JP2000330370A - Toner support and image forming device - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a toner support giving a high quality image free from unevenness in density, less liable to a change in characteristics in long-term use and excellent in durability and to provide an image forming device with the toner support. SOLUTION: The toner support 1 is a member which supplies a toner to the surface of an image forming body to form a visible image on the surface of the image forming body and has a coating layer 4 comprising a material containing a resin obtained by curing a mixture of an alkyd modified silicone compound and melamine resin on the surface of an electrically conductive elastic layer 3.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a toner carrier and an image forming apparatus, and more particularly, to an image forming apparatus such as a copying machine or a printer for forming an image on a photosensitive member or paper holding an electrostatic latent image. A toner carrier for supplying toner to the body to form a visible image on the surface of the image forming body, giving a high quality image without density unevenness, and having a small characteristic change in long-term use and durability. And an image forming apparatus equipped with the toner carrier.

[0002]

2. Description of the Related Art Conventionally, in an electrophotographic image forming apparatus such as a copying machine or a printer, a one-component toner is supplied to an image forming body such as a photoconductor holding an electrostatic latent image, and the toner is supplied to the latent image. As an image forming method for visualizing by attaching to
A pressure development method is known (U.S. Pat.
No., specification No. 3731146, etc.). In this pressure development method, an image is formed by bringing a toner carrier carrying a toner into contact with an image forming body (photoreceptor) holding an electrostatic latent image and adhering the toner to the latent image of the image forming body. Therefore, it is necessary to form the toner carrier from a conductive elastic material having conductivity and elasticity.
That is, in this pressure development method, as shown in FIG. 2, for example, a toner is applied between a toner applying roller 5 for supplying toner and an image forming body (photoconductor) 6 holding an electrostatic latent image. A carrier (developing roller) 1 is provided, and the toner 7 is rotated by the toner applying roller 5 by rotating the toner carrier 1, the image forming body 6 and the toner applying roller 5 in the direction of the arrow in FIG. The toner is supplied to the surface of the carrier 1, and the toner is formed into a uniform thin film by the layering blade 8. Then, in this state, when the toner carrier 1 rotates while being in contact with the image forming body 6, the toner formed in a thin layer adheres from the toner carrier 1 to the latent image of the image forming body 6, and The image is made visible. In the drawing, reference numeral 9 denotes a transfer unit, which transfers a toner image to a recording medium such as paper. Reference numeral 10 denotes a cleaning unit which removes toner remaining on the surface of the image forming body 6 after transfer by the cleaning blade 11.

In such an image forming apparatus using the pressure development method, the toner carrier 1 must rotate while maintaining a state in which the toner carrier 1 is in close contact with the image forming body 6. As shown in the figure, a silicone rubber, N
BR (acrylonitrile-butadiene copolymer rubber), E
Conductive elasticity made of a conductive elastic material obtained by adding a conductive agent to an elastic rubber or foam such as PR (ethylene-propylene rubber), EPDM (ethylene-propylene-diene copolymer rubber), polyurethane rubber, etc. It has a structure in which the layer 3 is formed. Further, in order to control the chargeability and adhesion of the toner 7, to control the frictional force between the image forming body 6 and the layering blade 8, or to prevent the elasticity of the image forming body from contaminating the resin 7. Is provided on the surface of the conductive elastic layer 3. On the other hand, an image forming method for forming an image by causing a toner carried on a toner carrier to fly in a straight line through an aperture-shaped control electrode on an image forming body made of paper such as paper or OHP paper is also proposed. Have been. Further, a non-magnetic toner having a thin layer is carried on a surface of a sleeve-like toner carrier provided in a non-contact state close to the image forming body (photoreceptor),
A method of forming an image by flying the image on an image forming body and developing the image is also proposed (JP-A-58-1165).
No. 59).

[0004] In any case, the toner carrier is provided on the toner carrier for controlling the chargeability and adhesion of the toner or for reducing the frictional force with other members such as an image forming body, a layered blade, and a control electrode. To this end, a coating layer made of a resin or the like is provided on the surface of the conductive elastic layer. The present inventors have proposed a toner carrier using a resin such as a melamine resin, a phenol resin, an alkyd resin, a fluorine resin, or a polyamide resin as a coating layer as a toner carrier capable of improving friction and an image. I've been.

[0005]

However, recently, the demand for image formation has become strict due to the speeding up of printers and the like, the demand for fine images, and the development of color images. Various problems that cannot be dealt with by the toner carrier have become apparent. That is, when an image is to be output after the toner carrier is incorporated in a printer or the like and kept in a non-use state for a long period of time, 1) In a white background image, a black line (black horizontal line) is perpendicular to the paper traveling direction. 2) In a halftone image, the problem of image defects such as "roughness" pattern and shading unevenness has become apparent. Further, as the toner carrier is used for a long period of time, 3) the phenomenon that the toner charge amount or the toner conveyance amount is reduced occurs, which is also a serious problem. The present inventors have repeatedly studied the above problem, and have found that the image defect is due to the following causes.

That is, for example, when the toner carrier 1 is used for a long period of time in an image forming apparatus as shown in FIG. 2, the friction between the toner carrier 1 and the toner application roller 5 or the layering blade 8 causes the toner carrier 1 Since the surface properties of the toner carrier change due to wear of the coating layer and occurrence of toner filming, the amount of toner charged and the amount of toner transported change, resulting in image defects.
Therefore, in order to solve the problem of the image defect, it is only necessary to increase the durability of the coating layer forming the surface. In order to increase the durability of the coating layer forming the surface, attempts have been made to increase the thickness of the coating layer. However, such an increase in the thickness of the film causes an increase in the charge amount due to the inability to control the charge amount of the toner in the initial use condition, or damage of the toner, fusion of the toner, and scratches on the image forming member due to an increase in the hardness of the toner carrier. Such a situation may cause an undesirable situation.

The present invention has been made in view of the above circumstances, and optimizes initial conditions so as to obtain a high-quality image without image unevenness, and prevents the occurrence of image defects during long-term use. It is an object of the present invention to provide a toner carrier having both charging performance and durability so that a good image can be reliably obtained, and an image forming apparatus equipped with the toner carrier.

[0008]

In order to achieve the above object, the present inventors have demonstrated excellent durability against friction with a toner, a toner coating roller or a layered blade, and have been used for a long time. With a small change in surface properties, and with a focus on constituent materials having various functions required in the design of the coating layer, such as prevention of contamination of the image forming body, prevention of toner adhesion, control of toner charge amount, resistance adjustment, control of friction coefficient, etc. As a result of repeated studies and investigations, it has been found that a material containing a resin obtained by curing a mixture of an alkyd-modified silicone compound and a melamine resin can satisfy these requirements. The silicone compound has a stable bond because the siloxane bond forming the skeleton has a larger binding energy than the C—C single bond and has about 50% ionic bondability. . In addition, the siloxane bond has a longer inter-bond distance and a lower electron density than a C—C single bond, so that rotation of the bond is easy,
It shows more flexible properties than the CC chain. Due to the above properties, the silicone compound can be used as a material having both flexibility and heat and weather resistance. However, the silicone compound is often used as a modified compound in combination with various organic resins because the silicone compound is inferior in adhesiveness and the mechanical strength is reduced when the resin is formed into a resin or elastomer. We believe that if the surface of a roller made of a conductive elastic material is coated with such a modified silicone resin, a roller with good durability can be realized without increasing the thickness of the film. It has been found that when a silicone resin is used, a film having both strength and flexibility can be formed.
However, the drying and curing of the modified silicone compound generally requires a high temperature of 150 to 200 ° C., which is higher than the heat resistance limit of the conductive elastic material that is the roller base material, and is therefore used as a roller coating. I couldn't. What the present inventors have paid attention to is that the modified silicone compound has improved compatibility with an organic resin by modification, and the modified silicone compound is mixed with another resin,
It is presumed that by curing, the organic resin is given properties such as flexibility that the silicone compound has and durability can be obtained. Therefore, as a result of a more detailed study, the combination of an alkyd-modified silicone compound and a melamine resin resulted in a coating layer with excellent surface properties, durability, tackiness, etc. It has been found that it can be formed in a medium to low temperature range that is within the range of durability. On the other hand, the melamine resin used as a curing agent in the present invention has a structure that is advantageous in electron donating performance, and exhibits excellent electron emitting ability. For this reason, by using the melamine resin for curing the alkyd-modified silicone compound, the toner works advantageously to charge by donating electrons, and also works to solve the above problem of “increase in charge amount due to inability to control toner charge amount”. It was presumed that a resin for a toner carrier coating layer having both excellent physical properties of an alkyd-modified silicone compound and excellent toner charging properties of a melamine resin was obtained.

The present invention has been completed based on such findings. That is, the present invention provides a method of forming a thin film by carrying a toner on a surface thereof, and contacting or approaching the image forming body in this state, and supplying the toner to the surface of the image forming body, thereby forming a surface of the image forming body. In a toner carrier for forming a visible image, the toner carrier has, on the surface of the conductive elastic layer, a coating layer made of a material containing a resin obtained by curing a mixture of an alkyd-modified silicone compound and a melamine resin. It is intended to provide a toner carrier characterized in that it is a toner carrier. Further, according to the present invention, there is provided an image forming apparatus comprising a toner carrier mounted thereon, and carrying a toner on the surface of the toner carrier to form a thin film thereof, and bringing the toner carrier into contact with or close to the image forming body. An image forming apparatus for forming a visible image on the surface of an image forming body by supplying toner to the body surface, wherein the toner supporting body of the present invention is used as the toner supporting body. Is also provided.

[0010]

DESCRIPTION OF THE PREFERRED EMBODIMENTS As shown in FIG. 1, a toner carrier according to the present invention has a conductive elastic layer 3 formed on the outer periphery of a good conductive shaft 2 and a coating layer 4 on the surface of the conductive elastic layer 3. Is formed. As the shaft 2, any material having good conductivity can be used, but usually, a metal such as a metal core bar made of a solid metal body or a metal cylindrical body having a hollow inside is used. A shaft made of is used. The conductive elastic layer 3 is made of an elastic material obtained by adding a conductive agent to an appropriate rubber material to impart conductivity. here,
There is no particular limitation on the rubber material. For example, nitrile rubber, ethylene propylene rubber, ethylene propylene diene rubber, styrene butadiene rubber, butadiene rubber, isoprene rubber, natural rubber, silicone rubber, urethane rubber, acrylic rubber, chloroprene rubber, butyl rubber, Epichlorohydrin rubber and the like may be used, and these may be used alone or in combination of two or more. Among them, particularly selected from butadiene rubber, ethylene propylene rubber, ethylene propylene diene rubber and urethane rubber. One or a mixture of two or more is preferred.

On the other hand, conductive agents added to these rubber materials include an ionic conductive agent and an electronic conductive agent. Examples of the former ionic conductive agent include tetraethylammonium, tetrabutylammonium, lauryltrimethylammonium and the like. Perchlorates, chlorates, hydrochlorides, such as octadecyltrimethylammonium, benzyltrimethylammonium, and modified aliphatic dimethylethylammonium, such as dodecyltrimethylammonium, hexadecyltrimethylammonium, and stearyltrimethylammonium;
Bromate, iodate, borofluoride, sulfate,
Ammonium salts such as alkyl sulfates, carboxylates, and sulfonates; perchlorates, chlorates, hydrochlorides, bromates, and iodines of alkali metals or alkaline earth metals such as lithium, sodium, calcium, and magnesium Acid salt,
Borofluoride, trifluoromethyl sulfate, sulfonate and the like can be mentioned. Examples of the electronic conductive agent include conductive carbon blacks such as Ketjen black and acetylene black; SAF, ISAF, HAF, F
Carbon black for rubber such as EF, GPF, SRF, FT, and MT; carbon black for ink after oxidation treatment, pyrolytic carbon black, graphite; conductive metal oxide such as tin oxide, titanium oxide, and zinc oxide; nickel And powders of metals such as copper.

[0012] These conductive agents may be used alone,
These may be used in combination. The amount of addition
Although not particularly limited, in the case of an ion conductive agent,
0.01 to 5 parts by weight based on 100 parts by weight of the rubber material
Parts, preferably in the range of 0.05 to 2 parts by weight.
1 to 50 parts by weight, preferably 5
It can be in the range of ４０40 parts by weight. This conductive additive
By adjusting the addition amount, the specific resistance of the conductive elastic layer is reduced to 10
^Three-10 ^TenΩ · cm, especially 10^Four-10⁸Ω · cm range
It is preferable to adjust to the surroundings. In addition, this conductive elastic layer
May be a conventionally known filler, if necessary, in addition to the conductive agent.
Add other rubber additives, such as crosslinking agents, as appropriate
Can be. The hardness of this conductive elastic layer is 6 according to JIS-A.
0 ° or less, preferably in the range of 25 to 55 °
No. When the hardness exceeds 60 °, the toner carrier becomes hard.
The contact area with the photoreceptor etc
May not be able to be formed, and may damage the toner.
Toner sticking to the image forming body and the layering blade
And cause image defects. On the contrary, low hardness
Too much friction with the image forming body and stratification blade
May cause image defects such as jitter.
You.

Since the conductive elastic layer is used in contact with an image forming body, a layered blade, or the like, it is preferable that the compression set is small, specifically, 20% or less, particularly 1%.
0% or less is preferable. In particular, polyurethane rubber is particularly preferable because the compression set can be designed to be small. The surface roughness of the conductive elastic layer is preferably 15 μmRz or less, particularly preferably 3 to 10 μmRz in terms of JIS 10-point average roughness. If the average roughness exceeds 15 μmRz, it is necessary to form a thick coating layer that forms the surface of the toner carrier, and as a result, the surface of the toner carrier becomes hard and damages the toner, resulting in damage to the image forming body and the laminating blade. This is not preferable because toner adheres to the toner, resulting in an image failure. On the other hand, if the Rz is too small, when the coating layer is formed, the Rz on the surface of the toner carrier becomes too small, and the amount of the toner carried becomes small, so that the image density may be reduced. The surface roughness was measured using a surface roughness meter “Surfcom 590A” (manufactured by Tokyo Seimitsu Co., Ltd.) in the circumferential direction at a measurement length of 2.4 mm, a measurement speed of 0.3 mm / sec, and a cutoff wavelength of 0 mm. It is a value obtained by measuring 300 points or more at 0.8 mm so that there is no deviation in the shaft direction and circumferential direction of the roller (the same applies to the following).

In the toner carrier of the present invention, for controlling the chargeability and adhesion of the toner, for reducing the frictional force with an image forming body, a layered blade, or the like, or
In order to prevent the image forming body from being contaminated by the elastic body, a coating layer made of a resin or the like is provided on the surface of the conductive elastic layer. This coating layer is formed of a material containing a resin obtained by curing a mixture of an alkyd-modified silicone compound and a melamine resin. Examples of the alkyd-modified silicone compound include those modified by dehydration condensation of an organopolysiloxane and an alkyd, those modified by a dealcoholization condensation reaction of an organoalkoxypolysiloxane and an alkyd, organopolysiloxanes, polyhydric alcohols, fatty acids And polybasic acids modified by a dehydration condensation reaction. In the present invention, any of these can be used. In general, there are two types: a room temperature curing type and a heating drying type. The heating drying type has no risk of gelation of the mixed solution at room temperature. It is considered to be advantageous from the viewpoint of. An example of a room temperature curing type is KR5206 manufactured by Shin-Etsu Chemical Co., Ltd.
An example of the heat drying type is KR206 manufactured by Shin-Etsu Chemical Co., Ltd. According to the study of the present inventors, when the coating layer is formed of the material containing the alkyd-modified silicone compound mentioned as an example of the heat-drying type, the toner chargeability is good and particularly preferable results are brought. There are various types of structures of the alkyd-modified silicone compound.

[0015]

Embedded image

(Wherein, R ¹ represents an alkylene group having an arbitrary number of carbon atoms, and R ^{2 to} R ⁶ represent an alkyl group or a phenyl group having an arbitrary number of carbon atoms. N and m indicate the constitutional ratio of the unit structure.). In the above formula, the alkylene group is preferably one having 1 to 60 carbon atoms, particularly 1 to 30 carbon atoms.
Are preferred. The alkyl group has 1 carbon atom.
~ 60, particularly preferably 1 ~ 30. These alkyd-modified silicone compounds may be used alone or in a combination of two or more.

On the other hand, examples of the melamine resin include trimethylol melamine resin, hexamethoxymethyl melamine resin, n-butyl ether melamine resin, isobutyl ether melamine resin and the like. Among them, trimethylol melamine resin, hexamethoxymethyl melamine resin and isobutyl ether melamine resin are particularly preferable. These melamine resins may be used alone or in combination of two or more. In the present invention, the alkyd-modified silicone compound and the melamine resin have a solid content weight ratio (alkyd-modified silicone compound: melamine resin) of preferably 20: 80-9.
It is advantageous to use a ratio of 8: 2, more preferably 30:70 to 95: 5, particularly preferably 40:60 to 70:30. The coating layer according to the present invention preferably has an insolubility in a solvent of 70% by weight or more,
If the insolubility is less than 70% by weight, the contact of the member in contact with the toner carrier, such as an image forming body or a stratified blade, is caused by a long-term storage, and as a result, the image has a defect such as a black horizontal line. May occur. Particularly, those having a solvent insolubility of 80% by weight or more are preferable.

The coating layer according to the present invention mainly comprises the above cured resin.
Component, but also has the ability to charge toner
Further improvement, reduction of frictional force with other members and addition of conductivity
Charge control agents, lubricants, conductive agents, and other resins
And other various additives. Of the present invention
In the toner carrier, the resistance of such a coating layer is
Making the resistance higher than the resistance of the conductive elastic layer depends on the toner carrier.
Is preferable in adjusting the resistance of the coating layer.
The specific resistance is 10⁹-10¹⁵Ω · cm range.
To 10 ^Ten-10¹³The range of Ω · cm is preferable. Also,
The resistance of the toner carrier is 10 ^Five-10¹²Ω is preferred
10⁷-10^TenΩ is particularly preferred. Also, the coating layer
The surface roughness of the formed toner carrier is an average of 10 points according to JIS.
10 μmRz or less, especially 1 to 8 μmRz in roughness
Is preferred. This average roughness exceeds 10 μmRz
Causes the toner charge amount to decrease,
Undesirably, image fogging occurs. Also, R
If z is too small, the amount of toner carried will decrease and the image density will decrease.
May be reduced. The toner carrier of the present invention
There is no particular limitation on the method of forming the coating layer in
Liquid modified silicone compound and melamine resin, required
A coating liquid obtained by dissolving or dispersing various additives according to
Dipping method, roll coater method, doctor blade
Applied on the conductive elastic layer by spraying, spraying, etc.
After that, dry at room temperature or about 50-170 ° C
Then, it is formed by crosslinking and curing.

The thickness of this coating layer can be about 3 to 50 μm, but is particularly preferably in the range of 5 to 30 μm. If the thickness of the coating layer is too small, local discharge occurs, and horizontal white lines are likely to occur in the image. On the other hand, if it is too thick, the toner carrier becomes too hard, damaging the toner and causing the toner to adhere to the image forming body or the layered blade, causing image defects. Examples of the solvent used for preparing the coating liquid include alcohol solvents such as methanol, ethanol, isopropanol and butanol; ketone solvents such as acetone, methyl ethyl ketone and cyclohexanone; aromatic hydrocarbon solvents such as toluene and xylene; Aliphatic hydrocarbon solvents such as hexane; alicyclic hydrocarbon solvents such as cyclohexane; ester solvents such as ethyl acetate; ether solvents such as isopropyl ether and tetrahydrofuran; amide solvents such as dimethylformamide; Examples thereof include halogenated hydrocarbon solvents such as chloroethane and the like, and mixed solvents thereof. In the present invention, ketone solvents and mixed solvents of ketone solvents and aromatic hydrocarbons are particularly preferably used.

The toner carrier of the present invention is used by being incorporated as a developing roller or the like in an image forming apparatus such as a developing apparatus in an electrophotographic apparatus. For example, as shown in FIG. Drum (image forming body) holding toner applying roller 5 and electrostatic latent image
6, the toner carrier of the present invention is arranged as a developing roller 1, and a toner 7 is carried by a toner applying roller 5, and the toner 7 is formed into a uniform thin layer by a layering blade 8. Apply toner to photosensitive drum (image forming body) 6
And makes toner adhere to the electrostatic latent image on the photosensitive drum (image forming body) 6 to visualize the latent image. The details of the image forming apparatus shown in FIG. The image forming apparatus to which the toner carrier of the present invention is attached is not limited to the one shown in FIG. 2, but carries the toner on the surface to form a thin layer of the toner, and in this state, forms the image forming body. Any material may be used as long as a visible image is formed on the surface of the image forming body by supplying the toner to the surface of the image forming body in contact with or close to the surface. For example, paper such as paper or OHP paper is used as an image forming body, and the toner carried on the toner carrier is directly flown through a hole formed in the control electrode to directly print an image on paper or OHP paper. It may be formed.

As the toner carried on the toner carrier of the present invention, a non-magnetic one-component developer is preferably used. However, a magnetic one-component developer can also be used. The toner carrier and the image forming apparatus of the present invention can be suitably used also when performing black and white image printing using an agent.

[0022]

Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. The rollers (toner carriers) obtained in Examples and Comparative Examples were subjected to characteristic tests in the following manner. (1) Layer Thickness of Coating Layer A vertical section of the roller to be tested was observed and measured with a scanning electron microscope. (2) Solvent insolubility of the coating layer A glass plate was prepared separately from the roller to be tested, and the coating liquid used for forming the coating layer of each roller was applied to the glass plate. The coating film was heated and cured to prepare a coating film sample. After immersing this glass plate in a solvent similar to that used for preparing the coating liquid at room temperature for 24 hours,
After drying, the weight of the coating film before and after immersion is measured, the solvent insolubility is calculated by the following equation, and the solvent insolubility of the coating layer of the roller is determined. Whether the solvent insolubility of the coating layer is 70% by weight or more It was confirmed. Solvent insolubility = [(coating weight after immersion in solvent and drying) /
(Coating weight before immersion in solvent)] x 100 (% by weight)

(3) Bending test Separately from the roller to be tested, a polypropylene tray is prepared, the coating liquid used for forming the coating layer of each roller is spread in this tray, and the solvent of the coating liquid is volatilized. After that, each roller was heated and dried under the same conditions as in the production of each roller, and cured to produce a coating film sample. The amount of coating liquid used is 15 μm
It was adjusted appropriately so as to obtain a sample of about m. Carefully peel off the obtained coating film from the tray, 30mm x 30m
The test piece was cut out into a size of m. This test piece was bent so that the diagonals overlap, and the process of crushing the central part of the swollen test piece until it was creased was repeated until the fold was sufficiently plastically deformed. Was confirmed. (4) Surface roughness (Rz) For the roller to be tested, use a surface roughness meter Surfcom 590A.
(Manufactured by Tokyo Seimitsu Co., Ltd.) in a direction perpendicular to the axial direction (circumferential direction), measuring length 2.4 mm, measuring speed 0.3 mm /
sec. At a cutoff wavelength of 0.8 mm, JIS 10 point average roughness was obtained by averaging the values measured at 300 or more locations so that there was no deviation in the shaft direction and circumferential direction of the roller.

(5) Roller Resistance A load of 500 g was applied to both ends of the roller to be tested, pressed against a copper plate, and the resistance was measured by applying a voltage of 100 V using a resistivity meter R8340A (manufactured by Advantest). did. (6) Amount of toner charge The roller under test is mounted on the developing unit shown in FIG. 2 as a developing roller, and the developing roller is rotated at a peripheral speed of 50 mm / sec to form a thin toner layer on the surface of the developing roller. ,
The thin toner layer was sucked and introduced into a Faraday gauge, and the charge amount was measured. At the same time, the amount of sucked toner is also measured, and the toner charge amount per unit weight [q / m
(ΜC / g)]. (7) Image evaluation The roller to be tested is incorporated in the developing unit shown in FIG. 2 as a developing roller, a developing bias is -400 V, a blade bias is 600 V, and a negatively charged non-magnetic one-component toner having an average particle diameter of 7 μm is used. An image was formed by reversal development while rotating at a peripheral speed of / sec, and image evaluation was performed on a white background image, a halftone image, and a black background image. A total of five images before and after the tenth print image as the initial image and the ten thousandth print image as the durable image were evaluated, and the evaluation results were obtained.

Example 1 Propylene oxide and ethylene oxide were added to glycerin, and 1,4 parts were added to 100 parts by weight of a polyether polyol (OH value: 33 mgKOH / g) having a molecular weight of 5,000.
-1.0 part by weight of butanediol, 0.5 part by weight of nickel acetylacetonate, 0.01 part by weight of dibutyltin dilaurate and 2.0 parts by weight of acetylene black are added, and mixed using a mixer to form a polyol composition. Was prepared. After defoaming by stirring this polyol composition under reduced pressure, urethane-modified MDI (diphenylmethane diisocyanate)
Was added to 17.5 parts by weight of the mixture and stirred for 2 minutes.
After curing at 10 ° C. for 2 hours, a conductive elastic layer was formed on the outer periphery of the metal shaft to obtain a roller. The surface of the obtained roller is polished, and the surface is JIS 10-point average roughness 10.5 μmR
Adjusted to z. As described above, the surface roughness was measured using a surface roughness meter “Surfcom 590A” (manufactured by Tokyo Seimitsu Co., Ltd.) (the same applies to the following examples).

Next, silicone alkyd varnish KR206 (manufactured by Shin-Etsu Chemical Co., Ltd., solid content: 50% by weight) as an alkyd-modified silicone compound, and Super Beckamine L-145-60 (manufactured by Dainippon Ink and Chemicals, Inc.) as a melamine resin. The above compound was mixed with a mixture of methyl ethyl ketone and toluene at a weight ratio of 9/1 as a solvent so as to have a solid weight ratio of 50/50. Dispersed carbon black # 220 (manufactured by Mikuni Color Co., Ltd., solid content concentration 40
(% By weight) was added so that the solid content was 30 parts by weight with respect to 100 parts by weight of the solid content of the above mixture, and dispersed to prepare a coating liquid having a total solid content concentration of 25% by weight. The conductive elastic roller was immersed in the coating liquid and pulled up, and heated at 110 ° C. for 4 hours to obtain a roller-shaped toner carrier similar to FIG. 1 having a cured coating layer. Table 1 shows the characteristics of the toner carrier. Example 2 In the formation of the coating layer in Example 1, the alkyd-modified silicone compound and the melamine resin were mixed at a solid content weight ratio of 9
A roller-shaped toner carrier was produced in the same manner as in Example 1, except that the mixture was 0/10. Table 1 shows the characteristics of the toner carrier.

Comparative Example 1 In forming the coating layer in Example 1, the alkyd-modified silicone compound and the melamine resin were mixed at a solid content weight ratio of 1
A roller-shaped toner carrier was produced in the same manner as in Example 1 except that 00/0, that is, only the alkyd-modified silicone compound was used. Table 1 shows the characteristics of the toner carrier. Comparative Example 2 In forming the coating layer in Example 1, an oil-free alkyd resin (manufactured by Dainippon Ink and Chemicals, Inc., trade name: M640) was used instead of the alkyd-modified silicone compound.
A roller-shaped toner carrier was produced in the same manner as in Example 1 except that 2) was used. The characteristics of this toner carrier are
It is shown in the table. Comparative Example 3 The procedure of Example 1 was repeated except that, in forming the coating layer in Example 1, 100 parts by weight of polyester polyol and 10 parts by weight of urethane-modified MDI were added instead of the mixture of the alkyd-modified silicone compound and the melamine resin. A roller-shaped toner carrier was produced in the same manner as in Example 1.
Table 1 shows the characteristics of the toner carrier.

[0028]

[Table 1]

From Table 1, it can be seen that the toner carriers of the examples show good toner charging properties, have flexibility not to cause cracks due to bending in the coating layer, and reproduce well durable images. It was confirmed that it was possible.

[0030]

The toner carrier of the present invention can be used continuously for a long period of time by forming a coating layer provided on the surface of the conductive elastic layer using an alkyd-modified silicone compound cured with a melamine resin. Also, it is possible to prevent the occurrence of various image defects without causing cracking or shaving in the coating layer, and to reproduce a good image over a long period of time. It is suitably used as a toner carrier.

[Brief description of the drawings]

FIG. 1 is a schematic sectional view showing an example of a toner carrier of the present invention.

FIG. 2 is a schematic sectional view showing an example of the image forming apparatus of the present invention.

[Explanation of symbols]

 1: toner carrier (developing roller) 2: shaft 3: conductive elastic layer 4: coating layer 5: toner applying roller 6: image forming body (photoreceptor) 7: toner 8: layered blade 9: transfer unit 10: Cleaning section 11: Cleaning blade

Continuation of front page (72) Inventor Takahiro Kawagoe 1302-57 Aobadai, Tokorozawa-shi, Saitama F-term (reference) 2H077 AC04 AD02 AD06 FA13 FA21 FA25 GA03

Claims (11)

[Claims] An image forming apparatus according to claim 1, wherein the toner is carried on the surface to form a thin film of the toner, and in this state, the toner is supplied to the surface of the image forming body by contacting or approaching the image forming body. In a toner carrier for forming a visible image,
The toner carrier having a coating layer made of a resin-containing material obtained by curing a mixture of an alkyd-modified silicone compound and a melamine resin on the surface of a conductive elastic layer. . 2. The mixing ratio of the alkyd-modified silicone compound to the melamine resin (alkyd-modified silicone compound: melamine resin) is 20:80 to 9 by weight of the solid content.
The toner carrier according to claim 1, wherein the ratio is 8: 2. 3. An alkyd-modified silicone compound obtained by modifying an organopolysiloxane and an alkyd by a dehydration-condensation reaction, a modified alkyd-modified silicone compound by a dealcoholization-condensation reaction between an organoalkoxypolysiloxane and an alkyd, and an organopolysiloxane. 2. The composition of claim 1, wherein the polyhydric alcohol, fatty acid and polybasic acid are modified by a dehydration condensation reaction.
Or the toner carrier according to 2. 4. The melamine resin is at least one selected from the group consisting of trimethylol melamine resin, hexamethoxymethyl melamine resin, n-butyl ether melamine resin, and isobutyl ether melamine resin.
4. The toner carrier according to any one of claims 1 to 3. 5. A rubber elastic body constituting a conductive elastic layer,
5. The toner carrier according to claim 1, which is at least one selected from butadiene rubber, ethylene propylene rubber, ethylene propylene diene rubber, and urethane rubber. 6. The conductive elastic layer has a specific resistance of 10 ³ to 1
0 ¹⁰ Ω · cm, the toner according to any hardness 60 ° or less in JIS-A, compression set 20% or less and the surface roughness of the claims 1 to 5 is 15μmRz less in JIS10 point average roughness Carrier. 7. The toner carrier according to claim 1, wherein the thickness of the coating layer is 3 to 50 μm. 8. The toner carrier according to claim 1, wherein the insolubility of the coating layer in the solvent is 70% by weight or more. 9. The coating layer having a specific resistance of 10 ⁹ to 10 ¹⁵
The toner carrier according to any one of claims 1 to 8, wherein Ω · cm. 10. The toner carrier has a resistance of 10 ⁵ to 10 ^12.
Ω and surface roughness are 10 μm Rz in JIS 10 point average roughness
The toner carrier according to claim 1, wherein: 11. An image forming apparatus comprising a toner carrier mounted thereon, and carrying toner on the surface of the toner carrier to form a thin film of the toner carrier. By supplying toner to the body surface,
An image forming apparatus for forming a visible image on the surface of an image forming body, wherein the toner holding body according to claim 1 is used as the toner holding body.