JP2003064286A5 - - Google Patents
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- JP2003064286A5 JP2003064286A5 JP2001256482A JP2001256482A JP2003064286A5 JP 2003064286 A5 JP2003064286 A5 JP 2003064286A5 JP 2001256482 A JP2001256482 A JP 2001256482A JP 2001256482 A JP2001256482 A JP 2001256482A JP 2003064286 A5 JP2003064286 A5 JP 2003064286A5
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- JP
- Japan
- Prior art keywords
- formula
- pigments
- compound
- ink composition
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000049 pigment Substances 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 9
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- -1 polyoxyethylene phenyl ether Polymers 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atoms Chemical group C* 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- RZVHIXYEVGDQDX-UHFFFAOYSA-N Anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N Diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N Phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N Thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000368 destabilizing Effects 0.000 description 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atoms Chemical class [H]* 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 229910000460 iron oxide Inorganic materials 0.000 description 1
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 125000000018 nitroso group Chemical group N(=O)* 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910001929 titanium oxide Inorganic materials 0.000 description 1
Description
〈ポリオキシエチレンフェニルエーテル〉
式(1)：
Ｃ6Ｈ5Ｏ(ＣＨ2ＣＨ2Ｏ)nＨ (1)
〔式中ｎは３〜２８の数を示す。〕
で表されるポリオキシエチレンフェニルエーテルにおいて、式中のｎが３〜２８であるのが好ましいのは下記の理由による。すなわち式中のｎが３未満あるいは２８を超える化合物はいずれも、前述した補助効果が不十分になるおそれがある。また、特にｎが２８を超える化合物はインク組成物の粘度を上昇させたり、水溶性が低下してインク組成物中に析出したりして、インク組成物の吐出を不安定化させるおそれもある。
<Polyoxyethylene phenyl ether>
Formula (1):
C 6 H 5 O (CH 2 CH 2 O) n H (1)
[Wherein n represents a number of 3 to 28. ]
In the polyoxyethylene phenyl ether represented, by the following reason why the n in the formula is preferably a 3 to 28. That is, any compound in which n in the formula is less than 3 or more than 28 may result in insufficient auxiliary effect. In particular, a compound in which n exceeds 28 may increase the viscosity of the ink composition or may decrease the water solubility and precipitate in the ink composition, thereby destabilizing ejection of the ink composition. .
式(1)のポリオキシエチレンフェニルエーテルの具体例としては、ｎが６である、式(1-1)：
Ｃ6Ｈ5Ｏ(ＣＨ2ＣＨ2Ｏ)6Ｈ (1-1)
で表される化合物を挙げることができる。
〈ポリオキシエチレンアルキルフェニルエーテル〉
式(2)：
Ｒ1Ｃ6Ｈ4Ｏ(ＣＨ2ＣＨ2Ｏ)mＨ (2)
〔式中Ｒ1は炭素数８〜１０のアルキル基、ｍは３〜２８の数を示す。〕
で表されるポリオキシエチレンアルキルフェニルエーテルにおいて、式中のｍが３〜２８で、かつＲ1のアルキル基の炭素数が８〜１０であるのが好ましいのは下記の理由による。すなわち式中のｍが３未満あるいは２８を超える化合物や、Ｒ1のアルキル基の炭素数が８未満あるいは１０を超える化合物はいずれも、前述した補助効果が不十分になるおそれがある。また、特にｍが２８を超える化合物や、Ｒ1のアルキル基の炭素数が１０を超える化合物はインク組成物の粘度を上昇させたり、水溶性が低下してインク組成物中に析出したりして、インク組成物の吐出を不安定化させるおそれもある。
As a specific example of the polyoxyethylene phenyl ether of the formula (1), n is 6, formula (1-1):
C 6 H 5 O (CH 2 CH 2 O) 6 H (1-1)
The compound represented by these can be mentioned.
<Polyoxyethylene alkyl phenyl ether>
Formula (2):
R 1 C 6 H 4 O (CH 2 CH 2 O) m H (2)
[Wherein R 1 represents an alkyl group having 8 to 10 carbon atoms, and m represents a number of 3 to 28. ]
In the polyoxyethylene alkyl phenyl ether represented in m in the formula is 3 to 28, and by the following reason why the preferably number of carbon atoms in the alkyl group R 1 is 8-10. That is, any of the compounds in which m in the formula is less than 3 or more than 28, or a compound in which the carbon number of the alkyl group of R 1 is less than 8 or more than 10 may be insufficient in the aforementioned auxiliary effect. In particular, a compound in which m exceeds 28 or a compound in which the carbon number of the alkyl group represented by R 1 exceeds 10 increases the viscosity of the ink composition or decreases in water solubility and precipitates in the ink composition. In some cases, the ejection of the ink composition may become unstable.
無機顔料としては、例えば酸化チタン、酸化鉄などの金属化合物や、あるいはコンタクト法、ファーネス法、サーマル法などの公知の方法によって製造されたカーボンブラック等の１種または２種以上を挙げることができる。
また有機顔料としては、例えばアゾ顔料（アゾレーキ、不溶性アゾ顔料、縮合アゾ顔料、またはキレートアゾ顔料などを含む）、多環式顔料（例えば、フタロシアニン顔料、ベリレン顔料、ベリノン顔料、アントラキノン顔料、キナクリドン顔料、ジオキサジン顔料、チオインジゴ顔料、イソインドリノン顔料、またはキノフタロン顔料など）、染料キレート（例えば、塩基性染料型キレート、酸性染料型キレートなど）、ニトロ顔料、ニトロソ顔料、アニリンブラックなどの１種または２種以上を挙げることができる。
Examples of the inorganic pigment include one or more of metal compounds such as titanium oxide and iron oxide, or carbon black produced by a known method such as a contact method, a furnace method , or a thermal method. .
Examples of organic pigments include azo pigments (including azo lakes, insoluble azo pigments, condensed azo pigments, or chelate azo pigments), polycyclic pigments (for example, phthalocyanine pigments, berylene pigments, berylnone pigments, anthraquinone pigments, quinacridone pigments, Dioxazine pigment, thioindigo pigment, isoindolinone pigment, or quinophthalone pigment), dye chelate (for example, basic dye chelate, acid dye chelate, etc.), nitro pigment, nitroso pigment, aniline black, etc. The above can be mentioned.
実施例１３
ＣＡＥＯ１の量を０．８重量部、式(1-1)の化合物の量を３．４重量部、式(2-1)の化合物の量を０．８重量部、そしてイオン交換水の量を６２．４重量部に変更したこと以外は実施例１２と同様にしてインクジェット用インク組成物を製造した。
実施例１４
ＣＡＥＯ１に代えて、前記式(3)中のＭ1、Ｍ3がアンモニウム基、Ｍ2が水素で、かつｐが６である、式(3-4)：
Example 13
The amount of CAEO1 is 0.8 parts by weight, the amount of the compound of formula (1-1) is 3.4 parts by weight, the amount of the compound of formula (2-1) is 0.8 parts by weight, and the amount of ion-exchanged water Was changed to 62.4 parts by weight in the same manner as in Example 12 to produce an ink-jet ink composition.
Example 14
In place of CAEO1, in formula (3), M 1 and M 3 are ammonium groups, M 2 is hydrogen, and p is 6, formula (3-4):
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001256482A JP4852715B2 (en) | 2001-08-27 | 2001-08-27 | Ink jet ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001256482A JP4852715B2 (en) | 2001-08-27 | 2001-08-27 | Ink jet ink composition |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003064286A JP2003064286A (en) | 2003-03-05 |
| JP2003064286A5 true JP2003064286A5 (en) | 2008-10-09 |
| JP4852715B2 JP4852715B2 (en) | 2012-01-11 |
Family
ID=19084291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001256482A Expired - Lifetime JP4852715B2 (en) | 2001-08-27 | 2001-08-27 | Ink jet ink composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4852715B2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4525012B2 (en) * | 2003-07-31 | 2010-08-18 | Ｄｉｃ株式会社 | Colored kneaded material for inkjet ink recording and method for producing the same |
| JP4452912B2 (en) * | 2003-07-31 | 2010-04-21 | Ｄｉｃ株式会社 | Aqueous pigment dispersion for inkjet ink, aqueous ink composition for inkjet ink, and method for producing the same |
| JP4600724B2 (en) * | 2004-01-20 | 2010-12-15 | Ｄｉｃ株式会社 | Aqueous pigment dispersion for inkjet recording, ink composition for inkjet recording, and method for producing the same |
| CN100595241C (en) | 2004-07-01 | 2010-03-24 | 通用株式会社 | Inkjet ink and printing method using same |
| JP2014094495A (en) * | 2012-11-09 | 2014-05-22 | Seiko Epson Corp | Inkjet recording method |
| BR112019027607A2 (en) | 2017-06-26 | 2020-07-07 | Basf Se | compost, process for producing compounds, and, use of compost |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3191881B2 (en) * | 1991-11-27 | 2001-07-23 | 大日本インキ化学工業株式会社 | Water-based ink |
| JP3689444B2 (en) * | 1993-12-20 | 2005-08-31 | キヤノン株式会社 | Liquid composition, ink set, and image forming method and apparatus using the same |
| JP3507934B2 (en) * | 1996-08-08 | 2004-03-15 | 株式会社リコー | Recording ink and recording method using the same |
| JPH10226763A (en) * | 1997-02-13 | 1998-08-25 | Ricoh Co Ltd | Recording ink and recording method |
| JP3785630B2 (en) * | 1997-08-25 | 2006-06-14 | セイコーエプソン株式会社 | Ink jet ink composition, method for producing the same, and ink jet recording method using the ink composition |
| JPH11131003A (en) * | 1997-10-29 | 1999-05-18 | Ricoh Co Ltd | Ink for recording and recording method |
-
2001
- 2001-08-27 JP JP2001256482A patent/JP4852715B2/en not_active Expired - Lifetime
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