JP2002227325A - Construction method and structure for fire compartment penetration part - Google Patents

Construction method and structure for fire compartment penetration part

Info

Publication number
JP2002227325A
JP2002227325A JP2001147930A JP2001147930A JP2002227325A JP 2002227325 A JP2002227325 A JP 2002227325A JP 2001147930 A JP2001147930 A JP 2001147930A JP 2001147930 A JP2001147930 A JP 2001147930A JP 2002227325 A JP2002227325 A JP 2002227325A
Authority
JP
Japan
Prior art keywords
tape
shaped molded
molded body
resin
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001147930A
Other languages
Japanese (ja)
Inventor
Kazuhiro Okada
和廣 岡田
Masaki Tono
正樹 戸野
Hitomi Muraoka
仁美 村岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sekisui Chemical Co Ltd
Original Assignee
Sekisui Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sekisui Chemical Co Ltd filed Critical Sekisui Chemical Co Ltd
Priority to JP2001147930A priority Critical patent/JP2002227325A/en
Publication of JP2002227325A publication Critical patent/JP2002227325A/en
Pending legal-status Critical Current

Links

Landscapes

  • Building Environments (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a construction method and a structure for a fire compartment penetration part for preventing heat, fire, smoke and the like generated on one side of a partition part in the fire compartment penetration part from reaching the outer side even if a resin pipe, a cable, or a thermally insulated coated pipe constructed through the fire compartment is deformed or burnt in a fire. SOLUTION: In this fire compartment penetration part 5 construction method, the resin pipe, the cable, or the thermally insulated coated pipe 1 penetrating the fire compartment 3 arranged in the partition part of the building is passe through the fire compartment penetrating part 5. The fire compartment penetration part of the resin pipe, the cable, or the thermally insulated coated pipe 1 is wound with a tape type molding body 2 made of an adhesive thermally expansible material having an expansive magnification of 3-40 times in heating under quantity of radiating heat of 50 kw/m2, and then, a clearance between the fire compartment penetration part 5 and the resin pipe, the cable, or the thermally insulated coated pipe 1 is filled up with morter, a nonflammable material, or putty 4.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、建築物の仕切り部
に設けられた防火区画貫通部を貫通して施工される樹脂
配管、ケーブル、又は断熱被覆管に、防火措置を施すた
めの防火区画貫通部の施工方法、及び防火区画貫通部構
造に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fire protection compartment for applying a fire protection measure to a resin pipe, a cable, or a heat insulating cladding pipe which is constructed to penetrate a fire protection compartment penetrating portion provided in a partition of a building. The present invention relates to a method for constructing a penetration portion and a fire penetration section penetration portion structure.

【0002】[0002]

【従来の技術】通常、建築物の床、壁、間仕切り等の仕
切り部に配管を貫通させる場合は、配管等を貫通させる
ための貫通孔(区画貫通部)を設け、この区画貫通部に
配管(給排水管、電線管、冷媒管、ダクト等)を貫通さ
せる。この区画貫通部が防火区画貫通部の場合は、配管
やケーブルとの間隙に防耐火のためモルタル等の充填剤
を充填して閉塞するための防火措置工法が行われてい
る。上記充填剤による間隙の閉塞は、仕切り部の一方の
側で発生した火災による熱、火炎、煙等が他方の側へ到
達するのを遅らせたり、防止するために必要な措置であ
る。
2. Description of the Related Art In general, when pipes are to penetrate through a partition such as a floor, a wall or a partition of a building, a through hole (a section penetrating section) for penetrating the pipe or the like is provided, and a pipe is formed in the section penetrating section. (Water supply / drainage pipes, electric conduits, refrigerant pipes, ducts, etc.). In the case where the section penetration portion is a fire prevention section penetration portion, a fire-prevention method is employed in which a gap such as a pipe or a cable is filled with a filler such as mortar or the like for fire prevention and closed. The clogging of the gap by the filler is a necessary measure for delaying or preventing heat, flame, smoke and the like from the fire generated on one side of the partition from reaching the other side.

【0003】上記配管が金属管等のそれ自体に耐熱性、
不燃性を有する配管の場合は、防火区画貫通部に従来の
防火措置工法を採用しても特に問題はないが、配管が、
硬質塩化ビニル管や架橋ポリエチレン管等の合成樹脂
管、ケーブル、又は断熱被覆金属管や断熱被覆樹脂管等
の断熱被覆管の場合は、上記防火措置工法を採用する
と、配管自体やケーブルや断熱被覆管の被覆材が燃焼性
であったり、耐熱性に劣るため、火災時に合成樹脂や被
覆材が燃焼により焼失したり、熱変形を起こしたりして
防火区画貫通部に隙間が形成され、仕切り部の一方の側
で発生した熱、火炎、煙等が他方側へ到達するのを防止
することができなかった。
[0003] The above-mentioned pipe has heat resistance to itself such as a metal pipe,
In the case of non-combustible piping, there is no particular problem even if the conventional fire protection method is adopted for the fire penetration section penetration part, but the piping is
In the case of synthetic resin pipes such as hard vinyl chloride pipes or cross-linked polyethylene pipes, cables, or heat-insulating cladding pipes such as heat-insulating metal pipes or heat-insulating coating resin pipes, if the above fire prevention method is adopted, the piping itself, cables, and heat-insulating coatings will be used. Since the coating material of the pipe is flammable or inferior in heat resistance, a gap is formed in the penetration part of the fire protection compartment due to the burning of the synthetic resin and the coating material or the occurrence of thermal deformation in the event of a fire. It was not possible to prevent heat, flame, smoke and the like generated on one side of the steel from reaching the other side.

【0004】上記問題点を解決するために、加熱に際し
て膨張する材料により、火災によって生じた隙間を埋め
る区画貫通措置キット(以下、単にキットという)が各
社から上市されている(例えば、古河テクノマテリアル
社製「ヒートメル」等)。これらのキットは、確かにそ
の効果を発揮するが、キットであるが故に、各種樹脂
管、ケーブル、又は冷媒管等の径に合わせたものをそれ
ぞれ用意する必要があり、区画貫通部の少ない現場では
特に問題はないが、多種多様の区画貫通部が存在する現
場では、それぞれに対応するキットが必要となり、混乱
を招く恐れがあった。また、これらのキットはコストが
高いため、安価な防火区画貫通措置方法が求められてい
た。
[0004] In order to solve the above-mentioned problems, kits for section penetrating measures (hereinafter, simply referred to as kits) for filling gaps caused by a fire with a material that expands when heated are marketed by various companies (for example, Furukawa Techno Material). "Heat Mel" etc.). Although these kits certainly exert their effects, it is necessary to prepare various types of resin pipes, cables, or refrigerant pipes, etc., because they are kits. Then, there is no particular problem, but in a site where various types of section penetration parts exist, a kit corresponding to each is required, which may cause confusion. In addition, since these kits are expensive, an inexpensive method for penetrating the fire protection compartment has been required.

【0005】[0005]

【発明が解決しようとする課題】本発明は、上記に鑑
み、防火区画を貫通して施工された樹脂配管、ケーブ
ル、又は断熱被覆管が火災時に変形したり、焼失するよ
うなことがあっても、防火区画貫通部の仕切り部の一方
の側で発生した熱、火炎、煙等が他方側へ到達するのを
防止する防火区画貫通部の施工方法、及び防火区画貫通
部構造を提供することを目的とする。
DISCLOSURE OF THE INVENTION In view of the above, the present invention has been made in view of the fact that a resin pipe, a cable, or a heat insulating cladding pipe constructed through a fire protection compartment may be deformed or burned out in a fire. In addition, the present invention provides a method for constructing a fire protection section penetration part for preventing heat, flame, smoke, etc. generated on one side of a partition part of the fire protection section penetration part from reaching the other side, and a fire protection section penetration part structure. With the goal.

【0006】[0006]

【課題を解決するための手段】本発明の防火区画貫通部
の施工方法、及び防火区画貫通部構造は、建築物の仕切
り部に設けられた防火区画を貫通する樹脂配管、ケーブ
ル、又は断熱被覆管が挿通される防火区画貫通部の施工
方法において、該樹脂配管、ケーブル、又は断熱被覆管
の防火区画貫通部分に、50kw/m2の照射熱量下で
加熱したときの膨張倍率が3〜40倍であり、且つ粘着
性を有する熱膨張性材料からなるテープ状成形体を巻き
付けた後、防火区画貫通部と樹脂配管、ケーブル、又は
断熱被覆管との間隙をモルタル、不燃材料、又はパテで
埋め戻すことを特徴とする。
SUMMARY OF THE INVENTION According to the present invention, there is provided a method for constructing a penetration section of a fire protection section, and a structure of the penetration section for a fire section, wherein a resin pipe, a cable, or a heat insulating coating penetrating a fire section provided in a partition section of a building. In the method for constructing a penetration section of a fire protection section through which a pipe is inserted, an expansion ratio when the resin pipe, cable, or heat insulation cladding pipe is heated under an irradiation heat of 50 kW / m 2 is 3 to 40. After winding a tape-shaped molded body made of a heat-expandable material that is twice as sticky, the gap between the fire-prevention section penetrating portion and the resin pipe, cable, or heat-insulated coating pipe is mortar, a non-combustible material, or putty. It is characterized by backfilling.

【0007】以下に、本発明の防火区画貫通部の施工方
法、及び防火区画貫通部構造につき詳細に説明する。図
1の斜視図に示すように、まず、樹脂配管、ケーブル、
又は断熱被覆管1の外面に、粘着性を有する熱膨張性材
料からなるテープ状成形体2をその粘着性を利用して巻
き付ける。(図1は樹脂配管にテープ状成形体を巻き付
けた状態を示したが、ケーブル、断熱被覆管についても
同様に巻き付けることができる)。次いで、テープ状成
形体2が巻き付けられた樹脂配管、ケーブル、又は断熱
被覆管1は、図2の模式斜視図に示すように、建築物の
仕切り部である防火区画3(スラブ等)に設けられた防
火区画貫通部5(貫通孔)に挿通される。
Hereinafter, the method for constructing a fire protection section penetration portion and the fire protection section penetration portion structure of the present invention will be described in detail. As shown in the perspective view of FIG. 1, first, a resin pipe, a cable,
Alternatively, a tape-shaped molded body 2 made of an adhesive heat-expandable material is wound around the outer surface of the heat insulating cladding tube 1 by utilizing the adhesiveness. (FIG. 1 shows a state in which a tape-shaped molded body is wound around a resin pipe, but a cable and a heat insulating covering tube can be wound similarly.) Next, as shown in the schematic perspective view of FIG. 2, the resin pipe, the cable, or the heat insulating cladding tube 1 around which the tape-shaped molded body 2 is wound is provided in a fire protection section 3 (slab or the like) which is a partition of a building. The fire protection compartment penetrating portion 5 (through hole) is inserted.

【0008】また、防火区画貫通部5(貫通孔)に既に
樹脂配管、ケーブル、又は断熱被覆管が施工されている
場合は、貫通孔内で巻き付け作業を行う。また、少なく
とも片面に離型基材が積層された上記テープ状成形体
を、樹脂配管、ケーブル、又は断熱被覆管に該離型基材
面側が内側になるように少なくとも一周巻き付けた後、
テープ状成形体の重なり部分の離型基材を剥離し、その
粘着性を利用して固定した後、貫通部にスライドさせて
挿通させてもよい。また、少なくとも片面に基材又は離
型基材が積層された上記テープ状成形体を、樹脂配管、
ケーブル、又は断熱被覆管に該基材又は離型基材面側が
内側になるように少なくとも一周巻き付けた後、粘着テ
ープでテープ状成形体を固定した後、貫通部にスライド
させて挿通させてもよい。
When a resin pipe, a cable, or a heat insulating cladding tube has already been installed in the fire protection section penetration portion 5 (through hole), winding work is performed in the through hole. Further, after winding the tape-shaped molded body having a release substrate laminated on at least one surface, at least one round so that the release substrate surface side is inside the resin pipe, cable, or heat insulation coating tube,
The release base material at the overlapping portion of the tape-shaped molded body may be peeled off, fixed using the adhesiveness, and then slid into the penetrating portion and inserted. Further, the tape-shaped molded body having a substrate or a release substrate laminated on at least one surface, a resin pipe,
After wrapping at least one round so that the base material or the release base material side is on the inside of the cable or the heat insulating coating tube, after fixing the tape-like molded body with the adhesive tape, it may be slid and inserted into the through portion. Good.

【0009】次に、図3に模式断面図を示したように、
テープ状成形体2が巻き付けられた樹脂配管、ケーブ
ル、又は断熱被覆管1と、防火区画貫通部5との間隙に
モルタル、不燃材料、又はパテ4が埋め戻しされる。上
記テープ状成形体2が巻き付けられた樹脂配管、ケーブ
ル、又は断熱被覆管1は、火災時の加熱によって熱変形
を起こしたり、焼失して隙間を生じても、テープ状成形
体2が燃焼熱により膨張して膨張断熱層を形成して間隙
を閉塞し、熱伝導を抑制することによって、仕切り部の
一方の側で発生した熱、火炎、煙等が他方側へ到達する
のを防止する。上記不燃材料としては、ロックウール、
セラミックウール、ガラスウール等が挙げられる。
Next, as shown in a schematic sectional view in FIG.
The mortar, non-combustible material, or putty 4 is back-filled in the gap between the resin pipe, cable, or heat-insulating cladding tube 1 around which the tape-shaped molded body 2 is wound and the fire-prevention section penetration portion 5. Even if the resin pipe, cable, or heat-insulating cladding tube 1 around which the tape-shaped molded body 2 is wound undergoes thermal deformation due to heating in a fire or is burned out and a gap is formed, the tape-shaped molded body 2 generates heat. As a result, an expansion heat insulating layer is formed to close the gap and suppress heat conduction, thereby preventing heat, flame, smoke, and the like generated on one side of the partition from reaching the other side. Rock wool,
Examples include ceramic wool and glass wool.

【0010】上記テープ状成形体2の幅が防火区画貫通
部5の厚さより短い場合は、防火区画貫通部5の厚さ方
向に略均等となるように配置することが好ましいが、貫
通部のどちらかの面に片寄って配置されてもよい。ま
た、防火区画貫通部5の厚さより長い場合は、防火区画
貫通部5の両側への突出長さが略均等となるように配置
することが好ましい。また、テープ状成形体2が巻き付
けられた樹脂配管、ケーブル、又は断熱被覆管1は、防
火区画貫通部5の貫通孔において略中央となるように配
置することが好ましい。
When the width of the tape-shaped molded body 2 is shorter than the thickness of the fire-prevention section penetrating portion 5, it is preferable to arrange the tape-like molded body 2 so as to be substantially uniform in the thickness direction of the fire-prevention section penetrating section 5. It may be arranged offset to either side. In addition, when the thickness is longer than the thickness of the fire protection section penetration portion 5, it is preferable that the protrusions on both sides of the fire protection section penetration portion 5 are arranged to be substantially equal. Further, it is preferable that the resin pipe, the cable, or the heat-insulating cladding tube 1 around which the tape-shaped molded body 2 is wound be disposed so as to be substantially at the center of the through-hole of the fire-prevention section through portion 5.

【0011】上記テープ状成形体の厚みは、0.3〜6
mmが好ましい。厚みが0.3mm未満になると必要な
巻き付け厚みを得るのに何回も巻き付ける必要があり、
6mmを超えると所定の厚みに巻き付けることが難しく
なる。
[0011] The thickness of the tape-shaped molded product is 0.3 to 6
mm is preferred. When the thickness is less than 0.3 mm, it is necessary to wind many times to obtain the required winding thickness,
If it exceeds 6 mm, it becomes difficult to wind it to a predetermined thickness.

【0012】上記テープ状成形体の巻き付け厚みは、挿
通される樹脂配管、ケーブル、又は断熱被覆管の外径の
0.5〜20%となされることが好ましい。巻き付け厚
みが、樹脂配管、ケーブル、又は断熱被覆管の外径の
0.5%未満になると火災時に十分な膨張断熱層が形成
されず、20%を超えると貫通部の開口面積を大きくし
なければならなくなる。
[0012] It is preferable that the winding thickness of the tape-shaped molded body is 0.5 to 20% of the outer diameter of the resin pipe, cable, or heat insulating cladding tube to be inserted. If the winding thickness is less than 0.5% of the outer diameter of the resin pipe, cable, or heat-insulating cladding tube, a sufficient expansion heat-insulating layer is not formed at the time of fire, and if it exceeds 20%, the opening area of the penetration portion must be increased. Have to be.

【0013】上記テープ状成形体の幅は、防火区画貫通
部の厚みの25〜150%が好ましい。厚みの25%未
満になると火災時に十分な膨張断熱層が形成されず、1
50%を超えると貫通部の際で配管を曲げることができ
なくなり、配管設計の自由度が小さくなる。
The width of the tape-shaped molded body is preferably 25 to 150% of the thickness of the fire section penetration part. If the thickness is less than 25%, a sufficient heat-insulating layer is not formed during a fire, and
If it exceeds 50%, it becomes impossible to bend the pipe in the case of the penetrating portion, and the degree of freedom in designing the pipe is reduced.

【0014】上記熱膨張性材料からなるテープ状成形体
は、50kw/m2の照射熱量下で加熱したときの膨張
倍率(初期厚みに対する膨張後の厚みの比)が3〜40
倍であり、火災時に防火区画貫通部と樹脂配管、ケーブ
ル、又は断熱被覆管との隙間を閉塞して、耐火断熱性を
発現し、粘着性を有するものであれば特に限定されない
が、下記樹脂組成物(I)又は(II)からなるものが好
ましい。
The tape-shaped molded body made of the above-mentioned heat-expandable material has an expansion ratio (ratio of the thickness after expansion to the initial thickness) of 3 to 40 when heated under the irradiation heat of 50 kW / m 2.
It is twice as large, and is not particularly limited as long as it closes the gap between the fire protection section penetration portion and the resin pipe, cable, or heat insulating cladding tube at the time of fire, expresses fire resistance and heat resistance, and has adhesiveness. Those comprising the composition (I) or (II) are preferred.

【0015】樹脂組成物(I)としては、ゴム成分を含
む樹脂成分、中和処理された熱膨張性黒鉛及び無機充填
剤を含有するものが用いられる。
As the resin composition (I), a resin composition containing a resin component containing a rubber component, neutralized heat-expandable graphite and an inorganic filler is used.

【0016】上記ゴム成分としては、例えば、天然ゴム
(NR)、イソプレンゴム(IR)、ブタジエンゴム
(BR)、1,2−ポリブタジエンゴム(1,2−B
R)、スチレン−ブタジエンゴム(SBR)、クロロプ
レンゴム(CR)、ニトリルゴム(NBR)、ブチルゴ
ム(IIR)、エチレン−プロピレンゴム(EPM,E
PDM)、クロロスルホン化ポリエチレン(CSM)、
アクリルゴム(ACM,ANM)、エピクロルヒドリン
ゴム(CO,ECO)、多加硫ゴム(U)、シリコーン
ゴム(O)、フッ素ゴム(FKM,FZ)、ウレタンゴ
ム(U)、ポリイソブチレンゴム、塩化ブチルゴム等が
挙げられる。これらは単独で用いられてもよく、2種以
上が併用されてもよい。
Examples of the rubber component include natural rubber (NR), isoprene rubber (IR), butadiene rubber (BR), and 1,2-polybutadiene rubber (1,2-B
R), styrene-butadiene rubber (SBR), chloroprene rubber (CR), nitrile rubber (NBR), butyl rubber (IIR), ethylene-propylene rubber (EPM, E
PDM), chlorosulfonated polyethylene (CSM),
Acrylic rubber (ACM, ANM), epichlorohydrin rubber (CO, ECO), polyvulcanized rubber (U), silicone rubber (O), fluoro rubber (FKM, FZ), urethane rubber (U), polyisobutylene rubber, butyl chloride rubber, etc. Is mentioned. These may be used alone or in combination of two or more.

【0017】上記ゴム成分以外の樹脂成分としては、例
えば、ポリプロピレン系樹脂、ポリエチレン系樹脂、ポ
リ(1−)ブテン系樹脂、ポリペンテン系樹脂等のポリ
オレフィン系樹脂;ポリスチレン系樹脂、アクリロニト
リル−ブタジエン−スチレン系樹脂、ポリカーボネート
系樹脂、ポリフェニレンエーテル系樹脂、アクリル系樹
脂、ポリアミド系樹脂、ポリ塩化ビニル系樹脂、フェノ
ール系樹脂、ポリウレタン系樹脂等が挙げられる。これ
らは単独で用いられてもよく、2種以上が併用されても
よい。
Examples of resin components other than the rubber component include polyolefin resins such as polypropylene resin, polyethylene resin, poly (1-) butene resin and polypentene resin; polystyrene resins, acrylonitrile-butadiene-styrene. Resin, polycarbonate resin, polyphenylene ether resin, acrylic resin, polyamide resin, polyvinyl chloride resin, phenol resin, polyurethane resin and the like. These may be used alone or in combination of two or more.

【0018】上記樹脂成分には、樹脂組成物(I)の耐
火性を損なわない範囲で、変性、架橋等が施されてもよ
い。変性、架橋の方法は、特に限定されず、公知の方法
により行われる。
The above resin component may be subjected to modification, cross-linking, etc. as long as the fire resistance of the resin composition (I) is not impaired. The method of modification and crosslinking is not particularly limited, and is performed by a known method.

【0019】上記テープ状成形体は、樹脂配管、ケーブ
ル、又は断熱被覆管に巻き付ける際の施工を容易にする
ために、自己粘着性を有するものが好ましい。自己粘着
性が付与された樹脂組成物としては、特に限定されず、
例えば、ブチルゴムにポリブテン等の液状樹脂及び粘着
付与剤として石油樹脂が配合されたものが挙げられる。
The above-mentioned tape-shaped molded body preferably has self-adhesiveness in order to facilitate the work when wound around a resin pipe, a cable, or a heat insulating cladding tube. The resin composition to which self-adhesiveness is imparted is not particularly limited,
For example, butyl rubber mixed with a liquid resin such as polybutene and a petroleum resin as a tackifier may be used.

【0020】上記熱膨張性黒鉛は、従来公知の物質であ
り、天然鱗状グラファイト、熱分解グラファイト、キッ
シュグラファイト等の粉末を、濃硫酸、硝酸、セレン酸
等の無機酸と、濃硝酸、過塩素酸、過塩素酸塩、過マン
ガン酸塩、重クロム酸塩、過酸化水素等の強酸化剤とで
処理することにより生成するグラファイト層間化合物で
あり、炭素の層状構造を維持したままの結晶化合物であ
る。
The above-mentioned heat-expandable graphite is a conventionally known substance. Powder such as natural scaly graphite, pyrolytic graphite, and quiche graphite is mixed with an inorganic acid such as concentrated sulfuric acid, nitric acid and selenic acid, and concentrated nitric acid and perchloric acid. A graphite intercalation compound produced by treating with acids, perchlorates, permanganates, dichromates, and strong oxidants such as hydrogen peroxide, and is a crystalline compound that maintains the layered structure of carbon It is.

【0021】上述のように酸処理された熱膨張性黒鉛
を、更に、アンモニア、脂肪族低級アミン、アルカリ金
属化合物、アルカリ土類金属化合物等で中和する。本発
明では、この中和処理された熱膨張性黒鉛を使用する。
The heat-expandable graphite treated as described above is further neutralized with ammonia, an aliphatic lower amine, an alkali metal compound, an alkaline earth metal compound or the like. In the present invention, this neutralized heat-expandable graphite is used.

【0022】上記脂肪族低級アミンとしては、特に限定
されず、例えば、モノメチルアミン、ジメチルアミン、
トリメチルアミン、エチルアミン、プロピルアミン、ブ
チルアミン等が挙げられる。
The aliphatic lower amine is not particularly restricted but includes, for example, monomethylamine, dimethylamine,
Trimethylamine, ethylamine, propylamine, butylamine and the like.

【0023】上記アルカリ金属化合物及びアルカリ土類
金属化合物としては、特に限定されず、例えば、カリウ
ム、ナトリウム、カルシウム、バリウム、マグネシウム
等の水酸化物、酸化物、炭酸塩、硫酸塩、有機酸塩等が
挙げられる。
The above-mentioned alkali metal compound and alkaline earth metal compound are not particularly restricted but include, for example, hydroxides, oxides, carbonates, sulfates and organic acid salts of potassium, sodium, calcium, barium, magnesium and the like. And the like.

【0024】上記中和処理された熱膨張性黒鉛の粒度
は、20〜200メッシュが好ましい。粒度が200メ
ッシュより小さくなると、黒鉛の膨張度が小さく、所定
の膨張断熱層が得られず、粒度が20メッシュより大き
くなると、黒鉛の膨張度が大きいという利点はあるが、
後述の樹脂分と混練する際に分散性が悪くなり、物性の
低下が避けられない。
The particle size of the neutralized heat-expandable graphite is preferably 20 to 200 mesh. When the particle size is smaller than 200 mesh, the degree of expansion of graphite is small, a predetermined expanded heat insulating layer cannot be obtained, and when the particle size is larger than 20 mesh, there is an advantage that the degree of expansion of graphite is large,
When kneading with a resin component described later, dispersibility deteriorates, and a decrease in physical properties is inevitable.

【0025】上記中和処理された熱膨張性黒鉛の市販品
としては、例えば、東ソー社製「フレームカットGRE
P−EG」、UCAR Carbon社製「GRAFG
UARD」等が挙げられる。
As a commercially available product of the neutralized heat-expandable graphite, for example, “Frame Cut GRE” manufactured by Tosoh Corporation
P-EG "," GRAFG "manufactured by UCAR Carbon
UARD ”and the like.

【0026】上記無機充填剤としては、特に限定され
ず、例えば、アルミナ、酸化亜鉛、酸化チタン、酸化カ
ルシウム、酸化マグネシウム、酸化鉄、酸化錫、酸化ア
ンチモン、フェライト類等の金属酸化物;水酸化カルシ
ウム、水酸化マグネシウム、水酸化アルミニウム、ハイ
ドロタルサイト等の含水無機物;塩基性炭酸マグネシウ
ム、炭酸カルシウム、炭酸マグネシウム、炭酸亜鉛、炭
酸ストロンチウム、炭酸バリウム等の金属炭酸塩;硫酸
カルシウム、石膏繊維、ケイ酸カルシウム等のカルシウ
ム塩;シリカ、珪藻土、ドーソナイト、硫酸バリウム、
タルク、クレー、マイカ、モンモリロナイト、ベントナ
イト、活性白土、セピオライト、イモゴライト、セリサ
イト、ガラス繊維、ガラスビーズ、シリカ系バルン、窒
化アルミニウム、窒化ホウ素、窒化ケイ素、カーボンブ
ラック、グラファイト、炭素繊維、炭素バルン、木炭粉
末、各種金属粉、チタン酸カリウム、硫酸マグネシウム
「MOS」(商品名)、チタン酸ジルコン酸鉛、アルミ
ニウムボレート、硫化モリブデン、炭化ケイ素、ステン
レス繊維、ホウ酸亜鉛、各種磁性粉、スラグ繊維、フラ
イアッシュ等が挙げられる。これらの無機充填剤は単独
で用いても、2種以上を併用してもよい。
The inorganic filler is not particularly restricted but includes, for example, metal oxides such as alumina, zinc oxide, titanium oxide, calcium oxide, magnesium oxide, iron oxide, tin oxide, antimony oxide and ferrites; Water-containing inorganic substances such as calcium, magnesium hydroxide, aluminum hydroxide, and hydrotalcite; metal carbonates such as basic magnesium carbonate, calcium carbonate, magnesium carbonate, zinc carbonate, strontium carbonate, and barium carbonate; calcium sulfate, gypsum fiber, and silica Calcium salts such as calcium acid; silica, diatomaceous earth, dawsonite, barium sulfate,
Talc, clay, mica, montmorillonite, bentonite, activated clay, sepiolite, imogolite, sericite, glass fiber, glass beads, silica-based balun, aluminum nitride, boron nitride, silicon nitride, carbon black, graphite, carbon fiber, carbon balun, Charcoal powder, various metal powders, potassium titanate, magnesium sulfate “MOS” (trade name), lead zirconate titanate, aluminum borate, molybdenum sulfide, silicon carbide, stainless steel fiber, zinc borate, various magnetic powders, slag fiber, Fly ash and the like. These inorganic fillers may be used alone or in combination of two or more.

【0027】上記無機充填剤の中では、特に含水無機物
及び/又は金属炭酸塩が好ましい。含水無機物と金属炭
酸塩は、骨材的な働きをするところから、燃焼残渣の強
度向上や熱容量の増大に寄与するものと考えられる。特
に、周期律表II族又はIII族に属する金属の炭酸塩
(炭酸カルシウム、炭酸マグネシウム)は、樹脂組成物
(I)の燃焼時に発泡して焼成物を形成するため、形状
保持性を高める点から好ましい。
Among the above inorganic fillers, hydrated inorganic substances and / or metal carbonates are particularly preferred. It is considered that the hydrated inorganic substance and the metal carbonate contribute to the improvement of the strength of the combustion residue and the increase of the heat capacity because they function as aggregate. In particular, a carbonate (calcium carbonate, magnesium carbonate) of a metal belonging to Group II or Group III of the periodic table foams when the resin composition (I) is burned to form a baked product, and thus enhances shape retention. Is preferred.

【0028】上記水酸化カルシウム、水酸化マグネシウ
ム、水酸化アルミニウム等の含水無機物は、加熱時の脱
水反応によって生成した水のために吸熱が起こり、温度
上昇が低減されて高い耐熱性が得られる点、及び、加熱
残渣として酸化物が残存し、これが骨材となって働くこ
とで残渣強度が向上する点で特に好ましい。水酸化マグ
ネシウムと水酸化アルミニウムは、脱水効果を発揮する
温度領域が異なるため、併用すると脱水効果を発揮する
温度領域が広がり、より効果的な温度上昇抑制効果が得
られる。
The above-mentioned water-containing inorganic substances such as calcium hydroxide, magnesium hydroxide, and aluminum hydroxide endothermic due to water generated by a dehydration reaction during heating, and the temperature rise is reduced to obtain high heat resistance. In addition, oxide remains as a heating residue, and this works as an aggregate, which is particularly preferable in that the residue strength is improved. Magnesium hydroxide and aluminum hydroxide have different temperature ranges in which the dehydration effect is exerted. Therefore, when used in combination, the temperature range in which the dehydration effect is exerted expands, and a more effective temperature rise suppression effect is obtained.

【0029】上記無機充填剤の粒径としては、0.5〜
100μmが好ましく、より好ましくは1〜50μmで
ある。上記無機充填剤は、添加量が少ないときは、分散
性が性能を大きく左右するため、粒径の小さいものが好
ましいが、0.5μm未満になると二次凝集が起こり、
分散性が悪くなる。添加量が多いときは、高充填が進む
につれて、樹脂組成物の粘度が高くなり成形性が低下す
るが、粒径を大きくすることで樹脂組成物の粘度を低下
させることができる点から、粒径の大きいものが好まし
い。また、粒径が100μmを超えると、成形体の表面
性、樹脂組成物の力学的物性が低下する。
The particle size of the inorganic filler is 0.5 to
It is preferably 100 μm, more preferably 1 to 50 μm. When the amount of the inorganic filler is small, since the dispersibility greatly affects the performance, a small particle size is preferable, but when the particle size is less than 0.5 μm, secondary aggregation occurs.
Dispersibility deteriorates. When the addition amount is large, as the high filling proceeds, the viscosity of the resin composition increases and the moldability decreases.However, by increasing the particle size, the viscosity of the resin composition can be reduced. Those having a large diameter are preferred. On the other hand, when the particle size exceeds 100 μm, the surface properties of the molded article and the mechanical properties of the resin composition deteriorate.

【0030】また、上記無機充填剤は、粒径の大きいも
のと粒径の小さいものを組み合わせて使用することがよ
り好ましく、組み合わせて用いることによって、膨張断
熱層の力学的性能を維持したまま、高充填化することが
可能となる。
It is more preferable to use a combination of the above-mentioned inorganic filler having a large particle diameter and a small particle having a small particle diameter. High filling is possible.

【0031】上記無機充填剤としては、例えば、水酸化
アルミニウムである粒径1μmの「ハイジライト H−
42M」(昭和電工社製)、粒径18μmの「ハイジラ
イトH−31」(昭和電工社製)、及び、炭酸カルシウ
ムである粒径1.8μmの「ホワイトンSB赤」(白石
カルシウム社製)、粒径8μmの「BF300」(備北
粉化工社製)等が挙げられる。
As the inorganic filler, for example, aluminum hydroxide “Hygilite H-particle having a particle size of 1 μm” is used.
42M "(manufactured by Showa Denko KK)," Heidilite H-31 "having a particle size of 18 m (manufactured by Showa Denko KK), and" Whiteton SB red "having a particle size of 1.8 m, which is calcium carbonate (manufactured by Shiraishi Calcium Co., Ltd.) ), And “BF300” (manufactured by Bihoku Powder Chemical Co., Ltd.) having a particle size of 8 μm.

【0032】上記樹脂組成物(I)において、中和処理
された熱膨張性黒鉛の配合量は、樹脂成分100重量部
に対して15〜300重量部が好ましい。配合量が、1
5重量部未満では、十分な厚さの耐火断熱層が形成され
ないため耐火性能が低下し、300重量部を超えると機
械的強度の低下が大きく、使用に耐えられなくなる。
In the resin composition (I), the amount of the neutralized heat-expandable graphite is preferably 15 to 300 parts by weight based on 100 parts by weight of the resin component. The amount is 1
If the amount is less than 5 parts by weight, a fire-resistant heat-insulating layer having a sufficient thickness is not formed, so that the fire resistance is deteriorated. If the amount exceeds 300 parts by weight, the mechanical strength is greatly reduced, and it cannot be used.

【0033】上記樹脂組成物(I)において、無機充填
剤の配合量は、樹脂成分100重量部に対して30〜5
00重量部が好ましい。配合量が、30重量部未満で
は、熱容量の低下に伴い十分な耐火性が得られなくな
り、500重量部を超えると機械的強度の低下が大き
く、使用に耐えられなくなる。
In the resin composition (I), the amount of the inorganic filler is from 30 to 5 per 100 parts by weight of the resin component.
00 parts by weight is preferred. If the amount is less than 30 parts by weight, sufficient heat resistance cannot be obtained due to the decrease in heat capacity, and if it exceeds 500 parts by weight, the mechanical strength is greatly reduced and the product cannot be used.

【0034】また、上記中和処理された熱膨張性黒鉛及
び無機充填剤の総量は、樹脂成分100重量部に対して
200〜600重量部が好ましい。総量が、200重量
部未満になると十分な耐火性が得られず、600重量部
を超えると機械的強度の低下が大きく、使用に耐えられ
なくなる。
The total amount of the neutralized heat-expandable graphite and inorganic filler is preferably 200 to 600 parts by weight based on 100 parts by weight of the resin component. If the total amount is less than 200 parts by weight, sufficient fire resistance cannot be obtained, and if the total amount exceeds 600 parts by weight, the mechanical strength is greatly reduced, and it cannot be used.

【0035】上記樹脂組成物(II)としては、ゴム成分
を含む樹脂成分、リン化合物、中和処理された熱膨張性
黒鉛及び無機充填剤を含有するものが用いられる。上記
樹脂組成物(II)で用いられる中和処理された熱膨張性
黒鉛及び無機充填剤は、樹脂組成物(I)と同様であ
る。
As the resin composition (II), a resin composition containing a resin component including a rubber component, a phosphorus compound, neutralized heat-expandable graphite and an inorganic filler is used. The neutralized heat-expandable graphite and inorganic filler used in the resin composition (II) are the same as those in the resin composition (I).

【0036】樹脂組成物(II)において、リン化合物を
配合することにより、難燃性、燃焼残渣の形状保持力が
向上する。
By blending a phosphorus compound in the resin composition (II), flame retardancy and shape retention of combustion residues are improved.

【0037】上記リン化合物としては、特に限定され
ず、例えば、赤リン;トリフェニルホスフェート、トリ
クレジルホスフェート、トリキシレニルホスフェート、
クレジルジフェニルホスフェート、キシレニルジフェニ
ルホスフェート等の各種リン酸エステル;リン酸ナトリ
ウム、リン酸カリウム、リン酸マグネシウム等のリン酸
金属塩;ポリリン酸アンモニウム類;下記一般式(1)
で表される化合物等が挙げられる。これらのうち、耐火
性の観点から、赤リン、ポリリン酸アンモニウム類、及
び、下記一般式(1)で表される化合物が好ましく、性
能、安全性、費用等の点においてポリリン酸アンモニウ
ム類がより好ましい。
The phosphorus compound is not particularly restricted but includes, for example, red phosphorus; triphenyl phosphate, tricresyl phosphate, trixylenyl phosphate,
Various phosphoric esters such as cresyl diphenyl phosphate and xylendiphenyl phosphate; metal phosphates such as sodium phosphate, potassium phosphate and magnesium phosphate; ammonium polyphosphates;
And the like. Among these, from the viewpoint of fire resistance, red phosphorus, ammonium polyphosphates, and compounds represented by the following general formula (1) are preferable, and ammonium polyphosphates are more preferable in terms of performance, safety, cost, and the like. preferable.

【0038】[0038]

【化1】 Embedded image

【0039】式中、R1及びR3は、水素、炭素数1〜1
6の直鎖状若しくは分岐状のアルキル基、又は、炭素数
6〜16のアリール基を表す。R2は、水酸基、炭素数
1〜16の直鎖状若しくは分岐状のアルキル基、炭素数
1〜16の直鎖状若しくは分岐状のアルコキシル基、炭
素数6〜16のアリール基、又は、炭素数6〜16のア
リールオキシ基を表す。
In the formula, R 1 and R 3 are hydrogen, C 1 -C 1
6 represents a linear or branched alkyl group or an aryl group having 6 to 16 carbon atoms. R 2 is a hydroxyl group, a linear or branched alkyl group having 1 to 16 carbon atoms, a linear or branched alkoxyl group having 1 to 16 carbon atoms, an aryl group having 6 to 16 carbon atoms, Represents an aryloxy group represented by Formulas 6 to 16.

【0040】上記赤リンは、少量の添加で難燃効果を向
上する。上記赤リンとしては、市販の赤リンを用いるこ
とができるが、耐湿性、混練時に自然発火しない等の安
全性の点から、赤リン粒子の表面を樹脂でコーティング
したもの等が好適に用いられる。
The above-mentioned red phosphorus improves the flame-retardant effect by adding a small amount. As the red phosphorus, commercially available red phosphorus can be used, but from the viewpoint of moisture resistance, safety such as not spontaneously igniting during kneading, those obtained by coating the surface of red phosphorus particles with a resin are preferably used. .

【0041】上記ポリリン酸アンモニウム類としては、
特に限定されず、例えば、ポリリン酸アンモニウム、メ
ラミン変性ポリリン酸アンモニウム等が挙げられるが、
取扱性等の点からポリリン酸アンモニウムが好適に用い
られる。市販品としては、例えば、クラリアント社製
「EXOLIT AP422」、「EXOLIT AP
462」、住友化学工業社製「スミセーフP」、チッソ
社製「テラージュC60」、「テラージュC70」、
「テラージュC80」等が挙げられる。
The above ammonium polyphosphates include:
Not particularly limited, for example, ammonium polyphosphate, melamine-modified ammonium polyphosphate and the like,
Ammonium polyphosphate is preferably used in terms of handleability and the like. Commercially available products include, for example, “EXOLIT AP422” and “EXOLIT AP” manufactured by Clariant.
462 ", Sumitomo Chemical Co., Ltd." Sumisafe P ", Chisso Corp." Terage C60 "," Terage C70 ",
"Terage C80" and the like.

【0042】上記一般式(1)で表される化合物として
は、特に限定されず、例えば、メチルホスホン酸、メチ
ルホスホン酸ジメチル、メチルホスホン酸ジエチル、エ
チルホスホン酸、プロピルホスホン酸、ブチルホスホン
酸、2−メチルプロピルホスホン酸、t−ブチルホスホ
ン酸、2,3−ジメチル−ブチルホスホン酸、オクチル
ホスホン酸、フェニルホスホン酸、ジオクチルフェニル
ホスホネート、ジメチルホスフィン酸、メチルエチルホ
スフィン酸、メチルプロピルホスフィン酸、ジエチルホ
スフィン酸、ジオクチルホスフィン酸、フェニルホスフ
ィン酸、ジエチルフェニルホスフィン酸、ジフェニルホ
スフィン酸、ビス(4−メトキシフェニル)ホスフィン
酸等が挙げられる。なかでも、t−ブチルホスホン酸
は、高価ではあるが、高難燃性の点において好ましい。
上記リン化合物は単独で用いても、2種以上を併用して
もよい。
The compound represented by the above general formula (1) is not particularly restricted but includes, for example, methylphosphonic acid, dimethylmethylphosphonate, diethylmethylphosphonate, ethylphosphonic acid, propylphosphonic acid, butylphosphonic acid, 2-methyl Propylphosphonic acid, t-butylphosphonic acid, 2,3-dimethyl-butylphosphonic acid, octylphosphonic acid, phenylphosphonic acid, dioctylphenylphosphonate, dimethylphosphinic acid, methylethylphosphinic acid, methylpropylphosphinic acid, diethylphosphinic acid, Examples include dioctylphosphinic acid, phenylphosphinic acid, diethylphenylphosphinic acid, diphenylphosphinic acid, and bis (4-methoxyphenyl) phosphinic acid. Among them, t-butylphosphonic acid is expensive, but is preferable in terms of high flame retardancy.
The above phosphorus compounds may be used alone or in combination of two or more.

【0043】上記リン化合物は、特に炭酸カルシウム、
炭酸亜鉛等の金属炭酸塩との反応で膨張を促すと考えら
れ、特に、リン化合物としてポリリン酸アンモニウムを
使用した場合に、高い膨張効果が得られる。また、有効
な骨材として働き、燃焼後に形状保持性の高い燃焼残渣
を形成する。
The above phosphorus compound is preferably calcium carbonate,
It is considered that the reaction with a metal carbonate such as zinc carbonate promotes expansion. Particularly, when ammonium polyphosphate is used as a phosphorus compound, a high expansion effect is obtained. In addition, it acts as an effective aggregate and forms a combustion residue having high shape retention after burning.

【0044】上記樹脂組成物(II)において、リン化合
物の配合量は、樹脂成分100重量部に対して50〜1
50重量部が好ましい。配合量が、50重量部未満にな
ると燃焼残渣に十分な形状保持性が得られず、150重
量部を超えると機械的物性の低下が大きくなり、使用に
耐えられなくなる。
In the above resin composition (II), the compounding amount of the phosphorus compound is 50 to 1 with respect to 100 parts by weight of the resin component.
50 parts by weight are preferred. If the amount is less than 50 parts by weight, sufficient shape retention of the combustion residue cannot be obtained, and if the amount exceeds 150 parts by weight, the mechanical properties are greatly reduced, and the resin cannot be used.

【0045】上記樹脂組成物(II)において、中和処理
された熱膨張性黒鉛の配合量は、上記樹脂組成物(I)
と同様の理由により、樹脂成分100重量部に対して1
5〜300重量部が好ましい。
In the above resin composition (II), the blending amount of the neutralized heat-expandable graphite is as follows.
For the same reason as described above, 1 to 100 parts by weight of the resin component
5-300 parts by weight are preferred.

【0046】上記樹脂組成物(II)において、無機充填
剤の配合量は、上記樹脂組成物(I)と同様の理由によ
り、樹脂成分100重量部に対して30〜500重量部
が好ましい。
In the resin composition (II), the amount of the inorganic filler is preferably 30 to 500 parts by weight based on 100 parts by weight of the resin component for the same reason as in the resin composition (I).

【0047】また、上記リン化合物、中和処理された熱
膨張性黒鉛及び無機充填剤の総量は、樹脂成分100重
量部に対して200〜600重量部が好ましい。総量
が、200重量部未満になると十分な耐火性が得られ
ず、600重量部を超えると機械的強度の低下が大き
く、使用に耐えられなくなる。
The total amount of the phosphorus compound, the neutralized heat-expandable graphite and the inorganic filler is preferably from 200 to 600 parts by weight based on 100 parts by weight of the resin component. If the total amount is less than 200 parts by weight, sufficient fire resistance cannot be obtained, and if the total amount exceeds 600 parts by weight, the mechanical strength is greatly reduced, and it cannot be used.

【0048】上記樹脂組成物(I)及び(II)には、そ
の物性を損なわない範囲で、フェノール系、アミン系、
イオウ系等の酸化防止剤、金属害防止剤、帯電防止剤、
安定剤、架橋剤、滑剤、軟化剤、顔料等が添加されても
よい。
The resin compositions (I) and (II) may be phenol-based, amine-based or resin-based as long as their physical properties are not impaired.
Sulfur-based antioxidants, metal damage inhibitors, antistatic agents,
Stabilizers, crosslinking agents, lubricants, softeners, pigments and the like may be added.

【0049】上記樹脂組成物(I)及び(II)は、上記
各成分を、例えば、押出機、ニーダーミキサー、二本ロ
ール、バンバリーミキサー等、公知の混練装置を用いて
溶融混練することにより得ることができる。上記樹脂組
成物は、公知の方法で成形することにより、テープ状成
形体とすることができる。
The resin compositions (I) and (II) are obtained by melt-kneading the above-mentioned components using a known kneading apparatus such as an extruder, a kneader mixer, a two-roller, a Banbury mixer and the like. be able to. The resin composition can be formed into a tape-shaped molded body by molding by a known method.

【0050】上記テープ状成形体は、巻物の形態でもよ
く、また、樹脂配管、ケーブル、又は断熱被覆管に巻き
付ける長さに合わせて、あらかじめ切断されていてもよ
い。
The above-mentioned tape-shaped molded body may be in the form of a roll, or may be cut in advance in accordance with the length to be wound around a resin pipe, a cable, or a heat insulating cladding tube.

【0051】上記テープ状成形体には、加熱膨張性能を
損なわない範囲で、基材又は離型基材が積層されてもよ
い。基材としては、特に限定されず、例えば、紙、織
布、不織布、フィルム、金網、これら基材の積層体等が
用いられる。
A base material or a release base material may be laminated on the tape-shaped molded body as long as the heat expansion performance is not impaired. The substrate is not particularly limited, and examples thereof include paper, woven fabric, nonwoven fabric, film, wire mesh, and a laminate of these substrates.

【0052】上記紙としては、クラフト紙、和紙、Kラ
イナー紙等、公知のものを使用することができる。水酸
化アルミニウムや炭酸カルシウムを高充填した不燃紙;
難燃剤を配合したり、難燃剤を表面に塗布した難燃紙;
ロックウール、セラミックウール、ガラス繊維を用いた
無機繊維紙、炭素繊維紙等を使用すると耐火性を向上さ
せることができる。
As the paper, known papers such as kraft paper, Japanese paper, and K liner paper can be used. Non-combustible paper highly filled with aluminum hydroxide and calcium carbonate;
Flame-retardant paper with a flame retardant incorporated or a flame retardant applied to the surface;
When rock wool, ceramic wool, inorganic fiber paper using glass fiber, carbon fiber paper, or the like is used, fire resistance can be improved.

【0053】上記不織布としては、ポリプロピレン、ポ
リエステル、ナイロン、セルロース繊維等からなる湿式
不織布、長繊維不織布等を使用することができる。上記
フィルムとしては、ポリエチレン、ポリプロピレン、ポ
リアミド、ポリエステル、ナイロン、アクリル等の樹脂
フィルム等を使用することができる。上記金属箔として
は、アルミニウム箔、ステンレス箔等を使用することが
できる。上記金網としては、通常使用されている金網の
他に、金属ラス等が使用可能である。
As the nonwoven fabric, a wet nonwoven fabric made of polypropylene, polyester, nylon, cellulose fiber or the like, a long-fiber nonwoven fabric, or the like can be used. As the film, a resin film of polyethylene, polypropylene, polyamide, polyester, nylon, acrylic, or the like can be used. As the metal foil, an aluminum foil, a stainless steel foil, or the like can be used. As the wire mesh, a metal lath or the like can be used in addition to a wire mesh that is usually used.

【0054】また、これら基材の積層体を用いてもよ
く、例えば、ポリエチレンフィルム積層不織布、ポリプ
ロピレン積層不織布、アルミニウム箔積層紙、アルミガ
ラスクロス等が挙げられる。
Also, a laminate of these substrates may be used, and examples thereof include polyethylene film laminated nonwoven fabric, polypropylene laminated nonwoven fabric, aluminum foil laminated paper, and aluminum glass cloth.

【0055】上記離型基材は、特に制限はなく、シリコ
ーン処理等の通常の離型処理されているものが挙げら
れ、上記基材を離型処理したものを用いてもよい。
The release substrate is not particularly limited, and includes those subjected to a usual release treatment such as silicone treatment, and those obtained by subjecting the substrate to a release treatment may be used.

【0056】上記基材又は離型基材は、テープ状成形体
の片面又は両面に積層されてもよく、一方の片面に基材
を、他の片面に離型基材を積層させてもよい。また、基
材を2枚のテープ状成形体の間に挟み込んで使用しても
よい。
The base material or the release base material may be laminated on one side or both sides of the tape-shaped molded body, or the base material may be laminated on one side and the release substrate on the other side. . Further, the base material may be used by being sandwiched between two tape-shaped molded bodies.

【0057】上記離型基材を積層させたテープ状成形体
を用いる場合は、離型基材を剥離してから樹脂配管、ケ
ーブル、又は断熱被覆管に巻き付けてもよい。また、管
の外周の一周以上巻き付ける場合は、テープ状成形体の
重なり部分の離型基材のみを剥離して巻き付けてもよ
い。
In the case of using a tape-shaped molded product obtained by laminating the release substrate, the release substrate may be peeled off and then wound around a resin pipe, a cable, or a heat-insulating coated tube. When winding one or more rounds of the outer circumference of the tube, only the release substrate in the overlapping portion of the tape-shaped molded body may be peeled off and wound.

【0058】上記テープ状成形体に基材を積層する場合
には、該基材に情報が記載されていてもよい。また、上
記テープ状成形体が巻物の場合には、その芯材の内部に
情報が記載されていてもよい。上記情報は、適応できる
配管、使用部位等に関する情報であり、記載することに
より、施工時の混乱を防止することができる。
When a base material is laminated on the tape-shaped molded body, information may be described on the base material. In the case where the tape-shaped molded body is a roll, information may be written inside the core material. The above information is information on applicable piping, used parts, and the like, and by describing the information, confusion at the time of construction can be prevented.

【0059】(作用)本発明の防火区画貫通部の施工方
法、及び防火区画貫通部構造は、防火区画貫通部に挿通
された樹脂配管、ケーブル、又は断熱被覆管が火災時に
熱変形を起こしたり、焼失して隙間を生じても、巻き付
けられたテープ状成形体が熱膨張して間隙を閉塞し熱伝
導を抑制するので、防火区画貫通部の一方の側で発生し
た熱、火災、煙等が他方側へ到達するのを防止する。テ
ープ状成形体は、施工時に、樹脂配管、ケーブル、又は
断熱被覆管の外径に合わせて切断して巻き付けるため、
管の外径にあった部材をそれぞれ用意する必要がなく、
現場での混乱を防止することができる。また、テープ状
成形体が粘着性を有しており、樹脂配管、ケーブル、又
は断熱被覆管への巻き付け作業が容易であり、施工を簡
便にすることが可能である。
(Function) The method for constructing a fire protection compartment penetration portion and the fire protection compartment penetration portion structure of the present invention are characterized in that a resin pipe, a cable, or a heat insulating cladding tube inserted into the fire protection compartment penetration portion undergoes thermal deformation during a fire. Even if it is burned out and a gap is formed, the wound tape-like molded body thermally expands and closes the gap to suppress heat conduction, so that heat, fire, smoke, etc. generated on one side of the fire protection section penetration portion From reaching the other side. The tape-shaped molded body is cut and wound in accordance with the outer diameter of the resin pipe, cable, or heat insulating cladding tube during construction,
There is no need to prepare each member suitable for the outer diameter of the pipe,
Confusion at the site can be prevented. Moreover, the tape-shaped molded body has adhesiveness, and the work of winding around a resin pipe, a cable, or a heat insulating cladding tube is easy, so that the construction can be simplified.

【0060】[0060]

【発明の実施の形態】以下に実施例を掲げて本発明を更
に詳しく説明するが、本発明はこれら実施例のみに限定
されるものではない。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples.

【0061】(実施例1)ブチルゴム(エクソン社製
「ブチル#065」)42重量部、ポリブテン(出光石
油化学社製「ポリブテン#100R」)50重量部、水
素添加石油樹脂(トーネックス社製「エスコレッツ#5
320」)8重量部、ポリリン酸アンモニウム(クラリ
アント社製「EXOLIT AP422」)100重量
部、中和処理された熱膨張性黒鉛(東ソー社製「フレー
ムカットGREP−EG」)30重量部、水酸化アルミ
ニウム(昭和電工社製「ハイジライトH−31」)50
重量部、及び、炭酸カルシム(備北粉化製「BF30
0」)100重量部を混練ロールを用いて混練した後、
得られた樹脂組成物をプレス成形により2mm厚のシー
トを作製した。得られたシートの片面にアルミガラスク
ロスを貼り合わせ、160mm幅に切断してテープ状成
形体を作製した。
Example 1 42 parts by weight of butyl rubber (“Butyl # 065” manufactured by Exxon), 50 parts by weight of polybutene (“Polybutene # 100R” manufactured by Idemitsu Petrochemicals), and hydrogenated petroleum resin (“ESCOLETS” manufactured by Tonex) # 5
320 ") 8 parts by weight, 100 parts by weight of ammonium polyphosphate (" EXOLIT AP422 "manufactured by Clariant), 30 parts by weight of neutralized heat-expandable graphite (" Frame Cut GREP-EG "manufactured by Tosoh Corporation), hydroxide Aluminum (Showa Denko “Heidilite H-31”) 50
Parts by weight and calcium carbonate (Bihoku Powder Chemical "BF30
0 ") After kneading 100 parts by weight using a kneading roll,
A 2 mm-thick sheet was produced from the obtained resin composition by press molding. An aluminum glass cloth was bonded to one side of the obtained sheet, and cut into a width of 160 mm to produce a tape-shaped molded body.

【0062】上記テープ状成形体を外径140mm(呼
び径125)の硬質塩化ビニル管の外面にアルミガラス
クロスが外側となるように1周分巻き付けて(巻き付け
厚2mm)、試験体を作製した。このテープ状成形体は
自己粘着性を有するため、巻き付け作業を容易に行うこ
とができた。また、厚みが薄いため、カッターやはさみ
等で簡単に切断可能であった。
The above-mentioned tape-shaped molded body was wound around the outer surface of a rigid vinyl chloride pipe having an outer diameter of 140 mm (nominal diameter 125) by one turn so that the aluminum glass cloth was on the outside (winding thickness: 2 mm) to prepare a test body. . Since this tape-shaped molded body had self-adhesiveness, the winding operation could be easily performed. In addition, because of its small thickness, it could be easily cut with a cutter or scissors.

【0063】この試験体を、図2に示したように、スラ
ブ3(図2において、厚さt=150mm)に開けた床
用丸型防火区画貫通部5(図2において、貫通孔の直径
D=175mm)に、テープ状成形体2の巻き付け部分
がスラブ3面から床上方向へ10mm出るように挿通さ
せた後、図3に示したように、試験体とスラブ3との間
隙にモルタル4を充填して固定した。上記スラブに固定
した試験体について、ISO 834に基づく床用2時
間耐火試験を行った結果、硬質塩化ビニル管は殆ど溶
融、焼失したが、テープ状成形体の膨張断熱層により熱
伝導が抑制され、非加熱面側に火炎の突き抜けは観測さ
れなかった。
As shown in FIG. 2, this test piece was inserted into a round fire-prevention section for floor 5 (in FIG. 2, the diameter of the through-hole was opened in a slab 3 (thickness t = 150 mm in FIG. 2)). D = 175 mm), the wrapped portion of the tape-shaped molded body 2 is inserted so that the wrapped portion of the tape-shaped molded body 2 projects 10 mm upward from the surface of the slab 3, and then, as shown in FIG. And fixed. The test specimen fixed to the slab was subjected to a two-hour fire resistance test for floors based on ISO 834. As a result, the hard vinyl chloride pipe was almost melted and burned off, but the heat conduction was suppressed by the expanded heat insulating layer of the tape-shaped molded article. No flame penetration was observed on the non-heated surface side.

【0064】(実施例2)ブチルゴム(エクソン社製
「ブチル#065」)42重量部、ポリブテン(出光石
油化学社製「ポリブテン#100R」)50重量部、水
素添加石油樹脂(トーネックス社製「エスコレッツ#5
320」)8重量部、ポリリン酸アンモニウム(クラリ
アント社製「EXOLIT AP422」)100重量
部、中和処理された熱膨張性黒鉛(東ソー社製「フレー
ムカットGREP−EG」)30重量部、水酸化アルミ
ニウム(昭和電工社製「ハイジライトH−31」)50
重量部、及び、炭酸カルシウム(備北粉化製「BF30
0」)100重量部をニーダーを用いて混練した後、得
られた樹脂組成物をカレンダー成形により、片面にアル
ミニウム箔離型紙を積層させた、長さ6m、幅1000
mm、0.5mm厚のロール原反を作製した。得られた
ロール原反を輪切り機にて60mm幅に切断し、テープ
状成形体を作製した。
(Example 2) 42 parts by weight of butyl rubber ("Butyl # 065" manufactured by Exxon), 50 parts by weight of polybutene ("Polybutene # 100R" manufactured by Idemitsu Petrochemical Co., Ltd.), and hydrogenated petroleum resin ("ESCOLETS" manufactured by Tonex Corporation) # 5
320 ") 8 parts by weight, 100 parts by weight of ammonium polyphosphate (" EXOLIT AP422 "manufactured by Clariant), 30 parts by weight of neutralized heat-expandable graphite (" Frame Cut GREP-EG "manufactured by Tosoh Corporation), hydroxide Aluminum (Showa Denko “Heidilite H-31”) 50
Parts by weight and calcium carbonate (Bihoku Powder Chemical "BF30
0 ") After kneading 100 parts by weight using a kneader, the obtained resin composition was calender-molded to laminate aluminum foil release paper on one side, length 6 m, width 1000
Rolls having a thickness of 0.5 mm and 0.5 mm were prepared. The obtained raw roll was cut into a width of 60 mm by a ring cutter to prepare a tape-shaped molded body.

【0065】上記テープ状成形体を外径42mm(呼び
径36)のポリエチレン鞘管(波形管)〔内管:外径2
7mm(呼び径20)の架橋ポリエチレン管〕の外面
に、アルミニウム箔離型紙が外側なるように1周分巻き
付けて(巻き付け厚0.5mm)、試験体を作製した。
同様に作製した試験体を7本準備した。このテープ状成
形体は自己粘着性を有するため、巻き付け作業を容易に
行うことができた。また、厚みが薄いため、カッターや
はさみ等で簡単に切断可能であった。
The above-mentioned tape-shaped molded product was formed into a polyethylene sheath tube (corrugated tube) having an outer diameter of 42 mm (nominal diameter 36) [inner tube: outer diameter 2
An aluminum foil release paper was wound around the outer surface of a crosslinked polyethylene pipe having a diameter of 7 mm (nominal diameter: 20) by one turn (winding thickness: 0.5 mm) to prepare a test body.
Seven test pieces prepared in the same manner were prepared. Since this tape-shaped molded body had self-adhesiveness, the winding operation could be easily performed. In addition, because of its small thickness, it could be easily cut with a cutter or scissors.

【0066】これらの試験体7本を、図4に示したよう
に、厚さ100mmのスラブに開けた壁用角型防火区画
貫通部5(300×75mm)に挿通させた後、テープ
状成形体2の巻き付け部分が加熱面から10mm出るよ
うに、また、ポリエチレン鞘管1b同士の間隔が10m
mとなるように配置し、試験体とスラブ3との間隙にモ
ルタル4を充填して固定した。上記スラブに固定した試
験体について、ISO 834に基づく壁用2時間耐火
試験を行った結果、ポリエチレン管は殆ど溶融、焼失し
たが、テープ状成形体の膨張断熱層により熱伝導が抑制
され、非加熱面側に火炎の突き抜けは観測されなかっ
た。
As shown in FIG. 4, these seven test pieces were passed through a rectangular fire-prevention section penetrating portion 5 (300 × 75 mm) formed in a slab having a thickness of 100 mm, and then tape-shaped. The wound portion of the body 2 should be 10 mm out of the heating surface, and the interval between the polyethylene sheath tubes 1 b should be 10 m.
m, and the mortar 4 was filled in the gap between the test piece and the slab 3 and fixed. The specimen fixed to the slab was subjected to a two-hour fire resistance test for walls based on ISO 834. As a result, the polyethylene pipe was almost completely melted and burned out. No penetration of the flame was observed on the heated side.

【0067】(実施例3)実施例2と同様のテープ状成
形体を用い、外径42mm(呼び径36)のポリエチレ
ン鞘管〔内管:外径27mm(呼び径20)の架橋ポリ
エチレン管〕の外面に1周分巻き付けて(巻き付け厚
0.5mm)、試験体を作製した。この試験体を、図2
に示したように、スラブ3(図2において、厚さt=1
50mm)に開けた床用丸型防火区画貫通部5(図2に
おいて、貫通孔の直径D=200mm)に、テープ状成
形体の巻き付け部分がスラブ3面から床上方向へ10m
m出るように挿通させた後、図3に示したように、試験
体とスラブ3との間隙にモルタル4を充填して固定し
た。
(Example 3) A polyethylene sheath tube having an outer diameter of 42 mm (nominal diameter 36) [inner tube: a cross-linked polyethylene tube having an outer diameter of 27 mm (nominal diameter 20)] was prepared using the same tape-shaped molded body as in Example 2. Was wound around the outer surface of the sample for one turn (wrapping thickness: 0.5 mm) to produce a test body. This specimen is shown in FIG.
As shown in FIG. 2, the slab 3 (in FIG. 2, the thickness t = 1)
In the round fire-prevention section for floor 5 opened at 50 mm) (the diameter D of the through hole in FIG. 2 is D = 200 mm), the winding portion of the tape-shaped molded body is 10 m upward from the slab 3 surface to the floor.
Then, as shown in FIG. 3, the gap between the test piece and the slab 3 was filled with mortar 4 and fixed.

【0068】上記スラブに固定した試験体について、I
SO 834に基づく床用2時間耐火試験を行った結
果、ポリエチレン管は溶融、焼失したが、テープ状成形
体の膨張断熱層により熱伝導が抑制され、非加熱面側に
火炎の突き抜けは観測されなかった。
With respect to the test specimen fixed to the slab, I
As a result of a 2-hour fire resistance test for floors based on SO 834, the polyethylene pipe was melted and burned out, but the heat conduction was suppressed by the expanded heat insulating layer of the tape-shaped molded body, and penetration of the flame was observed on the non-heated surface side. Did not.

【0069】(実施例4)実施例2と同様の試験体を、
図2に示したように、スラブ3(図2において、厚さt
=100mm)に開けた壁用丸型防火区画貫通部5(図
2において、貫通孔の直径D=200mm)に、テープ
状成形体2の巻き付け部分が、非加熱面から10mm出
るように挿通させた後、図3に示したように、試験体と
スラブ3との間隙にモルタル4を充填して固定した。上
記スラブに固定した試験体について、ISO 834に
基づく壁用2時間耐火試験を行った結果、ポリエチレン
管は溶融、焼失したが、テープ状成形体の膨張断熱層に
より熱伝導が抑制され、非加熱面側に火炎の突き抜けは
観測されなかった。
(Example 4) A test piece similar to that of Example 2 was used.
As shown in FIG. 2, the slab 3 (in FIG.
= 100 mm), the tape-shaped molded body 2 is inserted into the round fire-prevention section for wall 5 (in FIG. 2, the diameter D of the through-hole D = 200 mm) so that the wound portion of the tape-shaped molded body 2 comes out from the non-heating surface by 10 mm. After that, as shown in FIG. 3, a mortar 4 was filled in the gap between the test piece and the slab 3 and fixed. The test piece fixed to the slab was subjected to a 2-hour fire resistance test for walls based on ISO 834. As a result, the polyethylene pipe was melted and burned out. No flame penetration was observed on the surface side.

【0070】(実施例5)ブチルゴム(エクソン社製
「ブチル#065」)40重量部、ポリブテン(出光石
油化学社製「ポリブテン#100R」)50重量部、水
素添加石油樹脂(トーネックス社製「エスコレッツ#5
320」)10重量部、ポリリン酸アンモニウム(クラ
リアント社製「EXOLIT AP422」)45重量
部、中和処理された熱膨張性黒鉛(東ソー社製「フレー
ムカットGREP−EG」)30重量部、及び、水酸化
アルミニウム(昭和電工社製「ハイジライトH−3
1」)200重量部を混練ロールを用いて混練した後、
得られた樹脂組成物をプレス成形により、1.5mm
厚、80mm幅のテープ状成形体を作製した。
(Example 5) 40 parts by weight of butyl rubber ("Butyl # 065" manufactured by Exxon), 50 parts by weight of polybutene ("Polybutene # 100R" manufactured by Idemitsu Petrochemical Co., Ltd.), and hydrogenated petroleum resin ("ESCOLETS" manufactured by Tonex Corporation) # 5
320 ") 10 parts by weight, 45 parts by weight of ammonium polyphosphate (" EXOLIT AP422 "manufactured by Clariant), 30 parts by weight of neutralized heat-expandable graphite (" Frame Cut GREP-EG "manufactured by Tosoh Corporation), and Aluminum hydroxide (Heidilite H-3 manufactured by Showa Denko KK)
1)) After kneading 200 parts by weight using a kneading roll,
The obtained resin composition was pressed into a 1.5 mm
A tape-shaped molded body having a thickness of 80 mm was produced.

【0071】上記テープ状成形体を外径114mmの架
橋ポリエチレン管の外面に2周分巻き付けて(巻き付け
厚3mm)、試験体を作製した。このテープ状成形体は
自己粘着性を有するため、巻き付け作業を容易に行うこ
とができた。また、厚みが薄いため、カッターやはさみ
等で簡単に切断可能であった。この試験体を、図2に示
したように、スラブ3(図2において、厚さt=100
mm)に開けた防火区画貫通部5(図2において、貫通
孔の直径D=150mm)に、テープ状成形体の巻き付
け部分がスラブ3の中央にくるように挿通させた後、図
3に示したように、試験体とスラブ3との間隙にロック
ウール4を充填して固定した。
The tape-shaped molded body was wound around the outer surface of a cross-linked polyethylene pipe having an outer diameter of 114 mm by two turns (thickness of winding: 3 mm) to prepare a test body. Since this tape-shaped molded body had self-adhesiveness, the winding operation could be easily performed. In addition, because of its small thickness, it could be easily cut with a cutter or scissors. As shown in FIG. 2, this test piece was slab 3 (thickness t = 100 in FIG. 2).
After the tape-shaped molded body is inserted through the fire-prevention section penetrating portion 5 (in FIG. 2, the diameter D of the through-hole D = 150 mm) opened in the center of the slab 3, as shown in FIG. As described above, the gap between the test piece and the slab 3 was filled with rock wool 4 and fixed.

【0072】上記スラブに固定した試験体について、I
SO 834に基づく壁用2時間耐火試験を行った結
果、架橋ポリエチレン管は溶融、焼失したが、テープ状
成形体の膨張断熱層により熱伝導が抑制され、非加熱面
側に火炎の突き抜けは観測されなかった。
With respect to the specimen fixed to the slab, I
As a result of a 2-hour fire resistance test for walls based on SO 834, the crosslinked polyethylene pipe melted and burned off, but the heat conduction was suppressed by the expanded heat-insulating layer of the tape-shaped molded article, and flame penetration was observed on the non-heated surface side. Was not done.

【0073】(実施例6)ブチルゴム(エクソン社製
「ブチル#065」)50重量部、ポリエチレン系樹脂
(ダウケミカル社製「EG8200」)20重量部、ポ
リブテン(出光石油化学社製「ポリブテン#100
R」)21重量部、水素添加石油樹脂(トーネックス社
製「エスコレッツ#5320」)4重量部、赤リン(ク
ラリアント社製「EXOLIT RP602」)80重
量部、中和処理された熱膨張性黒鉛(UCAR Car
bon社製「GRAFGuard#220−50N」)
60重量部、水酸化マグネシウム(協和化学社製「キス
マ5B」)50重量部、及び、炭酸カルシウム(備北粉
化製「BF300」)100重量部を加圧ニーダーを用
いて混練した後、カレンダー成形により離型紙を積層さ
せた、1mm厚、100mm幅のテープ状成形体を作製
した。
Example 6 50 parts by weight of butyl rubber (“Butyl # 065” manufactured by Exxon), 20 parts by weight of a polyethylene resin (“EG8200” manufactured by Dow Chemical Company), and polybutene (“Polybutene # 100” manufactured by Idemitsu Petrochemical Co., Ltd.)
R ") 21 parts by weight, hydrogenated petroleum resin (" Escolets # 5320 "manufactured by Tonex Corporation) 4 parts by weight, red phosphorus (" EXOLIT RP602 "manufactured by Clariant) 80 parts by weight, neutralized heat-expandable graphite ( UCAR Car
Bon GRAFGuard # 220-50N)
After kneading 60 parts by weight, 50 parts by weight of magnesium hydroxide ("Kisuma 5B" manufactured by Kyowa Chemical Co., Ltd.) and 100 parts by weight of calcium carbonate ("BF300" manufactured by Bihoku Powder Co., Ltd.) using a pressure kneader, calender molding is performed. To form a 1 mm thick, 100 mm wide tape-like molded product on which release paper was laminated.

【0074】上記テープ状成形体を離型紙を剥離してか
ら、外径40mmのケーブルCV−Tの外面に1周分巻
き付けて(巻き付け厚1mm)、試験体を作製した。こ
のテープ状成形体は自己粘着性を有するため、巻き付け
作業を容易に行うことができた。また、厚みが薄いた
め、カッターやはさみ等で簡単に切断可能であった。こ
の試験体を、図2に示したように、スラブ3(図2にお
いて、厚さt=150mm)に開けた防火区画貫通部5
(図2において、貫通孔の直径D=75mm)に挿通さ
せた後、図3に示したように、テープ状成形体2の巻き
付け部分が加熱面側のスラブに面合わせになるように、
試験体とスラブ3との間隙にパテ4を充填して固定し
た。
After releasing the release paper from the tape-shaped molded body, the tape-shaped molded body was wound around the outer surface of the cable CV-T having an outer diameter of 40 mm by one turn (wrapping thickness: 1 mm) to prepare a test body. Since this tape-shaped molded body had self-adhesiveness, the winding operation could be easily performed. In addition, because of its small thickness, it could be easily cut with a cutter or scissors. As shown in FIG. 2, this test body was opened in a slab 3 (in FIG.
(In FIG. 2, the diameter of the through hole is D = 75 mm). Then, as shown in FIG. 3, the wound portion of the tape-shaped molded body 2 is flush with the slab on the heating surface side.
The putty 4 was filled in the gap between the test piece and the slab 3 and fixed.

【0075】上記スラブに固定した試験体について、I
SO 834に基づく床用2時間耐火試験を行った結
果、ケーブルは溶融、焼失したが、テープ状成形体の膨
張断熱層により熱伝導が抑制され、非加熱面側に火炎の
突き抜けは観測されなかった。
With respect to the specimen fixed to the slab, I
As a result of a two-hour fire resistance test for floors based on SO 834, the cable was melted and burned out, but the heat conduction was suppressed by the expanded heat insulating layer of the tape-shaped molded body, and no flame penetration was observed on the non-heated surface side. Was.

【0076】(実施例7)ブチルゴム(エクソン社製
「ブチル#065」)42重量部、ポリブテン(出光石
油化学社製「ポリブテン#100R」)50重量部、水
素添加石油樹脂(トーネックス社製「エスコレッツ#5
320」)8重量部、中和処理された熱膨張性黒鉛(東
ソー社製「フレームカットGREP−EG」)100重
量部、及び、炭酸ストロンチウム(堺化学社製)200
重量部を加圧ニーダーを用いて混練した後、プレス成形
により2mm厚のテープ状成形体を作製した。
Example 7 42 parts by weight of butyl rubber (“Butyl # 065” manufactured by Exxon), 50 parts by weight of polybutene (“Polybutene # 100R” manufactured by Idemitsu Petrochemical Co., Ltd.), and hydrogenated petroleum resin (“ESCOLETS” manufactured by Tonex Corporation) # 5
320 ") 8 parts by weight, 100 parts by weight of neutralized heat-expandable graphite (" Frame Cut GREP-EG "manufactured by Tosoh Corporation), and 200 strontium carbonate (manufactured by Sakai Chemical Co., Ltd.)
After the weight parts were kneaded using a pressure kneader, a 2 mm-thick tape-shaped molded body was produced by press molding.

【0077】上記テープ状成形体を断熱被覆銅管(外径
50mm、断熱層10mm)の外面に1周分巻き付けて
(巻き付け厚2mm)、試験体を作製した。このテープ
状成形体は自己粘着性を有するため、巻き付け作業を容
易に行うことができた。また、厚みが薄いため、カッタ
ーやはさみ等で簡単に切断可能であった。この試験体
を、図2に示したように、スラブ3(図2において、厚
さt=100mm)に開けた防火区画貫通部5(図2に
おいて、貫通孔の直径D=75mm)に、テープ状成形
体2の巻き付け部分がスラブ3面から均等にはみ出すよ
うに挿通させた後、図3に示したように、試験体とスラ
ブ3との間隙にモルタル4を充填して固定した。
The tape-shaped molded body was wound around the outer surface of a heat-insulated copper tube (outer diameter 50 mm, heat-insulating layer 10 mm) by one turn (wrapped thickness 2 mm) to prepare a test body. Since this tape-shaped molded body had self-adhesiveness, the winding operation could be easily performed. In addition, because of its small thickness, it could be easily cut with a cutter or scissors. As shown in FIG. 2, this test piece was taped to the fire protection section penetration portion 5 (in FIG. 2, the diameter D of the through hole D = 75 mm) opened in the slab 3 (thickness t = 100 mm in FIG. 2). After the wound portion of the shaped body 2 was inserted so as to protrude evenly from the surface of the slab 3, the mortar 4 was filled in the gap between the test body and the slab 3 and fixed as shown in FIG.

【0078】上記スラブに固定した試験体について、I
SO 834に基づく壁用2時間耐火試験を行った結
果、断熱被覆管は溶融、焼失したが、テープ状成形体の
膨張断熱層により熱伝導が抑制され、非加熱面側に火炎
の突き抜けは観測されなかった。
With respect to the specimen fixed to the slab, I
As a result of a 2-hour fire resistance test for walls based on SO 834, the heat-insulated cladding was melted and burned off, but the heat conduction was suppressed by the expanded heat-insulating layer of the tape-shaped molding, and flame penetration was observed on the non-heated surface side. Was not done.

【0079】(実施例8)実施例2と同様のテープ状成
形体を外径42mm(呼び径36)のポリエチレン鞘管
の外面に1周分巻き付けた(巻き付け厚いずれも0.5
mm)後、種類の異なる7種の内管を挿入して7種類の
試験体を作製した。尚、内管として、外径34mm(呼
び径25)のポリエチレン管、外径34mm(呼び径2
5)の架橋ポリエチレン管、外径34mm(呼び径2
5)のポリブテン管、外径34.6mm(呼び径25)
の被覆ステンレスフレキ管、外径32.2mm(銅管外
径22.2mm、保温材厚5mm)の被覆銅管、外径3
2.3mm(呼び径25)の金属強化架橋ポリエチレン
管、及び、外径28mm(CV600V 38mm2 ×
4C)のケーブルをそれぞれ使用した。このテープ状成
形体は自己粘着性を有するため、巻き付け作業を容易に
行うことができた。また、厚みが薄いため、カッターや
はさみ等で簡単に切断可能であった。
(Example 8) The same tape-shaped molded body as in Example 2 was wound around the outer surface of a polyethylene sheath tube having an outer diameter of 42 mm (nominal diameter 36) by one turn (the winding thickness was 0.5 in each case).
mm), seven different types of inner tubes were inserted to produce seven types of test specimens. As the inner pipe, a polyethylene pipe having an outer diameter of 34 mm (nominal diameter 25) and an outer diameter of 34 mm (nominal diameter 2
5) Crosslinked polyethylene pipe, outer diameter 34 mm (nominal diameter 2
5) Polybutene tube, outer diameter 34.6 mm (nominal diameter 25)
Coated stainless steel flexible tube, outer diameter 32.2 mm (copper pipe outer diameter 22.2 mm, heat insulating material thickness 5 mm) coated copper pipe, outer diameter 3
2.3 mm (nominal diameter 25) metal-reinforced cross-linked polyethylene pipe, and outer diameter 28 mm (CV600V 38 mm 2 ×
4C) was used. Since this tape-shaped molded body had self-adhesiveness, the winding operation could be easily performed. In addition, because of its small thickness, it could be easily cut with a cutter or scissors.

【0080】これらの試験体を、図4に示したように、
厚さ100mmのスラブ3に開けた壁用角型防火区画貫
通部5(538×76mm)に挿通させた後、テープ状
成形体の巻き付け部分がスラブ3の非加熱面から10m
m出るように、また、ポリエチレン鞘管1b同士の間隔
が10mmとなるように配置し、試験体とスラブ3との
間隙にモルタル4を充填して固定した。
As shown in FIG. 4, these test pieces were
After passing through the rectangular fire protection section penetration part 5 (538 × 76 mm) for the wall opened in the slab 3 having a thickness of 100 mm, the winding portion of the tape-shaped molded body is 10 m from the non-heating surface of the slab 3.
The mortar 4 was filled and fixed in the gap between the test piece and the slab 3 by disposing the polyethylene sheath pipe 1b so that the distance between the test pieces and the slab 3 was 10 mm.

【0081】上記スラブに固定した試験体について、I
SO 834に基づく壁用2時間耐火試験を行った結
果、樹脂部分は殆ど溶融、焼失したが、テープ状成形体
の膨張断熱層により熱伝導が抑制され、非加熱面側に火
炎の突き抜けは観測されなかった。
The test piece fixed on the slab was
As a result of a 2 hour fire resistance test for walls based on SO 834, the resin part was almost melted and burned off, but the heat conduction was suppressed by the expanded heat insulating layer of the tape-shaped molded body, and flame penetration was observed on the non-heated surface side. Was not done.

【0082】(実施例9)実施例2と同様のテープ状成
形体を種類の異なる7種の配管の外面にそれぞれ1周分
巻き付けて(巻き付け厚いずれも0.5mm)、7種類
の試験体を作製した。尚、配管には、実施例8で使用し
た7種の内管を使用した。上記7種類の試験体を、図2
に示したように、厚さ150mmのスラブに7個開けた
床用丸型防火区画貫通部5(図2において、貫通孔の直
径D=75mm)に、テープ状成形体2の巻き付け部分
がスラブ3面から床上方向へ10mm出るようにそれぞ
れ挿通させた後、試験体とスラブ3との間隙にモルタル
4を充填して固定した。このテープ状成形体は自己粘着
性を有するため、巻き付け作業を容易に行うことができ
た。また、厚みが薄いため、カッターやはさみ等で簡単
に切断可能であった。
Example 9 The same tape-shaped molded body as in Example 2 was wound around the outer surface of seven different kinds of pipes by one turn (the winding thickness was 0.5 mm in each case), and seven kinds of test pieces were obtained. Was prepared. Note that seven types of inner pipes used in Example 8 were used for the pipes. The above seven types of test specimens are shown in FIG.
As shown in the figure, the wound portion of the tape-shaped molded body 2 is slab-wrapped around the floor-shaped round fire-prevention section penetrating portion 5 (in FIG. 2, the diameter D of the through-hole D = 75 mm) formed in seven slabs having a thickness of 150 mm. After each of the slabs 3 was inserted so as to protrude from the three surfaces upward by 10 mm in the upward direction, the mortar 4 was filled in the gap between the test piece and the slab 3 and fixed. Since this tape-shaped molded body had self-adhesiveness, the winding operation could be easily performed. In addition, because of its small thickness, it could be easily cut with a cutter or scissors.

【0083】上記スラブに固定した試験体について、I
SO 834に基づく床用2時間耐火試験を行った結
果、樹脂部分は殆ど溶融、焼失したが、テープ状成形体
の膨張断熱層により熱伝導が抑制され、非加熱面側に火
炎の突き抜けは観測されなかった。
The test piece fixed to the slab was
As a result of a two-hour fire resistance test for floors based on SO 834, the resin portion was almost melted and burned off, but the heat conduction was suppressed by the expanded heat insulating layer of the tape-shaped molded body, and penetration of the flame on the non-heated surface side was observed. Was not done.

【0084】(実施例10)実施例9で使用した7種類
の試験体を、図5に示したように、厚さ100mmのス
ラブ3に開けた壁用角型防火区画貫通部5(538×7
6mm)にそれぞれ挿通させた後、テープ状成形体2の
巻き付け部分が加熱面から10mm出るように、また試
験体同士の間隔が10mmとなるように配置し、試験体
とスラブ3との間隙にモルタル4を充填して固定した。
上記スラブに固定した試験体について、ISO 834
に基づく壁用2時間耐火試験を行った結果、樹脂部分は
殆ど溶融、焼失したが、テープ状成形体の膨張断熱層に
より熱伝導が抑制され、非加熱面側に火炎の突き抜けは
観測されなかった。
(Example 10) As shown in FIG. 5, seven types of test pieces used in Example 9 were cut into a slab 3 having a thickness of 100 mm, and were formed into a rectangular fire-prevention section through wall 5 (538 × 5). 7
6 mm), the tape-shaped molded body 2 is arranged so that the winding portion of the tape-shaped molded body 2 comes out of the heating surface by 10 mm, and the interval between the specimens is 10 mm. Mortar 4 was filled and fixed.
For the specimen fixed to the slab, ISO 834
As a result of a 2-hour fire resistance test for walls based on JIS, most of the resin was melted and burned off, but the heat conduction was suppressed by the expanded heat insulating layer of the tape-shaped molded body, and no flame penetration was observed on the non-heated surface side. Was.

【0085】(実施例11)実施例9で使用した7種類
の試験体を、図2に示した、厚さ150mmのスラブ3
に床用丸型防火区画貫通部5(図2において、貫通孔の
直径D=75mm)を7個開け、テープ状成形体2の巻
き付け部分がスラブ3面から床上方向へ10mm出るよ
うに、また試験体同士の間隔が10mmとなるようにそ
れぞれ挿通し、試験体とスラブ3との間隙にモルタル4
を充填して固定した。上記スラブに固定した試験体につ
いて、ISO 834に基づく床用2時間耐火試験を行
った結果、樹脂部分は殆ど溶融、焼失したが、テープ状
成形体の膨張断熱層により熱伝導が抑制され、非加熱面
側に火炎の突き抜けは観測されなかった。
(Embodiment 11) The seven types of specimens used in Embodiment 9 were slab 3 having a thickness of 150 mm as shown in FIG.
Then, seven round floor fireproof section penetration portions 5 (in FIG. 2, the diameter of the through holes D = 75 mm) are opened, and the winding portion of the tape-shaped molded body 2 extends 10 mm upward from the slab 3 surface to the floor. The mortar 4 is inserted into the gap between the test piece and the slab 3 by inserting the test piece so that the interval between the test pieces is 10 mm.
And fixed. The test piece fixed to the slab was subjected to a two-hour fire resistance test for floors based on ISO 834. As a result, the resin portion was almost completely melted and burned off. No penetration of the flame was observed on the heated side.

【0086】[0086]

【発明の効果】本発明の防火区画貫通部の施工方法及び
防火区画貫通構造は、上述の構成からなり、防火区画貫
通部に挿通された樹脂配管、ケーブル、又は断熱被覆管
が火災時に熱変形を起こしたり、焼失しても、巻き付け
られたテープ状成形体が熱膨張して膨張断熱層を形成す
ることにより、間隙を閉塞し熱伝導を抑制するので、防
火区画貫通部の一方の側で発生した熱、火炎、煙等が他
方側へ到達するのを防止する。
According to the present invention, the method for constructing a fire protection section penetration portion and the fire protection section penetration structure of the present invention have the above-mentioned construction, and the resin pipe, cable, or heat insulating cladding tube inserted into the fire protection section penetration portion undergoes thermal deformation during a fire. Even if it is caused or burned out, the wound tape-shaped molded body thermally expands to form an expanded heat insulating layer, thereby closing the gap and suppressing heat conduction. Prevent generated heat, flame, smoke, etc. from reaching the other side.

【図面の簡単な説明】[Brief description of the drawings]

【図1】樹脂配管にテープ状成形体を巻き付けた状態を
示す模式斜視図である。
FIG. 1 is a schematic perspective view showing a state in which a tape-shaped molded body is wound around a resin pipe.

【図2】テープ状成形体を巻き付けた樹脂配管を防火区
画貫通部に挿通した状態を示す模式斜視図である。
FIG. 2 is a schematic perspective view showing a state in which a resin pipe around which a tape-shaped molded body is wound is inserted into a fire protection section penetration portion.

【図3】防火区画貫通部に挿通した樹脂配管の周囲にモ
ルタルを充填した状態を示す模式断面図である。
FIG. 3 is a schematic cross-sectional view showing a state in which mortar is filled around a resin pipe inserted through a fire protection section penetration portion.

【図4】実施例2及び8の試験体をスラブに固定した状
態を示す模式斜視図である。
FIG. 4 is a schematic perspective view showing a state where the test pieces of Examples 2 and 8 are fixed to a slab.

【図5】実施例10の試験体をスラブに固定した状態を
示す模式斜視図である。
FIG. 5 is a schematic perspective view showing a state where the test piece of Example 10 is fixed to a slab.

【符号の説明】[Explanation of symbols]

1 樹脂配管、ケーブル又は断熱被覆管 1a 内管 1b ポリエチレン鞘管 2 テープ状成形体 3 防火区画(スラブ) 4 モルタル、不燃材料又はパテ 5 防火区画貫通部 D 貫通孔の直径 t 防火区画貫通部の厚み DESCRIPTION OF SYMBOLS 1 Resin piping, a cable, or a heat insulation coating tube 1a Inner tube 1b Polyethylene sheath tube 2 Tape-like molded object 3 Fireproof section (slab) 4 Mortar, noncombustible material or putty 5 Fireproof section penetration part D Diameter of through hole t Fireproof section penetration section Thickness

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 2E001 DE04 DE07 FA00 FA03 FA11 FA71 GA07 GA12 GA26 GA65 GA76 HA01 HA33 HB04 HD11 HE01 JA06 JA21 JB01 JB07 KA03 LA16 MA02 MA04 MA06 MA08  ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 2E001 DE04 DE07 FA00 FA03 FA11 FA71 GA07 GA12 GA26 GA65 GA76 HA01 HA33 HB04 HD11 HE01 JA06 JA21 JB01 JB07 KA03 LA16 MA02 MA04 MA06 MA08

Claims (9)

【特許請求の範囲】[Claims] 【請求項1】 建築物の仕切り部に設けられた防火区画
を貫通する樹脂配管、ケーブル、又は断熱被覆管が挿通
される防火区画貫通部の施工方法において、該樹脂配
管、ケーブル、又は断熱被覆管の防火区画貫通部分に、
50kw/m2の照射熱量下で加熱したときの膨張倍率
が3〜40倍であり、且つ粘着性を有する熱膨張性材料
からなるテープ状成形体を巻き付けた後、防火区画貫通
部と樹脂配管、ケーブル、又は断熱被覆管との間隙をモ
ルタル、不燃材料、又はパテで埋め戻すことを特徴とす
る防火区画貫通部の施工方法。
1. A method for installing a resin pipe, a cable, or a heat insulating cladding through which a fire protection compartment provided in a partition of a building is inserted, wherein the resin piping, cable, or heat insulating coating is provided. In the fire section of the pipe
After winding a tape-shaped molded body made of an adhesive heat-expandable material having an expansion ratio of 3 to 40 times when heated under an irradiation heat of 50 kw / m 2 , the fire protection section penetration portion and the resin pipe A method for constructing a penetration part in a fire protection section, characterized by backfilling a gap with a mortar, a noncombustible material, or a putty with a cable, a cable, or a heat insulating cladding tube.
【請求項2】 上記テープ状成形体を、樹脂配管、ケー
ブル、又は断熱被覆管に巻き付ける際の厚みが、該樹脂
配管、ケーブル、又は断熱被覆管の外径の0.5〜20
%となされ、前記テープ状成形体の幅が防火区画貫通部
の厚さの25〜150%となされていることを特徴とす
る請求項1記載の防火区画貫通部の施工方法。
2. The thickness of the tape-shaped molded product when wound around a resin pipe, a cable, or a heat insulating cladding tube is 0.5 to 20 times the outer diameter of the resin piping, cable, or heat insulating cladding tube.
2. The method according to claim 1, wherein the width of the tape-shaped molded body is 25 to 150% of the thickness of the fire-prevention section penetration part.
【請求項3】 上記テープ状成形体が、ゴム成分を含む
樹脂成分、中和処理された熱膨張性黒鉛及び無機充填剤
を含有する樹脂組成物(I)からなり、それぞれの含有
量が、前記樹脂成分100重量部に対して、中和処理さ
れた熱膨張性黒鉛15〜300重量部、無機充填剤30
〜500重量部であり、且つ中和処理された熱膨張性黒
鉛及び無機充填剤の総量が200〜600重量部である
ことを特徴とする請求項1又は2記載の防火区画貫通部
の施工方法。
3. The tape-shaped molded body is composed of a resin composition containing a resin component containing a rubber component, neutralized heat-expandable graphite, and an inorganic filler. 15 to 300 parts by weight of neutralized heat-expandable graphite and inorganic filler 30 based on 100 parts by weight of the resin component
The method according to claim 1 or 2, wherein the total amount of the neutralized thermally expandable graphite and the inorganic filler is 200 to 600 parts by weight. .
【請求項4】 上記テープ状成形体が、ゴム成分を含む
樹脂成分、リン化合物、中和処理された熱膨張性黒鉛及
び無機充填剤を含有する樹脂組成物(II)からなり、そ
れぞれの含有量が、前記樹脂成分100重量部に対し
て、リン化合物50〜150重量部、中和処理された熱
膨張性黒鉛15〜300重量部、無機充填剤30〜50
0重量部であり、且つリン化合物、中和処理された熱膨
張性黒鉛及び無機充填剤の総量が200〜600重量部
であることを特徴とする請求項1又は2記載の防火区画
貫通部の施工方法。
4. The above-mentioned tape-shaped molded body is composed of a resin component (II) containing a resin component including a rubber component, a phosphorus compound, neutralized heat-expandable graphite and an inorganic filler. The amount is 50 to 150 parts by weight of a phosphorus compound, 15 to 300 parts by weight of a neutralized heat-expandable graphite, and 30 to 50 parts by weight of an inorganic filler based on 100 parts by weight of the resin component.
The fire protection compartment penetration part according to claim 1 or 2, wherein the total amount of the phosphorus compound, the neutralized heat-expandable graphite and the inorganic filler is 200 to 600 parts by weight. Construction method.
【請求項5】 上記無機充填剤が、含水無機物及び/又
は金属炭酸塩であることを特徴とする請求項3又は4記
載の防火区画貫通部の施工方法。
5. The method according to claim 3, wherein the inorganic filler is a hydrated inorganic substance and / or a metal carbonate.
【請求項6】 上記テープ状成形体の少なくとも片面に
離型基材が積層され、樹脂配管、ケーブル、又は断熱被
覆管に該離型基材面側が内側になるように少なくとも一
周巻き付けた後、テープ状成形体の重なり部分の離型基
材を剥離し、その粘着性を利用して固定することを特徴
とする請求項1〜5のいずれか1項に記載の防火区画貫
通部の施工方法。
6. A release base material is laminated on at least one surface of the tape-shaped molded body, and is wrapped at least once around a resin pipe, a cable, or a heat insulating coating tube such that the release substrate surface side is inside, The method according to any one of claims 1 to 5, wherein the mold release base material at the overlapping portion of the tape-shaped molded body is peeled off and fixed using the adhesiveness. .
【請求項7】 上記テープ状成形体の少なくとも片面に
基材が積層され、該基材表面に情報が記載されているこ
とを特徴とする請求項1〜6のいずれか1項に記載の防
火区画貫通部の施工方法。
7. The fire protection according to claim 1, wherein a base material is laminated on at least one surface of the tape-shaped molded body, and information is written on the base material surface. Construction method of section penetration part.
【請求項8】 上記テープ状成形体が巻物であって、そ
の芯材の内部に情報が記載されていることを特徴とする
請求項1〜7のいずれか1項に記載の防火区画貫通部の
施工方法。
8. The fire protection section penetration part according to claim 1, wherein the tape-shaped molded body is a roll, and information is described inside the core material. Construction method.
【請求項9】 請求項1〜8のいずれか1項に記載の施
工方法により施工されてなる防火区画貫通部構造。
9. A fire penetration section penetrating part structure constructed by the construction method according to claim 1. Description:
JP2001147930A 2000-05-19 2001-05-17 Construction method and structure for fire compartment penetration part Pending JP2002227325A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001147930A JP2002227325A (en) 2000-05-19 2001-05-17 Construction method and structure for fire compartment penetration part

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2000148079 2000-05-19
JP2000-364806 2000-11-30
JP2000-148079 2000-11-30
JP2000364806 2000-11-30
JP2001147930A JP2002227325A (en) 2000-05-19 2001-05-17 Construction method and structure for fire compartment penetration part

Publications (1)

Publication Number Publication Date
JP2002227325A true JP2002227325A (en) 2002-08-14

Family

ID=27343427

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001147930A Pending JP2002227325A (en) 2000-05-19 2001-05-17 Construction method and structure for fire compartment penetration part

Country Status (1)

Country Link
JP (1) JP2002227325A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003222271A (en) * 2002-01-30 2003-08-08 A & A Material Corp Penetration work structure for fire compartment
JP2004340245A (en) * 2003-05-15 2004-12-02 Tosetz Co Ltd Fire preventing separation penetrating part measure tool
JPWO2006054572A1 (en) * 2004-11-17 2008-08-07 積水化学工業株式会社 Penetration through structure of compartment
JP2015189975A (en) * 2014-03-28 2015-11-02 株式会社東穂 Thermally expandable fire-resistant resin composition and method for manufacturing molded product of the same
JP2017025510A (en) * 2015-07-17 2017-02-02 積水化学工業株式会社 Building mounted with solar cell module
JP2021147467A (en) * 2020-03-18 2021-09-27 積水化学工業株式会社 Fire-resistant resin composition, fire-resistant material, fire-resistant laminated body, block penetration processing structure and block penetration processing method

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003222271A (en) * 2002-01-30 2003-08-08 A & A Material Corp Penetration work structure for fire compartment
JP2004340245A (en) * 2003-05-15 2004-12-02 Tosetz Co Ltd Fire preventing separation penetrating part measure tool
JPWO2006054572A1 (en) * 2004-11-17 2008-08-07 積水化学工業株式会社 Penetration through structure of compartment
JP2015189975A (en) * 2014-03-28 2015-11-02 株式会社東穂 Thermally expandable fire-resistant resin composition and method for manufacturing molded product of the same
JP2017025510A (en) * 2015-07-17 2017-02-02 積水化学工業株式会社 Building mounted with solar cell module
JP2021147467A (en) * 2020-03-18 2021-09-27 積水化学工業株式会社 Fire-resistant resin composition, fire-resistant material, fire-resistant laminated body, block penetration processing structure and block penetration processing method
JP7547061B2 (en) 2020-03-18 2024-09-09 積水化学工業株式会社 Fire-resistant resin composition, fire-resistant material, fire-resistant laminate, compartment penetration treatment structure, and compartment penetration treatment method

Similar Documents

Publication Publication Date Title
JP3989291B2 (en) Construction method of through section of fire prevention section and structure of through section of fire prevention section
JP3817532B2 (en) Fireproof compartment penetration structure
JP3148209U (en) Penetration through structure of compartment
JP2007312599A (en) Penetrating structure of compartment piece
JP5280987B2 (en) Fireproof compartment penetration structure
JP3838780B2 (en) Refractory sheet-like molded body and sheet laminate
JP4698207B2 (en) Fire duct compartment penetration structure for bus ducts
JP2002172181A (en) Fire preventing section penetrating member and fire preventing section penetrating part structure using the same
JP4647772B2 (en) Construction method of through section of fire prevention section and structure of through section of fire prevention section
JP3119045U (en) Fireproof compartment penetration structure
JP2002227325A (en) Construction method and structure for fire compartment penetration part
JP4320108B2 (en) Wall structure
JP2016183508A (en) Fireproof structure for beam
JP3877429B2 (en) Fireproof multilayer sheet
JPH11201374A (en) Refractory heat insulation material for piping, and its execution method
JP4320110B2 (en) Fireproof wall structure
JP4157888B2 (en) Refractory material
JP4137285B2 (en) Fireproof / firewall construction
JP4527911B2 (en) Synthetic fireproof coating method
JP2001303692A (en) Fireproof compartment passing-through member
JP2017131561A (en) Fire-protection material and method for molding fire-protection material
JP4220995B2 (en) Refractory material
JP2020182375A (en) Protective tube for cable, and fire resistant structure
JP2002174367A (en) Piping structure provided with refractory expansible packing
JP6832055B2 (en) Thermally expandable bushing

Legal Events

Date Code Title Description
A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20040407

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20040607

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20040714

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20040913

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20040929

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20041129

A911 Transfer of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20050120

A912 Removal of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A912

Effective date: 20050225