JP2001104963A - Removing agent for heavy metal/chlorine type dioxin- containing compound, apparatus and method for removing heavy metal/chlorine type dioxine-containing compound and production of removing agent - Google Patents
Removing agent for heavy metal/chlorine type dioxin- containing compound, apparatus and method for removing heavy metal/chlorine type dioxine-containing compound and production of removing agentInfo
- Publication number
- JP2001104963A JP2001104963A JP31868399A JP31868399A JP2001104963A JP 2001104963 A JP2001104963 A JP 2001104963A JP 31868399 A JP31868399 A JP 31868399A JP 31868399 A JP31868399 A JP 31868399A JP 2001104963 A JP2001104963 A JP 2001104963A
- Authority
- JP
- Japan
- Prior art keywords
- metal
- heavy metal
- chlorine
- dioxin
- containing compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Removal Of Specific Substances (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
Description
【産業上の利用分野】本発明は人間が日常生活するにあ
たって有害である化学化合物で代表的な猛毒であるダイ
オキシン等の有害発生原因物質である塩素系化合物,亜
鉛酸化物,アルミニウム酸化物,硫黄酸化物,カドミウ
ム化合酸化物,カリウム・銀・クロム・水銀・スズ化合
酸化物・チタン・鉄・銅化合酸化物,バリウム化合酸化
物,ハロゲンかごう酸化物,フッソ化合酸化物,マグネ
シゥム・マンガン・リン・リチウム化合酸化物,脂肪族
系有機化合酸化物,芳香 族系・複素環状系有機化合酸
化物,有機ハロゲン化合酸化物,プラスチック ス化合
物,合成ゴム化合物,化合繊維,無機繊維化合物合成染
料酸化物,無 機・有機化合顔料酸化物,界面活性剤酸
化物,塗料・インキ酸化物,接着剤化合酸化物,食品添
加物,農薬酸化物(有機リン酸系殺虫剤含),発癌性の
ある過酸化水素・PCB・半導体液晶のシアン(野焼き
・自然発火の致死料200ppm)等があり,除去し,
地球環境破壊および人体,動植物,人類にとって有意義
に解決することを目的としている,重金属・塩素系ダイ
オキシン含む化合物の除去剤と取り除く装置方法に関す
るものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to chlorinated compounds, zinc oxide, aluminum oxide, sulfur, which are harmful substances such as dioxin, which is a very toxic chemical compound which is harmful to humans in daily life. Oxides, cadmium compound oxides, potassium / silver / chromium / mercury / tin compound oxides / titanium / iron / copper compound oxides, barium compound oxides, halogen cage oxides, fluorine compound oxides, magnesium / manganese / Phosphorus / lithium compound oxide, aliphatic organic compound oxide, aromatic / heterocyclic organic compound oxide, organic halogen compound oxide, plastics compound, synthetic rubber compound, compound fiber, inorganic fiber compound synthetic dye oxidation Compounds, organic / organic compound pigment oxides, surfactant oxides, paint / ink oxides, adhesive compound oxides, food additives, pesticide oxides Phosphate insecticide containing), there are lethal charges 200 ppm) and the like of carcinogenic is hydrogen peroxide, PCB-semiconductor crystal of cyan (burning-pyrophoric, is removed,
The present invention relates to an agent for removing compounds containing heavy metals and chlorine-based dioxins and an apparatus method for the purpose of solving the destruction of the global environment and meaningfully for the human body, animals and plants, and human beings.
【従来の技術】一例を言いますと飲料水で多数の安易な
塩素系除去(即ちカルキ臭)で完全な製品方法は無く野
放し状態である。2. Description of the Related Art For example, in drinking water, a large number of easy chlorine-based removals (that is, odors of chalky) have not been completed and there is no complete product method.
【発明が解決しようとする課題】本発明剤を有害物が発
生する製品に添加,混入することにより,安全に生命体
維持及び快適な生活ができます。又現在市場には有害な
製品があり,下記に示す一部分の例記にありますように
早急に処理し環境汚染を防がねばなりません。有害物質
毒性影響度として現状では手間・財政を圧迫するダイオ
キシンがあります,ダイオキシン類の毒性は毒ガス・リ
ン以上ともいわれています。大気や焼却灰(大気中飛
散),食品,人間の血液や母乳,地表ダイオキシン類の
地表落下により,海洋や河川及び湖沼汚染による飲料水
への汚染水,内湾に流れ込んでプランクトン,魚介類と
食物連鎖の混乱,さまざまな物質にふくまれています
(猛毒とされる2,3,7,8−ダイオキシン「TCD
D」がある)。一例としての食品添加物の有害度とし
て,発色剤 亜硝酸Na(ハム,イクラ等)による染色
体異常毒性。合成甘味料アスパルテーム,サッカリン,
サツカリンNa(清涼飲料,ガム,アイスクリーム,漬
け物,菓子類等)による脳腫瘍・骨格異常,染色体異
常,子宮癌,ボウ胱癌毒性。酸化防止剤 EDTA2N
a,EDTAカルシウム2Na,ジブチルヒドロキシト
ルエンBHT,ブチルヒドロキシアニソールBHA(マ
ヨネーズ,缶詰,バター類)による血液降下,胃腸障
害,催奇形性,歩行失調,呼吸促迫死亡毒性。防黴剤イ
マザリル,オルトフェニルフェノールOPP・Na,チ
アベンダゾールルTBZ(柑橘類)による遺伝子損傷
性,変異原性,ボウ胱癌,肝臓・腎臓障害,口蓋破裂奇
形,変異原性,染色体異常毒性。小麦粉改良剤臭素酸カ
リウム(パン類)による遺伝子損傷性,染色体異常,腎
臓癌毒性。合成着色料 食用赤色2号アマランス,アマ
ランスアルミニウムレーキ,食用赤色3号エリスロシ
ン,エリスロシンアルミニウムレーキ,食用赤色104
号フロキシン,105号ローズベンガル,106号アシ
ッドレッド,緑色3号,ファストグリーンアルミニウム
レーキ,青色1号,ブリリアントブルーアルニウムレー
キ,青色2号,インジゴカルミンアルミニウムレーキ
(菓子,清涼飲料,洋酒,冷菓,蒲鉾,ソーセージ類,
福神漬,イチゴ粉末食品,サクラエビ,あん類)による
発癌性,染色体異常,赤血球減少毒性。234種健康被
害・大気汚染物質の一例物質名(96度審議対策答申9
8年度基準)22物質名,ダイオキシン類,塩化ビニル
モノマー,アクリルニトリル,アセトアルデヒド,クロ
ロホルム,クロロジメチルエーテル,酸化エチレン,
1.2−ジクロロエタン,クロロメタン,水銀化合物,
タルク(アスベスト含),テトラクロロエチレン,トリ
クロロエチレン,ニッケル化合物,ヒ素化合物,1,3
−ブタジエン,ベリリウム化合物,ベンゼン,ベンゾピ
レン,ホルムアルデヒド,マンガン化合物,六価クロム
化合物,追記としてダイオキシン類には推定500〜6
30種あるといわています。少なくとも列記したものだ
けでも早急に解決し,環境保護を守ることを課題として
いる。[Problems to be Solved by the Invention] By adding and mixing the agent of the present invention into products that generate harmful substances, living organisms can be maintained safely and a comfortable life can be achieved. In addition, there are currently harmful products on the market, and they must be treated promptly to prevent environmental pollution as shown in the following example. At present, there is dioxin, which puts pressure on labor and finance as the degree of toxicity of harmful substances. The toxicity of dioxins is said to be higher than that of poisonous gas and phosphorus. Air and incinerated ash (scattered in the air), food, human blood and breast milk, surface dioxins falling to the surface, contaminated water from drinking water due to pollution of the ocean, rivers and lakes, plankton, seafood and food flowing into the inner bay Chain disruption, including various substances (2,3,7,8-dioxin "TCD
D "). As an example of the harmfulness of food additives, chromosome abnormal toxicity due to the coloring agent Na nitrite (ham, salmon roe, etc.). Synthetic sweetener aspartame, saccharin,
Toxicity to brain tumors and skeletal abnormalities, chromosomal abnormalities, uterine cancer, bowel cancer due to Saccharin Na (soft drink, gum, ice cream, pickles, confectionery, etc.). Antioxidant EDTA2N
a, EDTA calcium 2Na, dibutylhydroxytoluene BHT, butylhydroxyanisole BHA (mayonnaise, canned, butters), blood drop, gastrointestinal disorders, teratogenicity, ataxia, dystoxicity of respiratory distress. Genetic damage, mutagenicity, bowel bladder cancer, liver / kidney disorders, palatal rupture malformation, mutagenicity, chromosome abnormal toxicity caused by the fungicides imazalil, orthophenylphenol OPP.Na, and thiabendazole lu TBZ (citrus fruits). Genetic damage, chromosomal aberration, kidney cancer toxicity by flour improver potassium bromate (breads). Synthetic coloring food red 2 amaranth, amaranth aluminum lake, food red 3 erythrosin, erythrosine aluminum lake, food red 104
No. Phloxine, No. 105 Rose Bengal, No. 106 Acid Red, Green No. 3, Fast Green Aluminum Lake, Blue No. 1, Brilliant Blue Alnium Lake, Blue No. 2, Indigo Carmine Aluminum Lake (confectionery, soft drink, Western sake, frozen dessert, Kamaboko, sausages,
Carcinogenicity, chromosomal abnormalities, and erythrocyte toxicity due to Fukujinzuke, strawberry powder food, cherry shrimp, and bean jam. Example of 234 types of health hazards and air pollutants
FY2008 standard) 22 substance names, dioxins, vinyl chloride monomer, acrylonitrile, acetaldehyde, chloroform, chlorodimethyl ether, ethylene oxide,
1.2-dichloroethane, chloromethane, mercury compounds,
Talc (including asbestos), tetrachloroethylene, trichlorethylene, nickel compound, arsenic compound, 1,3
-Butadiene, beryllium compound, benzene, benzopyrene, formaldehyde, manganese compound, hexavalent chromium compound, and dioxins are estimated to be 500 to 6
It is said that there are 30 species. The task is to resolve at least the listed items as soon as possible and to protect the environment.
【課題を解決するための手段】そこで本発明はTM−M
D金属の非金属系とTM−M及びR−TM金属の金属系
との組み合わせによる単体金属に磁気を補助磁気とし
て,オゾンを付加することにより殺菌効果を高め有害物
を安全に処理する又TM−MD系はFe,Ni,COの
単独あるいは2種以上の合金を主成分とし,MD元素の
ひとつあるいは2種以上を15〜30原子%含む。TM
−M系ではZr,Ti,Hf等を40原子%以上含む,
残は還移金属のCO−Zr,Ni−Zr,CO−Ti。
還移金属と希土類金属からなるR−TM系にはGd,C
O。希土類金属は類属であるスカンジユム,イットリウ
ム,ランタン,セリウム,プラセオジム,ネオジム,プ
ロメチウム,サマリウム,ユウロピウム,ガドリニウ
ム,テルビウム,ジスプロシウム,ホルミウム,エルピ
ウム,ツリウム,イッテルピウム,ルテチウム,レアメ
タル,REM。植物系で炭化物。公開となっている4−
210624,アメリカ5198469,6−1070
93,8−157828,8−176600,9−18
8871,9−310070からなる項目から選ば1種
以上を含有する方法に着目し,重金属・塩素系ダイオキ
シン含む化合物の除去剤と取り除く装置方法の組成物が
広範囲に利用可能である。Accordingly, the present invention provides a TM-M
The addition of ozone to a single metal made of a combination of a non-metallic D metal and a metal of TM-M and R-TM metal as auxiliary magnetism enhances the sterilization effect and safely treats harmful substances. The MD system contains, as a main component, one or more alloys of Fe, Ni and CO, and contains 15 to 30 atomic% of one or more MD elements. TM
-M system contains more than 40 atomic% of Zr, Ti, Hf, etc.
The balance is CO-Zr, Ni-Zr, and CO-Ti, which are transfer metals.
Rd-TM system composed of transition metal and rare earth metal has Gd, C
O. The rare earth metals are of the genus scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erpium, thulium, ytterbium, lutetium, rare metal, REM. Carbide in plant system. 4-
210624, US 5198469, 6-1070
93, 8-157828, 8-176600, 9-18
Focusing on a method containing at least one selected from the items consisting of 8871 and 9-310070, a remover for a compound containing a heavy metal / chlorine-based dioxin and a composition of an apparatus method for removing the compound are widely applicable.
【実施例】以下実施例により本発明の具体例をさらに十
分に説明する。なをこれらの実施例は例示を目的とする
だけであって,決して本発明を限定することを意図しな
い。The present invention will be described in more detail with reference to the following examples. These examples are for illustrative purposes only and are not intended to limit the invention in any way.
【実施例1】実施例は請求項1,2,3の実施例を示す
ものである。重金属・塩素系ダイオキシン含む化合物除
去で組み込まれた剤に磁気体を付帯することにより,重
金属・塩素がJIS K 0102の基準にある数値以
上の物質が検出されず(工場排水試験法による)又厚生
省食品衛生5細菌検査も検出されず安全で有ることが証
明された。[Embodiment 1] The embodiment shows the first, second and third embodiments. By attaching a magnetic substance to the agent incorporated in the removal of compounds containing heavy metals and chlorine-based dioxins, substances with heavy metals and chlorine exceeding the values specified in JIS K 0102 are not detected (according to the factory drainage test method) and the Ministry of Health and Welfare Food hygiene 5 Bacteria test was not detected and proved to be safe.
【発明の効果】磁気的性質が高耐食性,高飽和磁束密
度,高透磁率,高磁歪,超電導,高靭性あることが確認
され,植物性炭化の効果とオゾンの0.01ppmで錆
の確認も無く,すなわち過酸化物が生じず味の劣化もな
かった。合金としてFe40Ni40P14B6,Fe
80B20,Fe82B10Si8,Fe81B13.
5Si3−5C2,Fe40Ni38,MO4B18,
CO75Si15B30,Fe72Cr3P13C7,
Pd80Si20,Fe70Cr10P13C7Fe
78Cr10Ni6C7,FeCr10PBC7,Fe
Cr10Ni5P13C7,18Cr−BNi等,磁
場,臨界電流が高い上超電導臨界温度,機械的性質が照
射により悪くならない事が確認[Effects of the Invention] It has been confirmed that the magnetic properties are high corrosion resistance, high saturation magnetic flux density, high magnetic permeability, high magnetostriction, superconductivity, and high toughness. The effect of vegetable carbonization and rust at 0.01 ppm of ozone are also confirmed. No, that is, no peroxide was generated and the taste was not deteriorated. Fe 40 Ni 40 P 14 B 6 , Fe
80 B 20, Fe 82 B 10 Si 8, Fe 81 B 13.
5 Si 3-5 C 2, Fe 40 Ni 38, MO 4 B 18,
CO 75 Si 15 B 30 , Fe 72 Cr 3 P 13 C 7 ,
Pd 80 Si 20 , Fe 70 Cr 10 P 13 C 7 Fe
78 Cr 10 Ni 6 C 7 , FeCr 10 PBC 7 , Fe
Cr 10 Ni 5 P 13 C 7 , 18Cr-BNi like, check field, on the superconducting critical temperature critical current is high, be mechanical properties is not deteriorated by irradiation
───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4D038 AA02 AA04 AB02 AB03 AB09 AB14 AB15 AB26 AB32 AB40 AB43 AB58 AB59 AB63 AB66 BB11 BB12 4D050 AA02 AA04 AB02 AB03 AB06 AB11 AB13 AB15 AB19 AB27 AB33 AB38 AB47 AB52 AB55 BB02 CA11 CA12 4D061 DA03 DB01 DB09 DB18 DB19 DC02 DC03 DC08 DC10 DC11 DC16 DC19 DC20 DC22 EA17 ED03 ────────────────────────────────────────────────── ─── Continued on the front page F term (reference) 4D038 AA02 AA04 AB02 AB03 AB09 AB14 AB15 AB26 AB32 AB40 AB43 AB58 AB59 AB63 AB66 BB11 BB12 4D050 AA02 AA04 AB02 AB03 AB06 AB11 AB13 AB15 AB19 AB27 AB33 AB38 AB47 AB52 AB55 BB06 CA11 CA12 DA03 DB01 DB09 DB18 DB19 DC02 DC03 DC08 DC10 DC11 DC16 DC19 DC20 DC22 EA17 ED03
Claims (3)
R−TM金属の金属系との組み合わせによる単体金属に
磁気を補助磁気として,オゾンを付加することにより殺
菌効果を高め有害物を安全に処理する重金属・塩素系ダ
イオキシン含む化合物の除去剤と取り除く装置方法の組
成物The present invention relates to a non-metallic TM-MD metal and a metal of TM-M and R-TM metal combined with an auxiliary magnetism to add ozone to a single metal to enhance the sterilizing effect and increase harmful substances. Of heavy metal / chlorine-based dioxin-containing compounds for safe treatment of wastewater
るいは2種以上の合金を主成分とし,MD元素のひとつ
あるいは2種以上を15〜30原子%含む。TM−M系
ではZr,Ti,Hf等を40原子%以上含む,残は還
移金属のCO−Zr,Ni−Zr,CO−Ti。還移金
属と希土類金属からなるR−TM系にはGd,CO。希
土類金属は類属であるスカンジユム,イットリウム,ラ
ンタン,セリウム,プラセオジム,ネオジム,プロメチ
ウム,サマリウム,ユウロピウム,ガドリニウム,テル
ビウム,ジスプロシウム,ホルミウム,エルピウム,ツ
リウム,イッテルピウム,ルテチウム,レアメタル,R
EM。植物系で炭化物。からなる属から選ばれる少なく
とも1種以上を含有する請求項1記載の重金属・塩素系
ダイオキシン含む化合物の除去剤と取り除く装置方法の
組成物2. The TM-MD system contains, as a main component, one or more alloys of Fe, Ni, and CO, and contains 15 to 30 atomic% of one or more MD elements. The TM-M system contains 40 atomic% or more of Zr, Ti, Hf, etc., and the balance is CO-Zr, Ni-Zr, CO-Ti of transfer metals. Gd, CO is used for the R-TM system composed of transition metals and rare earth metals. The rare earth metals are of the genus scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erpium, thulium, ytterbium, lutetium, rare metal, R
EM. Carbide in plant system. The composition for the method for removing a heavy metal / chlorine-containing dioxin-containing compound according to claim 1, which comprises at least one member selected from the genus consisting of:
リカ5198469,6−107093,8−1578
28,8−176600,9−188871,9−31
0070からなる項目から選ぱれる少なくとも1種以上
を含有する請求項1と請求項2記載の重金属・塩素系ダ
イオキシン含む化合物の除去剤と取り除く装置方法の組
成物3. Published Japanese Patent Application No. 4-210624, U.S. Pat. No. 5,198,469, 6-107093, 8-1578.
28, 8-176600, 9-188871, 9-31
3. The removing agent for a compound containing a heavy metal / chlorine-based dioxin according to claim 1, which contains at least one member selected from the group consisting of 0070;
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31868399A JP2001104963A (en) | 1999-10-04 | 1999-10-04 | Removing agent for heavy metal/chlorine type dioxin- containing compound, apparatus and method for removing heavy metal/chlorine type dioxine-containing compound and production of removing agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31868399A JP2001104963A (en) | 1999-10-04 | 1999-10-04 | Removing agent for heavy metal/chlorine type dioxin- containing compound, apparatus and method for removing heavy metal/chlorine type dioxine-containing compound and production of removing agent |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2001104963A true JP2001104963A (en) | 2001-04-17 |
Family
ID=18101867
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP31868399A Pending JP2001104963A (en) | 1999-10-04 | 1999-10-04 | Removing agent for heavy metal/chlorine type dioxin- containing compound, apparatus and method for removing heavy metal/chlorine type dioxine-containing compound and production of removing agent |
Country Status (1)
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JP (1) | JP2001104963A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002210305A (en) * | 2001-01-23 | 2002-07-30 | Ion Chemical Industry Kk | Dioxins detoxifying and removing agent and method for using the same |
CN103288202A (en) * | 2013-06-27 | 2013-09-11 | 江南大学 | Ozonization water treatment method taking iron-nickel magnetic composite material as catalyst |
CN105776498A (en) * | 2016-03-07 | 2016-07-20 | 浙江工业大学 | Method for removing anti-tumor medicine in water through catalytic ozonation of magnetic ordered mesopore nickel ferrite |
CN117123209A (en) * | 2023-09-28 | 2023-11-28 | 北京英诺格林科技有限公司 | Catalyst for oxidation treatment of landfill leachate and preparation method thereof |
-
1999
- 1999-10-04 JP JP31868399A patent/JP2001104963A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002210305A (en) * | 2001-01-23 | 2002-07-30 | Ion Chemical Industry Kk | Dioxins detoxifying and removing agent and method for using the same |
CN103288202A (en) * | 2013-06-27 | 2013-09-11 | 江南大学 | Ozonization water treatment method taking iron-nickel magnetic composite material as catalyst |
CN105776498A (en) * | 2016-03-07 | 2016-07-20 | 浙江工业大学 | Method for removing anti-tumor medicine in water through catalytic ozonation of magnetic ordered mesopore nickel ferrite |
CN117123209A (en) * | 2023-09-28 | 2023-11-28 | 北京英诺格林科技有限公司 | Catalyst for oxidation treatment of landfill leachate and preparation method thereof |
CN117123209B (en) * | 2023-09-28 | 2024-02-06 | 北京英诺格林科技有限公司 | Catalyst for oxidation treatment of landfill leachate and preparation method thereof |
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