JP2000344606A - Inclusion body of insect growth control agent - Google Patents
Inclusion body of insect growth control agentInfo
- Publication number
- JP2000344606A JP2000344606A JP11192213A JP19221399A JP2000344606A JP 2000344606 A JP2000344606 A JP 2000344606A JP 11192213 A JP11192213 A JP 11192213A JP 19221399 A JP19221399 A JP 19221399A JP 2000344606 A JP2000344606 A JP 2000344606A
- Authority
- JP
- Japan
- Prior art keywords
- insect growth
- packaging material
- control agent
- growth control
- inclusion body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 241000238631 Hexapoda Species 0.000 title claims abstract description 26
- 210000003000 inclusion body Anatomy 0.000 title claims abstract description 11
- 239000005022 packaging material Substances 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 229920002239 polyacrylonitrile Polymers 0.000 claims abstract description 7
- 229920001577 copolymer Polymers 0.000 claims description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 230000005012 migration Effects 0.000 abstract description 3
- 238000013508 migration Methods 0.000 abstract description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 12
- 239000003814 drug Substances 0.000 description 10
- 229940079593 drug Drugs 0.000 description 10
- 230000000694 effects Effects 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 239000000077 insect repellent Substances 0.000 description 6
- 239000005927 Pyriproxyfen Substances 0.000 description 3
- -1 S -Hydroprene Chemical compound 0.000 description 3
- 239000003630 growth substance Substances 0.000 description 3
- FYQGBXGJFWXIPP-UHFFFAOYSA-N hydroprene Chemical compound CCOC(=O)C=C(C)C=CCC(C)CCCC(C)C FYQGBXGJFWXIPP-UHFFFAOYSA-N 0.000 description 3
- 229930000073 hydroprene Natural products 0.000 description 3
- 239000002655 kraft paper Substances 0.000 description 3
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 3
- 241000255925 Diptera Species 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- NFGXHKASABOEEW-UHFFFAOYSA-N 1-methylethyl 11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate Chemical compound COC(C)(C)CCCC(C)CC=CC(C)=CC(=O)OC(C)C NFGXHKASABOEEW-UHFFFAOYSA-N 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 239000005885 Buprofezin Substances 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 239000005893 Diflubenzuron Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000258242 Siphonaptera Species 0.000 description 1
- 239000005938 Teflubenzuron Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000005667 attractant Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 description 1
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- QQQYTWIFVNKMRW-UHFFFAOYSA-N diflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC=C(Cl)C=C1 QQQYTWIFVNKMRW-UHFFFAOYSA-N 0.000 description 1
- 229940019503 diflubenzuron Drugs 0.000 description 1
- HJUFTIJOISQSKQ-UHFFFAOYSA-N fenoxycarb Chemical compound C1=CC(OCCNC(=O)OCC)=CC=C1OC1=CC=CC=C1 HJUFTIJOISQSKQ-UHFFFAOYSA-N 0.000 description 1
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000037406 food intake Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 230000003054 hormonal effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000000366 juvenile effect Effects 0.000 description 1
- 239000002949 juvenile hormone Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000029052 metamorphosis Effects 0.000 description 1
- 229930002897 methoprene Natural products 0.000 description 1
- 229950003442 methoprene Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、昆虫成長制御剤を
封入して保存するための封入体に関し、特に長期間保存
しても昆虫成長制御剤が封入体内に移行したりして、無
駄となることがないようにした昆虫成長制御剤封入体に
関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an enclosure for enclosing and storing an insect growth controlling agent. The present invention relates to an insect growth controlling agent inclusion body which is prevented from becoming.
【０００２】[0002]
【従来技術】防虫剤等の常温揮散性の薬剤を含む製剤の
包装材においては、その製剤を使用するまで外部に薬剤
が揮散しないようにするため、包装材にガス不透過性フ
ィルム等を組合せた層状構造のものなどが用いられてい
る。しかし保存している際に、内部で揮散した薬剤が包
装材に移行してしまい、実際に揮散に有効に使用される
揮散性の薬剤の量が減少してしまうという問題が生じる
ことから、その解決手段について検討されている。2. Description of the Related Art In the case of a packaging material for a preparation containing a normal-temperature-evaporating drug such as an insect repellent, a gas-impermeable film or the like is combined with the packaging material to prevent the drug from evaporating to the outside until the preparation is used. For example, those having a layered structure are used. However, during preservation, the internally volatilized drug migrates to the packaging material, which causes a problem that the amount of the volatile drug that is actually used effectively for volatilization is reduced. A solution is being considered.
【０００３】このような問題は、防虫剤等の常温揮散性
の薬剤において発生するものであって、昆虫成長制御剤
のような揮散性の少ない薬剤においては、保存時に薬剤
が包装材に移行することはほとんど問題とはされていな
かった。[0003] Such a problem occurs in a normal-volatility drug such as an insect repellent and the like, and in the case of a low-volatility drug such as an insect growth controlling agent, the drug migrates to the packaging material during storage. That was hardly a problem.
【０００４】[0004]
【発明が解決しようとする課題】ところが昆虫成長制御
剤のような薬剤においても、長期間保存する際には包装
材に薬剤が移行してしまい、使用時に十分な効果が得ら
れないという問題が生じた。本発明はこのような状況を
鑑みてなされたものであり、昆虫成長制御剤が移行する
ことがないか、或いは最小限に抑えられる昆虫成長制御
剤封入体を提供することを目的とするものである。However, even with a drug such as an insect growth control agent, the drug migrates to the packaging material when stored for a long period of time, and a sufficient effect cannot be obtained at the time of use. occured. The present invention has been made in view of such a situation, and an object of the present invention is to provide an insect growth control agent inclusion body in which an insect growth control agent does not migrate or is minimized. is there.
【０００５】[0005]
【課題を解決するための手段】本発明者らは、上記課題
を満足するため鋭意検討した結果、包装材の少なくとも
内部をエチレン・酢酸ビニル共重合体又はポリアクリル
ニトリルで構成するこで、長期間保存しても昆虫成長制
御剤が包装材へ移行するのを防止できることを見出し、
本発明に到達した。Means for Solving the Problems The present inventors have conducted intensive studies in order to satisfy the above-mentioned problems, and as a result, at least the interior of the packaging material is made of an ethylene / vinyl acetate copolymer or polyacrylonitrile, so Found that even if stored for a long period, the insect growth regulator can be prevented from migrating to the packaging material,
The present invention has been reached.
【０００６】すなわち本発明は、以下の手段によって上
記課題を解決することができたものである。 （１）昆虫成長制御剤を包装材により封入した封入体に
おいて、包装材としてその少なくとも内部がエチレン・
酢酸ビニル共重合体又はポリアクリルニトリルからなる
包装材を用いることにより、昆虫成長制御剤の包装材へ
の移行を防止したことを特徴とする昆虫成長制御剤封入
体。That is, the present invention has solved the above problems by the following means. (1) In an enclosure in which an insect growth controlling agent is encapsulated in a packaging material, at least the inside of the enclosure is made of ethylene.
An insect-growth-controlling-agent-encapsulated body characterized in that the transfer of the insect-growth-controlling agent to the packaging material is prevented by using a packaging material made of a vinyl acetate copolymer or polyacrylonitrile.
【０００７】[0007]
【発明の実施の形態】本発明において用いるエチレン・
酢酸ビニル共重合体又はポリアクリルニトリルからなる
包装材としては、全体がこれらの物質からなるもの、例
えば、フィルムでもよいし、また少なくとも内面側の層
がこれらの物質からなり、その他の層が他の物質からな
る２層以上の積層フィルムであってもよい。前記フィル
ム又は積層フィルムにおける前記の物質からなる層の厚
さは、昆虫成長制御剤がその層の内面から外面に移行し
ないような厚さであることが好ましいが、これらのフィ
ルムはガス不透過性を有しており、外からの水蒸気や酸
素の侵入を阻止する性質を有するので、ガス不透過性を
有するのに十分な厚さをもつことが好ましい。BEST MODE FOR CARRYING OUT THE INVENTION
The packaging material composed of vinyl acetate copolymer or polyacrylonitrile may be composed entirely of these substances, for example, a film, or at least an inner layer may be composed of these substances, and other layers may be composed of other substances. Or a laminated film of two or more layers made of the above substances. The thickness of the layer comprising the substance in the film or laminated film is preferably such that the insect growth controlling agent does not migrate from the inner surface to the outer surface of the layer, but these films are gas-impermeable. And has a property of preventing the invasion of water vapor and oxygen from the outside, so that it is preferable to have a thickness sufficient to have gas impermeability.
【０００８】ここでエチレン・酢酸ビニル共重合体の具
体例としては、エバール（商品名）が挙げられる。この
エバールは、従来、食品等の保存のために酸素不透過性
フィルムとして用いられているだけであって、昆虫成長
制御剤の移行防止のために利用されてはおらず、移行防
止に有効であることは本発明において見出された知見で
ある。A specific example of the ethylene / vinyl acetate copolymer is EVAL (trade name). This eval is conventionally used only as an oxygen impermeable film for preserving foods and the like, but is not used for preventing migration of insect growth regulators and is effective for preventing migration. That is the finding found in the present invention.
【０００９】本発明において、昆虫成長制御剤として
は、昆虫のキチン合成阻害あるいは幼若ホルモン様物質
など脱皮、変態を撹乱することにより昆虫を死亡させる
制虫作用のある物質を含む製剤であり、例えば、シート
製剤、ブロック製剤、顆粒製剤、ペースト製剤、通気性
不織布にこれらのいずれかを封入した製剤等が挙げられ
る。In the present invention, the insect growth regulator is a preparation containing a substance having an anti-insect action, such as inhibition of insect chitin synthesis or juvenile hormone-like substance, which kills insects by disrupting molting and metamorphosis. Examples thereof include sheet preparations, block preparations, granule preparations, paste preparations, preparations in which any of these is enclosed in a breathable nonwoven fabric, and the like.
【００１０】そして前記の制虫作用のある物質として
は、例えば、ピリプロキシフェン、ハイドロプレン、Ｓ
−ハイドロプレン、メトプレン、ジフルベンズロン、テ
フルベンズロン、クロルフルアズロン、フルフェノクス
ロン、テブフェノシド、ブプロフェジン、フェノキシカ
ルブ等が挙げられる。[0010] Examples of the substance having an insect repellent action include pyriproxyfen, hydroprene, S
-Hydroprene, methoprene, diflubenzuron, teflubenzuron, chlorfluazuron, flufenoxuron, tebufenoside, buprofezin, phenoxycarb and the like.
【００１１】これらの物質は、前記のような製剤とする
ために、単独で、又は他の増量剤と混合したものとし
て、例えば、アルコール、アセトン等の溶媒に溶かして
薬液とし、これを吸液性材料や多孔性材料に含浸させて
使用することができる。このような材料としては、例え
ば、クラフト紙、不織布等があり、これらの形状とし
て、平板状、凹凸状、起毛状等のシート、ブロック、粒
状体等が挙げられる。そして前記の制虫作用のある物質
は、材料にその有効量、例えば０．００１〜５重量％と
なるように含有させればよい。These substances are used alone or in a mixture with other bulking agents, for example, by dissolving them in a solvent such as alcohol or acetone to obtain a drug solution, which is then subjected to liquid absorption. It can be used by impregnating it with a porous material or a porous material. Such materials include, for example, kraft paper, nonwoven fabric, and the like, and examples of such shapes include sheets, blocks, and granules having a flat, irregular, or brushed shape. The substance having an insect repellent action may be contained in the material in an effective amount, for example, 0.001 to 5% by weight.
【００１２】また本発明の効果を奏する限り、他の物質
を製剤中に配合してもよく、例えば、殺虫剤、防虫剤、
殺菌剤、防黴剤、忌避剤、芳香剤、消臭剤、天然精油、
酸化防止剤、誘引剤等が挙げられる。As long as the effects of the present invention are exerted, other substances may be incorporated in the preparation, for example, insecticides, insect repellents,
Fungicides, fungicides, repellents, fragrances, deodorants, natural essential oils,
Examples include antioxidants, attractants and the like.
【００１３】さらにインジケータを設けたり、着色した
り、誤食防止剤を配合して、製剤としての機能を高める
こともできる。Further, the function as a preparation can be enhanced by providing an indicator, coloring, or blending an ingestion inhibitor.
【００１４】使用に際しては、昆虫成長制御剤を封入体
から取り出して、所望の場所に設置すればよく、その際
にベイト剤等の他の製剤を併用することで害虫等の防除
効果を高めることもできる。好ましくは他の製剤に含ま
れる有効成分が異なるもの、即ち、作用機作が違う物質
を用いると効果的である。これによって、前記した制虫
作用のある物質の対象となりうる害虫、例えば、ゴキブ
リ、ハエ、ノミ、カ等を防除することができる。At the time of use, the insect growth controlling agent may be removed from the inclusion body and placed in a desired place, and at this time, the effect of controlling other insects such as pests can be enhanced by using other preparations such as bait. Can also. Preferably, it is effective to use substances having different active ingredients in other preparations, that is, substances having different mechanisms of action. In this way, pests that can be targeted by the above-mentioned substances having an insect-controlling action, for example, cockroaches, flies, fleas, mosquitoes, etc. can be controlled.
【００１５】[0015]
【実施例】以下に実施例において本発明を具体的に説明
するが、ただし本発明はこれらの実施例のみに限定され
るものではない。 実施例１ ピリプロキシフェン０．０５ｍｇをアセトンを用いてク
ラフト紙（１０ｃｍ２）に含浸させ、乾燥させたシート
を以下の包装材に封入し封入体とした。包装材として
は、ポリアクリルニトリル（以下、ＰＡＮ）、エチレン
・酢酸ビニル共重合体（以下、エバール）及びポリエチ
レン（以下、ＰＥ）を用いた。そして各封入体を４０℃
条件下で６ケ月間保存し、ガスクロマトグラフィーで各
シートを分析して初期値に対するピリプロキシフェンの
減少率（％）を求めた。結果は第１表に示した。EXAMPLES The present invention will be described in more detail with reference to the following Examples, which should not be construed as limiting the scope of the present invention. Example 1 Kraft paper (10 cm 2 ) was impregnated with 0.05 mg of pyriproxyfen using acetone, and a dried sheet was enclosed in the following packaging material to obtain an enclosure. As a packaging material, polyacrylonitrile (hereinafter, PAN), ethylene / vinyl acetate copolymer (hereinafter, Eval) and polyethylene (hereinafter, PE) were used. And put each enclosure at 40 ℃
After storing for 6 months under the conditions, each sheet was analyzed by gas chromatography to determine the reduction rate (%) of pyriproxyfen with respect to the initial value. The results are shown in Table 1.
【００１６】[0016]
【表１】 [Table 1]
【００１７】実施例２ ハイドロプレン１７ｍｇをアセトンを用いてクラフト紙
（１０ｃｍ２）に含浸させ、乾燥させたシートを包装材
に封入し封入体とした。そして実施例１と同様にしてハ
イドロプレンの減少率（％）を求めた。結果は第２表に
示した。Example 2 Kraft paper (10 cm 2 ) was impregnated with 17 mg of hydroprene using acetone, and the dried sheet was sealed in a packaging material to form an enclosure. Then, the reduction rate (%) of hydroprene was determined in the same manner as in Example 1. The results are shown in Table 2.
【００１８】[0018]
【表２】 [Table 2]
【００１９】[0019]
【発明の効果】本発明によれば、その封入体に昆虫成長
制御剤が移行しないので、長期間保存しても、使用する
際に、十分な防虫効果を得ることができる。特に少くな
い薬量で効果が得られる昆虫成長制御剤においては、封
入体へのわずかな移行であってもその効果が大きく低下
することがあり、本発明はこのような悪影響を十分防止
することができる。According to the present invention, since the insect growth regulator does not transfer to the inclusion body, a sufficient insect repellent effect can be obtained even when stored for a long period of time. In particular, in the case of an insect growth controlling agent which can obtain an effect with a small dose, even if it is slightly transferred to an inclusion body, its effect may be greatly reduced, and the present invention is to sufficiently prevent such adverse effects. Can be.
Claims (1)
封入体において、包装材としてその少なくとも内部がエ
チレン・酢酸ビニル共重合体又はポリアクリルニトリル
からなる包装材を用いることにより、昆虫成長制御剤の
包装材への移行を防止したことを特徴とする昆虫成長制
御剤封入体。1. An insect growth controlling agent, wherein an insect growth controlling agent is encapsulated in a packaging material, wherein at least the inside of the encapsulating material is made of an ethylene / vinyl acetate copolymer or polyacrylonitrile. An insect-growth-controlling agent inclusion body, characterized in that transfer of the insect growth control material to a packaging material is prevented.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11192213A JP2000344606A (en) | 1999-06-02 | 1999-06-02 | Inclusion body of insect growth control agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11192213A JP2000344606A (en) | 1999-06-02 | 1999-06-02 | Inclusion body of insect growth control agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000344606A true JP2000344606A (en) | 2000-12-12 |
Family
ID=16287553
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11192213A Pending JP2000344606A (en) | 1999-06-02 | 1999-06-02 | Inclusion body of insect growth control agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000344606A (en) |
-
1999
- 1999-06-02 JP JP11192213A patent/JP2000344606A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU2018247325B2 (en) | Compositions, devices and methods for control of pests using vapor activity | |
| RU2450517C2 (en) | Paper saturated with insecticidal substances | |
| EP0194896B2 (en) | Methods and devices for controlled release | |
| US20180116198A1 (en) | Compositions, devices and methods for control of pests using vapor activity | |
| EP3021665B1 (en) | Methods and devices for sustained release of substances | |
| JP4324252B2 (en) | Insecticide for fiber pests and method | |
| AU617931B2 (en) | Composite insecticide and package thereof | |
| JPS5821603A (en) | Insecticide and fungicide preparation | |
| JP2000344606A (en) | Inclusion body of insect growth control agent | |
| JP3822917B2 (en) | Insecticide for clothing pests | |
| JPH0580441B2 (en) | ||
| JP3120393B2 (en) | Insect repellent for clothing | |
| JP4445459B2 (en) | Chemical transpiration device | |
| KR100767915B1 (en) | Grain quality preservatives containing stabilized mustard and/or horseradish extracts and package containing the same | |
| JP3694629B2 (en) | Antifungal repellent composition and antifungal repellent formulation | |
| JP4441017B2 (en) | Portable flying pest control device | |
| JPH0425242B2 (en) | ||
| JPH11343202A (en) | Laminated packaging material for preserving insecticidal formulation and preservation of insecticidal formulation utilizing the same | |
| JPH10316506A (en) | Heat-fumigation type noxious insect expellent and insect extermination using the same | |
| JPH11322508A (en) | Heating and transpiring type pest-controlling agent, and pest control by utilizing the same | |
| JPH11349405A (en) | Evaporation method | |
| JPS61129102A (en) | Acarid controller | |
| JPH0524795B2 (en) | ||
| JPH01163102A (en) | Miticide containing higher fatty acid amide condensate as active component | |
| JPS60228403A (en) | Vermin-proofing agent for pillow |