JP2002175618A - Magnetic recording medium - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a magnetic recording medium having excellent running properties, wear resistance and durability, wherein excellent lubricating properties is maintained. SOLUTION: In the magnetic recording medium 1 provided with a non- magnetic substrate 2, a magnetic layer 3 formed on one principal surface of the non-magnetic substrate 2, a carbon protective film 4 formed on the magnetic layer 3 and a lubricant layer 5 formed on the carbon protective film 4 and containing a lubricant, the lubricant layer 5 contains a compound having >=15% and <=80% adsorption ratio to carbon and >=5% and <=90% UV spectrum changing ratio that indicates the interaction with the lubricant and a perfluoropolyalkyl ether based compound wherein each polar group at both terminals has a carboxylic acid and an ester.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a magnetic recording medium having a magnetic layer made of a ferromagnetic metal material, a carbon protective film, and a lubricant layer containing a lubricant on a nonmagnetic support.

[0002]

2. Description of the Related Art Conventionally, as a magnetic recording medium, a magnetic coating comprising a ferromagnetic powder such as an oxide magnetic powder or an alloy magnetic powder, a binder, and an organic solvent is applied to a non-magnetic support. A so-called coating type magnetic recording medium in which a layer is formed is widely used.

On the other hand, as the demand for high-density recording and long-time recording has increased, Co, Co-Ni alloys, Co-
A ferromagnetic metal magnetic material such as a Cr alloy or Co-O is directly coated on a non-magnetic support such as a polyester film or a polyimide film by plating or a vacuum thin film forming technique (a vacuum deposition method, a sputtering method, an ion plating method, etc.). A magnetic recording medium of a so-called ferromagnetic metal thin film type, in which a magnetic layer is formed by being attached, has been used. And
Such a ferromagnetic metal thin film type magnetic recording medium is available in a consumer video format (8 mm Hi-8 format, DV format) or a commercial video format (D
VCAM) and the like.

This ferromagnetic metal thin film type magnetic recording medium is
Compared to the coating type magnetic recording medium, it has excellent magnetic properties such as coercive force, squareness ratio, etc., and not only excellent electromagnetic conversion characteristics in the short wavelength region, but also enables extremely thin magnetic layer, Because the thickness loss during recording demagnetization and reproduction is extremely small, and there is no need to mix a binder, which is a nonmagnetic material, into the magnetic layer, it is possible to increase the packing density of the magnetic material. Has the advantage of

In general, a magnetic recording medium is subjected to a high-speed relative motion with a magnetic head in the process of recording / reproducing a magnetic signal, in which case the running must be performed smoothly and in a stable state. . Further, it is better that the wear and damage due to the contact with the magnetic head be as small as possible.

However, in the above-mentioned ferromagnetic metal thin film type magnetic recording medium, since the surface smoothness of the magnetic layer is extremely good, a substantial contact area with the magnetic head is increased. In other words, so-called cracking tends to occur, the coefficient of friction increases, and there are many shortcomings in durability, running properties, and the like.

Therefore, in order to improve these problems,
Attempts have been made to reduce the coefficient of friction by forming a lubricating film by internally adding a lubricant to the magnetic layer of the magnetic recording medium or by applying the lubricant to the surface of the magnetic layer. In addition, the magnetic layer is coated with a protective film made of carbon, oxide, carbide, nitride, or the like, and a lubricant is applied on the protective film to form a lubricating film. Attempts have been made to solve the above problems by improving the above.

[0008] Lubricants used in such magnetic recording media are required to have severe properties due to their properties, and generally the following properties are required. (1) It has excellent low-temperature characteristics so that a predetermined lubricating effect is ensured even when used in cold regions. (2) The coating can be applied extremely thinly because spacing with the magnetic head becomes a problem, and sufficient lubrication characteristics are exhibited even in such a case. (3) To withstand long-term use and maintain the lubricating effect for a long time. Various lubricants satisfying such characteristics have been studied.

[0009]

However, when a conventionally used fluorine-containing lubricant is directly applied to a magnetic recording medium, the fluorine-containing lubricant has a low affinity for the surface of the magnetic recording medium. However, a sufficient amount is not applied to the surface of the magnetic recording medium, or the surface is not applied uniformly. As a result, sufficient lubricant is not supplied to the surface of the magnetic recording medium, the friction coefficient increases, shuttle durability and still durability deteriorate, and the level of reproduction output in shuttle running tests decreases. there were.
That is, due to lack of capacity of the lubricant used, a magnetic recording medium that satisfies practical characteristics such as a shuttle running test,
It has not been established yet.

[0010] Accordingly, the present invention has been made in view of the above-mentioned conventional circumstances, and provides a magnetic recording medium which has excellent lubricity and excellent running properties, abrasion resistance and durability. It is intended to provide.

[0011]

The inventor of the present invention has conducted intensive studies on the achievement of the above-mentioned object, and as a result, the adsorption rate to carbon was 15% or more and 80% or less, and the interaction with the lubricant was confirmed. UV spectrum change rate indicating 5% or more and 90%
The present inventors have found that the above objects can be achieved by using the following compounds and perfluoropolyalkyl ether-based compounds in which both polar groups at both ends have a carboxylic acid and an ester, and have completed the present invention.

That is, the magnetic recording medium according to the present invention comprises:
A non-magnetic support, a magnetic layer formed on one main surface of the non-magnetic support, a carbon protective film formed on the magnetic layer, and a lubricant layer formed on the carbon protective film and containing a lubricant. In the magnetic recording medium, the lubricant layer has a compound having an adsorption rate to carbon of 15% or more and 80% or less and an ultraviolet spectrum change rate indicating an interaction with the lubricant of 5% or more and 90% or less. Each of the terminal polar groups contains a perfluoropolyalkyl ether compound having a carboxylic acid and an ester.

In the magnetic recording medium according to the present invention configured as described above, the lubricant layer has a carbon adsorption rate of 15%.
% To 80% and a compound having an ultraviolet spectrum change rate indicating an interaction with a lubricant of 5% to 90%, and a perfluoropolymer having a carboxylic acid and an ester at each polar group at both terminals as a lubricant. Contains a polyalkyl ether compound. Thereby, the surface state of the carbon protective film is set to a state in which the lubricant is easily held, and the applicability of the lubricant is improved. That is, in this magnetic recording medium, a sufficient amount of lubricant is held on the carbon protective film. As a result, since the magnetic recording medium maintains excellent lubricity, the magnetic recording medium has excellent running properties, wear resistance, and durability.

[0014]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of the magnetic recording medium according to the present invention will be described in detail with reference to the drawings. In addition,
The present invention is not limited to the following description, and can be appropriately modified without departing from the gist of the present invention.

FIG. 1 shows an example of the configuration of a magnetic recording medium according to the present embodiment.

The magnetic recording medium 1 is a so-called metal thin film type magnetic recording medium in which a ferromagnetic metal material is deposited on a non-magnetic support by a method such as vapor deposition, and this is used as a magnetic layer.

The magnetic recording medium 1 includes a non-magnetic support 2
A metal magnetic film 3 formed on one main surface of the non-magnetic support 2 and a carbon protective film 4 formed on the metal magnetic film 3
A lubricant layer 5 formed on the carbon protective film 4, and a back coat layer 6 formed on the other main surface of the nonmagnetic support 2.
And

The non-magnetic support 2 is made of a known material usually used as a non-magnetic support for a magnetic recording medium. Examples of the non-magnetic support 2 include polyethylene terephthalate, an aluminum alloy plate, and a glass plate.

When a rigid material such as an aluminum alloy plate or a glass plate is used for the nonmagnetic support 2, an oxide film such as alumite treatment or Ni-P
A coating may be formed to harden the surface.

The metal magnetic film 3 is formed by forming a ferromagnetic metal material on one main surface of the nonmagnetic support 2 by a so-called physical vapor deposition (PVD) method such as plating, sputtering, or vacuum deposition. It is formed as a film. Such a metal magnetic film 3 includes an in-plane magnetization film and a perpendicular magnetization film.

Examples of the ferromagnetic metal material used for the in-plane magnetized film include metals such as Fe, Co, and Ni, and Co-based metals.
Ni-based alloy, Co-Pt-based alloy, Co-Pt-Ni-based alloy, Fe-Co-based alloy, Fe-Ni-based alloy, Fe-Co
-Ni-based alloy, Fe-Ni-B-based alloy, Fe-Co-B
Alloys, Fe-Co-Ni-B alloys, and the like.

When an in-plane magnetized film is formed, Bi, Sb, Pb, Sn, Ga, I
It is preferable to form an underlayer made of a low-melting non-magnetic material such as n, Ge, Si, or Tl. When the metal magnetic material is vapor-deposited or sputtered from the vertical direction to form the metal magnetic film 3, these non-magnetic materials having a low melting point are diffused, thereby eliminating the orientation of the metal magnetic film 3 and in-plane isotropy. And the coercivity is improved.

The ferromagnetic metal material used for the perpendicular magnetization film includes, for example, a Co—Cr alloy.

The carbon protective film 4 is formed by sputtering carbon on the metal magnetic film 3 or by chemical vapor deposition (CVD: Ch).
It is formed by being adhered by emical vapor deposition or the like. The thickness of the carbon protective film 4 is preferably 2 nm to 100 nm, more preferably 5 nm to 30 nm.
nm. If the thickness of the carbon protective film 4 is too small, the durability of the carbon protective film 4 will be reduced. On the other hand, if the carbon protective film 4 is too thick, sufficient output cannot be obtained when performing short-wavelength recording.

The non-magnetic support 2, metal magnetic film 3, and carbon protective film 4 are not limited to those described above.
All of the conventionally known materials can be used.

The lubricant layer 5 is formed on the carbon protective film 4 and has an adsorption rate to carbon of 15% or more and 80% or less and an ultraviolet spectrum change rate indicating interaction with the lubricant of 5% to 90%. % Or less of a compound and a perfluoropolyalkyl ether-based compound having a carboxylic acid and an ester at both ends as a lubricant are dissolved in a solvent and applied.

Generally, when the carbon protective film of the magnetic recording medium is formed of, for example, diamond-like carbon, the outermost surface of the carbon protective film is formed of a graphite structure and a diamond structure. Conventionally, before using a carbon protective film as a protective film, the outermost surface of a magnetic recording medium was formed of a metal oxide such as CoO, CoNiO, and NiO, and had a surface structure in which lubricant molecules were easily adsorbed. . The outermost surface of the metal oxide is -OH, -COO
It is known that a large number of polar groups such as H are formed, and a lubricant layer is formed on the surface of a magnetic recording medium by physical adsorption of a polar group of a lubricant molecule to the polar group. However, as the performance of the magnetic recording medium has been improved, the spacing between the magnetic head and the magnetic recording medium has been reduced, so that a carbon protective film has been formed on the surface of the magnetic recording medium. The carbon protective film is usually formed by sputtering or CVD. The surface of the carbon protective film thus produced has significantly less adsorption sites such as polar groups for adsorbing lubricant molecules than the surface of the metal oxide. For this reason, it was very difficult to form a lubricant layer on the surface of the carbon protective film. On the other hand, attempts have been made to activate the surface of the carbon protective film to form a lubricant layer on the surface of the carbon protective film.
-3649, a method of plasma-treating the surface of a carbon protective film of a nonmagnetic support with a mixed gas containing hydrogen, and a method of mechanically treating the surface of a carbonaceous protective film described in JP-A-7-296372. To activate by sliding on
JP-A-2-27522 describes a method of irradiating ultraviolet rays to the surface of a carbon protective film in an ozone atmosphere to form a surface-treated carbon protective film, and JP-A-63-308727 describes a surface of a carbon thin film. To irradiate the surface with ultraviolet rays to carry out a surface treatment.

However, although the plasma treatment using various gases in the above can activate the surface of the carbon protective film, the carbon protective film is etched during the plasma treatment, and the mechanical strength of the carbon protective film itself is reduced. Therefore, sufficient lubricating characteristics cannot be obtained. Further, merely irradiating the surface of the carbon protective film with ultraviolet rays cannot sufficiently activate the surface of the carbon protective film. Therefore, a method of sufficiently activating the surface of the carbon protective film to form a lubricant layer on the surface of the carbon protective film has not been established.

Therefore, in the magnetic recording medium 1 according to the present invention, the lubricant layer 5 has a carbon adsorption rate of 15%.
A compound having an ultraviolet spectrum change rate of 5% or more and 90% or less indicating an interaction with a lubricant,
And a perfluoropolyalkyl ether-based compound in which each polar group at both ends has a carboxylic acid and an ester as a lubricant.

As described above, the rate of adsorption of carbon on the lubricant layer 5 is 15% or more and 80% or less, and the rate of change in the ultraviolet spectrum indicating the interaction with the lubricant is 5% or more and 90%.
By containing the following compound and a perfluoropolyalkyl ether-based compound having both polar groups at both ends having a carboxylic acid and an ester as a lubricant, the surface state of the carbon protective film 4 is changed to a lubricant layer 5. It can be in an easy state. That is, the surface state of the carbon protective film 4 can be set to a state in which the lubricant is easily held, and the applicability of the lubricant can be improved. As a result, the magnetic recording medium 1 can be provided with a sufficient amount of lubricant, so that it is possible to maintain good lubricity even under various use conditions, and to improve running properties, wear resistance and durability. An excellent magnetic recording medium can be realized.

Here, when the adsorption rate to carbon is less than 15%, the adsorbing power of the above compound to the carbon protective film 4 becomes very weak, and the applicability of the lubricant becomes low. On the other hand, when the rate of adsorption to carbon is greater than 80%, only the above compound is adsorbed on the carbon protective film 4, and the lubricant molecules are not adsorbed on the surface of the carbon protective film 4. As a result, a desired amount of the lubricant cannot be held on the surface of the carbon protective film 4, and the amount of the lubricant on the surface of the carbon protective film 4 becomes insufficient, so that a sufficient lubricating effect cannot be exhibited.

A compound having an ultraviolet spectrum change rate of less than 5% when the interaction between the compound and the lubricant is evaluated based on the change rate of the ultraviolet spectrum when irradiating the ultraviolet light is determined to be a compound having the compound and the lubricant molecule. Interaction is weak and the applicability of the lubricant is reduced. On the other hand, a compound having an ultraviolet ray spectrum change rate of more than 90% has a strong lubricating effect because the interaction between the compound and the lubricant molecule is too strong and the lubricant molecule cannot exert its effect as a lubricant. Can not.

Therefore, the adsorption rate on carbon is reduced by 15%.
Not less than 80% and the UV spectrum change rate is 5%.
% To 90%, the carbon protective film 4
It is possible to hold a sufficient amount of lubricant thereon, and the lubricant molecules can sufficiently exhibit the effect as a lubricant. As a result, the magnetic recording medium 1 can maintain good lubricity even under various use conditions, and can realize a magnetic recording medium excellent in running properties, wear resistance, and durability.

Further, the coating amount of the compound in the carbon protective film 4 is desirably 0.5 to 100 mg / ^{m 2,} more preferably 1 to 20 mg / ^{m 2.} The application amount of the above compound is 0.5 to 100 mg / m ^2.
By doing so, the above-described effects can be obtained reliably.

By applying the above-mentioned compound, the lubricant can be applied uniformly, and the surface of the magnetic recording medium 1 can be surely covered to obtain a rust-preventive effect.

Further, as a solvent for dissolving the compound when forming the lubricant layer 5, for example, a general-purpose hydrocarbon solvent such as toluene, acetone and ethanol can be used. Is small.

Here, as a compound having an adsorption rate to carbon of 15% or more and 80% or less and an ultraviolet spectrum change rate indicating an interaction with a lubricant of 5% or more and 90% or less, for example, two or more compounds Aromatic amphiphilic compounds having a condensed ring to which four or less benzene rings are bonded and a polar group can be suitably used. In the following, the rate of absorption of carbon to carbon is 15% or more and 80% or less, and the rate of change in the ultraviolet spectrum indicating the interaction with the lubricant is 5% to 90%.
The case where an aromatic amphiphilic compound having a condensed ring in which two or more and four or less benzene rings are bonded and a polar group is used as the compound of not more than% is described. In the following, for convenience of explanation, an aromatic amphiphilic compound having a condensed ring in which two or more and four or less benzene rings are bonded and a polar group is abbreviated as an aromatic amphiphilic compound.

In general, a monocyclic compound such as a benzene ring has a weak interaction with the carbon protective film 4 only with the π-electron system present on the benzene ring, and has poor adsorption to the surface of the carbon protective film 4. For this reason, in order to improve the adsorptivity to the surface of the carbon protective film 4, the aromatic amphiphilic compound requires two or more condensed rings of naphthalene ring or more, that is, two or more benzene rings. On the other hand, when the number of benzene rings is five or more, the solubility of the aromatic amphiphilic compound in a general-purpose solvent becomes extremely poor, and it becomes impossible to apply. Therefore, it is preferable that the condensed ring portion of the aromatic amphiphilic compound used in the magnetic recording medium according to the present invention is formed by bonding two to four benzene rings.

In the aromatic amphiphilic compound, a hydrocarbon chain-(CH ₂ ) n- located between a condensed ring portion in which two or more benzene rings are bonded and a polar group:
The carbon number n is preferably 0 to 30, and more preferably the carbon number n is 0 to 18. When the carbon number n is 31 or more, the solubility in a solvent when the aromatic amphiphilic compound is applied to the surface of the carbon protective film 4 decreases, and a sufficient amount of aromatic Unable to apply amphiphilic compounds.

The polar groups in the aromatic amphiphilic compound include -OH, -COOH, -OCO-,
—NH ₂ , —CONH ₂ , —C (＝ O) — and the like. These polar groups interact with the lubricant molecule to form a complex compound with the lubricant molecule. And
The formation of this complex compound makes it easier for the lubricant molecules to be adsorbed on the surface of the carbon protective film 4.

Here, when an ultraviolet spectrum change rate is used as an index for forming a complex compound between an aromatic amphiphilic compound and a lubricant molecule, when the ultraviolet spectrum change rate is less than 5%, the aromatic A sufficient amount of complex compound is not formed between the systemic amphiphilic compound and the lubricant molecule, and the above-mentioned effects are not exhibited. When the rate of change in ultraviolet spectrum is greater than 90%,
Since the interaction between the aromatic amphiphilic compound and the lubricant molecule is too strong, the lubricant molecule cannot exert its effect as a lubricant, so that a good lubricating effect cannot be expected.

By holding such an aromatic amphipathic compound on the carbon protective film 4, the condensed ring portion of the aromatic amphiphilic compound in which two or more and four or less benzene rings are bonded to each other is formed on the carbon protective film 4. Interaction with the surface of the protective film 4 enables a sufficient amount of the aromatic amphiphilic compound to be adsorbed on the surface of the carbon protective film 4. Further, by holding the aromatic amphiphilic compound on the carbon protective film 4, the polar group in the aromatic amphiphilic compound interacts with the lubricant molecule, and the affinity with the lubricant can be increased. it can. That is, by holding the above-mentioned aromatic amphiphilic compound on the carbon protective film 4, the surface of the carbon protective film 4 can be brought into a state where the lubricant can be easily applied.

Further, as the above-mentioned aromatic amphiphilic compound, for example, compounds represented by the following formulas 7 to 11 can be preferably used.

[0044]

Embedded image

[0045]

Embedded image

[0046]

Embedded image

[0047]

Embedded image

[0048]

Embedded image

Further, in the present invention, a perfluoropolyalkyl ether-based compound having a carboxylic acid and an ester at both polar groups at both ends as a lubricant (hereinafter abbreviated as a perfluoropolyalkyl ether-based compound).
Is used. That is, the lubricant layer 5 is formed by dissolving the perfluoropolyalkyl ether-based compound and the aromatic-based amphiphilic compound in a solvent, and applying the mixture on the carbon protective film 4.

Here, when the perfluoropolyalkyl ether compound is applied as a lubricant on the carbon protective film 4, the carboxylic acid or ester group of the polar group of the lubricant molecule is adsorbed on the carbon protective film 4 and becomes hydrophobic. A lubricating film is formed by the cohesive force between groups. In a conventional lubricant, a compound having a relatively large polarity such as a carboxylic acid or a carboxylic acid amine salt has a small coefficient of friction, but tends to have poor still durability. Further, a compound having a relatively low polarity such as an ester is excellent in still durability, but has a large coefficient of friction. Therefore, since this perfluoropolyalkyl ether compound has both a carboxylic acid and an ester group in the polar group, the coefficient of friction is small,
It is considered to have excellent still durability.

Further, since this perfluoropolyalkyl ether compound has a carboxylic acid and an ester group at both ends, it has a very strong interaction with an aromatic amphiphilic compound. For this reason, the perfluoropolyalkyl ether compound and the aromatic amphiphilic compound are apt to form the above-mentioned complex compound, and the perfluoropolyalkyl ether compound as a lubricant is used as a carbon compound in a complex compound state. 4 It becomes easy to be applied on the surface. As a result, a sufficient amount of lubricant can be retained on the carbon protective film 4, and the magnetic recording medium 1 can exhibit a very excellent lubrication effect.

In addition, this perfluoropolyalkyl ether compound can be applied only by dissolving a conventional fluorine-based lubricant in a fluorine-based solvent, whereas it can be applied to various hydrocarbon-based compounds such as toluene, acetone and ethanol. Since coating can be performed by dissolving in a solvent, there is an advantage that the influence on the environment is small.

As such a perfluoropolyalkyl ether compound, for example, a compound represented by the following formula 12 can be suitably used.

[0054]

Embedded image

Here, in the perfluoropolyalkyl ether compound represented by the above formula, the hydrocarbon group R preferably has 6 to 30 carbon atoms, more preferably 8 to 20 carbon atoms. is there. When the number of carbon atoms of the hydrocarbon group R is 5 or less, the solubility in an organic solvent is reduced, so that the hydrocarbon group R cannot be dissolved and applied in the organic solvent. Further, when the number of carbon atoms of the hydrocarbon group R is 31 or more, the solubility in a solvent is reduced, so that it is impossible to dissolve in the solvent and apply.

In the perfluoropolyalkyl ether compound, the perfluoropolyether group R
The average molecular weight of _f is preferably from 500 to 6000, more preferably the average molecular weight is from 1000 to 400. When the average molecular weight of the perfluoropolyether group _Rf is less than 500, the length of the perfluoropolyether group is too short, and the coefficient of friction increases. Further, the average molecular weight of the perfluoropolyether group _Rf is 6,000.
If it is larger, the solubility in an organic solvent is reduced, so that application using an organic solvent becomes impossible.

Therefore, in the lubricant layer 5, for example, an aromatic amphiphilic compound having a polar group and a condensed ring in which two or more benzene rings are bonded to each other has an adsorption rate of 15% to carbon. A compound having an ultraviolet spectrum change rate of 5% or more and 90% or less indicating interaction with a lubricant of not less than 80% and a perfluoropolyalkyl having a carboxylic acid and an ester at both polar groups at both ends as a lubricant By containing an ether compound, a sufficient amount of the lubricant can be held on the carbon protective film 4, and the lubricant molecules can sufficiently exhibit the effect as a lubricant. As a result, the magnetic recording medium 1 can maintain good lubricity even under various use conditions, and can realize a magnetic recording medium excellent in running properties, wear resistance, and durability.

The lubricant contained in the lubricant layer 5 does not need to be all the above-mentioned perfluoropolyalkyl ether-based compound, but may be used by mixing it with another lubricant at a predetermined ratio. . In this case, the lubricant to be mixed is not particularly limited, and a conventionally known lubricant such as a fluorine-based lubricant can be used.

In the magnetic recording medium 1, the lubricant layer 5
Is formed on the surface of the carbon protective film 4,
The rate of adsorption to carbon is 15% or more and 80% or less, and the rate of change in the ultraviolet spectrum indicating interaction with the lubricant is 5% or less.
%, And a mixed solution obtained by mixing and dissolving a compound of not less than 90% and a perfluoropolyalkyl ether-based compound having a carboxylic acid and an ester at each terminal at both ends as a lubricant.

Here, a compound having an adsorption rate to carbon of 15% or more and 80% or less and an ultraviolet spectrum change rate indicating an interaction with a lubricant of 5% or more and 90% or less, and the above-mentioned perfluoropolyalkyl ether The mixing ratio with the system compound is preferably from 1: 100 to 100: 1 by weight ratio, and more preferably the mixing ratio is from 1:10 to 1:10 by weight.
10: 1.

The amount of the lubricant applied is 0.5 mg / m
^{2 to} 100 mg / m ² , preferably 1 mg / m ²
more preferably ^{m 2} ~20mg / m ^2. If the amount of lubricant applied is less than 0.5 mg / m ² ,
The effect of reducing the friction coefficient of the surface of the magnetic recording medium 1 and improving the shuttle durability is not sufficient. If the amount of the lubricant applied is more than 100 mg / m ² , the lubricant may be deposited on the surface of the magnetic recording medium 1 or the lubricant may adhere to the head and stain the head. Running performance of the vehicle is reduced. Therefore, the amount of the lubricant to be applied is set to 0.1.
With ^{5mg / m 2 ~100mg / m 2} , it is possible to reduce the friction coefficient of the magnetic recording medium 1, running properties, it is possible to improve the wear resistance and durability. here,
Since the magnetic recording medium 1 is provided with the above-described lubricant layer 5, it is possible to apply a sufficient amount of lubricant to obtain desired characteristics, so that the above-described effects are surely obtained. be able to.

The lubricant need not be present on the entire surface of the carbon protective film 4, but may be present on the carbon protective film 4 in, for example, an island shape.

The back coat layer 6 is formed on the surface of the nonmagnetic support 2 opposite to the surface on which the metal magnetic film 3 is formed. For example, a binder resin and a powder component are mixed and dispersed in an organic solvent. The non-magnetic support 2 is formed by applying the applied back coat paint to the non-magnetic support 2.

The binder resin used in the backcoat paint includes, for example, a vinyl chloride-vinyl acetate copolymer, a vinyl chloride-vinylidene chloride copolymer, a vinyl chloride-acrylonitrile copolymer, and an acrylic resin. Acid ester-acrylonitrile copolymer, thermoplastic polyurethane elastomer, vinylidene chloride-acrylonitrile copolymer, butadiene-acrylonitrile copolymer, polyamide resin, polyvinyl butyral, cellulose derivative, polyester resin, phenol resin, epoxy resin, polyurethane-curable resin , Melamine resin, alkyd resin, silicone resin, epoxy-polyamide resin,
Nitrocellulose-melamine resin, mixture of high molecular weight polyester resin and isocyanate prepolymer, mixture of methacrylate copolymer and diisocyanate prepolymer, mixture of polyester polyol and polyisocyanate, urea formaldehyde resin, low molecular weight glycol / high Examples thereof include a mixture with a molecular weight diol / triphenylmethane triisocyanate, a polyamine resin, and a mixture thereof.

Alternatively, in order to improve the dispersibility of the powder component, a binder resin having a hydrophilic polar group may be used.

On the other hand, the powder component has conductivity.
Control of carbon fine powder and surface roughness
And inorganic pigments added to improve durability
It is. As the carbon-based fine particles, for example, fur
Nes carbon, channel carbon, acetylene carb
, Thermal carbon, lamp carbon, etc.
As the inorganic pigment, α-FeOOH, α-Fe₂O
₃, Cr₂O₃, TiO ₂, ZnO, SiO, Si
O₂, SiO₂・ 2H₂O, Al₂O₃, CaCO₃,
MgCO₃, Sb₂O₃And the like.

Further, as the organic solvent of the back coat paint, for example, acetone, methyl ethyl ketone,
Methyl isobutyl ketone, ketone solvents such as cyclohexanone, methyl acetate, ethyl acetate, butyl acetate, ethyl lactate, ester solvents such as glycol acetate monoethyl ether, glycol dimethyl ether, glycol monoethyl ether, glycol ether solvents such as dioxane, Aromatic hydrocarbon solvents such as benzene, toluene and xylene; aliphatic hydrocarbon solvents such as hexane and heptane; chlorinated carbonization such as methylene chloride, ethylene chloride, carbon tetrachloride, chloroform, ethylene chlorohydrin and dichlorobenzene A general-purpose solvent such as a hydrogen-based solvent can be used.

Further, a lubricant may be used in combination with the back coat layer 6. In this case, the back coat layer 6
Internal lubricant or back coat layer 6
There is a method of applying a lubricant on top. In any case, as the lubricant, conventionally known lubricants such as fatty acids, fatty acid esters, fatty acid amides, metal soaps, aliphatic alcohols, and silicone-based lubricants can be used.

As described above, the metal magnetic film 3 is formed as a magnetic layer on the surface of the non-magnetic support 2 by vapor deposition or the like.
Furthermore, a carbon protective film was formed on the magnetic layer,
It can be suitably applied to a so-called metal thin film type magnetic recording medium 1.

The magnetic recording medium 1 according to the present embodiment as described above can be manufactured as follows.

First, a ferromagnetic metal thin film to be the metal magnetic film 3 is formed on one main surface of the nonmagnetic support 2 by, for example, a vacuum evaporation method.

Thereafter, a carbon protective film 4 is formed on the metal magnetic film 3 by, for example, a magnetron sputtering method.

Next, on the carbon protective film 4, the above-mentioned adsorption rate to carbon is 15% or more and 80% or less, and the ultraviolet ray spectrum change rate indicating the interaction with the lubricant is 5% or more and 90% or less. The lubricant layer 5 is obtained by dissolving a mixed solution of a compound and a perfluoropolyalkyl ether-based compound having a carboxylic acid and an ester at each of both terminals as a lubricant in a solvent and mixing and applying the mixture.
To form

The back coat layer 6 is formed on the other main surface of the non-magnetic support 2 by coating to obtain the magnetic recording medium 1.

More specifically, as the vacuum deposition apparatus for forming the magnetic layer, there is a continuous winding type vacuum deposition apparatus as shown in FIG.

This vacuum vapor deposition apparatus is configured for so-called oblique vapor deposition, and is cooled to, for example, about -20 ° C. in a vacuum chamber 11 in which the inside is evacuated to, for example, about 1 × 10 ⁻³ Pa. The cooling can 12 rotates counterclockwise as shown by an arrow A, and the evaporation source 13 for a ferromagnetic metal thin film is disposed to face the cooling can 12.

In this vacuum evaporation apparatus, a supply roll 14 rotating in a counterclockwise direction in the drawing and a winding roll 15 rotating in a counterclockwise direction in the drawing are also provided in the vacuum chamber 11. The non-magnetic support 16 is unreeled from the supply roll 14 in the direction indicated by the arrow B in the drawing, travels along the peripheral surface of the cooling can 12, and
5 is wound up.

Note that guide rollers 17 and 18 are disposed between the supply roll 14 and the cooling can 12 and between the cooling can 12 and the take-up roll 15, respectively. A predetermined tension is applied to the non-magnetic support 16 running from the cooling can 12 according to the take-up roll 15, and the non-magnetic support 16
Is designed to run smoothly.

The evaporation source 13 is a container such as a crucible in which a ferromagnetic metal material such as Co is contained. In this vacuum evaporation apparatus, the ferromagnetic metal material of the evaporation source 13 is heated and evaporated. Is also provided. In other words, the ferromagnetic metal material of the evaporation source 13 is acceleratedly irradiated with the electron beam 20 from the electron beam source 19, and the ferromagnetic metal material is heated and evaporated as shown by the arrow C in the figure. Then, the ferromagnetic metal material is deposited on the nonmagnetic support 16 running along the peripheral surface of the cooling can 12 facing the evaporation source 13, and a ferromagnetic metal thin film is formed on the nonmagnetic support 16. It will be.

In the above-mentioned vacuum vapor deposition apparatus, a deposition-preventing plate 21 is provided between the vapor deposition source 13 and the cooling can 12, and a shutter 22 is provided on the deposition-preventing plate 21 so as to be adjustable in position.
Only the vapor-deposited particles incident on the non-magnetic support 16 at a predetermined angle are passed. Thus, the ferromagnetic metal thin film is formed by the oblique deposition method.

Further, at the time of depositing such a ferromagnetic metal thin film, an oxygen gas is supplied to the vicinity of the surface of the nonmagnetic support 16 through an oxygen gas inlet (not shown), whereby the magnetic properties and It is preferable to improve durability and weather resistance. In addition, in order to heat the evaporation source, known means such as a resistance heating means, a high-frequency heating means, and a laser heating means can be used in addition to the above-described heating means using an electron beam.

Here, an example in which a ferromagnetic metal thin film made of Co is formed by the oblique deposition method has been described, but the method of forming a ferromagnetic metal thin film is not limited to this method.
A conventionally known thin film forming method such as a vertical evaporation method or a sputtering method can be applied.

As a material for the ferromagnetic metal thin film, Ni, Fe, or an alloy thereof can be used in addition to Co. At this time, the thickness of the ferromagnetic metal thin film is
It is preferably about 0.01 μm to 1 μm.

Next, a method for forming the carbon protective film 4 will be described. The carbon protective film 4 is formed by a magnetron sputtering method or the like. To form the carbon protective film 4, carbon is deposited on the metal magnetic film 3 using a magnetron sputtering apparatus as shown in FIG.

In this magnetron sputtering apparatus, after the pressure in the chamber 31 is reduced to, for example, about 10 ⁻⁴ Pa by the vacuum pump 32, the exhaust speed is reduced by reducing the angle of the valve 33 that exhausts to the vacuum pump 32 side. At the same time, the Ar gas is introduced from the gas introduction pipe 34, and the degree of vacuum is set to, for example, about 0.8 Pa. Further, the magnetron sputtering apparatus includes a cooling can 35 that is cooled to, for example, −40 ° C. and rotates in the direction of arrow D in FIG.
The cooling can 35 and a target 36 facing each other are provided. The target 36 is a material of the carbon protective film 4 and, for example, carbon or the like is used. Further, the target 36 is supported by a backing plate 37 constituting a cathode electrode.
On the back side of the backing plate 37, a magnet 38 for forming a magnetic field is provided.

Further, this magnetron sputtering apparatus
The above-described magnetic tape roll 15 on which the metal magnetic film 3 is formed is mounted on a rotatable supply shaft (not shown), and the magnetic tape roll 39 is mounted on a take-up shaft rotated by a driving source (not shown). The metal magnetic film 3
Is continuously driven in the direction E in the figure via the cooling can 35.

When the carbon protective film 4 is formed by this magnetron sputtering apparatus, first, Ar gas is introduced from the gas introduction pipe 34, and the cooling can 35 is used as an anode, and the backing plate 37 is used as a cathode.
A voltage of 00 V is applied so that a current of about 1.4 A flows.

Then, by the application of this voltage, Ar gas is turned into plasma, and the ionized ions collide with the target 36, whereby the atoms of the target 36 are repelled. At this time, the magnet 38 is provided on the back side of the backing plate 37, and a magnetic field is formed near the target 36, so that the ionized ions are concentrated near the target 36. The atoms ejected from the target 36 are fed out from the magnetic tape roll 15 in the direction of arrow E in the figure and adhere to the metal magnetic film 3 of the non-magnetic support 2 running along the outer peripheral surface of the cooling can 35. Thus, the carbon protective film 4 is formed. Finally, the non-magnetic support 2 on which the carbon protective film 4 is formed is attached to the magnetic tape roll 3 mounted on the winding shaft.
Winded by 9.

Here, an example in which the carbon protective film 4 is formed by the magnetron sputtering method has been described. However, as a method of forming the carbon protective film 4, in addition to this method, a CVD method, an ion beam sputtering method, an ion beam A conventionally known thin film forming method such as a plating method can be used.

Next, on the carbon protective film 4, the rate of change in the ultraviolet spectrum, which indicates the interaction with the lubricant, is between 5% and 90%.
% Or less of a compound, for example, an aromatic amphipathic compound having a condensed ring in which two or more and four or less benzene rings are bonded and a polar group, and a carboxylic acid and an ester in which each polar group at both ends is a lubricant. The lubricant layer 5 is formed by dissolving a mixed solution of the perfluoropolyalkyl ether-based compound in, for example, toluene and applying and drying the mixed solution.

Further, a back coat layer 6 is formed by applying a back coat paint to the main surface of the non-magnetic support 2 opposite to the surface on which the metal magnetic layer 3 is formed, whereby the magnetic recording medium 1 can be obtained. .

[0092]

EXAMPLES Examples of the present invention will be described below based on specific experimental results, but the present invention is not limited to these examples. 1. Production of Sample Tape <Example 1> In Example 1, a sample tape was produced as follows.

First, a 7.0 μm-thick polyethylene terephthalate film, which is a non-magnetic support, was placed on the above-described FIG.
Co was applied by oblique evaporation using the vacuum evaporation apparatus shown in (1), and a metal magnetic film to be a magnetic layer was formed to a thickness of 180 nm.

Next, a magnetron sputtering apparatus as shown in FIG. 3 described above, the interior ¹⁰ -4 (P
a) After reducing the pressure to about the extent, Ar gas is introduced,
The pressure was set to about 0.8 Pa. Then, the non-magnetic support having the metal magnetic film formed thereon is set in this magnetron sputtering apparatus, and is run at a speed of 5 m / min on a cooling can cooled to −40 ° C. to have a film thickness of approximately 5 m / min. 8
An nm-thick carbon protective film was formed.

Next, a 0.5 μm-thick back coat layer made of carbon and polyurethane resin was formed on the surface of the polyethylene terephthalate film opposite to the surface on which the metal magnetic film was formed.

Next, Compound 1 which is an aromatic amphipathic compound having a condensed ring and a polar group having two or more and four or less benzene rings shown in Table 1 below was added in an amount of 0.10 wt%.
And the lubricant A represented by the following formula 13 and the following table 2 in 0.1.
A mixed solution of 10 wt% dissolved in toluene was applied to the surface of the carbon protective film and dried to form a lubricant layer. Table 2 shows the structural formula of R and the average molecular weight of _Rf in the lubricants A to Q represented by the general formula.

Then, the obtained magnetic recording medium was filled with 6.35.
The sample tape of Example 1 was cut to a width of mm.

<Examples 2 to 375> As a compound to be dissolved in toluene, an aromatic amphiphilic compound having a condensed ring in which two or more and four or less benzene rings are bonded and a polar group shown in Table 1 below. Certain compounds 1 to 25
And the lubricants represented by the following formulas 13 and 2 are combined as shown in the following tables 4 to 18, except that
A sample tape was produced in the same manner as in Example 1.

<Comparative Example 1 and Comparative Example 2> Except that the lubricant shown in Table 3 below was used as a lubricant to be dissolved in toluene, and that no compound was dissolved in toluene,
A sample tape was produced in the same manner as in Example 1.

[0100]

Embedded image

[0101]

[Table 1]

[0102]

[Table 2]

[0103]

[Table 3]

[0104]

[Table 4]

[0105]

[Table 5]

[0106]

[Table 6]

[0107]

[Table 7]

[0108]

[Table 8]

[0109]

[Table 9]

[0110]

[Table 10]

[0111]

[Table 11]

[0112]

[Table 12]

[0113]

[Table 13]

[0114]

[Table 14]

[0115]

[Table 15]

[0116]

[Table 16]

[0117]

[Table 17]

[0118]

[Table 18]

[0119] 2. Evaluation of Characteristics First, the characteristics of the 377 types of sample tapes of Examples 1 to 375, Comparative Example 1 and Comparative Example 2 were evaluated. Here, the durability and the running property were evaluated. Specifically, the amount of the lubricant applied to the sample tape, the friction coefficient, the still durability, and the shuttle durability were evaluated. As the environmental conditions for evaluating these, the conditions considered to be the most severe conditions were adopted after studying by the present inventors. (1) Measurement of amount of lubricant applied The amount of lubricant applied was measured for each sample tape by measuring the absorbance of each sample tape by total reflection infrared absorption spectroscopy using a hemispherical ATR metal crystal. The amount of lubricant applied to the surface was measured. The results are shown in Tables 4 to 18. (2) Measurement of friction coefficient The measurement of the friction coefficient was performed by setting the environmental conditions in a thermostat to a temperature of 40 ° C.
The humidity was controlled at 80% RH, and each sample tape was run for 100 passes in this constant temperature bath. In addition, the numerical value of the 100th pass of friction running was defined as the friction coefficient. Table 1 shows the results.
9 to Table 33. (3) Evaluation of Still Durability Still durability was evaluated in a constant temperature bath at -5 ° C. A commercially available digital video camcorder (manufactured by Sony Corporation, model name:
Using DCR-VX1000), the time required for the reproduction output of each sample tape to drop by 3 dB was measured.
The results are shown in Tables 19 to 33. (4) Evaluation of shuttle durability Shuttle durability is determined by setting the environmental conditions in a constant temperature bath to a temperature of 40 ° C.
The humidity is controlled to 20% RH, and a commercially available digital video camcorder (manufactured by Sony Corporation, model name: DCR) is controlled in this thermostat.
-VX1000), each sample tape was run for 100 pass shuttles, and after running for 100 passes, how many dB the reproduction output dropped from the initial output was measured and evaluated. The results are shown in Tables 19 to 33.

[0120]

[Table 19]

[0121]

[Table 20]

[0122]

[Table 21]

[0123]

[Table 22]

[0124]

[Table 23]

[0125]

[Table 24]

[0126]

[Table 25]

[0127]

[Table 26]

[0128]

[Table 27]

[0129]

[Table 28]

[0130]

[Table 29]

[0131]

[Table 30]

[0132]

[Table 31]

[0133]

[Table 32]

[0134]

[Table 33]

By comparing the absorbances of the examples and comparative examples in Tables 4 to 18, it was found that in the lubricant layer, an aromatic ring having a condensed ring in which two or more and four or less benzene rings are bonded and a polar group. In the sample tape of the embodiment having a system amphiphilic compound and a perfluoropolyalkyl ether compound having both polar groups at both ends having a carboxylic acid and an ester as a lubricant, the amount of the lubricant retained on the carbon protective film Can be increased.

Further, in Tables 19 to 33, by comparing Examples and Comparative Examples, it was found that in the lubricant layer, an aromatic ring having a condensed ring in which two or more and four or less benzene rings are bonded and a polar group. Examples of sample tapes comprising an aromatic group-based amphiphilic compound and a perfluoropolyalkyl ether-based compound in which each polar group at both ends has a carboxylic acid and an ester as a lubricant, have various uses such as high temperature, high humidity, or low temperature. Under the conditions, the deterioration of the coefficient of friction, still durability and shuttle durability was extremely small, and it was found that very good results were obtained.

From the above results, an aromatic amphiphilic compound having a condensed ring in which two or more and four or less benzene rings are bonded and a polar group in the lubricant layer, and a polarizer having both polarities at both terminals as a lubricant By containing a perfluoropolyalkyl ether compound having a carboxylic acid and an ester as a group, the amount of lubricant retained on the carbon protective film of the magnetic recording medium can be increased, and even under various use conditions. Since the lubricity was maintained, it was found that a magnetic recording medium having excellent running properties, wear resistance, and durability could be realized. (5) Evaluation of Solubility in Solvent Next, the solubility of each of the lubricants A to S used in Examples 1 to 375 and Comparative Examples 1 and 2 in ethanol, acetone and toluene was investigated. Was. Table 34 shows the results. In Table 34, the symbol “○” indicates that the compound was easily soluble in the solvent, and the symbol “X” indicates that the compound was insoluble in the solvent.

[0138]

[Table 34]

From Table 34, it was found that the lubricant R and the lubricant S did not dissolve in all solvents of ethanol, acetone and toluene. On the other hand, the lubricants A to Q
Was soluble in all solvents of ethanol, acetone and toluene, and was found to be excellent in solubility in various hydrocarbon solvents.

Therefore, the perfluoropolyalkyl ether compound having polar groups at both ends having a carboxylic acid and an ester can be dissolved in various hydrocarbon solvents such as ethanol, acetone and toluene and applied. It has been found that the influence on the water is small. Next, Compound 1
Compound 25 was quantitatively evaluated for its adsorptivity to the carbon protective film and its interaction with the lubricant. (6) Evaluation of adsorptivity to carbon Examples 1 to 375, Comparative Examples 1 and 2 above
After forming the carbon protective film on the sample tape, the carbon powder adhering to the magnetron sputtering device is sampled, and the adsorptivity of each compound to carbon is determined by measuring the adsorptivity of each compound to this carbon powder. Was evaluated.

Specifically, 5 g of a carbon powder collected from a magnetron sputtering apparatus was packed in a column for liquid chromatography, and Compounds 1 to 25 were charged.
Was dissolved in each column to give an eluate. Next, the amount of the compound adsorbed on the carbon powder was measured by measuring the weight of each compound in the eluate. Then, the adsorption rate (%) to carbon was determined by the following equation (1). Table 35 shows the results. (7) Evaluation of Interaction with Lubricant The interaction between the compound and the lubricant was evaluated by determining the rate of change in the ultraviolet spectrum.

Specifically, first, compound 1 or compound 2
5 was dissolved in a methylene chloride solution at a concentration of 0.1 mM,
The UV spectrum was measured.

Next, 0.1 ml of the lubricant solution was added dropwise to the methylene chloride solution in which each compound was dissolved, and the ultraviolet spectrum was measured. Here, each compound and the lubricant are
When interacting, it has been found that the ultraviolet spectrum changes through the grading cluster. Therefore, from the values of the ultraviolet spectrum before and after the dropping of the lubricant solution, the ultraviolet spectrum change rate (%) was calculated by the following equation (2).
The results are shown in Table 35.

[0144]

(Equation 1)

[0145]

(Equation 2)

[0146]

[Table 35]

As shown in Table 35, Compounds 1 to 25
It was confirmed that the rate of adsorption to carbon was in the range of 15% to 80%, and the rate of change in ultraviolet spectrum was in the range of 5% to 90%.

As described above, in the lubricant layer, the rate of adsorption to carbon is 15% or more and 80% or less, and the rate of change in the ultraviolet spectrum showing the interaction with the lubricant is 5% or more and 9% or less.
By containing a compound containing 0% or less of a compound and a perfluoropolyalkyl ether compound having both polar groups at both ends having a carboxylic acid and an ester as a lubricant, the compound is retained on the carbon protective film of the magnetic recording medium. The amount of lubricant can be increased, and the lubricity is maintained under various use conditions, so that it is possible to realize a magnetic recording medium with excellent running properties, wear resistance, and durability. .

[0149]

The magnetic recording medium according to the present invention comprises a non-magnetic support, a magnetic layer formed on one main surface of the non-magnetic support, and a carbon protective film formed on the magnetic layer. A magnetic recording medium comprising a lubricant layer formed on the carbon protective film and containing a lubricant, wherein the lubricant layer comprises:
A compound having an adsorption rate to carbon of 15% or more and 80% or less and an ultraviolet spectrum change rate indicating an interaction with the lubricant of 5% or more and 90% or less; It contains a perfluoropolyalkyl ether compound having an ester.

The magnetic recording medium according to the present invention having the above-described structure has an absorption rate of 15% to 80% in carbon during lubrication and a change rate of ultraviolet spectrum indicating an interaction with the lubricant. And a perfluoropolyalkyl ether-based compound in which each polar group at both ends has a carboxylic acid and an ester.

Thus, in this magnetic recording medium, the surface state of the carbon protective film can be set to a state in which the lubricant is easily held, and the applicability of the lubricant can be improved. That is, this magnetic recording medium can hold a sufficient amount of lubricant on the carbon protective film.

Therefore, according to the present invention, it is possible to provide a magnetic recording medium having excellent running properties, abrasion resistance and durability by maintaining excellent lubricity.

[Brief description of the drawings]

FIG. 1 is a longitudinal sectional view showing a configuration example of a magnetic recording medium to which the present invention is applied.

FIG. 2 is a schematic configuration diagram of a continuous winding vacuum evaporation apparatus for forming a ferromagnetic metal thin film.

FIG. 3 is a schematic configuration diagram of a magnetron sputtering apparatus for forming a carbon protective film.

[Description of Signs] 1 magnetic recording medium, 2 nonmagnetic support, 3 metal magnetic film, 4 carbon protective film, 5 lubricant layer, 6 back coat layer

──────────────────────────────────────────────────続 き Continued on the front page (51) Int. Cl. ⁷ Identification symbol FI theme coat ゛ (Reference) C10M 129/12 C10M 129/12 129/40 129/40 129/42 129/42 129/44 129/44 129 / 72 129/72 129/76 129/76 131/10 131/10 131/12 131/12 133/06 133/06 133/08 133/08 169/04 169/04 // C10N 20:00 C10N 20: 00 B 30:00 30:00 Z 30:06 30:06 40:18 40:18 (72) Inventor Kenichi Kurihara 6-7-35 Kita-Shinagawa, Shinagawa-ku, Tokyo Inside Sony Corporation (72) Inventor Takeshi Kobayashi, Sony Corporation, 7-35 Kita-Shinagawa, Shinagawa-ku, Tokyo (72) Inventor Hiroshi Iwamoto Hiroshi Iwamoto, 6-35, Kita-Shinagawa, Shinagawa-ku, Tokyo Inside Sony Corporation (72) Inventor Toshinori Tsuboi F-term (reference) 4H104 BB02C BB04C BB05C BB08C BB17C BB18C BB19C BB33C 6-35 Kita Shinagawa, Shinagawa-ku, Tokyo BB35C BD06C BD07C BE02C BE04C CD04A EA11C LA03 LA20 PA16 5D006 AA01 AA02 AA05 AA06 FA06

Claims (9)

[Claims] 1. A non-magnetic support, a magnetic layer formed on one main surface of the non-magnetic support, a carbon protective film formed on the magnetic layer, and a carbon protective film formed on the carbon protective film A lubricant layer containing a lubricant, wherein the lubricant layer has a carbon adsorption rate of 15% to 80%.
% Or less, and a compound having an ultraviolet spectrum change rate indicating an interaction with the lubricant of 5% or more and 90% or less,
And a magnetic recording medium comprising a perfluoropolyalkyl ether compound having a carboxylic acid and an ester at both polar groups at both ends. 2. The magnetic recording medium according to claim 1, wherein the compound is an aromatic amphiphilic compound having a condensed ring in which two to four benzene rings are bonded and a polar group. . 3. The magnetic recording medium according to claim 2, wherein the aromatic amphiphilic compound has a structure represented by the following chemical formula 1. Embedded image 4. The magnetic recording medium according to claim 2, wherein the aromatic amphiphilic compound has a structure represented by the following chemical formula 2. Embedded image 5. The magnetic recording medium according to claim 2, wherein the aromatic amphiphilic compound has a structure represented by the following chemical formula (3). Embedded image 6. The magnetic recording medium according to claim 2, wherein the aromatic amphiphilic compound has a structure represented by the following chemical formula (4). Embedded image 7. The magnetic recording medium according to claim 2, wherein the aromatic amphiphilic compound has a structure represented by the following formula (5). Embedded image 8. The magnetic recording according to claim 1, wherein the perfluoropolyalkyl ether-based compound in which each of the polar groups at both ends has a carboxylic acid and an ester has a structure represented by the following chemical formula (6). Medium. Embedded image 9. The perfluoropolyalkyl ether compound in which each polar group at both ends represented by the above formula (6) has a carboxylic acid and an ester, wherein the hydrocarbon group R has 6 to 30 carbon atoms. 9. The magnetic recording medium according to claim 8, wherein the fluoropolyether group _{Rf has} an average molecular weight of 500 to 6000.