JP2002200639A - Method for manufacturing strong bacteriostatic container or material utilizing characteristics of humic substance - Google Patents

Abstract

PROBLEM TO BE SOLVED: To specially treat and process a specific humic substance and add the substance to a stock for manufacturing a bacteriostatic container or material for preventing a food poisoning or a contamination of a living environment, and to impart its characteristics to a product. SOLUTION: A method for manufacturing a strong bacteriostatic container utilizing characteristics of the humic substance or the material comprises the steps of strongly pressurizing a special humic substance blank matured while exposing with a direct sunshine in a house adopted in a specific production center and agitating, dissipating a moisture by a force of a pressurized heat of 100 to 150 deg.C to an anhydrous state, and then processing the substance to ultrafine powder having a particle size of 3 to 5 microns. The powder is good drapable with a plastic or a paint. Even when the powder is injection molded or coated, the powder is integrated and diffused on a surface due to its substance characteristics, and hence the powder can hold a bacteriostatic function of the container or the material to contribute to a healthy life.

Description

DETAILED DESCRIPTION OF THE INVENTION

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to the treatment of humic substances (hereinafter simply referred to as "materials"), which are used as materials added to manufacture containers and materials requiring bacteriostasis by utilizing the properties of specified humic substances. Law and use.

2. Description of the Related Art For human social life and health, containers and materials that require bacteriostasis are indispensable in the fields of food and environment, and many containers and materials corresponding to these are supplied. In many cases, heat-resistant resins and paints are made of organic compounds such as silver ions, copper ions, and tin ions to impart bactericidal activity to foods. And the security of the environment could be threatened. The emergence of containers and materials that can reliably fulfill the purpose of preventing food poisoning and environmental deterioration has been demanded as a pressing social issue in response to the manifestation of environmental deterioration.

SUMMARY OF THE INVENTION In view of the foregoing, the present inventors have conducted intensive research to meet social expectations.
Eventually, they have invented a method for utilizing the characteristics of a specific humic substance having properties that can match its purpose and results in the manufacture of containers and materials according to the present invention. That is, it is also a difficult method to transfer and expand organic material properties to inorganic solvents and paints. Materials with the desired characteristics are those that have been generated and accumulated millions of years ago in the area specified by the discoverer, and are excavated and matured over a long period of time and supplied with stable quality . The present inventors use it as it is,
Alternatively, many properties of the extract have been confirmed and their use has been expanded in various fields. (Japanese Patent Laid-Open No. 2000-14759, a method for suppressing the growth of Legionella bacteria) We have spent time developing technology that balances cost and quality by mixing and blending with lacquer and synthetic paints to transfer and expand the characteristics to express the characteristics, that is, to integrate organic substances including water with oily inorganic substances. In order to overcome the barriers by performing a special treatment to dehydrate the material and invent a measure to solve the difficult problem.

The material has a basic structure of 29% moisture even after aging for two years after excavation. Therefore, it was difficult to completely mix with the so-called oily raw material required by the present invention. In order to change the structural form of the material, the present inventors first strongly pressurize the material, disperse the water to 1% or less with the help of the generated pressurizing heat, and reform the structural form to an anhydrous state, Then, it was processed into an ultrafine powder of 3 to 5 microns (hereinafter simply referred to as powder). The powder was less than the particles of the target solvent and had good affinity, and the mixed state was diffused so as to rise to the surface like a colored integrated diffusing agent, so that mixing and integration with the solvent proceeded and the injection formation was facilitated. In addition, the powder has an organic part and has a property of being weak to heat, but the injection machine for molding strongly pressurizes the mixed raw material in a sealed and extremely low oxygen state, thereby raising the temperature to a high temperature and dissolving the raw material. Solvation, the solvation temperature 200
It was confirmed that the organic material did not burn and the material characteristics were maintained even when it was subjected to ~ 250 ° C. It has a good affinity when mixing the material powder with paints, and accumulates and diffuses on the surface as in the case of the above-mentioned solvent.
Since the heating temperature is ° C., no influence on the characteristics is recognized. When a solvent or a coating material which is usually dissolved by heating is subjected to injection molding or coating and drying, an extremely dense surface is formed, and the wrapped internal material is rarely exposed on the surface. However, because the material of the present invention is dehydrated by the means of the present invention and is ultra-fine processed to the same size as the solvent or paint object particles of several microns, it is completely integrated with the solvent or paint, and because of its low specific gravity, its surface activity characteristics Indeed, maintaining the material properties of the catalytic bioreactor function in the state of forming a film on the surface by the action of the colored accumulation diffusing agent is a structural factor of the subject of the present invention. Although the ultrafine processing itself is not necessarily new, the material of the present invention, which structurally contains more than 29% of moisture, undergoes a dehydration process under strong pressure, resulting in a significant change in the structural material composition. Will be developed everywhere, opening the way for the transfer of properties to expand, and the fields of use and effects that take advantage of the properties of this material will be greatly expanded. For example, the plum syrup that is extracted by sprinkling white plums with white sugar is sweet, but it is the opposite of the third time that the acidity becomes extremely strong like acetic acid. Next, the basic factors of what makes the strong bacteriostatic power according to the present invention obtainable are as follows. Naturally, humic substances are also known as diatomaceous earth and are widely known throughout the world. The diatomaceous earth used in the present invention is obtained from a specified production area, has a special composition, and has been aged by a special treatment of exposing it to direct sunlight for two years, thereby giving great characteristics. It is essentially a humus that has accumulated millions of years of marine flora and fauna, and is a unique substance that remains at the humus stage. Many other diatomaceous earths are combined with other elements and are in a petrified state, not pure humus. The material used in the present invention has two PHs, and the components are roughly divided into humic, humic and fulvic acids. Fulvic acid has a molecular weight of about 200 to 4100, and humic acid is said to be about 2,000 to 20,000. When separated, PH has a property that greatly separates each other. It is a substance that cannot be expressed. By the way, which PH is humin?
But it does not dissolve in water, humic acid dissolves in water at pH 2 or higher,
Fulvic acid has the property of dissolving in water at all PHs. Here may be the key to understand that properties are manifested straight out in anhydrous powdering. It is said that the elucidation of the structural formula of a substance has just begun. Once a humic substance researcher, such as the late Professor Noriko Shinozuka of the Institute of Industrial Science at the University of Tokyo, was working on it, and research is currently being carried out by Professor Toru Miyajima, Faculty of Environmental Science, Saga University. The latest basic structural formula is as shown in FIG. Fig. 2 shows the structural formula of the international standard sample as shown by the International Society for the Study of Humic Substances as a reference for comparison. It is said to be a substance with a secret. What is generally easy to understand as an essential property is that
It is said that the structural formula of the substance itself shows unsaturation, and as shown in the information on the elucidated prediction model diagram, it has a very large base substitution ability in a ring shape. It is a source of strong bacteriostatic power and its function while maintaining natural balance is unmatched. This material is in the form of mud with over 58% moisture when excavated,
After the excavation, it has been structurally held at 29% moisture through a ripening process in which it is agitated while being exposed to sunlight in a greenhouse for two years. The composition table is shown in Table 1. Ingredients are various minerals, usually used for 2 years as granules aged by the above-mentioned method or used as an extract thereof to obtain various effects. This opened the way for further uses and effects that could be described as expressing all the power. The powder having the above-mentioned properties is mixed with an oily substance by the above-mentioned treatment method, and is manufactured through the final process. However, it is miraculous that the bacteriostatic power is maintained and expanded without losing the properties of the material. It seems that the properties are diffused and expanded in the solvent or paint by the special dehydration ultrafine powdering treatment. It is no different from the bactericidal bacteriostatic action shown by diffusing the extract in water or air. It is a function that is very useful for human life. If a recommendation is allowed in the conclusion, a composition that can be said to be a complex complex that exists in nature but can be said to be a complex mystery will undergo a dehydration ultrafine powdering process, and will change to a new substance type that does not differentiate into a fusion body Is there anything? Moisture that is structurally incorporated to maintain more than 29% of moisture even after two years of sunlight exposure in the house for two years, loses it due to strong pressurization and pulverization, and exhibits its characteristics. Looking straightforwardly, it is conceivable that the structural form itself is reformed, and that its properties are integrated with the other party to form a composite, and that the modification is being extended. If the bacteriostatic action according to the present invention can be imagined again, the characteristics of the material accumulated and diffused on the surface can be said to act as a catalytic bioreactor and prevent bacteria from accumulating. Is even stranger.

EXAMPLES The following examples will be described in detail. The substance material that is the basis of the present invention is produced from a specific area of the Minamikogi group in Nagasaki Prefecture. No. 12 of Town 459) excavated, aligned the particles, repeated agitation while exposing to sunlight for a long period of 2 years in a greenhouse, matured and aged 29% of the water at the stage when the desired characteristics were reached. I'm holding it.
The material was added to a plus tip extrusion molding machine (10
(0 ton injection molding machine), and extruded into pellets while applying pressure. However, water was diffused due to the heat generation state (100 ° C. to 150 ° C.) due to the strong extrusion pressure, and the resulting pellets contained 1 % Or less, and the weight was reduced by half. Carefully pulverize the pellets in a mortar to pulverize, further place the resulting product in a water tank to precipitate large particles, dissolve in water and scoop up only the turbid state using filter paper. It was dried while being exposed to a light beam to obtain an ultrafine powder of 3 to 5 microns. The ultra-fine powder dried in this manner is structurally modified as a dehydrated ultra-fine powder different from the state at the time of aging because the drying proceeds without holding moisture structurally. . Although the powdering process of the embodiment of the present invention is a small-scale test, there is no concern about mass production since the technology of processing an anhydrous material into ultrafine powder has been advanced a long time. This anhydrous powder material is made from Teijin's pet manure 100
When kneading 5 is mixed, the affinity is good and the mixture is good. Looking at the diffusion state extruded by the pressurized heating element, it is the same as the function of the colored accumulation diffusing agent, and it will float on the surface so as to stick to the surface instead of being buried in the partner solvent or paint. Can be smoothly extruded from an injection molding machine, because of its low specific gravity or because of its surface activity treated and treated for two years as described above. ).
It can be said that the reproducibility is almost perfect without any fear in forming other materials. The anhydrous powder material was well blended when 5 was mixed with the cashew paint 100 and stirred well, and showed the same pattern as the mixture with the solvent and showed the same pattern as the mixture in the coating process and spread on the surface. For comparison of the bacteriostatic power, a starch paste was thinly applied to a plus chip container according to the method of the present invention and a similar container, and the mixture was allowed to stand for 7 days in a room at a temperature of about 30 ° C. so as not to dry.
Upon visual inspection at the end, white filamentous mold grew on the entire surface of the normal target container, but the mold could not be found in the plus tip container according to the present invention, so the expression that mold cannot be attracted is not unreasonable.

The material on which the present invention is based is a complex substance existing in nature, but the dehydrated ultra-fine powder processing designed for use in the subject matter has not been identified in previous applications. It seems to have led to the development of new properties that could not be obtained. The fact that the powerful bacteriostatic containers and materials of the subject of the present invention have been obtained may be the foreword. The complex composition described in the section on action, which had the power to make a great social contribution, has been released, and it is thought that this has opened up new ways of using it. At the heart of the inventor's pursuit of the use of this substance is that this substance is a valuable resource that the ancient earth has left for generations of suffering! Because he could not abandon the idea. Dehydration ultra-fine powder processing made for the present invention has a too complicated composition while existing in nature, and as the elucidation progresses, the extent of differentiation increases as much as possible, and whichever is essential It is the beginning of challenging the big use that utilizes the characteristics by overcoming what was difficult to determine by using the reverse method. There is information that dioxins are not formed even if incinerated materials are obtained by mixing a plurality of metal materials with a vinyl solvent to form a metal chlorine compound. (Slipper manufacturer) Compared to this, the fact that the powder can be mixed with an oily material by the present invention and opened the way makes it possible to mix with the fuel, thereby contributing to improved combustion efficiency and cleaner exhaust gas. The above-mentioned application is one specific example.However, the expansion of the application field brought about by the dehydration ultra-fine powdering technology of this material is It greatly contributes to the field of creation and environmental conservation.

[Brief description of the drawings]

FIG. 1 is a structural diagram of Marinex by a study by Toru Miyajima of Saga University.

FIG. 2 is a structural formula of an international reference sample indicated by the International Humic Society.

Claims (2)

[Claims] A humic substance produced in a specific production area is matured for a long period of time by a specified treatment method to produce a material having bacteriostatic properties into ultrafine powder by a specified method. Add to a plurality of target objects, that is, solvents such as plus chips, knead and mix well, and injection-mold into the desired container material.Add to natural wax or synthetic paint solution, mix well, mix well, and mix the required container material. A method for producing a container and a strong bacteriostatic force utilizing the characteristics of humic substances, characterized in that the composition is applied to a material or a material material to complete a product that retains the characteristics of the material material. 2. The humic substances specified in claim 1 are strongly pressurized to dissipate water, modified into an anhydrous structure composition, processed into ultrafine powder, and mixed with a solvent or a paint as described above. 2. The method for producing a container or material having a strong bacteriostatic force utilizing the characteristics of humic substances according to claim 1, characterized in that the characteristics of humic substances are directly expressed.