JP2001334514A - Manufacturing method for hardened body, and manufacturing device for hardened body - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a manufacturing method for a hardened body, and a manufacturing device for the hardened body by which the hardened body can be efficiently mass-produced from a paper-making sludge. SOLUTION: This manufacturing device for the hardened body comprises a material-adjusting mechanism 10, a paper-making mechanism 20, an inverting device 40, a pressing machine 50 and a dryer 60. In this case, the material- adjusting mechanism 10 adjusts the paper-making sludge, and forms a slurry 14. The paper-making mechanism 20 is equipped with a carrying belt 23 which transfers a paper-making body made from the slurry 14 in wire cylinders 22A, 22B and 22C and carries the paper-making body. The pressing machine 50 performs dehydration by pressurizing the paper-making body. By adjusting the carrying speed of the carrying belt 23 to be 20 to 80 m/minute, the paper- making body 26 of a proper thickness can be made from the slurry 14 at a high efficiency, and the hardened body 1 can be efficiently mass-produced.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method and an apparatus for producing a cured product capable of mass-producing a cured product obtained by solidifying papermaking sludge into a plate shape.

[0002]

2. Description of the Related Art Effective utilization of various industrial wastes has been studied in recent years from the viewpoint of protecting the global environment. For example, in the construction industry, which has consumed a large amount of forest resources until now, new construction materials are required for industrial waste,
It has been proposed to reduce the consumption of forest resources. On the other hand, it has been demanded to realize low cost and high functionality of conventionally used inorganic boards such as calcium silicate board, perlite board, slag gypsum board, wood chip cement board and gypsum board.

The present inventors have disclosed a technology for producing a cured product which can be effectively used as a building panel or the like, after dewatering and press-drying papermaking sludge generated after the production of paper and curing it by drying. No. 352586.

However, the dewatering press method is inferior in mass productivity. To solve such a problem, Japanese Unexamined Patent Publication No.
In Japanese Patent No. 114628, a mixture of papermaking sludge and cement diluted to a solid content of 3% is made by a rotating drum, transferred from the drum surface onto a band blanket, dewatered and pressed, and further wound up by a winding roll. A technique is disclosed in which after being increased, cut and conveyed. Also,
Japanese Patent Application Laid-Open No. 59-156956 discloses a papermaking method using a round wire mesh, and discloses a technique of forming a mat one by one and forming a multilayer. However, with these techniques, the thickness variation was large. Furthermore, paper sludge is colored under the influence of ink and pulp impurities, and in the dehydration press method, the impurities remain in the cured product as they are,
There was a problem that the lightness of the cured product was lowered, and the cured product could not be colored or decorated.

[0005]

In the above patent, the present inventor has shown that a cured product can be obtained by curing papermaking sludge, but the cured product cannot be produced in a profitable manner. . In order to actually mass-produce the cured product, it was necessary to establish a technique for forming a papermaking sludge by forming a papermaking sludge with an appropriate thickness.

SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and an object of the present invention is to provide a method and an apparatus for producing a cured product capable of efficiently mass-producing a cured product from papermaking sludge. Is to provide.

Another object is to provide a cured product having high brightness.

[0008]

According to a first aspect of the present invention, there is provided a method for producing a cured product, comprising forming a raw material solution containing papermaking sludge by using a filter body, and forming a papermaking sludge on the surface of the filter body. And the paper is transferred to a conveyor belt at a speed of 5 to 80 m / min and then transferred, cut to a predetermined size, and the paper is hardened to obtain a hardened papermaking sludge. The transport speed of the transport belt is 5 to 8
Since it is 0 m / min, a paper having an appropriate thickness can be formed from the raw material solution with high efficiency, and a cured product can be efficiently mass-produced from papermaking sludge. Here, if the conveying speed of the conveying belt is lower than 5 m / min, the sheet can be thickly formed, but the sheeting efficiency is low and the thickness is uneven.
On the other hand, if the conveying speed exceeds 80 m / min, the paper is thinned, it is difficult to obtain a uniform thickness, the paper may be cut off, and the thickness is uneven.

According to a second aspect of the present invention, the concentration of the raw material solution containing papermaking sludge is from 3.5 to 25% by weight of solid content, so that the papermaking property from papermaking sludge is improved.
The cured body can be mass-produced efficiently. That is, if the concentration is less than 3.5%, it is not possible to efficiently make a paper from a raw material solution using a filtrate, and if it exceeds 25%, the uniformity of the product is reduced.

In the method for producing a cured product according to the third aspect, since the paper is dewatered while being conveyed by the conveyor belt, the moisture in the paper can be efficiently reduced.

According to a fourth aspect of the present invention, the paper body on the conveyor belt is multilayered while being transferred to a rotary drum for cutting, and the multilayered paper body is cut when it reaches a predetermined thickness. For this reason, it is possible to continuously form a sheet having a uniform thickness.

In the method for producing a cured product according to a fifth aspect of the present invention, the cut sheet is further multi-layered and then pressed under pressure. Therefore, a cured body having a required thickness can be easily manufactured.

In the method for producing a cured product according to a sixth aspect, the pressing is performed at a pressure of 10 to 250 kg / cm ² . Pressing 10kg
If performed at less than / cm ² , the required strength cannot be obtained. On the other hand, even if the pressure exceeds 250 kg / cm ² , the strength cannot be increased even if the pressing is performed, and the press apparatus is increased in size and cost.

[0014] In the apparatus for producing a cured product according to a seventh aspect of the present invention, a raw material solution containing papermaking sludge is formed, and a filter body for adhering a papermaking sludge paperwork to the surface thereof and a paper body adhering to the surface of the filter body are transferred. Conveyor belt with a speed of 5 to 80 m / min, a cutting device that cuts the paper body conveyed by the conveyor belt into a predetermined size, and a hardened papermaking sludge by hardening the cut paper body. A curing device. Since the transport speed of the transport belt is 5 to 80 m / min, a paper having an appropriate thickness can be formed from the raw material solution with high efficiency, and the cured product can be efficiently mass-produced from papermaking sludge.
Here, if the conveying speed is lower than 5 m / min, the papermaking body can be made thicker, but the papermaking efficiency is low and the thickness uniformity is low. On the other hand, if the transport speed exceeds 80 m / min, the papermaking article becomes thinner, making it difficult to obtain a uniform thickness and cutting off the papermaking article.

[0018] The apparatus for manufacturing a cured product according to the present invention comprises a rotating drum in which the drainage body is a mesh. For this reason, it is possible to continuously form a paper having an appropriate thickness from the raw material solution, and it is possible to efficiently mass-produce the cured body from the papermaking sludge.

According to the ninth aspect of the present invention, since the rotating speed of the rotary drum is 1 to 100 times / minute, a paper having an appropriate thickness can be formed from the raw material solution with high efficiency, and the paper sludge can be efficiently formed. This makes it possible to mass-produce the cured body.
Here, if the rotating drum is lower than 1 rotation / minute, the papermaking efficiency is low. On the other hand, when the rotation speed exceeds 100 rotations / minute,
With a uniform thickness, it becomes difficult to form a papermaking body.

According to a tenth aspect of the present invention, there is provided an apparatus for producing a cured product, in which a plurality of drainage bodies are provided along a conveyor belt, and the papermaking body is transferred to the conveyor belt while being multilayered. For this reason, a paper having an appropriate thickness can be formed from the raw material solution with high efficiency, and the cured product can be efficiently mass-produced from papermaking sludge.

In the apparatus for manufacturing a cured product according to the eleventh aspect, the drainage body has a mesh structure of $ 40 to 150. For this reason, a paper having an appropriate thickness can be formed from the raw material solution with high efficiency, and a high-density cured product can be efficiently mass-produced from papermaking sludge. Here, if the mesh is coarser than # 40, only the inorganic non-crystalline material comes off from the raw material solution, and the density and strength of the cured product decrease. On the other hand, if the mesh is finer than # 150, the removal of water becomes worse, and it becomes impossible to make a papermaking product from the raw material solution with high efficiency.

In the apparatus for producing a cured product according to the twelfth aspect, since the transport belt is formed of a porous body having continuous pores, the paper can be dewatered while being transported by the transport belt, thereby efficiently forming the paper. We can reduce moisture in.

[0020] The apparatus for producing a cured product according to the thirteenth aspect of the present invention comprises a cutting rotary drum in which the cutting device forms a multilayer while transferring the papermaking product. Then, when the multilayered paper body on the surface of the cutting rotary drum reaches a predetermined thickness, the extrusion mechanism is operated to cut the paper body at a position corresponding to the groove. For this reason, it is possible to efficiently produce a paper having a uniform thickness.

According to a fourteenth aspect of the present invention, the cutting device includes a blade that cuts the paper having one end cut by the cutting rotary drum at a constant interval. For this reason, it is possible to efficiently form a papermaking body having a predetermined length.

[0022]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS First, the structure of a composite cured product produced by the method for producing a composite cured product of the present invention, which will be described later, will be described with reference to the schematic diagram of FIG. The composite cured body 1 is composed of an inorganic amorphous body 2 composed of two or more oxides.
And that the organic fibrous material 3 is mixed in the inorganic amorphous body 2. Here, the inorganic amorphous body composed of two or more oxides refers to an oxide (1) -oxide (2)... -Oxide (n) (where n is a natural number, Oxide (1), oxide (2), ... oxide (n)
Are different oxides).

Although it is difficult to accurately define such an amorphous substance, it is considered that an amorphous compound is an amorphous compound that is formed by a solid solution or hydration reaction of two or more oxides. Conceivable. Such inorganic amorphous compounds are analyzed by fluorescent X-ray analysis to determine the elements (Al, Si,
Ca, Na, Mg, P, S, K, Ti, Mn, Fe, Z
and at least two types selected from n), and a halo is observed in the range of 2θ: 10 ° to 40 ° in the analysis chart by X-ray diffraction. This halo is a gentle undulation of the intensity of the X-ray, and is observed as a broad swell on the X-ray chart. The halo has a half width of 2θ:
2 ° or more.

The above-mentioned composite cured product 1 is firstly made of an inorganic amorphous material 2
Becomes a strength developing material, and the organic fibrous material 3 is dispersed in the inorganic amorphous material 2 to improve the fracture toughness value, so that the bending strength value and impact resistance can be improved. Also,
A homogeneous cured product having no anisotropy in strength can be obtained. Furthermore, since it is an amorphous body, there is an advantage that sufficient strength can be obtained at a low density.

Although the reason why the above-mentioned amorphous material becomes a strength-expressing substance is not clear, it is presumed that it is because the progress of cracks is inhibited as compared with the crystalline structure. Further, since the fibrous material is more easily dispersed uniformly in the amorphous state than in the crystalline state, it is considered that the fracture toughness value is also improved. As a result, even if a nail is driven or a through hole is provided,
Since cracks do not occur, it is optimal for materials that require processing, such as building materials.

Here, as the oxide, a metal and / or non-metal oxide can be used, and Al ₂ O ₃ , Si
O ₂ , CaO, Na ₂ O, MgO, P ₂ O ₅ , SO ₃ ,
It is desirable to be selected from K ₂ O, TiO ₂ , MnO, Fe ₂ O ₃ and ZnO. In particular, Al ₂ O ₃ —S
iO ₂ -CaO-based or Al ₂ O ₃ -SiO ₂ -CaO
-An amorphous body composed of an oxide or a composite of these amorphous bodies is optimal. The oxide in the latter amorphous body is at least one kind of metal and / or non-metal oxide except Al ₂ O ₃ , SiO ₂ and CaO.

First, the amorphous body composed of the Al ₂ O ₃ —SiO ₂ —CaO system includes Al ₂ O ₃ , SiO ₂ and CaO.
Is a compound having an amorphous structure in which all or a part of each component is formed by solid solution or hydration reaction with each other. That is, Al ₂ O ₃ and SiO ₂ , SiO ₂ and Ca
O, Al ₂ O ₃ and CaO, and Al ₂ O ₃ , SiO ₂
It is considered to include any of the compounds formed by causing a solid solution or hydration reaction or the like with a combination of CaO and CaO.

Such an inorganic amorphous compound has a fluorescent X
Al, Si, and Ca were confirmed by the line analysis, and the halo was observed in the range of 2θ: 10 ° to 40 ° in the analysis chart by X-ray diffraction.

Further, Al ₂ O ₃ , SiO ₂ and CaO
Other than at least one oxide, ie, Al
_The amorphous body composed of ₂ O ₃ —SiO ₂ —CaO—oxide system includes, in addition to the combination of the above Al ₂ O ₃ —SiO ₂ —CaO system, Al ₂ O ₃ and oxide, and SiO ₂ and oxide ,
CaO and oxide, Al ₂ O ₃ and SiO ₂ and oxide, Si
O ₂ and CaO and oxide, Al ₂ O ₃ and CaO and oxide,
Then, it is considered that it contains any of the compounds formed by causing a solid solution or hydration reaction with a combination of Al ₂ O ₃ , SiO ₂ , CaO and oxide.

It is to be noted that the oxide is two or more, ie, Al
_{If it is a 2} O ₃ —SiO ₂ —CaO—oxide (n) -based (n is a natural number of 2 or more) amorphous material, these oxides, for example, oxide (1), oxide (2). ..Oxide (n)
(N is a natural number of 2 or more, and the oxide (n) means a different oxide if the value of n is different, and
₂ O ₃ , SiO ₂ , and CaO), and a compound formed by performing a solid solution or hydration reaction with at least two combinations selected from the group consisting of Al ₂ and Al _2.
Compounds formed by performing a solid solution or hydration reaction with at least two kinds of combinations selected from O ₃ , SiO ₂ , and CaO, and oxides (1), oxides (2),.
At least one selected from oxides (n) (n is a natural number of 2 or more) and Al ₂ O ₃ , SiO ₂ , Ca
It is considered to include any of the compounds formed by solid solution or hydration reaction in combination with at least one selected from O.

Such an inorganic amorphous compound has a fluorescent X
According to the line analysis, in addition to Al, Si and Ca, the elements (Na, Mg, P, S, K, Ti, Mn, F
e, Zn at least two types), and in the analysis chart by X-ray diffraction, 2θ: 10 ° to
The halo is seen in the range of 40 °.

Here, Al ₂ O ₃ , SiO ₂ and Ca
Oxides to be combined with O are one kind or two or more kinds, and are metals other than Al ₂ O ₃ , SiO ₂ and CaO and / or
Alternatively, non-metal oxides can be used, such as Na ₂ O, M
gO, P ₂ O ₅ , SO ₃ , K ₂ O, TiO ₂ , MnO,
It can be selected from Fe ₂ O ₃ and ZnO. This selection can be made based on the characteristics expected of the composite cured product.

For example, since Na ₂ O or K ₂ O can be removed with an alkali or the like, if the removal treatment is performed prior to the plating treatment, the surface to be plated of the surface of the composite hardened body is roughened and acts as an anchor for plating. be able to. Mg
O forms a solid solution with Al ₂ O ₃ , SiO ₂ , and CaO to contribute to strength development, and greatly improves bending strength and impact resistance. P
₂ O ₅ is particularly advantageous when used for biomaterials (artificial roots, artificial bones) to aid adhesion with bone. SO ₃
Has a bactericidal action and is suitable for antibacterial building materials. TiO
₂ is a white colorant and also acts as a photo-oxidation catalyst, so it can forcibly oxidize attached organic pollutants and can be cleaned only by irradiating light. Has a unique effect that it can be used as a reaction catalyst. MnO is useful as a dark colorant, Fe ₂ O ₃ is useful as a light colorant, and ZnO is useful as a white colorant. These oxides may be present alone in the amorphous body.

It is preferable that the raw material solution contains no cement or 30% by weight or less of cement in solid content. When the cement is contained, the papermaking property is improved, but the strength is lowered and the brightness is lowered. 30% by weight is the upper limit.

In the cured product of the present invention, papermaking sludge is formed and hardened, and an organic amorphous material composed of polysaccharide and carbonic acid are contained in an inorganic amorphous material composed of oxides of Si, Al and Ca. a cured product which comprises calcium, Ca in the cured product, Al, Si content, respectively CaO, Al ₂ O _3, in terms of SiO ₂ CaO / Si
The cured product has an O ₂ ratio of 0.2 to 7.9 and a CaO / Al ₂ O ₃ ratio of 0.2 to 12.5. The lightness of the cured product is N5 or more as a value based on JIS Z 8721. The amounts of Ca, Al, and Si (in terms of CaO, Al ₂ O ₃ , and SiO ₂ ) are the total amounts of Ca, Al, and Si in the composite cured body.
If so, it refers to the amount of calcium carbonate and all Ca in the inorganic amorphous material. In addition, the CaO / SiO ₂ ratio of 0.2
And the ratio of CaO / Al ₂ O ₃ is not more than 7.9 and not more than 7.9.
Most preferably, the cured product is adjusted to more than 2 and not more than 12.5.

In the present invention, the cured product is manufactured by making a paper using a mesh-shaped rotating drum. Since impurities are dropped from the mesh, the impurities can be reduced and the brightness can be increased. is there. Further, a cured product containing calcium carbonate, wherein Ca, Al, S in the cured product
When the amount of i is converted into CaO, Al ₂ O ₃ , and SiO ₂ , respectively, the ratio of CaO / SiO ₂ is 0.2 to 7.9,
Since the ratio of / Al ₂ O ₃ is adjusted from 0.2 to 12.5, the Ca component increases and the brightness improves. Also,
This is because strength and nailing performance are also high.

For this reason, the brightness of the cured product is determined according to JIS
It can be N5 or more with a value based on the definition of Z 8721.
Note that JIS Z 8721 sets the ideal black lightness to 0.
The ideal white lightness is assumed to be 10, and each color is divided into 10 so that the perception of the brightness is equal between the black lightness and the white lightness, and is indicated by symbols N0 to N10. It was done. The actual lightness measurement is compared with the color charts corresponding to N0 to N10. In this case, the first place of the decimal point is 0 or 5. The brightness of the cured product is JIS Z 8
Since the value based on the rule 721 can be N5 or more, coloring and decoration can be performed.

It is desirable that the calcium carbonate crystal habit is at least one form selected from a spindle shape, a square shape, a thin table shape, a cubic shape, and a column shape. This is because the whiteness is high, and since it has corners, it hardly gets caught in the fiber and falls off, so that it can be incorporated into the cured product even in papermaking.

In the present invention, the synthetic fibers are incorporated by papermaking, and the improvement of the strength and the improvement of the fracture toughness can be realized as compared with the case where the synthetic fibers are simply mixed with the raw materials and dewatered and pressed. The reason is that the synthetic fiber is taken into the cured body in an extended state.

When the papermaking sludge cement is added, its content is desirably 30% by weight or less. This is because the brightness decreases. Also, it is recognized that the addition of cement reduces the strength.

JP-A-55-12853 discloses a technique in which papermaking sludge is wire-pressed, dewatered, and hot-pressed. However, the sludge at that time was only about 2.6% by weight in terms of CaO according to the "Shizuoka Paper Industry Testing Laboratory Report" published in 1979, and the strength was not sufficient. Also, because it is not papermaking,
It contains a large amount of impurities and eventually has low brightness.

In Japanese Patent Publication No. 57-19019, a mixture of papermaking sludge and montmorillonite is press-molded. However, the papermaking sludge at that time contains a small amount of Ca. Poor strength etc. Japanese Patent Application Laid-Open No. 50-101604 discloses a board obtained by mixing papermaking sludge with hydrophobic fibers and adding a binder.

However, the papermaking sludge at that time contained only a small amount of Ca and had a bending strength of 2.5%.
kg / cm ² , even if it is compounded and has high strength,
Only about 15 kg / cm ² , the present invention is much better. JP-A-52-90585 discloses a papermaking sludge whose surface is subjected to paraffin treatment. However, the papermaking sludge at that time had a low Ca component,
It is considered to be inferior in strength. In any case, since it is not a papermaking method, it contains a large amount of impurities, and eventually has low brightness.

The composition of the above-mentioned amorphous body was made of Al ₂
Al ₂ O ₃ in terms of O ₃ , SiO ₂ and CaO:
3 to 51% by weight based on the total weight of the composite cured body, Si
O ₂ : 6 to 53% by weight based on the total weight of the composite cured body and CaO: 6 to 63% by weight, preferably 8 to 63% by weight based on the total weight of the composite cured body, and the total thereof is 1
It is preferable to contain it in a range not exceeding 00% by weight.

The reason is that the content of Al ₂ O ₃ is 3% by weight.
If the content is less than 50% or more than 51% by weight, the strength of the composite cured product will be reduced, and if the content of SiO ₂ is less than 6% by weight or more than 53% by weight, the strength of the composite cured product will be reduced. Further, the content of CaO is less than 6% by weight or 63% by weight.
Even when the amount exceeds the weight percentage, the strength of the composite cured product is reduced.

Further, Al ₂ O ₃ , SiO ₂ and CaO
Oxides other than Na ₂ O, MgO, P ₂ O ₅ , S
O ₃ , K ₂ O, TiO ₂ , MnO, Fe ₂ O ₃ and Z
When one or more kinds of nO are contained, the preferred contents of each component are as follows. It goes without saying that the total amount of these oxides does not exceed 100% by weight. Na ₂ O: 0.1 to 1.2% by weight based on the total weight of the composite cured body MgO: 0.3 to 11.0% by weight based on the total weight of the composite cured body P ₂ O ₅ : Composite cured body 0.1 to 3.5% by weight based on the total weight of the composite cured product SO ₃ : 0.1 to 3.5% by weight based on the total weight of the composite cured product K ₂ O: 0 based on the total weight of the composite cured product .1～1.2 wt% TiO _2: from 0.1 to 8.7 wt% MnO, relative to the total weight of the composite hardened product: 0.1 to 1.5 wt% Fe with respect to the total weight of the composite cured body ₂ O ₃ : 0.2 to 17.8% by weight based on the total weight of the composite cured body ZnO: 0.1 to 1.8% by weight based on the total weight of the composite cured body The reason for limiting the range is that if the ratio is outside the above range, the strength of the composite cured body is reduced.

Incidentally, it can be confirmed by X-ray diffraction whether or not it has an amorphous structure. That is, 2θ: 10 ° by X-ray diffraction
If a halo is observed in the region of ４０40 °, it can be confirmed that it has an amorphous structure. In the present invention, in addition to those having a completely amorphous structure, Hydrogen Aluminum Silicate, Kaolinite, Zeolit
e, Gehlenite, syn, Anorthite, Melitite, Gehlenit
e-synthetic, tobermorite, xonotlite, ettringite
Or SiO ₂ , Al ₂ O ₃ , CaO, Na ₂ O, Mg
O, P ₂ O ₅ , SO ₃ , K ₂ O, TiO ₂ , MnO, F
oxides such as e ₂ O ₃ and ZnO, and CaCO ₃
Crystals such as (Calcite) may be mixed.

[0048] These crystals are not considered to be strength-inducing substances themselves, but, for example, if they have the effects of increasing the hardness and density to improve the compressive strength and suppressing the progress of cracks. Conceivable. The content of the crystal is desirably 0.1 to 50% by weight based on the total weight of the composite cured product. This is because if the crystal content is less than 0.1% by weight, effects such as increasing the hardness and density to improve the compressive strength and suppressing the progress of cracks cannot be sufficiently obtained. This is because bending strength is reduced.

Incidentally, the above Al ₂ O ₃ —SiO ₂ type crystalline compound is made of Hydrogen Aluminum Silicate, Kaolini.
te, Zeolite, Al ₂ O ₃ —CaO based crystalline compounds are Calcium Aluminate, CaO—SiO ₂ based crystalline compounds are Calcium Silicate, Al ₂ O ₃ —SiO ₂ —Ca
O-type crystalline compounds are Gehlenite, syn and Anorthite, and Al ₂ O ₃ —SiO ₂ —CaO—MgO-type crystalline compounds are Melitite and Gehlenite-synthetic.
Further, it is desirable that the above-mentioned crystal contains Ca, and Gehlenite, syn (Ca ₂ Al ₂ O ₇ ), Melitite-s
_{ynthetic (Ca 2 (Mg 0.5 Al} 0.5) (Si 1. 5 Al
_0.5 O ₇ )), Gehlenite-synthetic (Ca ₂ (Mg
_0.25 Al _0.75 ) (Si _1.25 Al _0.75 O ₇ )), Anorthit
e, ordered (Ca ₂ Al ₂ Si ₂ O ₈ ) and calcium carbonate (Calcite) may be contained.

In the composite cured product produced by the production method of the present invention, a halogen may be added to an amorphous material composed of at least two oxides. The halogen serves as a catalyst for a solid solution or hydrate formation reaction and also acts as a combustion suppressing substance. Its content is 0.1-1.
2% by weight is desirable. This is because if it is less than 0.1% by weight, the strength is low, and if it exceeds 1.2% by weight, harmful substances are generated by combustion. As the halogen, chlorine, bromine and fluorine are desirable.

Similarly, calcium carbonate (Calcite) may be added. Calcium carbonate itself is not a strength-expressing substance, but it is thought that by surrounding the calcium carbonate with an amorphous body, it contributes to strength improvement by actions such as inhibiting the progress of cracks. The content of the calcium carbonate is 48 to the total weight of the composite cured product.
% By weight or less is desirable. The reason for this is that if it exceeds 48% by weight, the bending strength is reduced. Further, the content is desirably 0.1% by weight or more. If the content is less than 0.1% by weight, it does not contribute to the improvement in strength.

Further, the addition of a binder is advantageous for further improving the strength and for improving the water resistance, chemical resistance and fire resistance. The binder desirably comprises one or both of a thermosetting resin and an inorganic binder. As thermosetting resins, phenolic resins,
At least one resin selected from melamine resin, epoxy resin and urea resin is desirable. The inorganic binder is preferably at least one selected from the group consisting of sodium silicate, silica gel and alumina sol.

Next, in the method for producing a composite cured product of the present invention, the organic fibrous material mixed with the inorganic amorphous material is an organic fibrous material composed of a polysaccharide. This is because polysaccharides have an OH group, and Al ₂ O ₃ ,
This is because they are easily bonded to various compounds of SiO ₂ or CaO.

The polysaccharide is desirably at least one compound selected from amino sugars, uronic acids, starch, glycogen, inulin, lichenin, cellulose, chitin, chitosan, hemicellulose and pectin. As the organic fibrous material comprising these polysaccharides, in general, pulp, pulp grounds, and crushed waste paper such as newspapers and magazines are advantageously suited.

The content of the fibrous material is 2 to 75.
% By weight. The reason for this is that if the content is less than 2% by weight, the strength of the composite cured product is reduced, while if it exceeds 75% by weight, the fire protection performance, water resistance, dimensional stability and the like may be reduced. Further, the average length of the fibrous material is desirably 10 to 1000 μm. If the average length is too short, no entanglement occurs, and if the average length is too long, voids are formed and the strength of the composite cured product is likely to decrease.

The above composite cured product 1 is optimally obtained by drying and coagulating and curing paper sludge (scum). That is, the papermaking sludge is a pulp residue containing an inorganic substance, contains an organic fibrous substance, is low in cost because industrial waste is used as a raw material, and contributes to solving environmental problems. Moreover, this papermaking sludge itself has a function as a binder, and is kneaded with itself or with other industrial waste.
It has the advantage that it can be formed into a desired shape.

In the papermaking sludge, besides pulp, Al ₂ O ₃ , SiO ₂ , CaO, Na ₂ O, Mg
O, P ₂ O ₅ , SO ₃ , K ₂ O, TiO ₂ , MnO, F
It generally contains a crystal of e ₂ O ₃ and ZnO or a sol that is a precursor of these oxides, or a composite thereof, at least one selected from halogen and calcium carbonate, and water.

Here, as shown in FIG.
It is advantageous to mix the inorganic particles 4 therein to improve the fire resistance or to form a strength-expressing substance by reacting with the amorphous material to improve the strength. By doing so, the specific gravity of the composite cured product can also be adjusted.

As the inorganic particles 4, at least one selected from calcium carbonate, calcium hydroxide, shirasu, shirasu balloon, perlite, aluminum hydroxide, silica, alumina, talc, calcium carbonate, and industrial waste powder is used. it can. In particular, as the industrial waste powder, it is desirable to use at least one or more types of industrial waste powder selected from calcined powder of papermaking sludge, grinding dust of glass, and crushed silica sand. This is because by using these industrial waste powders, cost reduction can be realized and furthermore, it can contribute to solving environmental problems.

The inorganic particles obtained by firing papermaking sludge can be obtained by subjecting papermaking sludge to heat treatment at 300 to 1500 ° C. The inorganic particles thus obtained are:
Since it is amorphous, has excellent strength and toughness, and has a low density, it can be reduced in weight by being dispersed in a composite cured product. In addition, the papermaking sludge is heated to 300 ° C or more and 800 ° C
The inorganic particles obtained by quenching at less than or less than 300 ° C. and then heat-treating at 300 to 1500 ° C. are advantageous because they surely contain an amorphous body. It is desirable that the inorganic particles 4 have a specific surface area of 0.8 to 100 m ² / g. If it is less than 0.8 m ² / g, the contact area between the amorphous material and the inorganic particles becomes small and the strength is reduced.
If it exceeds m ² / g, effects such as crack development and improvement in hardness are reduced, and as a result, strength is reduced.

Further, the inorganic particles 4 may contain at least one inorganic substance selected from silica, alumina, iron oxide, calcium oxide, magnesium oxide, potassium oxide, sodium oxide and phosphorus pentoxide. desirable. This is because they are chemically stable and have excellent weather resistance, and have desirable characteristics as industrial materials such as building materials.

If the average particle diameter of the inorganic particles 4 is too small or too large, sufficient strength cannot be obtained.
It is desirably in the range of 〜100 μm. The content of the inorganic particles is desirably 10 to 90% by weight. That is, if the amount of the inorganic particles is too large, the strength is lowered, and if the amount of the inorganic particles is too large, the strength becomes brittle, and in any case, the strength is lowered.

Composite cured product 1 produced by the method of the present invention
Is used in various industries, calcium silicate plate,
It can be used for electronic materials such as artificial materials for artificial limbs, artificial bones, artificial dental roots, core substrates of printed wiring boards, interlayer resin insulation layers, as well as new building materials to replace perlite boards, plywood, gypsum boards, etc. it can.

Next, an embodiment of a method for producing a cured product and an apparatus for producing a cured product according to the present invention will be described with reference to FIGS. In the production method of the present invention, papermaking sludge is used as a raw material of the composite cured body without kneading with other industrial waste. The papermaking sludge used in the production method of the present invention includes printing / information paper, kraft paper, titanium paper,
Papermaking sludge discharged in the pulp manufacturing process when manufacturing tissue paper, dust paper, toilet paper, sanitary goods, towel paper, industrial hybrid paper or household hybrid paper, raw material processing such as waste paper, and papermaking processes, etc. desirable. Paper sludge is handled by Maruto Kiln.

FIG. 3 shows the entire structure of the apparatus for producing a cured body. The apparatus for producing a cured product includes a raw material adjustment mechanism 10 that adjusts papermaking sludge to generate a slurry 14, a papermaking mechanism 20 that papers a paper 26 from the slurry 14, and an inverting device 40 that inverts the paper 26. A press 50 for dehydrating by pressing after laminating the papers 26, and a drier 60 for drying the pressed papers to form the cured body 1.
Consists of

First, a raw material adjusting mechanism 10 for adjusting the raw material.
Will be described with reference to FIG. Raw material 1 above
1 and water 12 were weighed by suction dehydration described later so that the solid content became 3.5 to 25% by weight, and the mixture was mixed with a mixer 13.
And a coagulant (a flocculant: added amount of 0.01 to 4) of aluminum sulfate, ferric chloride, polyaluminum chloride, sodium polyacrylate, polymethacrylate, polyacrylate, or polyacrylamide. 5%) and organic fibers such as vinylon fibers (binder: added amount: 0.1 to 10% by weight).
The mixture is mixed at 3 to prepare a slurry 14. Organic fibers (binders) include synthetic fibers such as polyethylene, polypropylene, and vinylon, pipes, pulp recovered from waste paper,
Besides, fibrous industrial waste can be used. As a raw material, various inorganic powders and resins can be further added to papermaking sludge.

The slurry 14 was placed on the bottom of the filter 1
Suction dehydration is performed using the dehydration container 15 provided with 6.
The concentration is adjusted to 3.5 to 25% by weight of solid content by suction dehydration. In the suction dehydration, since the fibers of the papermaking sludge are not oriented, the resulting composite cured product is less likely to warp or crack.

The bottom of the dewatering vessel 15 is provided with a vacuum pump 17
And suction of water by the operation of the vacuum pump 17. The filter 16 is not particularly limited, but includes a sintered metal, a perforated metal plate (a metal plate having a hole having a diameter of 1 to 5 mm),
A porous ceramic filter, a porous resin, a glass fiber plate or the like can be used. The raw material 14 whose water content has been adjusted in the dehydration container 15 is temporarily stored in a chest tank 18.
The chest tank 18 is provided with a stirring propeller so that solids in the raw material do not settle.

In this embodiment, the water content is adjusted by the dehydration vessel 15, but as shown in FIG. 4B, only the amount of water added to the mixer 13 is reduced without using the dehydration vessel 15. It is also possible to adjust the water content with.

Subsequently, the papermaking unit 2 was prepared from the slurry 14 containing the papermaking sludge whose water content had been adjusted by the papermaking mechanism 20.
6 is generated. An inorganic binder such as cement or an organic binder such as a resin may be added to the slurry (raw material solution). The papermaking mechanism 20 will be described with reference to FIG. The papermaking mechanism 20 includes three bats 21A, 21B, and 21C that store the slurry 14, and a wire cylinder 2 that is provided in the bat and that papers the slurry 14.
2A, 22B, 22C and wire cylinders 22A, 2C
A conveyor belt 23 for transferring and conveying the paper body 26 formed by 2B and 22C, a cutting drum 30 for winding and cutting the paper body 26 conveyed by the conveyor belt 23 to a predetermined thickness, Cutter 36 for cutting the body 26
And a belt conveyor 38 for conveying the papermaking body 26.

Wire cylinders 22A, 22B, 22C
Has a diameter of 70 cm and a width of 1 mm. In this embodiment, since the drainage body for draining (papermaking) is composed of a rotating drum (wire cylinder) composed of a net-like body, the papermaking body 26 can be continuously formed from the raw material solution 14, and the papermaking sludge can be efficiently produced. The mass can be mass-produced.
The water that has passed through the wire cylinders 22A, 22B, and 22C passes through a pipe 17a and a vacuum pump 17 as shown in FIG.
It is returned to the mixer 13 shown in FIG.

In this embodiment, the wire cylinder 2
2A, 22B, and 22C are provided side by side along the transport belt 23, and the paper
Transfer 6 For this reason, the papermaking product 26
Paper with high efficiency, and it is possible to efficiently mass-produce cured products from papermaking sludge. In this embodiment, the rotation speed of the wire cylinder is set to 60 rotations / minute. This rotation speed is desirably 1 to 100 times / minute. This is because the papermaking body 26 can be formed from the raw material solution 14 with high efficiency, and the hardened body can be efficiently mass-produced from papermaking sludge. Here, if the rotating drum is lower than 1 rotation / minute, the papermaking efficiency is low. On the other hand, if the number of rotations exceeds 100 rotations / minute, it becomes difficult to form a sheet with a uniform thickness. In the present embodiment, three wire cylinders 22A, 22B, and 22C are provided in parallel, but one or more wire cylinders can be used.

The wire cylinders 22A, 22B,
The mesh of 22C is $ 60 (the number of meshes per inch is 60)
Is formed. Wire cylinders 22A, 22B,
The mesh size of 22C is preferably $ 40 to 150. From the raw material solution (slurry) 14, a papermaking body 26 can be produced with high efficiency,
This is because it is possible to efficiently mass-produce a high-density cured product from papermaking sludge. Here, if the mesh is coarser than # 40, only the inorganic non-crystalline material comes off from the raw material solution, and the density and strength of the cured product decrease. On the other hand, if the mesh is finer than # 150, the removal of water becomes worse, and it becomes impossible to make a papermaking product from the raw material solution with high efficiency. Since floc is formed in the papermaking sludge (raw material solution) by the coagulant, the papermaking can be performed efficiently.

The concentration of the raw material solution containing the papermaking sludge is desirably 3.5 to 25% by weight of the solid content. This is because the papermaking property from papermaking sludge can be improved and the cured product can be efficiently mass-produced. That is, if the concentration is less than 3.5%, it is not possible to efficiently make a paper from a raw material solution using a wire cylinder (filtration body), and if it exceeds 25%, the uniformity of the product is reduced.

The wire cylinders 22A, 22B, 22C
Conveyor belt 2 that transfers and conveys the paper made by
Numeral 3 is made of felt having a width of 1 m, suspended by rollers 34, provided with a suction box 24 on the back surface, and performing dehydration while suctioning by a vacuum pump 17. That is, the belt 23 adsorbs the moisture of the raw material 14 including the papermaking sludge into the pores of the felt, and the adsorbed moisture is absorbed by the suction box 2.
4 and is adsorbed to the vacuum pump 17 side and returned to the mixer 13 shown in FIG. In the first embodiment, the belt 23 is made of felt, but instead of this, a porous resin having continuous pores, a porous rubber, a material obtained by solidifying inorganic fibers with a binder, a sintered metal, A porous metal, a belt made of a porous metal block fixed with a flexible binder such as rubber, or the like can be used. In this embodiment, since the transport belt 23 is formed of a porous body having continuous pores and is dehydrated while being transported by the transport belt 23, the moisture in the papermaking body 26 can be efficiently reduced.

In the present embodiment, the transport speed of the transport belt 23 is set to 48 m / min, and the wire cylinders 22A, 22B, 22C, the cutting rotary drum 30, and the belt conveyor 38 are synchronized with the transport speed. Are driven by a motor (not shown). The transport speed of the transport belt 23 is desirably 5 to 80 m / min. This is because a paper having an appropriate thickness can be formed from the raw material solution with high efficiency, and the cured body can be efficiently mass-produced. Here, if the conveying speed is lower than 5 m / min, the papermaking body can be made thicker, but the papermaking efficiency is low. On the other hand, if the transport speed is 80
When the rate exceeds m / min, the sheet becomes thin, it is difficult to obtain a uniform thickness, and the sheet may be cut.

The cutting rotary drum 30, which winds and cuts the papermaking body conveyed by the conveyor belt 23 to a predetermined thickness,
It has a diameter of 64 cm (outer circumference 2 m), and has a storage groove 32 for retaining water on the surface and a piano wire 31 housed in a housing groove 33 located near the groove 32. The cutting rotary drum 30 winds the papermaking body 26 conveyed from the conveyor belt 23 on the surface thereof while forming a multilayered structure.

Then, the papermaking body 26 has a predetermined thickness (1.5
cm), and when this is detected by a sensor (not shown),
The piano wire 31 in the accommodation groove 33 is pushed out. Storage groove 3
At the position along 2, the paper body 26 has a high water content, and when the piano wire 31 is extruded, the paper body 26 is cut along the storage groove 32, and as shown in FIG. Fall. Then, with the rotation of the cutting rotary drum 30 and the transport of the belt conveyor 38, the papermaking body 26 having a predetermined thickness is transported onto the belt conveyor 38 (see FIG. 6B). Here, as shown in FIG. 6C, when the other cut end is conveyed to a position corresponding to the cutter 36, the cutter 36 is lowered to the belt conveyor 38 side, and
The cut end of the paper body 26 and the unstacked paper body conveyed on the conveyor belt 23 are separated.

In the present embodiment, the papermaking body on the conveyor belt 23 is multi-layered while being transferred to the rotary drum 30 for cutting.
When the multilayered paper body 26 reaches a predetermined thickness, it is cut into a predetermined size. The papermaking body 26 having a uniform thickness (1.5 cm) and a size (1 mx 2 m) is obtained by the rotary drum for cutting.
Can be continuously molded, so that the cured body can be efficiently mass-produced.

In this embodiment, the rotary drum 3 for cutting is used.
A cutter 36 is provided for cutting the papermaking body 26, one end of which is cut at 0, at regular intervals. Therefore, the predetermined length (2
m) of the papermaking body 26 can be formed. In the present embodiment, the thickness of the papermaking body 26 is 1.5 cm, but the thickness is desirably 2 cm or less. If the thickness is 2 cm or less, papermaking is easy, and handling is easy in transportation and the like.

A reversing device 40 for reversing a papermaking product will be described with reference to FIG. In the manufacturing apparatus of the present embodiment, as described later, since the papermaking bodies are alternately inverted and laminated, the papermaking bodies 26 are inverted every other sheet. The reversing device 40 includes a transport device 42 for sucking and transporting the papermaking body, a table 44, and a reversing plate 46.

As shown in FIG. 7A, the papermaking body 26 on the belt conveyor 38 is transported by the transport device 42 to the reversing plate 4.
6. The reversing plate 46 is driven, and the
Is inverted (see FIG. 7B). And FIG. 7 (C)
3 is transported by the transport device 42 to the press 50 shown in FIG. In addition,
As described above, in the present embodiment, the binder is added to the slurry 14 so that the papermaking body 26 has flexibility, and handling after cutting is easy.

Press machine 50 for pressurizing and dewatering the papermaking body
Will be described with reference to FIGS. 8 and 9. FIG.
As shown in (A), a press machine 50 includes a female mold 54 having a concave portion 54A and a male mold 52 fitted into the concave portion 54A.
The female mold 54 and the male mold 52 are formed with fine through holes 54a and 52a, respectively, for extracting water generated when the paper is pressed. In addition, the press 50 is provided with a curtain coater 56 for applying the raw material solution 14 to the papermaking body 26 (FIG. 8).
(B)).

The lamination and pressurization in the press machine 50 will be described. First, as shown in FIG. 8A, the cutting rotary drum 30 is inverted as a lowermost layer in the concave portion 54 </ b> A of the female mold 54 by the inverting device 40 described above with reference to FIG. Papermaking body 26 with the contact surface side of the
It is carried in by the transport device 42. Next, as shown in FIG. 8 (B), the raw material solution 14 is applied to the upper surface of the papermaking body 26, that is, the bonding surface with the upper layer papermaking body, by the curtain coater 56. The amount of this raw material solution is
50g / m ² ~500g / m ² are preferred in solids. In addition, although the curtain coater 56 is used here,
Various coating devices such as a roll coater can be used.

As shown in FIG. 8C, the papermaking body 26 on the belt conveyor 38 is carried into the concave portion 54A of the female mold 54 by the transfer device 42 without being inverted. Thereafter, as shown in FIG. 9A, the raw material solution 14 is applied, and then the inverted papermaking product 26 of the third layer is applied.
Is placed, and after applying the raw material solution 14, the fourth layer (top layer) of the non-inverted papermaking product 26 is placed, and the lamination is completed. Here, four layers are laminated, but any number of two or more sheets may be used, and even one sheet may be used when a thin cured product is manufactured.

Thereafter, the male mold 52 is pushed down, and a press is performed at 60 kg / cm ² (see FIG. 9B). At this time, the water seeping out of the papermaking body 26 is led out through the holes 54a and 52a. Thereafter, the male mold 52 is raised (see FIG. 9C), and the composite cured body 1 formed by pressurization is taken out of the female mold and transported to the dryer 60.

In this embodiment, the pressure is applied to the mold (recess 54A).
Since it is performed inside, the papermaking body 26 does not break even when pressurized at a high pressure, and it is possible to produce a high-strength cured body 1 from papermaking sludge at a high yield. In addition, since the male mold 52 and the female side 54 are provided with through holes 52a and 54a for removing water seeping out of the papermaking body 26, dehydration is performed at the time of pressurization, and the curing step by subsequent drying is completed in a short time. Let me do. Further, since a plurality of papermaking sludge papermaking bodies are laminated with the raw material solution 14 interposed therebetween, a multilayer cured body without peeling can be produced.

The pressure press is desirably performed at 10 to 250 kg / cm ² . If the pressing is performed at less than 10 kg / cm ² , the required strength cannot be obtained. Meanwhile, 2
This is because even if the pressure exceeds 50 kg / cm ² , the strength cannot be increased, and the press becomes larger and more expensive.

In this example, a plurality of papermaking sludge papermaking products obtained by papermaking a raw material solution using a wire cylinder (filtration body) are laminated. Since it is inefficient to obtain a thick paper by papermaking, a thin paper is efficiently formed from papermaking sludge and a cured product having the required strength and thickness is produced by stacking. This allows
Efficient mass production of cured products from papermaking sludge.

Further, in the production method of the present embodiment, the papermaking sludge is efficiently formed into a papermaking sludge by forming the papermaking body to a thickness of 20 mm or less, and the cured body having the required strength and thickness is manufactured by lamination. I do. For this reason, it is possible to efficiently mass-produce the cured body from the papermaking sludge.

In the present embodiment, the papermaking bodies 26 are laminated while alternately reversing the laminating surface. That is, since the papermaking body 26 is laminated while reversing the direction in which the warpage occurs, the papermaking body 2
6 does not warp and cause delamination. In addition, the uppermost and lowermost papermaking products are laminated so that the exposed surface is the surface that was in contact with the rotating drum and the uneven surface that was in contact with the conveyor belt 32 made of felt is inside. The surface of the cured product can be smoothed.

Further, in this embodiment, since a coagulant is added to the raw material solution containing papermaking sludge to cause coagulation, the cured product 1 having a uniform specific gravity (in the range of 1.2 to 1.3) is mass-produced from papermaking sludge. can do. Further, in this embodiment, since the lamination is performed in the female mold 54, it is not necessary to transfer the laminated papermaking body, which is suitable for mass production. In the present embodiment, the layers are stacked in the mold 54, but it is also possible to transfer them into the mold after the stacking.

[0093] Dehydration under pressure with the above press machine 50,
After lowering the water content, the drying reaction is continued to complete dehydration in the dryer 60 shown in FIG. 3 to advance the curing reaction. Dryer 60
Has an electric heater 62 and a fan 64, and performs drying at a temperature of 80 to 200 ° C. The dryer 60 includes an electric heater 62.
However, an infrared heater, steam, a solar dryer, or the like can be used instead.

The cured body 1 having undergone the drying step is further transported and cut into a predetermined size by a cutter (not shown).
The cutting is performed by a cutter or a saw provided on the conveyor. The cut composite cured body 1 is finally inspected for warpage or the like by an inspection machine (not shown). As an inspection machine,
X-ray sensors, infrared sensors and the like can be used. Further, the presence or absence of chipping or cracking may be inspected by an image processing device or the like.

Here, the relationship between the laminating direction (tension direction) of the papermaking body and the occurrence of delamination will be described with reference to FIG. 10 and FIG. The right side of FIG. 10 (A) shows a case where the papermaking body 26 is inverted and the felt contact surface side constituting the conveyor belt is adhered. Here, the paper 26
Has a stress remaining when it is wound by the cutting rotary drum 30 shown in FIG. 3 and warps in the winding direction even after cutting. The left side in the figure shows a cross section of the laminated papermaking body 26,
The unevenness in the figure indicates the felt contact surface. In this embodiment, the bonding direction shown in FIG.

FIG. 10 (B) shows a case where the papermaking bodies 26 are laminated without being inverted. FIG. 10C
Shows the case where the papermaking body 26 is inverted and bonded to the cutting drum abutment surface side.

FIG. 11 is a chart showing the relationship between the direction of lamination of the papermaking product and the occurrence of delamination, and the relationship between the pressure and the strength of the press machine. In the table, the coating amount indicates the coating amount of the raw material solution 14 between the papermaking body and the papermaking body, the pressure indicates the pressure in the press machine, the time indicates the pressing time, and the density indicates the value before drying. The maximum load is the density of the cured product, and the maximum load indicates the load that the cured product can withstand after drying, that is, the strength. The water content is a value after pressurization. The contraction rate thickness indicates the contraction rate in the thickness direction, the contraction rate length indicates the contraction rate in the length direction, and the contraction rate width indicates the contraction rate in the width direction. Here, five sheets of paper are laminated, the number of peeled layers is the number of peeled layers in the five sheets, and the number of peeled sides is the number of peels occurring in the four corners, and the peel length. Indicates the total extension of the portion where peeling has occurred.

First, it is understood that the maximum load can be increased by increasing the pressure. Also, as shown in FIG.
It is understood that delamination can be completely prevented by adopting "A" shown in (A) and applying a pressure of 60 kg / cm ² (No.
9). In the present embodiment, since the papermaking sludge is used as a raw material, the shrinkage is large, and during drying, the remaining stress acts when wound by the cutting rotary drum 30, and peeling easily occurs. By inverting and bonding the papermaking body, peeling can be prevented. In this embodiment, 1
Although the papermaking product is inverted for each layer, warping and delamination can be prevented by inverting and laminating every two layers or every third layer.

The manufacturing conditions of the examples and comparative examples are as follows.

[0100]

Table 1 Papermaking sludge flocculant Cement vinylon fiber speed m / s Example 1 95% 3% 0% 2% 5 Example 2 90% 2% 5% 3% 10 Example 3 98% 0.1% 0% 1. 9% 20 Example 4 80% 0.02% 15% 4.98% 30 Example 5 70% 3% 25% 2% 50 Example 6 90% 2% 0% 8% 60 Example 7 65% 5% 28% 2% 80 Comparative Example 1 95% 0% 0% 5% 3 Comparative Example 2 95% 0% 0% 5% 85

Further, Example 8 was adjusted as follows. Example 8 3020 parts by weight of unfired papermaking sludge (low quality paper for OA equipment of Nakamura Papers handled by Maruto Kiln Co., Ltd .: solid content 34% by weight, water content 66% by weight) were prepared. Next, acid washing is performed using a 2N hydrochloric acid aqueous solution to remove the Ca component almost completely.
This was designated as A. A pulp: 51.2 wt% MgO: 1.6 wt% SiO _2: 18.6 wt% SO _3: 3.5 wt% Al ₂ O _3: 22.3 wt% P ₂ O _5: 0.3 by weight % CaO: 0.0% by weight Cl: 0.1% by weight ZnO: 0.2% by weight Other trace

Further, papermaking sludge of ink-jet printer paper of Maki Paper Co., Ltd. handled by Maruto Kiln Co., Ltd .: B was 51% by weight of solid content and 49% by weight of water. B Pulp: 21.8 wt% SiO _2: 4.6 wt% Al ₂ O _3: 7.5 wt% P ₂ O _5: 0.1 wt% CaO: 65.0 wt% Na ₂ O: 0.2 % By weight SO ₃ : 0.2% by weight Other trace amount The amount of calcium carbonate was 55% by weight.

In addition, papermaking sludge of Maki Paper Co., Ltd.'s inkjet printer paper, which is handled by Maruto Kiln Co., Ltd .: 51% by weight of solid content, 49% by weight of water, and 10% by weight of calcium carbonate (cubic shape). And C Pulp: 15.0 wt% SiO _2: 2.6 wt% Al ₂ O _3: 5.5 wt% P ₂ O _5: 0.1 wt% CaO: 75.0 wt% Na ₂ O: 0.2 % By weight SO ₃ : 0.2% by weight Other trace amount The amount of calcium carbonate was 65% by weight.

Samples were prepared by appropriately mixing A, B, and C as described above, and a sheet was formed in the same manner as in Example 1 to produce a cured product, and the flexural strength, compressive strength, and nailability were measured. The results are shown in the graphs of FIGS. Here, FIG.
The relationship between O / SiO ₂ and compressive strength is shown, with the vertical axis representing compressive strength (Kg / cm ² ) and the horizontal axis representing the ratio of CaO / SiO ₂ . FIG. 16 shows the relationship between CaO / Al ₂ O ₃ and compressive strength, with the vertical axis representing compressive strength (Kg / cm ² ) and the horizontal axis representing CaO /
The ratio of Al ₂ O ₃ is shown. FIG. 17 shows the relationship between the CaO content and the bending strength / compression strength, with the ordinate representing the bending strength / compression strength (Kg / cm ² ) and the abscissa representing the CaO content (%). FIG. 18 shows the relationship between the CaO content and the nail pull-out strength, with the vertical axis representing the nail pull-out strength (Kg).
/ Cm ² ) is the CaO content (%) on the horizontal axis.
As shown in FIG. 15, the cured product has Ca, Al, and Si contents of CaO, Al ₂ O ₃ , and SiO ₂ , respectively.
When the O / SiO ₂ ratio is 0.2 to 7.9, high compressive strength is exhibited. On the other hand, as shown in FIG. 16, the cured body exhibits high compressive strength when the ratio of CaO / Al ₂ O ₃ is from 0.2 to 12.5.

The cured composites obtained in the above Examples and Comparative Examples were tested for bending strength, compressive strength, workability, nailing properties, fracture toughness, and abrasion resistance. Table 2 shows the results. The test method was such that the bending strength was JI
SA 6901 and JIS A 54
The measurement was performed according to the method specified in No. 16. The workability was determined by cutting using a circular saw for woodworking. Furthermore, regarding nailing properties, the diameter was 4 m.
A nail having a length of 50 mm and a length of 50 mm was hit and checked for cracks. Fracture toughness is measured by Vickers hardness tester (Akashi Seisakusho)
MVK-D) to calculate from the length of cracks generated by press-fitting an indenter. The Young's modulus was calculated from the curve of the bending fracture test and was from 1.4 to 2.7 kgf / cm ² , and this value was used. The Munsell color chart was used for lightness. Further, a 1 m square plate was divided into 100 parts, the thickness was measured, the average value was calculated, the difference between the maximum value and the minimum value was divided by the average value, and expressed as a percentage (%).

[0106]

[Table 2] Bending strength Compressive strength Workability Nailability Fracture toughness Lightness kg / cm ² kg / cm ² MPa · m ^1/2 Example 1 330 850 Workable None 3.37 Example 2 335 860 Workable None 3.3 7 Example 3 340 865 Processing possible None 3.3 7 Example 4 308 800 Processing possible None 3.1 5.5 Example 5 310 800 800 Processing possible None 3.1 5.5 Example 6 330 850 Processing Possible None 3.3 7 Example 7 310 800 Workable None 3.3 5.0 Comparative Example 1 330 850 Workable None 3.0 7 Comparative Example 2 330 850 Workable None 3.0 7 Thickness variation% Example 13% Example 2 3% Example 3 3% Example 4 4% Example 5 4% Example 6 3% Example 7 3% Comparative example 1 7% Comparative example 2 8%

Further, with respect to the composite cured product of Example 1, X
The crystal structure was confirmed by line diffraction. Charts of the X-ray diffraction are shown in FIGS. In addition, X-ray diffraction is Ri
MiniFlex made by gaku was used, and Cu was targeted. A gentle undulation (halo) is observed in the range of 2θ = 15 ° to 30 °, and a peak indicating a crystal structure is also observed, which indicates that the crystal structure is mixed in the amorphous structure. Also, crystals of calcium carbonate (Calsite) were identified from the peak.

The following is an example in which the composite cured product obtained in the above-described steps was analyzed using a fluorescent X-ray analyzer (Rigaku RIX2100). It was found that the composition was as follows in terms of oxide. The pulp was calcined at 1100 ° C. and measured from the weight loss. Serial Pulp: 51.4 wt%, SO _3: 0.5 wt% SiO _2: 24.2 wt%, P ₂ O _5: 0.2 wt% Al ₂ O _3: 14.0 wt%, Cl: 0 .2 wt% CaO: 8.0 wt%, ZnO: 0.1 wt% MgO: 1.4 wt%, others: traces TiO _2: 1.0 wt%,

Next, a method for manufacturing a cured product and a device for producing a cured product according to the second embodiment of the present invention will be described with reference to FIG. The second embodiment is almost the same as the first embodiment except for the method of cutting the papermaking body and the laminating direction.
Therefore, description is omitted except for the cutting direction and the laminating direction. In the first embodiment described above, the papermaking body 26 is 1 m × 2
m. On the other hand, in the second embodiment, the papermaking body 26 is cut into 1 m × 1 m by the cutter 36.
When the papermaking body 26 is placed on the reversing plate 46 of the reversing device 40 by the conveyor 42 from the belt conveyor 38, the papermaking body 26 is placed after being twisted 90 degrees in the horizontal direction. That is, when laminating the papermaking articles, the wire cylinders 22A, 22B, 22
The transfer direction from C to the conveyor belt 23 is shifted. A strength difference occurs in the papermaking body 26 along the transfer direction to the transport belt 23. Specifically, assuming that the strength when bending is applied along the transfer direction is 1, the strength in the direction perpendicular to the transfer direction is about 0.8. In the second embodiment, the papermaking body 2
When laminating 6, a cured body having uniform strength is manufactured by laminating so that the transfer direction to the conveyor belt 23 is shifted.

A composite building material will be described below as one application example of the composite cured body 1. That is, as shown in FIG. 19, in a composite building material in which the reinforcing layer 6 is formed on at least one surface of the core material 5 and on both surfaces in the illustrated example, the composite hardened body manufactured by the method of the present invention is applied to the core material 5. Apply 1. That is, by forming the core material 5 into the composite hardened body 1 manufactured by the method of the present invention, even when a tensile force is applied to the core material, the core material itself has excellent bending strength, and furthermore, In combination with the provision of the reinforcing layer on the surface, the structure is not easily broken.
Further, even when pressure is locally applied to the surface, no dent or dent occurs.

Further, in the use of this composite building material, a decorative layer such as a coating, a decorative panel and a decorative veneer is provided on the reinforcing layer 6, so that the impact resistance is improved, and Is less likely to occur, and the decorative surface is not distorted by the scratches and the design is not deteriorated.

Further, the reinforcing layer 6 has a structure in which the fiber base material 6b is embedded in the resin 6a. It is particularly desirable to use a thermosetting resin for the resin 6a. That is, unlike a thermoplastic resin, a thermosetting resin has excellent fire resistance and does not soften even at a high temperature, so that the function as a reinforcing layer is not lost. As the thermosetting resin, a phenol resin, a memelamine resin, an epoxy resin, a polyimide resin, a urea resin and the like are suitable. In order to impart sufficient rigidity, impact resistance, and even higher fire resistance to the reinforcing layer, the content of the thermosetting resin in the reinforcing layer is desirably in the range of 10% by weight to 65% by weight.

On the other hand, it is desirable to use inorganic fibers for the fiber base 6b. This is because the strength of the reinforcing layer 6 can be improved and the coefficient of thermal expansion can be reduced. Low-cost and heat-resistant use of at least one of inorganic fibers, glass fiber, rock wool, ceramic fiber, glass fiber chopped strand mat, glass fiber roving cloth, glass fiber continuous strand mat, and glass fiber paper It is preferable in terms of excellent properties and strength. This fiber base material is a material obtained by molding a discontinuous fiber into a mat shape, or a material obtained by cutting continuous long fibers into a mat shape by cutting into 3 to 7 cm (a so-called chopped strand mat), and dispersing in water to form a sheet. A material obtained by piling up, a continuous long fiber spirally laminated to form a mat, or a continuous long fiber woven is applicable.

Further, the thickness of the reinforcing layer is from 0.1 mm to
It is desirable to be 3.5 mm. This is because, if it is set in this range, sufficient rigidity and impact resistance can be obtained, and high workability can be maintained. The reinforcing layer may contain a flame retardant such as aluminum hydroxide and magnesium hydroxide, and a commonly used inorganic binder such as silica sol, alumina sol, and water glass. Here, the reinforcing layer is provided, but the surface may be coated with a resin or the like so that the cured body does not absorb moisture.

[Brief description of the drawings]

FIG. 1 is a schematic cross-sectional view of a composite cured product of the present invention.

FIG. 2 is a schematic cross-sectional view of the composite cured product of the present invention.

FIG. 3 is a conceptual diagram of an apparatus for manufacturing a cured body according to a first embodiment of the present invention.

FIGS. 4A and 4B are conceptual diagrams of a raw material adjustment mechanism.

FIG. 5 is a conceptual diagram of a papermaking mechanism.

FIGS. 6A, 6B, and 6C are explanatory views of the operation of the cutting rotary drum.

FIGS. 7A, 7B, and 7C are explanatory diagrams of the operation of the reversing device.

FIGS. 8A, 8B, and 8C are explanatory diagrams of the operation of the press machine.

FIGS. 9A, 9B, and 9C are explanatory diagrams of the operation of the press machine.

FIGS. 10 (A), (B), and (C) are explanatory views of a papermaking body in a laminating direction.

FIG. 11 is a table showing the relationship between the direction in which the papermaking body is adhered and the occurrence of delamination, and the relationship between the pressure and the strength in a press machine.

FIG. 12 is an X-ray diffraction chart of a composite cured product according to an example.

FIG. 13 is an X-ray diffraction chart of the composite cured product according to the example.

FIG. 14 is a conceptual diagram of an apparatus for manufacturing a cured body according to a second embodiment of the present invention.

FIG. 15 is a graph showing the relationship between CaO / SiO ₂ and compressive strength.

FIG. 16 is a graph showing the relationship between CaO / Al ₂ O ₃ and compressive strength.

FIG. 17 is a graph showing the relationship between CaO content and bending strength / compression strength.

FIG. 18 is a graph showing the relationship between the CaO content and nail pull-out strength.

FIG. 19 is a schematic sectional view of a composite building material using the composite cured body of the present invention.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 Composite hardened body 2 Amorphous body 3 Fibrous material 4 Inorganic powder 5 Core material 6 Reinforcement layer 10 Raw material adjustment mechanism 14 Raw material solution (slurry) 15 Dehydration container 16 Filter 17 Vacuum pump 18 Chest tank 20 Papermaking mechanism 21A, 21B, 21C Butt 22A, 22B, 22C Wire Cylinder 23 Conveyor Belt 24 Suction Box 26 Papermaking Machine 30 Rotating Drum 31 Piano Wire 32 Storage Groove 33 Housing Groove 36 Cutter 38 Belt Conveyor 40 Inverting Device 42 Transporting Device 44 Table 46 Inverting Plate 50 Press Machine 52 Male type 52a Through hole 54 Female type 54A Recess 54a Through hole 56 Curtain coater 60 Dryer

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁷ Identification symbol FI Theme coat ゛ (Reference) C04B 18/28 C04B 28/02 28/02 30/02 30/02 111: 30 // C04B 111: 30 B28B 11/00 Z (72) Inventor Tetsuji Ogawa 2-1-1 Kanda-cho, Ogaki-shi, Gifu Pref. (72) Inventor Toshihiro Nomura 2-1-1 Kanda-cho, Ogaki-shi, Gifu F-term in Ibiden Co., Ltd. (Reference) 4G012 PA33 PC11 PE04 4G052 EA01 EA02 EB02 EB22 GA01 GA02 GA17 GB81 GC06 4G055 AA02 AB05 AC01 AC09 BA12 BA22 BA43 BB05 BB12 BB13

Claims (14)

[Claims] 1. A raw material solution containing papermaking sludge is made into a paper using a filter body, and a papermaking sludge paperwork is attached to the surface of the filter body, and the papermaking body is transferred to a conveyor belt at a speed of 5 to 80 m / min. A method for producing a cured product, comprising transferring the product, cutting it into a predetermined size, and curing the papermaking product to obtain a cured product of papermaking sludge. 2. The method for producing a cured product according to claim 1, wherein the concentration of the raw material solution containing the papermaking sludge is 3.5 to 25% by weight on a solid basis. 3. The method for producing a cured product according to claim 1, wherein said paper is dehydrated while being transported by said transport belt. 4. The paper sheet on the conveyor belt is multi-layered while being transferred to a cutting rotary drum, and cut when the multi-layered paper sheet reaches a predetermined thickness. 3. The method for producing a cured product according to any one of items 1 to 3. 5. The method for producing a cured product according to claim 1, wherein the cut paper is further multilayered and then press-pressed. 6. The method according to claim 5, wherein the pressing is performed at 10 to 250 kg / cm ² . 7. A raw material solution containing papermaking sludge is formed,
A filter body for adhering a papermaking sludge paperwork to the surface; a conveyor belt for transferring and conveying the paperboard body adhering to the surface of the filter body; and a paper conveyor conveyed by the conveyor belt at a speed of 5 to 80 m / min. And a hardening device for hardening the cut papermaking body to obtain a hardened body of papermaking sludge. 8. The apparatus according to claim 7, wherein the drainage body is a rotating drum made of a net-like body. 9. The rotating speed of the rotating drum is 1 to 100.
9. The apparatus for producing a cured product according to claim 8, wherein the rate is times / minute. 10. The cured product according to any one of claims 7 to 9, wherein a plurality of the drainage bodies are provided along a conveyor belt, and the papermaking body is transferred while being multilayered on the conveyor belt. manufacturing device. 11. The apparatus according to claim 7, wherein the drainage body has a mesh structure of $ 40 to $ 150. 12. The apparatus according to claim 7, wherein the transport belt is formed of a porous body having continuous pores. 13. The cutting device comprises a cutting rotary drum for forming a multilayer while transferring a papermaking body, wherein the cutting rotary drum has a groove for retaining water on its surface,
An extruding mechanism located in the vicinity of the groove and for extruding the paper body from the inside; when the multilayered paper body on the surface of the cutting rotary drum reaches a predetermined thickness, the extrusion mechanism is operated. The apparatus for producing a cured body according to claim 7, wherein the papermaking body is cut at a position corresponding to the groove. 14. The apparatus for producing a cured product according to claim 13, wherein the cutting device further comprises a blade for cutting the papermaking material, one end of which is cut by the cutting rotary drum, at regular intervals.