomposing compound is an amino acid represented by the general formula [III], or an amino alcohol represented by the general formula [IV]. A compound, an alcohol compound or polyalcohol compound represented by the general formula [V], or an alcohol compound or a polyalcohol compound represented by the general formula [VI]. Method for decomposing carbonyl compound. 15. An analysis method for confirming the decomposition of a carbonyl compound represented by the general formula [II] decomposed by the method for decomposing a carbonyl compound according to any one of claims 4 to 13 with a detector tube.