JP2002129451A - Pile fabric for vehicle interior - Google Patents

Pile fabric for vehicle interior

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Publication number
JP2002129451A
JP2002129451A JP2000314807A JP2000314807A JP2002129451A JP 2002129451 A JP2002129451 A JP 2002129451A JP 2000314807 A JP2000314807 A JP 2000314807A JP 2000314807 A JP2000314807 A JP 2000314807A JP 2002129451 A JP2002129451 A JP 2002129451A
Authority
JP
Japan
Prior art keywords
core
pile fabric
spun yarn
vehicle interior
sheath
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000314807A
Other languages
Japanese (ja)
Inventor
Takashi Ando
隆 安藤
Naoshi Kanashige
尚士 金重
Naokata Komitsu
直方 好光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP2000314807A priority Critical patent/JP2002129451A/en
Publication of JP2002129451A publication Critical patent/JP2002129451A/en
Pending legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To provide a pile fabric for vehicle interior improved in spinnability while keeping multicolor property in the pile fabric for vehicle interior obtained by interknitting a regular polyester fiber with a basic dye-dyeable polyethylene terephthalate fiber. SOLUTION: This pile fabric for vehicle interior is obtained by interknitting a spun yarn A composed of a core-sheath type conjugate short fiber containing, as a sheath component, a copolyester containing ethylene terephthalate as a main recurring unit and copolymerized by using 5-sodium sulfoisophthalic acid as a third component and containing polyethylene terephthalate as a core component with a spun yarn B composed of polyester short fiber.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、車輌内装用パイル
布帛に関する。さらに詳しくは紡績性の良好な原綿を用
いた多色性に優れた車輌内装用パイル布帛に関するもの
である。
The present invention relates to a pile fabric for a vehicle interior. More particularly, the present invention relates to a pile fabric for a vehicle interior which is excellent in polychromaticity using raw cotton having good spinnability.

【0002】[0002]

【従来の技術】従来より、輸送用車輌のカーシート表皮
材、ドア内装材などの車輌内装材にはトリコットの起毛
によるもの、ダブルラッセル編やモケット織によるパイ
ルが広く用いられているが、これらの多くはナイロンや
ポリエステルといった合成繊維が用いられてきた。特に
ポリエチレンテレフタレートを中心とするポリエステル
は、その優れた機械的特性や耐光性が認められており、
その使用量が増加してきている。また、近年は消費者の
高級化志向により、更に多色化した複雑なデザインの車
輌内装材が好まれるようになり、様々な多色化の方法が
考案されてきた。最も代表的なものとして、染色性の異
なる2種以上の繊維、つまりレギュラーポリエステル繊
維と塩基性染料可染性ポリエチレンテレフタレート繊維
とをパイル部に交編し、分散染料および塩基性染料で各
パイル糸を染め分ける方法が挙げられ、これにより杢調
など様々なデザインを表現することが可能となった。但
し、この方法で用いる塩基性染料可染性ポリエチレンテ
レフタレートは、レギュラーポリエチレンテレフタレー
トに比べ溶融紡糸時の粘度が大幅に上昇するため、原料
ポリマーの重合度を下げなければならず、結果として得
られる短繊維の強度は低いものであった。そのため、精
紡糸切れを起こさずに安定して操業するためにはスピン
ドル回転数を下げて対応せざるを得ず、レギュラーポリ
エチレンテレフタレート繊維に比べて紡績性が悪いこと
が問題であった。
2. Description of the Related Art Heretofore, tricot napping, double raschel knitting and moquette piles have been widely used for car interior materials such as car seat skin materials and door interior materials for transportation vehicles. Many have used synthetic fibers such as nylon and polyester. In particular, polyester mainly polyethylene terephthalate has been recognized for its excellent mechanical properties and light resistance,
Its usage is increasing. Further, in recent years, due to consumers' desire for higher quality, more and more multi-colored vehicle interior materials having a complicated design have been favored, and various multi-coloring methods have been devised. As the most typical example, two or more kinds of fibers having different dyeing properties, that is, a regular polyester fiber and a basic dye-dyeable polyethylene terephthalate fiber are mixed and knitted in a pile portion, and each pile yarn is dispersed with a disperse dye and a basic dye. There is a method of dyeing different colors, which makes it possible to express various designs such as heather. However, the basic dye-dyeable polyethylene terephthalate used in this method has a much higher viscosity during melt spinning than regular polyethylene terephthalate. The fiber strength was low. Therefore, in order to operate stably without causing breakage of the spinning, the spindle rotation speed must be reduced to cope with the problem, and there is a problem that the spinnability is lower than that of regular polyethylene terephthalate fiber.

【0003】[0003]

【発明が解決しようとする課題】本発明の目的は、レギ
ュラーポリエステル繊維と塩基性染料可染性ポリエチレ
ンテレフタレート繊維の交編による車輌内装用パイル布
帛において、多色性を維持しつつ紡績性を向上させた車
輌内装用パイル布帛を提供することにある。
SUMMARY OF THE INVENTION An object of the present invention is to improve the spinnability of a pile fabric for a vehicle interior made by cross-knitting regular polyester fiber and basic dye-dyeable polyethylene terephthalate fiber while maintaining polychromaticity. Another object of the present invention is to provide a pile fabric for a vehicle interior.

【0004】[0004]

【課題を解決するための手段】本発明は上記課題を解決
するために次の構成を有する。すなわち、エチレンテレ
フタレートを主な繰り返し単位とし、5−ナトリウムス
ルホイソフタル酸を第3成分として共重合したコポリエ
ステルを鞘成分とし、ポリエチレンテレフタレートを芯
成分とする芯鞘型複合短繊維からなる紡績糸Aとポリエ
ステル短繊維からなる紡績糸Bとの交編によりなる車輌
内装用パイル布帛である。
The present invention has the following structure to solve the above-mentioned problems. That is, a spun yarn A comprising a core-sheath type composite short fiber having ethylene terephthalate as a main repeating unit, a copolyester copolymerized with 5-sodium sulfoisophthalic acid as a third component as a sheath component, and polyethylene terephthalate as a core component. And a spun yarn B made of polyester staple fiber.

【0005】[0005]

【発明の実施の形態】以下本発明について詳細に説明す
る。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail.

【0006】本発明において、紡績糸Aを構成する芯鞘
型複合短繊維は、鞘成分にエチレンテレフタレートを主
な繰り返し単位とし、5−ナトリウムスルホイソフタル
酸(以下、SSIという)を第3成分として共重合した
コポリエステルを使用する。SSIは該コポリエステル
を構成する全酸成分に対し2.5〜6.0モル%含有さ
せるのが好ましい。SSIの共重合率が2.5モル%未
満であるとカチオン染料の染着座席が少なく染色時に独
特の濃い色彩が得られないので好ましくない。6.0モ
ル%を超えて含有させても発色性は変わらず、溶融紡糸
時の粘度の増加が大きくなり紡糸性が劣るため好ましく
ない。紡績糸Aを構成する芯鞘型複合短繊維の芯成分に
はポリエチレンテレフタレートを使用する。該ポリエチ
レンテレフタレートには少量のイソフタル酸やアジピン
酸などを共重合させても良いが、安価に製造できる未変
成のポリエチレンテレフタレートを用いることが好まし
い。
In the present invention, the core-sheath type composite short fiber constituting the spun yarn A has ethylene terephthalate as a main repeating unit as a sheath component, and 5-sodium sulfoisophthalic acid (hereinafter, referred to as SSI) as a third component. A copolymerized copolyester is used. Preferably, SSI is contained in an amount of 2.5 to 6.0 mol% based on all the acid components constituting the copolyester. If the copolymerization ratio of SSI is less than 2.5 mol%, the number of dyeing seats of the cationic dye is so small that a unique dark color cannot be obtained at the time of dyeing. Even if the content exceeds 6.0 mol%, the color developability does not change, the viscosity during melt spinning increases, and the spinnability deteriorates. Polyethylene terephthalate is used as a core component of the core-sheath type composite short fiber constituting the spun yarn A. A small amount of isophthalic acid or adipic acid may be copolymerized with the polyethylene terephthalate, but it is preferable to use unmodified polyethylene terephthalate which can be produced at low cost.

【0007】このように芯成分にポリエチレンテレフタ
レートを用いることにより、単繊維強度を上昇させるこ
とができ、従来の塩基性染料可染性ポリエチレンテレフ
タレート短繊維の欠点であった紡績性を向上させること
が可能となる。
[0007] By using polyethylene terephthalate as the core component, the strength of the single fiber can be increased, and the spinnability, which is a drawback of the conventional basic dyeable polyethylene terephthalate short fiber, can be improved. It becomes possible.

【0008】本発明における紡績糸Aを構成する芯鞘型
複合短繊維の芯鞘複合重量比率は、芯:鞘が30:70
〜70:30であることが好ましい。芯成分比率が70
より高い場合は単繊維強度が上昇するものの、分散染料
およびカチオン染料で染色後の紡績糸Aの断面が淡染化
するため、車輌内装用パイル布帛として十分な多色効果
が得られないので好ましくない。一方、芯成分比率が3
0より低いと紡績糸Aの断面が淡染化することなく多色
効果が得られるが、単繊維強度が弱いため大きな紡績性
の改善効果が見込めないので好ましくない。また、芯鞘
複合形態は特に限定はされず同心円状、偏芯芯鞘状に複
合できるが、生産性の観点から同心円状に複合するのが
好ましい。
In the present invention, the core-sheath composite short fiber constituting the spun yarn A has a core-sheath composite weight ratio of 30:70.
7070: 30 is preferred. Core component ratio is 70
If it is higher, although the strength of the single fiber increases, the cross section of the spun yarn A after dyeing with a disperse dye and a cationic dye becomes lightly dyed, so that a sufficient multicolor effect as a pile fabric for vehicle interior is not obtained, so that it is preferable. Absent. On the other hand, when the core component ratio is 3
If it is lower than 0, a multicolor effect can be obtained without the cross section of the spun yarn A being lightly dyed. However, since the single fiber strength is weak, a large effect of improving spinnability cannot be expected, which is not preferable. The form of the core-sheath composite is not particularly limited, and the composite can be formed in a concentric shape or an eccentric core-sheath shape. However, from the viewpoint of productivity, the composite is preferably formed in a concentric shape.

【0009】本発明において、紡績糸Bを構成するポリ
エステルは特に限定はされず、ポリエチレンテレフタレ
ート、ポリプロピレンテレフタレート、ポリブチレンレ
テフタレートなどを用いることができるが、安価でかつ
機械的特性に優れたポリエチレンテレフタレートを用い
るのが好ましい。繊維断面は特に限定はされず、丸断
面、四角断面、中空断面、八葉断面、H型断面、Y型断
面など、いずれの断面形態をも用いることが出来る。ま
た、紡績糸Bは単一のポリエステル短繊維から作製して
も、2種以上のポリエステル短繊維を混紡して作製して
もよい。
In the present invention, the polyester constituting the spun yarn B is not particularly limited, and polyethylene terephthalate, polypropylene terephthalate, polybutylene retephthalate and the like can be used, but polyethylene terephthalate which is inexpensive and has excellent mechanical properties is used. It is preferable to use The fiber cross section is not particularly limited, and any cross section such as a round cross section, a square cross section, a hollow cross section, an Yaba cross section, an H-shaped cross section, and a Y-shaped cross section can be used. Further, the spun yarn B may be produced from a single polyester short fiber, or may be produced by blending two or more kinds of polyester short fibers.

【0010】本発明において、紡績糸Aの鞘成分および
芯成分には、見る角度によってパイル布帛の表面が白っ
ぽく見える白ボケ現象防止のため、無機粒子を含有させ
るのが好ましい。無機粒子の含有量は、鞘成分および芯
成分ともに好ましくは0.05〜1重量%、さらに好ま
しくは0.20〜0.40重量%である。
In the present invention, it is preferable that the sheath component and the core component of the spun yarn A contain inorganic particles in order to prevent the surface of the pile fabric from becoming whitish depending on the viewing angle. The content of the inorganic particles is preferably 0.05 to 1% by weight, more preferably 0.20 to 0.40% by weight, for both the sheath component and the core component.

【0011】紡績糸Bを構成するポリエステル短繊維に
も無機粒子を含有させることが上述した観点から好まし
く、無機粒子の含有量は、好ましくは0.05〜3.0
重量%、さらに好ましくは0.20〜2.5重量%であ
る。
From the above viewpoint, it is preferable that the polyester short fibers constituting the spun yarn B also contain inorganic particles, and the content of the inorganic particles is preferably 0.05 to 3.0.
% By weight, more preferably 0.20 to 2.5% by weight.

【0012】無機粒子としては二酸化チタン、硫酸バリ
ウム、酸化亜鉛、シリカ、酸化セリウム、炭酸カルシウ
ム等の化合物を用いることができるが、最も安価で汎用
的である二酸化チタンを使用するのが好ましい。
As the inorganic particles, compounds such as titanium dioxide, barium sulfate, zinc oxide, silica, cerium oxide, and calcium carbonate can be used, but it is preferable to use titanium dioxide which is the cheapest and is widely used.

【0013】本発明の車輌内装用パイル布帛は、上述の
紡績糸Aと紡績糸Bとからなる撚糸を、例えばトリコッ
ト編みし、カットした後起毛したパイル布帛、またはモ
ケット織り、ダブルラッセル編みした後、カットして得
られるパイル布帛を分散染料で染色後、引続き塩基性染
料で染色することにより得ることができる。
The pile fabric for a vehicle interior according to the present invention is obtained by, for example, tricot knitting the above-mentioned spun yarn consisting of the spun yarn A and the spun yarn B, cutting and then raising the pile yarn, or moquette weaving and double raschel knitting. After the dyed pile fabric is dyed with a disperse dye and subsequently dyed with a basic dye.

【0014】本発明の車輌内装用パイル布帛は、乗用
車、トラック、バス、鉄道、船舶、航空機等の輸送用車
輌の内装に用いる部材の少なくとも一部に用いることが
でき、特にカーシート表皮材、ドア内装材に好ましく用
いることができる。
The pile fabric for a vehicle interior according to the present invention can be used for at least a part of members used for the interior of a transport vehicle such as a passenger car, a truck, a bus, a railroad, a ship, an aircraft, and the like. It can be preferably used for door interior materials.

【0015】[0015]

【実施例】以下実施例により本発明を詳細に説明する。
なお、各特性値は以下の方法により求めた。 (1)固有粘度[η] o−クロロフェノールを溶媒として用い、25℃で測定
した溶液粘度から求めた。 (2)車輌内装用パイル布帛の多色性 目視により判定した。 実施例1 エチレンテレフタレート単位に対してSSIを2.5モ
ル%共重合した固有粘度[η]が0.50、二酸化チタ
ンを0.30重量%含有するコポリエステルを鞘成分と
し、固有粘度[η]が0.62、二酸化チタンを0.3
0重量%含有する未変成のポリエチレンフタレートを芯
成分として芯鞘複合重量比率(芯:鞘)50:50で複合
溶融紡糸後に延伸し、ステープル加工して、丸断面で単
繊維繊度2.8dtex、繊維長51mmの複合短繊維
を得て、30Sの紡績糸Aを作成した。また、固有粘度
[η]が0.62、二酸化チタンを2.0重量%含有す
る未変成のポリエチレンフタレートを用いて、丸断面で
単繊維繊度1.7dtex、繊維長51mmのポリエス
テル短繊維を得て、30Sの紡績糸Bを作成した。紡績
糸A、Bを1:1で撚糸後、ダブルラッセル編し、カッ
トした後、分散染料と塩基性染料で染色し、車輌内装用
パイル布帛を得た。紡績糸Aの紡績性は良好であり、ま
た車輌内装用パイル布帛の多色性も良好である。 比較例1 エチレンテレフタレート単位に対してSSIを2.5モ
ル%共重合した固有粘度[η]が0.50、二酸化チタ
ンを0.30重量%含有するコポリエステルを単成分で
使用し、丸断面で単繊維繊度2.8dtex、繊維長5
1mmの短繊維を得て30Sの紡績糸Aを作製した以外
は実施例1と同様の方法で車輌内装用パイル布帛を得
た。多色性は良好であるが、紡績糸Aの紡績性は不良で
あった。 実施例2 紡績糸Aを構成する複合短繊維の芯鞘複合重量比率
(芯:鞘)が35:65である以外は実施例1と同様の方
法で車輌内装用パイル布帛を得た。紡績糸Aの紡績性は
改善効果が見られ、多色性も良好である。 実施例3 紡績糸Aを構成する複合短繊維の芯鞘複合重量比率
(芯:鞘)が65:35である以外は実施例1と同様の方
法で車輌内装用パイル布帛を得た。紡績糸Aの紡績性は
良好であり、また多色性も得られた。
The present invention will be described in detail with reference to the following examples.
In addition, each characteristic value was obtained by the following method. (1) Intrinsic viscosity [η] It was determined from solution viscosity measured at 25 ° C. using o-chlorophenol as a solvent. (2) Polychromaticity of pile fabric for vehicle interior Judgment was made visually. Example 1 An intrinsic viscosity [η] obtained by copolymerizing 2.5 mol% of SSI with respect to ethylene terephthalate unit was 0.50, and a copolyester containing 0.30% by weight of titanium dioxide was used as a sheath component. Is 0.62 and titanium dioxide is 0.3
As a core component, unmodified polyethylene phthalate containing 0% by weight is stretched after composite melt-spinning at a core-sheath composite weight ratio (core: sheath) of 50:50, staple processing, and a single fiber fineness of 2.8 dtex in a round section; A composite short fiber having a fiber length of 51 mm was obtained, and a spun yarn A of 30S was produced. In addition, using unmodified polyethylene phthalate having an intrinsic viscosity [η] of 0.62 and 2.0% by weight of titanium dioxide, a polyester short fiber having a single fiber fineness of 1.7 dtex and a fiber length of 51 mm in a round cross section is obtained. Thus, a spun yarn B of 30S was prepared. The spun yarns A and B were twisted at a ratio of 1: 1 and then double-rasled, cut and then dyed with a disperse dye and a basic dye to obtain a pile fabric for vehicle interior. The spinnability of the spun yarn A is good, and the polychrome of the pile fabric for vehicle interior is also good. Comparative Example 1 A copolyester containing 2.5 mole% of SSI with respect to ethylene terephthalate unit, intrinsic viscosity [η] of 0.50, and titanium dioxide of 0.30% by weight was used as a single component, and a circular cross section was used. 2.8 dtex single fiber fineness, fiber length 5
A pile fabric for vehicle interior was obtained in the same manner as in Example 1 except that a 1 mm short fiber was obtained to produce a spun yarn A of 30S. The polychromaticity was good, but the spinnability of spun yarn A was poor. Example 2 Core-sheath composite weight ratio of composite short fibers constituting spun yarn A
A pile fabric for vehicle interior was obtained in the same manner as in Example 1 except that (core: sheath) was 35:65. The spinnability of the spun yarn A is improved, and the polychromaticity is also good. Example 3 Core-sheath composite weight ratio of composite short fibers constituting spun yarn A
A pile fabric for vehicle interior was obtained in the same manner as in Example 1 except that (core: sheath) was 65:35. The spinnability of the spun yarn A was good, and polychromaticity was also obtained.

【0016】[0016]

【表1】 [Table 1]

【0017】[0017]

【発明の効果】本発明によれば、多色性を維持しつつ紡
績性に優れた車輌内装用パイル布帛を提供することがで
きる。
According to the present invention, it is possible to provide a pile fabric for a vehicle interior excellent in spinnability while maintaining polychromaticity.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】エチレンテレフタレートを主な繰り返し単
位とし、5−ナトリウムスルホイソフタル酸を第3成分
として共重合したコポリエステルを鞘成分とし、ポリエ
チレンテレフタレートを芯成分とする芯鞘型複合短繊維
からなる紡績糸Aとポリエステル短繊維からなる紡績糸
Bとの交編によりなることを特徴とする車輌内装用パイ
ル布帛。
1. A core-sheath composite short fiber comprising ethylene terephthalate as a main repeating unit, a copolyester copolymerized with 5-sodium sulfoisophthalic acid as a third component, a sheath component, and polyethylene terephthalate as a core component. A pile fabric for vehicle interiors, comprising a cross-knitting of a spun yarn A and a spun yarn B made of polyester short fibers.
【請求項2】紡績糸Aを構成する芯鞘型複合短繊維の芯
鞘複合重量比率(芯:鞘)が30:70〜70:30であ
ることを特徴とする請求項1に記載の車輌内装用パイル
布帛。
2. The vehicle according to claim 1, wherein the core / sheath composite short fiber constituting the spun yarn A has a core / sheath composite weight ratio (core: sheath) of 30:70 to 70:30. Pile fabric for interior.
JP2000314807A 2000-10-16 2000-10-16 Pile fabric for vehicle interior Pending JP2002129451A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000314807A JP2002129451A (en) 2000-10-16 2000-10-16 Pile fabric for vehicle interior

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007132869A1 (en) * 2006-05-15 2007-11-22 Honda Motor Co., Ltd. Interior automotive polypropylene terephthalate cloth and production process
CN102362797A (en) * 2011-06-30 2012-02-29 江苏金辰针纺织有限公司 Double-side towel
CN102490409A (en) * 2011-11-01 2012-06-13 常熟新诚鑫织造有限公司 Double-faced towel fabric

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007132869A1 (en) * 2006-05-15 2007-11-22 Honda Motor Co., Ltd. Interior automotive polypropylene terephthalate cloth and production process
US7921677B2 (en) 2006-05-15 2011-04-12 Honda Motor Co., Ltd. Vehicular upholstery polypropyleneterephthalate fiber fabric and method for producing of fabric
JP5035698B2 (en) * 2006-05-15 2012-09-26 本田技研工業株式会社 Automotive interior polypropylene terephthalate fiber fabric and manufacturing method
CN102362797A (en) * 2011-06-30 2012-02-29 江苏金辰针纺织有限公司 Double-side towel
CN102490409A (en) * 2011-11-01 2012-06-13 常熟新诚鑫织造有限公司 Double-faced towel fabric

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