JP2001104963A - Removing agent for heavy metal/chlorine type dioxin- containing compound, apparatus and method for removing heavy metal/chlorine type dioxine-containing compound and production of removing agent - Google Patents

Abstract

PROBLEM TO BE SOLVED: To achieve solution significant to humankind by removing heavy metals, chlorine compounds, dioxins, cyano compounds, PCBs carcinogenic citrus fruits or the like representative as harmful substances. SOLUTION: A removing agent of a heavy metal, chlorine compound and dioxin enhanced in sterilizing effect by adding ozone to a single metal due to a combination of a nonmetal system of a TM-MD metal and a metal system of TM-M and R-TM metal by using magnetism as auxiliary magnetism and treating a harmful substance safely and an apparatus and method for removing the heavy metal, chlorine compounds, and dioxins are provided. A TM-MD system is based on each of Fe, Ni and Co or an alloy of more than two kinds of them and contains 15-30 atomic % of one of MD elements or more than two kinds of them. A TM-M system contains more than 40 atomic % of Zr, Ti or Hf and the remainder thereof is Co-Zr, Ni-Zr or Co-Ti of transition metals. An R-TM system consisting of a transition metal and a rare earth metal contains Gd and Co.

Description

DETAILED DESCRIPTION OF THE INVENTION

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to chlorinated compounds, zinc oxide, aluminum oxide, sulfur, which are harmful substances such as dioxin, which is a very toxic chemical compound which is harmful to humans in daily life. Oxides, cadmium compound oxides, potassium / silver / chromium / mercury / tin compound oxides / titanium / iron / copper compound oxides, barium compound oxides, halogen cage oxides, fluorine compound oxides, magnesium / manganese / Phosphorus / lithium compound oxide, aliphatic organic compound oxide, aromatic / heterocyclic organic compound oxide, organic halogen compound oxide, plastics compound, synthetic rubber compound, compound fiber, inorganic fiber compound synthetic dye oxidation Compounds, organic / organic compound pigment oxides, surfactant oxides, paint / ink oxides, adhesive compound oxides, food additives, pesticide oxides Phosphate insecticide containing), there are lethal charges 200 ppm) and the like of carcinogenic is hydrogen peroxide, PCB-semiconductor crystal of cyan (burning-pyrophoric, is removed,
The present invention relates to an agent for removing compounds containing heavy metals and chlorine-based dioxins and an apparatus method for the purpose of solving the destruction of the global environment and meaningfully for the human body, animals and plants, and human beings.

2. Description of the Related Art For example, in drinking water, a large number of easy chlorine-based removals (that is, odors of chalky) have not been completed and there is no complete product method.

[Problems to be Solved by the Invention] By adding and mixing the agent of the present invention into products that generate harmful substances, living organisms can be maintained safely and a comfortable life can be achieved. In addition, there are currently harmful products on the market, and they must be treated promptly to prevent environmental pollution as shown in the following example. At present, there is dioxin, which puts pressure on labor and finance as the degree of toxicity of harmful substances. The toxicity of dioxins is said to be higher than that of poisonous gas and phosphorus. Air and incinerated ash (scattered in the air), food, human blood and breast milk, surface dioxins falling to the surface, contaminated water from drinking water due to pollution of the ocean, rivers and lakes, plankton, seafood and food flowing into the inner bay Chain disruption, including various substances (2,3,7,8-dioxin "TCD
D "). As an example of the harmfulness of food additives, chromosome abnormal toxicity due to the coloring agent Na nitrite (ham, salmon roe, etc.). Synthetic sweetener aspartame, saccharin,
Toxicity to brain tumors and skeletal abnormalities, chromosomal abnormalities, uterine cancer, bowel cancer due to Saccharin Na (soft drink, gum, ice cream, pickles, confectionery, etc.). Antioxidant EDTA2N
a, EDTA calcium 2Na, dibutylhydroxytoluene BHT, butylhydroxyanisole BHA (mayonnaise, canned, butters), blood drop, gastrointestinal disorders, teratogenicity, ataxia, dystoxicity of respiratory distress. Genetic damage, mutagenicity, bowel bladder cancer, liver / kidney disorders, palatal rupture malformation, mutagenicity, chromosome abnormal toxicity caused by the fungicides imazalil, orthophenylphenol OPP.Na, and thiabendazole lu TBZ (citrus fruits). Genetic damage, chromosomal aberration, kidney cancer toxicity by flour improver potassium bromate (breads). Synthetic coloring food red 2 amaranth, amaranth aluminum lake, food red 3 erythrosin, erythrosine aluminum lake, food red 104
No. Phloxine, No. 105 Rose Bengal, No. 106 Acid Red, Green No. 3, Fast Green Aluminum Lake, Blue No. 1, Brilliant Blue Alnium Lake, Blue No. 2, Indigo Carmine Aluminum Lake (confectionery, soft drink, Western sake, frozen dessert, Kamaboko, sausages,
Carcinogenicity, chromosomal abnormalities, and erythrocyte toxicity due to Fukujinzuke, strawberry powder food, cherry shrimp, and bean jam. Example of 234 types of health hazards and air pollutants
FY2008 standard) 22 substance names, dioxins, vinyl chloride monomer, acrylonitrile, acetaldehyde, chloroform, chlorodimethyl ether, ethylene oxide,
1.2-dichloroethane, chloromethane, mercury compounds,
Talc (including asbestos), tetrachloroethylene, trichlorethylene, nickel compound, arsenic compound, 1,3
-Butadiene, beryllium compound, benzene, benzopyrene, formaldehyde, manganese compound, hexavalent chromium compound, and dioxins are estimated to be 500 to 6
It is said that there are 30 species. The task is to resolve at least the listed items as soon as possible and to protect the environment.

Accordingly, the present invention provides a TM-M
The addition of ozone to a single metal made of a combination of a non-metallic D metal and a metal of TM-M and R-TM metal as auxiliary magnetism enhances the sterilization effect and safely treats harmful substances. The MD system contains, as a main component, one or more alloys of Fe, Ni and CO, and contains 15 to 30 atomic% of one or more MD elements. TM
-M system contains more than 40 atomic% of Zr, Ti, Hf, etc.
The balance is CO-Zr, Ni-Zr, and CO-Ti, which are transfer metals.
Rd-TM system composed of transition metal and rare earth metal has Gd, C
O. The rare earth metals are of the genus scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erpium, thulium, ytterbium, lutetium, rare metal, REM. Carbide in plant system. 4-
210624, US 5198469, 6-1070
93, 8-157828, 8-176600, 9-18
Focusing on a method containing at least one selected from the items consisting of 8871 and 9-310070, a remover for a compound containing a heavy metal / chlorine-based dioxin and a composition of an apparatus method for removing the compound are widely applicable.

The present invention will be described in more detail with reference to the following examples. These examples are for illustrative purposes only and are not intended to limit the invention in any way.

[Embodiment 1] The embodiment shows the first, second and third embodiments. By attaching a magnetic substance to the agent incorporated in the removal of compounds containing heavy metals and chlorine-based dioxins, substances with heavy metals and chlorine exceeding the values specified in JIS K 0102 are not detected (according to the factory drainage test method) and the Ministry of Health and Welfare Food hygiene 5 Bacteria test was not detected and proved to be safe.

[Effects of the Invention] It has been confirmed that the magnetic properties are high corrosion resistance, high saturation magnetic flux density, high magnetic permeability, high magnetostriction, superconductivity, and high toughness. The effect of vegetable carbonization and rust at 0.01 ppm of ozone are also confirmed. No, that is, no peroxide was generated and the taste was not deteriorated. Fe ₄₀ Ni ₄₀ P ₁₄ B ₆ , Fe
_{80 B 20, Fe 82 B 10} Si 8, Fe 81 B 13.
_{5 Si 3-5 C 2, Fe 40} Ni 38, MO 4 B 18,
CO ₇₅ Si ₁₅ B ₃₀ , Fe ₇₂ Cr ₃ P ₁₃ C ₇ ,
Pd ₈₀ Si ₂₀ , Fe ₇₀ Cr ₁₀ P ₁₃ C ₇ Fe
₇₈ Cr ₁₀ Ni ₆ C ₇ , FeCr ₁₀ PBC ₇ , Fe
_{Cr 10 Ni 5 P 13 C 7} , 18Cr-BNi like, check field, on the superconducting critical temperature critical current is high, be mechanical properties is not deteriorated by irradiation

 ────────────────────────────────────────────────── ─── Continued on the front page F term (reference) 4D038 AA02 AA04 AB02 AB03 AB09 AB14 AB15 AB26 AB32 AB40 AB43 AB58 AB59 AB63 AB66 BB11 BB12 4D050 AA02 AA04 AB02 AB03 AB06 AB11 AB13 AB15 AB19 AB27 AB33 AB38 AB47 AB52 AB55 BB06 CA11 CA12 DA03 DB01 DB09 DB18 DB19 DC02 DC03 DC08 DC10 DC11 DC16 DC19 DC20 DC22 EA17 ED03

Claims (3)

[Claims] The present invention relates to a non-metallic TM-MD metal and a metal of TM-M and R-TM metal combined with an auxiliary magnetism to add ozone to a single metal to enhance the sterilizing effect and increase harmful substances. Of heavy metal / chlorine-based dioxin-containing compounds for safe treatment of wastewater 2. The TM-MD system contains, as a main component, one or more alloys of Fe, Ni, and CO, and contains 15 to 30 atomic% of one or more MD elements. The TM-M system contains 40 atomic% or more of Zr, Ti, Hf, etc., and the balance is CO-Zr, Ni-Zr, CO-Ti of transfer metals. Gd, CO is used for the R-TM system composed of transition metals and rare earth metals. The rare earth metals are of the genus scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erpium, thulium, ytterbium, lutetium, rare metal, R
EM. Carbide in plant system. The composition for the method for removing a heavy metal / chlorine-containing dioxin-containing compound according to claim 1, which comprises at least one member selected from the genus consisting of: 3. Published Japanese Patent Application No. 4-210624, U.S. Pat. No. 5,198,469, 6-107093, 8-1578.
28, 8-176600, 9-188871, 9-31
3. The removing agent for a compound containing a heavy metal / chlorine-based dioxin according to claim 1, which contains at least one member selected from the group consisting of 0070;