JP2002252146A - Electric double-layer capacitor - Google Patents

Electric double-layer capacitor

Info

Publication number
JP2002252146A
JP2002252146A JP2001049232A JP2001049232A JP2002252146A JP 2002252146 A JP2002252146 A JP 2002252146A JP 2001049232 A JP2001049232 A JP 2001049232A JP 2001049232 A JP2001049232 A JP 2001049232A JP 2002252146 A JP2002252146 A JP 2002252146A
Authority
JP
Japan
Prior art keywords
layer capacitor
electric double
separator
porosity
double layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001049232A
Other languages
Japanese (ja)
Inventor
Keisuke Oga
啓介 黄賀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Tokin Hyogo Ltd
Original Assignee
NEC Tokin Ceramics Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Tokin Ceramics Corp filed Critical NEC Tokin Ceramics Corp
Priority to JP2001049232A priority Critical patent/JP2002252146A/en
Publication of JP2002252146A publication Critical patent/JP2002252146A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors

Landscapes

  • Electric Double-Layer Capacitors Or The Like (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide an electric double-layer capacitor, whose electrical properties can be controlled freely so as to solve the problem in which a conventional electric double-layer capacitor is low in productivity and expensive, because the separators need to be different from each other in pore diameter, and porosity are used so as to change the electric double-layer capacitor in electrical properties. SOLUTION: This electric double-layer capacitor cell has a structure, in which a film part, having no pore or a film part having micro pores, is provided to a part of a porous film separator so as to freely regulate the separator in permeability to ions contained in an electrolyte, and to regulate the porous film separator in pore diameter and porosity.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、多孔膜セパレータのプ
ラス電極及びマイナス電極間の電解液中イオンの透過特
性及び電極粒子の分離特性に関与する孔径及び空孔率を
制御することにより、電気二重層コンデンサの電気的特
性を自由にコントロールするものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a porous membrane separator by controlling the pore size and porosity involved in the permeation characteristics of ions in the electrolyte between the positive electrode and the negative electrode and the separation characteristics of electrode particles. It controls the electrical characteristics of the double-layer capacitor freely.

【0002】[0002]

【従来の技術】従来、この種の電気二重層コンデンサセ
ル1(以後、基本セルと記す。)は、図3に示すように
構成されていた。すなわち、多孔膜セパレータ2(以
後、セパレータと記す。)は、プラス電極5及びマイナ
ス電極6の微粒子を分離(短絡防止)し、電解液中イオ
ンを透過させる必要があり、孔径は電極粒子径より小さ
く、空孔率は均一且つ均質な構造を有していた。
2. Description of the Related Art Conventionally, this type of electric double layer capacitor cell 1 (hereinafter referred to as a basic cell) has been configured as shown in FIG. That is, the porous membrane separator 2 (hereinafter, referred to as a separator) needs to separate the fine particles of the plus electrode 5 and the minus electrode 6 (prevent short circuit) and allow ions in the electrolyte to pass therethrough. It was small and had a uniform and homogeneous porosity.

【0003】また、電気二重層コンデンサ7は、セパレ
ータ2の孔径及び空孔率の異なるセパレータ7を用いる
ことにより、電解液中イオンの透過特性を制御し、電気
二重層コンデンサ7の電気的特性をコントロールしてい
た。
Further, the electric double layer capacitor 7 controls the permeation characteristics of ions in the electrolytic solution by using the separators 7 having different pore diameters and porosity of the separator 2, thereby improving the electric characteristics of the electric double layer capacitor 7. I was in control.

【0004】[0004]

【発明が解決しようとする課題】図4に示すような従来
の基本セル1では、電解液中イオンの透過特性及び電極
粒子の分離特性がセパレータ2の孔径及び空孔率に依存
性が高く、特性を変化させるためには、孔径及び空孔率
の異なるセパレータ2を複数そろえる必要があった。
In the conventional basic cell 1 as shown in FIG. 4, the permeability of ions in the electrolyte and the separation of electrode particles are highly dependent on the pore size and porosity of the separator 2, In order to change the characteristics, it was necessary to arrange a plurality of separators 2 having different pore diameters and porosity.

【0005】また、従来のセパレータ2は、孔径を小さ
く均一すること及び空孔率を低く抑え均質にすることが
非常に困難であり、生産性が悪く付加価値の高いもので
あった。
Further, it is very difficult for the conventional separator 2 to make the pore size small and uniform, and to keep the porosity low and uniform, so that the productivity is poor and the added value is high.

【0006】[0006]

【課題を解決するための手段】本発明は、前記、従来の
問題点を解決するためになされたもので、その構成上の
特徴を、一例として、図5、図6、図7、図8の本発明
の一実施例を示す電気二重層コンデンサセル斜視横断面
図を用いて説明する。
SUMMARY OF THE INVENTION The present invention has been made in order to solve the above-mentioned conventional problems, and its structural features are shown by way of example in FIGS. 5, 6, 7, and 8. FIG. An embodiment of the present invention will be described with reference to a perspective cross-sectional view of an electric double layer capacitor cell.

【0007】図5、図6、図7、図8に示す本発明のセ
パレータ2は、上記の均一且つ均質なセパレータ2の一
部分に無孔膜部分または微孔膜部分9を作為的に構成
し、セパレータ2の基本的物性である孔径及び空孔率を
自由に変えることができるものである。
In the separator 2 of the present invention shown in FIGS. 5, 6, 7 and 8, a nonporous membrane portion or a microporous membrane portion 9 is artificially formed in a part of the above-mentioned uniform and homogeneous separator 2. The pore diameter and the porosity, which are the basic physical properties of the separator 2, can be freely changed.

【0008】また、上記のセパレータ2は、電解液中イ
オンの制御により電気二重層コンデンサ7の電気的特性
を自由にコントロールすることができる。
Further, the separator 2 can freely control the electric characteristics of the electric double layer capacitor 7 by controlling the ions in the electrolytic solution.

【0009】無孔膜部分及び微孔膜部分9の形成は、熱
または圧力により容易に実現できる。
The formation of the nonporous membrane portion and the microporous membrane portion 9 can be easily realized by heat or pressure.

【0010】[0010]

【実施例】本発明の一実施例について、図1、図2、図
3、図4、図5、図6、図7、図8を参照し説明する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS One embodiment of the present invention will be described with reference to FIGS. 1, 2, 3, 4, 5, 6, 7, and 8. FIG.

【0011】図1は、本発明の実施例を説明する電気二
重層コンデンサ7の斜視断面図であり、図2は、図1に
示す電気二重層コンデンサ7の電気二重層コンデンサ素
子の断面図、図3は、基本セル1の断面図である。
FIG. 1 is a perspective sectional view of an electric double layer capacitor 7 for explaining an embodiment of the present invention. FIG. 2 is a sectional view of an electric double layer capacitor element of the electric double layer capacitor 7 shown in FIG. FIG. 3 is a sectional view of the basic cell 1.

【0012】また、図4は、従来例を示す基本セル1の
斜視横断面図である。
FIG. 4 is a perspective cross-sectional view of a basic cell 1 showing a conventional example.

【0013】図5は、本発明の実施例1を示す基本セル
1の斜視横断面図である。
FIG. 5 is a perspective cross-sectional view of the basic cell 1 showing the first embodiment of the present invention.

【0014】また、図6、図7、図8も同様に本発明の
一実施例を示す基本セル1の斜視横断面図である。
6, 7 and 8 are perspective cross-sectional views of a basic cell 1 showing an embodiment of the present invention.

【0015】次に、本発明の実施例1〜実施例5につい
て、図5、図6、図7、図8を参照して説明する。
Next, Embodiments 1 to 5 of the present invention will be described with reference to FIGS. 5, 6, 7, and 8. FIG.

【0016】図5に示す本発明の実施例1は、セパレー
タ2の中央部に無孔膜部分または微多孔膜部分9を配置
したものである。
In the first embodiment of the present invention shown in FIG. 5, a nonporous membrane portion or a microporous membrane portion 9 is arranged at the center of the separator 2.

【0017】図6に示す本発明の実施例2は、セパレー
タ2に無孔膜部分または微多孔膜部分9を規則性を持た
せ配置したものである。
In a second embodiment of the present invention shown in FIG. 6, a nonporous membrane portion or a microporous membrane portion 9 is arranged on a separator 2 with regularity.

【0018】図7に示す本発明の実施例3は、セパレー
タ2の外周部に無孔膜部分または微多孔膜部分9を配置
したものである。
In a third embodiment of the present invention shown in FIG. 7, a nonporous membrane portion or a microporous membrane portion 9 is arranged on the outer periphery of the separator 2.

【0019】図8に示す本発明の実施例4は、セパレー
タ2の全面に微多孔膜部分9を配置したものである。
Embodiment 4 of the present invention shown in FIG. 8 has a structure in which a microporous membrane portion 9 is arranged on the entire surface of the separator 2.

【0020】[0020]

【発明の効果】以上、述べたように、本発明の図5、図
6、図7、図8に示すセパレータ2によれば、孔径及び
空孔率が無孔膜部分または微孔膜部分9の面積比率によ
り自由に制御することができ、従来のセパレータ2の孔
径及び空孔率の問題を解決するものである。
As described above, according to the separator 2 shown in FIGS. 5, 6, 7 and 8 of the present invention, the pore diameter and porosity of the non-porous film portion or microporous film portion 9 are reduced. Can be freely controlled by the area ratio of the separator 2, and solves the problems of the conventional pore diameter and porosity of the separator 2.

【0021】また、本発明の基本セル1は、セパレータ
2に無孔膜部分または微孔膜部分9を配置し電解液中イ
オンの透過特性及び粒子の分離特性を制御する機能を有
しており、表−1、表−2に示すように電気二重層コン
デンサ7の電気的特性をコントロールすることができ
る。
Further, the basic cell 1 of the present invention has a function of arranging a nonporous membrane portion or a microporous membrane portion 9 on the separator 2 to control the permeation characteristics of ions in the electrolyte and the separation characteristics of particles. As shown in Table 1, Table 2, the electric characteristics of the electric double layer capacitor 7 can be controlled.

【表1】 [Table 1]

【表2】 [Table 2]

【図面の簡単な説明】[Brief description of the drawings]

【図1】電気二重層コンデンサの斜視断面図。FIG. 1 is a perspective sectional view of an electric double layer capacitor.

【図2】電気二重層コンデンサ素子の断面図。FIG. 2 is a sectional view of an electric double layer capacitor element.

【図3】電気二重層コンデンサセルの断面図。FIG. 3 is a sectional view of an electric double layer capacitor cell.

【図4】従来例を示す電気二重層コンデンサセルの斜視
横断面図。
FIG. 4 is a perspective cross-sectional view of an electric double layer capacitor cell showing a conventional example.

【図5】本発明の実施例1を示す電気二重層コンデンサ
セルの斜視横断面図。
FIG. 5 is a perspective cross-sectional view of an electric double-layer capacitor cell showing Embodiment 1 of the present invention.

【図6】本発明の実施例2を示す電気二重層コンデンサ
セルの斜視横断面図。
FIG. 6 is a perspective cross-sectional view of an electric double layer capacitor cell showing a second embodiment of the present invention.

【図7】本発明の実施例3を示す電気二重層コンデンサ
セルの斜視横断面図。
FIG. 7 is a perspective cross-sectional view of an electric double layer capacitor cell showing Embodiment 3 of the present invention.

【図8】本発明の実施例4を示す電気二重層コンデンサ
セルの斜視横断面図。
FIG. 8 is a perspective cross-sectional view of an electric double layer capacitor cell showing Embodiment 4 of the present invention.

【符号の説明】[Explanation of symbols]

1 電気二重層コンデンサセル(基本セル) 2 多孔膜セパレータ(セパレータ) 3 集電体 4 ガスケット 5 プラス電極 6 マイナス電極 7 電気二重層コンデンサ 8 電気二重層コンデンサ素子 9 無孔膜部分または微多孔膜部分 DESCRIPTION OF SYMBOLS 1 Electric double layer capacitor cell (basic cell) 2 Porous membrane separator (separator) 3 Current collector 4 Gasket 5 Positive electrode 6 Negative electrode 7 Electric double layer capacitor 8 Electric double layer capacitor element 9 Nonporous membrane part or microporous membrane part

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 電気二重層コンデンサセルの多孔膜セパ
レータそのものに無孔膜部分または微孔膜部分を形成す
ることにより、孔径及び空孔率を変化させプラス電極及
びマイナス電極間の電解液中イオンの透過特性及び電極
粒子の分離特性を制御し、電気的特性を自由にコントロ
ールした電気二重層コンデンサ。
1. A method of forming a nonporous membrane portion or a microporous membrane portion on a porous membrane separator itself of an electric double-layer capacitor cell to change a pore diameter and a porosity, thereby causing ions in an electrolyte between a plus electrode and a minus electrode to change. Electric double layer capacitor that controls the electrical characteristics freely by controlling the transmission characteristics and separation characteristics of electrode particles.
JP2001049232A 2001-02-23 2001-02-23 Electric double-layer capacitor Pending JP2002252146A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001049232A JP2002252146A (en) 2001-02-23 2001-02-23 Electric double-layer capacitor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001049232A JP2002252146A (en) 2001-02-23 2001-02-23 Electric double-layer capacitor

Publications (1)

Publication Number Publication Date
JP2002252146A true JP2002252146A (en) 2002-09-06

Family

ID=18910367

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001049232A Pending JP2002252146A (en) 2001-02-23 2001-02-23 Electric double-layer capacitor

Country Status (1)

Country Link
JP (1) JP2002252146A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011082364A (en) * 2009-10-07 2011-04-21 Seiko Instruments Inc Electrolyte for electric double layer capacitor, and electric double layer capacitor using the same
CN103151181A (en) * 2011-12-07 2013-06-12 太阳诱电株式会社 Electrochemical device and separator for electrochemical device
JP2013211193A (en) * 2012-03-30 2013-10-10 Tdk Corp Porous sheet and secondary battery using same
JP2016026400A (en) * 2010-08-18 2016-02-12 セイコーインスツル株式会社 Electric double layer capacitor

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011082364A (en) * 2009-10-07 2011-04-21 Seiko Instruments Inc Electrolyte for electric double layer capacitor, and electric double layer capacitor using the same
JP2016026400A (en) * 2010-08-18 2016-02-12 セイコーインスツル株式会社 Electric double layer capacitor
CN103151181A (en) * 2011-12-07 2013-06-12 太阳诱电株式会社 Electrochemical device and separator for electrochemical device
JP2013120832A (en) * 2011-12-07 2013-06-17 Taiyo Yuden Co Ltd Separator for electrochemical device, and electrochemical device
US8953302B2 (en) 2011-12-07 2015-02-10 Taiyo Yuden Co., Ltd. Electrochemical device and a separator for electrochemical device
JP2013211193A (en) * 2012-03-30 2013-10-10 Tdk Corp Porous sheet and secondary battery using same

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