JP2003071997A - Recycled decorative material - Google Patents
Recycled decorative materialInfo
- Publication number
- JP2003071997A JP2003071997A JP2001265208A JP2001265208A JP2003071997A JP 2003071997 A JP2003071997 A JP 2003071997A JP 2001265208 A JP2001265208 A JP 2001265208A JP 2001265208 A JP2001265208 A JP 2001265208A JP 2003071997 A JP2003071997 A JP 2003071997A
- Authority
- JP
- Japan
- Prior art keywords
- recycled
- surface layer
- layer
- decorative material
- pvc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明はグリーン購入法に適
合した床材、壁材等のリサイクル装飾材に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to recycled decorative materials such as floor materials and wall materials that comply with the Green Purchasing Law.
【０００２】[0002]
【従来の技術】環境問題が社会的に重要視され、最近は
グリーン購入法による資材調達が盛んに行われている。
メーカーとしても、製品品質ともに、環境に対し好まし
い製品を提供する義務を負っており、グリーン購入法に
適合した製品造りが必要になる。グリーン購入法は環境
負荷の少ない持続可能な社会を実現するため、国等の公
的機関が率先して環境に優しい物品の調達を推進するも
のである。具体的には、製造段階で再生材を利用する
か、再生しやすい材料を使用するか、廃棄物リサイクル
段階でリサイクルを容易にするシステムがあることが必
要である。ビニル系床材については、再生樹脂の使用比
率が３０重量％以上使用したものが要求される。2. Description of the Related Art Environmental problems are regarded as important socially, and recently, the procurement of materials by the Green Purchasing Law has been actively carried out.
As a manufacturer, it is obliged to provide products that are environmentally friendly in terms of product quality, and it is necessary to build products that comply with the Green Purchasing Law. Under the Green Purchasing Law, in order to realize a sustainable society with a low environmental impact, governments and other public institutions take the initiative in promoting the procurement of environmentally friendly goods. Specifically, it is necessary to use recycled materials at the manufacturing stage, to use materials that are easy to recycle, or to have a system that facilitates recycling at the waste recycling stage. The vinyl floor material is required to have a recycled resin content of 30% by weight or more.
【０００３】従来公知の発泡床材は、１００％バージン
ＰＶＣにより構成され、且つ製品にリサイクル思想が盛
り込められず、環境に対し優れた構成とは言えなかっ
た。しかし表面層として、単に再生ＰＶＣをフィルム成
形した床材を得ても、表面層が変色し、商品価値がなか
った。Conventionally known foam floor materials are composed of 100% virgin PVC, and the recycling concept cannot be incorporated in the products, so that they cannot be said to be environmentally friendly. However, even if a floor material obtained by simply film-forming a recycled PVC film as the surface layer was obtained, the surface layer was discolored and had no commercial value.
【０００４】一方特開２００１−３５５０号公報には、
床材に合成樹脂廃材を利用する開示はあるが、表面層に
配合して、しかも意匠性を損なわない技術思想はない。On the other hand, Japanese Patent Laid-Open No. 2001-3550 discloses that
Although there is a disclosure that a waste synthetic resin material is used as a floor material, there is no technical idea of blending it into the surface layer and not impairing the design.
【０００５】[0005]
【発明が解決しようとする課題】本発明は品質が優れ、
しかもグリーン購入法に適合した装飾材を提供するもの
である。従来より優れた製品を得るには一般に未使用
（バージン）原料を投入するのが一般的である。しか
し、これらの製品はエネルギー等資源を多く使用してお
り、資源の再利用をした製品造りが急務であった。リサ
イクル材を全プラスチック量の30重量％以上使用するグ
リーン購入法が普及すると、これに適合することが要求
される。The present invention has excellent quality,
Moreover, it provides decorative materials that comply with the Green Purchasing Law. In order to obtain a product superior to conventional products, it is general to add an unused (virgin) raw material. However, these products use a lot of resources such as energy, and it is an urgent task to make products that reuse the resources. If the Green Purchasing Law, which uses more than 30% by weight of recycled plastic, becomes widespread, it is required to comply with it.
【０００６】[0006]
【課題を解決するための手段】本発明は表面層と樹脂ベ
ース層を有する装飾材において、Ｂａ−Ｚｎ系安定剤が
添加され、再生ＰＶＣが全プラスチック量の３０〜８０
重量％使用されている表面層が樹脂ベース材と積層され
たことを特徴とするリサイクル装飾材、をその要旨とす
る。According to the present invention, in a decorative material having a surface layer and a resin base layer, a Ba-Zn stabilizer is added, and recycled PVC is 30-80% of the total plastic amount.
The gist is a recycled decoration material characterized in that a surface layer used in a weight percentage is laminated with a resin base material.
【０００７】[0007]
【発明の実施の形態】図1は本発明発泡内装材断面図で
ある。１は基材、２は発泡ベース層である。基材は薄い
プラスチックシート、合成繊維またはガラス繊維の織
布、不織布である。基材上に発泡または非発泡のＰＶＣ
ベース層が形成される。1 is a sectional view of a foam interior material of the present invention. Reference numeral 1 is a base material, and 2 is a foamed base layer. The substrate is a thin plastic sheet, a woven or non-woven fabric of synthetic fibers or glass fibers. Foamed or unfoamed PVC on a substrate
A base layer is formed.
【０００８】ＰＶＣベース層は、主としてバージンＰＶ
Ｃのペーストを使用している。非発泡樹脂シートの場合
は、バインダーに対し充填材が１〜２００重量部、可塑
剤１０〜１００部である。ベース層の厚さは０．５〜５
ｍｍが好ましい。The PVC base layer is mainly virgin PV.
C paste is used. In the case of a non-foamed resin sheet, the filler is 1 to 200 parts by weight and the plasticizer is 10 to 100 parts with respect to the binder. The thickness of the base layer is 0.5-5
mm is preferred.
【０００９】ＰＶＣベース層が発泡層の時、特に望まし
くはケミカルエンボスが付与された場合である。発泡層
はＰＶＣペーストに発泡剤、発泡促進剤を添加し、印刷
インキ中に発泡抑制剤を付与した状態で、発泡剤分解温
度以上で加熱するケミカル発泡模様のベース層を得る。When the PVC base layer is a foam layer, it is particularly desirable when chemical embossing is applied. The foaming layer is obtained by adding a foaming agent and a foaming accelerator to PVC paste and applying a foaming inhibitor to the printing ink to obtain a base layer having a chemical foaming pattern which is heated at a temperature above the decomposition temperature of the foaming agent.
【００１０】可塑剤としてはＤＯＰ、又はＤＨＰ等のフ
タル酸エステル系の他、リン酸エステル系、脂肪酸エス
テル系、トリメット酸系、エポシキ系、若しくはポリエ
ステル系の可塑剤を用いてもよい。As the plasticizer, a phthalate ester-based plasticizer such as DOP or DHP, or a phosphate ester-based, fatty acid ester-based, trimet acid-based, epoxy-based or polyester-based plasticizer may be used.
【００１１】発泡剤としてはジニトロソペンタメチレン
テトラミン、ベンゼンスルホニルヒドラジド、ｐ−トル
エンスルホニルヒドラジド、ｐ、ｐ’−オキシビス（ベ
ンゼンスルホニルヒドラジド）、３、３’−ジスルホン
ヒドラジドフェニルスルホン、アゾビスイソブチルニト
リル、アゾジカルボンアミド等が例示され、発泡促進剤
として尿素エタノールアミン、亜鉛華、炭酸鉛、ステア
リン酸鉛、ステアリン酸亜鉛、グリコール等が例示され
る。さらに充填剤として水酸化アルミニウム、重質炭酸
カルシウム、軽質炭酸カルシウム、クレー、タルク等が
例示される。As the foaming agent, dinitrosopentamethylenetetramine, benzenesulfonylhydrazide, p-toluenesulfonylhydrazide, p, p'-oxybis (benzenesulfonylhydrazide), 3,3'-disulfonehydrazidephenylsulfone, azobisisobutylnitrile, Examples thereof include azodicarbonamide, and examples of the foaming accelerator include urea ethanolamine, zinc white, lead carbonate, lead stearate, zinc stearate, glycol and the like. Further, examples of the filler include aluminum hydroxide, heavy calcium carbonate, light calcium carbonate, clay, talc and the like.
【００１２】発泡抑制剤として、マレイン酸無水物，ト
リメリット酸無水物，マレイン酸、無水酢酸、ベンズト
リアゾールをインキバインダーの１〜70重量％、好まし
くは１〜５０重量％が印刷インキに配合される．As the foaming inhibitor, maleic anhydride, trimellitic anhydride, maleic acid, acetic anhydride and benztriazole are blended in the printing ink in an amount of 1 to 70% by weight, preferably 1 to 50% by weight of the ink binder. The
【００１３】印刷模様３は転写でも、直接印刷でも良
く、発泡性樹脂層上に、印刷模様、透明表面層４を積層
して加熱発泡する。基材上にバージンＰＶＣ発泡性層を
０．２〜１．０ｍｍ厚で塗布し、プレヒートオーブンに
てプレヒートを行い、転写ロールで樹脂層表面に転写に
より模様形成し、透明表面層を積層し,メインオーブン
にて１２０〜２５０℃で加熱発泡を行う。発泡倍率は
１．３〜２０倍である。このようにケミカルエンボス５
を有する本発明発泡装飾材６が得られる。３ は印刷層
であり、印刷層直下に寸法安定性付与のため、不織布、
ネット等の繊維層を介在させても良い。The printed pattern 3 may be transferred or directly printed. The printed pattern and the transparent surface layer 4 are laminated on the expandable resin layer and heat-foamed. A virgin PVC foamable layer is applied on a base material in a thickness of 0.2 to 1.0 mm, preheated in a preheat oven, a pattern is formed on the resin layer surface by a transfer roll, and a transparent surface layer is laminated, Thermal foaming is performed in the main oven at 120 to 250 ° C. The expansion ratio is 1.3 to 20 times. Like this, chemical emboss 5
The foamed decorative material 6 of the present invention having is obtained. 3 is a printed layer, which is a non-woven fabric immediately below the printed layer for imparting dimensional stability,
A fiber layer such as a net may be interposed.
【００１４】さらに発泡樹脂層をオーブンで加熱発泡直
前に表面層フィルム４を積層し、所望により、付加的に
加熱発泡後エンボスロールで加圧エンボスをしてもよ
い。Further, the surface layer film 4 may be laminated immediately before heat-foaming the foamed resin layer in an oven, and if desired, after the heat-foaming, pressure embossing may be performed with an embossing roll.
【００１５】表面層４は好ましくは０．０５〜１．０ｍ
ｍさらに好ましくは０．１〜０．５ｍｍの透明樹脂層で
ある。表面層は実質的に再生ＰＶＣからなる樹脂を、カ
レンダー法、押出法等により形成される。この表面層に
は、Ba−Zn安定剤が添加されており、ケミカルエンボス
に効果的に寄与する。表面層は所望により、着色しても
良い。これは下地印刷層材が木目の時、それと対応する
ことによる。上記安定剤の量は好ましくは０．０１〜５
重量部、さらに好ましくは０．１〜２部が好適である。The surface layer 4 is preferably 0.05 to 1.0 m.
A transparent resin layer having a thickness of 0.1 to 0.5 mm is more preferable. The surface layer is formed of a resin substantially made of recycled PVC by a calender method, an extrusion method or the like. A Ba-Zn stabilizer is added to this surface layer and effectively contributes to chemical embossing. The surface layer may be colored if desired. This is because the base printing layer material corresponds to that when it is wood grain. The amount of the above stabilizer is preferably 0.01 to 5
Weight part is more preferable, and 0.1 to 2 parts is more preferable.
【００１６】上記のような構成の複合フィルムは、表面
層が透明でなく、木目模様や、マーブル模様の不透明シ
ートでも良い。このシートと発泡層との接着性が良い。
本発明において、特に優れた構成は、ベース層として、
ＰＶＣバージン樹脂ペーストに公知の発泡剤、発泡促進
剤、が配合され、転写によって印刷された、模様の印刷
インキに発泡抑制剤が含有され、表面層が再生ＰＶＣ
に、Ｂａ−Ｚｎ系安定剤が添加されることにより、透明
で、エンボス差がはっきり得られ、意匠性の良いリサイ
クルケミカルエンボス発泡床材５等の装飾材が得られ
る。この時、再生ＰＶＣ表面層は好ましくは０．１〜
０．5mm厚さでプラスチック床材全体、わけてもベース
層と表面層合計の３０重量％以上、３０〜８０重量％で
あり、好ましくは３０〜６０重量％が好適である。The composite film having the above structure may be an opaque sheet having a grain pattern or a marble pattern instead of a transparent surface layer. Good adhesion between this sheet and the foam layer.
In the present invention, a particularly excellent structure, as the base layer,
A known foaming agent and a foaming accelerator are blended with a PVC virgin resin paste, and a pattern printing ink printed by transfer contains a foaming inhibitor, and a surface layer is recycled PVC.
By adding a Ba-Zn stabilizer to the above, a decorative material such as a recycled chemical embossed foam floor material 5 which is transparent and has a clear embossing difference and good design can be obtained. At this time, the recycled PVC surface layer is preferably 0.1 to
It has a thickness of 0.5 mm and is 30% by weight or more, and 30 to 80% by weight, preferably 30 to 60% by weight, based on the total weight of the base material and the surface layer.
【００１７】本発明において,表面層に配合する可塑剤
の量は好ましくは１〜５０重量部,更に好ましくは１０
〜３０部である.添加するＢａ−Ｚｎ系安定剤は０．０
１〜５部さらに好ましくは０．１〜２部添加する。 上
記安定剤を多量に添加すると、ベタついて好ましくな
い。Ｂａ−Ｚｎ系安定剤を使用することにより、ケミカ
ルエンボスのエンボス段差が好ましくは０．３〜１．５
ｍｍの凹凸がシャープに得られ好ましい。一方、例えば
Ｓｎ系安定剤の場合は、エンボス差のシャープさにかけ
る。In the present invention, the amount of the plasticizer blended in the surface layer is preferably 1 to 50 parts by weight, more preferably 10 parts by weight.
-30 parts. The Ba-Zn stabilizer added is 0.0
1-5 parts, more preferably 0.1-2 parts are added. Addition of a large amount of the above-mentioned stabilizer is not preferable because it causes stickiness. By using a Ba-Zn stabilizer, the embossing step of chemical embossing is preferably 0.3 to 1.5.
mm unevenness is sharply obtained, which is preferable. On the other hand, for example, in the case of Sn-based stabilizers, the sharpness of the embossing difference is applied.
【００１８】得られた床材は、寸法安定性、反り、傷付
き、硬さは変わらず、外観上は全部バージンの材料を使
用した内装材と変わりなかった。The flooring material thus obtained did not change in dimensional stability, warpage, scratches and hardness, and in appearance it was the same as the interior material using the virgin material.
【００１９】[0019]
【実施例１】５０ｇ／ｍ2のガラス不織布の基材上に
「表１」配合で混入した発泡性樹脂をナイフコーターで
厚さ約０．３ｍｍになる様に塗布し、プレヒートオーブ
ンにて加熱してベンゾトリアゾール発泡抑制剤で形成さ
れた模様を転写後、その表面にＢａ−Ｚｎ安定剤１重量
部配合した廃農ビからなる厚さ０．３ｍｍのＰＶＣ再生
フィルムの押出しフィルムをラミネートし、その後メイ
ンオーブン（２００℃）で加熱発泡し、ケミカルエンボ
スを付与した厚さ２ｍｍの発泡床材を得た。[Example 1] A foaming resin mixed in a composition of "Table 1" was coated on a glass non-woven fabric substrate of 50 g / m 2 with a knife coater to a thickness of about 0.3 mm and heated in a preheat oven. Then, after transferring the pattern formed by the benzotriazole foaming inhibitor, an extruded film of a PVC recycled film having a thickness of 0.3 mm, which is made of waste agricultural plastic mixed with 1 part by weight of a Ba—Zn stabilizer, is laminated on the surface thereof, Then, it was heated and foamed in a main oven (200 ° C.) to obtain a foamed flooring material having a thickness of 2 mm to which chemical embossing was applied.
【００２０】得られた床材は、エンボス段差はシャープ
であり、表面外観は従来発泡床材と同じでエンボス段差
が０．５ｍｍのシャープな同調エンボスが得られる等の
効果があった。また性能、外観が全部バージン材料を使
用した場合と何ら遜色がなく、リサイクル材料を全プラ
スチックの５０重量％使用しているので、グリーン購入
法に適合された。表層重量は４００ｇ／ｍ2で下層重量
は４００ｇ／ｍ2であり、全重量８００ｇ／ｍ2 中再生
樹脂比率は５０重量％であった。The obtained flooring material had a sharp embossed step, and the surface appearance was the same as that of the conventional foamed flooring material, and there was an effect such that a sharp tuned embossing with an embossed stepped difference of 0.5 mm was obtained. Moreover, the performance and appearance are comparable to the case where the virgin material is used, and the recycled material uses 50% by weight of all the plastics, so that it is compliant with the Green Purchasing Law. The surface layer weight was 400 g / m 2 and the lower layer weight was 400 g / m 2 , and the ratio of recycled resin in the total weight of 800 g / m 2 was 50% by weight.
【００２１】[0021]
【表１】 [Table 1]
【００２２】[0022]
【比較例】表面層に添加した安定剤をＳｎ系とした他は
実施例１と同様の発泡床材を得た。得られたエンボス段
差は０．１ｍｍでシャープな外観は得られなかった。Comparative Example A foam flooring material similar to that of Example 1 was obtained except that the stabilizer added to the surface layer was Sn-based. The resulting embossed step was 0.1 mm, and no sharp appearance was obtained.
【００２３】[0023]
【実施例２】実施例１の基材上にバージンＰＶＣ１００
重量部に炭酸カルシウム充填剤１００重量部配合された
０．４ｍｍベース材上に印刷層を形成後、実施例１の
０．３ｍｍの再生ＰＶＣ表面層を積層した装飾材を得
た。ベース層６００ｇ／ｍ2、表面層４００ｇ／ｍ2で、
再生樹脂比率は４０％であった。Example 2 Virgin PVC 100 on the substrate of Example 1
A printing layer was formed on a 0.4 mm base material in which 100 parts by weight of a calcium carbonate filler was mixed in parts by weight, and then a 0.3 mm recycled PVC surface layer of Example 1 was laminated to obtain a decorative material. With a base layer of 600 g / m 2 and a surface layer of 400 g / m 2 ,
The recycled resin ratio was 40%.
【００２４】[0024]
【発明の効果】リサイクル性が高く、性能および意匠性
も全部バージン原料のものと比べ変わらなかった。本願
発明は、表面層として、多量の再生樹脂を使用している
ので、リサイクル性が最も優れた装飾材であり、グリー
ン購入法適合品であった。The recyclability is high, and the performance and the design are all the same as those of the virgin raw material. Since the present invention uses a large amount of recycled resin as the surface layer, it is a decorative material having the best recyclability and was a product compliant with the Green Purchasing Law.
【図１】 本発明発泡装飾材断面図である。FIG. 1 is a sectional view of a foamed decorative material of the present invention.
２ ベース層 ３ 印刷層 ４ 表面層 ５ 発泡床材 2 base layer 3 printing layers 4 surface layer 5 foam flooring
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 2E110 AB04 AB05 BA02 BA12 BB02 BB23 EA09 GB46W 4F100 AA08C AA21C AB09A AB18A AG00D AH02C AH03B AK15A AK15C AT00C BA04 BA07 BA10A CA01C CA05A CA30B DG15D EJ01 GB08 HB31B JA20A JL16 JL16A JN01A YY00A ─────────────────────────────────────────────────── ─── Continued front page F-term (reference) 2E110 AB04 AB05 BA02 BA12 BB02 BB23 EA09 GB46W 4F100 AA08C AA21C AB09A AB18A AG00D AH02C AH03B AK15A AK15C AT00C BA04 BA07 BA10A CA01C CA05A CA30B DG15D EJ01 GB08 HB31B JA20A JL16 JL16A JN01A YY00A
Claims (4)
いて、Ｂａ−Ｚｎ系安定剤が添加され、再生ＰＶＣが全
プラスチック量の３０〜８０重量％使用されている表面
層が樹脂ベース層と積層されたことを特徴とするリサイ
クル装飾材。1. A decorative material having a surface layer and a resin base layer, wherein a Ba—Zn stabilizer is added and recycled PVC is used in an amount of 30 to 80% by weight based on the total plastic amount. Recycled decorative material characterized by being laminated.
である請求項１のリサイクル装飾材。2. The recycled decorative material according to claim 1, wherein the resin base layer is a virgin material PVC foam.
された請求項１または２のリサイクル装飾材。3. The recycled decorative material according to claim 1, wherein the surface layer is transparent and chemical embossed.
て、ベース層としてＰＶＣバージン樹脂ペーストに公知
の発泡剤、発泡促進剤、が配合された発泡層に、模様の
印刷インキに発泡抑制剤が含有され、全プラスチック量
の３０〜８０重量％使用された再生ＰＶＣにＢａ−Ｚｎ
系安定剤が添加された透明表面層が積層されたケミカル
エンボス発泡床材。4. A flooring material having a surface layer and a resin base layer, a foaming layer comprising a PVC virgin resin paste and a known foaming agent and a foaming accelerator as a base layer, a pattern printing ink and a foaming inhibitor. Ba-Zn in recycled PVC containing 30 to 80% by weight of the total plastic content
Chemically embossed foam flooring with a transparent surface layer laminated with a stabilizer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001265208A JP2003071997A (en) | 2001-09-03 | 2001-09-03 | Recycled decorative material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001265208A JP2003071997A (en) | 2001-09-03 | 2001-09-03 | Recycled decorative material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2003071997A true JP2003071997A (en) | 2003-03-12 |
Family
ID=19091710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001265208A Pending JP2003071997A (en) | 2001-09-03 | 2001-09-03 | Recycled decorative material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2003071997A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007291840A (en) * | 2006-03-29 | 2007-11-08 | Dainippon Printing Co Ltd | Foam floor material sheet and its manufacturing method |
| CN103467882A (en) * | 2013-08-26 | 2013-12-25 | 界首市鑫豪塑胶有限公司 | Colored printing composite antiskid energy-saving plastic floor |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0952209A (en) * | 1995-08-10 | 1997-02-25 | Toli Corp Ltd | Floor material prepared by laminating surface layer containing short fibers |
| JPH10100334A (en) * | 1996-09-26 | 1998-04-21 | Toppan Printing Co Ltd | Wallpaper |
-
2001
- 2001-09-03 JP JP2001265208A patent/JP2003071997A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0952209A (en) * | 1995-08-10 | 1997-02-25 | Toli Corp Ltd | Floor material prepared by laminating surface layer containing short fibers |
| JPH10100334A (en) * | 1996-09-26 | 1998-04-21 | Toppan Printing Co Ltd | Wallpaper |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007291840A (en) * | 2006-03-29 | 2007-11-08 | Dainippon Printing Co Ltd | Foam floor material sheet and its manufacturing method |
| CN103467882A (en) * | 2013-08-26 | 2013-12-25 | 界首市鑫豪塑胶有限公司 | Colored printing composite antiskid energy-saving plastic floor |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5056889B2 (en) | Foamed wallpaper with high adhesion between paper substrate and resin layer | |
| EP0075832A1 (en) | Transfer sheets and production of decorative articles therewith | |
| US4828881A (en) | Process for producing self-adhesive sheet materials | |
| JP2003071997A (en) | Recycled decorative material | |
| AU598719B1 (en) | Thermoformable decorative rigid lamina for interiors of transportation vehicles | |
| JP2000211049A (en) | Foamed decorative material | |
| KR101310701B1 (en) | Polyurethane-based Covering Sheet and Composition for Preparing the Same | |
| JP2000218723A (en) | Foamed facing material | |
| JP3988896B2 (en) | Wall covering sheet | |
| JP3835278B2 (en) | Flooring | |
| JP4560678B2 (en) | Foamed wallpaper with high adhesion between paper substrate and resin layer | |
| JP2002069859A (en) | Decorative paper sheet | |
| JPH1158659A (en) | Chemical embossed sheet and its manufacture | |
| JPH10119227A (en) | Decorative sheet | |
| JP2018176568A (en) | Decorative sheet and method for producing the same | |
| JPH10280284A (en) | Flooring material and its production | |
| JP2890203B2 (en) | Manufacturing method of foam decorative material | |
| KR102510143B1 (en) | Adhesive Tile and Method for Preparing Same | |
| JP3209414U (en) | Adsorbent cushion floor | |
| JP2003019728A (en) | Decorative material | |
| JP2005232828A (en) | Floor material | |
| JP2006097212A (en) | Wallpaper | |
| JPH0686102B2 (en) | Foamed decorative material and method for producing the same | |
| JP2003127283A (en) | Decorative material | |
| JPS6397639A (en) | Production of synchronous embossed sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080117 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20100408 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100413 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20100803 |