JP2000328329A - Electric shock resistant glove - Google Patents
Electric shock resistant gloveInfo
- Publication number
- JP2000328329A JP2000328329A JP13433099A JP13433099A JP2000328329A JP 2000328329 A JP2000328329 A JP 2000328329A JP 13433099 A JP13433099 A JP 13433099A JP 13433099 A JP13433099 A JP 13433099A JP 2000328329 A JP2000328329 A JP 2000328329A
- Authority
- JP
- Japan
- Prior art keywords
- glove
- layer
- thickness
- latex
- rubber latex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Gloves (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は作業者の感電を防止
する耐電性手袋に関し、特に、手袋表面の摩耗に伴って
現れる手袋表面の色変化で、作業者が手袋交換の必要性
を容易に認識できる耐電性手袋に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a glove for preventing electric shock of an operator, and more particularly, to a glove surface color change caused by wear of a glove surface. Recognizable electricity resistant gloves.
【0002】[0002]
【従来の技術】耐電性手袋は、電気回路作業用の手袋と
して従来から用いられている。この電気回路作業用の手
袋としては、常時作業者の感電を防止しうることが必須
条件であり、耐電性手袋は耐電機能を保つために所定の
耐電層厚さが確保されている。ただし、耐電性手袋は使
用に伴い摩耗して耐電層厚さが減少していくことから、
耐電性手袋の摩耗による耐電機能の低下に対応して、耐
電性手袋を新品と交換する必要があった。2. Description of the Related Art Electrostatic gloves have been conventionally used as gloves for working on electric circuits. It is an essential condition of the gloves for working on an electric circuit that it is always possible to prevent an electric shock of an operator, and the electric-resistant gloves have a predetermined electric-resistant layer thickness in order to maintain the electric-proof function. However, since the gloves wear due to their use and the thickness of the glove layer decreases,
It was necessary to replace the glove with a new glove in response to the deterioration of the glove performance due to wear of the glove.
【0003】[0003]
【発明が解決しようとする課題】こうした従来の耐電性
手袋では、交換時期を知るためには耐電性手袋を使用す
る各作業者の目視による摩耗具合の観察に頼らざるを得
ず、仮に作業者が耐電性手袋の摩耗状態を見誤り、本来
の交換時期を越えて使用を続けた場合には、作業中に感
電する可能性があるという課題を有していた。In such conventional gloves, in order to know when to replace the gloves, each worker who uses the gloves must rely on visual observation of the degree of wear. However, there is a problem in that if the wear state of the electric-resistant glove is misunderstood and the use is continued beyond the original replacement time, an electric shock may occur during the work.
【0004】本発明は、前記課題を解消するためになさ
れたもので、摩耗に伴う厚み減少による耐電機能低下を
手袋表面の色変化で示し、手袋の交換時期を分かりやす
く容易に使用者に認識させられる耐電性手袋を提供する
ことを目的とする。SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problem, and indicates a decrease in the electric resistance function due to a decrease in thickness due to abrasion by a color change on the surface of the glove, so that the user can easily and easily recognize when to replace the glove. An object of the present invention is to provide a glove that is resistant to electricity.
【0005】[0005]
【課題を解決するための手段】本発明に係る耐電性手袋
は、布又は編物製の手袋の外面側に耐電性の弾性材を複
数層状に被覆させて形成される耐電性手袋において、前
記手袋からいずれかの層外面までの被覆厚さが手袋内側
で所定の耐電性を確保可能な限界の厚さとされてなると
共に、当該厚さをなす層外面より外側に被覆される層の
色を前記厚さをなす層外面の色と異ならせるものであ
る。このように本発明においては、手袋から層外面まで
の被覆厚さが手袋内側で所定の耐電性を確保可能な限界
の厚さとなる所定の層の外面とその外側に被覆される層
とを互いに異なる色に設定し、感電が起らない十分な耐
電層厚さを保っている状態と、それ以上の摩耗で感電の
可能性が生じる耐電層厚さとなった状態とで外表面がそ
れぞれ異なった色となることにより、手袋の耐電機能が
限界に達したことを色変化で明瞭に示せることとなり、
作業者の注意を引きやすく、作業者に確実に新品との交
換時期を認識させられ、感電事故を未然に防止すること
ができる。According to the present invention, there is provided a glove made of a cloth or a knitted fabric in which an outer surface of a glove made of cloth or knit is coated with a plurality of layers of a glove having a resistance to electricity. The coating thickness from the outer surface of any one of the layers to the limit thickness capable of securing a predetermined electric resistance inside the glove, and the color of the layer coated outside the outer surface of the layer having the thickness is set to the color. The thickness of the layer is different from the color of the outer surface. As described above, in the present invention, the outer surface of the predetermined layer whose coating thickness from the glove to the outer surface of the layer becomes the limit thickness capable of securing the predetermined electric resistance inside the glove and the layer coated on the outer side of the predetermined layer are mutually separated. The outer surface is different depending on whether the color is set to a different color and the thickness of the anti-electric layer is sufficient to prevent electric shock, and the thickness of the anti-electric layer is high enough to cause an electric shock due to further wear. By becoming color, it will be able to clearly show that the electric resistance function of the glove has reached the limit by color change,
It is easy to draw the attention of the operator, the operator can be surely aware of the time of replacement with a new one, and an electric shock accident can be prevented beforehand.
【0006】また、本発明に係る耐電性手袋は必要に応
じて、前記手袋内側で所定の耐電性を確保可能な限界の
厚さとして手袋に直接接触させて被覆形成され、気泡を
多量に含む発泡層と、当該発泡層の外側に被覆形成さ
れ、発泡層と異なる色の耐電性の弾性材のみからなる固
状ゴム状体層とを少なくとも備えるものである。[0006] Further, the anti-static glove according to the present invention, if necessary, is formed as a limit thickness capable of securing a predetermined anti-static property inside the glove, and is formed by coating directly on the glove, and contains a large amount of bubbles. It is provided with at least a foam layer and a solid rubber-like material layer formed only of an electro-resistant elastic material of a different color from the foam layer, which is formed on the outside of the foam layer.
【0007】このように本発明においては、手袋に接触
した層には発泡層を形成すると共に、発泡層の外表面に
異なる色の固状ゴム状体層を形成し、柔軟な発泡層を固
状ゴム状体層で覆った状態とすることにより、固状ゴム
状体層が外表面を完全に覆って十分な耐電層厚さを保っ
ている状態と、摩耗で発泡層が露出して感電の可能性が
生じる耐電層厚さとなった状態とが色変化で明瞭に識別
できることとなり、作業者の注意を引きやすく、作業者
に確実に新品との交換時期を認識させて感電事故を未然
に防止できる。さらに、発泡層が手袋の伸縮性を阻害せ
ず、手袋全体の柔軟性や作業性が保たれる上、発泡層で
固状ゴム状体層の屈曲が構造的に緩衝されて、より柔軟
な感触を与えることができ、作業者の指先の微妙な感覚
を保ち、使い勝手がよく作業性に優れる。加えて、製造
時に発泡層はその外層の固状ゴム状体層の目止めの役割
を果し、固状ゴム状体層にピンホール等を発生させず、
固状ゴム状体層を必要最小限の厚さ以上に厚くさせずに
済み、安全性や信頼性を確保しつつ、柔軟性、作業性の
向上が図れる。As described above, in the present invention, a foam layer is formed on the layer in contact with the glove, and a solid rubber-like body layer of a different color is formed on the outer surface of the foam layer to form a flexible foam layer. When the rubber layer is covered with the rubber layer, the solid rubber layer completely covers the outer surface and maintains a sufficient thickness of the electricity-proof layer. The color change can be clearly distinguished from the state in which the thickness of the anti-static layer at which the possibility of the occurrence of electric shock occurs.It is easy to draw the attention of the worker, and the worker is sure to recognize the time to replace it with a new one to prevent an electric shock accident. Can be prevented. Furthermore, the foam layer does not inhibit the elasticity of the glove, and the flexibility and workability of the entire glove can be maintained. In addition, the bending of the solid rubber-like material layer is structurally buffered by the foam layer, so that the glove is more flexible. The touch can be given, the subtle sensation of the operator's fingertip is maintained, and the operability is good and the workability is excellent. In addition, at the time of manufacture, the foam layer serves as a seal for the outer solid rubber-like material layer, and does not generate pinholes or the like in the solid rubber-like material layer.
The solid rubber-like material layer does not need to be thicker than the minimum necessary thickness, and safety and reliability can be ensured, and flexibility and workability can be improved.
【0008】また、本発明に係る耐電性手袋は必要に応
じて、所定厚さで手袋に直接接触させて被覆形成され、
気泡を多量に含む発泡層と、当該発泡層の外側に発泡層
を含めた厚さが前記手袋内側で所定の耐電性を確保可能
な限界の厚さとなる被覆厚さで被覆形成され、耐電性の
弾性材のみからなる一の固状ゴム状体層と、当該一の固
状ゴム状体層の外側に被覆形成され、一の固状ゴム状体
層と異なる色の耐電性の弾性材のみからなる他の固状ゴ
ム状体層とを少なくとも備えるものである。[0008] Further, the anti-static glove according to the present invention is formed by coating the glove with a predetermined thickness by directly contacting the glove, if necessary.
A foam layer containing a large amount of air bubbles, and a coating thickness including the foam layer on the outside of the foam layer is formed as a coating thickness that is a limit thickness capable of securing a predetermined electric resistance inside the glove; A solid rubber-like material layer composed of only the elastic material of the above, and only the electro-resistant elastic material of a color different from that of the one solid rubber-like material layer formed on the outside of the one solid rubber-like material layer And at least another solid rubber-like body layer made of
【0009】このように本発明においては、手袋に接触
した層には発泡層を形成すると共に、発泡層の外表面に
それぞれ異なる色の固状ゴム状体層を二層形成し、柔軟
な発泡層を二つの固状ゴム状体層で覆った状態とするこ
とにより、外側の固状ゴム状体層が外表面を完全に覆っ
て十分な耐電層厚さを保っている状態と、摩耗で内側の
固状ゴム状体層が露出して感電の可能性が生じる耐電層
厚さとなった状態とが色変化で明瞭に識別できることと
なり、作業者の注意を引きやすく、作業者に確実に新品
との交換時期を認識させて感電事故を未然に防止できる
と共に、発泡層の外側に固状ゴム状体層を二層以上形成
することで手袋全体としての信頼性も向上させられる。
さらに、発泡層が手袋の伸縮性を阻害せず、手袋全体の
柔軟性や作業性が保たれる上、発泡層で固状ゴム状体層
の屈曲が構造的に緩衝されて、より柔軟な感触を与える
ことができ、作業者の指先の微妙な感覚を保ち、使い勝
手がよく作業性に優れる。加えて、製造時に発泡層はそ
の外層の固状ゴム状体層の目止めの役割を果し、固状ゴ
ム状体層にピンホール等を発生させず、固状ゴム状体層
を必要最小限の厚さ以上に厚くさせずに済み、安全性や
信頼性を確保しつつ、柔軟性、作業性の向上が図れる。As described above, according to the present invention, a foam layer is formed on the layer in contact with the glove, and two solid rubber layers of different colors are formed on the outer surface of the foam layer, respectively. By covering the layer with two solid rubber layers, the outer solid rubber layer completely covers the outer surface and maintains a sufficient thickness of the antistatic layer, The state where the inner solid rubber-like material layer is exposed and there is a possibility of electric shock can be clearly distinguished by the color change from the state of the withstand layer thickness, which makes it easier to draw the attention of the worker and ensures that the worker has a new product. It is possible to prevent the electric shock accident beforehand by recognizing the replacement time, and the reliability of the entire glove can be improved by forming two or more solid rubber layers outside the foam layer.
Furthermore, the foam layer does not inhibit the elasticity of the glove, and the flexibility and workability of the entire glove can be maintained. In addition, the bending of the solid rubber-like material layer is structurally buffered by the foam layer, so that the glove is more flexible. The touch can be given, the subtle sensation of the operator's fingertip is maintained, and the operability is good and the workability is excellent. In addition, at the time of manufacture, the foamed layer serves as a seal for the outer solid rubber-like material layer, and does not generate pinholes in the solid rubber-like material layer. It is not necessary to make it thicker than the minimum thickness, and it is possible to improve flexibility and workability while securing safety and reliability.
【0010】また、本発明に係る耐電性手袋は必要に応
じて、前記手袋の外面に浸透防止処理を施され、当該処
理後の手袋外面に耐電性の弾性材を複数層状に被覆させ
て形成されるものである。このように本発明において
は、手袋外面に浸透防止処理を施し、被覆層として凝固
する前の液状の弾性材の手袋への浸透を防ぐことによ
り、被覆層が手袋をなす繊維中や布目もしくは編目孔に
入った状態とならず、手袋の伸縮性を阻害せず製品の柔
軟性や作業性が保たれる。The gloves according to the present invention may be formed, if necessary, by subjecting the outer surfaces of the gloves to a penetration preventing treatment, and covering the outer surfaces of the treated gloves with a plurality of layers of a glove having an electric resistance. Is what is done. In this way, in the present invention, the outer surface of the glove is subjected to a penetration preventing treatment to prevent the liquid elastic material from penetrating into the glove before solidifying as a coating layer, so that the coating layer forms a glove in a fiber, cloth, or stitch. The product does not enter the hole, and does not hinder the elasticity of the glove, thereby maintaining the flexibility and workability of the product.
【0011】また、本発明に係る耐電性手袋は必要に応
じて、前記手袋の外面側にゴムラテックスの凝固剤を付
着させると共に、前記発泡層が、発泡したゴムラテック
スの凝固膜として被覆形成され、前記固状ゴム状体層
が、35ないし65重量%の天然ゴムラテックスと65
ないし35重量%のイソプレンゴムラテックスからなる
混合ゴムラテックスの凝固膜として被覆形成されるもの
である。In addition, the antistatic glove according to the present invention has a rubber latex coagulant adhered to the outer surface side of the glove as required, and the foam layer is formed as a coagulated film of foamed rubber latex. Wherein said solid rubber layer comprises 35 to 65% by weight of natural rubber latex and 65% by weight.
It is formed by coating as a coagulated film of a mixed rubber latex comprising from 35 to 35% by weight of isoprene rubber latex.
【0012】このように本発明においては、手袋の発泡
層との接触部に凝固剤を付着させた後、発泡したゴムラ
テックスを手袋表面に凝固させて発泡層とし、この発泡
層の表面に、35ないし65重量%の天然ゴムラテック
スと65ないし35重量%のイソプレンゴムラテックス
との混合ゴムラテックスを凝固させて固状ゴム状体層と
することにより、泡状のゴムラテックスが手袋外面の編
目孔の中に浸透しにくく、また液圧も小さいことで、発
泡したゴムラテックスが手袋の外表面に泡構造のまま凝
固して発泡層を形成することとなり、発泡層は編目孔に
入った状態とならず、手袋の伸縮性を阻害せず製品の柔
軟性や作業性が保たれる。さらに、外側の固状ゴム状体
層も混合ゴムラテックスへの浸漬により被覆形成できる
ことから、厚さを薄く形成でき、柔軟性に富み、装着感
が向上すると共に、外観が良好で柔らかい耐電性の表面
を得ることができる。As described above, in the present invention, after a coagulant is adhered to the contact portion of the glove with the foam layer, the foamed rubber latex is coagulated on the glove surface to form a foam layer. A mixed rubber latex of 35 to 65% by weight of a natural rubber latex and 65 to 35% by weight of an isoprene rubber latex is coagulated to form a solid rubber layer. It is difficult to penetrate into the inside of the glove, and the liquid pressure is also small, so that the foamed rubber latex solidifies as a foam structure on the outer surface of the glove and forms a foam layer, and the foam layer enters the stitch hole In addition, the flexibility and workability of the product are maintained without hindering the elasticity of the glove. Furthermore, since the outer solid rubber-like material layer can also be formed by coating by dipping in the mixed rubber latex, it can be formed to be thinner, which is rich in flexibility, improves the feeling of wearing, and has good appearance and soft electric resistance. A surface can be obtained.
【0013】また、本発明に係る耐電性手袋は必要に応
じて、前記手袋の内面側に耐電性の弾性材を一又は複数
層状に被覆させて形成されるものである。このように本
発明においては、手袋の内側においても耐電性の弾性材
を層状に被覆配設することにより、手袋全体の強度を高
められ、外部から手袋内側への貫通等の危険をより少な
くすると共に、十分な耐電層厚さを確保できることとな
り、安全性をより一層向上させられる。The gloves according to the present invention may be formed by coating the inner surface of the gloves with one or more layers of a glove, if necessary. As described above, in the present invention, the strength of the entire glove can be increased by covering the glove with a layer of the electrically-resistant elastic material even inside the glove, and the danger of penetration from the outside to the inside of the glove can be further reduced. At the same time, it is possible to ensure a sufficient thickness of the withstand voltage layer, thereby further improving safety.
【0014】[0014]
【発明の実施の形態】(本発明の第1の実施形態)以
下、本発明の第1の実施形態を図1に基づいて説明す
る。この図1は本実施の形態に係る耐電性手袋の概略構
成断面図である。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS (First Embodiment of the Present Invention) Hereinafter, a first embodiment of the present invention will be described with reference to FIG. FIG. 1 is a schematic cross-sectional view of the configuration of the electricity-resistant glove according to the present embodiment.
【0015】前記図1に示す本実施形態の耐電性手袋
は、編物製の手袋1と、この手袋1の外側に発泡状態の
赤色の天然ゴムラテックスを凝固させて被覆形成した発
泡層としての所定厚さの赤色の発泡ラテックス凝固層2
と、この発泡ラテックス凝固層2の外側に35ないし6
5重量%の天然ゴムラテックスと65ないし35重量%
のイソプレンゴムラテックスによりなる白色のブレンド
ゴムラテックスを凝固させて被覆形成される固状ゴム状
体層としての白色ラテックス凝固層3とを備える構成で
ある。The glove 1 of the present embodiment shown in FIG. 1 has a knitted glove 1 and a foamed layer formed by coating and solidifying a foamed red natural rubber latex on the outside of the glove 1. Thick red foamed latex solidified layer 2
35 to 6 outside the solidified layer of the foamed latex 2
5% by weight of natural rubber latex and 65 to 35% by weight
And a white latex solidified layer 3 as a solid rubber-like material layer formed by coagulating a white blend rubber latex made of isoprene rubber latex.
【0016】次に、本実施形態の耐電性手袋の製造方法
について説明する。まず、手袋1を木製手型6に被せた
状態で、凝固剤である硝酸カルシウムの50%メタノー
ル溶液中に浸漬し、引上げて乾燥する。乾燥後、泡立て
た赤色の天然ゴムラテックス中に手袋1を所定時間浸漬
して引き上げる。浸漬している間、手袋1外表面には赤
色の天然ゴムラテックスが気泡を含んだまま凝固して赤
色の発泡ラテックス凝固層2が形成される。泡立てた天
然ゴムラテックスは手袋1外面の編目孔の中に浸透しに
くく、またラテックスの液圧も小さいことで、天然ゴム
ラテックスが手袋1の外表面に泡構造のまま凝固して発
泡層を形成することとなり、発泡層は編目孔に入った状
態とならず、手袋の伸縮性を阻害しない。発泡ラテック
ス凝固層2表面には、引き上げられた状態で未凝固の天
然ゴムラテックスも付着しているので、水シャワー等の
手段で未凝固分を洗い流す。Next, a method for manufacturing the electric resistant glove of the present embodiment will be described. First, while the glove 1 is put on the wooden hand mold 6, it is immersed in a 50% methanol solution of calcium nitrate as a coagulant, pulled up and dried. After drying, the glove 1 is immersed in the foamed red natural rubber latex for a predetermined time and pulled up. During the immersion, the red natural rubber latex solidifies on the outer surface of the glove 1 while containing air bubbles to form a red foamed latex solidified layer 2. The foamed natural rubber latex hardly penetrates into the stitch holes on the outer surface of the glove 1 and the liquid pressure of the latex is small, so that the natural rubber latex solidifies as a foam structure on the outer surface of the glove 1 to form a foam layer. As a result, the foamed layer does not enter the stitch hole and does not hinder the elasticity of the glove. Since the uncoagulated natural rubber latex is also adhered to the surface of the foamed latex coagulated layer 2 in the pulled up state, the uncoagulated component is washed away by means such as a water shower.
【0017】未凝固分を洗い流して乾燥させた後、35
ないし65重量%の天然ゴムラテックスと65ないし3
5重量%のイソプレンゴムラテックスとを混合した白色
ブレンドゴムラテックスに手袋1を所定時間浸漬し、引
き上げて乾燥した後、再度前記白色ブレンドゴムラテッ
クスに所定時間浸漬して引き上げ、発泡ラテックス凝固
層2の外側に白色ブレンドゴムラテックスを凝固させた
所定厚さの白色ラテックス凝固層3を得る。After the uncoagulated matter is washed off and dried, 35
-65% by weight of natural rubber latex and 65-3
The glove 1 is immersed in a white blend rubber latex mixed with 5% by weight of isoprene rubber latex for a predetermined time, pulled up and dried, then immersed again in the white blend rubber latex for a predetermined time and pulled up to form the foamed latex solidified layer 2 A white latex solidified layer 3 having a predetermined thickness obtained by solidifying a white blend rubber latex on the outside is obtained.
【0018】白色ラテックス凝固層3の形成後は、乾
燥、加硫工程を経て型抜きし、温水中で洗浄する(水洗
工程)。この水洗工程により、ラテックス凝固膜中の石
けん、カゼイン等の親水性物質を溶出させ、より耐電性
を向上させられる。洗浄後、所定時間の乾燥を経て製品
が得られる。After the formation of the white latex solidified layer 3, the mold is removed from the mold through drying and vulcanization steps, and washed in warm water (water washing step). By this washing step, a hydrophilic substance such as soap and casein in the coagulated latex film is eluted, and the electric resistance can be further improved. After washing, the product is obtained after drying for a predetermined time.
【0019】このようにして得られた本実施形態の耐電
性手袋は、使用に伴い最外層の白色ラテックス凝固層3
が摩耗して耐電層厚さが減少していき、耐電機能もそれ
に伴って低下していくが、さらなる摩耗が加わると感電
の可能性が生じる耐電層厚さまで摩耗した状態で、発泡
ラテックス凝固層2が露出して外表面に赤色が現れるこ
とから、耐電性手袋の耐電機能が限界に達したことを明
瞭に示すことができ、作業者の注意を引きやすく、作業
者に確実に新品との交換時期を認識させられ、感電事故
を未然に防止することができる。The antistatic glove of the present embodiment thus obtained is used as the outermost white latex coagulated layer 3 with use.
The thickness of the anti-static layer is reduced due to abrasion, and the anti-static function also decreases accordingly.However, if further abrasion is applied, the possibility of electric shock will occur. 2 is exposed and a red color appears on the outer surface, which can clearly indicate that the electric resistance function of the electric resistant glove has reached its limit, easily attracts the attention of the worker, and ensures that the worker is assured that the new product is new. The replacement time can be recognized, and an electric shock accident can be prevented.
【0020】なお、前記実施形態に係る耐電性手袋にお
いて、白色ラテックス凝固層3からなる固状ゴム状体層
は指先で細かい部品を掴んだり引張ったりする作業を容
易に行うため、厚みは0.1〜0.5mmであることが
好ましい。厚みが0.1mmよりも薄ければ耐久性がな
く、0.5mmより厚ければ細かい手作業が困難にな
る。また、発泡ラテックス凝固層2からなる発泡層は耐
電性の保持と作業性を考慮して0.4〜0.7mmの厚
みであることが好ましい。In the glove according to the embodiment, the thickness of the solid rubber-like body layer composed of the solidified layer of white latex 3 is set to 0. It is preferably 1 to 0.5 mm. If the thickness is less than 0.1 mm, there is no durability, and if it is more than 0.5 mm, fine manual work becomes difficult. Further, the foamed layer composed of the foamed latex solidified layer 2 preferably has a thickness of 0.4 to 0.7 mm in consideration of maintaining electric resistance and workability.
【0021】(本発明の第2の実施形態)本発明の第2
の実施形態を図2に基づいて説明する。この図2は本実
施の形態に係る耐電性手袋の概略構成断面図である。(Second Embodiment of the Present Invention) The second embodiment of the present invention
An embodiment will be described with reference to FIG. FIG. 2 is a schematic cross-sectional view of the configuration of the electricity-resistant glove according to the present embodiment.
【0022】前記図2に示す本実施形態の耐電性手袋
は、編物製の手袋1と、この手袋1の外側に発泡状態の
無色の天然ゴムラテックスを凝固させて被覆形成した発
泡層としての所定厚さの無色の発泡ラテックス凝固層4
と、この発泡ラテックス凝固層4の外側に35ないし6
5重量%の天然ゴムラテックスと65ないし35重量%
のイソプレンゴムラテックスによりなる赤色のブレンド
ゴムラテックスを凝固させて被覆形成される固状ゴム状
体層としての赤色ラテックス凝固層5と、この赤色ラテ
ックス凝固層5の外側に35ないし65重量%の天然ゴ
ムラテックスと65ないし35重量%のイソプレンゴム
ラテックスによりなる白色のブレンドゴムラテックスを
凝固させて被覆形成される固状ゴム状体層としての白色
ラテックス凝固層3とを備える構成である。次に、本実
施形態の耐電性手袋の製造方法について説明する。ま
ず、手袋1を木製手型6に被せた状態で、凝固剤である
硝酸カルシウムの50%メタノール溶液中に浸漬し、引
上げて乾燥する。The glove 1 of this embodiment shown in FIG. 2 has a knitted glove 1 and a foamed layer formed by solidifying a foamed colorless natural rubber latex on the outside of the glove 1 as a foam layer. Colorless foamed latex solidified layer 4 of thickness
35 to 6 outside the solidified layer 4 of the foamed latex
5% by weight of natural rubber latex and 65 to 35% by weight
A red latex coagulation layer 5 as a solid rubber-like material layer formed by coagulating a red blend rubber latex made of isoprene rubber latex of the above, and 35 to 65% by weight of natural A white latex coagulation layer 3 as a solid rubber-like material layer formed by coagulating a white blend rubber latex made of rubber latex and 65 to 35% by weight of isoprene rubber latex. Next, a method for manufacturing the electricity-resistant glove of the present embodiment will be described. First, while the glove 1 is put on the wooden hand mold 6, it is immersed in a 50% methanol solution of calcium nitrate as a coagulant, pulled up and dried.
【0023】乾燥後、泡立てた無色の天然ゴムラテック
ス中に手袋1を所定時間浸漬して引き上げる。浸漬して
いる間、手袋1外表面には無色の天然ゴムラテックスが
気泡を含んだまま凝固して無色の発泡ラテックス凝固層
4が形成される。泡立てた天然ゴムラテックスは手袋1
外面の編目孔の中に浸透しにくく、またラテックスの液
圧も小さいことで、天然ゴムラテックスが手袋1の外表
面に泡構造のまま凝固して発泡層を形成することとな
り、発泡層は編目孔に入った状態とならず、手袋の伸縮
性を阻害しない。発泡ラテックス凝固層4表面には、引
き上げられた状態で未凝固の天然ゴムラテックスも付着
しているので、水シャワー等の手段で未凝固分を洗い流
す。After drying, the glove 1 is immersed in a foamed colorless natural rubber latex for a predetermined time and pulled up. During the immersion, the colorless natural rubber latex solidifies on the outer surface of the glove 1 while containing air bubbles to form a colorless foamed latex solidified layer 4. Glove 1 with foamed natural rubber latex
The natural rubber latex solidifies as a foam structure on the outer surface of the glove 1 and forms a foamed layer due to the low penetration of the latex and the low liquid pressure of the latex. It does not enter the hole and does not hinder the elasticity of the glove. Uncoagulated natural rubber latex is also adhered to the surface of the foamed latex coagulated layer 4 in a pulled up state, so that uncoagulated components are washed away by means such as a water shower.
【0024】未凝固分を洗い流して乾燥させた後、35
ないし65重量%の天然ゴムラテックスと65ないし3
5重量%のイソプレンゴムラテックスとを混合した赤色
ブレンドゴムラテックスに手袋1を所定時間浸漬し、引
き上げて乾燥させ、発泡ラテックス凝固層4の外側に赤
色ブレンドゴムラテックスを凝固させた所定厚さの赤色
ラテックス凝固層5を得る。After the uncoagulated matter is washed off and dried, 35
-65% by weight of natural rubber latex and 65-3
The glove 1 is immersed in a red blended rubber latex mixed with 5% by weight of isoprene rubber latex for a predetermined time, pulled up and dried, and the red blended rubber latex is solidified on the outside of the foamed latex solidified layer 4 to a predetermined thickness of red. A latex coagulation layer 5 is obtained.
【0025】赤色ラテックス凝固層5の形成後、35な
いし65重量%の天然ゴムラテックスと65ないし35
重量%のイソプレンゴムラテックスとを混合した白色ブ
レンドゴムラテックスに手袋1を所定時間浸漬して引き
上げ、赤色ラテックス凝固層5の外側に白色ブレンドゴ
ムラテックスを凝固させた所定厚さの白色ラテックス凝
固層3を得る。After the formation of the red latex solidified layer 5, 35 to 65% by weight of natural rubber latex and 65 to 35%
The glove 1 is dipped in a white blend rubber latex mixed with isoprene rubber latex by weight for a predetermined time and pulled up, and the white latex solidified layer 3 having a predetermined thickness is formed by coagulating the white blend rubber latex outside the red latex solidified layer 5. Get.
【0026】白色ラテックス凝固層3の形成後は、乾
燥、加硫工程を経て型抜きし、温水中で洗浄する(水洗
工程)。洗浄後、所定時間の乾燥を経て製品が得られ
る。このようにして得られた本実施形態の耐電性手袋
は、使用に伴い最外層の白色ラテックス凝固層3が摩耗
して耐電層厚さが減少していき、耐電機能もそれに伴っ
て低下していくが、さらなる摩耗が加わると感電の可能
性が生じる耐電層厚さまで摩耗した状態で、赤色ラテッ
クス凝固層5が露出して外表面に赤色が現れることか
ら、耐電性手袋の耐電機能が限界に達したことを明瞭に
示すことができ、作業者の注意を引きやすく、作業者に
確実に新品との交換時期を認識させられ、感電事故を未
然に防止することができる。After the formation of the white latex solidified layer 3, the mold is removed through a drying and vulcanizing process and washed in warm water (water washing process). After washing, the product is obtained after drying for a predetermined time. The anti-static glove of the present embodiment obtained in this manner wears the outermost white latex solidified layer 3 due to use and the thickness of the anti-static layer decreases, and the anti-static function also decreases accordingly. However, if further abrasion is applied, the possibility of electric shock will occur. In the state of wear to the thickness of the antistatic layer, the red latex solidified layer 5 is exposed and red appears on the outer surface. It is possible to clearly indicate that the time has been reached, to easily draw the attention of the worker, to make the worker surely recognize the time of replacement with a new one, and to prevent an electric shock accident.
【0027】なお、前記第1及び第2の各実施の形態に
おいては、最外層の白色ラテックス凝固層3に対し、当
初から色の異なる赤色の発泡ラテックス凝固層2、もし
くは赤色ラテックス凝固層5が白色ラテックス凝固層3
の摩耗によって露出することで耐電性手袋の耐電機能が
限界に達したことを示す仕組みとしているが、この他、
例えば空気中の酸素や水等の、所定の雰囲気中の物質に
接触すると化学反応により所定の色を呈する物質を含ん
だ耐電性の弾性材を手袋に前記雰囲気と触れない状態で
被覆形成すると共に、最外層を前記所定色と異なる色と
して被覆形成する構成とすることもでき、最外層の摩耗
で内側の層が露出した際に雰囲気に触れて外側の層と異
なる色に変色することで前記同様に耐電性手袋の耐電機
能が限界に達したことを明瞭に示すことができ、作業者
に交換時期を認識させられる。In each of the first and second embodiments, the red foamed latex coagulation layer 2 or the red latex coagulation layer 5 having a different color from the beginning is different from the outermost white latex coagulation layer 3. White latex solidified layer 3
Exposure due to wear of the glove indicates that the anti-static function of the glove has reached its limit.
For example, a glove is formed on a glove in a state in which it does not come into contact with the atmosphere, including an anti-static elastic material containing a substance that exhibits a predetermined color by a chemical reaction when it comes into contact with a substance in a predetermined atmosphere, such as oxygen or water in the air. The outermost layer may be formed so as to cover the outermost layer as a color different from the predetermined color.When the innermost layer is exposed due to wear of the outermost layer, the outermost layer is exposed to an atmosphere and changes color to a color different from the outermost layer. Similarly, it is possible to clearly indicate that the electricity-resistant function of the electricity-resistant glove has reached its limit, and to make the worker aware of the replacement time.
【0028】また、前記第1及び第2の各実施の形態に
おいては、手袋1の外面に手袋1に浸透しにくい性質を
有する発泡した天然ゴムラテックスをそのまま接触させ
て凝固させ、発泡ラテックス凝固層2、4を被覆形成す
る構成としているが、この他、手袋1外面にあらかじめ
浸透防止処理を施してから、所定のゴムラテックスに接
触させて凝固させる構成とすることもでき、被覆層とし
て凝固する前のゴムラテックスの手袋への浸透を防ぐこ
とにより、凝固した層が手袋をなす繊維中や布目もしく
は編目孔に入った状態とならず、浸透しやすいゴムラテ
ックスを用いる場合でも手袋1の伸縮性を阻害せず、前
記実施の形態同様、製品の柔軟性や作業性が保たれる。In each of the first and second embodiments, a foamed natural rubber latex having a property of hardly penetrating the glove 1 is brought into contact with the outer surface of the glove 1 as it is to coagulate, and the foamed latex coagulated layer is formed. 2, 4 are coated. Alternatively, the outer surface of the glove 1 may be subjected to an anti-penetration treatment and then brought into contact with a predetermined rubber latex to be solidified. By preventing the previous rubber latex from penetrating into the glove, the solidified layer does not enter into the fibers forming the glove, the cloth or the stitch holes, and the elasticity of the glove 1 even when rubber latex that easily penetrates is used. And the flexibility and workability of the product are maintained as in the above embodiment.
【0029】また、前記第1及び第2の各実施の形態に
おいては、手袋1の外面に弾性材である発泡層及び固状
ゴム状体層を被覆形成する構成としているが、この他、
手袋1内面にも、耐電性の弾性材層を一又は複数層被覆
形成する構成とすることもでき、手袋1の外側に加えて
内側にも耐電性の弾性材層を設けることで、耐電性手袋
全体の強度を高められ、外部から手袋内側への貫通等の
危険をより少なくすると共に、十分な耐電層厚さを確保
できることとなり、安全性のより一層の向上が図れる。
さらに、手袋1内面にも耐電性の弾性材層を一又は複数
層被覆形成した前記の場合で、この手袋1内面側の弾性
材層の最内面(作業者の手部に直接接する面)から手袋
1外側の所定の層外面までの被覆厚さが耐電性手袋内側
で所定の耐電性を確保可能な限界の厚さとなるように設
定し、この所定層の外側に異なる色の層を被覆形成する
構成とすることもでき、感電の可能性が生じる耐電層厚
さまで摩耗すると色の異なる層が露出して耐電性手袋の
耐電機能限界を明瞭に示せる特長はそのままに、耐電性
手袋全体の厚さをより薄くして作業性を向上させられ
る。In each of the first and second embodiments, the outer surface of the glove 1 is formed by covering the outer surface of the glove 1 with the foamed layer and the solid rubber-like layer, which are elastic materials.
The inner surface of the glove 1 may be formed by coating one or more layers of an electro-resistant elastic material layer. By providing an electro-conductive elastic material layer on the inside as well as on the outside of the glove 1, The strength of the entire glove can be increased, the danger of penetration from the outside to the inside of the glove can be reduced, and a sufficient thickness of the withstand layer can be secured, so that safety can be further improved.
Further, in the above-described case where one or more layers of the electro-resistant elastic material layer are formed on the inner surface of the glove 1, the innermost surface of the elastic material layer on the inner surface side of the glove 1 (the surface directly in contact with the hand of the worker). The thickness of the coating up to the outer surface of the predetermined layer on the outer side of the glove 1 is set so as to be a limit thickness capable of securing the predetermined electric resistance inside the glove, and a layer of a different color is formed outside the predetermined layer. When abrasion is performed to the thickness of the anti-static layer where the possibility of electric shock is generated, layers of different colors are exposed and the characteristics of the anti-static glove can be clearly shown, while maintaining the thickness of the entire anti-static glove. Workability can be improved by making it thinner.
【0030】[0030]
【実施例】(実施例1)まず、木製手型6に、綿糸40
番手引揃えのメリヤス編みした手袋1を被せた。この手
袋1を凝固剤である硝酸カルシウムの50%メタノール
溶液に浸漬し、70℃の乾燥室に15分間入れて乾燥
し、室温に10分間静置後、赤色の天然ゴムラテックス
(ミキサーにて3.5〜4.0倍に泡立てたもの)中に
1分間浸漬して引き上げる。この時、手袋表面には赤色
の発泡ラテックス凝固層2が形成されており、その外側
には未凝固の天然ゴムラテックスが付着した状態で引き
上げられるので、未凝固の天然ゴムラテックスを水シャ
ワーで洗い流した。(Embodiment 1) First, a cotton hand 40 is put on a cotton hand mold 6.
Knitted gloves 1 of count-aligned knitting were put on. The glove 1 is immersed in a 50% methanol solution of calcium nitrate as a coagulant, placed in a drying chamber at 70 ° C. for 15 minutes, dried, and allowed to stand at room temperature for 10 minutes. And then lifted up by immersion for 1 minute. At this time, a red foamed latex coagulated layer 2 is formed on the surface of the glove, and the non-coagulated natural rubber latex is washed off with a water shower because the non-coagulated natural rubber latex is pulled up with the non-coagulated natural rubber latex adhered to the outside. Was.
【0031】常温風による乾燥後、前記手袋1を35重
量%の天然ゴムラテックスと65重量%のイソプレンゴ
ムラテックスによりなる白色ゴムラテックスに10秒間
浸漬し、引き上げて乾燥した後、再び、35重量%の天
然ゴムラテックスと65重量%のイソプレンゴムラテッ
クスによりなる白色ゴムラテックスに10秒間浸漬し引
き上げて白色ラテックス凝固層3を成形した。あとは段
階的に100℃まで昇温して乾燥させる。次いで加硫缶
にて100℃で50分間、間接加硫を行い型抜き後、7
5℃の温水中にて3時間洗浄し、70℃の乾燥室にて6
時間乾燥して本発明の耐電性手袋を得た。本実施例にお
いて、赤色の発泡ラテックス凝固層2の厚みは0.5m
m、白色ラテックス凝固層3の厚みは0.3mmであっ
た。After drying with normal temperature air, the glove 1 was immersed in white rubber latex composed of 35% by weight of natural rubber latex and 65% by weight of isoprene rubber latex for 10 seconds, pulled up and dried, and then dried again with 35% by weight. Was dipped in white rubber latex consisting of natural rubber latex and 65% by weight of isoprene rubber latex for 10 seconds and pulled up to form a white latex solidified layer 3. Then, the temperature is increased stepwise to 100 ° C. and dried. Next, indirect vulcanization was performed in a vulcanizer at 100 ° C. for 50 minutes, and after punching, 7
Wash in warm water at 5 ° C for 3 hours and dry in 70 ° C drying room for 6 hours.
After drying for an hour, an anti-static glove of the present invention was obtained. In this embodiment, the thickness of the red foamed latex solidified layer 2 is 0.5 m
m, the thickness of the white latex solidified layer 3 was 0.3 mm.
【0032】(実施例2)まず、木製手型6に、綿糸4
0番手引揃えのメリヤス編みした手袋1を被せた。この
手袋1を凝固剤である硝酸カルシウムの50%メタノー
ル溶液に浸漬し、70℃の乾燥室に15分間入れて乾燥
し、室温に10分間静置後、無色の天然ゴムラテックス
(ミキサーにて3.5〜4.0倍に泡立てたもの)中に
1分間浸漬して引き上げる。この時、手袋表面には無色
の発泡ラテックス凝固層4が形成されており、その外側
には未凝固の天然ゴムラテックスが付着した状態で引き
上げられるので、未凝固の天然ゴムラテックスを水シャ
ワーで洗い流した。(Example 2) First, a cotton hand 4 was put on a wooden hand mold 6.
The knitted gloves 1 of the 0th drawer were put on. The glove 1 is immersed in a 50% methanol solution of calcium nitrate as a coagulant, placed in a drying chamber at 70 ° C. for 15 minutes, dried, and allowed to stand at room temperature for 10 minutes. And then lifted up by immersion for 1 minute. At this time, a colorless foamed latex coagulated layer 4 is formed on the glove surface, and the non-coagulated natural rubber latex is washed out with a water shower because the coagulated natural rubber latex is pulled up with the non-coagulated natural rubber latex adhered to the outside. Was.
【0033】常温風による乾燥後、前記手袋1を35重
量%の天然ゴムラテックスと65重量%のイソプレンゴ
ムラテックスによりなる赤色ゴムラテックスに10秒間
浸漬し引き上げて乾燥し、赤色ラテックス凝固層5を成
形する。この後、35重量%の天然ゴムラテックスと6
5重量%のイソプレンゴムラテックスによりなる白色ゴ
ムラテックスに10秒間浸漬し引き上げて白色ラテック
ス凝固層3を成形した。After drying with air at normal temperature, the glove 1 was dipped in red rubber latex composed of 35% by weight of natural rubber latex and 65% by weight of isoprene rubber latex for 10 seconds, pulled up and dried to form a red latex solidified layer 5. I do. After that, 35% by weight of natural rubber latex and 6%
It was immersed in white rubber latex made of 5% by weight of isoprene rubber latex for 10 seconds and pulled up to form a white latex solidified layer 3.
【0034】あとは段階的に100℃まで昇温して乾燥
させる。次いで加硫缶にて100℃で50分間、間接加
硫を行い型抜き後、75℃の温水中にて3時間洗浄し、
70℃の乾燥室にて6時間乾燥して本発明の耐電性手袋
を得た。本実施例において、無色の発泡ラテックス凝固
層4の厚みは0.5mm、赤色ラテックス凝固層5の厚
みは0.1mm、白色ラテックス凝固層3の厚みは0.
2mmであった。Thereafter, the temperature is raised stepwise to 100 ° C. and dried. Next, indirect vulcanization was performed in a vulcanizer at 100 ° C. for 50 minutes, and after punching, the mold was washed in warm water at 75 ° C. for 3 hours.
Drying was performed in a drying chamber at 70 ° C. for 6 hours to obtain an antistatic glove of the present invention. In this example, the thickness of the colorless foamed latex coagulation layer 4 is 0.5 mm, the thickness of the red latex coagulation layer 5 is 0.1 mm, and the thickness of the white latex coagulation layer 3 is 0.1 mm.
2 mm.
【0035】[0035]
【発明の効果】このように本発明によれば、手袋から層
外面までの被覆厚さが手袋内側で所定の耐電性を確保可
能な限界の厚さとなる所定の層の外面とその外側に被覆
される層とを互いに異なる色に設定し、感電が起らない
十分な耐電層厚さを保っている状態と、それ以上の摩耗
で感電の可能性が生じる耐電層厚さとなった状態とで外
表面がそれぞれ異なった色となることにより、手袋の耐
電機能が限界に達したことを色変化で明瞭に示せること
となり、作業者の注意を引きやすく、作業者に確実に新
品との交換時期を認識させられ、感電事故を未然に防止
することができるという効果を奏する。As described above, according to the present invention, the outer surface of the predetermined layer and the outer surface thereof are coated so that the coating thickness from the glove to the outer surface of the layer becomes the limit thickness capable of securing the predetermined electric resistance inside the glove. The different layers are set to different colors to maintain a sufficient thickness of the electro-conductive layer that does not cause electric shock, and a state in which the thickness of the electro-conductive layer causes the possibility of electric shock due to further abrasion. Since the outer surface has a different color, it is possible to clearly indicate that the glove has reached the limit of the electric resistance function by color change, it is easy to draw the attention of the worker, and the worker is sure to replace the glove with a new one. And the electric shock accident can be prevented beforehand.
【0036】また、本発明によれば、手袋に接触した層
には発泡層を形成すると共に、発泡層の外表面に異なる
色の固状ゴム状体層を形成し、柔軟な発泡層を固状ゴム
状体層で覆った状態とすることにより、固状ゴム状体層
が外表面を完全に覆って十分な耐電層厚さを保っている
状態と、摩耗で発泡層が露出して感電の可能性が生じる
耐電層厚さとなった状態とが色変化で明瞭に識別できる
こととなり、作業者の注意を引きやすく、作業者に確実
に新品との交換時期を認識させて感電事故を未然に防止
できる。さらに、発泡層が手袋の伸縮性を阻害せず、手
袋全体の柔軟性や作業性が保たれる上、発泡層で固状ゴ
ム状体層の屈曲が構造的に緩衝されて、より柔軟な感触
を与えることができ、作業者の指先の微妙な感覚を保
ち、使い勝手がよく作業性に優れる。加えて、製造時に
発泡層はその外層の固状ゴム状体層の目止めの役割を果
し、固状ゴム状体層にピンホール等を発生させず、固状
ゴム状体層を必要最小限の厚さ以上に厚くさせずに済
み、安全性や信頼性を確保しつつ、柔軟性、作業性の向
上が図れるという効果を有する。According to the present invention, a foam layer is formed on the layer in contact with the glove, and a solid rubber layer of a different color is formed on the outer surface of the foam layer to form a flexible foam layer. When the rubber layer is covered with the rubber layer, the solid rubber layer completely covers the outer surface and maintains a sufficient thickness of the electricity-proof layer. The color change can be clearly distinguished from the state in which the thickness of the anti-static layer at which the possibility of the occurrence of electric shock occurs.It is easy to draw the attention of the worker, and the worker is sure to recognize the time to replace it with a new one to prevent an electric shock accident. Can be prevented. Furthermore, the foam layer does not inhibit the elasticity of the glove, and the flexibility and workability of the entire glove can be maintained. In addition, the bending of the solid rubber-like material layer is structurally buffered by the foam layer, so that the glove is more flexible. The touch can be given, the subtle sensation of the operator's fingertip is maintained, and the operability is good and the workability is excellent. In addition, at the time of manufacture, the foamed layer serves as a seal for the outer solid rubber-like material layer, and does not generate pinholes in the solid rubber-like material layer. It is not necessary to make it thicker than the minimum thickness, and there is an effect that flexibility and workability can be improved while ensuring safety and reliability.
【0037】また、本発明によれば、手袋に接触した層
には発泡層を形成すると共に、発泡層の外表面にそれぞ
れ異なる色の固状ゴム状体層を二層形成し、柔軟な発泡
層を二つの固状ゴム状体層で覆った状態とすることによ
り、外側の固状ゴム状体層が外表面を完全に覆って十分
な耐電層厚さを保っている状態と、摩耗で内側の固状ゴ
ム状体層が露出して感電の可能性が生じる耐電層厚さと
なった状態とが色変化で明瞭に識別できることとなり、
作業者の注意を引きやすく、作業者に確実に新品との交
換時期を認識させて感電事故を未然に防止できると共
に、発泡層の外側に固状ゴム状体層を二層以上形成する
ことで手袋全体としての信頼性も向上させられる。さら
に、発泡層が手袋の伸縮性を阻害せず、手袋全体の柔軟
性や作業性が保たれる上、発泡層で固状ゴム状体層の屈
曲が構造的に緩衝されて、より柔軟な感触を与えること
ができ、作業者の指先の微妙な感覚を保ち、使い勝手が
よく作業性に優れる。加えて、製造時に発泡層はその外
層の固状ゴム状体層の目止めの役割を果し、固状ゴム状
体層にピンホール等を発生させず、固状ゴム状体層を必
要最小限の厚さ以上に厚くさせずに済み、安全性や信頼
性を確保しつつ、柔軟性、作業性の向上が図れるという
効果を有する。According to the present invention, a foam layer is formed on the layer in contact with the glove, and two solid rubber layers of different colors are formed on the outer surface of the foam layer, respectively. By covering the layer with two solid rubber layers, the outer solid rubber layer completely covers the outer surface and maintains a sufficient thickness of the antistatic layer, The state in which the inner solid rubber-like material layer is exposed and the possibility of electric shock becomes the withstand layer thickness can be clearly distinguished by color change,
It is easy to draw the attention of the worker, and it is possible to prevent the electric shock accident beforehand by making the worker aware of the replacement time with the new one, and to form two or more solid rubber layers outside the foam layer. The reliability of the glove as a whole is also improved. Furthermore, the foam layer does not inhibit the elasticity of the glove, and the flexibility and workability of the entire glove can be maintained. In addition, the bending of the solid rubber-like material layer is structurally buffered by the foam layer, so that the glove is more flexible. The touch can be given, the subtle sensation of the operator's fingertip is maintained, and the operability is good and the workability is excellent. In addition, at the time of manufacture, the foamed layer serves as a seal for the outer solid rubber-like material layer, and does not generate pinholes in the solid rubber-like material layer. It is not necessary to make it thicker than the minimum thickness, and there is an effect that flexibility and workability can be improved while ensuring safety and reliability.
【0038】また、本発明によれば、手袋外面に浸透防
止処理を施し、被覆層として凝固する前の液状の弾性材
の手袋への浸透を防ぐことにより、被覆層が手袋をなす
繊維中や布目もしくは編目孔に入った状態とならず、手
袋の伸縮性を阻害せず製品の柔軟性や作業性が保たれる
という効果を有する。Further, according to the present invention, the outer surface of the glove is subjected to a penetration preventing treatment to prevent the liquid elastic material from penetrating into the glove before being solidified as the coating layer, so that the coating layer can be used in the fibers forming the glove. It does not enter the texture or stitch hole, and has the effect of maintaining the flexibility and workability of the product without inhibiting the elasticity of the glove.
【0039】また、本発明によれば、手袋の発泡層との
接触部に凝固剤を付着させた後、発泡したゴムラテック
スを手袋表面に凝固させて発泡層とし、この発泡層の表
面に、35〜65重量%の天然ゴムラテックスと65〜
35重量%のイソプレンゴムラテックスとの混合ゴムラ
テックスを凝固させて固状ゴム状体層とすることによ
り、泡状のゴムラテックスが手袋外面の編目孔の中に浸
透しにくく、また液圧も小さいことで、発泡したゴムラ
テックスが手袋の外表面に泡構造のまま凝固して発泡層
を形成することとなり、発泡層は編目孔に入った状態と
ならず、手袋の伸縮性を阻害せず製品の柔軟性や作業性
が保たれる。さらに、外側の固状ゴム状体層も混合ゴム
ラテックスへの浸漬により被覆形成できることから、厚
さを薄く形成でき、柔軟性に富み、装着感が向上すると
共に、外観が良好で柔らかい耐電性の表面を得ることが
できるという効果を有する。Further, according to the present invention, after a coagulant is adhered to the contact portion of the glove with the foam layer, the foamed rubber latex is coagulated on the glove surface to form a foam layer. 35-65% by weight of natural rubber latex and 65-65%
The rubber latex mixed with 35% by weight of isoprene rubber latex is coagulated to form a solid rubber layer, so that the foamy rubber latex hardly penetrates into the stitch holes on the outer surface of the glove and the liquid pressure is small. As a result, the foamed rubber latex solidifies on the outer surface of the glove with a foam structure and forms a foam layer, and the foam layer does not enter the stitch holes and does not inhibit the glove elasticity. Flexibility and workability are maintained. Furthermore, since the outer solid rubber-like material layer can also be formed by coating by dipping in the mixed rubber latex, it can be formed to be thinner, which is rich in flexibility, improves the feeling of wearing, and has good appearance and soft electric resistance. This has the effect that a surface can be obtained.
【0040】また、本発明によれば、手袋の内側におい
ても耐電性の弾性材を層状に被覆配設することにより、
手袋全体の強度を高められ、外部から手袋内側への貫通
等の危険をより少なくすると共に、十分な耐電層厚さを
確保できることとなり、安全性をより一層向上させられ
るという効果を有する。Further, according to the present invention, the inner layer of the glove is also provided with a layer of an anti-static elastic material, so that
The strength of the entire glove can be increased, the danger such as penetration from the outside to the inside of the glove can be reduced, and a sufficient thickness of the electricity-resistant layer can be secured, so that the safety can be further improved.
【図1】本発明の第1の実施形態に係る耐電性手袋の一
部切欠側面図である。FIG. 1 is a partially cutaway side view of an electric resistant glove according to a first embodiment of the present invention.
【図2】本発明の第2の実施形態に係る耐電性手袋の一
部切欠側面図である。FIG. 2 is a partially cutaway side view of an electric resistant glove according to a second embodiment of the present invention.
1 手袋 2、4 発泡ラテックス凝固層 3 白色ラテックス凝固層 5 赤色ラテックス凝固層 6 木製手型 DESCRIPTION OF SYMBOLS 1 Glove 2, 4 Coagulated layer of foamed latex 3 White coagulated layer of latex 5 Red coagulated layer of latex 6 Wooden hand mold
───────────────────────────────────────────────────── フロントページの続き (72)発明者 三浦 徹 東京都千代田区内幸町1丁目1番3号 東 京電力株式会社内 (72)発明者 愛川 倫明 福岡県筑後市大字蔵数571−25 (72)発明者 太田 幹人 福岡県久留米市梅満町1185 Fターム(参考) 3B033 AA27 AB14 AC02 AC03 AC04 AC05 BA02 BA03 ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Toru Miura Tokyo Electric Power Company, Inc. 1-3-1 Uchisaiwai-cho, Chiyoda-ku, Tokyo (72) Inventor Tomoaki Aikawa 571-25 (72) Inventor Mikito Ota 1185 Umeman-cho, Kurume-shi, Fukuoka F-term (reference) 3B033 AA27 AB14 AC02 AC03 AC04 AC05 BA02 BA03
Claims (6)
弾性材を複数層状に被覆させて形成される耐電性手袋に
おいて、 前記手袋からいずれかの層外面までの被覆厚さが手袋内
側で所定の耐電性を確保可能な限界の厚さとされてなる
と共に、当該厚さをなす層外面より外側に被覆される別
の層の色を前記厚さをなす層外面の外部露出状態におけ
る色と異ならせることを特徴とする耐電性手袋。An anti-static glove formed by coating a plurality of layers of an anti-static elastic material on the outer surface side of a cloth or knitted glove, wherein the coating thickness from the glove to the outer surface of one of the layers is glove. In addition to being the limit thickness capable of securing a predetermined electric resistance inside, the color of another layer which is coated outside the outer surface of the layer having the thickness in the externally exposed state of the outer surface of the layer having the thickness is changed. An electrically resistant glove characterized by different colors.
て、 前記手袋内側で所定の耐電性を確保可能な限界の厚さと
して手袋に直接接触させて被覆形成され、気泡を多量に
含む発泡層と、 当該発泡層の外側に被覆形成され、発泡層と異なる色の
耐電性の弾性材のみからなる固状ゴム状体層とを少なく
とも備えることを特徴とする耐電性手袋。2. The foam according to claim 1, wherein the foam is formed by directly contacting the glove as a limit thickness capable of securing a predetermined electricity resistance inside the glove, and the foam contains a large amount of bubbles. A glove characterized by comprising at least a layer and a solid rubber-like material layer formed of only a grease-resistant elastic material having a color different from that of the foam layer and formed on the outside of the foam layer.
て、 所定厚さで手袋に直接接触させて被覆形成され、気泡を
多量に含む発泡層と、 当該発泡層の外側に発泡層を含めた厚さが前記手袋内側
で所定の耐電性を確保可能な限界の厚さとなる被覆厚さ
で被覆形成され、耐電性の弾性材のみからなる一の固状
ゴム状体層と、 当該一の固状ゴム状体層の外側に被覆形成され、一の固
状ゴム状体層と異なる色の耐電性の弾性材のみからなる
他の固状ゴム状体層とを少なくとも備えることを特徴と
する耐電性手袋。3. The electric-resistant glove according to claim 1, wherein the foamed layer is formed by directly contacting the glove with a predetermined thickness, and includes a foam layer containing a large amount of air bubbles, and a foam layer outside the foam layer. A solid rubber-like layer made of only an elastic material having electric resistance, the thickness of the solid rubber-like body layer being formed with a coating thickness that is a limit thickness capable of securing predetermined electric resistance inside the glove; It is characterized by comprising at least one solid rubber-like layer and another solid rubber-like layer made of only an electrically resistant elastic material of a different color, which is formed on the outer side of the solid rubber-like body layer. Electric resistant gloves.
の耐電性手袋において、 前記手袋の外面に浸透防止処理を施され、前記処理後の
手袋外面に耐電性の弾性材を複数層状に被覆させて形成
されることを特徴とする耐電性手袋。4. The glove according to claim 1, wherein an outer surface of the glove is subjected to a penetration preventing treatment, and the glove after the treatment is formed into a plurality of layers of a glove having an electric resistance. An electrically resistant glove, which is formed by coating.
において、 前記手袋の外面側にゴムラテックスの凝固剤を付着させ
ると共に、 前記発泡層が、発泡したゴムラテックスの凝固膜として
被覆形成され、 前記固状ゴム状体層が、35ないし65重量%の天然ゴ
ムラテックスと65ないし35重量%のイソプレンゴム
ラテックスからなる混合ゴムラテックスの凝固膜として
被覆形成されることを特徴とする耐電性手袋。5. The glove according to claim 2, wherein a coagulant of rubber latex is adhered to an outer surface of the glove, and the foam layer is formed as a coagulated film of foamed rubber latex. Wherein the solid rubber layer is formed as a coagulated film of a mixed rubber latex comprising 35 to 65% by weight of natural rubber latex and 65 to 35% by weight of isoprene rubber latex. gloves.
の耐電性手袋において、 前記手袋の内面側に耐電性の弾性材を一又は複数層状に
被覆させて形成されることを特徴とする耐電性手袋。6. The electric glove according to claim 1, wherein the glove is formed by coating an inner surface of the glove with an elastic material having electric resistance in one or more layers. Electric resistant gloves.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13433099A JP3021450B1 (en) | 1999-05-14 | 1999-05-14 | Gloves |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13433099A JP3021450B1 (en) | 1999-05-14 | 1999-05-14 | Gloves |
Publications (2)
Publication Number | Publication Date |
---|---|
JP3021450B1 JP3021450B1 (en) | 2000-03-15 |
JP2000328329A true JP2000328329A (en) | 2000-11-28 |
Family
ID=15125823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13433099A Expired - Fee Related JP3021450B1 (en) | 1999-05-14 | 1999-05-14 | Gloves |
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JP (1) | JP3021450B1 (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002201515A (en) * | 2000-12-27 | 2002-07-19 | Atom Kk | Working glove and method for producing the same |
JP2002327317A (en) * | 2001-05-01 | 2002-11-15 | Hiroko Ishikawa | Protector having coloring mechanism for precaution |
JP2007100283A (en) * | 2005-10-06 | 2007-04-19 | Techno Tsukihoshi:Kk | Glove and method for producing the same |
WO2011158696A1 (en) | 2010-06-15 | 2011-12-22 | 株式会社東和コーポレーション | Work glove |
JP2013177717A (en) * | 2012-02-02 | 2013-09-09 | Sumitomo Rubber Ind Ltd | Glove and method for producing the same |
JP2014025160A (en) * | 2012-07-26 | 2014-02-06 | Sanko Kagaku Kogyo Kk | Surgical operation rubber glove, and method for manufacturing the same |
CN104287227A (en) * | 2014-10-13 | 2015-01-21 | 翟俊玮 | Pesticide protection glove and protection method |
JP2015120996A (en) * | 2013-12-25 | 2015-07-02 | 株式会社イノアックコーポレーション | Rubber gloves for electricity and producing method thereof |
JP2017008430A (en) * | 2015-06-18 | 2017-01-12 | 株式会社テクノ月星 | Glove |
JP2018044264A (en) * | 2016-09-15 | 2018-03-22 | ヨツギ株式会社 | Insulation glove |
-
1999
- 1999-05-14 JP JP13433099A patent/JP3021450B1/en not_active Expired - Fee Related
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002201515A (en) * | 2000-12-27 | 2002-07-19 | Atom Kk | Working glove and method for producing the same |
JP2002327317A (en) * | 2001-05-01 | 2002-11-15 | Hiroko Ishikawa | Protector having coloring mechanism for precaution |
JP2007100283A (en) * | 2005-10-06 | 2007-04-19 | Techno Tsukihoshi:Kk | Glove and method for producing the same |
WO2011158696A1 (en) | 2010-06-15 | 2011-12-22 | 株式会社東和コーポレーション | Work glove |
JP2013177717A (en) * | 2012-02-02 | 2013-09-09 | Sumitomo Rubber Ind Ltd | Glove and method for producing the same |
JP2014025160A (en) * | 2012-07-26 | 2014-02-06 | Sanko Kagaku Kogyo Kk | Surgical operation rubber glove, and method for manufacturing the same |
JP2015120996A (en) * | 2013-12-25 | 2015-07-02 | 株式会社イノアックコーポレーション | Rubber gloves for electricity and producing method thereof |
CN104287227A (en) * | 2014-10-13 | 2015-01-21 | 翟俊玮 | Pesticide protection glove and protection method |
JP2017008430A (en) * | 2015-06-18 | 2017-01-12 | 株式会社テクノ月星 | Glove |
JP2018044264A (en) * | 2016-09-15 | 2018-03-22 | ヨツギ株式会社 | Insulation glove |
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