JP2000355675A - Coating using natural material - Google Patents
Coating using natural materialInfo
- Publication number
- JP2000355675A JP2000355675A JP11168243A JP16824399A JP2000355675A JP 2000355675 A JP2000355675 A JP 2000355675A JP 11168243 A JP11168243 A JP 11168243A JP 16824399 A JP16824399 A JP 16824399A JP 2000355675 A JP2000355675 A JP 2000355675A
- Authority
- JP
- Japan
- Prior art keywords
- coating
- glue
- weight
- natural material
- natural
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D189/00—Coating compositions based on proteins; Coating compositions based on derivatives thereof
- C09D189/04—Products derived from waste materials, e.g. horn, hoof or hair
- C09D189/06—Products derived from waste materials, e.g. horn, hoof or hair derived from leather or skin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、主に木製品用の塗
布剤として有効な天然素材を用いた塗布剤に係り、塗
料,塗料下地剤,接着剤等として機能する天然素材を用
いた塗布剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a coating material using a natural material which is effective mainly as a coating material for wood products, and to a coating material using a natural material which functions as a paint, a paint base material, an adhesive, and the like. About.
【0002】[0002]
【従来の技術】一般に、木製品用等の塗布剤としては、
各種塗料,塗料下地剤,接着剤等があるが、近年、これ
らの塗料,塗料下地剤,接着剤等を使用することによ
り、あるいは、廃棄すること等によって、大気汚染、土
壌汚染などの環境汚染が生じ、人体に対する様々なアレ
ルギー反応や細胞の奇形等を引起こす原因となることか
ら、できるだけ、無公害な原材料を用いて製造すること
が望まれている。これを解決するために、本願出願人
は、化学合成の原材料に代えて天然素材を用いた有機物
の原材料を使用して製造し、これらの汚染の原因をでき
るだけ作らないようにする研究開発を行ない、有機物と
してニカワを含んで構成される天然素材を用いた塗布剤
の研究を試行錯誤しながら進めてきた。2. Description of the Related Art In general, coating agents for wood products and the like include:
There are various paints, paint base materials, adhesives, etc. In recent years, environmental pollution such as air pollution and soil pollution has been caused by using or discarding these paints, paint base materials, adhesives, etc. This causes various allergic reactions to the human body and cell deformity. Therefore, it is desired to produce the raw materials using pollution-free raw materials as much as possible. In order to solve this, the applicant of the present application has conducted research and development in which organic materials using natural materials are used in place of raw materials for chemical synthesis, and the cause of these contaminations is minimized. We have been conducting trial and error research on coating materials using natural materials composed of glue as an organic substance.
【0003】[0003]
【発明が解決しようとする課題】ところで、この研究し
てきた塗布剤においては、ニカワを使用しているが、ニ
カワは湯煎する等して粘度を低くして用いなければ、他
の組成物との均一な混合状態が得られない等の支障が生
じるので、取扱が煩雑になっているという問題があっ
た。本発明は、このような問題点に鑑みてなされたもの
で、天然素材を用いた有機物の原材料を使用してできる
だけ環境汚染物質が発生しないようにするとともに、ニ
カワと他の成分との混合性を向上させて取扱を容易にし
た天然素材を用いた塗布剤を提供することを目的とす
る。By the way, glue is used in the coating agent which has been studied, but glue is not used with other compositions unless the viscosity is reduced by baking water or the like. Since troubles such as the inability to obtain a uniform mixed state occur, there has been a problem that handling is complicated. The present invention has been made in view of such problems, and uses an organic raw material made of a natural material to minimize the generation of environmental pollutants, and to improve the compatibility between glue and other components. It is an object of the present invention to provide a coating material using a natural material which has been improved in ease of handling.
【0004】[0004]
【課題を解決するための手段】このような課題を解決す
るための本発明の技術的手段は、有機物としてニカワを
含んで構成され木材等の被塗布材に塗布される天然素材
を用いた塗布剤において、木酢液を含む構成としてい
る。ニカワ(膠)とは、一般に、不純物を含んだ低品質
ゼラチン質の総称であり、一般には、動物の皮や骨から
作られた動物膠(こう)を指す。水を加えるとコロイド
状になって溶け、加温するとゾル状になり再び冷却する
とゲル状になる。木酢液は、木材を乾留して得られる液
体で、酢酸を主成分とする。この木酢液の酢酸成分がニ
カワに作用し、ニカワを常温でも液状に保持できるよう
にする。そのため、他の組成物との均一な混合状態が得
られるようになり、粘性による取扱の煩雑さが解消され
るとともに、ニカワ及び木酢ともに天然素材を用いた有
機物の原材料であり、使用することにより、あるいは、
廃棄すること等によって、大気汚染、土壌汚染などの環
境汚染が抑制される。The technical means of the present invention for solving the above-mentioned problems is to apply a natural material which is constituted by containing glue as an organic substance and is applied to a material to be applied such as wood. The composition contains a wood vinegar solution. The glue is a general term for low-quality gelatin containing impurities, and generally refers to animal glue made from animal skin and bone. When water is added, it becomes a colloid and dissolves. When heated, it becomes a sol, and when cooled again, it becomes a gel. Wood vinegar is a liquid obtained by carbonizing wood, and contains acetic acid as a main component. The acetic acid component of the wood vinegar acts on the glue so that the glue can be kept in a liquid state even at room temperature. For this reason, a uniform mixed state with other compositions can be obtained, and the complexity of handling due to viscosity is eliminated, and both glue and wood vinegar are raw materials of organic substances using natural materials, and by using them, Or
Disposal and the like suppresses environmental pollution such as air pollution and soil pollution.
【0005】このような構成の天然素材を用いた塗布剤
として、本願出願人は、以下の(A)(B)(C)の3
種類の塗布剤を開発した。 (A)塗料として機能する天然素材を用いた塗布剤 これは、有機物として塗料主原料及びニカワを含んで構
成され木材等の被塗布材に塗布されて塗料として機能す
る天然素材を用いた塗布剤において、pH=3〜4の精
製木酢液を、5〜15重量%含む構成としている。望ま
しくは、上記精製木酢液を、6〜9重量%含む。5重量
%に満たないと、十分にニカワの粘度を低下させること
ができないし、15重量%を越えると、流動化し過ぎて
しまう。精製木酢液は、原液を真空蒸留等で成分調整す
るとともに、pH=3〜4になるように調整することに
より得られる。[0005] As a coating agent using a natural material having such a configuration, the present applicant has proposed the following three types (A), (B) and (C).
A variety of coatings have been developed. (A) Coating agent using natural material functioning as paint This is a coating agent using a natural material which is composed of a main material of coating material and glue as an organic material and is applied to a material to be coated such as wood to function as a coating material. , The composition contains 5 to 15% by weight of a purified wood vinegar solution having a pH of 3 to 4. Desirably, the purified wood vinegar is contained in an amount of 6 to 9% by weight. If it is less than 5% by weight, the viscosity of the glue cannot be sufficiently reduced, and if it exceeds 15% by weight, it will be too fluid. The purified wood vinegar solution is obtained by adjusting the components of the stock solution by vacuum distillation or the like and adjusting the pH to 3-4.
【0006】そして、必要に応じ、上記塗料主原料とし
て、柿渋液を用いた構成としている。柿渋液は、60〜
80重量%有することが望ましい。一般に、柿渋液は、
青い未熟の渋柿を絞り、発酵後、2〜3年熟成させた濃
褐色の液体である。柿渋は、高分子タンニンを主成分と
し、銀杏のような独特の臭みがあるが、乾燥により抜
け、日光に当たると、次第に色が濃くなる。また、塗料
機能のみならず、防虫,防水,防腐,抗菌作用も呈す
る。また、必要に応じ、上記ニカワを10〜15重量%
有する構成としている。[0006] If necessary, a persimmon juice liquid is used as the paint main material. Persimmon juice is 60 ~
It is desirable to have 80% by weight. Generally, persimmon juice is
It is a dark brown liquid obtained by squeezing blue immature astringent persimmon, fermenting, and aging for 2-3 years. Persimmon astringent contains high molecular weight tannin as a main component and has a unique smell like ginkgo, but it comes off when dried and gradually becomes darker in sunlight. In addition, it has not only a paint function but also insect repellent, waterproof, antiseptic and antibacterial effects. If necessary, the glue is added in an amount of 10 to 15% by weight.
Configuration.
【0007】このような構成により、塗料として機能す
る塗布剤においては、使用に際しては、塗布表面強度並
びに保護効果が増強するとともに、表面の硬化乾燥速度
が速まるようになる。これは、ニカワのコンドロイチン
成分が、柿渋と木酢液の混合液を配合することにより均
等に分布することになり、硬化速度がより促進されるこ
とに起因するものと考えられる。また、柿渋に木酢液を
混合することにより、柿渋の防水効果がより高められ、
また塗布面に対する均一性を向上させる相互作用がある
と考えられる。[0007] With such a configuration, in the case of a coating agent which functions as a coating material, the coating surface strength and the protective effect are enhanced when used, and the curing and drying speed of the surface is increased. This is considered to be due to the fact that the chondroitin component of glue will be evenly distributed by mixing a mixture of persimmon juice and wood vinegar, and the curing speed will be further accelerated. In addition, by mixing wood vinegar with persimmon juice, the waterproof effect of persimmon juice is enhanced,
Further, it is considered that there is an interaction for improving the uniformity on the application surface.
【0008】そして、必要に応じ、10重量%以下のヒ
バ油を添加した構成としている。また、必要に応じ、1
0重量%以下のワサビ油を添加した構成としている。一
般に、ヒバ油は、ヒノキ油とも言われ、ヒバ材等のオガ
クズを水蒸気蒸留法等により処理して抽出される。その
成分は、ツヨプセン等の中性油とヒノキチオールを初め
とする10%程度の酸性油との混合液である。このヒノ
キチオール等の成分が極めて強い抗菌力を示す。また、
一般に、ワサビ油は、ワサビ(山葵)の根茎から抽出し
たテルペン類やケトン類を含む精油成分で構成される。
シニグリンという配糖体とこれを分解するミロシナーゼ
と呼ばれる酵素とが、水分を加えると揮発性の精油を遊
離し、独特の香りを発生し、防腐殺菌作用も非常に強
い。この構成により、殺菌,抗菌,防カビ等の作用が発
揮されるとともに、加えて、表面の皮膜の強化作用等を
発揮させる作用も考えられ塗料としての機能が拡大する
ことが考えられる。[0008] If necessary, hiba oil is added in an amount of 10% by weight or less. Also, if necessary,
The composition is such that 0% by weight or less of wasabi oil is added. Generally, hiba oil is also called hinoki oil, and is extracted by treating sawdust such as hiba wood by a steam distillation method or the like. The component is a mixture of a neutral oil such as Tuyobsen and about 10% of an acidic oil such as hinokitiol. Components such as hinokitiol exhibit extremely strong antibacterial activity. Also,
Generally, wasabi oil is composed of an essential oil component containing terpenes and ketones extracted from the rhizome of wasabi (wasabi).
A glycoside called sinigrin and an enzyme called myrosinase, which degrades it, release volatile essential oils when water is added, generate a unique fragrance, and have a very strong antiseptic and bactericidal action. With this configuration, functions such as sterilization, antibacterial action, and antifungal action are exhibited, and in addition, an action of exerting a strengthening action of the surface film is also considered, so that the function as a paint may be expanded.
【0009】(B)塗料下地剤として機能する天然素材
を用いた塗布剤 これは、砥粉を有するとともに有機物としてニカワを含
んで構成され木材等の被塗布材に塗布されて塗料下地剤
として機能する天然素材を用いた塗布剤において、pH
=3〜4の精製木酢液を、15〜25重量%含む構成と
している。望ましくは、上記精製木酢液を、20〜22
重量%含む。15重量%に満たないと、十分にニカワの
粘度を低下させることができないし、25重量%を越え
ると、流動化し過ぎてしまう。そして、必要に応じ、上
記砥粉を30〜40重量%有する構成としている。ま
た、必要に応じ、上記ニカワを15〜30重量%有する
構成としている。(B) Coating agent using a natural material functioning as a coating base material This coating material has abrasive powder and contains organic glue as an organic substance, and is applied to a coating material such as wood to function as a coating base material. PH of natural materials
= 3-4 purified wood vinegar is contained in an amount of 15-25% by weight. Desirably, the purified wood vinegar solution is 20 to 22
% By weight. If it is less than 15% by weight, the viscosity of the glue cannot be sufficiently reduced, and if it exceeds 25% by weight, it will be too fluid. And it is set as the structure which contains the said abrasive powder 30-40 weight% as needed. In addition, if necessary, the composition is configured to have the above-mentioned glue in an amount of 15 to 30% by weight.
【0010】この構成により、塗料下地剤は木材等の被
塗布材加工品の塗装前の塗布面の凹凸を排除することに
最大の目的を有するが、この凹凸排除機能が従来から有
る塗料下地剤に比較して大幅に向上した。即ち、従来の
方式は「水」を使用し砥粉を泥状にするため、時間的経
過とともに、砥粉と水が完全に分離したが、砥粉に木酢
液を加えることにより、均一に混合され分離することが
ない。これは、木酢液に微量に含まれているフェノール
類の遊離作用の働きにより、完全に泥状に均等混合さ
れ、持続するものと考えられる。これにより凹凸に万遍
なく侵入し易くなり、凹凸排除機能が向上させられるの
である。With this configuration, the paint base material has the greatest purpose of eliminating irregularities on the coated surface of a workpiece such as wood before coating, but the paint base material which has a function of removing irregularities has been conventionally used. Greatly improved compared to. In other words, the conventional method uses "water" to make the abrasive powder muddy, and with the passage of time, the abrasive powder and water are completely separated, but by adding wood vinegar to the abrasive powder, they are uniformly mixed and separated. Nothing. This is considered to be due to the action of liberating the phenols contained in the wood vinegar in a trace amount, and to be completely and uniformly mixed in a mud-like manner and to be sustained. As a result, it is easy to uniformly enter the unevenness, and the unevenness eliminating function is improved.
【0011】更に、必要に応じ、粉状のもち米を加えた
構成としている。もち米は、10〜30重量%加えるこ
とが望ましい。これにより、ニカワの他にもち米を加え
るので、もち米は砥粉に比較して柔らかいことから、被
塗布材の凹凸部分にこれらが侵入し易く、付着効果及び
硬化作用が増強され、凹凸面の排除能力が向上させら
れ、塗布表面を均一にすることが可能となる。更にま
た、必要に応じ、2重量%以下のヒバ油を添加した構成
としている。殺菌,抗菌,防カビ等の作用が発揮される
とともに、加えて、表面の皮膜の強化作用等を発揮させ
る作用も考えられ下地機能が拡大することが考えられ
る。Further, if necessary, a powdery sticky rice is added. It is desirable to add 10 to 30% by weight of glutinous rice. As a result, glue rice is added in addition to glue, so glutinous rice is softer than abrasive powder, so that these easily penetrate into the uneven portions of the material to be coated, the adhesion effect and the hardening effect are enhanced, and the uneven surface is improved. The rejection ability is improved, and the coating surface can be made uniform. Furthermore, if necessary, 2 wt% or less of hiba oil is added. In addition to the effects of disinfecting, antibacterial, and antifungal, the effect of strengthening the surface film is also considered, and the underlying function may be expanded.
【0012】(C)接着剤として機能する天然素材 これは、有機物として60%以上のニカワを含んで構成
され木材等の被塗布材に塗布されて接着剤として機能す
る天然素材を用いた塗布剤において、pH=3〜4の精
製木酢液を、5〜10重量%含む構成としている。望ま
しくは、上記精製木酢液を、7〜8重量%含む。5重量
%に満たないと、十分にニカワの粘度を低下させること
ができないし、10重量%を越えると、流動化し過ぎて
しまう。この構成により、接着剤本来の目的は木材等の
被塗布材に使用する場合、塗装前に塗布面が凹凸状態に
あることを利用し、原材料に浸潤し接着硬化することが
最大の目的であるが、木酢液を混合したので、ニカワが
液状になり、そのため、接着面の硬化強度並びに凹凸部
分に対する浸潤速度がより増強され、浸透性が均一化さ
れる。また、従来から有る石油化学系の接着剤では、硬
化のために化学系溶解剤を添加し、揮発性物質で溶解状
態を確保する等するので、硬化時点や焼却時点で、毒性
の強い揮発性物質が気化することが多く、人体に有害で
あると考えられる環境ホルモン等が排泄されることが懸
念されるが、本発明で開発されたこの接着剤は、原材料
として天然素材を使用しているので、環境汚染並びに環
境ホルモン等の排泄が抑止される。(C) Natural material functioning as an adhesive This is a coating agent using a natural material which is composed of organic substances containing not less than 60% glue and is applied to a material to be coated such as wood to function as an adhesive. In the above, the purified wood vinegar having a pH of 3 to 4 is contained in an amount of 5 to 10% by weight. Preferably, the purified wood vinegar solution is contained in an amount of 7 to 8% by weight. If the amount is less than 5% by weight, the viscosity of the glue cannot be sufficiently reduced, and if it exceeds 10% by weight, the glue is excessively fluidized. With this configuration, the primary purpose of the adhesive, when used for a material to be coated such as wood, is to make use of the fact that the applied surface is uneven before coating, so that the greatest purpose is to infiltrate the raw material and cure the adhesive. However, since the wood vinegar liquid is mixed, the glue becomes liquid, and therefore, the curing strength of the bonding surface and the infiltration rate to the uneven portion are further enhanced, and the permeability is made uniform. In addition, with conventional petrochemical adhesives, a chemical dissolving agent is added for curing and a dissolved state is secured with volatile substances. Substances often evaporate, and there is a concern that excretion of environmental hormones and the like, which are considered harmful to the human body, may occur.However, this adhesive developed in the present invention uses a natural material as a raw material. Therefore, environmental pollution and excretion of environmental hormones are suppressed.
【0013】そして、必要に応じ、粉状のもち米を加え
た構成としている。もち米は、15〜30重量%加える
ことが望ましい。これにより、ニカワの他にもち米を加
えるので、接着面の硬化強度並びに凹凸部分に対する浸
潤速度がより増強され、浸透性を均一化する作用が向上
させられる。また、必要に応じ、2重量%以下のヒバ油
を添加した構成としている。更に、必要に応じ、2重量
%以下のワサビ油を添加した構成としている。この構成
により、殺菌,抗菌,防カビ等の作用が発揮されるとと
もに、加えて、接着の強化作用等を発揮させる作用も考
えられ接着剤としての機能が拡大することが考えられ
る。[0013] If necessary, powdery glutinous rice is added. It is desirable to add 15 to 30% by weight of glutinous rice. As a result, glue rice is added in addition to glue, so that the curing strength of the adhesive surface and the infiltration rate with respect to the uneven portion are further enhanced, and the effect of making the permeability uniform is improved. In addition, the composition is such that 2% by weight or less of hiba oil is added as required. Further, if necessary, 2 wt% or less of wasabi oil is added. With this configuration, functions such as sterilization, antibacterial action, and antifungal action are exhibited, and in addition, an action of exerting an action of strengthening adhesion is also considered, and the function as an adhesive is considered to be expanded.
【0014】[0014]
【発明の実施の形態】以下、添付図面に基づいて本発明
の実施の形態に係る天然素材を用いた塗布剤を説明す
る。 (A)本発明の第一の実施の形態に係る天然素材を用い
た塗布剤は、塗料として機能する塗布剤である。図1に
示すように、この塗布剤は、有機物として塗料主原料及
びニカワを含んで構成される。塗料主原料としては柿渋
液が用いられる。柿渋液の成分量は71.9〜72.1
重量%である。また、ニカワの成分量は12.5〜1
3.4重量%である。そして、pH=3〜4の精製木酢
液を、7.5〜7.6重量%含む構成としている。精製
木酢液は、原液を真空蒸留等で成分調整するとともに、
pH=3〜4になるように調整することにより得られ
る。参考のために、図7に木酢液原液の成分表を示す。
また、4.1〜4.2重量%のヒバ油及び3.1〜3.
6重量%のワサビ油が添加されている。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, a coating material using a natural material according to an embodiment of the present invention will be described with reference to the accompanying drawings. (A) The coating agent using a natural material according to the first embodiment of the present invention is a coating agent that functions as a coating material. As shown in FIG. 1, this coating agent is configured to include a main coating material and glue as organic substances. Persimmon juice liquid is used as the main material of the paint. The component amount of persimmon juice liquid is 71.9 to 72.1
% By weight. The amount of glue is 12.5-1.
3.4% by weight. And it is set as the composition containing 7.5-7.6 weight% of refined wood vinegar liquid of pH = 3-4. The purified wood vinegar is prepared by adjusting the ingredients of the stock solution by vacuum distillation, etc.
It is obtained by adjusting the pH to 3-4. For reference, FIG. 7 shows a component table of the undiluted wood vinegar solution.
In addition, 4.1 to 4.2% by weight of hiba oil and 3.1 to 3.
6% by weight of wasabi oil was added.
【0015】次に、図2に示す工程図を用い、この塗布
剤の製造工程について説明する。 工程1.柿渋液に精製木酢液を少量ずつ加えゆっくり混
ぜ合わせる。 工程2.ニカワを湯煎し、液状に成ってから、工程1で
作成した液を加える。 この場合、ニカワのコンドロイチン成分が、柿渋液と精
製木酢液の混合液を配合することにより均等に分布する
ようになる。 工程3.ヒノキ油とワサビ油を良く混ぜ合わせる。 工程4.工程3で作成した混合液を工程2で作成した液
に滴下し、攪拌して混ぜ合わせる。Next, the manufacturing process of this coating agent will be described with reference to the process chart shown in FIG. Step 1. Add the purified wood vinegar solution to the persimmon astringent solution little by little and mix slowly. Step 2. After the glue is roasted and turned into a liquid, the liquid prepared in step 1 is added. In this case, the chondroitin component of glue will be evenly distributed by mixing a mixture of persimmon juice and purified wood vinegar. Step 3. Mix cypress oil and wasabi oil well. Step 4. The liquid mixture prepared in step 3 is dropped into the liquid prepared in step 2 and mixed by stirring.
【0016】これにより製造された塗布剤は、使用に際
しては、ニカワのコンドロイチン成分が均等に分布する
ようになるので、硬化速度がより促進され、塗布表面強
度並びに保護効果が増強するとともに、表面の硬化乾燥
速度が速まるようになる。また、柿渋液に木酢液を混合
したので、柿渋の防水効果がより高められ、また塗布面
に対する均一性が向上させられる。更に、ヒノキ油とワ
サビ油が添加されているので、殺菌,抗菌,防カビ等の
作用が発揮されるとともに、加えて、表面の皮膜の強化
作用が発揮される。When the coating composition thus manufactured is used, the chondroitin component of glue is evenly distributed, so that the curing speed is further accelerated, the coating surface strength and the protective effect are enhanced, and The curing and drying speed is increased. In addition, since the wood vinegar liquid is mixed with the persimmon juice liquid, the waterproofing effect of the persimmon juice is further enhanced, and the uniformity of the applied surface is improved. Furthermore, since cypress oil and wasabi oil are added, the action of sterilization, antibacterial, antifungal and the like is exhibited, and in addition, the action of strengthening the surface film is exhibited.
【0017】(B)本発明の第二の実施の形態に係る天
然素材を用いた塗布剤は、塗料下地剤として機能する塗
布剤である。図3に示すように、この塗布剤は、砥粉を
有するとともに有機物としてニカワを含んで構成され
る。砥粉の成分量は、33.2〜37.3重量%であ
る。ニカワの成分量は、18.1〜25.7重量%であ
る。そして、pH=3〜4の精製木酢液を、21.6〜
21.8重量%含む構成としている。更に、粉状のもち
米を14.5〜25.9重量%加えている。また、0.
9〜1.0重量%のヒバ油を添加している。(B) The coating material using a natural material according to the second embodiment of the present invention is a coating material that functions as a paint base material. As shown in FIG. 3, the coating agent has abrasive powder and organic glue. The component amount of the abrasive powder is 33.2 to 37.3% by weight. The component amount of glue is 18.1 to 25.7% by weight. Then, a purified wood vinegar solution having a pH of 3 to 4 was added to
It is configured to contain 21.8% by weight. Further, 14.5 to 25.9% by weight of powdery glutinous rice is added. Also, 0.
9-1.0% by weight of hiba oil is added.
【0018】次に、図4に示す工程図を用い、この塗布
剤の製造工程について説明する。 工程1.砥粉に精製木酢液を加え、泥状均等になるまで
混ぜ合わせる。この場合、砥粉に精製木酢液を加えるこ
とにより、木酢液に微量に含まれているフェノール類の
遊離作用の働きにより、完全に泥状に均等混合され、均
一に混合され分離することがなくなる。そのため、従来
の水を使用して砥粉を泥状にする場合には、時間的経過
とともに砥粉と水が完全に分離したが、これがなくな
る。 工程2.ニカワを湯煎し、液状に成ってから、工程1で
作成した液に加える。 工程3.ヒノキ油をもち米に良く混ぜ合わせる。 工程4.工程3の混合物を工程2で作成した液に少量ず
つ加え、ゆっくり攪拌し、混ぜ合わせる。Next, the manufacturing process of this coating agent will be described with reference to the process chart shown in FIG. Step 1. Add purified wood vinegar to the grind and mix until the mixture is muddy. In this case, by adding the purified wood vinegar solution to the abrasive powder, the phenols contained in the wood vinegar solution in a very small amount are released, and the phenols are completely mixed in a mud-like manner, and are not uniformly mixed and separated. Therefore, in the case where the abrasive powder is made muddy using conventional water, the abrasive powder and the water are completely separated with the passage of time, but this disappears. Step 2. The glue is roasted in water and turned into a liquid, and then added to the liquid prepared in step 1. Step 3. Mix the cypress oil with the glutinous rice. Step 4. The mixture of step 3 is added little by little to the liquid prepared in step 2, stirred slowly and mixed.
【0019】これにより製造された塗布剤は、使用に際
しては、砥粉が完全に泥状に均等混合され、持続するの
で、被塗布材の塗装前の塗布面の凹凸に良く侵入して凹
凸が確実に排除される。また、粉状のもち米を加えてい
るので、もち米は砥粉に比較して柔らかいことから、被
塗布材の凹凸部分にこれらが侵入し易く、付着効果及び
硬化作用が増強され、凹凸面の排除能力が向上させら
れ、塗布表面がより一層均一化される。更に、ヒバ油の
添加により、殺菌,抗菌,防カビ等の作用が発揮される
とともに、加えて、表面の皮膜の強化作用等が発揮させ
られる。When the coating material thus manufactured is used, the abrasive powder is completely and uniformly mixed in a mud-like state and lasts. To be eliminated. In addition, since powdery glutinous rice is added, since glutinous rice is softer than abrasive powder, it is easy for these to penetrate into the uneven portions of the material to be coated, the adhesion effect and the hardening effect are enhanced, and the uneven surface is improved. The rejection ability is improved, and the coating surface is made more uniform. Further, the addition of hiba oil exerts effects such as sterilization, antibacterial and antifungal, and additionally exerts a strengthening effect on the surface film.
【0020】(C)本発明の第三の実施の形態に係る天
然素材を用いた塗布剤は、接着剤として機能する塗布剤
である。図5に示すように、この塗布剤は、有機物とし
て60%以上のニカワを含んで構成される。実施の形態
では、ニカワは65.3〜71.9重量%含む。そし
て、pH=3〜4の精製木酢液を、7.5〜7.6重量
%含む構成としている。また、粉状のもち米を、19.
6〜25.9重量%加えている。更に、0.7〜0.8
重量%のヒバ油及び0.3〜0.4重量%のワサビ油が
添加されている。(C) The coating agent using a natural material according to the third embodiment of the present invention is a coating agent that functions as an adhesive. As shown in FIG. 5, this coating composition contains 60% or more of glue as an organic substance. In an embodiment, the glue contains 65.3 to 71.9% by weight. And it is set as the composition containing 7.5-7.6 weight% of refined wood vinegar liquid of pH = 3-4. In addition, 19.
6 to 25.9% by weight is added. Furthermore, 0.7-0.8
% By weight of hiba oil and 0.3-0.4% by weight of wasabi oil.
【0021】次に、図6に示す工程図を用い、この塗布
剤の製造工程について説明する。 工程1.もち米に精製木酢液を加えながら、ゆっくり混
ぜ合わせる。 工程2.ヒノキ油とワサビ油を良く混ぜ合わせる。 工程3.ニカワを湯煎し、液状に成ってから、工程2で
作成した液を加える。 工程4.工程1で作成した混合物に工程3で作成した液
を少量ずつ加えながら、混ぜ合わせる。この場合、木酢
液を混合したので、ニカワ及びもち米が液状化してい
く。Next, the manufacturing process of this coating agent will be described with reference to the process chart shown in FIG. Step 1. While adding the purified wood vinegar to the glutinous rice, mix slowly. Step 2. Mix cypress oil and wasabi oil well. Step 3. After the glue is roasted and turned into a liquid, the liquid prepared in step 2 is added. Step 4. The liquid prepared in step 3 is added to the mixture prepared in step 1 little by little and mixed. In this case, since the wood vinegar liquid was mixed, glue and glutinous rice liquefied.
【0022】これにより製造された塗布剤は、使用に際
しては、精製木酢液を混合したので、ニカワが液状にな
り、そのため、接着面の硬化強度並びに凹凸部分に対す
る浸潤速度がより増強され、浸透性が均一化される。ま
た、ニカワの他にもち米を加えるので、接着面の硬化強
度並びに凹凸部分に対する浸潤速度がより増強され、浸
透性がより均一化される。更に、ヒバ油及びワサビ油の
添加により、殺菌,抗菌,防カビ等の作用が発揮される
とともに、加えて、接着の強化作用が発揮させられる。[0022] The coating agent produced by mixing purified wood vinegar solution at the time of use, the glue becomes liquid, so that the curing strength of the bonding surface and the rate of infiltration into the uneven portion are further enhanced, and the permeability is improved. Is made uniform. Further, since glue rice is added to glue, the curing strength of the bonding surface and the infiltration rate to the uneven portion are further enhanced, and the permeability is made more uniform. Further, by adding hiba oil and wasabi oil, actions such as sterilization, antibacterial and antifungal are exhibited, and in addition, an action of strengthening adhesion is exhibited.
【0023】[0023]
【発明の効果】以上説明したように、本発明の天然素材
を用いた塗布剤によれば、原材料として使われているも
のが天然原料なので、あらゆる木材等の被塗布材加工品
(例えば、家具,食器,木製品,建材等)並びに家屋等
に使用が可能になる。また、本発明は天然素材を用いた
有機物の原材料で形成するので、大気汚染等の環境汚染
などにより地球が汚染されている現状を考えるに、現在
使用されている塗料,塗料下地剤,接着剤等を使用また
は廃棄することにより起こると考えられる人体に対する
様々なアレルギー反応や細胞の奇形等を、防止すること
ができ、極めて有用になる。例えば、アレルギー過敏症
の人にもアレルギー反応パッチテストの結果、アレルギ
ー過敏症のアレルギー反応は見られないことが確認され
た。即ち、焼却及び廃棄しても、天然素材のみを原材料
としていると、環境汚染物質並びに環境ホルモン(ダイ
オキシン/コプラナーPCB)等々を大気及び土壌に残
留させることがなくなり、環境上極めて有用なものにな
るのである。更に、本発明は、化学合成品を原料とした
塗料,塗料下地剤,接着剤等との同時使用も可能であ
り、他の化学合成品等を原料にした製品の特性を弱体化
することもできるようになる。更にまた、本発明は、実
験の結果、特に漆と併用した場合、漆の使用量を激減さ
せることができることが確認された。これにより、高価
な漆塗り製品の製造が、低コストで生産可能になり、経
済的波及効果は非常に大きいものが有ると考えられる。As described above, according to the coating material using the natural material of the present invention, since the material used as a raw material is a natural raw material, any processed material such as wood (for example, furniture) , Tableware, wooden products, building materials, etc.) and houses. In addition, since the present invention is formed from organic raw materials using natural materials, the presently used paints, paint base materials, and adhesives are considered in view of the current situation in which the earth is polluted by environmental pollution such as air pollution. It is possible to prevent various allergic reactions to the human body and cell deformities, which are considered to be caused by using or discarding, etc., and it becomes extremely useful. For example, as a result of the allergic reaction patch test, it was confirmed that no allergic hypersensitivity allergic reaction was observed in persons with allergic hypersensitivity. That is, even when incinerated and discarded, if only natural materials are used as raw materials, environmental pollutants and environmental hormones (dioxin / coplanar PCB) and the like do not remain in the air and soil, which is extremely useful in the environment. It is. Furthermore, the present invention can also be used simultaneously with paints, paint base materials, adhesives, etc. made from chemically synthesized products, and can also weaken the characteristics of products made from other chemically synthesized products. become able to. Furthermore, as a result of experiments, it has been confirmed that the present invention can drastically reduce the amount of lacquer when used in combination with lacquer. This makes it possible to produce expensive lacquered products at low cost, and the economic ripple effect is considered to be very large.
【0024】また、本発明の塗料として機能する天然素
材を用いた塗布剤によれば、使用に際しては、ニカワの
コンドロイチン成分が均等に分布するようになるので、
硬化速度がより促進され、塗布表面強度並びに保護効果
が増強するとともに、表面の硬化乾燥速度が速まるよう
にすることができる。また、柿渋液に精製木酢液を混合
した場合には、柿渋の防水効果がより高められ、また塗
布面に対する均一性を向上させることができる。更に、
ヒノキ油とワサビ油が添加した場合には、殺菌,抗菌,
防カビ等の作用を発揮させることができるとともに、加
えて、表面の皮膜の強化作用を発揮させることができ
る。According to the coating composition of the present invention using a natural material which functions as a coating material, the chondroitin component of glue becomes evenly distributed when used.
The curing speed is further accelerated, the coating surface strength and the protective effect are enhanced, and the curing and drying speed of the surface can be increased. In addition, when purified wood vinegar is mixed with the persimmon astringent liquid, the waterproofing effect of the persimmon astringent can be further enhanced, and the uniformity of the applied surface can be improved. Furthermore,
When cypress oil and wasabi oil are added, sterilization, antibacterial,
In addition to being able to exert an action such as anti-mold, it can exert an effect of strengthening the surface film.
【0025】更に、本発明の塗料下地剤として機能する
天然素材を用いた塗布剤によれば、使用に際しては、砥
粉が完全に泥状に均等混合され、持続するので、被塗布
材の塗装前の塗布面の凹凸に良く侵入し凹凸を確実に排
除することができる。また、粉状のもち米を加えた場合
には、もち米は砥粉に比較して柔らかいことから、被塗
布材の凹凸部分にこれらが侵入し易く、付着効果及び硬
化作用を増強させ、凹凸面の排除能力を向上させて塗布
表面をより一層均一化させることができる。更に、ヒバ
油を添加した場合には、殺菌,抗菌,防カビ等の作用を
発揮させることができるとともに、表面の皮膜の強化作
用等を発揮させることができる。Furthermore, according to the coating material of the present invention using a natural material which functions as a coating base material, when used, the abrasive powder is completely and uniformly mixed in a mud-like state and lasts. And the irregularities on the coated surface can be well penetrated and the irregularities can be reliably eliminated. In addition, when powdery glutinous rice is added, since glutinous rice is softer than abrasive powder, it is easy for these to penetrate into the uneven portions of the material to be coated, and the adhesion effect and the hardening effect are enhanced, and the uneven surface is improved. And the coating surface can be made more uniform. Furthermore, when hiba oil is added, it is possible to exert effects such as sterilization, antibacterial action and fungicide, and also to exert an effect of strengthening the surface film.
【0026】そしてまた、本発明の接着剤として機能す
る塗布剤によれば、使用に際しては、精製木酢液を混合
したので、ニカワが液状になり、そのため、接着面の硬
化強度並びに凹凸部分に対する浸潤速度がより増強さ
れ、浸透性を均一化することができる。また、ニカワの
他にもち米を加えた場合には、接着面の硬化強度並びに
凹凸部分に対する浸潤速度がより増強され、浸透性をよ
り均一化することができる。更に、ヒバ油及びワサビ油
を添加した場合には、殺菌,抗菌,防カビ等の作用を発
揮させることができるとともに、接着の強化作用を発揮
させることができる。Further, according to the coating agent functioning as the adhesive of the present invention, the glue becomes liquid because the purified wood vinegar is mixed at the time of use, so that the curing strength of the bonding surface and the infiltration of the uneven surface are improved. The speed is further enhanced and the permeability can be made uniform. In addition, when glue rice is added in addition to glue, the curing strength of the bonding surface and the infiltration rate to the uneven portion are further enhanced, and the permeability can be made more uniform. Further, when hiba oil and wasabi oil are added, it is possible to exert effects such as sterilization, antibacterial and antifungal, and also to exert an effect of enhancing adhesion.
【図1】本発明の第一の実施の形態に係る天然素材を用
いた塗布剤の成分構成を示す表図である。FIG. 1 is a table showing the components of a coating composition using a natural material according to a first embodiment of the present invention.
【図2】本発明の第一の実施の形態に係る天然素材を用
いた塗布剤の製造工程を示す図である。FIG. 2 is a diagram showing a manufacturing process of a coating agent using a natural material according to the first embodiment of the present invention.
【図3】本発明の第二の実施の形態に係る天然素材を用
いた塗布剤の成分構成を示す表図である。FIG. 3 is a table showing the components of a coating composition using a natural material according to a second embodiment of the present invention.
【図4】本発明の第二の実施の形態に係る天然素材を用
いた塗布剤の製造工程を示す図である。FIG. 4 is a diagram showing a manufacturing process of a coating agent using a natural material according to a second embodiment of the present invention.
【図5】本発明の第三の実施の形態に係る天然素材を用
いた塗布剤の成分構成を示す表図である。FIG. 5 is a table showing the component composition of a coating composition using a natural material according to a third embodiment of the present invention.
【図6】本発明の第三の実施の形態に係る天然素材を用
いた塗布剤の製造工程を示す図である。FIG. 6 is a view showing a manufacturing process of a coating agent using a natural material according to a third embodiment of the present invention.
【図7】木酢液の原液の成分構成の一例を示す図であ
る。FIG. 7 is a diagram showing an example of the component configuration of a stock solution of wood vinegar.
Claims (21)
材等の被塗布材に塗布される天然素材を用いた塗布剤に
おいて、 木酢液を含むことを特徴とする天然素材を用いた塗布
剤。1. A coating composition using a natural material, which comprises natural glue as an organic substance and is applied to a material to be coated such as wood, wherein the coating material contains a wood vinegar solution.
んで構成され木材等の被塗布材に塗布されて塗料として
機能する天然素材を用いた塗布剤において、pH=3〜
4の精製木酢液を、5〜15重量%含むことを特徴とす
る天然素材を用いた塗布剤。2. An application agent comprising a natural material which contains a main material of coating material and glue as an organic material and is applied to a material to be applied such as wood and functions as a coating material.
A coating agent using a natural material, comprising 5 to 15% by weight of the purified wood vinegar liquid of 4.
とを特徴とする請求項2記載の天然素材を用いた塗布
剤。3. The coating material using a natural material according to claim 2, wherein the purified wood vinegar solution contains 6 to 9% by weight.
ことを特徴とする請求項2または3記載の天然素材を用
いた塗布剤。4. A coating composition using a natural material according to claim 2, wherein a persimmon juice liquid is used as the main raw material of the coating material.
とを特徴とする請求項4記載の天然素材を用いた塗布
剤。5. A coating composition using a natural material according to claim 4, wherein said persimmon juice is contained in an amount of 60 to 80% by weight.
とを特徴とする請求項2,3,4または5記載の天然素
材を用いた塗布剤。6. A coating composition using a natural material according to claim 2, wherein said coating has 10 to 15% by weight of said glue.
を特徴とする請求項2,3,4,5または6記載の天然
素材を用いた塗布剤。7. A coating composition using a natural material according to claim 2, wherein 10% by weight or less of hiba oil is added.
とを特徴とする請求項2,3,4,5,6または7記載
の天然素材を用いた塗布剤。8. A coating composition using a natural material according to claim 2, wherein 10% by weight or less of wasabi oil is added.
ワを含んで構成され木材等の被塗布材に塗布されて塗料
下地剤として機能する天然素材を用いた塗布剤におい
て、pH=3〜4の精製木酢液を、15〜25重量%含
むことを特徴とする天然素材を用いた塗布剤。9. A coating agent using a natural material which has abrasive powder and contains organic glue as an organic substance and which is applied to a material to be coated such as wood and functions as a coating base material. A coating agent using a natural material, comprising 15 to 25% by weight of a liquid.
含むことを特徴とする請求項9記載の天然素材を用いた
塗布剤。10. The purified wood vinegar solution is 20 to 22% by weight.
The coating material using a natural material according to claim 9, wherein the coating material comprises:
とを特徴とする請求項9または10記載の天然素材を用
いた塗布剤。11. A coating material using a natural material according to claim 9, wherein said coating material contains 30 to 40% by weight of said abrasive powder.
ことを特徴とする請求項9,10または11記載の天然
素材を用いた塗布剤。12. A coating composition using a natural material according to claim 9, wherein said glue contains 15 to 30% by weight of said glue.
る請求項9,10,11または12記載の天然素材を用
いた塗布剤。13. A coating composition using a natural material according to claim 9, wherein powdery glutinous rice is added.
たことを特徴とする請求項13記載の天然素材を用いた
塗布剤。14. The coating material according to claim 13, wherein the glutinous rice is added in an amount of 10 to 30% by weight.
を特徴とする請求項9,10,11,12,13または
14記載の天然素材を用いた塗布剤。15. A coating composition using a natural material according to claim 9, wherein 2% by weight or less of hiba oil is added.
んで構成され木材等の被塗布材に塗布されて接着剤とし
て機能する天然素材を用いた塗布剤において、pH=3
〜4の精製木酢液を、5〜10重量%含むことを特徴と
する天然素材を用いた塗布剤。16. An application agent made of a natural material which contains 60% or more glue as an organic substance and is applied to a material to be applied such as wood and functions as an adhesive, wherein pH = 3.
A coating agent using a natural material, comprising 5 to 10% by weight of the purified wood vinegar liquid of No. 4 to No. 4.
ことを特徴とする請求項16記載の天然素材を用いた塗
布剤。17. The coating agent using a natural material according to claim 16, wherein the purified wood vinegar solution is contained in an amount of 7 to 8% by weight.
る請求項16または17記載の天然素材を用いた塗布
剤。18. A coating composition using a natural material according to claim 16, wherein powdery glutinous rice is added.
たことを特徴とする請求項18記載の天然素材を用いた
塗布剤。19. The coating material according to claim 18, wherein the glutinous rice is added in an amount of 15 to 30% by weight.
を特徴とする請求項16,17,18または19記載の
天然素材を用いた塗布剤。20. A coating composition using a natural material according to claim 16, wherein hiba oil is added in an amount of 2% by weight or less.
とを特徴とする請求項16,17,18,19または2
0記載の天然素材を用いた塗布剤。21. The method according to claim 16, wherein 2% by weight or less of wasabi oil is added.
A coating agent using the natural material described in Item 0.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16824399A JP3448514B2 (en) | 1999-06-15 | 1999-06-15 | Coating agent using natural materials |
PCT/JP2000/003718 WO2000077106A1 (en) | 1999-06-15 | 2000-06-08 | Coatings with the use of natural materials |
AU52457/00A AU5245700A (en) | 1999-06-15 | 2000-06-08 | Coatings with the use of natural materials |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16824399A JP3448514B2 (en) | 1999-06-15 | 1999-06-15 | Coating agent using natural materials |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2000355675A true JP2000355675A (en) | 2000-12-26 |
JP3448514B2 JP3448514B2 (en) | 2003-09-22 |
Family
ID=15864424
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP16824399A Expired - Fee Related JP3448514B2 (en) | 1999-06-15 | 1999-06-15 | Coating agent using natural materials |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP3448514B2 (en) |
AU (1) | AU5245700A (en) |
WO (1) | WO2000077106A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008115352A (en) * | 2006-10-12 | 2008-05-22 | Sumitomo Forestry Co Ltd | High water-resistant resin layer-forming agent |
JP2008274056A (en) * | 2007-04-27 | 2008-11-13 | Sumitomo Forestry Co Ltd | Primer for japanese lacquer coating |
JP2009007498A (en) * | 2007-06-28 | 2009-01-15 | Sumitomo Forestry Co Ltd | Composition for highly weather-resisting coating material |
JP2012158733A (en) * | 2011-01-28 | 2012-08-23 | Eri Hayashi | Composite comprising urusi (or japanese lacquer) mixture and natural fiber |
CN107190522A (en) * | 2017-07-24 | 2017-09-22 | 安徽柏拉图涂层织物有限公司 | A kind of preparation method of antibacterial and deodouring coating cloth for cleaning up excrement band |
JP2022031591A (en) * | 2020-08-08 | 2022-02-21 | 株式会社松本工業所 | Paper material structure and adhesive for paper material |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102054457B1 (en) * | 2019-09-02 | 2019-12-10 | 주식회사 아이템 | Wood panel and its manufacturing method thereof |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4945786B1 (en) * | 1969-02-19 | 1974-12-06 | ||
JPH10158549A (en) * | 1996-11-27 | 1998-06-16 | Chiyafuroozu Corp:Kk | Coating material |
JPH1134012A (en) * | 1997-07-22 | 1999-02-09 | Kiyoshi Kamiyama | Preservative coating for lumber, and preservative applying method for lumber |
-
1999
- 1999-06-15 JP JP16824399A patent/JP3448514B2/en not_active Expired - Fee Related
-
2000
- 2000-06-08 AU AU52457/00A patent/AU5245700A/en not_active Abandoned
- 2000-06-08 WO PCT/JP2000/003718 patent/WO2000077106A1/en active Application Filing
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008115352A (en) * | 2006-10-12 | 2008-05-22 | Sumitomo Forestry Co Ltd | High water-resistant resin layer-forming agent |
JP4648299B2 (en) * | 2006-10-12 | 2011-03-09 | 住友林業株式会社 | High water resistant resin layer forming agent |
JP2008274056A (en) * | 2007-04-27 | 2008-11-13 | Sumitomo Forestry Co Ltd | Primer for japanese lacquer coating |
JP2009007498A (en) * | 2007-06-28 | 2009-01-15 | Sumitomo Forestry Co Ltd | Composition for highly weather-resisting coating material |
JP2012158733A (en) * | 2011-01-28 | 2012-08-23 | Eri Hayashi | Composite comprising urusi (or japanese lacquer) mixture and natural fiber |
CN107190522A (en) * | 2017-07-24 | 2017-09-22 | 安徽柏拉图涂层织物有限公司 | A kind of preparation method of antibacterial and deodouring coating cloth for cleaning up excrement band |
JP2022031591A (en) * | 2020-08-08 | 2022-02-21 | 株式会社松本工業所 | Paper material structure and adhesive for paper material |
JP7236746B2 (en) | 2020-08-08 | 2023-03-10 | 株式会社松本工業所 | Adhesives for paper structures and paper materials |
Also Published As
Publication number | Publication date |
---|---|
JP3448514B2 (en) | 2003-09-22 |
AU5245700A (en) | 2001-01-02 |
WO2000077106A1 (en) | 2000-12-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100553475B1 (en) | Natural adhesive composition utilizing glue | |
JP2000355675A (en) | Coating using natural material | |
CN107459874A (en) | A kind of sealer and preparation method thereof | |
CA1188459A (en) | Wood preservative composition | |
EP1426420A3 (en) | The use of surfactants as plasticizers to reduce volatile organic compounds in water-based polymer coating compositions | |
EP0152852B1 (en) | Antimicrobial agent for treating buildings, building materials, textiles, leather, agricultural products and foodstuffs | |
CN110024805A (en) | A kind of forest limb sterilization smears and its preparation method and application | |
JP2003277687A (en) | Natural coating material and method for producing the same | |
DE69902903T2 (en) | ADHESIVES | |
GB2128091A (en) | Wood preservative composition | |
KR100826774B1 (en) | Adhesive composition for paint utilizing natural material | |
JPS6348202A (en) | Microbicidal composition | |
KR100738505B1 (en) | Preparing method of composition for blocking harmful material and deordorizing | |
CN1116802C (en) | Pesticide for preventing and treating rot of apple tree | |
CN112266716A (en) | High-performance waterproof coating and use method thereof | |
CN109294360A (en) | Carbonize material water-borne wood coating and its manufacturing method | |
CN108997865A (en) | A kind of Novel environment-friendlymaterial material and preparation method thereof | |
JPS6341405A (en) | Microbicide | |
JPH10212457A (en) | Wood-protecting coating composition and wood coated therewith | |
CN108552241A (en) | A kind of insect prevention composite board | |
US3323928A (en) | Cement containing calcium carbonate particles coated with bis (tributyltin)-oxide | |
KR100674443B1 (en) | Functional water paint composite annexing charcoal | |
JP3924505B2 (en) | Coating method for coating material, building material and coating method for foundation | |
KR100678586B1 (en) | A manufacturing method of salifying sol for blocking harmful material using natural mineral composition | |
JP4312182B2 (en) | Adhesive for paint |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080704 Year of fee payment: 5 |
|
LAPS | Cancellation because of no payment of annual fees |