JP2001311097A5 - - Google Patents
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- Publication number
- JP2001311097A5 JP2001311097A5 JP2000131561A JP2000131561A JP2001311097A5 JP 2001311097 A5 JP2001311097 A5 JP 2001311097A5 JP 2000131561 A JP2000131561 A JP 2000131561A JP 2000131561 A JP2000131561 A JP 2000131561A JP 2001311097 A5 JP2001311097 A5 JP 2001311097A5
- Authority
- JP
- Japan
- Prior art keywords
- copolymer
- ethylene
- styrene
- molded
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 11
- 239000000178 monomer Substances 0.000 description 6
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920000428 triblock copolymer Polymers 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Description
被塗装物及び被接着物としては、例えば、高圧法ポリエチレン、中低圧法ポリエチレン、ポリプロピレン、ポリ−4−メチル−1−ペンテン、ポリ−1−ブテン、ポリスチレン、エチレン・プロピレン共重合体、エチレン・ブテン共重合体、エチレン・オクテン共重合体、プロピレン・ブテン共重合体、エチレン・プロピレン・ターポリマー、エチレン・環状モノマー共重合体等のポリオレフィンからなる成型品に好適に使用することができる。また、本発明の前処理剤組成物は、ポリオレフィン以外にもポリエステル、ポリアミド、ポリカーボネート等の各種成型品、さらには鋼板等への適用も可能である。また、本発明の前処理剤組成物が適用される成型品は、上記の各種重合体または樹脂が、射出成形、圧縮成型、中空成型、押出成型、回転成型等の公知の成型法のいずれの方法によって成型されたものであっても良い。また、成型物が、発砲体、架橋物であっても適用することができる。
Examples of the object to be coated and the object to be bonded include high-pressure polyethylene, medium-low pressure polyethylene, polypropylene, poly-4-methyl- 1-pentene , poly-1-butene, polystyrene, ethylene-propylene copolymer, ethylene It can be suitably used for molded articles composed of polyolefin such as butene copolymer, ethylene / octene copolymer, propylene / butene copolymer, ethylene / propylene / terpolymer, ethylene / cyclic monomer copolymer. In addition, the pretreatment composition of the present invention can be applied to various molded products such as polyester, polyamide, and polycarbonate in addition to polyolefins, and further to steel plates and the like. In addition, the molded article to which the pretreatment agent composition of the present invention is applied, the various polymers or resins described above are injection-molded, compression-molded, hollow-molded, extruded, or any of known molding methods such as rotational molding. It may be molded by a method. Further, the present invention can be applied even when the molded product is a foam or a crosslinked product.
(樹脂の種類)
(1)オレフィン(共)重合体
オレフィン(共)重合体を構成するオレフィンとしては、エチレン、炭素数3以上のα−オレフィンを挙げることができる。好ましくは、エチレン・プロピレン共重合体、プロピレン・1−ブテン共重合体、プロピレン・ブテン・エチレン共重合体、エチレン・オクテン共重合体等を例示できる。
(2)極性モノマーがグラフトされたオレフィン(共)重合体
オレフィン(共)重合体としては、(1)記載のものを挙げることができる。極性モノマーとしては、水酸基含有エチレン性不飽和化合物、アミノ基含有エチレン性不飽和化合物、エポキシ基含有エチレン性不飽和化合物、不飽和カルボン酸及びその誘導体、ビニルエステル化合物、塩化ビニル等を挙げることができるが、特には、水酸基含有エチレン性不飽和化合物及び不飽和カルボン酸及びその誘導体が好ましい。
(Type of resin)
(1) Olefin (co) polymer Examples of the olefin constituting the olefin (co) polymer include ethylene and α-olefins having 3 or more carbon atoms. Preferably, an ethylene / propylene copolymer, a propylene / 1-butene copolymer, a propylene / butene / ethylene copolymer, an ethylene / octene copolymer and the like can be exemplified.
(2) Olefin (co) polymer grafted with polar monomer Examples of the olefin (co) polymer include those described in (1). As the polar monomer, include water acid group-containing ethylenically unsaturated compounds, amino group-containing ethylenic unsaturated compounds, epoxy group-containing ethylenically unsaturated compounds, unsaturated carboxylic acids and their derivatives, vinyl ester compounds, vinyl chloride In particular, a hydroxyl group-containing ethylenically unsaturated compound and an unsaturated carboxylic acid and a derivative thereof are preferable.
このオレフィン(共)重合体はさらに前述の極性モノマーがグラフトされていても良い。ハロゲンとしては、フッ素、塩素、臭素等を例示できる。
(4)スチレン・共役ジエン・スチレントリブロック共重合体またはその水添物及びスチレン・共役ジエン共重合体またはその水添物
(5)前記極性モノマーがグラフトされたスチレン・共役ジエン・スチレントリブロック共重合体またはその水添物及びスチレン・共役ジエン共重合体またはその水添物
(6)前記ハロゲン化されたスチレン・共役ジエン・スチレントリブロック共重合体またはその水添物及びスチレン・共役ジエン共重合体またはその水添物。これはさらに極性モノマーがグラフトされていても良い。
The olefin (co) polymer may be further grafted with the aforementioned polar monomer. Examples of the halogen include fluorine, chlorine, and bromine.
(4) a styrene-conjugated diene-styrene triblock copolymer or its hydrogenated Mono及 beauty styrene-conjugated diene copolymer or its hydrogenated product (5) wherein said polar monomer is styrene-conjugated diene-styrene tri-grafted Block copolymer or hydrogenated product thereof and styrene / conjugated diene copolymer or hydrogenated product thereof (6) Halogenated styrene / conjugated diene / styrene triblock copolymer or hydrogenated product thereof and styrene / conjugated product Diene copolymer or hydrogenated product thereof. It may be further grafted with a polar monomer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000131561A JP2001311097A (en) | 2000-04-26 | 2000-04-26 | Pretreating agent composition, method for coating and method for adhesion using the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000131561A JP2001311097A (en) | 2000-04-26 | 2000-04-26 | Pretreating agent composition, method for coating and method for adhesion using the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2001311097A JP2001311097A (en) | 2001-11-09 |
JP2001311097A5 true JP2001311097A5 (en) | 2006-05-25 |
Family
ID=18640433
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2000131561A Withdrawn JP2001311097A (en) | 2000-04-26 | 2000-04-26 | Pretreating agent composition, method for coating and method for adhesion using the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2001311097A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2038357A2 (en) * | 2006-07-07 | 2009-03-25 | Arkema France | Adhesion activator intended for application to a thermoplastic polymer elastomer substrate or pa substrate, and methods of surface treatment and of assembly by corresponding adhesive bonding |
US11034922B2 (en) | 2016-06-07 | 2021-06-15 | The Yokohama Rubber Co., Ltd. | Cleaning agent composition |
-
2000
- 2000-04-26 JP JP2000131561A patent/JP2001311097A/en not_active Withdrawn
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