JP2001303224A - Hot dip metal coating method and hot dip metal coating apparatus - Google Patents

Hot dip metal coating method and hot dip metal coating apparatus

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Publication number
JP2001303224A
JP2001303224A JP2000127704A JP2000127704A JP2001303224A JP 2001303224 A JP2001303224 A JP 2001303224A JP 2000127704 A JP2000127704 A JP 2000127704A JP 2000127704 A JP2000127704 A JP 2000127704A JP 2001303224 A JP2001303224 A JP 2001303224A
Authority
JP
Japan
Prior art keywords
snout
vibration
steel strip
plating
wave
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000127704A
Other languages
Japanese (ja)
Inventor
Takayuki Hori
隆行 堀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP2000127704A priority Critical patent/JP2001303224A/en
Publication of JP2001303224A publication Critical patent/JP2001303224A/en
Pending legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To provide a hot dip metal coating method with which dross defect or ripple defect of a steel sheet obtained in a continuous hot dip metal coating for steel sheet can effectively be prevented, and a hot dip metal coating apparatus. SOLUTION: In the hot dip metal coating method, the steel sheet is continuously dipped into coating bath of molten metal through a snout for shutting off the atmosphere, and after turning around a sink roll disposed in the coating bath to change this running direction, the steel sheet is drawn upward from the coating bath surface to continuously apply the hot dip coating. Further, in the hot dip metal coating method, the waving of the bath surface in the snout is measured, and based on the obtained measured result, the vibration for eliminating the waving, is given to a vibrating plate dipped into the snout and the coating bath in the snout. This hot dip metal coating apparatus is the one suitably used for this hot dip metal coating method.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、鋼帯の連続溶融金
属めっきにおいて、得られる鋼帯(鋼板を含む)のドロ
ス欠陥あるいはさざ波欠陥を防止することが可能な溶融
金属めっき方法および溶融金属めっき装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hot metal plating method and a hot metal plating capable of preventing dross defects or ripples in a steel strip (including a steel sheet) obtained in continuous hot metal plating of a steel strip. Related to the device.

【0002】[0002]

【従来の技術】図5に、従来の溶融金属めっき装置を縦
断面図によって示す。なお、図5において、1は溶融金
属であるめっき浴、2はめっき用ポット、3はシンクロ
ール、4は鋼帯(:ストリップ)、5はスナウト、f1
鋼帯の搬送方向(通板方向)、f2はシンクロールの回転
方向を示す。
2. Description of the Related Art FIG. 5 is a longitudinal sectional view showing a conventional hot-dip metal plating apparatus. In FIG. 5, 1 is the plating bath is molten metal, 2 plating pot, the sink roll 3, 4 strip (: Strip), 5 snout, f 1 is the transport direction of the steel strip (strip passing direction), f 2 represents the rotation direction of the sink roll.

【0003】すなわち、鋼帯の連続溶融金属めっきにお
いては、鋼帯を大気遮断のためのスナウト5を介して溶
融金属であるめっき浴1中に連続的に侵入させ、めっき
浴1中に配設したシンクロール3を周回後、方向転換
し、めっき浴1浴面より上方へ引き上げて連続的にめっ
きを施す。以下、溶融金属めっきにおける従来技術を、
溶融金属めっきの代表例である溶融亜鉛めっきを例とし
て説明する。
That is, in the continuous hot-dip metal plating of a steel strip, the steel strip is continuously penetrated into a plating bath 1 which is a molten metal through a snout 5 for shielding the atmosphere, and is disposed in the plating bath 1. After turning around the sink roll 3 thus turned, the direction is changed, and it is pulled up from the bath surface of the plating bath 1 to continuously perform plating. Hereinafter, the conventional technology in hot-dip metal plating,
A description will be given by taking hot-dip galvanizing, which is a typical example of hot-dip metal plating, as an example.

【0004】従来、溶融亜鉛めっきにおいては、得られ
る溶融亜鉛めっき鋼帯表面のドロス欠陥やさざ波欠陥な
どと呼ばれる品質欠陥が大きな問題となっている。上記
した欠陥は、スナウト5内の溶融亜鉛浴面に生成および
成長したFe2Al5を主成分とするドロスや溶融亜鉛の酸化
物が、浴面に発生する波によって浮遊し鋼帯表面に付着
して発生するものである。
Heretofore, in hot-dip galvanizing, quality defects called dross defects and ripple defects on the surface of the hot-dip galvanized steel strip have been a major problem. The above-mentioned defects are caused by the dross and molten zinc oxide mainly composed of Fe 2 Al 5 formed and grown on the molten zinc bath surface in the snout 5 floating by waves generated on the bath surface and adhering to the steel strip surface. It occurs.

【0005】従来、上記した欠陥の発生を防止するため
に、めっき浴の溶融亜鉛の品質管理が行われている。す
なわち、溶融亜鉛の酸化物の生成を防止するために、ス
ナウト内雰囲気ガスの露点管理や酸素濃度の規制などが
行われている。また、ドロスの抑制方法としては、例え
ば、特開平8−176770号公報に示されるように、溶融亜
鉛めっき浴の流れを利用して、スナウト内部のドロスを
鋼帯の通板位置から離れたスナウト内部に滞留させ、除
去するようにしたスナウトや、特開平10−158796号公報
に示されるように、鋼帯を振動させないようにして高速
で搬送し、浴面の波立ちによる異物の付着を抑制したス
ナウトが開示されている。
Conventionally, in order to prevent the above-mentioned defects from occurring, quality control of the molten zinc in the plating bath has been performed. That is, in order to prevent the formation of oxides of molten zinc, dew point management of atmospheric gas in snout, regulation of oxygen concentration, and the like are performed. Further, as a method of suppressing dross, for example, as disclosed in Japanese Patent Application Laid-Open No. 8-176770, a dout inside a snout is separated from a thread passing position of a steel strip by using a flow of a hot dip galvanizing bath. The snout was retained inside and removed, and as shown in Japanese Patent Application Laid-Open No. 10-158796, the steel strip was conveyed at a high speed without being vibrated, and the adhesion of foreign substances due to the waving of the bath surface was suppressed. A snout is disclosed.

【0006】上記した発生ドロスを回収する方法や鋼帯
の振動を抑制する方法もドロスの付着を防止するための
有効な手段であるが、スナウト内の浮遊ドロスを大幅に
低減することは困難であると共に、高速で搬送される鋼
帯の振動を大幅に抑制することも困難である。このた
め、前記した溶融亜鉛めっき鋼帯表面のドロス欠陥やさ
ざ波欠陥の発生を効果的に防止することが可能な溶融金
属めっき方法および溶融金属めっき装置が求められてい
た。
Although the above-mentioned method of collecting generated dross and a method of suppressing vibration of the steel strip are effective means for preventing the dross from adhering, it is difficult to greatly reduce floating dross in the snout. In addition, it is difficult to significantly suppress the vibration of the steel strip conveyed at high speed. Therefore, there has been a demand for a hot-dip metal plating method and a hot-dip metal plating apparatus capable of effectively preventing the occurrence of dross defects and ripple defects on the surface of the hot-dip galvanized steel strip.

【0007】[0007]

【発明が解決しようとする課題】本発明は、前記した従
来技術の問題点を解決し、鋼帯の連続溶融金属めっきに
おいて、得られる鋼帯のドロス欠陥あるいはさざ波欠陥
を効果的に防止することが可能な溶融金属めっき方法お
よび溶融金属めっき装置を提供することを目的とする。
An object of the present invention is to solve the above-mentioned problems of the prior art and to effectively prevent dross defects or ripple defects in the obtained steel strip in continuous hot-dip metal plating of the steel strip. It is an object of the present invention to provide a hot-dip metal plating method and a hot-dip metal plating apparatus capable of performing the above-described processes.

【0008】[0008]

【課題を解決するための手段】第1の発明は、鋼帯を、
大気遮断用のスナウトを介して溶融金属であるめっき浴
中に連続的に侵入せしめ、めっき浴中に配設したシンク
ロールを周回後、方向転換し、めっき浴浴面より上方へ
引き上げて連続的にめっきを施す溶融金属めっき方法で
あって、前記スナウト内の浴面の波動を測定し、得られ
た測定結果に基づいて前記波動を消去する振動をスナウ
トおよび/またはスナウト内めっき浴中に浸漬した振動
板に付与することを特徴とする溶融金属めっき方法であ
る。
According to a first aspect of the present invention, a steel strip is provided.
Continuously penetrate into the plating bath, which is a molten metal, through a snout for shielding the atmosphere, turn around the sink roll provided in the plating bath, change direction, and pull it up above the bath surface to continuously A method of plating a molten metal, wherein the vibration of the bath surface in the snout is measured, and the vibration for eliminating the wave is immersed in the plating bath in the snout and / or the snout based on the measurement result obtained. A hot-dip metal plating method characterized by applying the method to a vibrating plate.

【0009】なお、前記した前記波動を消去する振動
は、スナウトおよび/またはスナウト内めっき浴中に浸
漬した振動板を水平に往復運動することによって与えら
れたものであることが好ましい。第2の発明は、鋼帯を
大気と遮断して溶融金属であるめっき浴中に連続的に侵
入させるためのスナウト5と、前記めっき浴を収納する
めっき用ポット2と、めっき浴中に侵入させた鋼帯を方
向転換させめっき浴浴面より上方へ引き上げるためにめ
っき浴中に配設したシンクロール3を有する溶融金属め
っき装置であって、前記スナウト5内の浴面の波動を測
定する波動測定装置10と、該波動測定装置10で得られた
波動と逆位相の振動をスナウト5および/またはスナウ
ト5内めっき浴中に浸漬した振動板11に付与する加振装
置12を配設したことを特徴とする溶融金属めっき装置で
ある。
It is preferable that the vibration for canceling the wave is given by horizontally reciprocating a diaphragm immersed in a snout and / or a plating bath in the snout. In the second invention, a snout 5 for blocking a steel strip from the atmosphere and continuously intruding into a plating bath which is a molten metal, a plating pot 2 for accommodating the plating bath, and an intrusion into the plating bath are provided. A molten metal plating apparatus having a sink roll 3 disposed in a plating bath to change the direction of the steel strip and raise the steel strip above the plating bath surface, and measures the wave motion of the bath surface in the snout 5. A wave measuring device 10 and a vibrating device 12 for applying vibration having an opposite phase to the wave obtained by the wave measuring device 10 to the snout 5 and / or the vibration plate 11 immersed in the plating bath in the snout 5 are provided. A hot-dip metal plating apparatus characterized in that:

【0010】なお、前記した逆位相の振動は、スナウト
および/またはスナウト内めっき浴中に浸漬した振動板
を水平に往復運動させるものであることが好ましい。
It is preferable that the above-mentioned vibration of the opposite phase is one that horizontally reciprocates a diaphragm immersed in a snout and / or a plating bath in the snout.

【0011】[0011]

【発明の実施の形態】以下、本発明をさらに詳細に説明
する。本発明者は、前記した課題を解決するために鋭意
検討した結果、下記知見を得、本発明に至った。 (1) 鋼帯表面へのドロスおよび溶融亜鉛の酸化物の付着
機構:スナウト内で発生するドロスおよび溶融亜鉛の酸
化物(以下、溶融亜鉛酸化物と記す)が鋼帯表面に付着
する過程においては、前記したドロスや溶融亜鉛酸化物
が、浴面に発生する波によって浮遊し鋼帯表面に付着す
るばかりでなく、スナウトの内壁面に付着、成長したド
ロスや溶融亜鉛酸化物の凝固物が、浴面の波動(揺れ)
によって剥離し、浴面を浮遊しながら鋼帯表面へ付着す
ることを見出した。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in more detail. The present inventor has conducted intensive studies in order to solve the above-described problems, and as a result, has obtained the following findings, leading to the present invention. (1) Adhesion mechanism of dross and molten zinc oxide on steel strip surface: In the process of dross and molten zinc oxide generated in snout (hereinafter referred to as molten zinc oxide) adhere to the steel strip surface The above-mentioned dross or molten zinc oxide floats due to waves generated on the bath surface and not only adheres to the steel strip surface, but also adheres to the inner wall surface of the snout, and the coagulated dross and molten zinc oxide grow. , Wave of the bath surface (swaying)
Was found to adhere to the steel strip surface while floating on the bath surface.

【0012】(2) スナウト内めっき浴浴面の波動(波立
ち)の抑制:上記した付着機構の解明に基づき、浴面の
波動(波立ち)を抑制することによってドロス欠陥、さ
ざ波欠陥の発生を防止することが可能であることを見出
した。図1に、本発明の溶融金属めっき装置の一例を側
断面図(a) およびA部部分側断面図(b) によって示す。
(2) Suppression of ripples on the bath surface of the plating bath in the snout: Based on the elucidation of the above-mentioned adhesion mechanism, generation of dross defects and ripple defects is prevented by suppressing the ripples on the bath surface. It was found that it is possible. FIG. 1 shows an example of a hot-dip metal plating apparatus of the present invention in a side sectional view (a) and a partial sectional view in section A (b).

【0013】なお、図1において、1は溶融金属である
めっき浴、2はめっき用ポット、3はシンクロール、4
は鋼帯(:ストリップ)、5はスナウト、10はスナウト
5内の浴面の波動を測定する波動測定装置、12はスナウ
ト5に振動を付与する加振装置、13はアンプ、14は演算
器、15は加振制御装置、16はスナウト支持板、17はスナ
ウト5内浴面、18はスナウト5内浴面の波の谷、19はス
ナウト5内浴面の波の山、f1は鋼帯の搬送方向(通板方
向)、f2はシンクロールの回転方向、f3はスナウト支持
板16およびスナウト5の振動方向、f4はスナウト5の振
動方向、hはスナウト5内めっき浴浴面17の波動(波立
ち)の高さを示す。
In FIG. 1, reference numeral 1 denotes a plating bath made of a molten metal, 2 denotes a plating pot, 3 denotes a sink roll,
Is a steel strip (: strip), 5 is a snout, 10 is a wave measuring device for measuring the wave of the bath surface in the snout 5, 12 is a vibration device for applying vibration to the snout 5, 13 is an amplifier, and 14 is a calculator. , 15 is a vibration control device, 16 is a snout support plate, 17 is a wave valley of the snout 5 inner bath surface, 18 is a wave valley of the snout 5 inner bath surface, 19 is a wave peak of the snout 5 inner bath surface, f 1 is steel the conveying direction of the strip (sheet passing direction), f 2 is the rotational direction of the sink roll, f 3 is the vibration direction, h is the snout 5 within the plating bath bath vibration direction, f 4 is the snout 5 of snout supporting plate 16 and snout 5 The height (wave) of the surface 17 is shown.

【0014】図1に示す溶融金属めっき装置において
は、スナウト5内に、スナウト5内のめっき浴浴面の波
動(波立ち)を測定する波動測定装置10を配設し、該波
動測定装置10からの信号をアンプ13で増幅して演算器14
に取り込み、浴面の波動(波立ち)の高さ(振幅)hと
周期(:時間)Wを演算する。なお、上記しためっき浴
浴面の波動(波立ち)の測定は、特定点の浴面の高さの
変動を測定することによって行う。
In the hot-dip metal plating apparatus shown in FIG. 1, a wave measuring device 10 for measuring a wave (ripening) of a plating bath surface in the snout 5 is provided in the snout 5, and the wave measuring device 10 Is amplified by the amplifier 13 and the arithmetic unit 14
To calculate the height (amplitude) h and the cycle (time) W of the wave (ripening) of the bath surface. In addition, the above-mentioned measurement of the wave (ripening) of the plating bath surface is performed by measuring the fluctuation of the height of the bath surface at a specific point.

【0015】図2(a) に、波動測定装置10からの信号の
演算結果を示す。次に、得られた演算結果に基づき、め
っき浴浴面の波動(波立ち)を打ち消すような、加振装
置12から付与する振動の周波数、振幅を演算し、得られ
た演算結果を制御出力として加振装置12へ送信し、加振
装置12によって、波動測定装置10で得られた波動と逆位
相の振動(:水平方向の往復運動)をスナウト5に発生
させる。
FIG. 2A shows a calculation result of a signal from the wave measuring device 10. Next, based on the obtained calculation result, the frequency and amplitude of the vibration applied from the vibrating device 12 that cancels the wave (undulation) of the plating bath surface are calculated, and the obtained calculation result is used as a control output. The vibration is transmitted to the vibration device 12 and the vibration device 12 causes the snout 5 to generate a vibration having a phase opposite to that of the wave obtained by the wave measurement device 10 (reciprocal motion in the horizontal direction).

【0016】図2(b) に、加振制御装置15からの制御出
力によって得られる波形の例を示す。なお、図2(b) に
おいて、W0 は周期を示し、h0 は振幅を示す。また、
図2(c) に制御出力を介して加振装置12によって制御さ
れた浴面の波立ちの状態(波動測定装置10からの信号の
演算結果)を示す。
FIG. 2B shows an example of a waveform obtained by a control output from the vibration control device 15. In FIG. 2B, W 0 indicates a period, and h 0 indicates an amplitude. Also,
FIG. 2 (c) shows a state of undulation of the bath surface (result of calculation of a signal from the wave measuring device 10) controlled by the vibration device 12 via the control output.

【0017】なお、本発明における加振装置12として
は、スナウト5内めっき浴浴面の波立ちを打ち消すこと
が可能な周波数、振幅の振動をスナウトおよび/または
後記する振動板に付与することが可能な加振装置12であ
ればその方式は特に制限されるものではない。図3に、
加振装置12の一例を示す。
The vibration device 12 of the present invention can apply a vibration having a frequency and an amplitude capable of canceling the waving of the plating bath in the snout 5 to the snout and / or a diaphragm described later. The type of the vibrating device 12 is not particularly limited. In FIG.
An example of the vibration device 12 is shown.

【0018】なお、図3において、5はスナウト、11は
振動板、21はモータ、22はインバータ、23は偏心カム、
24はスライドプレート、25は偏心カムの回転駆動軸、f6
は回転駆動軸25の回転方向、f7はスライドプレートの水
平方向の往復動方向(振動方向)、f8はスナウト5また
は振動板11の水平方向の振動方向を示す。図3に示す加
振装置12は、モータ21の回転数を制御するインバータ22
と、インバータ22によって回転数が定められたモータ21
と、モータ21の回転を水平方向の往復運動に変える偏心
カム23を備えた機構と、水平方向に往復運動するスライ
ドプレート24から構成され、偏心カム23の偏心量を変え
ることによってスナウト5あるいは後記する図4に示す
振動板11(11A、11B)の水平方向の振動の振幅を変えるこ
とができる。
In FIG. 3, 5 is a snout, 11 is a diaphragm, 21 is a motor, 22 is an inverter, 23 is an eccentric cam,
24 is a slide plate, 25 is an eccentric cam rotation drive shaft, f 6
Represents the rotation direction, the vibration direction of the horizontal f 7 is a horizontal reciprocating direction of the slide plate (vibration direction), f 8 is snout 5 or diaphragm 11 of the rotary drive shaft 25. The vibration device 12 shown in FIG.
And the motor 21 whose rotation speed is determined by the inverter 22
And a mechanism having an eccentric cam 23 for changing the rotation of the motor 21 into a reciprocating motion in the horizontal direction, and a slide plate 24 reciprocating in the horizontal direction, and by changing the amount of eccentricity of the eccentric cam 23, the snout 5 or The amplitude of the vibration of the diaphragm 11 (11A, 11B) shown in FIG. 4 in the horizontal direction can be changed.

【0019】なお、図3においては、スナウト5の板面
あるいは後記する図4に示す振動板11を垂直方向に配置
した例を示したが、スナウト5の板面が斜め方向に配置
された前記した図1に示すスナウト5あるいは振動板11
が斜め方向に配置された振動板についても図3に示す加
振装置12と同様の加振装置を用いることができる。以上
述べたように、図1に示す溶融金属めっき装置によれ
ば、制御出力を波立ちの逆位相で与えることによって、
スナウト5の振動が浴面に対して制御力となり、スナウ
ト5内めっき浴浴面の波立ちを大幅に抑制することがで
きる。
FIG. 3 shows an example in which the plate surface of the snout 5 or the diaphragm 11 shown in FIG. 4, which will be described later, is arranged in a vertical direction, but the plate surface of the snout 5 is arranged in an oblique direction. The snout 5 or the diaphragm 11 shown in FIG.
A vibration device similar to the vibration device 12 shown in FIG. As described above, according to the hot-dip metal plating apparatus shown in FIG. 1, by giving the control output in the opposite phase of the undulation,
The vibration of the snout 5 acts as a control force on the bath surface, so that the ripple of the plating bath surface in the snout 5 can be largely suppressed.

【0020】この結果、ドロスや溶融亜鉛酸化物が、浴
面に発生する波によって浮遊し鋼帯表面に付着すること
が防止できると共に、スナウトの内壁面に付着、成長し
たドロスや溶融亜鉛酸化物の凝固物が、浴面の波動(揺
れ)によって剥離し、浴面を浮遊しながら鋼帯表面に付
着することが防止でき、鋼帯表面のドロス欠陥やさざ波
欠陥を大幅に減少することが可能となった。
As a result, dross and molten zinc oxide can be prevented from floating and adhering to the steel strip surface due to waves generated on the bath surface, and dross and molten zinc oxide adhered to and grown on the inner wall surface of the snout. The solidified material can be prevented from exfoliating due to the wave (sway) of the bath surface, preventing it from adhering to the steel strip surface while floating on the bath surface, and drastically reducing dross defects and ripple defects on the steel band surface It became.

【0021】次に、図4に、本発明に係わる振動付与装
置の他の例を、図1のA部部分側断面図によって示す。
なお、図4は、スナウト5内めっき浴中に振動板を浸漬
し、該振動板に振動を付与する方式を示す。また、図4
において、10A 、10B はスナウト内の浴面の波動を測定
する波動測定装置、11A 、11B はスナウト5内めっき浴
中に浸漬した振動板、12A 、12B は振動板11A 、11B に
振動を付与する加振装置、13A 、13B はアンプ、14A 、
14Bは演算器、15A 、15B は加振制御装置、20はめっき
浴浴面の波動測定装置10B に対する開口部、f5は振動板
11A 、11B の振動方向を示し、その他の符号は前記した
図1と同一の内容を示す。
Next, FIG. 4 shows another example of the vibration imparting device according to the present invention by a partial sectional view of a portion A in FIG.
FIG. 4 shows a method in which a diaphragm is immersed in a plating bath in the snout 5 to apply vibration to the diaphragm. FIG.
, 10A and 10B are wave measuring devices for measuring the wave of the bath surface in the snout, 11A and 11B are vibration plates immersed in the plating bath in the snout 5, and 12A and 12B apply vibration to the vibration plates 11A and 11B. Exciters, 13A, 13B are amplifiers, 14A,
14B is arithmetic unit, 15A, 15B is oscillated controller, 20 an opening for the wave measuring apparatus 10B of the plating bath bath surface, f 5 the diaphragm
The vibration directions of 11A and 11B are shown, and the other symbols indicate the same contents as those in FIG.

【0022】すなわち、図4に示すように、本発明にお
いては、スナウト5に振動を付与する代わりに、スナウ
ト5内めっき浴中に振動板11A 、11B を浸漬し、該振動
板に振動を付与してもよい。図4に示す振動付与方式に
おいては、鋼帯の表面側および裏面側の両者に波動測定
装置10A および10B を配設し、それぞれの測定結果に基
づき、それぞれ独立に、前記した図1に示す方法と同様
の方法で、アンプ13A 、13B 、演算器14A 、14B 、加振
制御装置15A 、15B 、加振装置12A 、12B を介して振動
板11A 、11Bに、波動測定装置10A 、10B で得られた波
動と逆位相の振動を付与し、スナウト5内めっき浴浴面
の波立ちを抑制する。
That is, as shown in FIG. 4, in the present invention, instead of imparting vibration to the snout 5, the diaphragms 11A and 11B are immersed in a plating bath in the snout 5 to impart vibration to the diaphragm. May be. In the vibration applying method shown in FIG. 4, the wave measuring devices 10A and 10B are provided on both the front side and the back side of the steel strip, and based on the respective measurement results, each of them is independently shown in FIG. In the same manner as described above, the vibrations are obtained by the vibration measuring devices 10A and 10B on the diaphragms 11A and 11B via the amplifiers 13A and 13B, the arithmetic units 14A and 14B, the vibration control devices 15A and 15B, and the vibration devices 12A and 12B. Vibration of the opposite phase to the generated wave is applied to suppress the ripple of the plating bath surface in the snout 5.

【0023】なお、図4に示すスナウト5内めっき浴中
に浸漬した振動板に振動を付与する方式においては、鋼
帯の表面側のめっき浴浴面の波立ちの大きさ、および鋼
帯の裏面側のめっき浴浴面の波立ちの大きさによって
は、振動板11A 、11B の片方のみに振動を付与してもよ
く、片方の振動板のみを付設してもよい。また、本発明
においては、鋼帯の表面側および/または裏面側に波動
測定装置を配設し、得られた測定結果に基づき、スナウ
トに、波動測定装置で得られた波動と逆位相の振動を付
与すると共に、めっき浴中に浸漬した振動板に、波動測
定装置で得られた波動と逆位相の振動を付与してもよ
い。
In the method shown in FIG. 4 in which vibration is applied to the diaphragm immersed in the plating bath in the snout 5, the magnitude of the waving of the plating bath surface on the front side of the steel strip and the back surface of the steel strip are determined. Vibration may be applied to only one of the diaphragms 11A and 11B, or only one of the diaphragms may be provided, depending on the magnitude of the waving of the plating bath surface on the side. Further, in the present invention, a wave measuring device is provided on the front side and / or the back side of the steel strip, and based on the obtained measurement result, a vibration having a phase opposite to that of the wave obtained by the wave measuring device is provided to the snout. And vibration having a phase opposite to the wave obtained by the wave measuring device may be applied to the diaphragm immersed in the plating bath.

【0024】以上述べたように、本発明においては、ス
ナウト内めっき浴浴面の波動(波立ち)を抑制するため
に、浴面の波動(波立ち)を測定し、それと逆位相とな
る周波の振動を、浴面の波動を打ち消すような周波数、
振幅でスナウトおよび/またはスナウト内めっき浴中に
浸漬した振動板に付与することによって、スナウト内浴
面の波動を消波する。
As described above, in the present invention, in order to suppress the undulation of the bath surface of the plating bath in the snout, the undulation of the bath surface is measured. The frequency that counteracts the wave of the bath surface,
By imparting the amplitude to the snout and / or the diaphragm immersed in the plating bath in the snout, the wave of the bath surface in the snout is eliminated.

【0025】この結果、本発明によれば、スナウト内の
浴面の波立ちが無くなり、ドロスや溶融亜鉛酸化物が浴
面を浮遊して鋼板へ付着することによって発生する鋼帯
表面のドロス欠陥やさざ波欠陥を大幅に減少することが
可能となった。以上本発明について述べたが、本発明に
おける鋼帯の連続溶融金属めっきにおける溶融金属とし
ては、溶融亜鉛に限定されることはなく、亜鉛を主成分
とする溶融(亜鉛−アルミ:Zn-Al )、アルミを主成分
とする溶融(アルミ−亜鉛:Al-Zn )など、溶融亜鉛以
外の溶融金属を用いることもできる。
As a result, according to the present invention, the bath surface in the snout is no longer wavy, and dross or molten zinc oxide floats on the bath surface and adheres to the steel plate. Ripple defects can be greatly reduced. Although the present invention has been described above, the molten metal in the continuous hot-dip metal plating of the steel strip in the present invention is not limited to molten zinc, but is a molten metal containing zinc as a main component (zinc-aluminum: Zn-Al). A molten metal other than molten zinc, such as molten aluminum (Al-Zn) containing aluminum as a main component, can also be used.

【0026】すなわち、本発明は、前記した本発明の作
用、効果に基づき、溶融亜鉛以外の溶融金属を用いた鋼
帯の溶融金属めっき装置におけるスナウト内めっき浴浴
面浮遊物の付着による鋼帯表面欠陥の防止を目的とした
溶融金属めっき方法および溶融金属めっき装置としても
好適に用いることができる。
That is, the present invention is based on the above-mentioned functions and effects of the present invention, in which a steel strip formed by adhesion of a floating material on a plating bath surface in a snout in a steel strip hot metal plating apparatus using a molten metal other than molten zinc. It can also be suitably used as a hot-dip metal plating method and a hot-dip metal plating apparatus for the purpose of preventing surface defects.

【0027】[0027]

【実施例】以下、本発明を実施例に基づいてさらに具体
的に説明する。本発明の溶融金属めっき装置を用い、鋼
帯への連続溶融亜鉛めっきを行い、鋼帯表面のドロス欠
陥およびさざなみ欠陥の発生状況を調べた。 (実施例1)前記した図1に示す本発明の溶融金属めっ
き装置を用い、下記条件下で鋼帯の連続溶融亜鉛めっき
を行い、得られた溶融亜鉛めっき鋼帯の品質を下記試験
方法で評価した。
EXAMPLES The present invention will be described below more specifically based on examples. Continuous hot-dip galvanizing was performed on a steel strip using the hot-dip metal plating apparatus of the present invention, and the occurrence of dross defects and ripple defects on the steel strip surface was examined. (Example 1) Using the hot-dip galvanizing apparatus of the present invention shown in FIG. 1 described above, continuous hot-dip galvanizing of a steel strip was performed under the following conditions, and the quality of the obtained hot-dip galvanized steel strip was determined by the following test method. evaluated.

【0028】なお、本実施例においては、加振装置12作
動後(本発明例1)の溶融亜鉛めっき鋼帯の品質と加振
装置12作動前(比較例1)の溶融亜鉛めっき鋼帯の品質
とを対比した。 (溶融亜鉛めっきの条件:) 鋼帯:冷延鋼帯、板厚0.4 〜3.2mm ×板幅750 〜1850mm 溶融亜鉛めっき浴侵入板温:470 〜480 ℃ 溶融亜鉛めっき浴Al濃度 :0.13〜0.15% 通板速度 :30〜150m/min (スナウト内めっき浴浴面の波立ち防止方法:)波動測
定装置10によってスナウト5内のめっき浴浴面の波動
(波立ち)を測定し、波動測定装置10からの信号をアン
プ13で増幅して演算器14に取り込み、浴面の波動(波立
ち)の高さhと周期Wを演算した。
In the present embodiment, the quality of the hot-dip galvanized steel strip after the operation of the vibrating device 12 (Example 1 of the present invention) and the hot-dip galvanized steel strip before the operation of the vibrating device 12 (Comparative Example 1). Quality and contrast. (Conditions of hot-dip galvanizing :) Steel strip: Cold-rolled steel strip, sheet thickness 0.4 to 3.2 mm x sheet width 750 to 1850 mm Hot-dip galvanizing bath penetration plate temperature: 470 to 480 ° C Hot-dip galvanizing bath Al concentration: 0.13 to 0.15 % Passing speed: 30 to 150m / min (Method of preventing the plating bath surface in the snout from waving :) The wave measuring device 10 measures the wave (waving) of the plating bath surface in the snout 5, and the wave measuring device 10 Was amplified by an amplifier 13 and taken into a computing unit 14 to calculate a height h and a cycle W of a wave (undulation) on the bath surface.

【0029】次に、得られた演算結果を加振制御装置15
に取り込み、めっき浴浴面の波動(波立ち)を打ち消す
ような、加振装置12から付与する振動の周波数、振幅を
演算し、得られた演算結果を制御出力として加振装置12
へ送信し、加振装置12によって、波動測定装置10で得ら
れた波動と逆位相の振動(:水平方向の往復運動)をス
ナウト5に発生させた。
Next, the obtained calculation result is transmitted to the vibration control device 15.
To calculate the frequency and amplitude of the vibration applied from the vibration device 12 such as to cancel the wave (ripening) of the plating bath surface, and to use the obtained calculation result as a control output as the vibration device 12
The vibrator 12 caused the snout 5 to generate a vibration (a horizontal reciprocating motion) having a phase opposite to that of the wave obtained by the wave measuring device 10.

【0030】なお、加振装置12としては、前記した図3
に示す加振装置12を用いた。その結果、スナウト内めっ
き浴浴面の波立ちの状態が、加振装置12作動前(比較例
1)は前記した図2(a) に示すような波立ちの状態であ
ったのに対して、加振装置12作動後(本発明例1)は前
記した図2(c) に示すような波立ちの状態となり、スナ
ウト5内めっき浴浴面の波立ちを大幅に打ち消すことが
できた。
The vibration device 12 is the same as that shown in FIG.
The vibration device 12 shown in FIG. As a result, the waving state of the plating bath surface in the snout was wavy as shown in FIG. 2A before actuation of the vibrating device 12 (Comparative Example 1). After the operation of the shaking device 12 (Example 1 of the present invention), the wave was formed as shown in FIG. 2 (c), and the wave of the plating bath surface in the snout 5 could be largely canceled.

【0031】(溶融亜鉛めっき鋼帯の試験方法:)得ら
れた鋼帯 100コイルについて下記試験を行い、品質を評
価した。 鋼帯表面のドロス欠陥による不良率:溶融亜鉛めっき
鋼帯をプレス加工し、プレス加工後の製品のドロス付着
個数が平均値で2個/m2以上の製品を不良とした。
(Testing method for hot-dip galvanized steel strip :) The following test was performed on 100 coils of the obtained steel strip to evaluate the quality. Defect rate due to dross defects on the steel strip surface: Hot-dip galvanized steel strip was pressed, and products with an average dross adhesion number of 2 pieces / m 2 or more after the press processing were regarded as defective.

【0032】鋼帯表面のさざなみ欠陥による不良率:
溶融亜鉛めっき鋼帯表面を目視で観察し、各コイルの波
模様の発生の有無を調査し、全コイルについてのさざな
み欠陥発生部位の重量割合を求めた。表1に、得られた
試験結果を示す。表1に示されるように、本発明によれ
ば、溶融亜鉛めっき装置のスナウト内めっき浴浴面の波
立ちが効果的に抑制され、その結果、鋼帯へのドロス、
溶融亜鉛酸化物の付着による鋼帯表面のドロス欠陥ある
いはさざ波欠陥の発生を効果的に防止することが可能と
なった。
Failure rate due to ripple defects on steel strip surface:
The surface of the hot-dip galvanized steel strip was visually observed, the presence or absence of generation of a wave pattern in each coil was investigated, and the weight ratio of the ripple-defect-generating site in all the coils was determined. Table 1 shows the test results obtained. As shown in Table 1, according to the present invention, the ripple of the plating bath surface in the snout of the hot dip galvanizing apparatus is effectively suppressed, and as a result, dross on the steel strip,
It has become possible to effectively prevent the occurrence of dross defects or ripple defects on the steel strip surface due to the adhesion of the molten zinc oxide.

【0033】(実施例2)前記した図1に示す本発明の
溶融金属めっき装置において、前記した図4および下記
に示す振動付与方式に基づいてスナウト5内めっき浴浴
面の波立ちを抑制した以外は実施例1と同様の条件で鋼
帯への連続溶融亜鉛めっきを行い、得られた溶融亜鉛め
っき鋼帯の品質を前記した実施例1と同様の方法で評価
した。
(Example 2) In the hot-dip metal plating apparatus of the present invention shown in FIG. 1 described above, except for suppressing the ripple of the plating bath surface in the snout 5 based on the vibration imparting method shown in FIG. 4 and described below. Was subjected to continuous hot-dip galvanizing on a steel strip under the same conditions as in Example 1, and the quality of the obtained hot-dip galvanized steel strip was evaluated in the same manner as in Example 1 described above.

【0034】なお、本実施例においては、前記した実施
例1と同様に、加振装置12作動後(本発明例2)の溶融
亜鉛めっき鋼帯の品質と加振装置12作動前(比較例2)
の溶融亜鉛めっき鋼帯の品質とを対比した。 (スナウト内めっき浴浴面の波立ち防止方法:)鋼帯の
表面側および裏面側の両者に配設した波動測定装置10A
および10B それぞれの測定結果に基づき、それぞれ独立
に、前記した図1に示す方法と同様の方法で、アンプ13
A 、13B 、演算器14A 、14B 、加振制御装置15A 、15B
、加振装置12A 、12B を介して振動板11A 、11B に、
波動測定装置10A 、10B で得られた波動と逆位相の振動
を付与し、スナウト5内めっき浴浴面の波立ちを抑制し
た。
In this embodiment, the quality of the hot-dip galvanized steel strip after the operation of the vibration device 12 (Example 2 of the present invention) and before the operation of the vibration device 12 (comparative example) 2)
And the quality of hot-dip galvanized steel strip. (Method for preventing ripples on plating bath surface in snout :) Wave measurement device 10A installed on both front and back sides of steel strip
And 10B, based on the respective measurement results, independently of the amplifier 13B in the same manner as the method shown in FIG.
A, 13B, computing units 14A, 14B, vibration control devices 15A, 15B
To the diaphragms 11A and 11B via the vibration devices 12A and 12B,
Vibrations having a phase opposite to that of the waves obtained by the wave measuring devices 10A and 10B were applied to suppress the ripple of the plating bath surface in the snout 5.

【0035】なお、加振装置12(12A 、12B )として
は、前記した図3に示す加振装置12を用いた。その結
果、スナウト内めっき浴浴面の波立ちの状態が、加振装
置12作動前(比較例2)は前記した図2(a) に示すよう
な波立ちの状態であったのに対して、加振装置12作動後
(本発明例2)は前記した図2(c) に示すような波立ち
の状態となり、スナウト5内めっき浴浴面の波立ちを大
幅に打ち消すことができた。
As the vibration device 12 (12A, 12B), the above-described vibration device 12 shown in FIG. 3 was used. As a result, the state of the plating bath surface in the snout was wavy as shown in FIG. 2A before actuation of the vibration device 12 (Comparative Example 2). After the operation of the shaking device 12 (Example 2 of the present invention), the wave was formed as shown in FIG. 2 (c), and the wave of the plating bath surface in the snout 5 could be largely canceled.

【0036】表1に、得られた試験結果を示す。表1に
示されるように、本発明によれば、溶融亜鉛めっき装置
のスナウト内めっき浴浴面の波立ちが効果的に抑制さ
れ、その結果、鋼帯へのドロス、溶融亜鉛酸化物の付着
による鋼帯表面のドロス欠陥あるいはさざ波欠陥の発生
を効果的に防止することが可能となった。
Table 1 shows the test results obtained. As shown in Table 1, according to the present invention, undulation of the plating bath surface in the snout of the hot dip galvanizing apparatus is effectively suppressed, and as a result, dross and adhesion of the molten zinc oxide to the steel strip are caused. It has become possible to effectively prevent the occurrence of dross defects or ripple defects on the steel strip surface.

【0037】なお、前記した実施例1、実施例2におい
ては、鋼帯の溶融亜鉛めっきについて説明したが、本発
明は、前記した本発明の作用、効果に基づき、溶融亜鉛
以外の溶融金属を用いた鋼帯の溶融金属めっき装置にお
けるスナウト内めっき浴浴面浮遊物の付着による鋼帯表
面欠陥の防止を目的とした溶融金属めっき方法および溶
融金属めっき装置としても好適に用いることができる。
In the first and second embodiments described above, hot-dip galvanizing of a steel strip has been described. However, the present invention is based on the above-described functions and effects of the present invention. The present invention can also be suitably used as a molten metal plating method and a molten metal plating apparatus for the purpose of preventing a steel strip surface defect due to adhesion of a plating bath bath surface in a snout in a used steel strip molten metal plating apparatus.

【0038】[0038]

【表1】 [Table 1]

【0039】[0039]

【発明の効果】本発明によれば、溶融亜鉛めっき装置の
スナウト内めっき浴浴面の波立ちが効果的に抑制され、
その結果、鋼帯へのドロス、溶融亜鉛酸化物の付着によ
る鋼帯表面のドロス欠陥あるいはさざ波欠陥の発生を効
果的に防止することが可能となり、操業の安定に大きく
貢献することができる。
According to the present invention, ripples on the plating bath surface in the snout of the hot dip galvanizing apparatus are effectively suppressed,
As a result, it is possible to effectively prevent dross defects or ripple defects on the surface of the steel strip due to the attachment of dross and molten zinc oxide to the steel strip, which can greatly contribute to stable operation.

【0040】本発明は、本発明の作用、効果に基づき、
溶融亜鉛以外の溶融金属を用いた鋼帯の溶融金属めっき
装置におけるスナウト内めっき浴浴面浮遊物の付着によ
る鋼帯表面欠陥の防止を目的とした溶融金属めっき方法
および溶融金属めっき装置としても好適に用いることが
できる。
The present invention is based on the actions and effects of the present invention.
Also suitable as a hot metal plating method and a hot metal plating apparatus for the purpose of preventing steel strip surface defects due to adhesion of floating substances on the bath surface of a plating bath in a snout in a hot metal plating apparatus for steel strip using a molten metal other than molten zinc Can be used.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の溶融金属めっき装置の一例を示す側断
面図(a) およびA部部分側断面図(b) である。
FIG. 1 is a side sectional view (a) and an A part partial side sectional view (b) showing an example of a hot-dip metal plating apparatus of the present invention.

【図2】波動測定装置からの信号の演算結果を示すグラ
フ(a) 、加振制御装置からの制御出力を示すグラフ(b)
、および加振装置によって制御された浴面の波立ちの
状態(波動測定装置からの信号の演算結果)を示すグラ
フ(c) である。
FIG. 2 is a graph (a) showing a calculation result of a signal from a wave measurement device, and a graph (b) showing a control output from a vibration control device.
FIG. 7C is a graph (c) showing the state of undulation on the bath surface controlled by the vibrating device (the calculation result of the signal from the wave measuring device).

【図3】本発明に係わる加振装置の一例を示す説明図で
ある。
FIG. 3 is an explanatory view showing an example of a vibration device according to the present invention.

【図4】本発明に係わる振動付与装置の他の例を示す図
1のA部部分側断面図である。
FIG. 4 is a partial sectional view of a part A in FIG. 1 showing another example of the vibration imparting device according to the present invention.

【図5】従来の溶融金属めっき装置を示す側断面図であ
る。
FIG. 5 is a side sectional view showing a conventional hot-dip metal plating apparatus.

【符号の説明】[Explanation of symbols]

1 めっき浴(溶融金属) 2 めっき用ポット 3 シンクロール 4 鋼帯(:ストリップ) 5 スナウト 10、10A 、10B 波動測定装置 11、11A 、11B 振動板 12、12A 、12B 加振装置 13、13A 、13B アンプ 14、14A 、14B 演算器 15、15A 、15B 加振制御装置 16 スナウト支持板 17 スナウト内浴面 18 スナウト内浴面の波の谷 19 スナウト内浴面の波の山 20 開口部 21 モータ 22 インバータ 23 偏心カム 24 スライドプレート 25 偏心カムの回転駆動軸 f1 鋼帯の搬送方向(通板方向) f2 シンクロールの回転方向 f3 スナウト支持板およびスナウトの振動方向 f4 スナウトの振動方向 f5 振動板の振動方向 f6 回転駆動軸の回転方向 f7 スライドプレートの水平方向の往復動方向(振動方
向) f8 スナウトまたは振動板の水平方向の振動方向 h スナウト内のめっき浴浴面の波動(波立ち)の高さ h0 加振装置から付与する振動の振幅 W スナウト内のめっき浴浴面の波動(波立ち)の周期
(:時間) W0 加振装置から付与する振動の周期
Reference Signs List 1 plating bath (molten metal) 2 plating pot 3 sink roll 4 steel strip (strip) 5 snout 10, 10A, 10B wave measuring device 11, 11A, 11B diaphragm 12, 12A, 12B vibrating device 13, 13A, 13B Amplifier 14, 14A, 14B Computing unit 15, 15A, 15B Vibration control unit 16 Snout support plate 17 Snout inner bath surface 18 Wave trough of snout inner bath surface 19 Wave peak of snout inner bath surface 20 Opening 21 Motor 22 Inverter 23 Eccentric cam 24 Slide plate 25 Rotary drive shaft of eccentric cam f 1 Transport direction of steel strip (passing direction) f 2 Rotation direction of sink roll f 3 Vibration direction of snout support plate and snout f 4 Vibration direction of snout f 5 Vibration direction of diaphragm f 6 Rotation direction of rotary drive shaft f 7 Reciprocating direction of horizontal reciprocation of slide plate (vibration direction) f 8 Horizontal vibration direction of snout or diaphragm h Plating bath surface in snout Wave of the wave Period of the wave of the plating bath bath surface in the amplitude W snout of the vibration (waving) that imparts from a height h 0 vibrator (: Time) cycle of the vibration applied from the W 0 vibrator

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 鋼帯を、大気遮断用のスナウトを介して
溶融金属であるめっき浴中に連続的に侵入せしめ、めっ
き浴中に配設したシンクロールを周回後、方向転換し、
めっき浴浴面より上方へ引き上げて連続的にめっきを施
す溶融金属めっき方法であって、前記スナウト内の浴面
の波動を測定し、得られた測定結果に基づいて前記波動
を消去する振動をスナウトおよび/またはスナウト内め
っき浴中に浸漬した振動板に付与することを特徴とする
溶融金属めっき方法。
1. A steel strip is continuously penetrated into a plating bath, which is a molten metal, through a snout for shielding air, and after turning around a sink roll provided in the plating bath, the steel strip is turned.
A hot-dip metal plating method in which a plating bath is raised above a bath surface to continuously perform plating, wherein a wave of the bath surface in the snout is measured, and vibration for eliminating the wave based on the obtained measurement result is measured. A hot-dip metal plating method, which is applied to a diaphragm immersed in a snout and / or a plating bath in the snout.
【請求項2】 鋼帯を大気と遮断して溶融金属であるめ
っき浴中に連続的に侵入させるためのスナウト(5) と、
前記めっき浴を収納するめっき用ポット(2)と、めっき
浴中に侵入させた鋼帯を方向転換させめっき浴浴面より
上方へ引き上げるためにめっき浴中に配設したシンクロ
ール(3) を有する溶融金属めっき装置であって、前記ス
ナウト(5) 内の浴面の波動を測定する波動測定装置(10)
と、該波動測定装置(10)で得られた波動と逆位相の振動
をスナウト(5) および/またはスナウト(5) 内めっき浴
中に浸漬した振動板(11)に付与する加振装置(12)を配設
したことを特徴とする溶融金属めっき装置。
2. A snout (5) for shielding a steel strip from the atmosphere and continuously intruding into a plating bath which is a molten metal;
A plating pot (2) for storing the plating bath and a sink roll (3) disposed in the plating bath to change the direction of the steel strip penetrating into the plating bath and pull it upward from the plating bath surface. A molten metal plating apparatus having a wave measuring apparatus for measuring a wave of a bath surface in the snout (5).
And a vibration device (10) for applying vibration having an opposite phase to the wave obtained by the wave measurement device (10) to the snout (5) and / or the diaphragm (11) immersed in the plating bath in the snout (5). A hot-dip metal plating apparatus characterized by including 12).
JP2000127704A 2000-04-27 2000-04-27 Hot dip metal coating method and hot dip metal coating apparatus Pending JP2001303224A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000127704A JP2001303224A (en) 2000-04-27 2000-04-27 Hot dip metal coating method and hot dip metal coating apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000127704A JP2001303224A (en) 2000-04-27 2000-04-27 Hot dip metal coating method and hot dip metal coating apparatus

Publications (1)

Publication Number Publication Date
JP2001303224A true JP2001303224A (en) 2001-10-31

Family

ID=18637251

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000127704A Pending JP2001303224A (en) 2000-04-27 2000-04-27 Hot dip metal coating method and hot dip metal coating apparatus

Country Status (1)

Country Link
JP (1) JP2001303224A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101070080B1 (en) * 2008-12-23 2011-10-04 주식회사 포스코 Snout Apparatus for Strip Galvanizing Line
CN113166915A (en) * 2018-11-06 2021-07-23 日本制铁株式会社 Hot dip coating method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101070080B1 (en) * 2008-12-23 2011-10-04 주식회사 포스코 Snout Apparatus for Strip Galvanizing Line
CN113166915A (en) * 2018-11-06 2021-07-23 日本制铁株式会社 Hot dip coating method
US11566315B2 (en) 2018-11-06 2023-01-31 Nippon Steel Corporation Hot-dip plating method

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