JP2002317337A - Combined filament yarn of different shrinkage and method for producing the same - Google Patents

Combined filament yarn of different shrinkage and method for producing the same

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Publication number
JP2002317337A
JP2002317337A JP2001120866A JP2001120866A JP2002317337A JP 2002317337 A JP2002317337 A JP 2002317337A JP 2001120866 A JP2001120866 A JP 2001120866A JP 2001120866 A JP2001120866 A JP 2001120866A JP 2002317337 A JP2002317337 A JP 2002317337A
Authority
JP
Japan
Prior art keywords
yarn
sea
island
uniform
shrinkage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001120866A
Other languages
Japanese (ja)
Inventor
Katsuyuki Kasaoka
勝行 笠岡
Nobuyoshi Miyasaka
信義 宮坂
Tomoo Mizumura
知雄 水村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Ltd
Original Assignee
Teijin Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teijin Ltd filed Critical Teijin Ltd
Priority to JP2001120866A priority Critical patent/JP2002317337A/en
Publication of JP2002317337A publication Critical patent/JP2002317337A/en
Pending legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To provide a combined filament yarn of different shrinkages capable of sufficiently readily opening and dispersing ultrafine yarns and suitable for obtaining a sueded fabric assuming a uniform surface appearance without a feeling of unevennessses. SOLUTION: This combined filament yarn of the different shrinkages comprises a low-shrinkable yarn which is a sea-island type thick and thin conjugated yarn having 8-72 number of filaments and comprising an island component having 0.04-0.70 dtex single filament fineness of the island component and 0.4-2.5% Uster evenness (U%) in <=1.5 thick/thin ratio and a highly-shrinkable yarn which is a uniform yarn having 1.5-7 dtex single filament fineness and 6-48 number of filaments without unevenness of thickness.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、開繊性に優れ、均
整な表面外観を呈するスエード調布帛を得るに好適なポ
リエステル混繊糸及びその製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a polyester mixed yarn suitable for obtaining a suede-like fabric having an excellent spreadability and exhibiting a uniform surface appearance, and a method for producing the same.

【0002】[0002]

【従来の技術】極細糸を用いて均整な表面外観を呈する
布帛を得ようとすると、極細糸が充分に開繊し、布帛表
面に凹凸を形成しないことが重要である。しかし、極細
糸はそのしなやかさからして、繊維同士が集束しやすい
性質を有するため、今日までその解決方法が未達のまま
であった。例えば特開平4−91249号公報には、わ
ざさわざ一方のマルチフイラメントを過剰供給しながら
混繊することにより、たるみやループを形成して引き揃
え斑、地割れ、イラツキ斑などの欠点解消を図っている
が、この方法では、混繊斑や形態斑が必然的に混在する
ため、極細糸を用いると均整のとれた表面外観を呈する
布帛を得ることは困難である。また特開平7−1024
36号公報には、開繊手段として極細マルチフイラメン
トに仮撚加工を施す方法が採用されているが、このよう
な方法では、フイラメントが本来有するタッチが消失し
て捲縮タッチとなるだけでなく、捲縮による表面乱れが
起こるという欠点を有する。さらに特開平7−1269
51号公報には、極細分割型複合糸と高収縮糸とを混繊
する方法が提案されているが、この方法では、極細糸の
性質はそのまま残るため、機械的に剥離又は溶剤で一方
成分を溶出して分割極細化後の極細糸は、従来と同様に
繊維同士が部分的に集束しやすく、均整な表面外観を呈
する布帛は得られない。
2. Description of the Related Art In order to obtain a fabric having a uniform surface appearance using ultrafine yarn, it is important that the ultrafine yarn is sufficiently opened and no irregularities are formed on the surface of the fabric. However, since the ultrafine yarn has a property that fibers are easily bundled due to its flexibility, the solution has not been achieved to date. For example, Japanese Unexamined Patent Publication No. Hei 4-91249 discloses a method in which a multifilament is excessively supplied while one fiber is mixed to form a slack or a loop, thereby eliminating defects such as uneven alignment, cracks in the ground, and uneven spots. However, in this method, mixed fiber spots and morphological spots are inevitably mixed, and it is difficult to obtain a fabric having a uniform surface appearance when using ultrafine yarn. Also, Japanese Patent Application Laid-Open No. 7-1024
In Japanese Patent No. 36, a method of performing false twisting on an ultra-fine multifilament is employed as a fiber opening means. In such a method, not only the touch originally possessed by the filament disappears, but also a crimped touch is obtained. However, there is a disadvantage that surface disorder due to crimping occurs. Further, JP-A-7-1269
No. 51 proposes a method of blending an ultrafine splitting composite yarn and a high shrinkage yarn. However, in this method, since the properties of the ultrafine yarn remain as they are, the one component is mechanically peeled off or separated with a solvent. As for the ultrafine yarn after eluted, the fibers are easily partially bundled as in the conventional method, and a fabric having an even surface appearance cannot be obtained.

【0003】[0003]

【発明が解決しようとする課題】本発明は、上記従来技
術を背景になされたもので、その目的は、極細糸が充分
開繊・分散しやすく、凹凸感のない均整な表面外観を呈
するスエード調性布帛を得るに好適な異収縮混繊糸及び
その製造方法を提供することにある。
SUMMARY OF THE INVENTION The present invention has been made on the background of the above-mentioned prior art, and has as its object to provide a suede in which an ultrafine yarn is easily spread and dispersed sufficiently and has a uniform surface appearance without unevenness. It is an object of the present invention to provide a different shrinkage mixed fiber suitable for obtaining a tough fabric and a method for producing the same.

【0004】[0004]

【課題を解決するための手段】本発明者らは、上記目的
を達成するため鋭意検討した結果、低収縮糸として微細
な太さ斑を有する海島型複合糸、高収縮糸として太さ斑
を有しない糸を混繊すれば、布帛となした後に海島型複
合糸の各島成分を極細糸となしても、その微細な太さ斑
により該極細糸の開繊・分散が向上するため、均整のと
れた表面外観を呈する布帛が得られることを知り、本発
明を完成するに至った。
Means for Solving the Problems The present inventors have conducted intensive studies to achieve the above object, and as a result, have found sea-island type composite yarn having fine unevenness in thickness as low shrinkage yarn and unevenness in thickness as high shrinkage yarn. If yarns having no fibers are mixed, even if each island component of the sea-island composite yarn is formed into an ultrafine yarn after being formed into a fabric, the spread and dispersion of the ultrafine yarn are improved due to the fine unevenness of the thickness, The inventors have learned that a fabric having a uniform surface appearance can be obtained, and have completed the present invention.

【0005】かくして、本発明によれば、「低収縮糸
が、フィラメント数8〜72本で、下記(1)〜(3)
を同時に満足する海島型太細複合糸であり、高収縮糸
が、単繊維繊度1.5〜7デシテックス、フイラメント
本数6〜48本の太さ斑を有しない均一糸であることを
特徴とする異収縮混繊糸。 (1)ウースターイブネス(U%)が0.4〜2.5% (2)島成分の太細比が1.5以下 (3)島成分の単繊度が0.04〜0.70デシテック
ス」 が提供され、また、「フィラメント数が8〜72本、自
然延伸倍率が1.8以下、伸度が120〜200%、島
成分繊度が0.042〜0.90デシテックスである海
島型複合糸を、温度80〜230℃で1.05〜1.3
5倍に延伸してウースターイブネス(U%)が0.4〜
2.5%の海島型太細複合低収縮糸となし、次いで、単
繊度が1.5〜7デシテックス、フイラメント数が6〜
48本の太さ斑を有しない均一高収縮糸と混繊すること
を特徴とする異収縮混繊糸の製造方法。」が提供され
る。
[0005] Thus, according to the present invention, "the low shrinkage yarn has 8 to 72 filaments and has the following (1) to (3)
The high-shrink yarn is a uniform yarn having a monofilament fineness of 1.5 to 7 dtex and a filament count of 6 to 48 and having no unevenness in thickness. Different shrinkage mixed fiber. (1) Worcester evenness (U%) is 0.4 to 2.5% (2) Thickness ratio of island component is 1.5 or less (3) Single fineness of island component is 0.04 to 0.70 decitex And "a sea-island composite having 8 to 72 filaments, a natural stretch ratio of 1.8 or less, an elongation of 120 to 200%, and an island component fineness of 0.042 to 0.90 decitex." The yarn is treated at a temperature of 80 to 230 ° C. and 1.05 to 1.3.
Stretched 5 times to make Worcester Evenness (U%) 0.4 ~
2.5% sea-island type thin composite low shrinkage yarn, followed by a single fineness of 1.5 to 7 dtex and a filament number of 6 to
A method for producing a different shrinkage mixed fiber yarn, comprising mixing 48 uniformly high shrinkage yarns having no thickness unevenness. Is provided.

【0006】[0006]

【発明の実施の形態】以下、本発明の実施の形態につい
て詳細に説明する。先ず、本発明の異収縮混繊糸を構成
する一方成分の低収縮糸は、海島型太細複合糸であり、
例えば後加工段階で海成分を溶解除去することにより、
島成分を極細糸にでき、該極細糸が繊維軸方向に太細斑
を有するものをいう。すなわち、繊維軸横断面形状とし
ては、易溶解性ポリマー中に、該溶剤(アルカリ水溶液
も含む)には溶解し難い難溶解性ポリマーが島状に分散
(繊維軸方向には実質的に連続)してる形態を有するも
のである。
Embodiments of the present invention will be described below in detail. First, the low shrinkage yarn of one component constituting the hetero-shrinkage mixed fiber yarn of the present invention is a sea-island type thick and thin composite yarn,
For example, by dissolving and removing sea components in the post-processing stage,
It means that the island component can be made into an ultrafine yarn, and the ultrafine yarn has thick and thin spots in the fiber axis direction. In other words, the cross-sectional shape of the fiber axis is such that the sparingly soluble polymer which is hardly dissolved in the solvent (including the alkaline aqueous solution) is dispersed in the easily soluble polymer in an island shape (substantially continuous in the fiber axis direction). It has the form of doing.

【0007】該複合糸を構成するポリマーの組合わせ
は、上記のとおり海成分と島成分とがある溶剤に対する
溶解性が異なり、島成分を極細糸として分割できる限り
どのような組合わせでもよい。なかでも、得られる織編
物等の風合や取扱い性などの観点から、島成分はエチレ
ンテレフタレートが95モル%以上のポリエチレンテレ
フタレート系ポリエステルが好ましく、海成分は5−ナ
トリウムスルホイソフタル酸、イソフタル酸、ポリエチ
レングリコール、ジエチレングリコール、アジピン酸、
シクロヘキサンジメタノール、テトラメチレングリコー
ル等を、前記ポリエチレンテレフタレート系ポリエステ
ルよりも易溶解性となる割合で共重合したポリエチレン
テレフタレート系ポリエステル、又は、ポリエチレング
リコール、ジカルボン酸成分とポリオキシアルキレング
リコール成分とからなるポリエーテルエステル等の重合
体をポリエチレンテレフタレート等のポリエステルに混
合して易溶解性としたポリエステル組成物が好ましい。
[0007] As described above, the combination of the polymers constituting the composite yarn may be any combination as long as the sea component and the island component have different solubilities in a certain solvent and the island component can be divided into ultrafine yarns. Above all, from the viewpoint of the feeling and handleability of the obtained woven or knitted fabric, the island component is preferably a polyethylene terephthalate-based polyester having ethylene terephthalate of 95 mol% or more, and the sea component is 5-sodium sulfoisophthalic acid, isophthalic acid, Polyethylene glycol, diethylene glycol, adipic acid,
Polyethylene terephthalate-based polyester obtained by copolymerizing cyclohexane dimethanol, tetramethylene glycol or the like at a ratio that makes it more soluble than the polyethylene terephthalate-based polyester, or polyethylene glycol, a polyoxyalkylene glycol component comprising a polycarboxylic acid component and a polyoxyalkylene glycol component A polyester composition which is easily soluble by mixing a polymer such as an ether ester with a polyester such as polyethylene terephthalate is preferred.

【0008】次に該海島型太細複合糸のウースターイブ
ネス(U%)は、前記海成分を除去する前に測定した時
の値であって、その値は0.4〜2.5%の範囲、好ま
しくは0.5〜1.5%の範囲とする必要がある。0.
4%未満の場合には、極細糸化した後の極細糸間の開繊
性が低下して本発明の目的とする均整な表面外観を呈す
る布帛を得ることができなるので好ましくない。一方、
2.5%を越える場合には、極細糸の太細斑が目立つよ
うになり、また布帛の凹凸感も大きくなり、均整な外観
が得られなくなるので好ましくない。
Next, the Worcester evenness (U%) of the sea-island type thick and thin composite yarn is a value measured before removing the sea component, and the value is 0.4 to 2.5%. , Preferably in the range of 0.5 to 1.5%. 0.
If it is less than 4%, the spreadability between the ultrafine yarns after the ultrafine yarn formation is reduced, and it is not possible to obtain a fabric having a uniform surface appearance which is the object of the present invention. on the other hand,
If it exceeds 2.5%, thick and fine spots of extra-fine yarn become conspicuous and the unevenness of the fabric becomes large, so that a uniform appearance cannot be obtained.

【0009】また、該極細糸の繊維軸方向の太細斑は、
直径比でいって1.5以下、好ましく1.3以下とする
必要があり、該比が1.5を超える場合には、太細間で
の光沢差が生じて筋斑が発生しやすくなり、均整性が損
なわれるので好ましくない。
[0009] The thick and thin spots in the fiber axis direction of the ultrafine yarn are as follows:
The diameter ratio needs to be 1.5 or less, preferably 1.3 or less, and when the ratio exceeds 1.5, a gloss difference between thick and thin is generated, so that streaks easily occur. This is not preferred because the uniformity is impaired.

【0010】また、該極細糸の単繊度は、0.04〜
0.70デシテックス、好ましくは0.05〜0.40
デシテックスの範囲である必要があり、0.04デシテ
ックス未満の場合には、本発明によっても極細糸間を開
繊させることは困難になり、均整な表面外観が得られな
くなるので好ましくない。一方、0.70デシテックス
を越える場合には、単繊維の開繊は十分できるが、スエ
ード調布帛を得ることができなくなる。なお、海島型複
合繊維中の島成分の島径は、繊維軸方向の太細斑を別に
すれば、すなわち、太部同士又は細部同士を比較する
と、その比は最大で1.5、好ましくは1.2以下、特
に好ましくはほぼ均一であることが、均整な表面外観を
得る上で好ましい。
The fineness of the ultrafine yarn is 0.04 to 0.04.
0.70 decitex, preferably 0.05-0.40
It is necessary to be in the range of decitex, and if it is less than 0.04 decitex, it is difficult to open the gap between the ultrafine yarns according to the present invention, and it is not preferable because a uniform surface appearance cannot be obtained. On the other hand, when it exceeds 0.70 decitex, it is possible to open the single fiber sufficiently, but it is not possible to obtain a suede-like fabric. In addition, the island diameter of the island component in the sea-island type conjugate fiber is 1.5 at the maximum, preferably 1.0 when the thick portion or the detail is compared, except for the thick and thin spots in the fiber axis direction. It is preferably 2 or less, particularly preferably substantially uniform, to obtain a uniform surface appearance.

【0011】なお、該海島型太細複合糸の伸度は、80
〜180%の範囲、特に100〜170%の範囲が好ま
しく、かかる複合糸では、海成分を溶解除去して得られ
る極細糸の配向が適度なので、該極細糸の機械的な特性
を維持しながらソフトなタッチに優れたスエード調布帛
が得られ好ましい。
The elongation of the sea-island type thick and thin composite yarn is 80
In the case of such a composite yarn, the orientation of the ultrafine yarn obtained by dissolving and removing the sea component is appropriate, so that the mechanical characteristics of the ultrafine yarn can be maintained. A suede-like fabric excellent in soft touch is obtained, which is preferable.

【0012】次に、本発明の異収縮混繊糸中の上記海島
型太細複合糸のフィラメント数は、多すぎても少なすぎ
ても後述する均一糸と混繊する際の均一混合性が低下す
るので、8〜72本、特に16〜60本の範囲とする必
要がある。
[0012] Next, whether the number of filaments of the sea-island type thick and thin composite yarn in the hetero-shrink mixed yarn of the present invention is too large or too small, the uniform mixing property at the time of blending with the uniform yarn described later is insufficient. Therefore, it is necessary to set the range to 8 to 72, especially 16 to 60.

【0013】本発明の異収縮混繊糸を構成するもう一方
の高収縮糸は、太さ斑を有しない均一糸であって、その
単繊度が1.5〜7.0デシテックス、好ましくは2.
0〜5.0デシテックスの範囲である必要がある。該高
収縮糸が太さ斑を有する場合では、該高収縮糸の斑に起
因して均整性が低下して本発明の目的を達成できなくな
る。なお、ここでいう太さ斑を有しないとは、通常のフ
ラットな太細を意識していないマルチフィラメントのこ
とであり、かかる通常のマルチフィラメントが有してい
る、ウースターイブネス(U%)でいって0.2%程度
以下の太さ斑を有していてもよいことは勿論である。
The other high shrinkage yarn constituting the hetero-shrinkage mixed fiber yarn of the present invention is a uniform yarn having no unevenness in thickness, and has a single fineness of 1.5 to 7.0 decitex, preferably 2 .
It must be in the range of 0-5.0 dtex. When the high shrinkage yarn has unevenness in thickness, the uniformity is reduced due to the unevenness of the high shrinkage yarn, and the object of the present invention cannot be achieved. The term "having no thickness unevenness" as used herein refers to a multifilament that is not conscious of a normal flat and thin shape, and has a Worcester evenness (U%) that the normal multifilament has. Needless to say, it may have a thickness unevenness of about 0.2% or less.

【0014】また該単繊度が1.5デシテックス未満の
場合には、混繊による繊維間の絡み合いが強くなりする
ため、前記複合糸を処理して形成される極細糸の開繊性
が低下し、均整な表面外観を呈する布帛を得ることがで
きなくなる。一方、7.0デシテックスを超える場合に
は、前記複合糸との混繊性が低下して混繊不良となり、
同じく均整な表面外観を呈する布帛を得ることができな
くなる。
When the single fineness is less than 1.5 decitex, the entanglement between the fibers due to the blending becomes strong, and the opening property of the ultrafine yarn formed by treating the composite yarn is reduced. Thus, it is not possible to obtain a fabric having a uniform surface appearance. On the other hand, when it exceeds 7.0 decitex, the fiber mixing property with the composite yarn is reduced and the fiber mixing becomes poor,
Similarly, a fabric having a uniform surface appearance cannot be obtained.

【0015】また該均一糸のフイラメント数は6〜48
本、好ましくは12〜36本の範囲とする必要があり、
該本数が6本未満では、海島型太細複合糸の各フイラメ
ントを分散する効果は少なくなり、逆に48本を超える
場合には、絡み部分が多くなりすぎ、それが原因でブロ
ック状の形態が所々に形成されるため、均整な表面外観
が得られなくなる。なお、海島型太細複合糸と均一糸と
の合計のフィラメント数は、あまりに多くなると混繊乱
れにより一部フイラメントが乱れて均整な表面外観を呈
さなくなるので、120本以下、好ましくは72本以下
とし、また海島型太細複合糸のフイラメント数を均一糸
のフイラメント数の4倍以下、好ましくは3.5倍以下
とするのが望ましい。
The number of filaments of the uniform yarn is 6 to 48.
Book, preferably in the range of 12 to 36,
When the number is less than 6, the effect of dispersing the filaments of the sea-island type thick and thin composite yarn is reduced, and when the number is more than 48, the entangled portion becomes too large, which results in a block-like form. Are formed in places, so that a uniform surface appearance cannot be obtained. In addition, the total number of filaments of the sea-island type thick and thin composite yarn and the uniform yarn is 120 or less, preferably 72 or less, because if it is too large, some filaments will be disturbed due to mixed fiber disorder and will not exhibit a uniform surface appearance. In addition, it is desirable that the number of filaments of the sea-island type thick and thin composite yarn is 4 times or less, preferably 3.5 times or less of the number of filaments of the uniform yarn.

【0016】かかる高収縮糸を構成するポリマーは、前
記低収縮糸よりも熱収縮率が高ければ、例えば沸水収縮
率でいって好ましくは5%以上大きければ特に限定する
必要はないが、得られる布帛の風合からポリエステル、
特に第3成分を共重合させたポリエチレンテレフタレー
トが好ましい。勿論、該ポリエステルは、前記海島型太
細複合糸の海成分に好ましく使用されるポリエステルと
比較して難溶解性である必要があることは改めていうま
でもない。好ましく用いられる第3成分としては、イソ
フタル酸、ビスフェノールA及びそのエチレンオキサイ
ド付加体、ネオペンチルグリコールなどをあげることが
できるが、その共重合量は、高収縮特性を発揮する上で
は通常2モル%以上であり、上限は得られる布帛の風合
や機械的特性の点から通常は20モル%以下である。
The polymer constituting such a high shrinkage yarn is obtained as long as the heat shrinkage is higher than that of the low shrinkage yarn, for example, the boiling water shrinkage is preferably not less than 5%, although there is no particular limitation. Polyester from the texture of the fabric,
Particularly, polyethylene terephthalate obtained by copolymerizing the third component is preferable. Of course, it is needless to say that the polyester needs to be less soluble than the polyester preferably used for the sea component of the sea-island type thick and thin composite yarn. Preferred examples of the third component include isophthalic acid, bisphenol A and its ethylene oxide adduct, neopentyl glycol, and the like. The copolymerization amount is usually 2 mol% in order to exhibit high shrinkage characteristics. The upper limit is usually 20 mol% or less from the viewpoint of the feeling and mechanical properties of the obtained fabric.

【0017】次に、以上に説明した異収縮混繊糸を製造
するための好ましい方法について説明する。まず、易溶
解性ポリマーを海成分、それより溶解速度の遅いポリマ
ーを島成分として複合紡糸して得た、フィラメント数が
8〜72本、好ましくは12〜60本、自然延伸倍率が
1.8以下、好ましくは1.2〜1.6、伸度が120
〜200%、好ましくは130〜180%、さらに島成
分の単繊度が0.042〜0.90デシテックス、好ま
しくは0.05〜0.40デシテックスの海島型複合未
延伸糸を用いる。
Next, a preferred method for producing the above-described hetero-shrinkage mixed fiber yarn will be described. First, the number of filaments was 8 to 72, preferably 12 to 60, and the natural stretching ratio was 1.8, which was obtained by compound spinning using a readily soluble polymer as a sea component and a polymer having a slower dissolution rate as an island component. Below, preferably 1.2 to 1.6, elongation is 120
A sea-island composite undrawn yarn having a single fineness of 0.042 to 0.90 dtex, preferably 0.05 to 0.40 dtex, is used.

【0018】ここで外未延伸糸の伸度が120%未満の
場合には、後述する斑延伸を施こそうとしても島成分に
太細斑を形成することができなくなり、溶解処理により
形成される極細糸の開繊性が不十分となる。一方200
%を超える場合には、該斑延伸により発現されるウース
ターイブネス(U%)が大きくなりすぎ、極細糸の太細
斑が目立つようになり、また布帛の凹凸感も大きくな
り、均整な外観が得られなくなるので好ましくない。
If the elongation of the outer unstretched yarn is less than 120%, thick and thin spots cannot be formed on the island component even when the spot stretching described below is performed, and the yarn is formed by dissolution treatment. The opening property of the ultrafine yarn becomes insufficient. 200
%, The Worcester evenness (U%) expressed by the mottling stretching becomes too large, the fine mottling of extra-fine yarn becomes conspicuous, and the unevenness of the fabric also increases, resulting in a uniform appearance. Is not preferred because it is no longer possible to obtain

【0019】次に、未延伸糸の自然延伸倍率は高い程、
斑を形成させるための延伸に幅が大きくなって多種多様
な斑形成が可能となるが、逆に異常延伸斑が発生しやす
くなる。この延伸斑は、自然延伸倍率が小さいほど発生
し難くなるが、逆に小さくなると本発明の目的とする太
細を形成する際の安定性が低下するので、本発明におい
ては、自然延伸倍率は1.8以下が必要であり、好まし
くは1.2〜1.6倍の範囲とする。この範囲であれ
ば、次に述べる斑延伸により、本発明にかかる海島太細
複合糸を得ることができる。
Next, the higher the natural drawing ratio of the undrawn yarn, the more
The width of the stretching for forming the spots increases, and a wide variety of spots can be formed. On the contrary, abnormal stretching spots are likely to occur. This stretch unevenness is less likely to occur as the natural stretch ratio is smaller, but conversely, if it is smaller, the stability at the time of forming the thin and thick object aimed at in the present invention is reduced, so in the present invention, the natural stretch ratio is 1.8 or less is required, and it is preferably in the range of 1.2 to 1.6 times. Within this range, the sea-island thick and thin composite yarn according to the present invention can be obtained by spot stretching described below.

【0020】本発明においては、上記未延伸糸を温度8
0〜230℃、好ましくは110〜210℃で1.05
〜1.35倍、好ましくは1.10〜1.25倍に延伸
(斑延伸)してウースターイブネス(U%)が0.4〜
2.5%の海島型太細複合糸となす。ここで延伸温度が
80℃未満の場合には、不規則な斑が発生しやすいだけ
でなくウースターイブネスが大きくなりすぎるので好ま
しくない。一方230℃を超える場合には過熱されて安
定に延伸することが困難になるので好ましくない。
In the present invention, the undrawn yarn is treated at a temperature of 8
0 to 230 ° C, preferably 1.05 to 110 to 210 ° C.
Stretched to 1.35 times, preferably 1.10 to 1.25 times (spot stretching) to give a Worcester evenness (U%) of 0.4 to
A 2.5% sea-island type thick and thin composite yarn is formed. Here, when the stretching temperature is lower than 80 ° C., not only irregular spots are liable to be generated but also the Worcester evenness becomes too large, which is not preferable. On the other hand, when the temperature is higher than 230 ° C., it is not preferable because it is difficult to stretch stably due to overheating.

【0021】延伸中の糸が受ける温度は、加熱体の温度
と一致するように熱処理時間の調整をすることが好まし
く、該調整ができれば、接触タイプだけでなく、非接触
タイプの加熱体をも使用することができる。なお、非接
触タイプの加熱体で延伸を行なう際には、予め加熱ロー
ラに数ターンさせて十分に予熱した(加熱ローラ温度は
90℃〜130℃が好ましい)後、非接触加熱体での延
伸を行なうことが好ましく、単に非接触加熱体のみで延
伸しようとすると、延伸斑が発生しやすくなる。より好
ましい延伸方法は、加熱ローラと加熱プレート(接触)
との併用であって、この際も、加熱ローラ温度は90℃
以上が好ましく、加熱プレート温度は加熱プレート単独
使いの際よりも低くするのがよい。
It is preferable to adjust the heat treatment time so that the temperature applied to the yarn being drawn matches the temperature of the heating element. If the adjustment can be performed, not only the contact type heating element but also the non-contact type heating element can be used. Can be used. When stretching is performed with a non-contact heating body, the heating roller is preliminarily heated by making several turns on a heating roller (the heating roller temperature is preferably 90 ° C. to 130 ° C.). It is preferable to perform the stretching, and if the stretching is performed only by the non-contact heating body, stretching unevenness is likely to occur. A more preferred stretching method is a heating roller and a heating plate (contact)
In this case, the heating roller temperature is 90 ° C.
Preferably, the heating plate temperature is lower than when the heating plate is used alone.

【0022】次に延伸倍率は、1.05倍未満では島成
分(極細糸)に太細を形成することができなくなり、一
方1.35倍を超える場合には斑がハッキリしすぎてウ
ースターイブネス(U%)が2.5%を超えるようにな
るので好ましくない。
If the draw ratio is less than 1.05, thick and thin island components (extremely thin yarns) cannot be formed. If the draw ratio is more than 1.35, the spots become too clear to make the wool eve. Ness (U%) is not preferable because it exceeds 2.5%.

【0023】以上に述べた方法により得られた海島型太
細複合糸は、常法により製造された単繊度が1.5〜
7.0デシテックス、フイラメント数が6〜48本の太
さ斑を有しない均一高収縮糸と混繊して異収縮混繊糸と
なす。混繊方法は、従来公知の方法を採用すればよく、
例えばインタレースノズルを用いるのが一般的であり好
ましい。
The sea-island type thick and thin composite yarn obtained by the above-described method has a single fineness of 1.5 to 1.5 produced by a conventional method.
The fibers are mixed with a uniform high shrinkage yarn having a thickness of 6 to 48 and having no unevenness in filaments to form a different shrinkage mixed yarn. As the fiber mixing method, a conventionally known method may be adopted,
For example, it is general and preferable to use an interlace nozzle.

【0024】以下、図面に基づいてさらに具体的に説明
する。図2は、本発明の異収縮混繊糸の製造工程の一概
略図である。図において、海島型複合未延伸糸(1)を
製造工程のクリルスタンドに、一方太さ斑を有しない均
一糸(2)を別のクリルスタンドに配置する。海島型複
合未延伸糸をコツトローラ(3)に通し、供給ローラ
(4)に数ターンさせ、その間の糸張力は延伸を加えな
い程度に張った状態として走行させ、加熱プレート
(5)に接触させた後、段付ローラ(6)大径ローラ間
で斑延伸と熱処理を同時に行い小ローラに入る手前でイ
ンターレースノズル(7)に導くが、その際、均一糸も
段付きローラの大径ローラに導き数ターン後、該ノズル
(7)の手前で両糸を引き揃え、ノズルに圧搾空気を供
給して混繊した後、小径ローラに数ターンして異収縮混
繊糸(8)として巻き取る。
Hereinafter, a more specific description will be given with reference to the drawings. FIG. 2 is a schematic view of a process for producing a different shrinkage mixed fiber of the present invention. In the figure, the sea-island composite undrawn yarn (1) is placed on a krill stand in the manufacturing process, and the uniform yarn (2) having no thickness unevenness is placed on another krill stand. The sea-island composite undrawn yarn is passed through a cott roller (3) and made to turn several times on a supply roller (4). After that, uneven stretching and heat treatment are performed simultaneously between the large-diameter rollers with the stepped roller (6), and the uneven yarn is guided to the interlace nozzle (7) before entering the small roller. After a few turns of guiding, the two yarns are aligned in front of the nozzle (7), compressed air is supplied to the nozzle, and the fibers are mixed. .

【0025】図3は、本発明の異収縮混繊糸を製造する
ための別の工程概略図である。ここでは、海島型複合未
延伸糸(1−1)をクリルスタンドに、一方均一糸(2
−1)は別のクリルスタンドに配置する。海島型複合未
延伸糸をコツトローラ(3−1)に通し、加熱ローラ
(4−1)に数ターンさせ、その間の糸張力は延伸を加
えない程度に張った状態として走行させ、非接触加熱体
(5−1)に通した後、段付ローラ(6−1)大径ロー
ラ間で斑延伸と熱処理を同時に行い小ローラに入る手前
でインターレースノズル(7−1)に導くが、その際、
均一糸も段付きローラの大径ローラに導き数ターン後、
該ノズル(7−1)の手前で両糸を引き揃え、ノズルに
圧搾空気を供給して混繊した後、小径ローラに数ターン
して異収縮混繊糸(8−1)として巻き取る。
FIG. 3 is a schematic view showing another process for producing the different shrinkage mixed fiber of the present invention. Here, the sea-island composite undrawn yarn (1-1) is set on the krill stand, while the uniform yarn (2
-1) is placed on another krill stand. The non-stretched sea-island composite yarn is passed through a cott roller (3-1) and is turned several times on a heating roller (4-1). After passing through (5-1), uneven stretching and heat treatment are simultaneously performed between the large-diameter rollers with the stepped roller (6-1), and are guided to the interlace nozzle (7-1) before entering the small roller.
The uniform yarn is also guided to the large-diameter roller of the stepped roller, and after several turns,
Before the nozzle (7-1), the two yarns are aligned and compressed air is supplied to the nozzle to mix the fibers. Then, the yarn is wound several times on a small-diameter roller to form a differently shrink mixed yarn (8-1).

【0026】また図4は、本発明の異収縮混繊糸を製造
するための別の工程の概略図である。ここで、海島型複
合未延伸糸(1−2)をクリルスタンドに、一方均一糸
(2−2)を別のクリルスタンドに配置する。海島型複
合未延伸糸をコツトローラ(3−2)に通し、加熱ロー
ラ(4−2)に数ターンさせ、その間の糸張力は延伸を
加えない程度に張った状態として走行させ、加熱プレー
ト(5−2)に通した後、段付ローラ(6−2)大径ロ
ーラ間で斑延伸と熱処理を同時に行い小ローラに入る手
前でインターレースノズル(7−2)に導くが、その
際、均一糸も段付きローラの大径ローラに導き数ターン
後、該ノズル(7−2)の手前で両糸を引き揃え、ノズ
ルに圧搾空気を供給して混繊した後、小径ローラに数タ
ーンして異収縮混繊糸(8−2)として巻き取る。
FIG. 4 is a schematic view of another process for producing the hetero-shrinkage mixed fiber yarn of the present invention. Here, the sea-island composite undrawn yarn (1-2) is placed on a krill stand, while the uniform yarn (2-2) is placed on another krill stand. The unstretched sea-island composite yarn is passed through a cott roller (3-2) and made to turn on a heating roller (4-2) for a few turns. -2), uneven stretching and heat treatment are performed simultaneously between the large-diameter rollers with the stepped roller (6-2), and the roller is guided to the interlace nozzle (7-2) before entering the small roller. After a few turns, the yarn is guided to the large-diameter roller of the stepped roller, the two yarns are aligned before the nozzle (7-2), compressed air is supplied to the nozzle and mixed, and then several turns to the small-diameter roller. It winds up as a different shrinkage mixed fiber (8-2).

【0027】[0027]

【実施例】以下、実施例をあげて本発明をさらに具体的
に説明する。なお、実施例中の各測定項目は下記の方法
で測定した。
EXAMPLES The present invention will be described below more specifically with reference to examples. In addition, each measurement item in an Example was measured by the following method.

【0028】ウースターイブネス(U%) 日本計測器工業製のウースターイブネス(U%)測定機
を用い、糸速度100m/分、ハーフイナート、仮撚り
数5500回/分にて測定した。
Worcester Evenness (U%) Using a Worcester Evenness (U%) measuring machine manufactured by Nippon Keiso Co., Ltd., the measurement was performed at a yarn speed of 100 m / min, half inert, and a false twist number of 5,500 times / min.

【0029】沸水収縮率 試料を枠周1.125mの検尺機を用いて、10回の綛
を作り、0.0177cN/dtex(0.02g/d
e)の荷重を綛にかけて綛カセ長L0を測り、次に荷重
をはずして、98℃の温水中に30分浸漬した後、取り
出し、和紙で水分を切り水平状態で自然乾燥し、再び前
記荷重をかけて綛長L1を測り、次式より沸水収縮率
(%)を算出した。 沸水収縮率(%)=((L0−L1)/L0)×100
Boiling water shrinkage ratio The sample was skeined 10 times using a measuring machine having a frame circumference of 1.125 m, and was subjected to 0.0177 cN / dtex (0.02 g / d
e) Load the skein with a skein and measure the skein length L 0 , then remove the load, immerse in 98 ° C. warm water for 30 minutes, take out, cut off moisture with Japanese paper, air dry in a horizontal state, and again measure the skein length L 1 under a load was calculated boiling water shrinkage from the following formula (%). Boiling water shrinkage (%) = ((L 0 −L 1 ) / L 0 ) × 100

【0030】島成分(極細糸)の太細比 海島型太細複合糸を構成する全フイラメントをアルカリ
溶液で処理して海成分を完全に溶解して極細糸(島成
分)のみとし、任意の極細糸について光学顕微鏡で太部
と細部の直径を測定し、その比を算出(n10の平均)
した。なお、島成分の繊度分布については、斑延伸する
前の複合糸について、全フイラメントをアルカリ溶液で
処理して海成分を完全に溶解して極細糸(島成分)のみ
とし、パラフインに包埋し、ミクロトームにて切片をつ
くる。これを光学顕微鏡にて測定し、個々の断面直径を
測り、最大直径と最小直径を選びだす。この作業を初め
から5回繰り返し、5回中の最大直径と最小直径を夫々
さらに抽出し、その最大直径を最小直径で割って繊度分
布とした。
Thickness ratio of island component (ultrafine yarn) All the filaments constituting the sea-island type thick composite yarn are treated with an alkaline solution to completely dissolve the sea component to make only the ultrafine yarn (island component). The diameter of the thick part and the fine part is measured with an optical microscope for the ultrafine yarn, and the ratio is calculated (average of n10).
did. Regarding the fineness distribution of the island component, for the composite yarn before spot drawing, all the filaments were treated with an alkaline solution to completely dissolve the sea component, leaving only the ultrafine yarn (island component) and embedding in paraffin. Make sections with a microtome. This is measured with an optical microscope, the diameter of each cross section is measured, and the maximum diameter and the minimum diameter are selected. This operation was repeated five times from the beginning, and the maximum diameter and the minimum diameter of the five times were further extracted, respectively, and the maximum diameter was divided by the minimum diameter to obtain a fineness distribution.

【0031】[実施例1]海島型複合糸の島成分として、
酸化チタン0.3wt%含有のポリエチレンテレフタレ
ート(固有粘度0.63)、易溶解性の海成分として5
−ナトリウムスルホイソフタルル酸1.5モル%とポリ
エチレングリコール(分子量4000)1.5wt%と
を共重合したポリエチレンテレフタレート(固有粘度
0.63)に、ポリエチレングリコール分子量2000
0を4wt%と水溶性ボリエーテルエステル(フタル酸
・ポリエチレングリコール(分子量20000)の重合
体、分子量15万)とを4wt%ブレンしたものを用
い、通常の複合紡糸口金から島及び海成分を同時紡糸し
て図1に示す断面形状の海島型複合未延伸糸を得た。そ
の際の紡糸温度は290℃、紡糸速度は3000m/分
で、総繊度は133dtex、フイラメント数は36
本、1フィラメント中の島数は25、島成分の重量割合
は65%(島成分の単繊度は0.10デシテックス)、
海成分35%、引張切断伸度160%、自然延伸倍率
1.6倍の未延伸糸を得た。
Example 1 As an island component of a sea-island type composite yarn,
Polyethylene terephthalate (intrinsic viscosity: 0.63) containing 0.3 wt% of titanium oxide, 5 as an easily soluble sea component
-Polyethylene terephthalate (intrinsic viscosity 0.63) obtained by copolymerizing 1.5 mol% of sodium sulfoisophthalic acid and 1.5 wt% of polyethylene glycol (molecular weight 4000), and polyethylene glycol molecular weight 2000
0 and 4 wt% of a water-soluble polyetherester (a polymer of phthalic acid / polyethylene glycol (molecular weight: 20,000), molecular weight: 150,000) are blended, and the island and sea components are simultaneously fed from a normal composite spinneret. Spinning was performed to obtain a sea-island composite undrawn yarn having a cross-sectional shape shown in FIG. At this time, the spinning temperature was 290 ° C., the spinning speed was 3000 m / min, the total fineness was 133 dtex, and the number of filaments was 36.
The number of islands in this filament was 25, the weight ratio of the island component was 65% (the single fineness of the island component was 0.10 decitex),
An undrawn yarn having a sea component of 35%, a tensile elongation at break of 160%, and a natural draw ratio of 1.6 was obtained.

【0032】この複合未延伸糸を、図2に示す製造工程
に掛け、その際の延伸条件としては、供給ローラと段付
きローラ間の延伸倍率は1.15倍、加熱プレート(ヒ
ーター長36cm)温度は200℃、延伸速度400m
/分で斑延伸を行った。一方均一糸用として、イソフタ
ル酸を10モル%共重合したボリエチレンテレフタレー
トを紡糸温度280℃、紡糸速度1450m/分で紡糸
した未延伸糸を87℃の加熱ローラに6ターンし延伸ロ
ーラ温度120℃に3ターン巻きつけて、3倍に延伸し
て得た、沸水収縮率が15%、55dtex/12フィ
ラメントの高収縮均一糸を用いた。
The composite undrawn yarn is subjected to the manufacturing process shown in FIG. 2, and the drawing conditions are as follows: the drawing ratio between the supply roller and the stepped roller is 1.15 times, and the heating plate (heater length is 36 cm). Temperature is 200 ° C and stretching speed is 400m
/ Min. On the other hand, for a uniform yarn, undrawn yarn obtained by spinning polyethylene terephthalate obtained by copolymerizing 10% by mole of isophthalic acid at a spinning temperature of 280 ° C. and a spinning speed of 1450 m / min is turned 6 times on a heating roller at 87 ° C., and a drawing roller temperature of 120 ° C. And a three-fold stretch, and a high shrinkage uniform yarn having a boiling water shrinkage of 15% and 55 dtex / 12 filaments was used.

【0033】両糸を段付きローラ上で引き揃え、同工程
のインターレースノズルを用いて圧搾空気圧力196k
Pa(2kg/cm2)、弛緩率2%で混繊し172d
tex/48フィラメント(155de/48フィラメ
ント)の異収縮混繊糸を得た。なお、海島型複合未延伸
糸を単独で上記条件と同一で斑延伸して物性をみると、
117dtex(105で)/36フィラメント、伸度
110%、U%が0.6%で島成分の太細直径比は1.
3であった。
Both yarns are aligned on a stepped roller, and compressed air pressure of 196 k using the interlace nozzle of the same process.
172d after mixing at Pa (2kg / cm 2 ) and 2% relaxation
A tex / 48 filament (155 de / 48 filament) hetero-shrink mixed fiber was obtained. In addition, when the sea-island composite undrawn yarn is stretched independently under the same conditions as above, and the physical properties are observed,
117 dtex (at 105) / 36 filaments, elongation 110%, U% 0.6%, ratio of small to large diameter of island component is 1.
It was 3.

【0034】この混繊糸を経糸及び緯糸に用い、経糸に
は600回のS撚り、緯糸には1000回のSZ撚りを
施して綾変化組織で製織した。得られた生機は100℃
の温水で精錬処理した後、中和しプレセットとしてピン
テンター装置を用いて経方向に1%緯(幅)方向に5%
の弛緩率で180℃下30秒乾熱セットした。次いで、
90℃の35g/リッターの水酸化ナトリウム水溶液で
30%減量加工して海成分を溶解し、島成分を極細糸と
して分割した後、通常の高圧染色(130℃45分)
で、ベイジュ色に染色した。染色前後の織物の収縮率は
経方向3%、緯(幅)方向5%の収縮率であり、この収
縮は均一糸の収縮力によるもので、該均一糸は織物内層
部に位置して表面からは観察することは困難であった。
その後風乾させ、ファイナルセットとして160℃1分
乾熱でセットして、織物を仕上た。織物目付は220g
/m2、仕上り織密度は経288本/25.4mm、緯
155本/25.4mmであつた。織物は均整な表面外
観を呈し、極細糸は集団で密着することなく、開繊効果
も十分なスエード調の織物にしあがった。追加加工とし
て、織物をバフ加工(400番のサンドペーパを回転シ
ャフトに巻きつけ、その表面上にかすかに接触するよ
う、織物表面を移動しながら、繊維を切断し毛羽とす
る)することにより、均整でよりソフトな風合に仕上が
った。
The blended yarn was used as a warp and a weft, and the warp was S-twisted 600 times and the weft was SZ-twisted 1000 times, and woven with a twill change structure. The obtained greige is 100 ° C
1% in the longitudinal direction and 5% in the weft (width) direction using a pin tenter device as a preset
At 180 ° C. for 30 seconds. Then
After reducing the weight of the sea component by 30% with a 35 g / liter sodium hydroxide aqueous solution at 90 ° C. to dissolve the sea component and dividing the island component into ultrafine yarn, ordinary high-pressure dyeing (130 ° C. for 45 minutes)
With a beige color. The shrinkage ratio of the woven fabric before and after dyeing is 3% in the warp direction and 5% in the weft (width) direction, and this shrinkage is due to the shrinkage force of the uniform yarn. Was difficult to observe.
Thereafter, the fabric was air-dried and set as a final set by drying at 160 ° C. for 1 minute to finish the fabric. 220g fabric weight
/ M 2, the finished weave density was 288 warps / 25.4 mm, weft 155 warps / 25.4 mm. The woven fabric exhibited a uniform surface appearance, and the ultrafine yarn did not adhere to the group as a whole, resulting in a suede-like woven fabric having a sufficient opening effect. As an additional process, the fabric is buffed (winding a # 400 sandpaper around a rotating shaft and cutting the fibers to make fluff while moving the fabric surface so as to make slight contact on the surface), thereby smoothing the fabric. The result is a softer texture.

【0035】[実施例2]実施例1に用いた海島型複合
未延伸糸と均一糸とを図3に示す装置を用い、加熱ロー
ラ温度120℃、延伸倍率は実施例1と同じ1.15
倍、非接触加熱体(スリットタイプ)は温度220℃と
した他は、実施例1と同じ条件で異収縮混繊糸を得た。
海島型複合糸単独で、上記条件と同一で延伸して物性を
見てみると117dtex(105de)/36フィラ
メント、伸度は115%、U%は0.5%、島成分の太
細比は1.2であった。
Example 2 The sea-island composite undrawn yarn and the uniform yarn used in Example 1 were heated using the apparatus shown in FIG. 3 at a heating roller temperature of 120 ° C. and a draw ratio of 1.15 as in Example 1.
A non-shrinkable mixed fiber was obtained under the same conditions as in Example 1 except that the temperature of the non-contact heating element (slit type) was 220 ° C.
When the sea-island composite yarn alone is drawn under the same conditions as above and the physical properties are examined, 117 dtex (105 de) / 36 filaments, elongation is 115%, U% is 0.5%, and the thickness ratio of the island component is 1.2.

【0036】この混繊糸を実施例1と同じ方法で製織染
色仕上を行い、製品に仕上た。織物目付230g/
2、仕上織密度は経229本/25.4mm、緯15
7本/25.4mmとほぼ実施例1同等の製品であっ
た。織物は均整な表面外観を呈し、極細糸が集団で密着
することなく、開繊効果も十分なスエード調の織物にし
あがった。追加加工として、織物をバフ加工(400番
のサンドペーパを回転シャフトに巻きつけ、その表面上
にかすかに接触するよう、織物表面を移動しながら、繊
維を切断し毛羽とする)することにより、均整でよりソ
フトな風合いに仕上がった。
The mixed fiber was subjected to weaving and dyeing in the same manner as in Example 1 to obtain a finished product. Fabric weight 230g /
m 2 , the finish weave density is 229 warps / 25.4 mm, weft 15
7 pieces / 25.4 mm, which is almost the same as Example 1. The woven fabric exhibited an even surface appearance, and the fine fibers did not adhere to each other in a group. As an additional process, the fabric is buffed (winding a # 400 sandpaper around a rotating shaft and cutting the fibers to make fluff while moving the fabric surface so as to make slight contact on the surface), thereby smoothing the fabric. The result is a softer texture.

【0037】[比較例1]実施例1と同等の紡糸方法
で、海島型複合未延伸糸として総繊度133dtex
(120de)、フイラメント数36本、島数25、島
成分重量割合65%、海成分35%、引張り切断伸度1
60%、自然延伸倍率1.6倍の未延伸糸を得た。この
未延伸糸を実施例1同様の第2図に示す装置を用い、加
熱プレート70℃として1.15倍に延伸して117d
tex(105de)/36フィラメント、U%3.0
%の太細糸としたところで、実施例1と同じ均一糸を同
様に混繊して、172detx(155de)/48フ
ィラメントの異収縮混繊糸を得た。
Comparative Example 1 The same spinning method as in Example 1 was used to obtain a sea-island composite undrawn yarn having a total fineness of 133 dtex.
(120de), 36 filaments, 25 islands, 65% island component weight ratio, 35% sea component, 1 tensile elongation at break
An undrawn yarn having a draw ratio of 60% and a natural draw ratio of 1.6 was obtained. This unstretched yarn was stretched 1.15 times using a device shown in FIG.
tex (105 de) / 36 filament, U% 3.0
%, The same uniform yarn as in Example 1 was mixed in the same manner to obtain a 172 detx (155 de) / 48 filament hetero-shrink mixed yarn.

【0038】この混繊糸を、経糸・緯糸に用い、経糸に
600回のS撚り、緯糸に1000回のSZ撚りを施し
て綾変化組織で製織した。得られた生機は実施例1と同
様の方法で染色仕上げを行い織物を得た。織物の表面は
凸凹外観をしており、けっして均整といえる表面外観で
はく、拡大観察してみると、部分的に極細糸が集束密着
しあって開繊した部分との形態差が凹凸を形成してい
た。
This mixed yarn was used for warp and weft, and the warp was twisted 600 times in S and the weft 1000 times in SZ, and woven in a twill change structure. The obtained green fabric was dyed and finished in the same manner as in Example 1 to obtain a woven fabric. The surface of the woven fabric has an uneven appearance, and it cannot be said to be a uniform surface appearance. Was.

【0039】[比較例2]実施例1同じ口金、ポリマー
を用い、同じ紡糸方法により198dtex(178d
e)/36フィラメントの海島型複合未延伸糸を得、次
いで延伸倍率1.7倍、加熱プレート160℃で延伸し
てU%が0.2%の太細斑のでない延伸を施して117
dtex(105de)/36フィラメントの海島型複
合糸を得た。この複合糸を実施例1と同じ均一糸と、実
施例1と同様にして混繊し、172dtex(155d
e)/48フィラメントの混繊糸となした。以下実施例
1と同様にして織物を仕上たが、得られた織物は極細糸
が所々集束しあい、筆先のような形態部が各所に点在し
て、けっして均整とは言えるものではなかった。
Comparative Example 2 Example 1 The same spinneret and polymer were used, and 198 dtex (178 d
e) A sea-island composite undrawn yarn of / 36 filaments was obtained, and then drawn at a draw ratio of 1.7 times on a heating plate at 160 ° C. to give a drawing with a U% of 0.2% without thick and thin spots.
A sea-island composite yarn of dtex (105 de) / 36 filament was obtained. This composite yarn was blended with the same uniform yarn as in Example 1 in the same manner as in Example 1, and 172 dtex (155 d
e) It was made into a mixed fiber of / 48 filaments. Thereafter, the woven fabric was finished in the same manner as in Example 1. However, in the obtained woven fabric, extra-fine yarns were sometimes bundled together, and morphological portions such as a brush tip were scattered at various places, and it could not be said that the fabric was uniform.

【0040】[0040]

【発明の効果】本発明の異収縮混繊糸によれば、天然繊
維の有する自然な斑を再現するのではなく、合成繊維の
均一性をより強調した均整な表面外観を呈するスエード
調布帛を提供することができる。
According to the hetero-shrinkage mixed fiber yarn of the present invention, a suede-like fabric having a uniform surface appearance that emphasizes the uniformity of a synthetic fiber rather than reproducing the natural spots of the natural fiber is provided. Can be provided.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明にかかる海島型複合糸の横断面の一概略
図である。
FIG. 1 is a schematic cross-sectional view of a sea-island composite yarn according to the present invention.

【図2】本発明の異収縮混繊糸を製造するための工程を
示す一概略図である。
FIG. 2 is a schematic view showing a process for producing the different shrinkage mixed fiber yarn of the present invention.

【図3】本発明の異収縮混繊糸を製造するための別の工
程を示す一概略図である。
FIG. 3 is a schematic view showing another process for producing the different shrinkage mixed fiber of the present invention.

【図4】本発明の異収縮混繊糸を製造するためのさらに
別の工程を示す一概略図である。
FIG. 4 is a schematic view showing still another step for producing the hetero-shrinkage mixed fiber of the present invention.

【符号の説明】[Explanation of symbols]

A 島成分 B 海成分 1,1−1,1−2 海島型複合糸 2,2−1,2−2 太さ斑を有しない均一糸 3,3−1,3−2 コットローラ 4,4−1,4−2 供給ローラ 5,5−1,5−2 加熱プレート 6,6−1,6−2 段付ローラ 7,7−1,7−2 インターレースノズル 8,8−1,8−2 異収縮混繊糸 A island component B sea component 1,1-1,1-2 Sea-island type composite yarn 2,2-1,2-2 Uniform yarn without thickness unevenness 3,3-1,3-2 Cot roller 4,4 -1,4-2 supply roller 5,5-1,5-2 heating plate 6,6-1,6-2 stepped roller 7,7-1,7-2 interlace nozzle 8,8-1,8- 2 Different shrinkage mixed fiber

フロントページの続き (72)発明者 水村 知雄 愛媛県松山市北吉田町77番地 帝人株式会 社松山事業所内 Fターム(参考) 4L036 MA05 MA16 MA33 MA39 PA01 PA03 PA33 PA46 RA03 UA25Continued on the front page (72) Inventor Tomio Mizumura 77 Kitayoshida-cho, Matsuyama-shi, Ehime Prefecture Teijin Limited Matsuyama Works F-term (reference) 4L036 MA05 MA16 MA33 MA39 PA01 PA03 PA33 PA46 RA03 UA25

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 低収縮糸が、フィラメント数8〜72本
で、下記(1)〜(3)を同時に満足する海島型太細複
合糸であり、高収縮糸が、単繊維繊度1.5〜7デシテ
ックス、フイラメント数6〜48本の太さ斑を有しない
均一糸であることを特徴とする異収縮混繊糸。 (1)ウースターイブネス(U%)が0.4〜2.5% (2)島成分の太細比が1.5以下 (3)島成分の単繊度が0.04〜0.70デシテック
The low-shrink yarn is a sea-island type thick and thin composite yarn having 8 to 72 filaments and simultaneously satisfying the following (1) to (3), and the high-shrink yarn is a single fiber fineness of 1.5. A non-shrinkable mixed yarn comprising a uniform yarn having a thickness of 6 to 48 decitex and a filament number of 6 to 48 and having no unevenness. (1) Worcester evenness (U%) is 0.4 to 2.5% (2) Thickness ratio of island component is 1.5 or less (3) Single fineness of island component is 0.04 to 0.70 decitex
【請求項2】 海島型太細複合糸の伸度が80〜180
%である請求項1記載の異収縮混繊糸。
2. The sea-island type thick and thin composite yarn has an elongation of 80 to 180.
%.
【請求項3】 海島型太細複合糸及び均一糸を構成する
ポリマーがポリエステルである請求項1又は2記載の異
収縮混繊糸。
3. The hetero-shrink mixed yarn according to claim 1, wherein the polymer constituting the sea-island type thick and thin composite yarn and the uniform yarn is polyester.
【請求項4】 フィラメント数が8〜72本、自然延伸
倍率が1.8以下、伸度が120〜200%、島成分繊
度が0.042〜0.90デシテックスである海島型複
合糸を、温度80〜230℃で1.05〜1.35倍に
延伸してウースターイブネス(U%)が0.4〜2.5
%の海島型太細複合低収縮糸となし、次いで、単繊維繊
度が1.5〜7デシテックス、フイラメント数が6〜4
8本の太さ斑を有しない均一高収縮糸と混繊することを
特徴とする異収縮混繊糸の製造方法。
4. A sea-island composite yarn having a filament count of 8 to 72, a natural draw ratio of 1.8 or less, an elongation of 120 to 200%, and an island component fineness of 0.042 to 0.90 decitex, The film is stretched 1.05 to 1.35 times at a temperature of 80 to 230 ° C. to have a Worcester evenness (U%) of 0.4 to 2.5.
% Of the sea-island type thick and thin composite low shrinkage yarn, followed by a single fiber fineness of 1.5 to 7 dtex and a filament number of 6 to 4
A method for producing a different shrinkage mixed fiber yarn, wherein the fiber is mixed with eight uniform high shrinkage yarns having no thickness unevenness.
JP2001120866A 2001-04-19 2001-04-19 Combined filament yarn of different shrinkage and method for producing the same Pending JP2002317337A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001120866A JP2002317337A (en) 2001-04-19 2001-04-19 Combined filament yarn of different shrinkage and method for producing the same

Publications (1)

Publication Number Publication Date
JP2002317337A true JP2002317337A (en) 2002-10-31

Family

ID=18970840

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2002317337A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007262610A (en) * 2006-03-28 2007-10-11 Teijin Fibers Ltd Combined filament yarn
CN106192034A (en) * 2016-09-20 2016-12-07 哈尔滨工业大学 A kind of island spinning spinning pack and utilize its preparation method preparing ultrafine carbon fiber
CN112567084A (en) * 2018-09-06 2021-03-26 东丽纤维研究所(中国)有限公司 Fabric

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007262610A (en) * 2006-03-28 2007-10-11 Teijin Fibers Ltd Combined filament yarn
CN106192034A (en) * 2016-09-20 2016-12-07 哈尔滨工业大学 A kind of island spinning spinning pack and utilize its preparation method preparing ultrafine carbon fiber
CN112567084A (en) * 2018-09-06 2021-03-26 东丽纤维研究所(中国)有限公司 Fabric

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