JP2001258416A - Shaped product for treating evacuated urine - Google Patents

Shaped product for treating evacuated urine

Info

Publication number
JP2001258416A
JP2001258416A JP2000398416A JP2000398416A JP2001258416A JP 2001258416 A JP2001258416 A JP 2001258416A JP 2000398416 A JP2000398416 A JP 2000398416A JP 2000398416 A JP2000398416 A JP 2000398416A JP 2001258416 A JP2001258416 A JP 2001258416A
Authority
JP
Japan
Prior art keywords
urination
surfactant
urine
molded article
pulp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000398416A
Other languages
Japanese (ja)
Other versions
JP3338700B2 (en
Inventor
Kazuya Otsuji
一也 大辻
Yasuki Tsutsumi
泰樹 堤
Hiromi Yamaguchi
広美 山口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to JP2000398416A priority Critical patent/JP3338700B2/en
Publication of JP2001258416A publication Critical patent/JP2001258416A/en
Application granted granted Critical
Publication of JP3338700B2 publication Critical patent/JP3338700B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To provide a shaped product for treating evacuated urine, excellent in absorption of urine, or the like, high in deodorant effect, easy in treatment and disposal, and capable of being used for a long period. SOLUTION: This shaped product for treating the urine is obtained by shaping a mixture obtained by mixing a surfactant having antibacterial properties, or a surfactant and an antibacterial agent, and at least one kind of a binder, a crosslinking agent and water, with a urine-absorbing substrate comprising at least one kind of a vegetable fiber and a pulp, into a flat plate shape, and is characterized by 0.05-0.3 g/cm3 bulk density, >=2 g/g saturated water absorption, <=30 s water absorbing rate, >=49 cN wet strength and >=3 mm thickness.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、犬、猫等の動物用
又は人用の排尿処理成形物に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a molded article for urination treatment for animals such as dogs and cats or for humans.

【0002】[0002]

【従来の技術及び発明が解決しようとする課題】犬、猫
等の動物用又は人用の排尿処理成形物として、珪砂等の
天然砂を破砕したものや、ゼオライト、吸水性ポリマー
等の吸水性材料を造粒したもの等の粒状タイプの排尿処
理成形物が従来から知られている。しかし、粒状タイプ
の排尿処理成形物は、使用時に該排尿処理成形物が飛散
して周囲を汚し易い、粉塵が発生し易い、不定形で流動
性があるため取扱い及び廃棄が不便である、可燃物とし
て廃棄ができない等の欠点がある。また、シート状タイ
プの排尿処理成形物も従来から知られており、例えば、
実開平1−105448号公報には、紙状シートである
し尿脱臭殺菌シートが記載されている。しかし、紙状シ
ートは、尿等の吸収性に劣る、強度的に弱いため取扱い
及び廃棄が不便で長期間使用できない等の欠点がある。
また、排尿処理成形物は消臭効果があることも要求され
るが、消臭効果が高く且つ上記欠点のない排尿処理成形
物はまだ開発されていない。
2. Description of the Related Art As urination treatment molded products for animals or humans such as dogs and cats, crushed natural sands such as silica sand, and water absorbing materials such as zeolites and water absorbing polymers. BACKGROUND ART Granular-type urination molded articles such as granulated materials are conventionally known. However, the urine-treated molded product of the granular type is liable to be scattered when used to pollute the surroundings, to easily generate dust, to be inconsistent in shape and fluidity, and to be inconvenient to handle and dispose of. There are drawbacks such as the fact that they cannot be disposed of. Further, a sheet-shaped type urination treatment molded product is also conventionally known, for example,
Japanese Utility Model Laid-Open Publication No. 1-105448 describes a paper-like sheet, a human urine deodorizing and sterilizing sheet. However, paper-like sheets have drawbacks such as poor absorbency for urine and the like, and inconvenient handling and disposal due to their low strength, and cannot be used for a long period of time.
Further, although the urination-treated molded article is required to have a deodorizing effect, a urination-treated molded article having a high deodorizing effect and free from the above-mentioned disadvantages has not yet been developed.

【0003】従って、本発明は、尿等の吸収性に優れ、
消臭効果が高く、取扱い及び廃棄が容易で、長期間使用
可能な排尿処理成形物を提供することを目的とするもの
である。
[0003] Therefore, the present invention is excellent in the absorption of urine and the like,
It is an object of the present invention to provide a urination molded article which has a high deodorizing effect, is easy to handle and dispose, and can be used for a long time.

【0004】[0004]

【課題を解決するための手段】本発明は、植物性繊維又
はパルプの少なくとも一種からなる排尿吸収基材に、抗
菌性を有する界面活性剤又は界面活性剤及び抗菌剤と、
バインダー、架橋剤又は水の少なくとも一種とを混合し
て得られた混合物を平板状に成形してなり、嵩密度が
0.05〜0.3g/cm3 、飽和吸水量が2g/1g
以上、吸水速度が30秒以下、湿潤強度が49cN以
上、厚みが3mm以上である排尿処理成形物を提供する
ことにより前記目的を達成したものである。
SUMMARY OF THE INVENTION The present invention provides a urinary absorption substrate comprising at least one of vegetable fiber or pulp, comprising a surfactant having an antibacterial property or a surfactant and an antibacterial agent;
A mixture obtained by mixing at least one of a binder, a cross-linking agent, and water is formed into a flat plate, and has a bulk density of 0.05 to 0.3 g / cm 3 and a saturated water absorption of 2 g / 1 g.
As described above, the above object has been achieved by providing a urination treatment molded product having a water absorption rate of 30 seconds or less, a wet strength of 49 cN or more, and a thickness of 3 mm or more.

【0005】[0005]

【発明の実施の形態】以下、本発明の排尿処理成形物
を、その好ましい実施形態に基づき図面を参照しながら
説明する。図1に示すように、本実施形態の排尿処理成
形物1は、所定厚みを有し、上下面が平坦な平板状のも
のであり、排尿吸収基材に、抗菌性を有する界面活性剤
又は界面活性剤及び抗菌剤と、バインダー、架橋剤又は
水の少なくとも一種とを混合して得られた混合物を成形
してなるものである。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, a molded article for urination treatment of the present invention will be described based on a preferred embodiment with reference to the drawings. As shown in FIG. 1, the urination-treated molded article 1 of the present embodiment has a predetermined thickness, is a flat plate having upper and lower surfaces flat, and has a urinary absorption base material having a surfactant having antibacterial properties or It is obtained by molding a mixture obtained by mixing a surfactant, an antibacterial agent, and at least one of a binder, a crosslinking agent and water.

【0006】前記排尿吸収基材は、植物性繊維又はパル
プの少なくとも一種からなる。このような植物性繊維を
主体とした排尿吸収基材を具備する排尿処理成形物は、
多孔質且つ低密度であるため尿等の吸収性に優れ、消臭
効果も有する。また、可燃物であるため、使用後は可燃
ゴミとして容易に焼却廃棄ができる。本明細書において
「植物性繊維」とは、植物体を構成する繊維又はその集
合体であって、セルロース以外にリグニン、ヘミセルロ
ース、樹脂分、灰分等の成分を含んでいるものをいう。
また、「パルプ」とは、「植物性繊維」からセルロース
以外の成分を極力除いた、セルロース純度の高いものを
いい、いわゆる化学パルプがこれに該当する。
[0006] The urine absorbing substrate is made of at least one of vegetable fiber and pulp. A urination-treated molded article comprising a urine absorption base mainly composed of such vegetable fibers,
Since it is porous and has a low density, it has excellent absorption of urine and the like, and also has a deodorizing effect. Further, since it is a combustible substance, it can be easily incinerated and disposed of as combustible waste after use. As used herein, the term "vegetable fiber" refers to a fiber constituting a plant or an aggregate thereof, which contains components such as lignin, hemicellulose, resin, and ash in addition to cellulose.
The term "pulp" refers to a high-purity cellulose obtained by removing components other than cellulose from "vegetable fiber" as much as possible, and corresponds to so-called chemical pulp.

【0007】前記植物性繊維としては、グランドパル
プ、おが屑、ジュート、ヤシ繊維等を、これらの1種又
は2種以上で用いることができる。特に、尿等の吸収性
及び消臭効果の向上、並びに安定供給の観点から、グラ
ンドパルプ及び/又はおが屑を用いることが好ましい。
グランドパルプ(GP)は、砕木パルプとも呼ばれるも
のでいわゆる機械パルプである。機械パルプには、GP
の他、ストーン砕木パルプ(SGP)、リファイナー砕
木パルプ(RGP)、サーモメカニカルパルプ(TM
P)等があるが、本明細書では、これらを総称してグラ
ンドパルプという。グランドパルプのうち、消臭効果の
観点から、ストーン砕木パルプを用いることが特に好ま
しい。また、前記パルプとしては、古紙パルプを用いる
ことが好ましいが、吸水性の観点から、脱墨処理パルプ
を用いることが特に好ましい。前記植物性繊維及び前記
パルプは、それぞれ単独で排尿吸収基材として用いても
よいし、両者を混合して排尿吸収基材として用いてもよ
い。両者を混合する場合には、植物性繊維とパルプとの
混合比(重量)は、植物性繊維:パルプ=10:1〜
1:100の範囲で適宜選択できる。
[0007] As the vegetable fiber, ground pulp, sawdust, jute, coconut fiber and the like can be used alone or in combination of two or more. In particular, it is preferable to use ground pulp and / or sawdust from the viewpoints of improving the absorption and deodorizing effects of urine and the like and providing a stable supply.
Ground pulp (GP) is also called groundwood pulp and is a so-called mechanical pulp. For mechanical pulp, GP
, Stone ground wood pulp (SGP), refiner ground wood pulp (RGP), thermomechanical pulp (TM
P) and the like, but in the present specification, these are collectively referred to as ground pulp. Among ground pulp, it is particularly preferable to use ground stone wood pulp from the viewpoint of the deodorizing effect. Further, as the pulp, it is preferable to use waste paper pulp, but it is particularly preferable to use deinking pulp from the viewpoint of water absorption. The vegetable fiber and the pulp may each be used alone as a urine absorbing base material, or both may be used as a urinary absorbing base material. When both are mixed, the mixing ratio (weight) between the vegetable fiber and the pulp is as follows: vegetable fiber: pulp = 10: 1 to 1
It can be appropriately selected in the range of 1: 100.

【0008】本発明の排尿処理成形物は、前記植物性繊
維、前記パルプ又はこれらの混合物を好ましくは50〜
95重量%、特に70〜90重量%含有することが、尿
等の吸収性及び消臭効果を向上させると共に、必要な強
度を付与する点から好ましい。
[0008] The molded article for urination treatment of the present invention preferably contains the vegetable fiber, the pulp or a mixture thereof in an amount of 50 to 50%.
The content of 95% by weight, particularly 70 to 90% by weight, is preferable from the viewpoint of improving the absorbability of urine and the like and the deodorizing effect, and imparting necessary strength.

【0009】排尿処理成形物1は、抗菌性を有するか又
は有しない界面活性剤を含有している。これにより、排
尿処理成形物1の親水性が向上して、尿等の吸収速度を
向上させることができる。その結果、後述するように、
排尿処理成形物1が低密度、高多孔性であることと相俟
って、吸水量及び吸水速度が向上する。
The urination-treated molded article 1 contains a surfactant having or not having an antibacterial property. Thereby, the hydrophilicity of the urination-treated molded article 1 is improved, and the absorption speed of urine and the like can be improved. As a result, as described below,
In combination with the low density and high porosity of the urination-treated molded article 1, the water absorption amount and the water absorption speed are improved.

【0010】前記界面活性剤が抗菌性を有する場合に
は、尿等の排泄物を分解してアンモニアを生成する菌の
繁殖を抑制できるので、周囲に悪臭を発散させることな
く長期間使用できる。一方、前記界面活性剤が抗菌性を
有さない場合には、該界面活性剤を抗菌剤と併用するこ
とにより同様の効果を発現させ得る。
When the surfactant has an antibacterial property, the growth of bacteria that generate ammonia by decomposing excretions such as urine can be suppressed, so that the surfactant can be used for a long period of time without emitting malodor to the surroundings. On the other hand, when the surfactant has no antibacterial property, the same effect can be exhibited by using the surfactant in combination with the antibacterial agent.

【0011】抗菌性を有する前記界面活性剤としては、
カチオン性界面活性剤又は両性界面活性剤を用いること
ができる。カチオン性界面活性剤としては、例えば、塩
化アルキルトリメチルアンモニウム、塩化ジアルキルジ
メチルアンモニウム、塩化ベンザルコニウム等を、これ
らの1種又は2種以上で用いることができ、特に、抗菌
性の観点から、塩化ベンザルコニウムを用いることが好
ましい。また、両性界面活性剤としては、例えば、アル
キルジメチルアミノ酢酸ベタイン、アルキルジメチルア
ミンオキサイド、アルキルカルボキシメチルヒドロキシ
エチルイミダゾリニウムベタイン、アルキルアミドプロ
ピルベタイン等を、これらの1種又は2種以上で用いる
ことができ、特に、抗菌消臭性の観点から、アルキルジ
メチルアミンオキサイドを用いることが好ましい。尚、
排尿処理成形物1の抗菌性を一層向上させるために、抗
菌性を有する前記界面活性剤を、抗菌剤と併用してもよ
い。この場合、該抗菌剤は、水溶性のものが好ましい。
The surfactant having antibacterial properties includes:
Cationic or amphoteric surfactants can be used. As the cationic surfactant, for example, alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, benzalkonium chloride and the like can be used alone or in combination of two or more thereof. It is preferable to use benzalkonium. In addition, as the amphoteric surfactant, for example, alkyldimethylaminoacetate betaine, alkyldimethylamine oxide, alkylcarboxymethylhydroxyethylimidazolinium betaine, alkylamidopropyl betaine, and the like may be used alone or in combination of two or more. In particular, it is preferable to use an alkyldimethylamine oxide from the viewpoint of antibacterial and deodorant properties. still,
In order to further improve the antibacterial properties of the urination-treated molded article 1, the surfactant having antibacterial properties may be used in combination with an antibacterial agent. In this case, the antibacterial agent is preferably a water-soluble one.

【0012】排尿処理成形物1は、抗菌性を有する前記
界面活性剤を好ましくは0.1〜5重量%、特に0.5
〜3重量%含有することが、尿等の吸収性が向上すると
共に悪臭の発散が防止されて長期間使用できることから
好ましい。
The urination-treated molded article 1 contains 0.1 to 5% by weight, preferably 0.5 to 5% by weight of the surfactant having antibacterial properties.
It is preferred that the content be contained in an amount of from 3 to 3% by weight, since the absorption of urine and the like is improved, and the emission of offensive odors is prevented, so that it can be used for a long time.

【0013】抗菌性を有さない前記界面活性剤として
は、非イオン性界面活性剤を用いることができる。非イ
オン性界面活性剤としては、例えば、グリセリン脂肪酸
エステル、ソルビタン脂肪酸エステル、ポリオキシエチ
レンソルビタン脂肪酸エステル、ポリオキシエチレンア
ルキルエーテル、ポリオキシエチレングリコール脂肪酸
エステル等を、これらの1種又は2種以上で用いること
ができ、特に、水に可溶という観点から、HLB−数方
式により算出されたHLBが10〜19の非イオン性界
面活性剤を用いることが好ましい。また、抗菌性を有さ
ない該界面活性剤と併用される抗菌剤としては、水溶性
のものが好ましく、例えば、安息香酸ナトリウム、クロ
ラミンT、クロルクレゾール、サルチル酸ナトリウム、
臭化エチルトリメチルアンモニウム、ソルビン酸カリウ
ム、デヒドロ酢酸ナトリウム、パラクロロフェノール、
フェノール等を、これらの1種又は2種以上で用いるこ
とができ、特に、臭いや動物に対する安全性の観点か
ら、安息香酸ナトリウムを用いることが好ましい。
As the surfactant having no antibacterial properties, a nonionic surfactant can be used. As the nonionic surfactant, for example, glycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene glycol fatty acid ester, etc., by one or more of these In particular, from the viewpoint of solubility in water, it is preferable to use a nonionic surfactant having an HLB calculated from the HLB number method of 10 to 19. As the antibacterial agent used in combination with the surfactant having no antibacterial property, a water-soluble antibacterial agent is preferable. For example, sodium benzoate, chloramine T, chlorcresol, sodium salicylate,
Ethyltrimethylammonium bromide, potassium sorbate, sodium dehydroacetate, parachlorophenol,
Phenol and the like can be used alone or in combination of two or more thereof. In particular, it is preferable to use sodium benzoate from the viewpoint of odor and safety for animals.

【0014】排尿処理成形物1は、抗菌性を有さない界
面活性剤を好ましくは0.01〜5重量%、更に好まし
くは0.1〜5重量%、とりわけ0.1〜2重量%含有
すると共に、前記抗菌剤を好ましくは0.001〜5重
量%、更に好ましくは0.1〜0.5重量%含有する。
The urination-treated molded article 1 preferably contains 0.01 to 5% by weight, more preferably 0.1 to 5% by weight, especially 0.1 to 2% by weight of a surfactant having no antibacterial properties. In addition, the antibacterial agent is preferably contained in an amount of 0.001 to 5% by weight, more preferably 0.1 to 0.5% by weight.

【0015】前記バインダー、架橋剤又は水は、前記植
物性繊維及び前記パルプの結合剤として使用される(以
下、これらの成分を総称して繊維間結合剤という)。排
尿処理成形物1に、これら繊維間結合剤を含有させるこ
とにより、実用上必要とされる強度を排尿処理成形物1
に付与することができ、取扱性及び廃棄性に優れ、長期
間使用できる排尿処理成形物とすることができる。
The binder, the crosslinking agent or the water is used as a binder for the vegetable fiber and the pulp (hereinafter, these components are collectively referred to as an interfiber binder). By including these inter-fiber binders in the urination-treated molded article 1, the strength required for practical use can be increased.
To provide a urination-treated molded article that is excellent in handleability and disposability and can be used for a long period of time.

【0016】本明細書において「架橋剤」とは、水素結
合により繊維間を架橋するものをいい、後述する湿式製
造法により排尿処理成形物を製造する場合に特に好適に
使用できる。また、「バインダー」とは、接着剤(同種
あるいは異種の2つの固体を貼り合わせる目的で用いら
れる物質)のうち、上記「架橋剤」を除いたものをい
う。
As used herein, the term "crosslinking agent" refers to a substance which crosslinks between fibers by hydrogen bonding, and can be particularly suitably used when producing a urination-treated molded article by a wet production method described later. The term "binder" refers to an adhesive (a substance used for bonding two solids of the same or different types) excluding the "crosslinking agent".

【0017】前記バインダーとしては、例えば、ポリビ
ニルアルコール、化工澱粉、寒天、カルボキシメチルセ
ルロース、ポリアクリルアミド等を、これらの1種又は
2種以上で用いることができ、特に、吸水性の観点か
ら、ポリビニルアルコール及び/又は化工澱粉を用いる
ことが好ましい。更に、ポリビニルアルコール及び化工
澱粉は、何れも糊化温度が60℃以上、特に70〜80
℃であることが好ましい。これらバインダーの糊化温度
が60℃以上であると、室温下、湿潤状態にある使用後
の排尿処理成形物中で該バインダーが溶け出すことがな
いので、排尿処理成形物は、その湿潤強度が一定に保た
れて形状が崩れることがなく、取扱い及び廃棄が容易で
ある。排尿処理成形物1は、前記バインダーを好ましく
は1〜45重量%、更に好ましくは5〜45重量%、と
りわけ7〜20重量%含有する。
As the binder, for example, polyvinyl alcohol, modified starch, agar, carboxymethylcellulose, polyacrylamide and the like can be used alone or in combination of two or more. In particular, from the viewpoint of water absorption, polyvinyl alcohol is used. It is preferable to use modified starch. Further, both the polyvinyl alcohol and the modified starch have a gelatinization temperature of 60 ° C. or higher, especially 70 to 80.
C. is preferred. When the gelatinization temperature of these binders is 60 ° C. or higher, the binder does not dissolve in the used urination treated molded product in a wet state at room temperature, so that the urination treatment molded product has a wet strength. It is kept constant and does not lose its shape, and is easy to handle and dispose. The urination-treated molded article 1 contains the binder preferably in an amount of 1 to 45% by weight, more preferably 5 to 45% by weight, especially 7 to 20% by weight.

【0018】前記架橋剤としては、湿式抄紙法において
一般に紙力増強剤として使用されるものを使用でき、例
えば、ポリアミドアミン・エピクロルヒドリン樹脂、ポ
リアクリルアミド、ポリエチレン、メチロール化ポリア
クリルアミド等を、これらの1種以上で用いることがで
きる。架橋剤は、繊維間結合剤として単独でも使用で
き、また、媒体として水を併用することもできる。排尿
処理成形物1は、前記架橋剤を好ましくは0.01〜3
重量%、更に好ましくは0.3〜1重量%含有する。
As the cross-linking agent, those generally used as a paper strength agent in a wet papermaking method can be used. For example, polyamidoamine / epichlorohydrin resin, polyacrylamide, polyethylene, methylolated polyacrylamide and the like can be used. More than one species can be used. The cross-linking agent can be used alone as an inter-fiber binder, or water can be used in combination as a medium. The urination-treated molded article 1 preferably contains 0.01 to 3 of the crosslinking agent.
%, More preferably 0.3 to 1% by weight.

【0019】前記植物性繊維等の結合剤として水のみを
使用する場合、排尿処理成形物1の含水量は、好ましく
は1〜20重量%、更に好ましくは5〜20重量%であ
る。
When only water is used as the binder for the vegetable fiber or the like, the water content of the urination-treated molded article 1 is preferably 1 to 20% by weight, more preferably 5 to 20% by weight.

【0020】排尿処理成形物1は、前記の各成分(排尿
吸収基材、抗菌性を有するか又は有さない界面活性剤、
抗菌剤及び繊維間結合剤)に加えて、必要に応じて、消
臭剤、マスキング剤等の添加剤を適宜含有させることが
できる。これらの添加剤の含有量は好ましくは0.01
〜1重量%、更に好ましくは0.03〜0.1重量%で
ある。
The urination-treated molded article 1 comprises the above-mentioned components (a urination absorbing base material, a surfactant having or not having an antibacterial property,
In addition to the antibacterial agent and the inter-fiber binder), if necessary, additives such as a deodorant and a masking agent can be appropriately contained. The content of these additives is preferably 0.01
To 1% by weight, more preferably 0.03 to 0.1% by weight.

【0021】排尿処理成形物1は、前記の各成分と、必
要に応じて用いられる前記添加剤とを混合して得られた
混合物を、厚さが3mm以上、好ましくは5〜50m
m、更に好ましくは10〜20mmの平板状に成形して
なるものである。このように所定の厚みを有する平板状
に成形された排尿処理成形物は、紙状シートのものに比
べて尿等の吸水量が多く、強度も高い。また、粒状タイ
プの排尿処理成形物のように取扱い時に粉塵が発生する
ことがほとんどなく、廃棄が容易である。
The urination-treated molded article 1 is obtained by mixing a mixture obtained by mixing each of the above-mentioned components and the above-mentioned additives used as necessary with a thickness of 3 mm or more, preferably 5 to 50 m.
m, more preferably 10-20 mm. The urination-treated molded article formed into a flat plate having a predetermined thickness in this manner has a greater amount of water absorption of urine and the like and a higher strength than those of a paper-like sheet. Moreover, unlike the granular type urination molded product, dust is hardly generated at the time of handling, and disposal is easy.

【0022】厚みは、以下のようにして測定される。 〈厚みの測定方法〉排尿処理成形物の幅方向に沿って、
10cm間隔でマイクロゲージ(厚み測定器)を当てて
各箇所における厚みを測定し、これらの平均値を該排尿
処理成形物の厚みとした。
The thickness is measured as follows. <Measuring method of thickness> Along the width direction of the urination treated molded product,
The thickness at each location was measured by applying a micro gauge (thickness measuring device) at intervals of 10 cm, and the average value of these was defined as the thickness of the urination molded article.

【0023】排尿処理成形物1は、その嵩密度が0.0
5〜0.3g/cm3 、好ましくは0.1〜0.25g
/cm3 、更に好ましくは0.15〜0.2g/cm3
となっている。嵩密度を前記範囲内とすることにより、
成形物としての必要強度を維持しつつ、尿等の吸収速度
を向上させることができる。本発明の排尿処理成形物
は、その嵩密度が前記範囲内にある低密度体であり、且
つ前述の如く多孔質体であるから、低湿度下では吸収し
た尿等に含まれる水分を放出するので、排尿処理成形物
が本来有する、後述する測定方法により測定される吸水
量以上の尿等を吸収することができる。
The urination-treated molded article 1 has a bulk density of 0.0
5 to 0.3 g / cm 3 , preferably 0.1 to 0.25 g
/ Cm 3 , more preferably 0.15 to 0.2 g / cm 3
It has become. By setting the bulk density within the above range,
The rate of absorption of urine and the like can be improved while maintaining the required strength as a molded product. The urination-treated molded article of the present invention is a low-density body whose bulk density is within the above range, and is a porous body as described above, and releases water contained in absorbed urine and the like under low humidity. Therefore, it is possible to absorb urine or the like originally having a water absorption amount equal to or greater than the water absorption measured by a measurement method described later, which is inherent in the urination-treated molded article.

【0024】嵩密度は、次の方法により測定される。 〈嵩密度の測定方法〉排尿処理成形物から、縦6cm、
横6cm、厚さ1cmの試験片(体積36cm3 )を裁
断し、該試験片の重量を測定して、次式により嵩密度
(g/cm3 )を求めた。
The bulk density is measured by the following method. <Measurement method of bulk density>
A test piece (volume: 36 cm 3 ) having a width of 6 cm and a thickness of 1 cm was cut, the weight of the test piece was measured, and the bulk density (g / cm 3 ) was obtained by the following formula.

【0025】[0025]

【数1】 (Equation 1)

【0026】排尿処理成形物1は、尿等の吸水性に優れ
たものであり、その飽和吸水量は2g/1g以上、好ま
しくは5g/1g以上、更に好ましくは8g/1g以上
となっており、その吸水速度は30秒以下、好ましくは
10秒以下、更に好ましくは3秒以下となっている。こ
れにより、排泄された尿による四肢の汚れが効果的に防
止される。尚、飽和吸水量及び吸水速度は何れもその上
限に制限はなく、高いほど好ましいが、実際は飽和吸水
量の上限は5g/1g程度となり、吸水速度の上限は1
秒程度となる。
The urination treated molded article 1 is excellent in water absorption of urine and the like, and has a saturated water absorption of 2 g / 1 g or more, preferably 5 g / 1 g or more, more preferably 8 g / 1 g or more. The water absorption rate is 30 seconds or less, preferably 10 seconds or less, and more preferably 3 seconds or less. As a result, dirt on the extremities due to excreted urine is effectively prevented. The upper limit of each of the saturated water absorption and the water absorption rate is not limited and is preferably as high as possible. However, in practice, the upper limit of the saturated water absorption is about 5 g / 1 g, and the upper limit of the water absorption rate is 1 g / g.
Seconds.

【0027】飽和吸水量は、次の方法により測定され
る。 〈飽和吸水量の測定方法〉排尿処理成形物から、厚みは
そのままで縦60mm、横60mmの試験片を裁断し、
該試験片を105℃に設定した乾燥器内で1時間乾燥さ
せた後、デシケーター内に移して室温まで冷却させた。
その後、DW法を実施する装置として一般的に知られて
いる図2に示す装置(Demand Wettability Tester )を
用い、図2に示す如く、ビュレット内の生理食塩水の液
面を等水位にセットしたガラスフィルター上に該試験片
を載せ、三方活栓を開栓して該試験片に生理食塩水を吸
水させ、気泡が出なくなったときの吸水量(この吸水量
は、生理食塩水の水位の低下量を示すビュレットの目盛
りで測定される)を測定し、この値を試験片の重量で除
した値を飽和吸水量(g/g)とした(n=3の平均
値。試験片1つにつき測定は1回)。
The saturated water absorption is measured by the following method. <Measurement method of saturated water absorption> From the urination treated molded product, a test piece of 60 mm in length and 60 mm in width was cut as it was,
The test piece was dried in a dryer set at 105 ° C. for 1 hour, then transferred to a desiccator and cooled to room temperature.
Thereafter, using a device (Demand Wettability Tester) shown in FIG. 2 which is generally known as a device for performing the DW method, the liquid level of the physiological saline in the burette was set at an equal water level as shown in FIG. Place the test piece on a glass filter, open the three-way stopcock and allow the test piece to absorb physiological saline, and the amount of water absorbed when air bubbles no longer appear (this water absorption is the decrease in the level of saline water). (Measured on a buret scale indicating the amount), and this value was divided by the weight of the test piece to obtain a saturated water absorption (g / g) (average value of n = 3; per test piece) One measurement).

【0028】吸水速度は、次の方法により測定される。 〈吸水速度の測定方法〉排尿処理成形物から、厚みはそ
のままで縦60mm、横60mmの試験片を裁断し、該
試験片を105℃に設定した乾燥器内で1時間乾燥させ
た後、デシケーター内に移して室温まで冷却させた。該
試験片の中央に2.5ccの生理食塩水を滴下し、滴下
直後から水滴が試験片に吸収されるまでの時間を測定
し、これを吸水速度(秒)とした(n=3の平均値。試
験片1つにつき測定は1回)。
The water absorption rate is measured by the following method. <Method of measuring water absorption rate> A test piece having a length of 60 mm and a width of 60 mm was cut from the urine-treated product while keeping its thickness, and the test piece was dried for 1 hour in a drier set at 105 ° C, and then desiccator. And allowed to cool to room temperature. 2.5 cc of physiological saline was dropped at the center of the test piece, the time from immediately after dropping until the water drop was absorbed by the test piece was measured, and this was taken as the water absorption rate (second) (average of n = 3). Value, one measurement per specimen).

【0029】排尿処理成形物1は、湿潤強度が49cN
以上、好ましくは98cN以上、更に好ましくは196
cN以上となっている。湿潤強度が前記値以上である排
尿処理成形物は、尿等を吸収して湿潤状態となっても平
板状の形状を維持することができるので取扱い及び廃棄
が容易である。尚、湿潤強度はその上限に制限はなく、
高いほど好ましいが、他の必要強度とのバランスの点か
ら、196cN程度が実際の上限となる。
The urination-treated molded article 1 has a wet strength of 49 cN.
Or more, preferably 98 cN or more, and more preferably 196 or more.
cN or more. A urination-treated molded product having a wet strength not less than the above-mentioned value can maintain a flat shape even when it absorbs urine and the like and becomes wet, so that it is easy to handle and dispose. The upper limit of the wet strength is not limited.
Higher is preferable, but the upper limit is about 196 cN in terms of balance with other required strengths.

【0030】湿潤強度は、次の方法により測定される。 〈湿潤強度の測定方法〉排尿処理成形物から、厚みはそ
のままで縦80mm、横25mmの試験片を裁断し、該
試験片を水に5分間浸漬する。浸漬後、図3に示すよう
に、該試験片を、50mm間隔で設けられた三角柱状の
2つの支持台上に、該試験片の縦方向の中央部が2つの
該支持台間の中央にくるように載置する。その後、プッ
シュプルケージを、該試験片の中心に押しつけ、該試験
片が折れたときのゲージ圧を測定し、これを湿潤強度
(cN)とした(n=3の平均値)。
The wet strength is measured by the following method. <Method of Measuring Wet Strength> A test piece having a length of 80 mm and a width of 25 mm is cut from the urine-treated product while keeping its thickness, and the test piece is immersed in water for 5 minutes. After immersion, as shown in FIG. 3, the test piece was placed on two triangular prism-shaped supports provided at intervals of 50 mm, and the longitudinal center of the test piece was placed at the center between the two supports. Place it so that it fits. Thereafter, the push-pull cage was pressed against the center of the test piece, and the gauge pressure when the test piece was broken was measured, and this was defined as the wet strength (cN) (average value of n = 3).

【0031】前述の嵩密度等の各物性値を満たす排尿処
理成形物とするためには、グランドパルプからなる排尿
吸収基材を用いて、後述する製造方法により製造するこ
とが好ましい。グランドパルプは、剛性の高いリグニン
及び吸水性の高いヘミセルロースをそれぞれ多量に含ん
でいるため、グランドパルプを前記所定量含有する排尿
処理成形物は、通常の化学パルプを含有する排尿処理形
成物と比べて嵩密度が低く、嵩高で厚みがあり、飽和吸
水量及び吸水速度が大きくなる。また、グランドパルプ
自体にある程度の消臭・抗菌効果があるので、グランド
パルプからなる排尿吸収基材に、更に抗菌性のある薬剤
(抗菌剤又は抗菌性を有する界面活性剤)を配合すると
共に、必要に応じて消臭剤を適宜配合すれば、長期間悪
臭が発散せず、衛生的に使用できる排尿処理成形物が得
られる。尚、グランドパルプを用いる場合、その含有量
が多くなると、排尿処理成形物の強度、特に湿潤強度が
低下する傾向があるが、本発明の排尿処理成形物は、前
述の通り繊維間結合剤を前記所定量含有しているので、
実用上十分な強度及び湿潤強度を有している。また、用
いる繊維間結合剤によっては、排尿処理成形物の親水性
が低下して、尿等の吸収性が低下するおそれがあるが、
本発明の排尿処理成形物は、前述の通り界面活性剤を前
記所定量含有しているので、繊維間結合剤を用いること
による親水性の低下が防止されるのみならず、グランド
パルプ本来の吸水能力以上の吸水能力が排尿処理成形物
に付与されて、尿等の吸収性が極めてすぐれたものとな
っている。
In order to obtain a urination-treated product which satisfies the above-mentioned physical properties such as bulk density, it is preferable to produce the urine-absorbing base material made of ground pulp by the following production method. Since the ground pulp contains a large amount of lignin having high rigidity and a large amount of hemicellulose having a high water absorption, a urination treatment molded product containing the predetermined amount of the ground pulp is compared with a urination treatment formed product containing ordinary chemical pulp. Low bulk density, bulky and thick, and high saturated water absorption and water absorption speed. In addition, since the ground pulp itself has a certain degree of deodorant and antibacterial effect, a further antibacterial agent (an antibacterial agent or a surfactant having an antibacterial effect) is added to the urine absorbing and absorbing base material made of the ground pulp. By appropriately blending a deodorant as needed, a urination-treated molded article that does not emit malodor for a long time and can be used hygienically can be obtained. In the case of using the ground pulp, if the content increases, the strength of the urination-treated molded article, particularly the wet strength tends to decrease, but the urination-treated molded article of the present invention uses the interfiber binder as described above. Because it contains the predetermined amount,
It has sufficient strength and wet strength for practical use. Also, depending on the inter-fiber binder used, the hydrophilicity of the urination-treated molded article is reduced, and there is a possibility that the absorbability of urine and the like may be reduced.
Since the urination-treated molded article of the present invention contains the surfactant in the predetermined amount as described above, not only the decrease in hydrophilicity due to the use of the interfiber binder is prevented, but also the original water absorption of the ground pulp. A water absorption capacity higher than the capacity is given to the urine-treated product, so that the urine and the like can be absorbed very well.

【0032】排尿処理成形物1は、乾式、湿式の何れの
製造方法でも製造できる。乾式の製造方法としては、例
えば、排尿吸収基材の原料である植物性繊維等に、界面
活性剤、抗菌剤及び繊維間結合剤であるバインダー等を
混合して混合物とし、該混合物を所定形状の型枠に入れ
てシート状物とし、該シート状物に熱プレス処理を施し
て予備的に脱水させた後、乾燥器等で該シート状物を所
望の含水率になるまで乾燥させる方法が採用できる。そ
の際、熱プレス処理の条件は、嵩密度を前記範囲内と
し、厚みを前記値以上とする観点から、プレス圧力が好
ましくは4〜2400kPa、更に好ましくは10〜1
000kPaであり、プレス温度が好ましくは60〜1
20℃、更に好ましくは20〜105℃であり、プレス
時間が0.5〜20分、更に好ましくは3〜5分であ
る。一方、湿式の製造方法としては、例えば、一般の紙
の製造で行われている長網式抄紙法や円網式抄紙法等が
採用でき、公知の抄紙機が使用できる。湿式の製造方法
では、繊維間結合剤として、前述の如く架橋剤(紙力増
強剤)が好適に用いられる。排尿処理成形物は、特に、
畳の芯材や壁材等として用いられるインシュレーション
ボードの製造方法と同様の方法で製造できる。
The urination-treated molded article 1 can be produced by any of a dry method and a wet method. As a dry production method, for example, a mixture of a vegetable fiber or the like, which is a raw material of the urinary absorption substrate, is mixed with a surfactant, an antibacterial agent, and a binder as an interfiber binder, and the mixture is formed into a predetermined shape. A sheet-shaped material is placed in a mold frame, subjected to a hot press treatment and preliminarily dehydrated, and then dried with a dryer or the like until the sheet-shaped material has a desired moisture content. Can be adopted. At that time, the conditions of the hot press treatment are such that the press pressure is preferably 4 to 2400 kPa, more preferably 10 to 1 from the viewpoint of setting the bulk density within the above range and setting the thickness to the above value or more.
000 kPa, and the pressing temperature is preferably 60 to 1
The temperature is 20 ° C., more preferably 20 to 105 ° C., and the pressing time is 0.5 to 20 minutes, more preferably 3 to 5 minutes. On the other hand, as a wet-type production method, for example, a fourdrinier-type papermaking method or a circular-mesh-type papermaking method, which is performed in general paper production, can be employed, and a known papermaking machine can be used. In the wet production method, a cross-linking agent (paper strength agent) is suitably used as the inter-fiber binder as described above. Urination-treated molded articles are, in particular,
It can be manufactured by the same method as the method of manufacturing an insulation board used as a core material or a wall material of a tatami mat.

【0033】排尿処理成形物1は、例えば、図1に示す
ように、これをトレー2内部の底面に敷き、その上部
に、排尿処理成形物1を物理的に保護するための網目状
の蓋3を被せて、ペット用トイレとして使用できる。こ
の際、排尿処理成形物1は定形物であるので、粒状タイ
プの排尿処理成形物のように粉塵が発生したりせず取扱
いが容易である。また、使用時においては、排尿処理成
形物1は消臭効果が高く、抗菌効果により悪臭の発散を
抑制できるので、該ペット用トイレの設置場所を考慮す
る必要がなく衛生的に使用できる。更に、排尿処理成形
物1は尿等の吸収量が多く吸収性に優れるので、消臭効
果及び抗菌効果が高いことと相俟って、長期間使用する
ことができる。使用後においては、排尿処理成形物1は
湿潤強度が高く、尿等を吸収しても平板形状を維持でき
るので、これをたやすく取り出すことができ、可燃ゴミ
として容易に焼却廃棄できる。
As shown in FIG. 1, for example, the urination-treated molded article 1 is laid on the bottom surface inside the tray 2 and a mesh-shaped lid is provided on the upper part thereof for physically protecting the urination-treated molded article 1. 3 can be used as a pet toilet. At this time, since the urination-treated molded article 1 is a fixed-shaped article, it is easy to handle without generating dust unlike the granular type urination-treated molded article. Further, at the time of use, the urination-treated molded article 1 has a high deodorizing effect and can suppress the emission of offensive odors due to the antibacterial effect, so that it is not necessary to consider the installation location of the pet toilet and can be used hygienically. Further, since the urination-treated molded article 1 has a large amount of absorption of urine and the like and is excellent in absorbability, it can be used for a long time in combination with high deodorizing effect and antibacterial effect. After use, the urination-treated molded article 1 has a high wet strength and can maintain a flat plate shape even when urine or the like is absorbed, so that it can be easily taken out and easily incinerated as combustible waste.

【0034】本発明の排尿処理成形物1は、動物用のみ
ならず人用の排尿処理成形物としても使用できる。ま
た、その使用形態も特に制限されない。
The urination-treated molded article 1 of the present invention can be used not only for animals but also for humans. Further, the usage form is not particularly limited.

【0035】[0035]

【実施例】〔実施例1〜3〕下記の製造方法に従って得
られた排尿処理成形物について、前述した測定方法に従
い、嵩密度、飽和吸水量、吸水速度、湿潤強度及び厚み
の各物性を測定した。各排尿処理成形物における各成分
の含有量及び製造条件と併せて、その結果を下記〔表
1〕に示す。
EXAMPLES [Examples 1 to 3] The physical properties of bulk density, saturated water absorption, water absorption rate, wet strength and thickness of a urine-treated product obtained according to the following production method were measured according to the above-mentioned measurement methods. did. The results are shown in the following [Table 1] together with the content of each component in each urination treated molded article and the production conditions.

【0036】〔排尿処理成形物の製造〕表1に示す量の
SGPに、抗菌性を有する界面活性剤(ラウリルジメチ
ルアミンオキサイドの2%水溶液、商品名「アンヒトー
ル20N」、花王(株)社製)又は界面活性剤(ポリオ
キシエチレンソルビタン脂肪酸エステル、商品名「レオ
ドールTW−L120」、花王(株)社製)及び抗菌剤
(安息香酸ナトリウム、商品名「安息香酸ナトリウ
ム」、(株)状見製薬社製)を表1に示す量添加し、ヘ
ンシェルミキサーで混合した後、繊維間結合剤としてバ
インダー(タピオカデンプン、商品名「Z−100」、
日澱化学社製)を表1に示す量混合して混合物を得た。
該混合物を所定形状の型枠に流し込んで脱水し、シート
状物を得た。該シート状物を、加熱された油圧プレス機
を用いて表1に示す温度、時間及び圧力でプレスした。
その後、該シート状物を、乾燥機を用い105℃で3時
間乾燥して、排尿処理成形物を得た。
[Production of urination-treated molded article] An amount of SGP shown in Table 1 was added to a surfactant having antibacterial properties (a 2% aqueous solution of lauryl dimethylamine oxide, trade name "Amphitol 20N", manufactured by Kao Corporation). ) Or a surfactant (polyoxyethylene sorbitan fatty acid ester, trade name "Reodol TW-L120", manufactured by Kao Corporation) and an antibacterial agent (sodium benzoate, trade name "sodium benzoate", Hitomi Co., Ltd.) Pharmaceutical Co., Ltd.) was added in the amount shown in Table 1 and mixed with a Henschel mixer, and then a binder (tapioca starch, trade name "Z-100",
Was mixed together in the amounts shown in Table 1 to obtain a mixture.
The mixture was poured into a mold having a predetermined shape and dehydrated to obtain a sheet. The sheet was pressed using a heated hydraulic press at the temperature, time and pressure shown in Table 1.
Thereafter, the sheet was dried using a dryer at 105 ° C. for 3 hours to obtain a urination-treated product.

【0037】〔比較例1〕排尿処理成形物として、市販
のトイレシート(商品名「デオシート」、ユニハートス
社製)を用い、前述した測定方法に従い、飽和吸水量及
び吸水速度の各物性を測定した。その結果を下記〔表
1〕に示す。
[Comparative Example 1] A commercially available toilet sheet (trade name "Deosheet", manufactured by Unihearts) was used as a urination-treated molded article, and the properties of saturated water absorption and water absorption rate were measured in accordance with the above-mentioned measurement methods. . The results are shown in Table 1 below.

【0038】[0038]

【表1】 [Table 1]

【0039】〔吸収性、消臭性及び消臭効果持続性の評
価〕実施例1〜3及び比較例1の各排尿処理成形物につ
いて、下記の〔吸収性の評価基準〕、〔消臭性の評価基
準〕及び〔消臭効果持続性の評価基準〕により評価し
た。結果を下記〔表2〕に示す。
[Evaluation of Absorbency, Deodorant Property, and Persistence of Deodorant Effect] For each of the urination-treated products of Examples 1 to 3 and Comparative Example 1, the following [Evaluation criteria of absorbency], [Deodorant property] Evaluation criteria] and [Evaluation criteria for deodorant effect persistence]. The results are shown in Table 2 below.

【0040】〔吸収性の評価基準〕各排尿処理成形物の
「吸水速度」を、下記評価基準により評価した。評価基準 ◎:吸水速度が3秒以内。 ○:吸水速度が3秒を超え10秒まで。 △:吸水速度が10秒を超え30秒まで。 ×:吸水速度が30秒を超える。
[Evaluation Criteria of Absorbency] The "water absorption rate" of each urination-treated product was evaluated according to the following evaluation criteria. Evaluation criteria :: Water absorption rate is within 3 seconds. :: Water absorption rate exceeds 3 seconds and up to 10 seconds. Δ: Water absorption rate exceeds 10 seconds and up to 30 seconds. X: Water absorption speed exceeds 30 seconds.

【0041】〔消臭性の評価基準〕排尿処理成形物の尿処理 ビーグル犬(メス、8才)から採尿され、冷凍保存され
た尿を解凍した後、該尿5mlを、各排尿処理成形物
(縦50mm、横50mm、厚さ15mm)にメスピペ
ットを用いてふりかけた。その後、該各排尿処理成形物
を、温度25℃、相対湿度65%の環境下に30分間放
置した。評価基準 尿処理直後の各排尿処理成形物の臭いを、被験者3人に
嗅がせ、それぞれ、「無臭」(=1ポイント)、「かす
かに臭う」(=2ポイント)、「やや臭う」(=3ポイ
ント)、「やや強く臭う」(=4ポイント)、「強く臭
う」(=5ポイント)とし、次にこれらのポイントを集
計し、1ポイントを○、2〜3ポイントを△、4〜5ポ
イントを×とした。
[Evaluation Criteria of Deodorizing Property] Urine treatment of urine-treated molded product [0038] After thawing urine collected from a beagle dog (female, 8 years old) and frozen and stored, 5 ml of the urine was treated with each urine-treated molded product. (Length 50 mm, width 50 mm, thickness 15 mm) using a female pipette. Thereafter, each of the urination-treated molded articles was left for 30 minutes in an environment at a temperature of 25 ° C. and a relative humidity of 65%. Evaluation criteria Immediately after the urine treatment, the smell of each urination-treated molded article was smelled by three subjects, and was “odorless” (= 1 point), “slightly smell” (= 2 points), and “slightly smell” (= 3 points), "Slightly smell" (= 4 points), "Strongly smell" (= 5 points), then sum up these points, 1 point is circled, 2-3 points are △, 4-5 The points were marked as x.

【0042】〔消臭効果持続性の評価基準〕前記〔消臭
性の評価基準〕と同様にして尿処理された各排尿処理成
形物の「尿処理直後の臭い」を、被験者3人(各排尿処
理成形物につき1人)に嗅がせた。その後、各排尿処理
成形物を、温度25℃、相対湿度65%の環境下に放置
し、24時間経過毎に、各排尿処理成形物の臭いを同じ
被験者にそれぞれ嗅がせて、被験者が、「尿処理直後の
臭い」と比較して臭いが強くなったと感じたときの尿処
理後からの経過時間をそれぞれ記録し、下記評価基準に
より評価した。 〔評価基準〕 ○:尿処理後3日経過しても臭いの強さが変化しない。 △:尿処理後1日経過しても臭いの強さが変化しない
が、尿処理後3日経過する迄には臭いが強くなる。 ×:尿処理後1日経過する迄に臭いが強くなる。
[Evaluation Criteria of Deodorant Effect Sustainability] The “odor immediately after urine treatment” of each urine-treated molded article subjected to urine treatment in the same manner as in the above “Evaluation Criteria of Deodorant Properties” was evaluated by three subjects (each (One person per urination-treated product) smelled. Thereafter, each of the urination-treated molded articles was left in an environment of a temperature of 25 ° C. and a relative humidity of 65%, and every 24 hours, the same subject was smelled by the same subject every 24 hours. The time elapsed after urine treatment when the odor was felt to be stronger than "odor immediately after urine treatment" was recorded and evaluated according to the following evaluation criteria. [Evaluation criteria] :: The odor intensity does not change even after 3 days from urine treatment. Δ: The odor intensity does not change even after one day from urine treatment, but the odor increases by three days after urine treatment. ×: The odor increases until one day after the urine treatment.

【0043】[0043]

【表2】 [Table 2]

【0044】[0044]

【発明の効果】本発明の排尿処理成形物は、尿等の吸収
性に優れ、消臭効果が高く、取扱い及び廃棄が容易で、
長期間使用可能である。
EFFECTS OF THE INVENTION The urination-treated molded article of the present invention is excellent in absorbing urine and the like, has a high deodorizing effect, is easy to handle and dispose,
It can be used for a long time.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の排尿処理成形物の一使用形態を示す斜
視図である。
FIG. 1 is a perspective view showing one mode of use of a molded article for urination treatment of the present invention.

【図2】本発明の排尿処理成形物の飽和吸水量の測定方
法を示す概略図である。
FIG. 2 is a schematic view showing a method for measuring the saturated water absorption of the urination-treated molded article of the present invention.

【図3】本発明の排尿処理成形物の湿潤強度の測定方法
を示す概略図である。
FIG. 3 is a schematic diagram showing a method for measuring the wet strength of the urination-treated molded article of the present invention.

【符号の説明】[Explanation of symbols]

1 排尿処理成形物 2 トレー 3 蓋 DESCRIPTION OF SYMBOLS 1 Urination molded article 2 Tray 3 Lid

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 植物性繊維又はパルプの少なくとも一種
からなる排尿吸収基材に、抗菌性を有する界面活性剤又
は界面活性剤及び抗菌剤と、バインダー、架橋剤又は水
の少なくとも一種とを混合して得られた混合物を平板状
に成形してなり、嵩密度が0.05〜0.3g/c
3 、飽和吸水量が2g/1g以上、吸水速度が30秒
以下、湿潤強度が49cN以上、厚みが3mm以上であ
る排尿処理成形物。
1. A urinary absorption substrate composed of at least one of vegetable fiber or pulp, and a surfactant having an antibacterial property or a surfactant and an antibacterial agent mixed with at least one of a binder, a crosslinking agent and water. The resulting mixture is formed into a flat plate and has a bulk density of 0.05 to 0.3 g / c.
A urination treated molded product having m 3 , a saturated water absorption of 2 g / 1 g or more, a water absorption rate of 30 seconds or less, a wet strength of 49 cN or more, and a thickness of 3 mm or more.
【請求項2】 前記植物性繊維又は前記パルプが、グラ
ンドパルプ、古紙パルプ又はおが屑であり、該植物性繊
維、該パルプ又はこれらの混合物の含有量が30〜95
重量%である請求項1記載の排尿処理成形物。
2. The vegetable fiber or the pulp is ground pulp, waste paper pulp or sawdust, and the content of the vegetable fiber, the pulp or a mixture thereof is 30 to 95.
The urination-treated molded article according to claim 1, which is in weight%.
【請求項3】 前記抗菌性を有する界面活性剤が、カチ
オン性界面活性剤又は両性界面活性剤であり、該抗菌性
を有する界面活性剤の含有量が0.1〜5重量%である
請求項1又は2記載の排尿処理成形物。
3. The surfactant having an antibacterial property is a cationic surfactant or an amphoteric surfactant, and the content of the surfactant having an antibacterial property is 0.1 to 5% by weight. Item 7. A urination-treated molded article according to Item 1 or 2.
【請求項4】 前記界面活性剤が、非イオン性界面活性
剤であり、前記抗菌剤が、水溶性抗菌剤であり、該界面
活性剤の含有量が0.01〜5重量%であり、該抗菌剤
の含有量が0.001〜5重量%である請求項1又は2
記載の排尿処理成形物。
4. The method according to claim 1, wherein the surfactant is a nonionic surfactant, the antibacterial agent is a water-soluble antibacterial agent, and the content of the surfactant is 0.01 to 5% by weight. The content of the antibacterial agent is 0.001 to 5% by weight.
A urination-treated molded article according to the above.
【請求項5】 前記バインダーが、糊化温度60℃以上
のポリビニルアルコール、糊化温度60℃以上の化工澱
粉又はこれらの混合物であり、該バインダーの含有量が
1〜45重量%である請求項1〜4の何れかに記載の排
尿処理成形物。
5. The binder according to claim 1, wherein the binder is polyvinyl alcohol having a gelatinization temperature of 60 ° C. or higher, a modified starch having a gelatinization temperature of 60 ° C. or higher, or a mixture thereof, and the content of the binder is 1 to 45% by weight. 7. The urination-treated molded article according to any one of 1 to 4.
JP2000398416A 2000-01-14 2000-12-27 Urination treatment molding Expired - Fee Related JP3338700B2 (en)

Priority Applications (1)

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JP2000-5440 2000-01-14
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Country Link
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003153639A (en) * 2001-11-19 2003-05-27 Kao Corp Pet toilet
JP2003527213A (en) * 2000-03-21 2003-09-16 キンバリー クラーク ワールドワイド インコーポレイテッド Super absorbent material with permanent wettability
WO2006080514A1 (en) * 2005-01-31 2006-08-03 Kao Corporation Material for treating excretion of pet
JP2015029495A (en) * 2013-08-06 2015-02-16 花王株式会社 Absorber for pets

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003527213A (en) * 2000-03-21 2003-09-16 キンバリー クラーク ワールドワイド インコーポレイテッド Super absorbent material with permanent wettability
JP2003153639A (en) * 2001-11-19 2003-05-27 Kao Corp Pet toilet
US7128023B2 (en) 2001-11-19 2006-10-31 Kao Corporation Pet toilet
WO2006080514A1 (en) * 2005-01-31 2006-08-03 Kao Corporation Material for treating excretion of pet
US8726839B2 (en) 2005-01-31 2014-05-20 Kao Corporation Material for treating excretion of pet
JP2015029495A (en) * 2013-08-06 2015-02-16 花王株式会社 Absorber for pets

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