JP2003090837A - Coloration sheet and manufacturing method thereof - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a coloration sheet allowing easy identification by coloration for a chlorine solvent and solvents such as an alcohol and an amine. SOLUTION: A coloration test paper includes at least three kinds of coloring agents and a paper strength potentiator and has a paper sizing rate of 100 seconds or more, a Munsell hue of 10.0R to 10.0Y for the paper hue in Munsell color system, a lightness in Munsell value of 5.0-10.0 and a chroma in Munsell chroma of 0.5-5.0. This coloration sheet has the coloration test papers laminated in sheet shape and changes color into red when contacting the chlorine solvent, yellow when contacting alcohols and dark verdigris when contacting amines.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a colored paper which can identify a mist or a liquid medicine. In particular, the present invention relates to a coloring sheet that can instantly identify the type of a chemical that is an organic solvent having different properties, without using an analytical instrument or a special technique.

[0002]

2. Description of the Related Art For example, PH test paper, which can measure the degree of acidity or alkalinity of an aqueous solution, is known as a means for easily identifying liquid chemicals. Also, a test paper for semi-quantitatively measuring a specific ionic species in an aqueous solution is commercially available. However, regarding organic solvents, there is no colored paper or colored sheet that can instantly identify the type of the solvent.

To identify the organic solvent species, it is empirically empirically based on the color, viscosity, odor, solubility with other compounds, and the like, and the identification is performed by chemical analysis or instrumental analysis. Is.

For example, in the method of chemical analysis, there is a method of utilizing a redox reaction after collecting Cl 2 obtained by a flask combustion method for chlorine-containing organic matter. For amines, quinhydrone is used for coloring, and for alcohols, cerium ammonium nitrate and HNO3 acid are used to form a coordination compound. In instrumental analysis, it is identified by a chromatographic method or an absorption method. However, according to the analysis of such a method, test equipment and facilities are required, and it is difficult to identify easily and quickly.

In the method by chemical analysis or instrumental analysis as described above, it is unclear what the substance is, for example, when a liquid chemical (organic solvent, etc.) flows out in an emergency, for example, in a laboratory or a laboratory. In such cases, appropriate measures cannot be promptly determined. When an acid or alkali flows out, it is possible to take appropriate measures by neutralizing the pH by measuring the pH with a PH test paper or the like. However, when the organic solvent or the like flows out, the PH test paper does not develop a color, and it is difficult to identify the substance, and it is difficult to take appropriate measures.

[0006] In recent years, in order to prevent the outflow of chemicals out of business facilities due to the increased awareness of global environmental protection, there is a demand for prompt identification of accidentally leaked out chemicals and prevention of the spread of damage.

[0007]

DISCLOSURE OF THE INVENTION The present invention makes it possible to easily and instantly perform color identification with respect to chlorine-based solvents, alcohols, amines and other solvents, especially in the presence of water, assuming the case of spillage into wastewater. The present invention provides a colored sheet and a colored test paper that can be (identified).

[0008]

In order to solve the above-mentioned problems, the inventors of the present invention have earnestly studied and, as a result, arrived at the present invention. That is, it contains at least three kinds of coloring agents and a paper strengthening agent,
In the Munsell color system, the hue of the paper is Munsell Hue
The range is from 10.0R to 10.0Y, and the brightness is Munsell V
It is a color test paper having a range of 5.0 or more and 10.0 or less in the value of Al and a range of 0.5 or more and 5.0 or less in the Munsell Chroma, and further, the bulk density of the paper is 0.1 g / cc or more, 1.0 g / cc or less, and a thickness of 0.1 mm or more and 0.3 mm or less.
The sizing degree is 100 seconds or more, and is red when contacted with a chlorine-based solvent, yellow when contacted with alcohols, and dark green-blue when contacted with amines. It is a coloration sheet characterized in that a coloration paper is laminated on an adhesive sheet, a non-woven fabric, or a base material of paper or the like.

Further, as a color-developing agent, a particle size of 10
A coloring sheet characterized by using a powdery coloring agent having a proportion of 0 μm or less and a proportion of 1 μm or less of less than 1%.

Further, when paper is made by the inner surface sizing method, a fixing agent and a sizing agent are mixed with pulp and a paper strengthening agent,
Next, the present invention relates to a colored paper which is prepared by mixing a precipitant and a coloring agent powder into a mixed slurry and then adding a coagulant to make a paper.

It is desirable that PVA, which is a paper strengthening agent, is contained in an amount of 1.0% by weight or more and 10.0% by weight or less. If the content is too small, the strength of the paper will be weak, and if the content is too large, the permeation of the target organic solvent will be poor and the color development will be poor.

As the precipitant, a pigment dispersant is used, and the amount used is 3 to 20 times, preferably 5 to 10 times that of the coloring agent. If it is 3 times or less, the colorant is insufficiently dispersed, and if it is 20 times or more, the cohesiveness of the colorant on the test paper is deteriorated.

As the coagulant, there is a synthetic sticky agent for papermaking, and polyacrylamide type is particularly preferable. The amount used is 0.1 to 1.0%, preferably 0.2 to pulp.
It is 0.5%. If it is 0.1% or less, the coloring agent is insufficiently aggregated, and if it is 1.0% or more, it is excessively aggregated and the texture of the paper is deteriorated.

The coloration sheet obtained as described above is laminated on a sheet-like material, for example, an adhesive sheet having a base material such as paper, non-woven fabric or film to obtain a coloration sheet. This laminate can be used by directly attaching it to a floor, a medicine shelf, an organic solvent bottle or can, and the like. When an organic solvent comes into contact with these sheet-like materials, it is possible to determine what kind of solvent leaks by coloring.

[0015]

BEST MODE FOR CARRYING OUT THE INVENTION The colored paper has a hue of 10.0R to 10.0Y, preferably 5.0YR to 5.0 in the Munsell color system.
Within the range of Y or less, and the brightness is 5.0 or more and 10.0 or less,
Preferably, the range of 6.5 or more and 8.5 or less, and the saturation is 0.
The range is 5 or more and 5.0 or less, preferably 1.0 or more and 3.0 or less. In other cases, there is a problem in that the distinctiveness when coloring is deteriorated.

The colored paper has a bulk density of 0.1 g / cc or more and 1.0 g / cc or less, preferably 0.3 g / cc or more and 0.6 g / cc or less and a thickness. 0.1
mm or more and 0.3 mm or less, preferably 0.15 mm
As described above, it is 0.20 mm or less. Bulk density is 0.1g /
When it is less than cc, the paper strength becomes insufficient, and when minute droplets of the drug to be identified adhere, the droplets do not spread and as a result, the droplets cannot be identified. Also, 1.0
Paper exceeding g / cc has a problem that it is difficult to manufacture. Similarly, it is difficult to manufacture a paper having a thickness of less than 0.1 mm, and when the thickness exceeds 0.3 mm, there is a problem that droplets are difficult to spread.

The color test paper has a Steckigt sizing degree of 100 seconds or longer, preferably 200 seconds or longer. If it is less than 100 seconds, it tends to be difficult to color the test paper with a very small amount of solvent when it gets wet with water.

The following combinations of coloring agents are most suitable for use in the present invention, but the present invention is not limited thereto. The fact that color test papers show different colors in different solvents means that 2,5,2 ', 5'TetraMethyl
triphenylmethane-4,4'-Diazo-bis-β-hydroxynaphtoic
anilid (hereinafter abbreviated as TMD), 4- (4'-Phenylazoyl) Phe
nylazo-Phenol (hereinafter abbreviated as PPP) and Ethyl-bis
It is obtained by containing-(2,4-Dinitrophenyl) Acetate (hereinafter abbreviated as EDA).

When the combination of the solvents to be identified and identified is a chlorine-based solvent, an alcohol and an amine-based solvent, TMD is dissolved only in the chlorine-based solvent when the liquid adheres to the colored paper and turns red, and adheres. Informs that the droplet is a chlorine-based solvent. Further, when the adhered liquid is alcohols, the vibration of electrons causes the PPP to be deep-colored, and the colored paper develops a yellow color to inform that the adhered droplets are alcohols. Similarly, when the adhered liquid is an amine-based solvent, the charge is transferred to the benzene ring, which causes the colored paper to develop a green color, which indicates that the adhered droplets are the amine-based solvent.

In the present invention, as the hue adjusting dye,
Addition of 0.005-0.02% of RBY7GL (manufactured by bayer japan) enables more vivid coloration.

It is sufficient that the amount of the organic solvent that comes into contact with the color test paper is at least 0.01 μLt or more.
If it is less than this, it tends to be difficult to judge, but conversely, if too many are attached, the effect is the same. It is sufficient for this organic solvent to adhere to the color paper together with water.

The coloring paper has a coloring agent having a particle size of 1 μm or more, 1
00 μm or less and preferably 5 μm or more and 75 μm
The following are desirable: When the particle size of the color-developing agent exceeds 100 μm, it is difficult to distinguish the color of the trace amount of solvent and
When it is more than m, the background color of the paper becomes dark and the lightness becomes dark so that it becomes difficult to distinguish the coloration of the trace amount of organic solvent, and thus the coloration paper aimed at by the present invention cannot be obtained.

Further, the proportion of the color former having a particle size of 1 μm or less is less than 1%, preferably 0%. When it is 1% or more, the background color of the paper is dark and the lightness is dark, and it is difficult to identify the coloration of the trace amount of the organic solvent.

The coloring paper contains 0.2% by weight or more and 2.0% by weight or less of TMD as a coloring agent, 1.0% by weight or more and 10.0% by weight or less of PPP, and 1.0% by weight of EDA. %that's all,
It is desirable that the content is 10.0% by weight or less. When the content of the coloring agent is low, it is difficult to identify the color when it is colored, and when the content is high, the background color of the paper is dark and the lightness is dark, and the coloring of a very small amount of solvent Since it becomes difficult to identify the colored paper, the colored paper which is the object of the present invention cannot be obtained.

The colored paper thus formed is laminated on a non-woven fabric or a substrate such as paper or film to form a colored sheet. The base material of the pressure-sensitive adhesive sheet is not particularly limited as long as it is a sheet material, and is selected according to the application.

As a method of laminating, there are a method of adhering the colored paper and these base materials with an adhesive, a method of sewing and the like, but there is no particular specification as long as they can be integrated. or,
The tear strength of the sheet is preferably 50 N or less so that it can be easily torn by hand during use.

[0027]

EXAMPLES Examples will be shown below.

The Steckigt sizing degree of paper is JIS P8
It was measured based on the "Steckigt-Sizing test method for paper" defined in 122. The larger this value, the higher the water resistance of the paper.

Regarding hue, lightness, and saturation, JIS Z
It was measured based on the “display method of color by three attributes” defined in 8721.

As a method of testing the color development performance, tetrachloroethylene (chemical A) was used in the standard condition (20 ° C., RH 60%) and the condition that the sample was wet (soaked in 20 ° C. water for 30 minutes). , Isopropyl alcohol (Chemical agent B), and dimethylamine (Chemical agent C) were added dropwise at 0.1 and 0.01 μLt respectively, and the color development performance was judged as ○ when the color development was within 5 seconds after the addition, and the discrimination performance What was able to be identified as red, yellow and green 5 seconds after the dropping was judged to be acceptable and was evaluated as ◯ ×.

Example 1 50 parts each of NBKP pulp and LBKP pulp with a beating degree of SR-15, a fineness of 1.1 decitex, 3 parts of a fibrous binder (PVA) having a fiber length of 3 mm, and a yellow dye for adjusting the hue (bayer japan). Manufactured by RBY7GL), and then mixed with 5 parts of aluminum sulfate and 5 parts of white rosin (Size Pine N-771 manufactured by Arakawa Chemical Co., Ltd.) in order. next,
After mixing 5 parts of an antifoaming agent (Homeless P0 manufactured by Meisei Chemical Co., Ltd.), the average particle size was previously dispersed in water using a dispersant (Dispar TL manufactured by Meisei Chemical Co., Ltd.) 5 times as much as the coloring agent. A wet papermaking process was carried out by mixing 0.7 parts of TMD having a ratio of 25 μm and 1 μm or less of 0.8%, 5 parts of PPP and 5 parts of EDA, and finally 0.2 part of an anionic polymer flocculant (PAM). The color paper with a basis weight of 75 g / m ² ,
This was laminated with an adhesive sheet having a nonwoven fabric as a base material to prepare a coloring sheet.

Comparative Example 1 NBK having the same beating degree SR-15 as used in Example 1
50 parts each of P pulp and LBKP pulp, 3 parts of fibrous binder and 0.01 part of yellow dye are mixed, and then 5 parts of aluminum sulfate and 5 parts of white rosin are mixed in order. Next, after mixing 5 parts of the defoaming agent here, 5 parts of the coloring agent was previously prepared.
TMD0.7 having an average particle size of 14 μm dispersed in water with a double dispersant and a ratio of 1 μm or less is 15%
Parts, 5 parts of PPP and 5 parts of EDA are mixed, and finally 0.2 parts of an anionic polymer flocculant is mixed to perform wet papermaking to prepare colored paper having a basis weight of 75 g / m ² , and a non-woven fabric is used as a base. A colored sheet was prepared by laminating the adhesive sheet as a material.

Comparative Example 2 NBK having the same beating degree SR-15 as used in Example 1
50 parts each of P pulp and LBKP pulp, 3 parts of fibrous binder and 0.01 part of yellow dye are mixed, and then 5 parts of aluminum sulfate and 5 parts of white rosin are mixed in order. Next, after mixing 5 parts of the defoaming agent here, 5 parts of the coloring agent was previously prepared.
Average particle size of 150 μm dispersed in water with double dispersant
And the ratio of TMD0.
Wet papermaking was carried out by mixing 7 parts, 5 parts of PPP and 5 parts of EDA, and finally 0.2 parts of anionic polymer flocculant.
A colored paper having a basis weight of 75 g / m ² was prepared, and a colored sheet was prepared by laminating the colored paper with an adhesive sheet using the paper as a base material.

Comparative Example 3 50 parts each of NBKP pulp and LBKP pulp having a beating degree SR-15, a fineness of 1.1 decitex, 3 parts of a fibrous binder having a fiber length of 3 mm, and 0.01 part of a yellow dye for hue adjustment were mixed. Then, 0.7 parts of TMD having an average particle diameter of 25 μm and a ratio of 1 μm or less of 0.8% dispersed in water using a dispersant 5 times as much as the color former, 5 parts of PPP, E
5 parts of DA are mixed, and finally an anionic polymer flocculant (P
AM) 0.2 parts are mixed to perform wet papermaking, and basis weight is 75 g.
A color test sheet of / m ² was prepared and laminated with an adhesive sheet having a nonwoven fabric as a base material to prepare a color sheet.

Table 1 shows the properties of the colored papers of Example 1 and Comparative Examples 1 to 3 and Table 2 shows the results of comparison of the coloring performance.

[0036]

[Table 1]

[0037]

[Table 2]

[0038]

As described above, the coloration sheet of the present invention in which the coloration paper and the pressure-sensitive adhesive sheet based on a non-woven fabric are laminated, uses three kinds of colorants, and the particle size control and the hue thereof are used. Further, by adjusting the thickness and bulk density of the paper, it is very excellent in the color discrimination of organic solvents such as chlorine solvents, alcohols and amines. Further, since it has very high water resistance, it is possible to color-identify a very small amount of organic solvent even in the presence of a large amount of water, such as when the organic solvent flows out into wastewater.

Continued front page    F-term (reference) 2G042 AA01 BD02 BD04 BD13 CA02                       CB03 DA08 FA11 FB07 FC02                       FC07 FC09                 2G054 AA02 CA30 CE01 EA06 GB10                       GE06

Claims (9)

[Claims] 1. Bulk density of 0.1 g / cc or more and 1.0 g / c
c or less, a thickness of 0.1 mm or more and 0.3 mm or less, a water resistance of Steckigt sizing degree of 100 seconds or more, and at least one color when contacted with an organic solvent of at least 0.01 μLt or more. , And the hue of the paper in Munsell Hue is 10.0 R to 10.
In the range of 0Y, and the brightness is 5.0 or more in Munsell Value 1
A coloring sheet comprising: a coloring paper having a saturation of 0.0 or less and a Munsell Chroma of 0.5 or more and 5.0 or less, an adhesive sheet, and a release paper, which are laminated. 2. The coloring sheet according to claim 1, further comprising a coloring agent that exhibits different colors when brought into contact with a chlorine-based solvent, alcohols, and amines. 3. The coloring agent is 2,5,2 ′, 5′TetraMethyltriphenylm
ethane-4,4'-Diazo-bis-β-hydroxynaphtoic anilid
(Hereinafter abbreviated as TMD), 4- (4'-Phenylazoyl) Phenylazo-
Phenol (hereinafter abbreviated as PPP) and Ethyl-bis- (2,4-D
3. The coloring sheet according to claim 1, which is at least one kind of initrophenyl) Acetate (hereinafter abbreviated as EDA). 4. The coloring paper according to claim 1, wherein a powdery coloring agent having a particle size of 100 μm or less and a proportion of 1 μm or less is less than 1% by weight is used as the coloring agent. Manufacturing method. 5. The method for producing colored paper according to claim 1, wherein a hue adjusting dye is added in addition to the coloring agent. 6. A paper making method comprising mixing a fixing agent and a sizing agent in order with a pulp and a paper strengthening agent, and then adding a flocculant to a mixed slurry containing a precipitating agent and a coloring agent. The coloring sheet according to any one of 1 to 3. 7. The method for producing colored paper according to claim 1, wherein fibrous polyvinyl alcohol is used as a paper strength enhancer. 8. A color test paper comprising the color paper according to any one of claims 1 to 7. 9. A coloring sheet comprising the coloring paper according to claim 1, wherein the pressure-sensitive adhesive sheet is laminated with a nonwoven fabric or paper as a base material, and has a tear strength of 50 N or less.