JP2001231492A - Mayonnaise-like seasoning - Google Patents
Mayonnaise-like seasoningInfo
- Publication number
- JP2001231492A JP2001231492A JP2000047954A JP2000047954A JP2001231492A JP 2001231492 A JP2001231492 A JP 2001231492A JP 2000047954 A JP2000047954 A JP 2000047954A JP 2000047954 A JP2000047954 A JP 2000047954A JP 2001231492 A JP2001231492 A JP 2001231492A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- mayonnaise
- mass
- seasoning
- medium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Edible Oils And Fats (AREA)
- Seasonings (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は風味良好なマヨネー
ズ様調味料に関する。マヨネーズ様調味料とはマヨネー
ズ及びマヨネーズタイプ調味料を含む。マヨネーズとは
日本農林規格に定めるマヨネーズであり、マヨネーズタ
イプ調味料とはマヨネーズの日本農林規格に入らない
が、風味、外観、物性、使用目的等がマヨネーズに類似
するものである。TECHNICAL FIELD The present invention relates to a mayonnaise-like seasoning having good flavor. The mayonnaise-like seasoning includes mayonnaise and mayonnaise-type seasoning. Mayonnaise is mayonnaise defined in Japanese Agricultural Standards, and mayonnaise-type seasoning does not fit into Japanese Agricultural Standards in mayonnaise, but is similar in flavor, appearance, physical properties, purpose of use, etc. to mayonnaise.
【0002】[0002]
【従来の技術】マヨネーズ様調味料はサラダ料理類をは
じめ各種の料理に用いられ万人に広く好まれており、そ
の風味は主に食用油脂、卵、食酢で構成されている。マ
ヨネーズ様調味料の食用油脂には通常大豆油、菜種油、
紅花油、綿実油、コーン油、ひまわり油、オリーブ油、
胡麻油等の食用油脂が用いられ、食用油脂によるコクあ
るいはマイルド感を得ている。ただし食用油脂にはコク
あるいはマイルドな風味を与える利点がある一方で、マ
ヨネーズ様調味料の様なO/W型乳化物では卵のコク、
風味を味覚及び嗅覚上抑制する難点がある。マヨネーズ
の風味、口溶けを改善するために気泡を含気させたもの
(特開昭48-68778)等があるが、卵のコク、風味と食用
油脂のもたらすコク、マイルド感の両立については検討
されて来なかった。昨今、マヨネーズの原料卵の鮮度が
注目されおり、卵の風味に留意する視点は重要度を増し
ている。マヨネーズタイプ調味料はマヨネーズに比べて
油分を減じて澱粉等で代替するもの(特開平7-31414)
が一般的である。しかし上記マヨネーズと同様の問題点
がある。2. Description of the Related Art Mayonnaise-like seasonings are used in various dishes such as salad dishes and are widely preferred by everyone, and their flavor is mainly composed of edible oils and fats, eggs and vinegar. Edible oils and fats of mayonnaise-like seasoning usually include soybean oil, rapeseed oil,
Safflower oil, cottonseed oil, corn oil, sunflower oil, olive oil,
Edible oils and fats such as sesame oil are used, and the edible oils and fats have a rich or mild feeling. However, edible fats and oils have the advantage of giving a rich or mild flavor, whereas O / W emulsions such as mayonnaise-like seasonings have a rich body of eggs,
There is a problem that taste is suppressed in taste and smell. Mayonnaise flavors and air bubbles are included to improve melting in the mouth (Japanese Patent Application Laid-Open No. 48-68778). Egg richness, flavor and richness of edible oils and fats, and balance of mildness have been studied. Did not come. In recent years, attention has been paid to the freshness of raw egg of mayonnaise, and the viewpoint of paying attention to the flavor of the egg is increasing in importance. Mayonnaise-type seasoning is less oily than mayonnaise and can be replaced with starch etc. (Japanese Patent Laid-Open No. 7-31414)
Is common. However, there is a problem similar to the above mayonnaise.
【0003】[0003]
【発明が解決しようとする課題】本発明は、風味良好
な、特に卵のコクを引き出し、風味と食用油脂のもたら
すコク・マイルド感とのバランスに優れた、風味良好な
マヨネーズ様調味料を提供することに関する。DISCLOSURE OF THE INVENTION The present invention provides a mayonnaise-like seasoning having a good taste, especially a rich flavor of eggs, which is excellent in the balance between the flavor and the richness of the edible oils and fats. About doing.
【0004】[0004]
【発明が解決するための手段】上記目的を達成するため
に、本発明者らは鋭意研究を重ねた結果、食用油脂とし
て中鎖脂肪酸を一定量含有するものを使用することで、
卵のコクが引き立つことを見出し、また、これらと食用
油脂のもたらすコク、マイルド感のバランスのとれたマ
ヨネーズ様調味料が得られることを見出し、本発明を完
成した。すなわち本発明は少なくとも食用油脂、卵黄、
食酢からなり、食用油脂が全体の10〜80質量%であ
り、該食用油脂が主としてトリグリセリドからなる油脂
組成物であって、油脂組成物を構成する全脂肪酸に占め
る中鎖脂肪酸の割合が3〜40質量%であり、全トリグ
リセリドに占める中鎖脂肪酸残基を分子内に1つ以上有
するトリグリセリドの割合が3〜90質量%であり、卵
を卵黄分として全体の3〜20質量%含むことを特徴と
するマヨネーズ様調味料である。また、該中鎖脂肪酸が
炭素数6〜12の飽和脂肪酸であることが好ましい。Means for Solving the Problems In order to achieve the above object, the present inventors have conducted intensive studies and as a result, by using edible oils and fats containing a certain amount of medium-chain fatty acids,
The inventors have found that the richness of eggs is enhanced, and that a canonnaise-like seasoning with a good balance of the richness and mildness of the edible oils and fats and the edible oils and fats can be obtained, thereby completing the present invention. That is, the present invention at least edible oil, egg yolk,
The edible oil / fat is composed of vinegar, the edible oil / fat is 10 to 80% by mass of the whole, and the edible oil / fat is mainly a triglyceride, and the ratio of the medium-chain fatty acid to the total fatty acids constituting the oil / fat composition is 3 to 10%. 40% by mass, the proportion of triglycerides having one or more medium-chain fatty acid residues in the molecule in all triglycerides is 3 to 90% by mass, and the egg contains 3 to 20% by mass as the yolk component. A distinctive mayonnaise-like seasoning. Further, it is preferable that the medium-chain fatty acid is a saturated fatty acid having 6 to 12 carbon atoms.
【0005】[0005]
【発明の実施の形態】以下、本発明を詳しく説明する。
本発明は食用油脂に中鎖脂肪酸を含む風味良好な、特に
卵のコク、風味と食用油脂のもたらすコク、マイルド感
の両立したマヨネーズ様調味料を提供することに関す
る。本発明のマヨネーズ様調味料は少なくとも食用油
脂、卵黄、食酢からなる。食用油脂は全体の10〜80
質量%であり、該食用油脂が主としてトリグリセリドか
らなる油脂組成物である。「主として」は、油脂組成物
中に、トリグリセリドが85質量%以上、好ましくは9
5質量%以上含まれていることを意味するものとする。
本発明で中鎖脂肪酸とは炭素数が6〜12の脂肪酸、特
に飽和脂肪酸が好ましい。例としては、カプロン酸、カ
プリル酸、カプリン酸、ラウリン酸が挙げられ、炭素数
が8〜10の飽和脂肪酸、特にカプリル酸およびカプリ
ン酸が好ましい。脂肪酸残基は脂肪酸からカルボキシル
基のOHを取った基である。本発明のマヨネーズ様調味
料においては、食用油脂を構成する全脂肪酸に占める中
鎖脂肪酸の割合が3〜40質量%で、かつ全トリグリセ
リドに占める、中鎖脂肪酸残基を分子内に1つ以上有す
るトリグリセリドの割合が3〜90質量%であることが
必要である。中鎖脂肪酸の割合と中鎖脂肪酸残基を分子
内に1つ以上有するトリグリセリドの割合がこの範囲外
では卵黄のコク・うまみを引き立たせ、これらと食用油
脂のもたらすコク・マイルド感の両立という特長が生じ
ない。また、食用油脂を構成する全脂肪酸に占める中鎖
脂肪酸の割合は3〜40質量%、好ましくは4〜30質
量%、さらに好ましくは5〜25質量%である。全トリ
グリセリドに占める、中鎖脂肪酸残基を分子内に1つ以
上有するトリグリセリドの割合は3〜90質量%、好ま
しくは5〜80質量%、さらに好ましくは7〜75質量
%である。繰り返しになるが食用油脂は全体の10〜8
0質量%である。10質量%以下では食用油脂のもたら
すコク、マイルド感が得られず、80質量%以上ではマ
ヨネーズ様調味料の風味が油っぽくなり過ぎ、卵黄のう
まみが引き立たないので好ましくない。また、食用油脂
は全体に対して好ましくは15〜75質量%であり、さ
らに好ましくは20〜70質量%である。また、本発明
のマヨネーズ様調味料は卵を必須としてその卵黄分は全
体の3〜20質量%である。卵は全卵、卵黄の1種また
は2種以上、およびこれらと卵白を組み合わせたものを
使用することができる。卵黄分は全体の3〜20質量
%、好ましくは5〜19質量%、さらに好ましくは10
〜18質量%である。本発明のマヨネーズ様調味料の食
用油脂は、原料油脂と中鎖脂肪酸とを適宜混合した後、
ナトリウムメチラートを触媒としてまたは脂質分解酵素
の存在下にエステル交換反応を行い、この際に、油脂組
成物を構成する全脂肪酸に占める中鎖脂肪酸の割合、お
よび全トリグリセリドに占める、中鎖脂肪酸残基を分子
内に1つ以上有するトリグリセリドの割合が前記特定範
囲内に入るようにエステル交換反応を調整することによ
り得ることができる。原料油脂としては、通常の食用油
脂、例えば大豆油、菜種油、高オレイン酸菜種油、コー
ン油、ゴマ油、ゴマサラダ油、シソ油、亜麻仁油、落花
生油、紅花油、高オレイン酸紅花油、ひまわり油、高オ
レイン酸ひまわり油、綿実油、ブドウ種油、マカデミア
ナッツ油、ヘーゼルナッツ油、カボチャ種子油、クルミ
油、椿油、茶実油、エゴマ油、ボラージ油、オリーブ
油、米糠油、小麦胚芽油、パーム油、パーム核油、ヤシ
油、カカオ脂、牛脂、ラード、鶏脂、乳脂、魚油、アザ
ラシ油、藻類油、品質改良によって低飽和化されたこれ
らの油脂およびこれらの水素添加油脂、分別油脂等が挙
げられる。中鎖脂肪酸についてはすでに記述したが、中
鎖脂肪酸に代えてまたはこれと共に中鎖脂肪酸トリグリ
セリドを用いることもできる。中鎖脂肪酸トリグリセリ
ドとしては、前記中鎖脂肪酸とグリセリンとを常法によ
りエステル化反応に付して得られるトリグリセリドを用
いることができるが、一般にMCT(MediumCh
ain Triglycerides)と称せられる、
ヤシ油分解脂肪酸等の炭素数が8〜10の飽和脂肪酸か
ら構成される単酸基もしくは混酸基トリグリセリド、例
えばカプリル酸/カプリン酸=60/40〜75/25
(質量比)のトリグリセリドが好適に使用できる。油脂
組成物を構成する全脂肪酸に占める中鎖脂肪酸の割合、
および全トリグリセリドに占める、中鎖脂肪酸残基を分
子内に1つ以上有するトリグリセリドの割合は原料油脂
組成を勘案し、原料油脂と中鎖脂肪酸との使用比率を調
整し、エステル交換反応中の反応生成物のトリグリセリ
ド組成を測定することによって調整できる。ここで、卵
のコク、風味とは主に卵黄に由来する旨味と濃厚感を指
している。食用油脂のもたらすコク、マイルド感とは油
脂に独特の旨味と滑らかなテクスチャーである。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail.
The present invention relates to providing a mayonnaise-like seasoning having good flavor, particularly rich in eggs, rich in flavor and edible oils and fats, and having a mild feeling, in which the edible fat contains medium-chain fatty acids. The mayonnaise-like seasoning of the present invention comprises at least edible oil and fat, egg yolk, and vinegar. Edible fats and oils are 10-80
% By mass, and the edible oil / fat is an oil / fat composition mainly consisting of triglycerides. "Mainly" means that the oil composition contains 85% by mass or more of triglyceride, preferably 9% by mass.
It means that the content is 5% by mass or more.
In the present invention, the medium-chain fatty acid is preferably a fatty acid having 6 to 12 carbon atoms, particularly a saturated fatty acid. Examples include caproic acid, caprylic acid, capric acid, lauric acid, with saturated fatty acids having 8 to 10 carbon atoms being preferred, especially caprylic acid and capric acid. A fatty acid residue is a group obtained by removing the OH of a carboxyl group from a fatty acid. In the mayonnaise-like seasoning of the present invention, the ratio of the medium-chain fatty acid in the total fatty acids constituting the edible fat and oil is 3 to 40% by mass, and one or more medium-chain fatty acid residues in the whole triglyceride are included in the molecule. It is necessary that the proportion of triglycerides to be contained is 3 to 90% by mass. If the proportion of medium-chain fatty acids and the proportion of triglycerides having one or more medium-chain fatty acid residues in the molecule are out of this range, the yolk's richness and umami will be enhanced, and the richness and mildness of edible fats and oils will be achieved. Does not occur. The ratio of the medium-chain fatty acid to the total fatty acids constituting the edible fat is 3 to 40% by mass, preferably 4 to 30% by mass, and more preferably 5 to 25% by mass. The proportion of triglycerides having one or more medium-chain fatty acid residues in the molecule in the total triglycerides is 3 to 90% by mass, preferably 5 to 80% by mass, and more preferably 7 to 75% by mass. Again, edible oils and fats are 10-8 of the whole
0% by mass. If it is less than 10% by mass, the richness and mildness of the edible fats and oils cannot be obtained, and if it is more than 80% by mass, the flavor of the mayonnaise-like seasoning becomes too oily and the taste of the egg yolk is unfavorable. The edible oil / fat is preferably 15 to 75% by mass, more preferably 20 to 70% by mass, based on the whole. In addition, the mayonnaise-like seasoning of the present invention requires an egg, and the yolk content thereof is 3 to 20% by mass of the whole. Eggs may be whole eggs, one or more egg yolks, or a combination of these and egg whites. The yolk content is 3 to 20% by mass, preferably 5 to 19% by mass, more preferably 10% by mass.
1818% by mass. Edible fats and oils of the mayonnaise-like seasoning of the present invention, after appropriately mixing the raw fats and oils and medium-chain fatty acids,
A transesterification reaction is carried out using sodium methylate as a catalyst or in the presence of a lipolytic enzyme. At this time, the proportion of medium-chain fatty acids in the total fatty acids constituting the fat and oil composition and the medium-chain fatty acid residues in the total triglycerides are determined. It can be obtained by adjusting the transesterification reaction so that the proportion of triglycerides having one or more groups in the molecule falls within the above specific range. As raw material fats and oils, normal edible fats and oils, for example, soybean oil, rapeseed oil, high oleic rapeseed oil, corn oil, sesame oil, sesame salad oil, perilla oil, linseed oil, peanut oil, safflower oil, high oleic safflower oil, sunflower oil, High oleic sunflower oil, cottonseed oil, grape seed oil, macadamia nut oil, hazelnut oil, pumpkin seed oil, walnut oil, camellia oil, teaseed oil, sesame oil, borage oil, olive oil, rice bran oil, wheat germ oil, palm oil, palm Kernel oil, coconut oil, cocoa butter, beef tallow, lard, chicken fat, milk fat, fish oil, seal oil, algal oil, these fats and oils which have been low-saturated by quality improvement and their hydrogenated fats, fractionated fats and the like. . Although medium chain fatty acids have already been described, medium chain fatty acid triglycerides can be used in place of or with medium chain fatty acids. As the medium-chain fatty acid triglyceride, triglyceride obtained by subjecting the above-mentioned medium-chain fatty acid and glycerin to an esterification reaction by a conventional method can be used. Generally, MCT (Medium Ch) is used.
ain Triglycerides)
Mono- or mixed-acid triglycerides composed of saturated fatty acids having 8 to 10 carbon atoms such as coconut oil-decomposed fatty acids, for example, caprylic acid / capric acid = 60/40 to 75/25.
(Mass ratio) triglyceride can be suitably used. Ratio of medium-chain fatty acids in the total fatty acids constituting the oil and fat composition,
The ratio of triglycerides having one or more medium-chain fatty acid residues in the molecule to the total triglycerides is adjusted in consideration of the composition of the raw material fats and oils, and the reaction ratio during the transesterification reaction is adjusted by adjusting the ratio of the raw material fats and medium-chain fatty acids used. It can be adjusted by measuring the triglyceride composition of the product. Here, the richness and flavor of the egg refer to the umami and richness mainly derived from the yolk. The richness and mildness of the edible fats and oils is the unique taste and smooth texture of the fats and oils.
【0006】本発明のマヨネーズ様調味料は少なくとも
食用油脂、卵黄、食酢からなる。食用油脂が一定量含ま
れ、中鎖脂肪酸が一定量含まれることにより、卵黄のコ
ク・うまみ等が引き立った、また、食用油脂によるマイ
ルド感等のバランスのとれた、風味が良好なマヨネーズ
様調味料が得られる。[0006] The mayonnaise-like seasoning of the present invention comprises at least edible oil, fat, egg yolk and vinegar. A certain amount of edible oils and fats and a certain amount of medium-chain fatty acids enhance the richness and umami of egg yolks, and have a good mayonnaise-like flavor with a good balance of mildness, etc. due to edible oils and fats Fees are obtained.
【0007】本発明のマヨネーズ様調味料においては、
食用油脂は全体の10〜80質量%、好ましくは15〜
75質量%、さらに好ましくは20〜70質量%であ
る。10質量%以下では食用油脂のもたらすコク、マイ
ルド感が得られないので好ましくなく、80質量%以上
ではマヨネーズ様調味料の風味が油っぽくなり過ぎ、卵
黄のうまみが引き立たないので好ましくない。該食用油
脂が主としてトリグリセリドからなる油脂組成物であ
る。「主として」は、油脂組成物中に、トリグリセリド
が85質量%以上、好ましくは95質量%以上含まれて
いることを意味するものとする。[0007] In the mayonnaise-like seasoning of the present invention,
The edible oil / fat is 10 to 80% by mass, preferably 15 to 80% by mass.
It is 75% by mass, more preferably 20 to 70% by mass. If it is less than 10% by mass, the richness and mildness of the edible oils and fats cannot be obtained, and if it is more than 80% by mass, the flavor of the mayonnaise-like seasoning becomes too greasy and the flavor of the egg yolk is unfavorable. The edible oil / fat is an oil / fat composition mainly comprising triglycerides. "Mainly" shall mean that the fat or oil composition contains 85% by mass or more, preferably 95% by mass or more of triglyceride.
【0008】上記中鎖脂肪酸を含むことで本発明の効果
を得ることができ、通常の長鎖脂肪酸からなる食用油脂
等と比べて、卵のコク等について向上されている。短鎖
脂肪酸を一定量含む場合については、独特の異臭がする
場合が多く、マヨネーズ様調味料全体の風味を考えると
好ましいとはいえない。本発明で中鎖脂肪酸とは炭素数
が6〜12の脂肪酸、特に飽和脂肪酸が好ましい。例と
しては、カプロン酸、カプリル酸、カプリン酸、ラウリ
ン酸が挙げられ、炭素数が8〜10の飽和脂肪酸、特に
カプリル酸およびカプリン酸が好ましい。脂肪酸残基は
脂肪酸からカルボキシル基のOHを取った基である。中
鎖脂肪酸はヤシ油、パーム核油等に含まれ分解、蒸留に
より得ることが出来る。また、その機能として体脂肪蓄
積抑制、エネルギー消費の増加、腹持ち効果、血中脂質
低下、インシュリン分泌促進、カルシウム吸収促進、ビ
タミンE吸収促進等が知られている。[0008] The effects of the present invention can be obtained by containing the above-mentioned medium-chain fatty acid, and the richness of eggs and the like are improved as compared with edible oils and fats composed of ordinary long-chain fatty acids. When a certain amount of a short-chain fatty acid is contained, a peculiar off-flavor often occurs, which is not preferable in consideration of the flavor of the whole mayonnaise-like seasoning. In the present invention, the medium-chain fatty acid is preferably a fatty acid having 6 to 12 carbon atoms, particularly a saturated fatty acid. Examples include caproic acid, caprylic acid, capric acid, lauric acid, with saturated fatty acids having 8 to 10 carbon atoms being preferred, especially caprylic acid and capric acid. A fatty acid residue is a group obtained by removing the OH of a carboxyl group from a fatty acid. Medium chain fatty acids are contained in coconut oil, palm kernel oil and the like, and can be obtained by decomposition and distillation. Further, its functions are known to suppress body fat accumulation, increase energy consumption, increase abdominal effect, lower blood lipids, promote insulin secretion, promote calcium absorption, promote vitamin E absorption, and the like.
【0009】本発明のマヨネーズ様調味料においては、
食用油脂を構成する全脂肪酸に占める中鎖脂肪酸の割合
が3〜40質量%で、かつ全トリグリセリドに占める、
中鎖脂肪酸残基を分子内に1つ以上有するトリグリセリ
ドの割合が3〜90質量%であることが必要である。中
鎖脂肪酸の割合と中鎖脂肪酸残基を分子内に1つ以上有
するトリグリセリドの割合がこの範囲外では、卵黄のコ
ク・うまみを引き立たせることができず、また、これら
と食用油脂のもたらすコク・マイルド感の両立という特
長が生じない。食用油脂を構成する全脂肪酸に占める中
鎖脂肪酸の割合は3〜40質量%、好ましくは4〜30
質量%、さらに好ましくは5〜25質量%である。全ト
リグリセリドに占める、中鎖脂肪酸残基を分子内に1つ
以上有するトリグリセリドの割合は3〜90質量%、好
ましくは5〜80質量%、さらに好ましくは7〜70質
量%である。また、全トリグリセリドに占める、中鎖脂
肪酸残基を分子内に1つまたは2つ有するトリグリセリ
ドの割合は3〜85質量%、好ましくは5〜75質量
%、さらに好ましくは7〜65質量%である。さらに
は、全トリグリセリドに占める、中鎖脂肪酸残基を分子
内に2つ有するトリグリセリドの割合は1〜40質量
%、好ましくは2〜30質量%、さらに好ましくは3〜
20質量%である。In the mayonnaise-like seasoning of the present invention,
The proportion of medium-chain fatty acids in the total fatty acids constituting the edible fats and oils is 3 to 40% by mass, and accounts for all the triglycerides.
It is necessary that the proportion of triglycerides having one or more medium-chain fatty acid residues in the molecule is 3 to 90% by mass. If the proportion of medium-chain fatty acids and the proportion of triglycerides having one or more medium-chain fatty acid residues in the molecule are outside these ranges, the richness and umami of egg yolk cannot be enhanced, and the richness of edible fats and oils cannot be achieved.・ The feature of achieving a mild feeling does not occur. The ratio of the medium-chain fatty acid to the total fatty acids constituting the edible oil and fat is 3 to 40% by mass, preferably 4 to 30% by mass.
%, More preferably 5 to 25% by mass. The proportion of triglycerides having one or more medium-chain fatty acid residues in the molecule in all triglycerides is 3 to 90% by mass, preferably 5 to 80% by mass, and more preferably 7 to 70% by mass. The proportion of triglycerides having one or two medium-chain fatty acid residues in the molecule is 3 to 85% by mass, preferably 5 to 75% by mass, and more preferably 7 to 65% by mass of all triglycerides. . Furthermore, the proportion of triglycerides having two medium-chain fatty acid residues in the molecule in the total triglycerides is 1 to 40% by mass, preferably 2 to 30% by mass, more preferably 3 to 30% by mass.
20% by mass.
【0010】ここで、トリグリセリドを構成する脂肪酸
で中鎖脂肪酸以外の脂肪酸は、主に長鎖脂肪酸である
が、これらについては特に制限はないが、C16〜C1
8の場合が好ましく、さらに不飽和が多く含まれている
ことが好ましく、特にオレイン酸18:1(9)、リノ
ール酸18:2(9,12)が一定量含まれている場合
が好ましい。Here, the fatty acids constituting the triglycerides other than the medium-chain fatty acids are mainly long-chain fatty acids, and these are not particularly limited.
8 is preferable, and it is preferable that a large amount of unsaturation is further contained, and it is particularly preferable that oleic acid 18: 1 (9) and linoleic acid 18: 2 (9, 12) are contained in a certain amount.
【0011】本発明のマヨネーズ様調味料の食用油脂
は、原料油脂と中鎖脂肪酸とを適宜混合した後、ナトリ
ウムメチラートを触媒としてまたは脂質分解酵素の存在
下にエステル交換反応を行い、この際に、油脂組成物を
構成する全脂肪酸に占める中鎖脂肪酸の割合、および全
トリグリセリドに占める、中鎖脂肪酸残基を分子内に1
つ以上有するトリグリセリドの割合が前記特定範囲内に
入るようにエステル交換反応を調整することにより得る
ことができる。The edible fat or oil of the mayonnaise-like seasoning of the present invention is prepared by appropriately mixing a raw fat and oil with a medium-chain fatty acid and then subjecting it to a transesterification reaction using sodium methylate as a catalyst or in the presence of a lipolytic enzyme. The ratio of medium-chain fatty acids in the total fatty acids constituting the oil and fat composition and the medium-chain fatty acid residues in the total triglycerides in the molecule is 1%.
It can be obtained by adjusting the transesterification reaction so that the ratio of triglycerides having two or more triglycerides falls within the above specific range.
【0012】ナトリウムメチラートを触媒とするエステ
ル交換反応を行う場合、原料油脂と中鎖脂肪酸もしくは
中鎖脂肪酸トリグリセリドとを脂肪酸の質量で前者/後
者の質量比=60/40〜97/3で混合し、混合物を
100mmHg以下の減圧下で80〜120℃に加熱
し、原料混合物に含まれる気体成分および水分を除去す
る。これにナトリウムメチラート0.02〜0.5質量
%を添加し、常圧・窒素気流下あるいは10mmHg以
下の減圧下で10〜60分間、80〜120℃で攪拌す
ることによりエステル交換反応を行う。エステル交換反
応の率はガスクロマトグラフィーにより反応生成物のト
リグリセリド組成を測定することにより確認する。反応
の停止は反応生成物に水を添加するかリン酸などの酸を
添加することにより行う。その後、触媒および過剰の酸
を除去するために十分な水洗を行い、乾燥後、反応生成
物を常法により脱色、脱臭する。When a transesterification reaction is carried out using sodium methylate as a catalyst, the raw fat and oil and medium-chain fatty acid or medium-chain fatty acid triglyceride are mixed in the former / latter mass ratio of fatty acids = 60 / 40-97 / 3. Then, the mixture is heated to 80 to 120 ° C. under reduced pressure of 100 mmHg or less to remove gas components and moisture contained in the raw material mixture. To this, 0.02 to 0.5% by mass of sodium methylate is added, and the ester exchange reaction is carried out by stirring at 80 to 120 ° C. for 10 to 60 minutes under normal pressure and nitrogen stream or under reduced pressure of 10 mmHg or less. . The transesterification rate is confirmed by measuring the triglyceride composition of the reaction product by gas chromatography. The reaction is stopped by adding water or an acid such as phosphoric acid to the reaction product. Thereafter, washing is carried out sufficiently to remove the catalyst and excess acid, and after drying, the reaction product is decolorized and deodorized by a conventional method.
【0013】脂質分解酵素を用いてエステル交換反応を
行う場合、原料油脂と中鎖脂肪酸もしくは中鎖脂肪酸ト
リグリセリドとを脂肪酸の質量で前者/後者の質量比=
60/40〜97/3で混合し、脂質分解酵素の活性が
十分に発揮される反応温度である40〜100℃の範囲
に調温する。これに脂質分解酵素を原料混合物に対して
0.005〜10質量%の割合で添加し、2〜48時間
の範囲でエステル交換反応を行う。この反応は常圧下で
窒素気流中で行うことが望ましい。求める油相部の品質
に応じ、また、酵素の寿命等を含む製造コストを考慮
し、エステル交換反応率を好適に調整することもでき
る。エステル交換反応の完了はガスクロマトグラフィー
により反応生成物のトリグリセリド組成を測定すること
により確認する。反応の停止は酵素を濾過により除去す
ることにより行う。反応生成物は水洗、乾燥の後、常法
により脱色、脱臭する。なお、中鎖脂肪酸を使用した場
合は、反応の停止後に遊離脂肪酸を薄膜式エバポレータ
ーで除去しておく。When a transesterification reaction is carried out using a lipolytic enzyme, the raw material fat and the medium-chain fatty acid or medium-chain fatty acid triglyceride are expressed by the mass ratio of the former to the latter in terms of the mass of the fatty acid =
The mixture is mixed at 60/40 to 97/3, and the temperature is adjusted to the range of 40 to 100 ° C., which is the reaction temperature at which the activity of the lipolytic enzyme is sufficiently exhibited. To this, a lipolytic enzyme is added at a ratio of 0.005 to 10% by mass based on the raw material mixture, and a transesterification reaction is performed for a period of 2 to 48 hours. This reaction is desirably carried out in a nitrogen stream at normal pressure. The transesterification rate can also be suitably adjusted according to the quality of the oil phase required and in consideration of the production cost including the life of the enzyme. Completion of the transesterification reaction is confirmed by measuring the triglyceride composition of the reaction product by gas chromatography. The reaction is stopped by removing the enzyme by filtration. The reaction product is washed with water, dried, and then decolorized and deodorized by a conventional method. When a medium-chain fatty acid is used, free fatty acids are removed by a thin-film evaporator after the reaction is stopped.
【0014】ここで、エステル交換反応、精製等の過程
で中鎖脂肪酸の含量が低減することもあることから、上
記よりも多めに配合することで、最終状態の含量を好適
な範囲に調整することもできる。Here, the content of the medium-chain fatty acid may be reduced in the course of transesterification, purification, etc., so that the content in the final state is adjusted to a suitable range by blending more than the above. You can also.
【0015】脂質分解酵素としては、アルカリゲネス
属、キャンデイダ属、リゾプス属、ムコール属またはシ
ュードモナス属由来のリパーゼや、肝臓由来のホスホリ
パーゼA等が挙げられるが、特にキャンデイダ属または
リゾプス属由来のリパーゼが好ましい。Examples of the lipolytic enzyme include lipases derived from genus Alcaligenes, Candida, Rhizopus, Mucor or Pseudomonas, and phospholipase A derived from liver, and lipases derived from Candida or Rhizopus are particularly preferred. .
【0016】原料油脂としては、通常の食用油脂、例え
ば大豆油、菜種油、高オレイン酸菜種油、コーン油、ゴ
マ油、ゴマサラダ油、シソ油、亜麻仁油、落花生油、紅
花油、高オレイン酸紅花油、ひまわり油、高オレイン酸
ひまわり油、綿実油、ブドウ種油、マカデミアナッツ
油、ヘーゼルナッツ油、カボチャ種子油、クルミ油、椿
油、茶実油、エゴマ油、ボラージ油、オリーブ油、米糠
油、小麦胚芽油、パーム油、パーム核油、ヤシ油、カカ
オ脂、牛脂、ラード、鶏脂、乳脂、魚油、アザラシ油、
藻類油、品質改良によって低飽和化されたこれらの油脂
およびこれらの水素添加油脂、分別油脂等が挙げられ
る。本発明のマヨネーズ様調味料の食用油脂の油脂組成
物は、また、遺伝子組換えの技術を用いて、本発明の油
脂組成物を生産するように品種改良した植物、例えば大
豆、菜種、コーン、ヤシ、パーム、オリーブ、亜麻仁、
ひまわり、紅花、つばき、綿実、クヘアから抽出によっ
て得ることも可能である。The raw fats and oils include ordinary edible fats and oils such as soybean oil, rapeseed oil, high oleic rapeseed oil, corn oil, sesame oil, sesame salad oil, perilla oil, linseed oil, peanut oil, safflower oil, high oleic safflower oil, Sunflower oil, high oleic sunflower oil, cottonseed oil, grape seed oil, macadamia nut oil, hazelnut oil, pumpkin seed oil, walnut oil, camellia oil, teaseed oil, perilla oil, borage oil, olive oil, rice bran oil, wheat germ oil, palm Oil, palm kernel oil, coconut oil, cocoa butter, tallow, lard, chicken fat, milk fat, fish oil, seal oil,
Algae oils, these fats and oils which have been made less saturated by quality improvement, hydrogenated fats and oils, and fractionated fats and oils are exemplified. The oil and fat composition of the edible oil and fat of the mayonnaise-like seasoning of the present invention is also a plant breeded to produce the oil and fat composition of the present invention using a genetic recombination technique, for example, soybean, rapeseed, corn, Palms, palms, olives, linseed,
It can also be obtained by extraction from sunflowers, safflowers, camellia, cottonseed, and hair.
【0017】中鎖脂肪酸についてはすでに記述したが、
中鎖脂肪酸に代えてまたはこれと共に中鎖脂肪酸トリグ
リセリドを用いることもできる。中鎖脂肪酸トリグリセ
リドとしては、前記中鎖脂肪酸とグリセリンとを常法に
よりエステル化反応に付して得られるトリグリセリドを
用いることができるが、一般にMCT(MediumC
hain Triglycerides)と称せられ
る、ヤシ油分解脂肪酸等の炭素数が8〜10の飽和脂肪
酸から構成される単酸基もしくは混酸基トリグリセリ
ド、例えばカプリル酸/カプリン酸=60/40〜75
/25(質量比)のトリグリセリドが好適に使用でき
る。油脂組成物を構成する全脂肪酸に占める中鎖脂肪酸
の割合、および全トリグリセリドに占める、中鎖脂肪酸
残基を分子内に1つ以上有するトリグリセリドの割合は
原料油脂組成を勘案し、原料油脂と中鎖脂肪酸との使用
比率を調整し、エステル交換反応中の反応生成物のトリ
グリセリド組成を測定することによって調整できる。Although the medium-chain fatty acids have already been described,
Medium chain fatty acid triglycerides can be used instead of or together with medium chain fatty acids. As the medium-chain fatty acid triglyceride, triglyceride obtained by subjecting the above-mentioned medium-chain fatty acid and glycerin to an esterification reaction by a conventional method can be used, and generally, MCT (Medium C)
triglycerides, which are composed of saturated fatty acids having 8 to 10 carbon atoms such as coconut oil-decomposed fatty acids, such as caprylic acid / capric acid = 60 / 40-75.
/ 25 (mass ratio) triglyceride can be suitably used. The proportion of medium-chain fatty acids in the total fatty acids constituting the fat and oil composition, and the proportion of triglycerides having one or more medium-chain fatty acid residues in the molecule in all triglycerides are determined in consideration of the composition of the raw fats and oils, and The ratio can be adjusted by adjusting the use ratio with the chain fatty acid and measuring the triglyceride composition of the reaction product during the transesterification reaction.
【0018】また、本発明のマヨネーズ様調味料の食用
油脂は上記に列挙したようなエステル交換によって得ら
れた油脂組成物と原料油脂とを適宜混合して所望の中鎖
脂肪酸含量とトリグリセライド組成を得ることができ
る。同様に原料油脂とMCTとを単純に適宜混合するこ
とによって得ることもできるが上記に列挙したようにエ
ステル交換を行うことにより中鎖脂肪酸残基を分子内に
1つまたは2つ有するトリグリセリドが含まれる方がよ
り食用油脂のもたらすコク、マイルド感が好適に得られ
る。The edible fat of the mayonnaise-like seasoning of the present invention is prepared by appropriately mixing the fat composition obtained by transesterification and the raw fat as described above to obtain the desired medium-chain fatty acid content and triglyceride composition. Obtainable. Similarly, triglycerides having one or two medium-chain fatty acid residues in the molecule can be obtained by transesterification as described above by simply appropriately mixing the raw material fat and MCT with MCT. The more rich the edible oils and fats, the better the feeling of mildness.
【0019】また、本発明のマヨネーズ様調味料は卵を
必須としてその卵黄分は全体の3〜20質量%である。
卵は全卵、卵黄の1種または2種以上、およびこれらと
卵白を組み合わせたものを使用することができる。本発
明において卵黄分は全体の3〜20質量%、好ましくは
5〜19質量%、さらに好ましくは10〜18質量%で
ある。一般に、卵黄の成分は約50%が水分、約30%
が脂質、約15%がたん白質であり、マヨネーズ様調味
料における卵黄の働きは乳化作用、風味への影響、色調
への影響である。乳化作用は親水性のレシチンやケファ
リンと親油性のステロール類が卵黄中に共存することに
よって生じる。風味への影響は脂質とたん白質による独
特の旨味と食酢への緩衝作用を示し酸味をマイルドにす
ることが主なものである。色調への影響はマヨネーズ様
調味料の呈する淡黄色が卵黄に由来することである。In addition, the mayonnaise-like seasoning of the present invention requires an egg and its yolk content is 3 to 20% by mass of the whole.
Eggs may be whole eggs, one or more egg yolks, or a combination of these and egg whites. In the present invention, the yolk content is 3 to 20% by mass, preferably 5 to 19% by mass, and more preferably 10 to 18% by mass. Generally, the yolk component is about 50% water and about 30%
Is a lipid, and about 15% is a protein. The action of egg yolk in a mayonnaise-like seasoning is an emulsifying effect, an effect on flavor, and an effect on color tone. The emulsifying action is caused by the coexistence of hydrophilic lecithin and kephalin and lipophilic sterols in egg yolk. The main effect of flavor is to show a unique umami by lipids and proteins and a buffering effect on vinegar to make the acidity mild. The effect on color tone is that the pale yellow color of the mayonnaise-like seasoning is derived from egg yolk.
【0020】卵のコク、風味とは主に卵黄に由来する旨
味と濃厚感を指している。食用油脂のもたらすコク、マ
イルド感とは油脂に独特の旨味と滑らかなテクスチャー
である。The richness and flavor of eggs refer to umami and richness mainly derived from egg yolk. The richness and mildness of the edible fats and oils is the unique taste and smooth texture of the fats and oils.
【0021】本発明でいうマヨネーズ様調味料は主とし
てサラダ料理類に使用される半固体状調味料であり、マ
ヨネーズ及びマヨネーズタイプ調味料を含む。マヨネー
ズとは日本農林規格に定めるマヨネーズであり、マヨネ
ーズタイプ調味料とはマヨネーズの日本農林規格に入ら
ないが、風味、外観、物性、使用目的等がマヨネーズに
類似するものである。日本農林規格に定めるマヨネーズ
とは半固体状のドレッシングのうち、油脂が65%以上
であり、卵黄又は全卵を使用し、かつ、必須原材料、卵
黄、卵白、たん白加水分解物、食塩、糖類、香辛料、調
味料(アミノ酸等)及び酸味料以外の原材料を使用して
いないものをいう。半固体状のドレッシングとはドレッ
シングのうち粘度が30,000Pa・s以上のものを言
う。The mayonnaise-like seasoning referred to in the present invention is a semi-solid seasoning mainly used in salad dishes, and includes mayonnaise and mayonnaise-type seasonings. Mayonnaise is mayonnaise defined in Japanese Agricultural Standards, and mayonnaise-type seasoning does not fit into Japanese Agricultural Standards in mayonnaise, but is similar in flavor, appearance, physical properties, purpose of use, etc. to mayonnaise. Mayonnaise defined by Japanese Agricultural Standards is a semi-solid dressing that contains at least 65% fat and oil, uses egg yolk or whole egg, and has essential ingredients, egg yolk, egg white, protein hydrolysate, salt, and saccharides. , Spices, seasonings (such as amino acids) and sour foods without raw materials. The semi-solid dressing is a dressing having a viscosity of 30,000 Pa · s or more.
【0022】本発明のマヨネーズ様調味料の原材料はマ
ヨネーズの場合は日本農林規格の定めに従うが、それ以
外のマヨネーズタイプ調味料の場合は多様な原材料が使
用できる。すなわち少なくとも食用油脂、卵黄、食酢か
らなり、卵は全卵、卵黄の1種または2種、およびこれ
らにに卵白を組み合わせたものを使用することが、その
他必要に応じて食塩、甘味料等の糖類、胡椒、パプリ
カ、バジル、ディル、ローズマリー、クミン、タラゴ
ン、コリアンダー、スターアニス、クローブ、カルダモ
ン、ローレル、ターメリック、フェンネル、マスター
ド、タイム、セージ、メース、オールスパイス、セロリ
シード、山椒、わさび、とうがらし、オレガノ、カイエ
ンペッパー、チリパウダー、ケッパー等のハーブおよび
香辛料類、コーン、パスタ等の穀類、くるみ、ごま、松
の実、アーモンド等の種実類、味噌、納豆、豆乳等の豆
類、ツナ、ホタテ、かつおぶし、うに、たらこ等の魚介
類、ベーコン、コンビーフ、ハム、豚肉・牛肉・鶏肉の
ひき肉等の獣鳥鯨肉類、ヨーグルト、チーズ、牛乳、ク
リーム等の乳類、あさつき、かぼちゃ、しそ、しょう
が、セロリー、だいこん、たけのこ、玉ねぎ、トマト
(加工品含む)、にんじん、にんにく、ねぎ、パセリ、ピ
ーマン、赤ピーマン、黄ピーマン、ピクルス、ザーサ
イ、ホースラッデッシュ、みょうが、わけぎ、グリーン
ピース、しその実等の野菜類、梅干し、うめ、かぼす、
オリーブ、グレープフルーツ、すだち、パインアップ
ル、ぶどう、マンゴ、もも、ゆず、ライム、りんご、レ
モン、みかん、キウイフルーツ、なつみかん、はっさ
く、パッションフルーツ等の果実類の実およびその果
汁、しいたけ、マッシュルーム、きくらげ等のきのこ
類、こんぶ、のり、ひじき、とさかのり、わかめ等の藻
類、清酒、ワイン、みりん、こぶ茶、梅酒等の嗜好飲料
類、コンソメ、醤油、ケチャップ、豆板醤、アミノ酸、
テンメンジャン、醗酵調味料、酸味料、うまみ調味料
(アミノ酸、核酸等)、風味調味料等の調味料類、チリ
ソース、トマトソース、オイスターソース、ウスターソ
ス、オイスターソース等のソース類、天然エキス、酵母
エキス、肉エキス、魚介類エキス、野菜エキス等のエキ
ス類、たんぱく加水分解物、酸化防止剤、香料、増粘
剤、澱粉、乳化剤、水等を加えることができる。The raw materials of the mayonnaise-like seasoning of the present invention comply with the Japanese Agriculture and Forestry Standards for mayonnaise, but various other raw materials can be used for other mayonnaise-type seasonings. That is, at least edible oils and fats, egg yolk, vinegar, eggs are whole eggs, one or two of egg yolk, and it is possible to use a combination of egg white and these, if necessary, such as salt, sweetener and the like Sugars, pepper, paprika, basil, dill, rosemary, cumin, tarragon, coriander, star anise, clove, cardamom, laurel, turmeric, fennel, mustard, thyme, sage, mace, allspice, celery seed, sansho, wasabi, Herbs and spices such as pepper, oregano, cayenne pepper, chili powder, caper, cereals such as corn, pasta, seeds such as walnuts, sesame, pine nuts, almonds, beans such as miso, natto, soy milk, tuna, Scallops, bonito, sea urchin, seafood such as cod, bacon, corned beef, ham, Beast bird whale meat of minced meat such as meat, beef, chicken, yogurt, cheese, milk, milk such as cream, chives, pumpkin, basil, ginger, celery, radish, bamboo shoots, onions, tomatoes
(Including processed goods), carrots, garlic, green onions, parsley, peppers, red peppers, yellow peppers, pickles, sasay, horseradish, ginger, scallions, green peas, vegetables such as citrus seeds, dried plums, ume, kabosu,
Fruits such as olive, grapefruit, sudachi, pineapple, grape, mango, thigh, yuzu, lime, apple, lemon, tangerine, kiwifruit, natsumikan, hassaku, passion fruit and their fruit juice, shiitake, mushroom, jellyfish Algae such as mushrooms, konbu, seaweed, hijiki, seaweed, seaweed, etc., sake, wine, mirin, kobucha, plum wine, etc., favorite drinks, consomme, soy sauce, ketchup, soy sauce, amino acids,
Seasonings such as tenmenjian, fermented seasonings, sour seasonings, umami seasonings (amino acids, nucleic acids, etc.), flavor seasonings, etc., sauces such as chili sauce, tomato sauce, oyster sauce, woster sos, oyster sauce, natural extract, yeast extract , Meat extract, seafood extract, vegetable extract, etc., protein hydrolyzate, antioxidant, fragrance, thickener, starch, emulsifier, water and the like.
【0023】マヨネーズ様調味料の製造方法は通常公知
の製造方法を用いることができる。以下に述べる方法で
製造できるが、これに限定されるものではない。食用油
脂と卵以外の各種原材料を加温可能な攪拌槽に投入し、
加熱攪拌を行い水相部を調製する。加熱攪拌は原材料の
均一な分散、溶解、および殺菌を目的として必要に応じ
て行う、これを達成できれば特に条件に制限はない。加
熱攪拌は加圧、減圧、常圧下で可能であり、通常は常圧
下で行われる。温度の制限はなく原材料が溶解、殺菌が
なされれば良く、通常は40〜95℃で、好ましくは6
0℃〜95℃で行われる。攪拌は原料の均一な分散等が
なされれば良く、プロペラ、ホモミキサー、ブレンダ
ー、ディスパー、パドルミキサー、コロイドミル、連続
ミキサー、スタティックミキサー、超音波等の撹拌機ま
たは方法を用いることができ、回転数、攪拌時間は原材
料が均一に分散されれば特に制限はない。加熱した場合
は、その後、水相部を常温程度まで冷却し、別途に殺菌
された卵と別途調製された食用油脂とを合わせ乳化す
る。乳化は通常減圧下で行い、プロペラ、ホモミキサ
ー、ブレンダー、ディスパー、パドルミキサー、コロイ
ドミル、連続ミキサー、スタティックミキサー等を用い
ることができマヨネーズ様調味料が得られる。As a method for producing the mayonnaise-like seasoning, generally known production methods can be used. It can be manufactured by the method described below, but is not limited thereto. Various raw materials other than edible oils and eggs are put into a stirring tank that can be heated,
Heat and stir to prepare the aqueous phase. The heating and stirring are performed as necessary for the purpose of uniform dispersion, dissolution, and sterilization of the raw materials. There is no particular limitation on the conditions as long as this can be achieved. Heating and stirring can be performed under increased pressure, reduced pressure, and normal pressure, and is usually performed under normal pressure. The temperature is not limited, and the raw materials may be dissolved and sterilized. Usually, the temperature is 40 to 95 ° C, preferably 6 to 95 ° C.
Performed at 0 ° C to 95 ° C. The stirring may be performed by uniformly dispersing the raw materials, and a stirring machine or a method such as a propeller, a homomixer, a blender, a disper, a paddle mixer, a colloid mill, a continuous mixer, a static mixer, and an ultrasonic wave can be used. The number and stirring time are not particularly limited as long as the raw materials are uniformly dispersed. When heated, the aqueous phase is then cooled to about room temperature, and the separately sterilized egg and the separately prepared edible fat are emulsified. The emulsification is usually performed under reduced pressure, and a propeller, a homomixer, a blender, a disper, a paddle mixer, a colloid mill, a continuous mixer, a static mixer, or the like can be used to obtain a mayonnaise-like seasoning.
【0024】本発明で得られるマヨネーズ様調味料は、
特に卵のコクが引き立った、食用油脂のもたらすコク、
マイルド感のバランスのとれた、風味良好なマヨネーズ
様調味料を提供することに関する。また、中鎖脂肪酸は
体内で分解されやすく本発明のマヨネーズ様調味料を適
量継続的に摂取することにより、体脂肪蓄積を抑制する
作用も期待できる。同様の理由でエネルギーになり易い
ため、体調の改善等の好影響も期待される。The mayonnaise-like seasoning obtained in the present invention comprises:
The richness of edible oils and fats, especially the richness of eggs,
The present invention relates to providing a well-flavored mayonnaise-like seasoning with a balanced mild feeling. In addition, medium-chain fatty acids are easily decomposed in the body, and the action of suppressing the accumulation of body fat can be expected by continuously ingesting the mayonnaise-like seasoning of the present invention in an appropriate amount. For the same reason, energy is likely to be generated, and positive effects such as improvement in physical condition are also expected.
【0025】[0025]
【実施例】以下に実施例を挙げて本発明をより具体的に
説明するが、本発明はそれらによって限定されるもので
はない。実施例および比較例で得られるマヨネーズ様調
味料の風味評価方法を以下に示す。 [風味評価法]風味評価の方法は、レタスを適度な大き
さに取り分けた後、マヨネーズ様調味料一定量レタスに
かけて風味を評価する。風味評価の内容は、全体の風
味、卵のコク、風味と食用油脂のもたらすコク、マイル
ド感に関して30人のパネルの5段階評点の平均値を求
め評価した。評点は、 5点:好ましい 4点:どちらかといえば好ましい 3点:どちらともいえない 2点:どちらかといえば好ましくない 1点:好ましくない とした。EXAMPLES The present invention will be described in more detail with reference to the following Examples, but it should not be construed that the invention is limited thereto. The flavor evaluation methods of the mayonnaise-like seasonings obtained in the examples and comparative examples are shown below. [Flavor evaluation method] In the method of flavor evaluation, after dividing lettuce into an appropriate size, the flavor is evaluated by applying a fixed amount of mayonnaise-like seasoning lettuce. The content of the flavor evaluation was evaluated by calculating the average value of the five grades of a panel of 30 persons regarding the overall flavor, the richness of the egg, the richness of the flavor and the edible oil and fat, and the mildness. The rating was 5 points: favorable 4 points: rather favorable 3 points: neither can be said 2 points: rather unfavorable 1 point: unfavorable
【0026】製造例1 大豆サラダ油(日清製油(株)製)85質量部と構成脂
肪酸が質量比でカプリル酸/カプリン酸=3/1である
MCT15質量部との混合物にリパーゼQL(名糖産業
(株)製)0.1質量部を添加し、攪拌下60℃で15
時間、エステル交換反応を行った。反応生成物から酵素
を濾別し、濾液を水洗、乾燥後、脱色、脱臭して油脂組
成物1を得た。油脂組成物1のトリグリセリド組成およ
び脂肪酸組成を表1に示す。Production Example 1 Lipase QL (name sugar) was added to a mixture of 85 parts by mass of soybean salad oil (manufactured by Nisshin Oil Co., Ltd.) and 15 parts by mass of MCT in which the constituent fatty acids were in a mass ratio of caprylic acid / capric acid = 3/1. 0.1 part by mass (manufactured by Sangyo Co., Ltd.)
The transesterification was performed for hours. The enzyme was separated from the reaction product by filtration, and the filtrate was washed with water, dried, decolorized and deodorized to obtain an oil / fat composition 1. Table 1 shows the triglyceride composition and fatty acid composition of the oil and fat composition 1.
【0027】製造例2 菜種白絞油(日清製油(株)製)80質量部と構成脂肪
酸が質量比でカプリル酸/カプリン酸=3/1であるM
CT20質量部とを混合後、減圧下120℃で攪拌し、
脱気および脱水処理を行った。これに触媒としてナトリ
ウムメチラート0.1質量部を加え、120℃で30分
間、ランダムエステル交換反応を行った。反応生成物を
常法により水洗、乾燥後、脱色、脱臭して油脂組成物2
を得た。油脂組成物2のトリグリセリド組成および脂肪
酸組成を表1に示す。Production Example 2 80 parts by mass of rapeseed white squeezed oil (manufactured by Nisshin Oil Co., Ltd.) and the constituent fatty acids in a mass ratio of caprylic acid / capric acid = 3/1.
After mixing with 20 parts by mass of CT, the mixture was stirred at 120 ° C. under reduced pressure,
Degassing and dehydration were performed. To this was added 0.1 parts by mass of sodium methylate as a catalyst, and a random transesterification reaction was performed at 120 ° C. for 30 minutes. The reaction product is washed with water, dried, decolorized and deodorized by a conventional method to obtain an oil and fat composition 2
I got Table 1 shows the triglyceride composition and the fatty acid composition of the oil and fat composition 2.
【0028】製造例3 菜種白絞油(日清製油(株)製)93質量部と構成脂肪
酸が質量比でカプリル酸/カプリン酸=3/1であるM
CT7質量部とを混合後、減圧下120℃で攪拌し、脱
気および脱水処理を行った。これに触媒としてナトリウ
ムメチラート0.1質量部を加え、120℃にて30分
間、ランダムエステル交換反応を行った。反応生成物を
常法により水洗、乾燥後、脱色、脱臭して油脂組成物3
を得た。油脂組成物3のトリグリセリド組成および脂肪
酸組成を表1に示す。Production Example 3 93 parts by mass of rapeseed white squeezed oil (manufactured by Nisshin Oil Co., Ltd.) and the constituent fatty acids in a mass ratio of caprylic acid / capric acid = 3/1 M
After mixing with 7 parts by mass of CT, the mixture was stirred at 120 ° C. under reduced pressure to perform deaeration and dehydration. To this, 0.1 part by mass of sodium methylate was added as a catalyst, and a random transesterification reaction was performed at 120 ° C. for 30 minutes. The reaction product is washed with water, dried, decolorized and deodorized by a conventional method to obtain an oil / fat composition 3.
I got Table 1 shows the triglyceride composition and fatty acid composition of Oil Composition 3.
【0029】製造例4 菜種白絞油(日清製油(株)製)90質量部と構成脂肪
酸が質量比でカプリル酸/カプリン酸=3/1であるM
CT10質量部とを混合後、減圧下120℃で攪拌し、
脱気および脱水処理を行った。これに触媒としてナトリ
ウムメチラート0.1質量部を加え、120℃にて30
分間、ランダムエステル交換反応を行った。反応生成物
を常法により水洗、乾燥後、脱色、脱臭して油脂組成物
4を得た。油脂組成物4のトリグリセリド組成および脂
肪酸組成を表1に示す。Production Example 4 M in which 90 parts by mass of rapeseed white squeezed oil (manufactured by Nisshin Oil Co., Ltd.) and constituent fatty acids are caprylic acid / capric acid = 3/1 by mass ratio.
After mixing with 10 parts by mass of CT, the mixture was stirred at 120 ° C. under reduced pressure,
Degassing and dehydration were performed. To this, 0.1 part by mass of sodium methylate was added as a catalyst.
A random transesterification reaction was performed for minutes. The reaction product was washed with water, dried, decolorized and deodorized by a conventional method to obtain an oil / fat composition 4. Table 1 shows the triglyceride composition and fatty acid composition of Fat and Oil Composition 4.
【0030】製造例5 菜種白絞油(日清製油(株)製)と構成脂肪酸が質量比
でカプリル酸/カプリン酸=3/1であるMCTとを
4:1(質量比)で配合して油脂組成物5を得た。油脂
組成物5のトリグリセリド組成および脂肪酸組成を表1
に示す。Production Example 5 Rapeseed white squeezed oil (manufactured by Nisshin Oil Co., Ltd.) and MCT in which the constituent fatty acids are caprylic acid / capric acid = 3/1 by mass ratio are mixed at a ratio of 4: 1 (mass ratio). Thus, an oil / fat composition 5 was obtained. Table 1 shows the triglyceride composition and fatty acid composition of the fat composition 5.
Shown in
【0031】比較製造例1 菜種白絞油(日清製油(株)製)99質量部と構成脂肪
酸が質量比でカプリル酸/カプリン酸=3/1であるM
CT1質量部とを混合後、減圧下120℃で攪拌し、脱
気および脱水処理を行った。これに触媒としてナトリウ
ムメチラート0.1質量部を加え、120℃で30分
間、ランダムエステル交換反応を行った。反応生成物を
常法により水洗、乾燥後、脱色、脱臭して比較油脂組成
物1を得た。比較油脂組成物1のトリグリセリド組成お
よび脂肪酸組成を表1に示す。Comparative Production Example 1 M in which rapeseed white squeezed oil (manufactured by Nisshin Oil Co., Ltd.) is 99 parts by mass and the constituent fatty acids are caprylic acid / capric acid = 3/1 by mass ratio.
After mixing with 1 part by mass of CT, the mixture was stirred at 120 ° C. under reduced pressure to perform deaeration and dehydration. To this was added 0.1 parts by mass of sodium methylate as a catalyst, and a random transesterification reaction was performed at 120 ° C. for 30 minutes. The reaction product was washed with water, dried, decolorized and deodorized by a conventional method to obtain Comparative Oil and Fat Composition 1. Table 1 shows the triglyceride composition and fatty acid composition of Comparative Fat and Oil Composition 1.
【0032】また、対照として大豆油のトリグリセリド
組成および脂肪酸組成を表1に示す。Table 1 shows the triglyceride composition and fatty acid composition of soybean oil as controls.
【0033】[0033]
【表1】 [Table 1]
【0034】実施例1 製造例1の油脂組成物を使用し、下表2に示すようなマ
ヨネーズを作製した。その手順は、加塩卵黄を除く水相
部原材料を表中の配合比で、攪拌機付きの加温可能な容
器に投入し、パドルミキサーを用いて60rpmで攪拌
しながら品温が90℃になるまで加熱し、品温を90℃
に保持しながら25分間攪拌を行った。その後、品温が
20℃になるまで冷却して加塩卵黄を加えた後に食用油
脂と合わせ減圧下でパドルミキサーの60rpmとホモ
ミキサーの7000rpmを併用して、10分の条件で
乳化を行いマヨネーズを製造した。このマヨネーズの風
味評価をおこなった。その結果を表3に示す。Example 1 Using the oil or fat composition of Production Example 1, mayonnaise as shown in Table 2 below was prepared. The procedure is as follows. The raw materials in the aqueous phase excluding the salted egg yolk are charged at the mixing ratio shown in the table into a warmable container equipped with a stirrer, and stirred at 60 rpm using a paddle mixer until the product temperature reaches 90 ° C. Heat to 90 ° C
While stirring for 25 minutes. Thereafter, the product temperature was cooled to 20 ° C., salted egg yolk was added, and the mixture was added with edible oil and fat. Under reduced pressure, 60 rpm of a paddle mixer and 7000 rpm of a homomixer were used in combination, and emulsification was performed for 10 minutes under conditions of mayonnaise. Manufactured. The flavor of this mayonnaise was evaluated. Table 3 shows the results.
【0035】実施例2 製造例5の油脂組成物を使用して、表2に示す配合で、
実施例1と同様の方法でマヨネーズを製造した。このマ
ヨネーズの風味評価を行った。風味評価の結果を表3に
示す。Example 2 Using the oil and fat composition of Production Example 5, with the composition shown in Table 2,
Mayonnaise was produced in the same manner as in Example 1. The flavor of this mayonnaise was evaluated. Table 3 shows the results of the flavor evaluation.
【0036】比較例1 比較製造例1の油脂組成物を使用して、表2の配合で、
実施例1と同様の方法でマヨネーズを製造した。このマ
ヨネーズの風味評価を行った。その風味評価の結果を表
3に示す。Comparative Example 1 Using the oil and fat composition of Comparative Production Example 1,
Mayonnaise was produced in the same manner as in Example 1. The flavor of this mayonnaise was evaluated. Table 3 shows the results of the flavor evaluation.
【0037】比較例2 大豆サラダ油(日清製油(株)製)を使用して、表2の
配合で、実施例1と同様の方法でマヨネーズを製造し
た。このマヨネーズの風味評価を行った。その風味評価
の結果を表3に示す。Comparative Example 2 Mayonnaise was produced in the same manner as in Example 1 using the soybean salad oil (manufactured by Nisshin Oil Co., Ltd.) with the composition shown in Table 2. The flavor of this mayonnaise was evaluated. Table 3 shows the results of the flavor evaluation.
【0038】[0038]
【表2】 [Table 2]
【0039】[0039]
【表3】 [Table 3]
【0040】実施例1は卵のコク、風味が十分に感じら
れ、かつ油相部からもコク・マイルド感が得られた風味
良好なマヨネーズであった。実施例2は卵のコク、風味
が比較的良く感じられ、かつ油相部からもコク・マイル
ド感が得られた風味良好なマヨネーズであった。比較例
1及び2は油相部からコク・マイルド感が得られたもの
の卵のコク、風味が実施例1及び2に比べて劣り十分に
良好な風味のマヨネーズとは言えないものであった。Example 1 was a good-flavored mayonnaise in which the richness and flavor of the egg were sufficiently felt, and the richness and mildness were obtained from the oil phase. Example 2 was a good-flavored mayonnaise in which the richness and flavor of the eggs were felt relatively well, and the richness and mildness were also obtained from the oil phase. In Comparative Examples 1 and 2, the richness and flavor of the eggs were inferior to those of Examples 1 and 2 although the richness was obtained from the oil phase, and the eggs were not sufficiently well-flavored mayonnaise.
【0041】実施例3 製造例2の油脂組成物を使用し、下表4に示すようなマ
ヨネーズタイプ調味料を作製した。その手順は、加塩卵
黄を除く水相部原材料を表中の配合比で、攪拌機付きの
加温可能な容器に投入し、パドルミキサーを用いて60
rpmで攪拌しながら品温が90℃になるまで加熱し、
品温を90℃に保持しながら25分間攪拌を行った。そ
の後、品温が20℃になるまで冷却して加塩卵黄を加え
た後に食用油脂と合わせ減圧下でパドルミキサーの60
rpmとホモミキサーの7000rpmを併用して、1
0分の条件で乳化を行いマヨネーズタイプ調味料を製造
した。このマヨネーズタイプ調味料の風味評価をおこな
った。その結果を表5に示す。Example 3 Using the oil / fat composition of Production Example 2, a mayonnaise-type seasoning as shown in Table 4 below was prepared. The procedure is as follows. The raw materials in the aqueous phase excluding the salted egg yolk are charged into a warmable container equipped with a stirrer in the mixing ratio shown in the table, and the mixture is mixed with a paddle mixer at 60%.
While stirring at rpm, heat until the product temperature reaches 90 ° C,
Stirring was performed for 25 minutes while maintaining the product temperature at 90 ° C. Thereafter, the product is cooled to a temperature of 20 ° C., and the salted egg yolk is added thereto.
rpm and a homomixer of 7000 rpm,
Emulsification was performed under the condition of 0 minutes to produce a mayonnaise type seasoning. The flavor of this mayonnaise type seasoning was evaluated. Table 5 shows the results.
【0042】実施例4 製造例5の油脂組成物を使用して、表4に示す配合で、
実施例3と同様の方法でマヨネーズタイプ調味料を製造
した。このマヨネーズタイプ調味料の風味評価を行っ
た。風味評価の結果を表5に示す。Example 4 Using the oil and fat composition of Production Example 5, with the formulation shown in Table 4,
A mayonnaise-type seasoning was produced in the same manner as in Example 3. The flavor of this mayonnaise type seasoning was evaluated. Table 5 shows the results of the flavor evaluation.
【0043】比較例3 比較製造例1の油脂組成物を使用して、表4の配合で、
実施例3と同様の方法でマヨネーズタイプ調味料を製造
した。このマヨネーズタイプ調味料の風味評価を行っ
た。その風味評価の結果を表5に示す。Comparative Example 3 Using the oil and fat composition of Comparative Production Example 1,
A mayonnaise-type seasoning was produced in the same manner as in Example 3. The flavor of this mayonnaise type seasoning was evaluated. Table 5 shows the results of the flavor evaluation.
【0044】比較例4 大豆サラダ油(日清製油(株)製)を使用して、表4の
配合で、実施例3と同様の方法でマヨネーズタイプ調味
料を製造した。このマヨネーズタイプ調味料の風味評価
を行った。その風味評価の結果を表5に示す。Comparative Example 4 A soybean salad oil (manufactured by Nisshin Oil Co., Ltd.) was used to produce a mayonnaise-type seasoning in the same manner as in Example 3 with the composition shown in Table 4. The flavor of this mayonnaise type seasoning was evaluated. Table 5 shows the results of the flavor evaluation.
【0045】比較例5 製造例2の油脂組成物を使用して、表4の配合で、実施
例3と同様の方法でマヨネーズタイプ調味料を製造し
た。このマヨネーズタイプ調味料の風味評価を行った。
その風味評価の結果を表5に示す。Comparative Example 5 A mayonnaise-type seasoning was produced in the same manner as in Example 3 by using the oil / fat composition of Production Example 2 with the composition shown in Table 4. The flavor of this mayonnaise type seasoning was evaluated.
Table 5 shows the results of the flavor evaluation.
【0046】[0046]
【表4】 [Table 4]
【0047】[0047]
【表5】 [Table 5]
【0048】実施例3は卵のコク、風味が十分に感じら
れ、かつ油相部からもコク・マイルド感が得られた風味
良好なマヨネーズタイプ調味料であった。実施例4は卵
のコク、風味が比較的良く感じられ、かつ油相部からも
コク・マイルド感が得られた風味良好なマヨネーズタイ
プ調味料であった。比較例3及び4は油相部からコク・
マイルド感が得られたものの卵のコク、風味が実施例2
に比べて劣り十分に良好な風味のマヨネーズタイプ調味
料とは言えないものであった。比較例5は卵のコク、風
味は得られたものの油相部が少ないためにコク・マイル
ド感が得られず風味良好なマヨネーズタイプ調味料とは
言えないものであった。Example 3 was a well-flavored mayonnaise-type seasoning in which the richness and flavor of the egg were sufficiently felt, and the richness was also obtained from the oil phase. Example 4 was a good-flavored mayonnaise-type seasoning in which the richness and flavor of the egg were felt relatively well and the richness and mildness were obtained even from the oil phase. Comparative Examples 3 and 4 were rich in oil phase.
Egg richness and flavor, although mild feeling was obtained Example 2
It was inferior to, and could not be called a mayonnaise-type seasoning with a sufficiently good flavor. In Comparative Example 5, the richness and flavor of the egg were obtained, but the richness of the oil phase was small, so the rich and mild feeling was not obtained and the flavor was not a good mayonnaise type seasoning.
【0049】[0049]
【発明の効果】本発明の構成をとることで、特に卵のコ
クが引き立った、食用油脂のもたらすコク、マイルド感
のバランスのとれた、風味良好なマヨネーズ様調味料を
提供することができる。また、中鎖脂肪酸は体内で分解
されやすく本発明のマヨネーズ様調味料を適量継続的に
摂取することにより、体脂肪蓄積を抑制する作用も期待
できる。同様の理由でエネルギーになり易いため、体調
の改善等の好影響も期待される。EFFECTS OF THE INVENTION By adopting the constitution of the present invention, it is possible to provide a well-flavored mayonnaise-like seasoning in which the richness of eggs is particularly enhanced, the richness and mildness of edible oils and fats are balanced. In addition, medium-chain fatty acids are easily decomposed in the body, and the action of suppressing the accumulation of body fat can be expected by continuously ingesting the mayonnaise-like seasoning of the present invention in an appropriate amount. For the same reason, energy is likely to be generated, and positive effects such as improvement in physical condition are also expected.
フロントページの続き (72)発明者 室賀 香織 神奈川県横須賀市神明町1番地 日清製油 株式会社研究所内 Fターム(参考) 4B026 DC06 DH10 DX04 4B047 LB09 LE03 LG09 LG10 LG53Continued on the front page (72) Inventor Kaori Muroka 1 Shinmeicho, Yokosuka-shi, Kanagawa Prefecture Nisshin Oil Co., Ltd. F-term (reference) 4B026 DC06 DH10 DX04 4B047 LB09 LE03 LG09 LG10 LG53
Claims (2)
らなり、(2)食用油脂が全体の10〜80質量%であ
り、(3)食用油脂が主としてトリグリセリドからなる
油脂組成物であって、油脂組成物を構成する全脂肪酸に
占める中鎖脂肪酸の割合が3〜40質量%であり、
(4)全トリグリセリドに占める中鎖脂肪酸残基を分子
内に1つ以上有するトリグリセリドの割合が3〜90質
量%であり、(5) 卵黄分を全体の3〜20質量%含
有する上記(1)〜(5)を満たすことを特徴とするマ
ヨネーズ様調味料。1. An oil / fat composition comprising (1) at least edible oil / fat, egg yolk and vinegar, (2) edible oil / fat in an amount of 10 to 80% by mass of the whole, and (3) edible oil / fat mainly comprising triglyceride. The proportion of medium-chain fatty acids in the total fatty acids constituting the fat composition is 3 to 40% by mass,
(4) The proportion of triglycerides having one or more medium-chain fatty acid residues in the molecule in all triglycerides is 3 to 90% by mass, and (5) the above (1) containing 3 to 20% by mass of egg yolks in total. (5) A mayonnaise-like seasoning characterized by satisfying (5).
酸である請求項1記載のマヨネーズ様調味料。2. The mayonnaise-like seasoning according to claim 1, wherein the medium-chain fatty acid is a saturated fatty acid having 6 to 12 carbon atoms.
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JP2000047954A JP3517626B2 (en) | 2000-02-24 | 2000-02-24 | Mayonnaise-like seasoning |
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JP2000047954A JP3517626B2 (en) | 2000-02-24 | 2000-02-24 | Mayonnaise-like seasoning |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003056928A1 (en) * | 2001-12-28 | 2003-07-17 | The Nisshin Oillio, Ltd. | Fat and oil compositions for decreasing blood lipid |
JP2009089669A (en) * | 2007-10-10 | 2009-04-30 | Nippon Shokuhin Kako Co Ltd | Method for producing food which has homogenizing step |
JP5480456B1 (en) * | 2012-11-29 | 2014-04-23 | キユーピー株式会社 | Mayonnaise food |
CN109645424A (en) * | 2019-01-04 | 2019-04-19 | 颐海(上海)食品有限公司 | A kind of chafing dish bottom flavorings and preparation method thereof containing medium chain triglyceride |
-
2000
- 2000-02-24 JP JP2000047954A patent/JP3517626B2/en not_active Expired - Fee Related
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003056928A1 (en) * | 2001-12-28 | 2003-07-17 | The Nisshin Oillio, Ltd. | Fat and oil compositions for decreasing blood lipid |
US6827963B2 (en) | 2001-12-28 | 2004-12-07 | The Nisshin Oillio, Ltd. | Fats and oils composition for reducing lipids in blood |
JPWO2003056928A1 (en) * | 2001-12-28 | 2005-05-12 | 日清オイリオグループ株式会社 | Oil composition for lowering blood lipid |
JP2009089669A (en) * | 2007-10-10 | 2009-04-30 | Nippon Shokuhin Kako Co Ltd | Method for producing food which has homogenizing step |
JP5480456B1 (en) * | 2012-11-29 | 2014-04-23 | キユーピー株式会社 | Mayonnaise food |
WO2014083663A1 (en) * | 2012-11-29 | 2014-06-05 | キユーピー 株式会社 | Mayonnaise-like food |
CN109645424A (en) * | 2019-01-04 | 2019-04-19 | 颐海(上海)食品有限公司 | A kind of chafing dish bottom flavorings and preparation method thereof containing medium chain triglyceride |
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