JP2002179543A - Deodorizer composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a deodorizer composition for excellently masking and deodorizing an unpleasant odor such as tobacco smell attached to the body, a cooking smell, a smell of sweat, a scalp smell, etc. SOLUTION: This deodorizer composition contains an amidobetaine represented by general formula (1) [R1 and R2 are each independently a hydrogen atom, a 1-36C straight-chain or branched alkyl group or alkenyl group; n is a number of 0-10; when n is 0, R3 is a 21-36C straight-chain or branched alkyl group or alkenyl group; when n is not 0, R3 is a 1-36C straight-chain or branched alkyl group or alkenyl group; R4 is a 1-36C straight-chain or branched alkylene group; A is a 2-4C straight-chain or branched alkylene group; Y is a 1-4C straight-chain or branched alkylene group].

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a deodorant composition excellent in deodorizing unpleasant odors such as tobacco odor, cooking odor, sweat odor and scalp odor attached to the body.

[0002]

2. Description of the Related Art It is important to maintain a beautiful and beautiful hair condition and to give a pleasant scent from the hair after washing the hair, in order to carry out daily life comfortably. Causes that hinder this include cigarette odors and cooking odors emitted into the space. These odors easily adhere to hair, and women with long hair in particular often felt very uncomfortable. In addition, sweat odor and scalp odor generated on the head also cause unpleasant odor.
These unpleasant odors are mainly composed of amines such as trimethylamine, mercaptans such as methyl mercaptan, lower fatty acids such as acetic acid, propionic acid and valeric acid, cholesterol, squalene, higher fatty acids and amino acids. Conventionally, it has been common to use a hair colon, a styling agent, or the like to mask such tobacco odor, cooking odor, sweat odor, and scalp odor with the fragrance. Similarly, a pleasant smell of tobacco, cooking, and sweat is attached to the body, hindering a comfortable life, and a method of masking with a fragrance using a colon or the like has been common.

[0003]

However, in any case, the unpleasant odor cannot be sufficiently eliminated because the unpleasant odor is mixed with the used colon and the styling agent.
In the case where a hair colon or the like having a strong odor that does not cause an unpleasant odor is used, there is a problem that the odor is perceived as an unpleasant odor by others. Therefore, an object of the present invention is to provide a deodorant composition that effectively deodorizes unpleasant odors such as tobacco odor, cooking odor, sweat odor, and scalp odor attached to hair and body.

[0004]

Means for Solving the Problems The present inventor, by using a specific amidobetaine, deodorizes unpleasant odors such as tobacco odor and cooking odor attached to hair and body, sweat odor on the head and the like, and scalp odor. Has been found to have an excellent effect. The present invention provides the following general formula (1)

[0005]

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(Wherein R ¹ and R ² independently represent a hydrogen atom or a linear or branched alkyl or alkenyl group having 1 to 36 carbon atoms, and n represents a number of 0 to 10) , N = 0, R ³ represents a linear or branched alkyl or alkenyl group having 21 to 36 carbon atoms, and n ≠
When 0, R ³ represents a linear or branched alkyl or alkenyl group having 1 to 36 carbon atoms, and R ⁴ represents 1 to 3 carbon atoms.
6 represents a linear or branched alkylene group, A represents a linear or branched alkylene group having 2 to 4 carbon atoms, and Y represents a linear or branched alkylene group having 1 to 4 carbon atoms. The present invention provides a deodorant composition containing an amidobetaine represented by the following formula:

[0007]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention uses an amidobetaine represented by the general formula (1), and the alkyl group, alkenyl group and alkylene group in the general formula (1) may have a substituent. Frequently, examples of the substituent include an aryl group such as a phenyl group, an alkoxy group such as a methoxy group and an ethoxy group, and an aryloxy group such as a phenoxy group.

As R ¹ and R ² , an alkyl group having 1 to 4 carbon atoms is more preferable, and a methyl group is particularly preferable. n is preferably from 0 to 3. When n = 0, R ³ is more preferably one having 21 to 26 carbon atoms. R ³ when n ≠ 0
Has 1 to 24 carbon atoms, particularly 21 to 24 carbon atoms
Are preferred. R ⁴ preferably has 1 to 10 carbon atoms, particularly preferably 4 to 10 carbon atoms. A is particularly preferably an ethylene group or a propylene group.

Amidobetaine (1) is, for example, a compound represented by formula (3) (hereinafter referred to as compound (3)) and a compound represented by formula (4) (hereinafter referred to as compound (4)). In the presence of a solvent.

[0010]

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(Wherein, R ¹ , R ² , R ³ , R ⁴ , Y, A and n have the same meanings as above, and X represents a halogen atom.) The solvent used here is a solvent for the raw material. Depending on the nature, diethyl ether, acetone, chloroform or the like is used.
The reaction temperature can be selected according to the boiling point of the solvent used in the range of 15 to 100 ° C, and is preferably 25 to 50 ° C, particularly preferably 40 to 45 ° C. The charging ratio of the compounds (3) and (4) is preferably such that the compound (4) is used in excess in order to increase the reaction rate and to facilitate the purification of the product. A range of 1: 1.2 is preferred.

Among the amidobetaines (1), particularly preferred are compounds represented by the following general formula (2) (hereinafter referred to as amidobetaines (2)).

[0013]

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(Wherein, R ¹ , R ² , R ³ and n have the same meaning as described above, R ⁵ represents a hydrogen atom or a methyl group, and m
Represents 1 or 2. )

Among these amidobetaines, specifically, N-carboxymethyl-N, N-dimethyl-N'-
(3- (octadecanoylamino) propyl) ammonium, N-carboxymethyl-N, N-dimethyl-N '
-(3- (docosanoylamino) propyl) ammonium, N-carboxymethyl-N, N-dimethyl-N'-
(3- (tricosanoylamino) propyl) ammonium, N-carboxymethyl-N, N-dimethyl-N'-
(3- (Tetracosanoylamino) propyl) ammonium is preferred.

The content of the amidobetaine represented by the general formula (1) in the deodorant composition of the present invention is 30 to 100% by weight.
(Hereinafter simply referred to as%), particularly preferably 50 to 100%, more preferably 70 to 100%.

It is preferable to add a functional fragrance to the deodorant composition of the present invention because the deodorant effect is further enhanced. The content of the fragrance in the deodorant composition is 0.001 to 70%, particularly 0.1%.
005 to 50%, more preferably 0.01 to 30%.

As the functional fragrance, α-pinene, β-pinene, methyl anthranilate, isobutyl quinoline,
Eugenol, aldehyde C-10, coumarin, vanillin, tripral, cis-3-hexenol, α-yonone, β-yonone, γ-yonone, α-isomethylyonone,
Allylyonone, α-methylyonone, β-methylyonone,
γ-methylyonone, α-iron, β-iron, γ-iron, methylyonone-G, sandalmysole core, aldehyde C-14 peach, α-damascon, β-damascon, γ-damascon, α-dynascon, β-dynascon, Lilial, tuberose, calanar, ambroxane, p-cresol, malakja, mossins, oribanum resinoid, geranyl nitrile, phenoxyethyl alcohol, florosa, heliotropin,
Anisyl acetate, anisyl acetone, acetyl eugenol, acetyl isoeugenol, pentalide and cyclohexyl salicylate are used,
It has an excellent effect of masking scalp odor, and has an effect of masking scalp odor other than malodor such as tobacco odor and cooking odor attached to hair and head and sweat odor generated on head.

Further, among the functional fragrances alone, l-carvone, geraniol, citral, thymol, 1,8-cineole, ぺ permint oil, spearmint oil,
Lemongrass and Hiba oil have antibacterial effects,
It is preferable as a fragrance that suppresses the generation of offensive odors due to the propagation of bacteria and the like from sebum and sweat components attached to hair and body.

The fragrance used as a fragrance when the deodorant composition of the present invention is used in cosmetics is not particularly limited, and may contain one or more fragrances contained in the above-mentioned functional fragrances. The content thereof is 0.01 to 30%, particularly 0.0
01-5% is preferred.

The functional fragrance and the fragrance used as a perfume are:
Further, it can be used after being diluted with a diluent. In that case,
As the diluent to be used, 2-methyl-2,4-dihydroxybutane, 2-methyl-2,4-dihydroxypentane, 2,4-dihydroxybutane, propylene glycol, dipropylene glycol, tripropylene glycol, ethanol, liquid paraffin , 3-methoxy-3-
One or more compounds selected from methyl butanol, diethyl phthalate, and IP solvent are preferred.

Further, antibacterial agents other than the functional fragrance alone having an antibacterial effect include zinc pyrithione (2-pyridinethiol-1-oxide zinc salt), aluminum chloride, zinc oxide, isopropylmethylphenol, benzalkonium chloride, and the like. Triclosan, chlorhexidine hydrochloride, halocarban, benzethonium chloride, chlorohydroxyaluminum, allantoincloxyaluminum, zinc p-phenolsulfonate, etc. are contained in the cosmetic in an amount of 0.
001 to 10%, preferably 0.01 to 1%.

In the deodorant composition of the present invention, these components can be prepared by using a solvent such as water, ethanol, liquid paraffin, benzyl alcohol, benzyloxyethanol, menthol, limonene, exepal, excel (mono fatty acid glyceride) or various interfaces. It is produced by dissolving and separating in an activator, especially by dissolving and dispersing in exepar, ethanol and menthol.

[0024] The deodorant composition of the present invention can be contained in the cosmetic composition in an amount of 0.01 to 50%, preferably 0.01 to 20%.

The cosmetic composition of the present invention may further contain a surfactant. These surfactants are preferably contained because they have an effect of retaining bad odors such as tobacco odor, cooking odor, and sweat odor. Specific examples of the surfactant include the following. First, examples of the anionic surfactant include N-alkyl (or alkenyl) amide sulfate, glycol benzene sulfonate, polyoxyethylene alkyl (or alkenyl) ether sulfate, alkyl (or alkenyl) sulfate, and olefin. Sulfonate, alkane sulfonate, saturated or unsaturated fatty acid salt, alkyl (or alkenyl) ether carboxylate, α-sulfonate or ester, N-acyl amino acid type surfactant, phosphoric acid mono- or diester type Surfactants and sulfosuccinates.

Examples of the nonionic surfactant include polyoxyethylene alkyl (or alkenyl) ether, polyoxyethylene alkyl phenyl ether, polyoxypropylene alkyl (or alkenyl) ether, higher fatty acid alkanolamide or an alkylene oxide adduct thereof, Examples include sucrose fatty acid esters and glycerin fatty acid monoesters. Of these, polyoxyethylene (1 to 30) lauryl ether and glycerin fatty acid monoester are preferred because they do not exhibit a thickening effect.

As the cationic surfactant, a quaternary ammonium salt, in particular, a mono-long chain type or a di-long chain type quaternary ammonium is preferable. Here, as the mono long chain or di long chain, an alkyl group, an alkenyl group, a hydroxyalkyl group, an alkylcarbonylaminoalkyl group, an alkenylcarbonylaminoalkyl group, an alkylaminocarbonylalkyl group, an alkenylaminocarbonylalkyl group, an alkoxyalkyl group, Examples include an alkenyloxyalkyl group, an aliphatic acyloxyalkyl group, an alkoxycarbonylalkyl group, and an alkenyloxycarbonylalkyl group. Here, the alkyl portion and the alkenyl portion may be linear or branched. More specifically, JP-A Nos. 62-141176, 63-50574, 63-260991, 63-2609992, and 6
3-295765, JP-A-7-90773, 7-90773
Nos. 309723, 7-309724, 7-309
Quaternary ammonium salts used in hair cosmetics and softeners described in JP-A-724 and the like. Preferred examples include mono-long (straight or branched) alkyl trimethyl ammonium salts, di-long (straight or branched) alkyl dimethyl ammonium salts, mono-long (straight or branched) alkyl dimethyl benzyl ammonium salts And di-long-chain (linear or branched) alkylmethylbenzylammonium salts, and di-long-chain (linear or branched) alkylmethylhydroxyethylammonium salts.

Further, examples of amphoteric surfactants include, for example, imidazoline type, amide amino acid salt, carbobetaine type, alkylbetaine type, alkylamidobetaine type, alkylsulfobetaine type and the like.

Two or more surfactants can be used, and 0.05 to 30%, particularly 0.1 to 10%, in the cosmetic.
It is preferred to contain.

Further, the cosmetic composition of the present invention can contain a silicone derivative, and can improve the feel and the lingering scent. Examples of such silicone derivatives include dimethylpolysiloxane, methylphenylsiloxane, methylphenylpolysiloxane, amino-modified silicone, polyether-modified silicone, fatty acid-modified silicone, fluorine-type modified silicone, cyclic silicone, alkyl-modified silicone, alcohol-modified silicone, and aliphatic. Modified silicone, epoxy-modified silicone and the like can be mentioned.

Two or more silicone derivatives can be used, and 0.01 to 15%, especially 0.1 to 15% in the cosmetic.
It is preferred to contain 10%.

Further, the cosmetic composition of the present invention can contain a cationic polymer, and can improve slipperiness and fragrance. Examples of such a cationic polymer include a cationized cellulose derivative, a cationic starch, a cationized guar gum derivative, a diallyl quaternary ammonium salt polymer, a diallyl quaternary ammonium salt / acrylamide copolymer, and a quaternized polyvinylpyrrolidone derivative. Can be

The cationic polymer is contained in the cosmetic in an amount of 0.0
The content is preferably 1 to 30%, particularly preferably 0.1 to 15%.

The form of the cosmetic composition of the present invention is appropriately selected and used in liquid, powder, gel, granule, etc.
In order to effectively exhibit the deodorizing effect, a liquid solvent using water or a lower alcohol having 1 to 4 carbon atoms, preferably an aqueous lower alcohol solution, and more preferably an aqueous ethanol solution is preferable.

The deodorant effect of the cosmetic composition of the present invention is particularly effective when used in hair tonics, hair liquids, hair foams, styling agents, hair treatments, hair sprays, and other hair styling and hair growth and hair restoration products that are not washed out and used. Excellent deodorizing effect can be obtained. Also, excellent deodorizing effects can be obtained even when used in body cosmetics such as deodorants and antiperspirants.

[0036]

EXAMPLES (Synthesis Example) (1) N-carboxymethyl-N, N-dimethyl-N '
-(3- (Octadecanoylamino) propyl) ammonium (amidobetaine (a))
N, N-dimethyl-N-ethyloxycarbonylmethyl-N '-(3- (octadecanoylamino) propyl)
12.28 g (25 mmol) of ammonium and 99.5
35 g of ethanol (HPLC grade) was added and stirred at room temperature, and after confirming uniform dissolution, 250 mL of a 1N aqueous sodium hydroxide solution was added thereto.
Stirred for hours. 1 mol / L hydrochloric acid 220
To 230 mL to neutralize, and the pH of the reaction
After confirming that it was 6.7, the reaction product was divided into 5 parts, and water and ethanol were distilled off under reduced pressure using an evaporator. 2-Propanol was added to the remaining residue, and a pale brown to white precipitate (sodium chloride) was removed by decantation. The operation of decantation was repeated three times for each residue. The collected 2-propanol was concentrated by an evaporator under reduced pressure. When sodium chloride crystals settled, decantation was repeated again. Thereafter, the solution was suction-dried overnight with a pump to obtain amide betaine (1) as a white powder. ¹ H-NMR (200 MHz, DMSO-d ₆ ); δ [ppm] 0.86 (3 H, t, J = 6.4 Hz,-(CH ₂ ) ₁₆ - CH ₃ ), 1.24 (28 H, br s,- (CH
_{2) 14 -CH 3), 1.48} (2H, t, J = 6.4Hz, - CH 2 -CH 2 -CONH -), 1.8 (2
H, m, NC-CH ₂ -CN), 2.05 (2H, t, J = 7.3Hz, -CH ₂ -CH ₂ -CONH
-), 3.05 (2H, -CONH- CH ₂ -C-), 3.09 (6H, s, CH ₃ -N ⁺ -CH ₃ ),
3.46 (2H, t, J = 7.3Hz, -CH ₂ -CH ₂ -N ⁺ -), 3.52 (2H, s, N ⁺ -CH _2-
C = O), 7.92 (1H, t, J = 6.2Hz, -CONH-). (2) N-carboxymethyl-N, N-dimethyl-N '
-(3- (docosanoylamino) propyl) ammonium (amidobetaine (b)) The synthesis was carried out in the same manner as in the method for synthesizing the above amidobetaine (1). ¹ H-NMR (500MHz, benzene-d ₆ : CD ₃ OD = 3: 2); δ [ppm] 0.86 (3H, t, J = 6.4Hz,-(CH ₂ ) ₂₀ -CH ₃ ), 1.24 (36H , br s,- (CH
_{2) 18 -Me), 1.67 (} 2H, m, NC-CH 2 -CN), 1.72 (2H, t, J = 6.4Hz,
-CH ₂ -CH ₂ -CONH-), 2.23 (2H, t, J = 7.3Hz, -CH ₂ - CH ₂ -CONH
-), 2.80 (6H, s, CH ₃ -N ⁺ -CH ₃ ), 3.15 (2H, t, -CONH- CH ₂ -C
-), 3.32 (2H, t, J = 7.3Hz, -CH ₂ - CH ₂ -N ⁺ -), 3.52 (2H, s, N ⁺ -
CH ₂ -C = O), 7.92 (1H, t, J = 6.2Hz, -CONH-).

The deodorizing effect of the deodorant composition of the present invention was evaluated by the following method. (1) Masking effect of scalp odor Using a hair bundle about 21 g (15 cm),
With the model scalp odor shown in Tables 1 and 2 sprayed once (spray: Mark II spray K-24-410),
Spray once (spray: Mark II Spray K-24-410) or 1 g of the deodorant composition or hair cosmetic, apply it with a brush, spread it all over, before and after the treatment, 30 minutes, 1 hour, and the next day The masking effect was evaluated based on the following criteria, with the model scalp odor being 5, and then the average score was determined. Average score of 1 or more and less than 2 was evaluated as ◎; 1: Completely deodorized or masked. 2: Almost deodorized or masked. 3: Scalp smell is faint. 4: Scalp smell (slightly insufficient masking). 5: Smell of scalp clearly (insufficient masking).

[0038]

[Table 1]

[0039]

[Table 2]

(2) Masking effect of body odor and foot odor 10 m × 10 m kept at a temperature of 25 ° C. and a humidity of 65 HR
In a closed training room with a size of 10 m, 10 men performed running training for about 1 hour, sweated, and after 6 hours had passed, the present invention was applied to both arms, neck, chest, back, and both feet. 5 g of body cosmetics, and the masking effect immediately after the treatment, 2 hours later, and after the body cosmetics are washed away, the sweat odor and foot odor before the treatment being 5,
After evaluation according to the following criteria, an average score was obtained. Average score of 1 or more and less than 2 was evaluated as ◎; 1: Completely deodorized or masked. 2: Almost deodorized or masked. 3: Smell of sweat or foot odor. 4: sweat odor or foot odor (deodorization or masking is slightly insufficient). 5: sweat odor or foot odor is clearly observed (deodorization or insufficient masking).

Example 1 Hair cosmetics shown in Table 3 were prepared and the scalp odor masking effect was measured.

[0042]

[Table 3]

Composition of perfume composition A: limonene 15% cis-3-hexanol 1 rigstral 0.5 helional 1.5 benzyl alcohol 15 benzaldehyde 0.1 lilial 3 linal 2 α-damascon 0.1 methyl methyl dihydrojasmonate 6 linalool 20 Benzyl salicylate 5 Coumarin 0.1 Vanillin 0.2 Tentalome 8 β-Yonone 2 γ-Undecalactone 0.8 cis-Jasmon 0.2 Dipropylene glycol 19.5 100

Perfume composition B composition: hexyl acetate 1.5% tripral 0.9 helional 0.3 magnole 1.5 allyl aproate 0.3 benzaldehyde (10% dipropylene glycol solution) 0.6 iso-amyl acetate ( 1.5 Eucalyptol 3 Menthol 18 Mint oil 6 Peppermint oil 0.6 Camphor 3 α-Pinene 9 iso-boronylacetate 6 Basil oil 0.6 Eugenol (10% dipropylene glycol solution) 0.6 Geraniol 1.5 Phenylethyl alcohol 3 Edion 9 Jasmopiranforte 0.3 Lilyal 3 Linalool 6 Phenylacetaldehyde 0.3 Cedarwood 1.5 Ethylene blush rate 3 Pearlride (musk ketone) 6 Indole (10% dipropylene glycol solution) 0.6 amyl salicylate 6 propylene glycol 6.4 100

As shown in Table 3, all of the products of the present invention exhibited an excellent scalp odor masking effect.

Example 2 The body cosmetics shown in Table 4 were prepared, and the masking effects of body odor and foot odor were measured.

[0047]

[Table 4]

As shown in Table 4, all of the products of the present invention exhibited excellent masking effects on body odor and foot odor.

Example 3 (Lotion agent) Amidobetaine (b) 2% Styrene / methyl methacrylate / dimethylpolysiloxane Grout copolymer 3.5 Methylpolysiloxane (Silicone KF-96A, Shin-Etsu Silicone Co., Ltd.) 1 Acrylic acid -Alkyl methacrylate copolymer (manufactured by PEMULEN TR-1 BF Goodrich) 0.2 L-arginine 0.2 dl-α-tocopherol acetate 0.1 PEG 600 1 1-menthol 0.3 ethanol 30 ethyl paraoxybenzoate 0.2 Perfume composition A 0.1 Purified water 100 in total

Example 4 (Hair Restorative) Amidobetaine (b) 2% Nicotinamide 0.1 dl-α-Tocopherol acetate 0.05 β-Glycyrrhetinic acid 0.1 Assembly extract 1.2 Carrot extract 0.3 St. John's wort extract 0.5 l-menthol 0.2 Huangkai extract 0.3 Polyoxyethylene (25) hydrogenated castor oil 0.2 Stearyltrimethylammonium chloride (Cotamine 86W; manufactured by Kao Corporation) 0.5 Ethanol 50 Fragrance composition A 0.1 Purified water All 100 Carbon dioxide: Propellant (undiluted solution / propellant) 98/2

Example 5 (tonic agent) Amidobetaine (b) 2% Stearyltrimethylammonium chloride (Coatamine 86PC; manufactured by Kao Corporation) 0.2 Polyoxyethylene (25) hydrogenated castor oil 1 Polyoxyethylene / polyoxypropylene stearyl Ether 0.7 dl-α-tocopherol acetate 0.05 Dipotassium glycyrrhizinate 0.1 Triclosan 0.1 Ethanol 60 Fragrance composition A 0.1 Purified water Total 100

Example 6 (Shampoo composition) Amidobetaine (b) 2% polyoxyethylene (3) sodium lauryl ether sulfate 10 sodium lauryl sulfate 5 polyoxyethylene (15) lauryl ether 1 lauric acid diethanolamide 1 lauric amide Propyl betaine 1 Stearyl trimethyl ammonium chloride 0.1 Perfume composition A 0.4 Purified water 100 in total

Example 7 (Rinse) Amidobetaine (b) 2% Stearyltrimethylammonium chloride 1.1 Cetanol 3 Isopropyl palmitate 0.5 Dimethylpolysiloxane emulsion 4 Hydroxyethylcellulose 0.1 Perfume composition A 0.3 Purified water All 100

Example 8 (Spray) Amidobetaine (b) 2% Glycerin 2 Cetanol 4 Light Liquid Isoparaffin (Nisseki Mitsubishi Isosol 400) 4 Polyoxyethylene (20) Isocetyl Ether 0.5 Isostearyl Glyceryl Ether 2 Dimethyl Poly Siloxane 1 95% ethanol 85.4 Perfume composition A 0.1

Example 9 (Hair Mist) Amidobetaine (b) 2% Polyoxyethylene hydrogenated castor oil 0.2 Stearyltrimethylammonium chloride (28%) 0.5 Softanol 0.1 Glycerin 3 95% Ethanol 10 Fragrance composition A 0.05 purified water all 100

Example 10 (Hair Cream) Amidobetaine (b) 2% dimethylpolysiloxane 5 sorbitol 10 α-monoisostearylglyceryl ether 1 higher alcohol (oleyl alcohol) 7 propylene glycol 2 95% ethanol 2 polyoxyethylene sorbitan mono Olate 4 Glycerol monostearate 2 Fragrance composition A 0.1 Purified water Total 100

Example 11 (Hair Restorative) Amidobetaine (b) 2% 95% Ethanol 60 1-Menthol 0.15 Nicotinamide 0.15 β-Glycyrrhetinic acid 0.12 Suertianin 1.5 Yellowish yellow extract 0. 95 Hypericum grass extract 0.09 Feeling enhancer 0.2 pH adjuster Appropriate amount Fragrance composition A 0.1 Purified water 100 in total

Example 12 (Hair Restorative) Amidobetaine (b) 2% 95% Ethanol 74 1-Menthol 0.7 Decyltetradecyldimethylamine oxide 0.15 1,3-Butanediol 0.12 Pantothenyl ethyl ether 0 .4 nicotinamide 0.1 benzyl nicotinate 0.01 beta-glycyrrhetinic acid 0.2 l-dodecene 0.01 titanium oxide 0.5 pH adjuster qs perfume composition A 0.1 purified water total 100

Example 13 (Hair Liquid) Amidobetaine (b) 2% Acrylic amide / acrylic acid / methoxy methacrylate polyethylene glycol copolymer 2 Polyoxypropylene (21) butyl ether phosphate 7 Polyoxyethylene hydrogenated castor oil 5 Dipropylene glycol 3 Polyoxyethylene (20) isocetyl ether 0.4 Diethylene glycol monoethyl ether 0.6 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid 0.1 Fragrance composition A 0.3 Sodium hydroxide 3 95% ethanol 60 Buffer 0.4 Hair penetrant 0.2 Purified water Total 100

The hair cosmetics of Examples 3 to 13 were all excellent in scalp odor masking and deodorizing effects.

Example 14 (Whole body cleaning agent) Amidobetaine (b) 2% N-lauryl-L-glutamate triethanolamine 6 N-laurylmethyltaurine sodium 3 Trilaurate laurate 10 Triethanolamine myristate 10 Lauryl imidazo Linium betaine 5 Lauroyl diethanolamide 5 Propylene glycol 7 Fragrance composition B 0.5 Preservative, chelating agent Appropriate amount Purified water 100

Example 15 (Body Lotion) Amidobetaine (b) 2% Polyoxyethylene (50) hydrogenated castor oil 0.7 Triclosan 0.2 Bisabolol 0.01 Tetrahydroxybenzophenone 0.04 Triethyl citrate 0.2 Adipine Diisobutyl acid 0.15 isopropylene glycol 0.05 dl-camphor 0.02 menthol 0.6 eucalyptus oil 0.15 clove extract 0.005 fragrance composition B 0.1 95% 8-acetylated sucrose-modified alcohol 50 edetic acid Disodium 0.01 Citric acid 0.05 Sodium citrate 0.02 Purified water Total 100

Example 16 (Gel lotion) Amidobetaine (b) 2% Styrene / methyl methacrylate / dimethylpolysiloxane 4 Graft copolymer Methylpolysiloxane 0.5 95% 8-acetylated sucrose-modified alcohol 25 1,3 -Butylene glycol 1 polyethylene glycol 400 0.1 menthol 0.1 isopropylmethyl phenol 0.1 methyl paraoxybenzoate 0.1 fragrance composition B 0.1 pH adjuster (sodium carbonate) qs purified water 100

Example 17 (Body Sheet) Amidobetaine (b) 2% Emanone 1112 8 86% Glycerin 4 95% 8-Acetylated Sucrose Modified Alcohol 15 Menthol 0.15 Amino Modified Silicone Emulsion SM8704C 1 Fragrance Composition B 0. 02 Preservative (methyl paraben) 0.05 pH adjuster (48% sodium hydroxide) Appropriate amount Purified water 100

The body cosmetics of Examples 14 to 17 were all excellent in masking body odor and foot odor and in deodorizing effects.

[0066]

The present invention is excellent in masking and deodorizing unpleasant odors such as tobacco odor, cooking odor, sweat odor and scalp odor attached to the body.

Continued on front page F-term (reference) 4C083 AA112 AA122 AB032 AB222 AB242 AB312 AB442 AC022 AC032 AC072 AC102 AC122 AC132 AC182 AC212 AC242 AC352 AC422 AC432 AC442 AC472 AC482 AC532 AC562 AC582 AC642 AC692 AC711 AC712 AC782 AC792 AC812 AD842 AC852 AD042 AD252 AD282 AD532 AD662 BB01 BB41 CC01 CC04 CC22 CC23 CC32 CC33 CC37 CC38 CC39 DD08 DD12 DD23 DD27 DD31 DD41 EE03 EE18

Claims (5)

[Claims] 1. The following general formula (1): (Wherein, R ¹ and R ² independently represent a hydrogen atom or a linear or branched alkyl or alkenyl group having 1 to 36 carbon atoms, n represents a number of 0 to 10, and n =
When 0, R ³ represents a linear or branched alkyl or alkenyl group having 21 to 36 carbon atoms;
³ represents a linear or branched alkyl or alkenyl group having 1 to 36 carbon atoms, R ⁴ represents a linear or branched alkylene group having 1 to 36 carbon atoms, and A represents 2 to 4 carbon atoms. Y represents a linear or branched alkylene group having 1 to 4 carbon atoms; A deodorant composition containing amidobetaine represented by the formula: 2. The general formula (1) has the following general formula (2): (Wherein, R ¹ , R ² , R ³ and n have the same meaning as described above, R ⁵ represents a hydrogen atom or a methyl group, and m represents 1 or 2
Is shown. 2. The deodorant composition according to claim 1, which is an amidobetaine represented by the formula: 3. The deodorant composition according to claim 1, further comprising a fragrance. 4. A cosmetic composition containing the deodorant composition according to claim 1. 5. The cosmetic composition according to claim 4, further comprising a surfactant.