JP2002317174A - Antistatic agent composition - Google Patents
Antistatic agent compositionInfo
- Publication number
- JP2002317174A JP2002317174A JP2001124186A JP2001124186A JP2002317174A JP 2002317174 A JP2002317174 A JP 2002317174A JP 2001124186 A JP2001124186 A JP 2001124186A JP 2001124186 A JP2001124186 A JP 2001124186A JP 2002317174 A JP2002317174 A JP 2002317174A
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- Prior art keywords
- water
- antistatic agent
- antistatic
- soluble
- reel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、帯電防止剤組成物
に関する。特に、異方性導電フィルム用のリールの帯電
防止用に適した帯電防止剤組成物に関する。[0001] The present invention relates to an antistatic composition. In particular, the present invention relates to an antistatic agent composition suitable for antistatic of a reel for an anisotropic conductive film.
【０００２】[0002]
【従来の技術】一般に、異方性導電フィルムは、２ｍｍ
程度の非常に狭い幅にスリットされている。このため、
従来より、異方性導電フィルムの荷崩れを防止し、取り
扱い性を高めるために、異方性導電フィルムを、ポリス
チレン、ポリカーボネートなどの樹脂材料からなるリー
ルに巻き付け、使用時にリールから巻き出して使用して
いる。2. Description of the Related Art Generally, an anisotropic conductive film has a thickness of 2 mm.
It is slit to a very narrow width. For this reason,
Conventionally, in order to prevent collapse of the anisotropic conductive film and improve handling, the anisotropic conductive film is wound around a reel made of resin material such as polystyrene and polycarbonate, and unwound from the reel when used. are doing.
【０００３】ところが、樹脂性のリールを使用した場
合、異方性導電フィルムの巻き取りや巻き出しの際にリ
ールが帯電するという問題が生ずる。帯電したリールに
は静電的に塵芥が引き寄せられ付着し、その結果、塵芥
が異方性導電フィルムに巻き込まれたり、異方性導電フ
ィルムに付着したまま異方性導電接続処理が行われ、接
続信頼性の低下が生じるという問題がある。However, when a resinous reel is used, a problem arises in that the reel is charged when winding or unwinding the anisotropic conductive film. The dust is attracted to and adheres to the charged reel, and as a result, the dust is caught in the anisotropic conductive film, or the anisotropic conductive connection process is performed while the dust remains attached to the anisotropic conductive film. There is a problem that connection reliability is reduced.
【０００４】このような問題を解決するためには、カー
ボンブラック等の導電粉末を練り込んだリールを使用す
ることが確実であるが、リールが透明ではなくなるた
め、リールの側面から異方性導電フィルムの残量や巻き
状態の確認ができないという問題がある。In order to solve such a problem, it is certain to use a reel into which conductive powder such as carbon black is kneaded. However, since the reel is not transparent, an anisotropic conductive material is used from the side of the reel. There is a problem that the remaining amount of the film and the winding state cannot be confirmed.
【０００５】そこで、陽イオン系界面活性剤や両イオン
系界面活性剤を主成分とする水性帯電防止剤組成物をリ
ールにスプレーすることが行われている。[0005] Therefore, it has been practiced to spray a reel with an aqueous antistatic composition containing a cationic surfactant or a zwitterionic surfactant as a main component.
【０００６】[0006]
【発明が解決しようとする課題】しかしながら、水性帯
電防止剤組成物をリールにスプレーした場合、リールの
透明性は維持されるが、均一な連続被膜が形成し難いた
めに、リールの表面の一部に塵芥が依然として引き寄せ
られるという問題がある。更に、スプレーにより形成さ
れた水性帯電防止剤組成物の被膜は、それ自身が水溶性
であるために、水に接触した場合や高湿度環境下に置か
れた場合には、リールの表面から異方性導電フィルムへ
移行する可能性が高まり、異方性導電フィルムの接続信
頼性が損なわれるおそれもある。However, when the aqueous antistatic agent composition is sprayed on the reel, the transparency of the reel is maintained, but it is difficult to form a uniform continuous film. There is a problem that garbage is still drawn to the part. Further, since the coating of the aqueous antistatic agent composition formed by spraying is itself water-soluble, it differs from the reel surface when it comes into contact with water or is placed in a high humidity environment. The possibility of shifting to an isotropic conductive film increases, and the connection reliability of the anisotropic conductive film may be impaired.
【０００７】以上のような問題は、異方性導電フィルム
だけでなく、帯電を嫌う種々の高分子物品（粘着テープ
加工品等）にも伴う問題である。[0007] The above-mentioned problems are problems not only with anisotropic conductive films, but also with various polymer articles (such as processed adhesive tapes) which dislike charging.
【０００８】本発明は、従来の技術の問題点を解決しよ
うとするものであり、異方性導電フィルム用のリール等
の高分子物品の表面全体に亘って、均一で連続的な帯電
防止機能を付与し、且つ帯電防止剤が他の物体へ移行し
ないようにすることを目的とする。The present invention is to solve the problems of the prior art, and has a uniform and continuous antistatic function over the entire surface of a polymer article such as a reel for an anisotropic conductive film. And to prevent the antistatic agent from migrating to other objects.
【０００９】[0009]
【課題を解決するための手段】本発明者は、水溶性帯電
防止剤に水混和性アルコールを混合すると、得られた帯
電防止剤組成物を帯電防止すべき高分子物品に塗布し乾
燥した際に、ハジキ現象を生じることなく塗布面を均一
且つ連続的に被覆できること、また、そのような帯電防
止剤組成物に特定の樹脂エマルジョンを成膜成分として
配合すると、成膜の際に水溶性帯電防止剤と樹脂エマル
ジョンとの相溶状態を維持でき、乾燥後に耐湿性に優れ
た膜を形成することを見出し、本発明を完成させるに至
った。SUMMARY OF THE INVENTION The present inventor has proposed that when a water-soluble antistatic agent is mixed with a water-miscible alcohol, the obtained antistatic agent composition is applied to a polymer article to be antistatic and dried. In addition, the coating surface can be uniformly and continuously coated without repelling phenomenon, and when a specific resin emulsion is blended with such an antistatic agent composition as a film-forming component, water-soluble charging during film formation can be achieved. The present inventors have found that a compatible state between the inhibitor and the resin emulsion can be maintained and a film having excellent moisture resistance can be formed after drying, and the present invention has been completed.
【００１０】即ち、本発明は、水溶性帯電防止剤と、Ｎ
−メチロールアクリルアミド単位を含むアクリル酸エス
テル共重合体エマルジョンと、水混和性アルコールと、
水とを含有することを特徴とする帯電防止剤組成物を提
供する。That is, the present invention relates to a water-soluble antistatic agent,
-An acrylate copolymer emulsion containing methylol acrylamide units, a water-miscible alcohol,
An antistatic composition comprising water and water.
【００１１】また、本発明は、この帯電防止剤組成物の
乾燥塗布膜が表面に形成された高分子物品、特に異方性
導電フィルム用リールを提供する。The present invention also provides a polymer article, particularly a reel for an anisotropic conductive film, on the surface of which a dry coating film of the antistatic composition is formed.
【００１２】[0012]
【発明の実施の形態】以下、本発明を詳細に説明する。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
【００１３】本発明の帯電防止剤組成物は、水溶性帯電
防止剤と、Ｎ−メチロールアクリルアミド単位を含むア
クリル酸エステル共重合体エマルジョンと、水混和性ア
ルコールと、水とを含有する。The antistatic composition of the present invention contains a water-soluble antistatic agent, an acrylate copolymer emulsion containing N-methylolacrylamide units, a water-miscible alcohol, and water.
【００１４】本発明において使用できる水溶性帯電防止
剤としては、イオン伝導性を有するもので、例えば水溶
性ポリエステルとポリエチレンオキシドと過塩素酸リチ
ウムとを含有するタイプのものが挙げられる。具体的に
は、ソルベックス社のイオンソルバーシリーズの水溶性
帯電防止剤等を挙げることができるが、中でもイオンソ
ルバー９ａ（ソルベックス社製）を好ましく使用するこ
とができる。The water-soluble antistatic agent that can be used in the present invention has ionic conductivity, and includes, for example, those containing a water-soluble polyester, polyethylene oxide and lithium perchlorate. Specific examples include a water-soluble antistatic agent of the ion solver series of Solvex, etc. Among them, ion solver 9a (manufactured by Solvex) can be preferably used.
【００１５】水溶性帯電防止剤組成物における水溶性帯
電防止剤の含有量は、少なすぎると帯電防止効果が不十
分であり、多すぎると成膜成分も多量に使用する必要が
生じ、帯電防止層に厚みムラが発生し、外観不良となる
ので、好ましくは０．０１〜１重量％、より好ましくは
０．１〜０．５重量％である。If the content of the water-soluble antistatic agent in the water-soluble antistatic agent composition is too small, the antistatic effect is insufficient, and if it is too large, it is necessary to use a large amount of a film-forming component. The thickness is preferably 0.01 to 1% by weight, and more preferably 0.1 to 0.5% by weight, since thickness unevenness occurs in the layer and the appearance becomes poor.
【００１６】本発明において使用するＮ−メチロールア
クリルアミド単位を含むアクリル酸エステル共重合体エ
マルジョンは成膜成分である。このエマルジョンにおけ
る樹脂分は、エマルジョンの製造方法にもよるが、通常
４０〜６０重量％、好ましくは４１〜５１重量％であ
る。The acrylate copolymer emulsion containing N-methylolacrylamide units used in the present invention is a film-forming component. The resin content of this emulsion is usually from 40 to 60% by weight, preferably from 41 to 51% by weight, depending on the method for producing the emulsion.
【００１７】このアクリル酸エステル共重合体を構成す
るモノマーとしては、Ｎ−メチロールアクリルアミド、
アクリル酸エチル、メタクリル酸メチル等が挙げられ
る。ここで、Ｎ−メチロールアクリルアミドは、成膜後
に約１００℃以上に加熱されると、自己縮合反応し、帯
電防止膜の膜強度を向上させることができる。The monomers constituting the acrylate copolymer include N-methylol acrylamide,
Examples include ethyl acrylate and methyl methacrylate. Here, when N-methylolacrylamide is heated to about 100 ° C. or more after film formation, it undergoes a self-condensation reaction, and can improve the film strength of the antistatic film.
【００１８】これらのモノマー比に関し、全モノマー１
００重量部中にＮ−メチロールアクリルアミドを好まし
くは０．１〜１重量部となる量で使用する以外、特に制
限はない。これは、Ｎ−メチロールアクリルアミドが少
なすぎると硬化不足で過度に柔らかくなり、多すぎると
混合液が不安定となるからである。With respect to these monomer ratios,
There is no particular limitation, except that N-methylolacrylamide is preferably used in an amount of 0.1 to 1 part by weight in 00 parts by weight. This is because if N-methylolacrylamide is too small, the composition becomes too soft due to insufficient curing, and if it is too large, the mixture becomes unstable.
【００１９】Ｎ−メチロールアクリルアミド単位を含む
アクリル酸エステル共重合体エマルジョンの帯電防止剤
組成物中の含有量は、少なすぎると耐水性が不足し、多
すぎると帯電防止効果が不足するので、その樹脂分が水
溶性帯電防止剤１重量部に対し好ましくは０．２〜５重
量部、より好ましくは０．５〜１．５重量部となる割合
で含有する。If the content of the acrylate copolymer emulsion containing N-methylolacrylamide units in the antistatic agent composition is too small, the water resistance is insufficient, and if it is too large, the antistatic effect is insufficient. The resin component is contained in an amount of preferably 0.2 to 5 parts by weight, more preferably 0.5 to 1.5 parts by weight based on 1 part by weight of the water-soluble antistatic agent.
【００２０】本発明で使用するＮ−メチロールアクリル
アミド単位を含むアクリル酸エステル共重合体エマルジ
ョンは、公知のラジカルエマルジョン重合法により調製
することができる。The acrylate copolymer emulsion containing N-methylolacrylamide units used in the present invention can be prepared by a known radical emulsion polymerization method.
【００２１】本発明において使用する水混和性アルコー
ルとしては、メタノール、エタノール、イソプロピルア
ルコール等の水混和性の低級アルコール、中でもエタノ
ールを使用することが好ましい。As the water-miscible alcohol used in the present invention, it is preferable to use water-miscible lower alcohols such as methanol, ethanol and isopropyl alcohol, and particularly ethanol.
【００２２】このような水混和性アルコールの帯電防止
剤組成物中の含有量は、少なすぎると、組成物を異方性
導電フィルム用リール等の被塗布面に塗布した際に、組
成物のハジキ現象を有効に防止することができず、多す
ぎると樹脂分が分離するので、好ましくは１０〜６０重
量％、より好ましくは２０〜４０重量％である。If the content of such a water-miscible alcohol in the antistatic agent composition is too small, when the composition is applied to a surface to be coated such as a reel for an anisotropic conductive film, the content of the composition is reduced. The repelling phenomenon cannot be effectively prevented, and if the amount is too large, the resin component is separated, so that the content is preferably 10 to 60% by weight, more preferably 20 to 40% by weight.
【００２３】なお、本発明の帯電防止剤組成物は、アク
リル酸エステル共重合体エマルジョンに由来する水に加
えて、粘度調整等を目的として水、好ましくはイオン交
換水を必要に応じて別途含有されることができる。The antistatic agent composition of the present invention contains water, preferably ion-exchanged water, if necessary, for the purpose of adjusting viscosity, etc., in addition to water derived from the acrylate copolymer emulsion. Can be done.
【００２４】本発明の帯電防止剤組成物には、以上の成
分の他に必要に応じて種々の添加剤（例えば、消泡剤）
を含有させることができる。In the antistatic composition of the present invention, various additives (for example, an antifoaming agent) may be added as required in addition to the above components.
Can be contained.
【００２５】本発明の帯電防止剤組成物は、以上の成分
を常法により均一に混合することにより製造することが
できる。The antistatic composition of the present invention can be produced by uniformly mixing the above components by a conventional method.
【００２６】本発明の帯電防止剤組成物は、浸漬法やス
プレー法など公知の手法に従って使用することができ
る。例えば、浸漬法は、帯電防止剤組成物の液中に帯電
防止すべき対象である高分子物品を浸漬し、それを液か
ら取り出し、１００〜１２０℃の乾燥炉中で乾燥するこ
とにより、高分子物品の表面に帯電防止層を形成する方
法である。ここで、そのような高分子物品としては、種
々の熱可塑性樹脂、熱硬化型、紫外線硬化型もしくは電
子線硬化型樹脂からなる成型品が挙げられるが、中でも
ポリスチレンやポリカーボネート製の異方性導電フィル
ム用リールを好ましく挙げることができる。The antistatic composition of the present invention can be used according to a known method such as a dipping method or a spray method. For example, in the dipping method, a polymer article to be antistatic is immersed in a liquid of an antistatic agent composition, taken out of the liquid, and dried in a drying oven at 100 to 120 ° C. This is a method of forming an antistatic layer on the surface of a molecular article. Here, examples of such a polymer article include molded articles made of various thermoplastic resins, thermosetting resins, ultraviolet-curing resins, or electron beam-curing resins. Film reels are preferred.
【００２７】[0027]
【実施例】実施例１〜３及び比較例１〜５ ２リットルビーカーに、表１に示す配合量で、水溶性帯
電防止剤（イオンソルバー９ａ、ソルベックス社製）、
Ｎ−メチロールアクリルアミド単位を有するアクリル酸
エステル共重合体エマルジョン（樹脂分４５重量％；モ
ビニール７１０、クラリアント社製）、イオン交換水及
びエタノールに投入し、撹拌機で均一に混合して液状の
帯電防止剤組成物を調製した。Examples 1 to 3 and Comparative Examples 1 to 5 Into a 2 liter beaker, a water-soluble antistatic agent (ion solver 9a, manufactured by Solbex Co.) was added in the amount shown in Table 1.
Acrylic ester copolymer emulsion having N-methylolacrylamide units (resin content: 45% by weight; Movinyl 710, manufactured by Clariant), ion-exchanged water and ethanol, and uniformly mixed with a stirrer to prevent liquid antistatic An agent composition was prepared.
【００２８】得られた液条の帯電防止剤組成物に、ポリ
カーボネート製の異方性導電フィルム用リールを一分間
浸漬した後に取り出し、１００℃で３分間乾燥し、リー
ルの表面に帯電防止層を形成した。A reel for a polycarbonate anisotropic conductive film is immersed in the obtained liquid antistatic composition for 1 minute, taken out, dried at 100 ° C. for 3 minutes, and an antistatic layer is formed on the surface of the reel. Formed.
【００２９】なお、比較例５の場合には、得られた液状
の帯電防止剤組成物をポリカーボネート製の異方性導電
フィルム用リールに１０ｇ／ｍ２となる量でスプレー
し、１００℃で３分間乾燥し、リールの表面に帯電防止
層を形成した。In the case of Comparative Example 5, the obtained liquid antistatic agent composition was sprayed onto a polycarbonate anisotropic conductive film reel at an amount of 10 g / m 2 , After drying for a minute, an antistatic layer was formed on the surface of the reel.
【００３０】[0030]
【表１】 実施例 比較例 １ ２ ３ １ ２ ３ ４ ５ 水溶性帯電防止剤 50 10 5 5 150 1 5 10 共重合体エマルシ゛ョン 50 10 5 5 150 1 0 10 イオン交換水 540 588 594 990 420 599 597 980エタノール 360 392 396 0 280 399 398 0 [Table 1] Examples Comparative Examples 1 2 3 1 2 3 4 5 Water-soluble antistatic agent 50 10 5 5 150 1 5 10 Copolymer emulsion 50 10 5 5 150 1 0 10 Ion-exchanged water 540 588 594 990 420 599 597 980 Ethanol 360 392 396 0 280 399 398 0
【００３１】（評価）帯電防止層が形成されたリールに
ついて、帯電防止効果として表面抵抗値を表面抵抗測定
器（高抵抗計、ヒューレットパッカード社製）で測定し
た。得られた結果を表２に示す。表面抵抗値が１×１０
１１Ω以下、好ましくは１×１０９Ω以下である場合に
帯電防止効果が良好であると判断できる。(Evaluation) With respect to the reel on which the antistatic layer was formed, the surface resistance value was measured as an antistatic effect using a surface resistance measuring device (high resistance meter, manufactured by Hewlett Packard). Table 2 shows the obtained results. Surface resistance value is 1 × 10
When it is 11 Ω or less, preferably 1 × 10 9 Ω or less, it can be determined that the antistatic effect is good.
【００３２】また、帯電防止層の外観について目視観察
した。帯電防止層が均一で連続膜を形成した場合をＯＫ
と評価し、ハジキ現象や膜厚ムラが観察された場合をＮ
Ｇと評価した。得られた結果を表２に示す。The appearance of the antistatic layer was visually observed. OK if the antistatic layer is uniform and forms a continuous film
And the case where repelling phenomenon and film thickness unevenness were observed
It was rated G. Table 2 shows the obtained results.
【００３３】更に、形成された帯電防止層に水をスプレ
ーし、帯電防止層の耐水性を目視評価した。変化がない
場合をＯＫと評価し、帯電防止層が水に溶け出した場合
をＮＧと評価した。得られた結果を表２に示す。Further, water was sprayed on the formed antistatic layer, and the water resistance of the antistatic layer was visually evaluated. The case where there was no change was evaluated as OK, and the case where the antistatic layer was dissolved in water was evaluated as NG. Table 2 shows the obtained results.
【００３４】[0034]
【表２】 表２注 ＊１： ハジキ現象有り ＊２： 膜厚ムラ有り ＊３： 膜厚ムラ（スプレーパターン）有り[Table 2] Table 2 Note * 1: With repelling phenomenon * 2: With uneven thickness * 3: With uneven thickness (spray pattern)
【００３５】表２から、実施例１〜３の帯電防止剤組成
物は、帯電防止効果に優れ、外観も耐水性にも優れてい
ることがわかる。From Table 2, it can be seen that the antistatic agent compositions of Examples 1 to 3 are excellent in antistatic effect, and excellent in appearance and water resistance.
【００３６】一方、エタノールを使用しない比較例１の
帯電防止剤組成物の場合には、リールの表面にハジキ現
象が生じた。帯電防止剤を過剰に用いた比較例２の帯電
防止剤組成物の場合には、膜厚ムラが生じ、帯電防止剤
を過度に少ない量で用いた比較例３の帯電防止剤組成物
の場合には、帯電防止効果が不十分であった。また、ア
クリル酸エステル共重合体エマルジョンを使用しない比
較例４の帯電防止剤組成物の場合には、耐水性に問題が
あった。また、エタノールを使用しない比較例５の帯電
防止剤組成物の場合には、組成物をスプレーでリール表
面に適用してもリールの表面にスプレーパターンが残っ
てしまった。On the other hand, in the case of the antistatic agent composition of Comparative Example 1 in which ethanol was not used, repelling phenomenon occurred on the reel surface. In the case of the antistatic agent composition of Comparative Example 2 in which an excessive amount of the antistatic agent was used, film thickness unevenness occurred, and in the case of the antistatic agent composition of Comparative Example 3 in which the antistatic agent was used in an excessively small amount. Had an insufficient antistatic effect. In the case of the antistatic agent composition of Comparative Example 4 in which the acrylate copolymer emulsion was not used, there was a problem in water resistance. In the case of the antistatic agent composition of Comparative Example 5 in which ethanol was not used, even when the composition was applied to the reel surface by spraying, a spray pattern remained on the reel surface.
【００３７】[0037]
【発明の効果】本発明の帯電防止剤組成物によれば、異
方性導電フィルム用のリール等の高分子物品の表面全体
に亘って、均一で連続的な帯電防止機能を付与し、且つ
帯電防止剤が他の物体へ移行しないようにできる。According to the antistatic composition of the present invention, a uniform and continuous antistatic function is provided over the entire surface of a polymer article such as a reel for an anisotropic conductive film, and The antistatic agent can be prevented from migrating to other objects.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ０８Ｋ 5/05 Ｃ０８Ｋ 5/05 Ｃ０９Ｄ 5/00 Ｃ０９Ｄ 5/00 Ｚ 5/02 5/02 133/08 133/08 133/24 133/24 167/00 167/00 171/02 171/02 (72)発明者 新井 晃司 栃木県鹿沼市さつき町12−３ ソニーケミ カル株式会社内 Ｆターム(参考） 4F006 AA36 AB24 AB32 AB35 AB64 AB72 BA07 CA00 4J002 BG041 BG051 BG121 CF002 CH023 DE196 EC007 FD106 FD207 GB00 4J038 CG141 CG201 CH03 DD00 DF02 HA08 HA086 JA19 KA12 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C08K 5/05 C08K 5/05 C09D 5/00 C09D 5/00 Z 5/02 5/02 133/08 133 / 08 133/24 133/24 167/00 167/00 171/02 171/02 (72) Inventor Koji Arai 12-3 Satsukicho, Kanuma City, Tochigi Prefecture Sony Chemical Corporation F term (reference) 4F006 AA36 AB24 AB32 AB35 AB64 AB72 BA07 CA00 4J002 BG041 BG051 BG121 CF002 CH023 DE196 EC007 FD106 FD207 GB00 4J038 CG141 CG201 CH03 DD00 DF02 HA08 HA086 JA19 KA12
Claims (7)
クリルアミド単位を含むアクリル酸エステル共重合体エ
マルジョンと、水混和性アルコールと、水とを含有する
ことを特徴とする帯電防止剤組成物。1. An antistatic composition comprising a water-soluble antistatic agent, an acrylate copolymer emulsion containing N-methylolacrylamide units, a water-miscible alcohol, and water.
で含有する請求項１記載の帯電防止剤組成物。2. A water-soluble antistatic agent in an amount of 0.01 to 1% by weight.
The antistatic agent composition according to claim 1, wherein
むアクリル酸エステル共重合体エマルジョンを、その樹
脂分が水溶性帯電防止剤１重量部に対し０．２〜５重量
部となる割合で含有する請求項１又は２記載の帯電防止
剤組成物。3. An acrylic ester copolymer emulsion containing N-methylol acrylamide units at a ratio of 0.2 to 5 parts by weight of a resin component to 1 part by weight of a water-soluble antistatic agent. 3. The antistatic composition according to 1 or 2.
で含有する請求項１〜３のいずれかに記載の帯電防止剤
組成物。4. A water-miscible alcohol containing 10 to 60% by weight.
The antistatic agent composition according to claim 1, wherein the composition comprises:
ルとポリエチレンオキシドと過塩素酸リチウムとを含有
する請求項１〜４のいずれかに記載の帯電防止剤組成
物。5. The antistatic composition according to claim 1, wherein the water-soluble antistatic agent contains a water-soluble polyester, polyethylene oxide and lithium perchlorate.
止剤組成物の乾燥塗布膜が表面に形成された高分子物
品。6. A polymer article having a dried coating film of the antistatic agent composition according to claim 1 formed on a surface thereof.
ールである請求項６記載の高分子物品。7. The polymer article according to claim 6, wherein the polymer article is a reel for an anisotropic conductive film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001124186A JP3873651B2 (en) | 2001-04-23 | 2001-04-23 | Antistatic composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001124186A JP3873651B2 (en) | 2001-04-23 | 2001-04-23 | Antistatic composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002317174A true JP2002317174A (en) | 2002-10-31 |
| JP3873651B2 JP3873651B2 (en) | 2007-01-24 |
Family
ID=18973613
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001124186A Expired - Lifetime JP3873651B2 (en) | 2001-04-23 | 2001-04-23 | Antistatic composition |
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| Country | Link |
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| JP (1) | JP3873651B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2019050011A1 (en) * | 2017-09-11 | 2020-08-20 | 日立化成株式会社 | Adhesive film for circuit connection, manufacturing method thereof, manufacturing method of circuit connection structure, and adhesive film accommodating set |
| JPWO2019050005A1 (en) * | 2017-09-11 | 2020-08-20 | 日立化成株式会社 | Adhesive film accommodating set and manufacturing method thereof |
| JPWO2019050012A1 (en) * | 2017-09-11 | 2020-08-27 | 日立化成株式会社 | Adhesive film for circuit connection, manufacturing method thereof, manufacturing method of circuit connection structure, and adhesive film accommodating set |
-
2001
- 2001-04-23 JP JP2001124186A patent/JP3873651B2/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2019050011A1 (en) * | 2017-09-11 | 2020-08-20 | 日立化成株式会社 | Adhesive film for circuit connection, manufacturing method thereof, manufacturing method of circuit connection structure, and adhesive film accommodating set |
| JPWO2019050005A1 (en) * | 2017-09-11 | 2020-08-20 | 日立化成株式会社 | Adhesive film accommodating set and manufacturing method thereof |
| JPWO2019050012A1 (en) * | 2017-09-11 | 2020-08-27 | 日立化成株式会社 | Adhesive film for circuit connection, manufacturing method thereof, manufacturing method of circuit connection structure, and adhesive film accommodating set |
| JP7210846B2 (en) | 2017-09-11 | 2023-01-24 | 株式会社レゾナック | Adhesive film for circuit connection, manufacturing method thereof, manufacturing method of circuit connection structure, and adhesive film housing set |
| JP7210845B2 (en) | 2017-09-11 | 2023-01-24 | 株式会社レゾナック | Adhesive film storage set and manufacturing method thereof |
| JP7264054B2 (en) | 2017-09-11 | 2023-04-25 | 株式会社レゾナック | Adhesive film for circuit connection, manufacturing method thereof, manufacturing method of circuit connection structure, and adhesive film housing set |
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| Publication number | Publication date |
|---|---|
| JP3873651B2 (en) | 2007-01-24 |
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