JP2002101858A - Emulsion stabilizer for milk beverage - Google Patents

Emulsion stabilizer for milk beverage

Info

Publication number
JP2002101858A
JP2002101858A JP2000295394A JP2000295394A JP2002101858A JP 2002101858 A JP2002101858 A JP 2002101858A JP 2000295394 A JP2000295394 A JP 2000295394A JP 2000295394 A JP2000295394 A JP 2000295394A JP 2002101858 A JP2002101858 A JP 2002101858A
Authority
JP
Japan
Prior art keywords
fatty acid
acid ester
emulsion stabilizer
milk
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000295394A
Other languages
Japanese (ja)
Inventor
Yasutaka Muratsubaki
康隆 村椿
Yoshiyo Kondo
佳代 近藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DKS Co Ltd
Original Assignee
Dai Ichi Kogyo Seiyaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dai Ichi Kogyo Seiyaku Co Ltd filed Critical Dai Ichi Kogyo Seiyaku Co Ltd
Priority to JP2000295394A priority Critical patent/JP2002101858A/en
Publication of JP2002101858A publication Critical patent/JP2002101858A/en
Pending legal-status Critical Current

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  • Dairy Products (AREA)
  • Tea And Coffee (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide an emulsion stabilizer for a milk beverage, excellent in preservation stability, and capable of being stably applied to the milk beverage without using special stirring devices, when the stabilizer is heated to be dissolved. SOLUTION: This emulsion stabilizer for the milk beverage is compounded from 6-16 wt.% of a sucrose fatty acid ester, 29-69 wt.% of a glycerol fatty acid monoester, 9-21 wt.% of a sorbitan fatty acid ester, 8-28 wt.% of a glycerol citric acid fatty acid ester and/or a polyglycerol fatty acid ester, and 3-7 wt.% of sodium caseinate.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、乳飲料用乳化安定
剤に関するものである。
TECHNICAL FIELD The present invention relates to an emulsion stabilizer for milk drinks.

【0002】[0002]

【従来の技術】コーヒー乳飲料、ミルクティー、ココア
飲料のような乳飲料は保存安定性を確保するために各種
乳化剤、安定剤が使用されるのが一般的であった。乳飲
料を保存したときに脂肪の浮上によってできるオイルリ
ング現象を防止し、またオイルリングが生じた場合でも
軽い振とうで分散できる乳化安定剤(特開平6−125
706号公報)も提案されているが、これらの乳化安定
剤は使用時すなわち溶解時に、ホモミキサー等の特別な
攪拌装置を使用しないと、完全な溶解が望めず、品質の
よい乳飲料を得難いという問題があった。
2. Description of the Related Art Milk drinks such as coffee milk drinks, milk teas and cocoa drinks generally use various emulsifiers and stabilizers to ensure storage stability. An emulsion stabilizer which prevents the oil ring phenomenon caused by floating of fat when storing a milk drink and which can be dispersed by light shaking even if an oil ring occurs (Japanese Patent Laid-Open No. 6-125)
706) has been proposed, but these emulsion stabilizers cannot be completely dissolved unless a special stirring device such as a homomixer is used at the time of use, that is, at the time of dissolution, and it is difficult to obtain a high-quality milk beverage. There was a problem.

【0003】[0003]

【発明が解決しようとする課題】本発明は、保存安定性
が優れており、しかも加熱溶解する際に、通常のプロペ
ラ攪拌にて簡単に溶解するため、特別な攪拌装置を要す
ることなく安定して使用できる乳飲料用乳化安定剤を提
供することを課題とする。
DISCLOSURE OF THE INVENTION The present invention has excellent storage stability and, when heated and dissolved, is easily dissolved by ordinary propeller stirring. It is an object of the present invention to provide an emulsion stabilizer for milk beverages which can be used by using.

【0004】[0004]

【課題を解決するための手段】本発明者等は、全く予期
されなかったことであるが、前述の特開平6−1257
06号公報記載の発明において、グリセリン脂肪酸エス
テルとしてグリセリンモノ脂肪酸エステルと、グリセリ
ンコハク酸脂肪酸エステルを使用していたが、グリセリ
ンコハク酸脂肪酸エステルの代わりにグリセリンクエン
酸脂肪酸エステル及び/又はポリグリセリン脂肪酸エス
テルを使用することによって、保存安定性に非常に優
れ、しかも容易に安定して溶解できる乳飲料用乳化安定
剤が得られることを見いだし、本発明を完成した。
Means for Solving the Problems Although the present inventors have not expected at all, the above-mentioned Japanese Patent Application Laid-Open No. 6-1257 / 1994 has been proposed.
In the invention described in Japanese Patent Application Publication No. 06-2006, a glycerin monofatty acid ester and a glycerin succinic acid fatty acid ester are used as the glycerin fatty acid ester. It has been found that the use of E.g. provides an emulsion stabilizer for milk drinks which is very excellent in storage stability and which can be easily and stably dissolved, thereby completing the present invention.

【0005】すなわち、本発明の乳飲料用乳化安定剤
は、ショ糖脂肪酸エステル6〜16重量%、グリセリン
モノ脂肪酸エステル29〜69重量%、ソルビタン脂肪
酸エステル9〜21重量%、グリセリンクエン酸脂肪酸
エステル及び/又はポリグリセリン脂肪酸エステル8〜
28重量%およびカゼインナトリウム3〜7重量%を必
須成分として含有してなる乳飲料用乳化安定剤である。
That is, the emulsion stabilizer for milk beverages of the present invention comprises 6 to 16% by weight of sucrose fatty acid ester, 29 to 69% by weight of glycerin mono fatty acid ester, 9 to 21% by weight of sorbitan fatty acid ester, and glycerin citrate fatty acid ester. And / or polyglycerin fatty acid ester 8 to
It is an emulsion stabilizer for milk beverages containing 28% by weight and sodium caseinate 3 to 7% by weight as essential components.

【0006】[0006]

【発明の実施の形態】上記各脂肪酸エステルを構成する
脂肪酸の種類は特に限定されないが、炭素数が12〜2
2の飽和又は不飽和脂肪酸の1種又は2種以上の混合物
であるのが一般的である。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The type of fatty acid constituting each of the above fatty acid esters is not particularly limited, but may have 12 to 2 carbon atoms.
It is generally a mixture of one or more of two saturated or unsaturated fatty acids.

【0007】グリセリンクエン酸脂肪酸エステルとポリ
グリセリン脂肪酸エステルは単独で使用されても併用さ
れてもよい。また、ポリグリセリン脂肪酸エステルのグ
リセリンの平均重合度は4以下で、脂肪酸の結合数が3
以下であるのが好ましい。
[0007] Glycerin fatty acid fatty acid ester and polyglycerin fatty acid ester may be used alone or in combination. The average degree of polymerization of glycerin in the polyglycerol fatty acid ester is 4 or less, and the number of fatty acid bonds is 3 or less.
It is preferred that:

【0008】なお、カゼインナトリウムは一般に食品に
用いられるものであればよく、特に限定されるものでは
ない。
The sodium caseinate is not particularly limited as long as it is generally used in foods.

【0009】かかる本発明の乳化安定剤は、コーヒー乳
飲料、ミルクティー、ココア飲料などの乳及び乳製品を
原料とする飲料に使用されるものであり、乳飲料全量に
対して、0.1〜0.5重量%程度の配合で十分な効果
を得ることができる。
The emulsion stabilizer of the present invention is used in beverages containing milk and dairy products as raw materials, such as coffee milk beverages, milk teas, and cocoa beverages. A sufficient effect can be obtained with a blending amount of about 0.5% by weight.

【0010】本発明の乳化安定剤の各成分の割合は、前
述の通りであるが、一般にショ糖脂肪酸エステルは9〜
14重量%、グリセリン脂肪酸エステルは39〜59重
量%、ソルビタン脂肪酸エステルは12〜18重量%で
あるのが好ましい。
The proportion of each component of the emulsion stabilizer of the present invention is as described above.
Preferably, 14% by weight, 39 to 59% by weight of glycerin fatty acid ester and 12 to 18% by weight of sorbitan fatty acid ester.

【0011】[0011]

【実施例】次に、本発明の実施例および比較例を挙げる
が、本発明はこれによって限定されるものではない。 実施例1〜4及び比較例1〜4 表1の処方に従って乳化安定剤を得た。なお、表中の数
値は特に断らない限り重量%を示す。
EXAMPLES Next, examples and comparative examples of the present invention will be described, but the present invention is not limited thereto. Examples 1 to 4 and Comparative Examples 1 to 4 Emulsion stabilizers were obtained according to the formulation in Table 1. The numerical values in the table indicate% by weight unless otherwise specified.

【0012】[0012]

【表1】 [Table 1]

【0013】(コーヒー乳飲料)つぎの手順でコーヒー
乳飲料を調製し本発明の効果を確認した。 (1)配合 . 原 料 配合割合(部) . 牛乳 25 . 砂糖 8 . インスタントコーヒー 1.4 . 重曹(pH調整) 0.01 . 乳化安定剤 0.1 . 水 残 . 合計 100 (2)調製方法 (1)に示した配合処方に従い、水に乳化安定剤、イン
スタントコーヒー、牛乳、砂糖、重曹を添加し、65℃
に加温し、ホモミキサーにて攪拌混合(10,000rpm ×5m
in)して乳化物を得た。これを容器に充填後、オートク
レーブにて殺菌(120℃×15min )後、5℃に冷却
してコーヒー乳飲料を調製した。 (3)評価 上記の方法にて調製したコーヒー乳飲料を、40℃で1
日、5℃で1日保存を1サイクルとし、保存安定性を評
価し、その結果を表2に示した。
(Coffee milk drink) A coffee milk drink was prepared by the following procedure, and the effect of the present invention was confirmed. (1) Formulation. Raw material mixing ratio (parts) . Milk 25. Sugar 8. Instant coffee 1.4. Baking soda (pH adjustment) 0.01. Emulsion stabilizer 0.1. Water remains . Total 100 (2) Preparation method Emulsion stabilizer, instant coffee, milk, sugar and baking soda are added to water according to the formulation shown in (1),
And stirred and mixed with a homomixer (10,000rpm × 5m
in) to give an emulsion. This was filled in a container, sterilized in an autoclave (120 ° C. × 15 min), and cooled to 5 ° C. to prepare a coffee milk beverage. (3) Evaluation The coffee milk beverage prepared by the above-mentioned method was
The storage stability was evaluated as one cycle of storage at 5 ° C. for one day, and the results are shown in Table 2.

【0014】[0014]

【表2】 [Table 2]

【0015】(評価方法) 溶解性:乳化安定剤が0.4%の水溶液を70℃にて3
0分攪拌溶解し、120メッシュの篩で濾過し、不溶物
を目視にて判断する。 ○:プロペラ攪拌で不溶物がない ×:プロペラ攪拌で不溶物がある 保存安定性:保存中のコーヒー乳飲料のオイルリングを
目視にて観察する。 ○:オイルリングなし △:オイルリング僅かにあり ×:オイルリングあり
(Evaluation method) Solubility: An aqueous solution containing 0.4% of an emulsion stabilizer was added at 70 ° C. for 3 hours.
The mixture is stirred and dissolved for 0 minutes, filtered through a sieve of 120 mesh, and insoluble matter is visually determined. :: No insoluble material was stirred by propeller. X: Insoluble material was stirred by propeller. Storage stability: The oil ring of the coffee milk beverage during storage was visually observed. ○: No oil ring △: Slight oil ring ×: With oil ring

【0016】実施例1〜4の乳化安定剤では、溶解性及
び保存安定性のいずれにも非常に優れた、品質のよいコ
ーヒー乳飲料を安定して製造できた。しかし、比較例
1、2、3の乳化安定剤では、溶解性には優れるが、保
存安定性が悪く、また、比較例4の乳化安定剤では、保
存安定性は良好だが、溶解性が悪く、品質のよいコーヒ
ー乳飲料を製造することが困難であった。
The emulsion stabilizers of Examples 1 to 4 were able to stably produce high-quality coffee milk beverages having excellent solubility and storage stability. However, the emulsion stabilizers of Comparative Examples 1, 2, and 3 are excellent in solubility but poor in storage stability, and the emulsion stabilizers of Comparative Example 4 have good storage stability but poor solubility. It was difficult to produce a high quality coffee milk beverage.

【0017】(ミルクティー)つぎの手順でミルクティ
ーを調製し本発明の効果を確認した。 (1)配合 . 原 料 配合割合(部) . 牛乳 25 . 砂糖 8 . 紅茶抽出液 30 . 重曹(pH調整) 0.01 . 乳化安定剤 0.1 . 水 残 . 合計 100 (2)調製方法 (1)に示した配合処方に従い、水に乳化安定剤、紅茶
抽出液、牛乳、砂糖、重曹を添加し、65℃に加温し、
ホモミキサーにて攪拌混合(10,000rpm ×5min)して乳
化物を得た。これを容器に充填後、オートクレーブにて
殺菌(120℃×15min )後、5℃に冷却してミルク
ティーを調製した。 (3)評価 上記の方法にて調製したミルクティーを、40℃で1
日、5℃で1日保存を1サイクルとし、保存安定性を評
価し、その結果を表3に示した。
(Milk Tea) A milk tea was prepared by the following procedure, and the effect of the present invention was confirmed. (1) Formulation. Raw material mixing ratio (parts) . Milk 25. Sugar 8. Black tea extract 30. Baking soda (pH adjustment) 0.01. Emulsion stabilizer 0.1. Water remains . Total 100 (2) Preparation method According to the formulation shown in (1), add an emulsion stabilizer, black tea extract, milk, sugar, and sodium bicarbonate to water, and heat to 65 ° C.
An emulsion was obtained by stirring and mixing (10,000 rpm × 5 min) with a homomixer. This was filled in a container, sterilized in an autoclave (120 ° C. × 15 min), and cooled to 5 ° C. to prepare milk tea. (3) Evaluation The milk tea prepared by the above method was
The storage stability was evaluated as one cycle of storage at 5 ° C. for one day, and the results are shown in Table 3.

【0018】[0018]

【表3】 [Table 3]

【0019】(評価方法) 溶解性:乳化安定剤が0.4%の水溶液を70℃にて3
0分攪拌溶解し、120メッシュの篩で濾過し、不溶物
を目視にて判断する。 ○:プロペラ攪拌で不溶物がない ×:プロペラ攪拌で不溶物がある 保存安定性:保存中のミルクティーのオイルリングを目
視にて観察する。 ○:オイルリングなし △:オイルリング僅かにあり ×:オイルリングあり
(Evaluation method) Solubility: An aqueous solution containing 0.4% of an emulsion stabilizer was added at 70 ° C. for 3 hours.
The mixture is stirred and dissolved for 0 minutes, filtered through a sieve of 120 mesh, and insoluble matter is visually determined. :: No insoluble matter was stirred by propeller. X: Insoluble matter was found by stirring propeller. Storage stability: The oil ring of milk tea during storage was visually observed. ○: No oil ring △: Slight oil ring ×: With oil ring

【0020】実施例1〜4の乳化安定剤では、溶解性及
び保存安定性のいずれにも非常に優れた、品質のよいミ
ルクティーを安定して製造できた。しかし、比較例1、
2、3の乳化安定剤では、溶解性には優れるが、保存安
定性が悪く、また、比較例4の乳化安定剤では、保存安
定性は良好だが、溶解性が悪く、品質のよいミルクティ
ーを製造することが困難であった。
The emulsion stabilizers of Examples 1 to 4 were able to stably produce high-quality milk teas having excellent solubility and storage stability. However, Comparative Example 1,
A few emulsion stabilizers are excellent in solubility but poor in storage stability, and the emulsion stabilizer of Comparative Example 4 is good in storage stability but poor in solubility and high quality milk tea. Was difficult to manufacture.

【0021】[0021]

【発明の効果】本発明による乳化安定剤では、溶解性及
び保存安定性のいずれにも非常に優れた、品質のよい乳
飲料を得ることができる。
EFFECTS OF THE INVENTION The emulsion stabilizer according to the present invention makes it possible to obtain a milk beverage of excellent quality in both solubility and storage stability.

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4B001 AC05 AC40 AC44 EC53 4B017 LC10 LE10 LG14 LK09 LK11 LK18 LL06 LP13 LP15 4B027 FB13 FB24 FC05 FE08 FK03 FK18 FP85 FQ19  ──────────────────────────────────────────────────続 き Continued on front page F term (reference) 4B001 AC05 AC40 AC44 EC53 4B017 LC10 LE10 LG14 LK09 LK11 LK18 LL06 LP13 LP15 4B027 FB13 FB24 FC05 FE08 FK03 FK18 FP85 FQ19

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 ショ糖脂肪酸エステル6〜16重量%、
グリセリンモノ脂肪酸エステル29〜69重量%、ソル
ビタン脂肪酸エステル9〜21重量%、グリセリンクエ
ン酸脂肪酸エステル及び/又はポリグリセリン脂肪酸エ
ステル8〜28重量%、及びカゼインナトリウム3〜7
重量%を必須成分として含有してなる乳飲料用乳化安定
剤。
1. A sucrose fatty acid ester having 6 to 16% by weight,
29-69% by weight of glycerin mono fatty acid ester, 9-21% by weight of sorbitan fatty acid ester, 8-28% by weight of glyceric acid fatty acid ester and / or polyglycerin fatty acid ester, and 3-7% of sodium caseinate
An emulsion stabilizer for dairy beverages containing, by weight, an essential component.
【請求項2】 ポリグリセリン脂肪酸エステルのグリセ
リンの平均重合度が4以下であり、脂肪酸の結合数が3
以下である請求項1記載の乳飲料用乳化安定剤。
2. The polyglycerol fatty acid ester has an average degree of polymerization of glycerin of 4 or less, and the number of fatty acid bonds is 3 or less.
The emulsion stabilizer for milk beverages according to claim 1, which is:
【請求項3】 請求項1記載の乳化安定剤を含有する乳
飲料。
3. A milk beverage containing the emulsion stabilizer according to claim 1.
JP2000295394A 2000-09-28 2000-09-28 Emulsion stabilizer for milk beverage Pending JP2002101858A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000295394A JP2002101858A (en) 2000-09-28 2000-09-28 Emulsion stabilizer for milk beverage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000295394A JP2002101858A (en) 2000-09-28 2000-09-28 Emulsion stabilizer for milk beverage

Publications (1)

Publication Number Publication Date
JP2002101858A true JP2002101858A (en) 2002-04-09

Family

ID=18777824

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000295394A Pending JP2002101858A (en) 2000-09-28 2000-09-28 Emulsion stabilizer for milk beverage

Country Status (1)

Country Link
JP (1) JP2002101858A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003325147A (en) * 2002-05-08 2003-11-18 Sanei Gen Ffi Inc Coconut milk-containing food and drink and method for producing the same
JP2006025743A (en) * 2004-07-20 2006-02-02 Mitsubishi Chemicals Corp Emulsion stabilizer and milk beverage containing the same
JP2012105638A (en) * 2010-10-22 2012-06-07 Sanei Gen Ffi Inc Stabilizer for high raw-bean content coffee and method for stabilization thereof
KR101165691B1 (en) * 2003-01-20 2012-07-18 미쓰비시 가가꾸 가부시키가이샤 Emulsion stabilizer and milk drink containing the same
CN104824161A (en) * 2015-05-26 2015-08-12 内蒙古蒙牛乳业(集团)股份有限公司 Milk beverage and preparation method thereof
CN112568347A (en) * 2019-09-27 2021-03-30 理研维他命株式会社 Milk component-containing beverage

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003325147A (en) * 2002-05-08 2003-11-18 Sanei Gen Ffi Inc Coconut milk-containing food and drink and method for producing the same
KR101165691B1 (en) * 2003-01-20 2012-07-18 미쓰비시 가가꾸 가부시키가이샤 Emulsion stabilizer and milk drink containing the same
JP2006025743A (en) * 2004-07-20 2006-02-02 Mitsubishi Chemicals Corp Emulsion stabilizer and milk beverage containing the same
JP2012105638A (en) * 2010-10-22 2012-06-07 Sanei Gen Ffi Inc Stabilizer for high raw-bean content coffee and method for stabilization thereof
CN104824161A (en) * 2015-05-26 2015-08-12 内蒙古蒙牛乳业(集团)股份有限公司 Milk beverage and preparation method thereof
CN112568347A (en) * 2019-09-27 2021-03-30 理研维他命株式会社 Milk component-containing beverage
CN112568347B (en) * 2019-09-27 2024-07-05 理研维他命株式会社 Milk component-containing beverage

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