JP2002340187A - Seal structure of pipe joint for high temperature - Google Patents

Seal structure of pipe joint for high temperature

Info

Publication number
JP2002340187A
JP2002340187A JP2001142843A JP2001142843A JP2002340187A JP 2002340187 A JP2002340187 A JP 2002340187A JP 2001142843 A JP2001142843 A JP 2001142843A JP 2001142843 A JP2001142843 A JP 2001142843A JP 2002340187 A JP2002340187 A JP 2002340187A
Authority
JP
Japan
Prior art keywords
packing
pipe
high temperature
main seal
pipe joint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001142843A
Other languages
Japanese (ja)
Other versions
JP3786587B2 (en
Inventor
Takahisa Ueda
隆久 上田
Masaru Fujiwara
優 藤原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Pillar Packing Co Ltd
Original Assignee
Nippon Pillar Packing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Pillar Packing Co Ltd filed Critical Nippon Pillar Packing Co Ltd
Priority to JP2001142843A priority Critical patent/JP3786587B2/en
Publication of JP2002340187A publication Critical patent/JP2002340187A/en
Application granted granted Critical
Publication of JP3786587B2 publication Critical patent/JP3786587B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To provide a seal structure of a pipe joint for a high temperature suitably usable even in a high temperature environment such as a flame propagating pipe part used for a gas turbine combustor of a power plant, and superior in follow-up performance to a shaft directional inclination of a pipe by the thermal expansion. SOLUTION: Main seal packing 4 molded in a ring shape by pressurization by winding a mica sheet in layers is loaded in a packing chamber 3 formed in an outer peripheral part of the pipe 1. A mesh spring 5 molded in a ring shape after knitting or weaving a metallic fine line is loaded on both ends of this main seal packing 4, and is pressurized by a packing presser member 6.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、高温用配管継手の
シール構造に係り、より詳しくはボイラー、タービン、
焼却炉等の高温環境条件下での配管継手のシールに好適
に使用可能である高温用配管継手のシール構造に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a sealing structure for a high temperature pipe joint, and more particularly to a boiler, a turbine,
The present invention relates to a high-temperature pipe joint seal structure that can be suitably used for sealing pipe joints under high-temperature environmental conditions such as an incinerator.

【0002】[0002]

【従来の技術】従来、配管継手のシール構造として、た
とえば、自己潤滑特性、熱伝導性、耐薬品性等に優れる
膨張黒鉛系シール材からなるグランドパッキンを使用し
たものがある。
2. Description of the Related Art Conventionally, as a sealing structure of a pipe joint, for example, there is a structure using a gland packing made of an expanded graphite-based sealing material having excellent self-lubricating properties, thermal conductivity, chemical resistance and the like.

【0003】[0003]

【発明が解決しようとする課題】しかるに、膨張黒鉛系
シール材からなるグランドパッキンによる上記配管継手
のシール構造では、これが高温環境下に置かれると、熱
的影響で配管が傾斜した場合膨張黒鉛系シール材は前記
配管の傾斜に対する追随性が悪く、応力緩和が大きいた
め、シール性が短期間で低下し、気体の漏洩を起こす。
また、膨張黒鉛系シール材は600゜C付近を越える高
温度条件下では酸化消耗による劣化が激しく、シール特
性を持続することができなくなる。したがって、例え
ば、発電所のガスタービン燃焼器に使用される火炎伝播
管部などのように450〜600゜C付近を越える高温
度環境下においては使用不可能であり、このような高温
度環境下においても使用可能な高温用配管継手のシール
構造が要望されている。
However, in the above-described pipe joint sealing structure using a gland packing made of an expanded graphite sealing material, if the pipe is inclined under a high temperature environment when the pipe is inclined due to thermal influence, the expanded graphite system is not used. Since the sealing material has poor followability with respect to the inclination of the pipe and has a large stress relaxation, the sealing property is reduced in a short period of time, causing gas leakage.
In addition, the expanded graphite-based sealing material is severely deteriorated by oxidative consumption under a high temperature condition exceeding about 600 ° C., so that the sealing characteristics cannot be maintained. Therefore, for example, it cannot be used in a high temperature environment exceeding about 450 to 600 ° C., such as a flame transmission pipe used in a gas turbine combustor of a power plant. There is a demand for a seal structure for a high-temperature pipe joint that can be used in the above.

【0004】本発明の目的は、上記要望に応えるべくな
されたもので、高温での耐酸化性、弾力性に優れ、発電
所のガスタービン燃焼器に使用される火炎伝播管部など
の高温環境下でも好適に使用可能であるとともに、熱膨
張による配管の軸方向傾斜に対する追随性に優れる高温
用配管継手のシール構造を提供することにある。
SUMMARY OF THE INVENTION An object of the present invention is to meet the above-mentioned demands, and is excellent in oxidation resistance and elasticity at high temperatures, and is used in a high-temperature environment such as a flame propagation tube used in a gas turbine combustor of a power plant. An object of the present invention is to provide a seal structure for a high-temperature pipe joint that can be suitably used even under the pipe and has excellent followability with respect to the axial inclination of the pipe due to thermal expansion.

【0005】[0005]

【課題を解決するための手段】本発明は、接続される配
管の外径より大きい内径の配管貫通部を有して、配管の
外周部に円筒状のパッキン室を形成するとともに、この
パッキン室の軸方向の少なくとも片側にパッキン押え部
材を備えた高温用配管継手において、前記パッキン室
に、マイカシートを巻き重ねてリング状に加圧成形した
主シールパッキンと、この主シールパッキンの軸方向両
端に配される、金属細線を製編するか製織したのちリン
グ状に成形したメッシュスプリングとを装填してあるこ
とに特徴を有するものである。この場合において、上記
マイカシートとしては、金マイカを80%以上含有する
マイカシートを使用することが耐熱性を高めるうえで好
ましい。
According to the present invention, a cylindrical packing chamber is formed on the outer periphery of a pipe having a pipe penetration having an inner diameter larger than the outer diameter of the pipe to be connected. A high-pressure pipe joint having a gasket holding member on at least one side in the axial direction of the main seal packing, wherein a mica sheet is wound around the packing chamber and formed into a ring-shaped pressure; And a mesh spring formed by knitting or weaving a metal thin wire and then forming a ring shape. In this case, it is preferable to use a mica sheet containing 80% or more of gold mica in order to enhance heat resistance.

【0006】[0006]

【作用】マイカシートを巻き重ねてリング状に加圧成形
してなる主シールパッキンのリング成形品は、高温にお
ける耐酸化性に優れ、また高温での弾力性を確保するた
め、高温条件下においてもシール特性を長い使用期間に
わたって確保できる。主シールパッキンの軸方向両端に
配される、金属細線を製編織したのちリング状に成形さ
れたメッシュスプリングは、耐熱性を有し、また弾力性
に富むため、高温条件下においてもパッキン押え部材に
より加えられる締付圧の低下を補償できる。また、これ
ら主シールパッキン及びメッシュスプリングはいずれも
高温での弾力性を確保できるため、熱的影響により生じ
る配管の傾斜にも追随することができる。
[Function] A ring molded product of a main seal packing formed by winding a mica sheet into a ring and press-molding it in a ring shape has excellent oxidation resistance at high temperatures, and in order to ensure elasticity at high temperatures, under high temperature conditions. Also, the sealing characteristics can be secured over a long use period. The mesh spring, which is arranged on both ends in the axial direction of the main seal packing and formed by weaving and weaving a thin metal wire, has heat resistance and is highly resilient. Thus, the decrease in the tightening pressure applied can be compensated. Further, since both the main seal packing and the mesh spring can ensure elasticity at a high temperature, the main seal packing and the mesh spring can follow the inclination of the pipe caused by the thermal influence.

【0007】[0007]

【発明の実施の形態】本発明の高温用配管継手のシール
構造の好適な実施形態を図面に基づいて説明する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A preferred embodiment of a seal structure for a high temperature pipe joint according to the present invention will be described with reference to the drawings.

【0008】図1は高温用配管継手のシール構造の概略
断面図を示しており、高温用配管継手は圧力容器、機器
等における高温流体側Aと大気側Bを仕切る壁部材Wに
配管1の外径より大きい内径の配管貫通部2を形成し、
この配管貫通部2内の配管1の外周部に円筒状の空間、
すなわちパッキン室3を形成している。パッキン室3に
は主シールパッキン4を1個もしくは2個以上(図示例
では2個)を装填するとともに、この主シールパッキン
4の軸方向両端にメッシュスプリング5,5を配備し装
填している。パッキン室3の軸方向片側にはパッキン押
え部材6が備えられ、このパッキン押え部材6でメッシ
ュスプリング5及び主シールパッキン4を壁部材Wに向
けて加圧している。
FIG. 1 is a schematic sectional view of a sealing structure of a high-temperature pipe joint. The high-temperature pipe joint is connected to a wall member W for partitioning a high-temperature fluid side A and an atmosphere side B in a pressure vessel, equipment, or the like. Forming a pipe penetration portion 2 having an inner diameter larger than the outer diameter,
A cylindrical space around the outer periphery of the pipe 1 in the pipe penetration 2;
That is, the packing chamber 3 is formed. One or two or more (two in the illustrated example) main seal packings 4 are loaded into the packing chamber 3, and mesh springs 5, 5 are provided and loaded at both axial ends of the main seal packing 4. . A packing holding member 6 is provided on one axial side of the packing chamber 3, and the packing holding member 6 presses the mesh spring 5 and the main seal packing 4 toward the wall member W.

【0009】主シールパッキン4は、マイカシート、よ
り好ましくは金マイカ(phlogopite) を80%以上含有
するマイカシートを巻き重ね、この巻重体をリング状に
加圧成形してなる。メッシュスプリング5は、SUS3
16等の金属細線を横編あるいは縦編等の組織に製編し
た金属細線編物体、または金属細線を平織等の組織に製
織した金属細線織物体をリング状に成形してなる。
The main seal packing 4 is formed by winding a mica sheet, more preferably a mica sheet containing 80% or more of gold mica (phlogopite), and press-molding the wound body into a ring shape. Mesh spring 5 is SUS3
It is formed by shaping a thin metal wire knitted object obtained by knitting a thin metal wire such as 16 into a weft knitting or vertical knitting structure, or a thin metal wire woven body obtained by weaving a thin metal wire into a plain weaving texture.

【0010】上記構成の高温用配管継手のシール構造に
よれば、高温環境条件下の熱的影響で配管1が傾斜する
ようなことがあっても、マイカシートからなるリング状
の主シールパッキン4、及び金属細線の編物体または織
物体からなるリング状のメッシュスプリング5は、いず
れも高温での弾力性を確保するので、配管1の傾斜に追
随することができ、したがって常に主シールパッキン4
の内周面と配管1の外周面間に隙間をつくることなく気
密状にシール性を確保できて気体の漏洩を防止できる。
また、マイカシートからなる主シールパッキン4は高温
における耐酸化性にも優れるため、450〜600゜C
付近を越える高温度環境下でも酸化消耗するようなこと
がなく、この点でもシール特性を長期間にわたって確保
することができる。また、金属細線の編物体または織物
体からなるリング状のメッシュスプリング5は耐熱性、
弾力性に富むため、高温条件下においてもパッキン押え
部材6による主シールパッキン4の締付圧を低下させる
ことなく確保することができる。
According to the high-temperature pipe joint seal structure having the above-described structure, even if the pipe 1 is inclined due to the thermal effect under high-temperature environmental conditions, the ring-shaped main seal packing 4 made of mica sheet is used. , And a ring-shaped mesh spring 5 made of a knitted object or a woven body made of a thin metal wire can ensure elasticity at a high temperature, and can follow the inclination of the pipe 1.
It is possible to secure gas-tight sealing without forming a gap between the inner peripheral surface of the pipe and the outer peripheral surface of the pipe 1, thereby preventing gas leakage.
In addition, the main seal packing 4 made of mica sheet has excellent oxidation resistance at high temperatures.
Even in a high temperature environment exceeding the vicinity, there is no oxidative consumption, and in this respect, the sealing characteristics can be secured for a long period of time. Further, the ring-shaped mesh spring 5 made of a knitted or woven metal thin wire has heat resistance,
Because of its high elasticity, it can be ensured even under high temperature conditions without reducing the tightening pressure of the main seal packing 4 by the packing holding member 6.

【0011】上記実施形態では主シールパッキン4及び
メッシュスプリング5を片側からのみパッキン押え部材
6で加圧する場合について説明したが、これに代えて、
図2に示すように主シールパッキン4及びメッシュスプ
リング5を両側よりパッキン押え部材6,6で加圧する
形態においても同様に適用できる。
In the above embodiment, the case where the main seal packing 4 and the mesh spring 5 are pressed by the packing pressing member 6 from only one side has been described.
As shown in FIG. 2, the present invention can be similarly applied to a mode in which the main seal packing 4 and the mesh spring 5 are pressed from both sides by the packing pressing members 6, 6.

【0012】本発明のマイカシートからなる主シールパ
ッキン4と金属細線からなるメッシュスプリング5との
組合わせによる下記の実施例と、膨張黒鉛パッキンによ
る下記の比較例の圧縮復元試験を実施した。
A compression restoring test was carried out in the following example using a combination of the main seal packing 4 made of a mica sheet and a mesh spring 5 made of a thin metal wire, and in the following comparative example using an expanded graphite packing.

【0013】(実施例)主シールパッキン4とメッシュ
スプリング5との組合わせによる実施品は、主シールパ
ッキン4がマイカシートを巻き重ねてリング状に加圧成
形されてなり(マイカリング)、メッシュスプリング5
が、SUS316の細線を編むか織ったのちリング状に
成形されてなり、これら2個の主シールパッキン4と2
個のメッシュスプリング5とを組合わせたリングの内径
寸法aは110mm、外径寸法bは124mm、軸方向長さ
(高さ)Hは20mm(1個の主シールパッキン4の軸方
向長さは7mm、1個のメッシュスプリング5の軸方向長
さは3mm)とするものである。
(Embodiment) The main seal packing 4 is combined with a mesh spring 5 to form a main seal packing 4 with a mica sheet wound thereon and formed into a ring-shaped pressure (mica ring). Spring 5
Is formed by knitting or weaving a fine wire of SUS316 and then forming it into a ring. These two main seal packings 4 and 2
The inner diameter a of the ring in which the mesh springs 5 are combined is 110 mm, the outer diameter b is 124 mm, the axial length (height) H is 20 mm (the axial length of one main seal packing 4 is 7 mm, and the length of one mesh spring 5 in the axial direction is 3 mm).

【0014】(比較例)比較例の膨張黒鉛パッキンは膨
張黒鉛をリング状に圧縮成形してなり、その内径寸法は
110mm、外径寸法は124mm、軸方向長さ(高さ)は
20mmとするものである。
(Comparative Example) The expanded graphite packing of the comparative example is formed by compression-molding expanded graphite into a ring shape. The inner diameter is 110 mm, the outer diameter is 124 mm, and the axial length (height) is 20 mm. Things.

【0015】上記実施例及び比較例の圧縮復元試験に用
いる装置には、図3にその概略断面図を示すように、ア
ムスラー式圧縮引張試験機が用いられ、試験治具(パッ
キン押え)10(内径110.5mm、外径123.5m
m) 、荷重変換器(締付圧記録)11、変位変換器(圧
縮量記録)12、動歪計13、及びX−Yレコーダ14
により構成される。
As shown in the schematic sectional view of FIG. 3, an Amsler type compression / tensile testing machine is used for the apparatus used for the compression restoring test of the above-mentioned embodiment and comparative example, and a test jig (packing presser) 10 ( 110.5mm inside diameter, 123.5m outside diameter
m), load transducer (tightening pressure record) 11, displacement transducer (compression amount record) 12, dynamic strain gauge 13, and XY recorder 14
It consists of.

【0016】上記装置を用いて下記の要領で圧縮復元試
験を実施した。試験方法は、室温下において、図3の試
験装置の試験治具10に上記実施品(主シールパッキン
(マイカリング)とメッシュスプリングの組合わせによ
るパッキン)T、または上記比較品(膨張黒鉛パッキ
ン)Pを組込み、それぞれを締付圧49.0MPa(5
00Kgf/cm2 )まで圧縮スピード約9.8MPa(10
0Kgf/cm2 )/min で締付け、その時の圧縮量を変位変
換器12で測定して、両者の締付圧と圧縮率の関係を対
比した。
A compression restoration test was performed using the above-described apparatus in the following manner. The test method is as follows. At room temperature, a test jig 10 of the test apparatus shown in FIG. 3 is mounted on a test jig 10 (packing obtained by combining a main seal packing (mica ring) and a mesh spring) T or a comparative product (expanded graphite packing) P, each having a tightening pressure of 49.0 MPa (5
Up to about 9.8 MPa (10 Kgf / cm 2 ).
Tighten 0Kgf / cm 2) / min, to measure the amount of compression when the displacement transducer 12, of comparing relationships compression ratio with both the tightening pressure.

【0017】パッキンの各締付圧時における圧縮率の試
験結果を図4に示す。この結果から、例えば締付圧が4
9.0MPa時における圧縮率は、実施例のものでは約
30%であり、これに対し比較例のものでは約20%で
あり、したがって実施例のものが比較例のものに比べて
流体漏洩の発生が著しく減少することになり、優れたシ
ール特性を確保することを確認できた。
FIG. 4 shows the test results of the compressibility at each tightening pressure of the packing. From this result, for example, when the tightening pressure is 4
The compression ratio at 9.0 MPa is about 30% in the example, whereas it is about 20% in the comparative example. Therefore, the example has a lower fluid leakage than the comparative example. The occurrence was remarkably reduced, and it was confirmed that excellent sealing characteristics were secured.

【0018】因みに、主シールパッキンであるマイカリ
ングと膨張黒鉛パッキンの熱減量試験の結果は図5に示
すとおりである。試験条件については、試験雰囲気は電
気炉内曝露加熱、試験時間は各温度にて1時間とする。
Incidentally, the results of the heat loss test of the mica ring as the main seal packing and the expanded graphite packing are as shown in FIG. Regarding the test conditions, the test atmosphere is an exposure heating in an electric furnace, and the test time is 1 hour at each temperature.

【0019】図5に示す熱減量試験の結果、膨張黒鉛パ
ッキンでは600゜Cを越えると酸化消耗が激しく熱減
量率が著しいが、マイカリングでは600゜C前後にお
いてもバインダー以外の質量減量は発生せず熱減量率は
著しく低く、450〜600゜を越える高温条件下でも
シール性を確保できることが判る。なお、本発明の高温
用配管継手のシール構造は回転軸や往復動軸の軸封部な
どにも同様に適用できることはいうまでもない。
As a result of the heat loss test shown in FIG. 5, when the expanded graphite packing exceeds 600 ° C., oxidative consumption is intense and the heat loss rate is remarkable, but in mica ring, weight loss other than the binder occurs even at around 600 ° C. It was found that the heat loss rate was extremely low, and the sealing property could be ensured even under a high temperature condition exceeding 450 to 600 °. Needless to say, the seal structure of the high temperature pipe joint of the present invention can be similarly applied to a shaft sealing portion of a rotating shaft or a reciprocating shaft.

【0020】[0020]

【発明の効果】本発明の高温用配管継手のシール構造に
よれば、高温での耐酸化性、弾力性に優れるマイカシー
トからなる主シールパッキンと、耐熱性、弾力性に富む
金属細線からなるメッシュスプリングとを組合わせてパ
ッキン室に装填してあるので、高温環境条件下でも好適
に使用でき、また熱膨張による配管の傾斜に対する追随
性にも優れてシール特性を確保することができ、しかも
構造が簡単で安価に提供できて有利である。
According to the seal structure for a high temperature pipe joint of the present invention, the main seal packing is made of a mica sheet having excellent oxidation resistance and elasticity at high temperatures, and a thin metal wire having excellent heat resistance and elasticity. Since it is loaded in the packing chamber in combination with the mesh spring, it can be used suitably even under high temperature environment conditions, and it has excellent followability to the inclination of the pipe due to thermal expansion, ensuring the sealing characteristics, and Advantageously, the structure is simple and can be provided at low cost.

【図面の簡単な説明】[Brief description of the drawings]

【図1】一実施例の高温用配管継手のシール構造の概略
断面図である。
FIG. 1 is a schematic sectional view of a seal structure of a high-temperature pipe joint according to an embodiment.

【図2】他の実施例の高温用配管継手のシール構造の概
略断面図である。
FIG. 2 is a schematic sectional view of a seal structure of a high-temperature pipe joint according to another embodiment.

【図3】圧縮復元試験装置の概略断面図である。FIG. 3 is a schematic sectional view of a compression recovery test apparatus.

【図4】実施品と比較品の圧縮復元試験結果を示す図表
である。
FIG. 4 is a table showing the results of a compression restoration test of an embodiment product and a comparative product.

【図5】マイカリングと膨張黒鉛パッキンの熱減量試験
結果を示す図表である。
FIG. 5 is a table showing the results of a heat loss test of mica ring and expanded graphite packing.

【符号の説明】[Explanation of symbols]

1 配管 2 配管貫通部 3 パッキン室 4 主シールパッキン 5 メッシュスプリング 6 パッキン押え部材 DESCRIPTION OF SYMBOLS 1 Piping 2 Piping penetration part 3 Packing room 4 Main seal packing 5 Mesh spring 6 Packing holding member

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 接続される配管の外径より大きい内径の
配管貫通部を有して、この配管貫通部内の配管の外周部
に円筒状にパッキン室を形成するとともに、このパッキ
ン室の軸方向の少なくとも片側にパッキン押え部材を備
えた高温用配管継手において、前記パッキン室に、マイ
カシートを巻き重ねてリング状に加圧成形した主シール
パッキンと、この主シールパッキンの軸方向両端に配さ
れる、金属細線を製編織したのちリング状に成形したメ
ッシュスプリングとを装填してあることを特徴とする高
温用配管継手のシール構造。
1. A piping chamber having an inner diameter larger than an outer diameter of a pipe to be connected, a packing chamber formed in a cylindrical shape on an outer peripheral portion of the pipe in the pipe penetrating section, and an axial direction of the packing chamber. In the high temperature pipe joint having a packing holding member on at least one side, a main seal packing formed by winding a mica sheet into a ring shape and forming a ring shape in the packing chamber, and disposed at both axial ends of the main seal packing. And a mesh spring formed by knitting and weaving a thin metal wire and then forming a ring shape.
【請求項2】 前記マイカシートが金マイカを80%以
上含むことを特徴とする請求項1記載の高温用配管継手
のシール構造。
2. The sealing structure for a high temperature pipe joint according to claim 1, wherein said mica sheet contains 80% or more of gold mica.
JP2001142843A 2001-05-14 2001-05-14 Seal structure for high-temperature pipe joints Expired - Fee Related JP3786587B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001142843A JP3786587B2 (en) 2001-05-14 2001-05-14 Seal structure for high-temperature pipe joints

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001142843A JP3786587B2 (en) 2001-05-14 2001-05-14 Seal structure for high-temperature pipe joints

Publications (2)

Publication Number Publication Date
JP2002340187A true JP2002340187A (en) 2002-11-27
JP3786587B2 JP3786587B2 (en) 2006-06-14

Family

ID=18989073

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001142843A Expired - Fee Related JP3786587B2 (en) 2001-05-14 2001-05-14 Seal structure for high-temperature pipe joints

Country Status (1)

Country Link
JP (1) JP3786587B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005330205A (en) * 2004-05-19 2005-12-02 Mitsubishi Chemicals Corp Method for producing (meth)acrolein or (meth)acrylic acid
CN103603952A (en) * 2013-11-29 2014-02-26 中国有色(沈阳)冶金机械有限公司 Rotary kiln riding wheel bearing set cooling water pipe sealing structure
CN111535402A (en) * 2020-04-25 2020-08-14 上海南汇压力容器厂有限公司 Diaphragm air pressure tank with joint sealing structure

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005330205A (en) * 2004-05-19 2005-12-02 Mitsubishi Chemicals Corp Method for producing (meth)acrolein or (meth)acrylic acid
US7868202B2 (en) 2004-05-19 2011-01-11 Mitsubishi Chemical Corporation Process for producing (meth)acrolein or (meth)acrylic acid
CN103603952A (en) * 2013-11-29 2014-02-26 中国有色(沈阳)冶金机械有限公司 Rotary kiln riding wheel bearing set cooling water pipe sealing structure
CN103603952B (en) * 2013-11-29 2015-11-18 中国有色(沈阳)冶金机械有限公司 A kind of supporting roller of rotary kiln bearing pack water-cooling tube sealing configuration
CN111535402A (en) * 2020-04-25 2020-08-14 上海南汇压力容器厂有限公司 Diaphragm air pressure tank with joint sealing structure
CN111535402B (en) * 2020-04-25 2021-03-26 上海南汇压力容器厂有限公司 Diaphragm air pressure tank with joint sealing structure

Also Published As

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