JP2000321718A - Silver halide color photographic sensitive material - Google Patents

Abstract

PROBLEM TO BE SOLVED: To enhance UV absorbing characteristics without deteriorating stability in production by forming a protective layer containing a specified compound and having a specified dry film thickness. SOLUTION: The silver halide color photographic sensitive material has at least one protective layer containing a compound of formula I or II and having 1.5-2.0 μm total dry film thickness. In the formula I, R1 and R2 are each a substituent, at least one of R1 and R2 is alkoxy, aryloxy or amido, X1 and X2 are each halogen, (m), (n), (p) and (q) are each an integer of 0-4, m+n<=4, p+q<=4, (m) and (n) are not simultaneously 0, and when (m), (n), (p) or (q) is >=2, plural symbols R1, R2, X1 or X2 may be the same or different. In the formula II, R11 and R12 are each alkyl, aryl, alkoxy or aryloxy and R13 is alkoxy or aryloxy.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a silver halide color photographic light-sensitive material (hereinafter, also simply referred to as "light-sensitive material").
More specifically, the present invention relates to a silver halide color photographic material having improved coating film properties and production stability.

[0002]

2. Description of the Related Art A photosensitive silver halide used in a silver halide photosensitive material is originally sensitive to light such as ultraviolet light having a shorter wavelength than visible light. When used for general photography, it is necessary to spectrally sensitize the visible light region in accordance with human vision and to reduce the influence of light having a shorter wavelength than ultraviolet light which cannot be sensed by humans.

A silver halide color photographic light-sensitive material for photography is photographed in all kinds of light, such as in the natural world or with an artificial light source. The constituent layer contains an ultraviolet absorber. That is, it is added to the non-photosensitive layer farther from the photosensitive layer farthest from the support in the photographic constituent layer.

[0004] Therefore, the blue light which cuts the ultraviolet light,
A silver halide color photographic light-sensitive material is formed by a photographic component layer designed to effectively capture three main wavelengths of green light and red light having a longer wavelength.

On the other hand, in the handling of a silver halide color photographic light-sensitive material, in order to cut off ultraviolet rays generated by electrostatic discharge or the like, the light-sensitive layer is further closer to the photosensitive layer closest to the support of the silver halide color photographic light-sensitive material. An ultraviolet absorber is added in the non-photosensitive layer on the side or the non-photosensitive layer farther from the photosensitive layer farthest from the support. If the ultraviolet absorber for protecting the photographic constituent layer of the silver halide color photographic light-sensitive material does not function sufficiently, an image defect called a so-called static mark occurs, which is not preferable.

[0006] The ultraviolet absorbing compound used in the photosensitive material contains not only the absorption spectrum characteristic relating to the essential function of absorbing ultraviolet light and the physical characteristic such as the extinction coefficient in a necessary wavelength region, but also the photosensitive material. In such a case, photographic characteristics such as sensitivity or chemical characteristics that do not adversely affect photographic processing during production and development are required.

In general, the absorption spectrum needs to be sufficiently wide in order to effectively absorb ultraviolet rays. However, when the spectrum extends to visible light (blue), the sensitivity in this part is reduced, and it becomes sharp. The long wavelength side must be cut off.

For this reason, for example, Japanese Patent Application Laid-Open No. 58-15223
Although a desirable spectrum can be obtained by an ultraviolet absorber as described in No. 7, the problem of devitrification after photographic processing due to a so-called perspiration phenomenon occurs when the photosensitive material is stored, particularly when stored at high temperatures. there were.

On the other hand, by using a polymer ultraviolet absorber as described in JP-B-63-65140, the above-mentioned sweating phenomenon is improved.

However, in order to obtain the same level of UV absorbing effect as the conventional UV absorber in the polymer form, a large amount of UV absorber is required. The strength of the swollen film composed of the hydrophilic colloid layer in the treatment liquid is deteriorated.

Furthermore, even if sweating is improved, another problem is caused one after another, such as sharpness degradation when gelatin is increased to maintain the strength of the swollen film.

A technique disclosed in Japanese Patent Application Laid-Open No. 3-175443 has been disclosed, in which the use of an ultraviolet absorber which is a liquid at ordinary temperature makes it possible to reduce the thickness of a non-photosensitive protective layer, thereby improving sharpness. However, when the ultraviolet absorber is contained in at least one of the non-photosensitive layers farther from the support than the silver halide photosensitive layer farthest from the support, the ultraviolet absorber is a liquid at room temperature. With other UV absorbers combined with, the problem of precipitation over time,
Further, it was found that a problem of coating failure due to precipitation occurred.

[0013]

SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a silver halide color photographic light-sensitive material having excellent ultraviolet absorption characteristics without deteriorating photographic characteristics, coating film properties and production stability. It is in.

[0014]

The object of the present invention has been attained by the following constitutions.

1. A photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer on one side of the support, the photosensitive layer being furthest from the support; A silver halide color photographic light-sensitive material having at least one non-light-sensitive protective layer further away from the layer, wherein the protective layer contains a compound represented by the following general formula (1) or (2); A silver halide color photographic light-sensitive material, characterized in that the total dry film thickness of the protective layer is 1.5 μm to 2.0 μm.

[0016]

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In the formula, R ₁ and R ₂ each represent a substituent. Here, at least one of R ₁ and R ₂ represents an alkoxy group, an aryloxy group or an amide group. X ₁ and X ₂ each represent a halogen atom. m, n, p and q are each 0 to 4
Represents an integer. However, the sum of m and n and the sum of p and q are each an integer of 0 to 4, and both m and n are not 0. When m, n, p or q is 2 or more, a plurality of R ₁ ,
R ₂ , X ₁ or X ₂ may be the same or different.

[0018]

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In the formula, R ₁₁ and R ₁₂ each represent an alkyl group, an aryl group, an alkoxy group or an aryloxy group;
R ₁₃ represents an alkoxy group or an aryloxy group.

2. A photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer on one side on the support, wherein the photosensitive layer closest to the support is A silver halide color photographic material having at least one non-photosensitive undercoat layer on a side closer to the layer, wherein the undercoat layer contains a compound represented by the formula (1) or (2); And a silver halide color photographic light-sensitive material, characterized in that the total dry film thickness of the undercoat layer is from 1.80 μm to 2.0 μm.

3. A silver halide color photographic material having a photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer on one side of a support, At least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and at least one of the photosensitive layers has
70% or more of the total projected area contains a silver halide emulsion having tabular silver halide grains having an aspect ratio of 5 or more having 20 or more dislocation lines per grain, and the dry thickness of the photographic constituting layer Is a total of 12 μm to 20 μm.

4. A silver halide color photographic material having a photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer on one side of a support, At least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and at least one of the photographic constituent layers contains the compound represented by the following general formula (3) A silver halide color photographic light-sensitive material, characterized in that:

[0023]

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Wherein R ₁ and R ₂ are each a hydrogen atom,
Represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group, and R ₁ and R ₂ may form a heterocyclic ring. G is _{-COOR 3, -SO 2 R 3,} -COR 3, -C
_{ONR 3 R 4, -SO 2 NR} 3 R 4, represents a -CN, R _3, R
₄ represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group. n is 1
Or an integer of 2.

[5] A silver halide color photographic material having a photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer on one side of a support, The compound represented by the general formula (1) or (2) is contained in at least one of the photographic constituent layers, and the compound represented by the following general formula (4) or (5) is contained in at least one of the photographic constituent layers. Silver halide color photographic light-sensitive material, characterized by containing a compound to be prepared.

[0026]

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In the formula, R ³ and R ⁴ each represent an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group. X is -CN, -COOR ^5, -CONR ^{5
_{R 6, -SO 2 NR 5 R}} 6, -COR 5, -SO 2 R 5 or -
Represents CF ₃ , and R ⁵ and R ⁶ each represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group. L _{1 to} L ₃ represent a methine group, and n is 0
Or an integer of 2.

[0028]

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In the formula, A represents an acidic nucleus residue, L ₁ , L ₂ and L ₃ represent a methine group, n represents 0, 1 or 2, and Z is a bond to a nitrogen atom shown in the formula. Represents a group of nonmetallic atoms necessary to form a heterocyclic residue, and Y represents a substituent or a heterocyclic residue represented by the general formula (a). In the general formula (a), R ₁ and R ₂ represent an alkyl group, which may be bonded to each other to form a ring. R
₃ represents a hydrogen atom or an electron-withdrawing group having a Hammett's σ _p value of 0.3 or more. However, the compound represented by the general formula (5) has at least one carboxyl group or alkylsulfonamide group in the aromatic ring portion in the molecular structure.

13. A silver halide color photographic material having a photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer on one side of a support, At least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and at least one of the photographic constituent layers contains the compound represented by the following general formula (7) A silver halide color photographic light-sensitive material, characterized in that:

[0031]

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In the formula, R ₃₁ is a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group. R ₂₉ , R ₃₀ and R ₃₁ represent an organic group, at least one of which is an alkyl group.

[7] A silver halide color photographic material having a photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer on one side of a support, At least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and at least one of the photographic constituent layers contains a high-boiling organic solvent dispersion. Silver halide color photographic light-sensitive material.

8. A silver halide color photographic material having a photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer on one side of a support, Halogen characterized in that at least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and at least one of the photographic constituent layers contains a wax dispersion. Silver halide color photographic material.

9. A silver halide color photographic material having a photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer on one side of a support, At least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and the photographic constituent layer is hardened with a hardener represented by the following general formula (8) A silver halide color photographic light-sensitive material, characterized in that:

Formula (8) (CH ₂ ＣＨCHSO ₂ ) _n A In the formula, A represents an n-valent group having at least one hydroxy group or amide group, and n represents 2, 3 or 4.
In Formula (8), A represents an n-valent carbon number of 1 to 1;
A non-cyclic hydrocarbon group (preferably an alkylene group having 1 to 8 carbon atoms), a 5- or 6-membered heterocyclic ring having a nitrogen, oxygen or sulfur atom, a 5- or 6-membered alicyclic group or a C7 to C6 And 10 aralkylene groups. These include an alkoxy group (methoxy group, ethoxy group, etc.),
May be substituted with an alkyl group, a halogen atom, or an acetoxy group, and may be bonded to each other via the hetero atom, carbonyl group, or carbamide group.

10. A silver halide color photographic material having a photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer on one side of a support, The compound represented by the general formula (1) or (2) is contained in at least one of the photographic constituent layers, and the compound is represented by the following general formulas (A) to (A).
(E) A silver halide color photographic light-sensitive material characterized by being dispersed in oil droplets by a high-boiling organic solvent shown in (E).

The general formula _{(A) R a OOC (CH} 2) in _m COOR _b formula, R _a, R _b each represent a linear or branched alkyl group having 4 to 10 carbon atoms. m represents an integer of 2 to 10.

Formula (B) R _c OOC (C _n H _2n-2 ) COOR _{d In the} formula, R _c and R _d each represent a linear or branched alkyl group having 4 to 10 carbon atoms. n represents an integer of 2 to 10.

The general formula _{(C) R e COO (CH} 2) in _p OCOR _f formula, R _e, R _f represents a linear or branched alkyl group having 3 to 24 carbon atoms. p represents an integer of 2 to 10.

Formula (D) C (R _g ) (R _h ) (R _i ) (OH) In the formula, R _g represents an alkyl group or an alkenyl group.
R _h and R _i each represent a hydrogen atom or a group represented by R _g . However, the total number of carbon atoms of the groups represented by R _g , R _h , and R _i is at least 10 or more.

The general formula (E) X - in _{((CH 2) q -O (} CO) R j) r Formula, X represents a saturated hydrocarbon having 5 to 7 membered ring, q is 0
Represents an integer of 2, and r represents an integer of 1 to 3. R _j represents a linear or branched alkyl group having 4 to 16 carbon atoms.

11. A silver halide color photographic material having a photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer on one side of a support, A silver halide color photographic light-sensitive material characterized in that at least one of the photographic constituent layers contains a compound represented by the above general formula (1) or (2) and a compound represented by the following general formula (9). .

[0044]

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In the formula, R ₅ and R ₆ each represent a hydrogen atom, an alkyl group or an acyl group, X represents —CO— or —COO—, m is an integer of 1 to 5, and n is 1
-4. p is an integer of 1 to 4.

Hereinafter, the present invention will be described in more detail.

The ultraviolet absorbent of the present invention represented by the general formula (1) will be described.

In the general formula (1), among the substituents represented by R ₁ and R ₂ , alkyl groups include methyl, ethyl, hexyl, octyl and the like, and aryl groups include phenyl group and the like. Is mentioned. The alkoxy group represented by at least one of R ₁ and R ₂ includes methoxy,
Each group such as butoxy, hexyloxy, octoxy and the like, and the aryloxy group include a phenoxy group and the like.

These groups may be straight-chain, branched or cyclic, and may be further substituted by other substituents, but are preferably branched. Further, a plurality of substituents may be bonded to each other to form a ring.

The amide group is preferably an alkylamide group or an arylamide group, particularly preferably an alkylamide group having 4 or more carbon atoms and having a branched alkyl group.

As the halogen atom represented by X ₁ and X ₂ ,
Examples include atoms such as fluorine, chlorine, and bromine.

[0052]

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UV-1: 2-OCH ₂ CH (C ₂ H ₅ ) C _{4
H 9 UV-2: 2-} OC 8 H 17, 6-Cl UV-3: 1-CH 3, 2-OCH 2 CH (C 2 H 5) C 4
_{H 9, 6-Cl UV-} 4: 1-CH 3, 2-OCH 2 CH (C 2 H 5) C 4
_{H 9, 4,6-Cl UV-} 5: 1-CH 3, 2-OCH 2 CH (C 2 H 5) C 4
_{H 9, 4-Br, 6} -Cl UV-6: 2-OCH 2 CH (C 2 H 5) C 4 H 9, 3-C
l UV-7: 2-OC 18 H 37, 3-Cl UV-8: 1-CH 3, 2-OC 18 H 37 UV-9: 1,3-C 4 H 9 (t), 6-OCH 3 _{UV-10: 1,3-C 5} H 11 (t), 6-OCH 3 UV-11: 1,3-C 4 H 9 (t), 6-OC 2 H 5 UV-12: 1,3- _{C 5 H 11 (t),} 6-OC 2 H 5

[0054]

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[0055]

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Further, in addition to the above compounds, JP-A-3-29
Exemplified compounds I-3 to I-2 described in No. 4846, pp. 3-4.
3 and the like.

The ultraviolet absorber represented by the general formula (1) is
The content is preferably 0.1 to 5 g per 1 m ^{2 of the} photosensitive material.

The compound represented by formula (2) of the present invention will be described.

In the compound represented by the general formula (2),
The alkyl group represented by R ₁₁ and R ₁₂ has 1 to 1 carbon atoms.
Eighteen are preferred, and they may be linear, branched, or cyclic. The alkoxy group preferably has 1 to 18 carbon atoms, and may be linear, branched, or cyclic. The aryl group is preferably a phenyl group, and the aryloxy group is preferably a phenoxy group. These alkyl group, alkoxy group, aryl group and aryloxy group may be substituted by other substituents. R
At least one of ₁₁ and R _12, it is particularly preferred that it include a 2-hydroxyphenyl group.

The alkoxy group represented by R ₁₃ may be linear, branched, or cyclic. The alkoxy group and the aryloxy group represented by R ₁₃ may be substituted with another substituent.

Next, typical compounds represented by the general formula (2) will be described, but the present invention is not limited to these.

[0062]

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[0063]

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[0064]

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[0065]

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[0066]

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[0067]

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[0068]

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[0069]

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[0070]

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The compound represented by the general formula (2) is disclosed in
The compound can be synthesized by the method described in JP-A-117282.

The compound represented by the general formula (2) may be added to any of the photosensitive layer and the non-photosensitive layer, but is preferably added at least to the non-photosensitive layer, more preferably It is added to the non-photosensitive layer opposite to the support adjacent to the farthest photosensitive layer. Although there is no limit to the amount, preferably 0.05~15g / m ^2, more preferably from 0.1-5 g / m ^2.

The compound represented by the general formula (1) or (2) of the present invention is preferably a compound having a maximum absorption wavelength having a molecular extinction coefficient of 17,000 or more at 335 nm to 390 nm, and 400 nm to 390 nm. It is preferable not to have an absorption maximum wavelength at 700 nm.

The molecular absorption coefficient at 335 nm to 390 nm is preferably 19,000 or more,
More preferably, it is not less than 00.

The maximum absorption wavelength having a molecular extinction coefficient of 17,000 or more is preferably 344 nm to 370 nm.

In the invention of claim 1 of the present invention, the protective layer may be a single layer, but preferably has a multilayer structure of two to three layers. The compound represented by the general formula (1) or (2) is preferably added to a layer other than the layer farthest from the support among the plurality of layers.

In the invention of claim 1 of the present invention, the total dry film thickness of the protective layer is 1.5 μm to 2.0 μm, preferably 1.5 μm to 1.9 μm, particularly preferably 1 μm to 1.9 μm. .1.7 μm to 1.8 μm. The dry film thickness of the layer containing the compound represented by the general formula (1) or (2) is preferably 0.8 μm to 1.2 μm.

In the invention of claim 2 of the present invention, the total dry film thickness of the undercoat layer is from 1.0 μm to 2.0 μm,
It is preferably from 1.2 μm to 2.0 μm, and particularly preferably from 1.5 μm to 1.8 μm. The dry film thickness of the layer containing the compound represented by the general formula (1) or (2) is
It is preferably from 0.60 μm to 1.4 μm.

In the invention of claim 3 of the present invention, in at least one of the photosensitive layers, 70% or more of the total projected area is a flat plate having an aspect ratio of 5 or more and having 20 or more dislocation lines per grain. The effect of the present invention is exhibited by containing a silver halide emulsion having silver halide grains.

The tabular grains may have so-called dislocation lines. The dislocation lines referred to here are, for example, J.I. F. Hami
Iton; Photo. Sci. Eng. 11 (196
7) 57 pages, T.A. Shiozawa; Soc. P
photo. Sci. Japan 35 (1972) 213
Refers to what can be observed by a direct method using a transmission electron microscope at low temperature described on page.

At this time, the thicker the tabular grains, the more difficult it is for an electron beam to pass through. Therefore, a clearer observation can be obtained by using a high-pressure electron microscope. From the grain photograph obtained by such a method, the position and number of dislocation lines in each silver halide grain can be determined.

The method for introducing dislocation lines into tabular grains is not particularly limited. For example, a method of adding an aqueous solution of an iodide ion such as potassium iodide and a solution of a water-soluble silver salt by double jet, or adding silver iodide fine grains. A desired position and amount of dislocation lines can be introduced by a known method such as a method, a method of adding only an iodide ion solution, and a method using an iodide ion releasing compound described in JP-A-6-11781.

The tabular grains preferably have dislocation lines. There is no particular limitation on the position where the dislocation line exists, but it is preferable that it exists near the outer peripheral portion, near the ridge line, or near the vertex of the silver halide grain. The introduction time of dislocation lines in the silver halide grains is preferably after 50% of the total silver added during the production of the silver halide grains, and is introduced between 60% and less than 85%. Is more preferred. The number of dislocation lines is preferably 30% or more (number) of silver halide grains having 5 or more dislocation lines, more preferably 50% or more, and further preferably 80% or more. preferable. In each case, the number of dislocation lines in one grain is preferably 10 or more, more preferably 20 or more, and further preferably 30 or more.

When a tabular silver halide emulsion having the above dislocation lines is contained, the total dry film thickness of the photographic constituent layers is 1
2 μm to 20 μm, preferably 13 μm to 20 μm
m, particularly preferably 13 μm to 19 μm. Thereby, the effect of the present invention is exhibited.

In the invention of claim 4 of the present invention, the effect of the present invention is exhibited by including the compound represented by the general formula (3) in at least one of the photographic constituent layers.

In the general formula (3), R ₁ and R ₂ each represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group, and R ₁ and R ₂ form a heterocyclic ring. Is also good. G is -COOR ₃ , -SO
_{2 R 3, -COR 3, -CONR} 3 R 4, -SO 2 NR 3 R 4,
Represents —CN, and R ₃ and R ₄ each represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group. n represents an integer of 1 or 2. In the general formula (3), examples of the alkyl group represented by R _{1 to} R ₄ include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a tert-butyl group, a pentyl group, a synlopentyl group, Hexyl, cyclohexyl, octyl, 2-ethylhexyl, dodecyl and the like. These alkyl groups further include a halogen atom (eg, a chlorine atom, a bromine atom, a fluorine atom, etc.), an alkoxyl group (eg, a methoxy group, an ethoxy group,
1-dimethylethoxy group, hexyloxy group, dodecyloxy group, etc.), aryloxy group (eg, phenoxy group, naphthyloxy group, etc.), aryl group (eg, phenyl group, naphthyl group, etc.), alkoxycarbonyl group (eg, methoxy group) Carbonyl group, ethoxycarbonyl group, butoxycarbonyl group, 2-ethylhexylcarbonyl group, etc.), aryloxycarbonyl group (eg, phenoxycarbonyl group, naphthyloxycarbonyl group, etc.), alkenyl group (eg, vinyl group, allyl group, etc.), Heterocyclic group (eg, 2-pyridyl group, 3-pyridyl group, 4-pyridyl group, morpholyl group, piperidyl group, piperazyl group, pyrimidyl group, pyrazolyl group, furyl group, etc.), alkynyl group (eg, propargyl group, etc.) ), An amino group (eg, an amino group, N N-dimethylamino group, anilino group, etc.), hydroxyl group, cyano group, sulfo group, carboxyl group, sulfonamide group (for example, methylcarbonylamino group, ethylsulfonylamino group, butylsulfonylamino group, octylsulfonylamino group) Phenylsulfonylamino group) and the like.

The alkenyl groups represented by R _{1 to} R ₄ include, for example, vinyl and allyl groups. These groups can be substituted by an alkyl group represented by R _{1 to} R ₄ and a group similar to the group shown as a substituent of the alkyl group.

Examples of the alkynyl group represented by R _{1 to} R ₄ include a propargyl group. These groups can be substituted by an alkyl group represented by R _{1 to} R ₄ and a group similar to the group shown as a substituent of the alkyl group.

The aryl groups represented by R _{1 to} R ₄ include:
Examples include a phenyl group and a naphthyl group. These groups can be substituted by an alkyl group represented by R _{1 to} R ₄ and a group similar to the group shown as a substituent of the alkyl group.

Examples of the heterocyclic group represented by R _{1 to} R ₄ include a pyridyl group (for example, a 2-pyridyl group, a 3-pyridyl group, a 4-pyridyl group, etc.), a thiazolyl group, an oxazolyl group, and an imidazolyl group. , A furyl group, a thienyl group, a pyrrolyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a selenazolyl group, a sulfolanyl group, a piperidinyl group, a pyrazolyl group, a tetrazolyl group, and the like. These groups can be substituted by an alkyl group represented by R _{1 to} R ₄ and a group similar to the group shown as a substituent of the alkyl group.

Examples of the heterocyclic group which can be formed by R ₁ and R ₂ include a piperidino group, a morpholino group, a pyrrolidino group, a hexahydroazepino group, a piperazino group and the like. These groups include an alkyl group represented by R _{1 to} R ₄ ,
And a group similar to the group shown as the substituent of the alkyl group.

Specific examples of the ultraviolet absorbent represented by formula (3) of the present invention are shown below, but the present invention is not limited to these compounds.

[0093]

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[0094]

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In the present invention, the amount of the ultraviolet absorber represented by the general formula (3) is preferably 0.001 to 0.001.
3 g / m ² , more preferably 0.005 to 0.6
g / m ² .

In the invention of claim 5 of the present invention, the effect of the present invention is exhibited by including the compound represented by the general formula (4) or (5) in at least one of the photographic constituent layers. .

In the general formula (4), R ³ and R ⁴ each represent an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group. X is -CN, -COOR
^{5, -CONR 5 R 6, -SO} 2 NR 5 R 6, -COR 5, -
Represents SO ₂ R ⁵ or —CF ₃ , wherein R ⁵ and R ⁶ each represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group. L _{1 to} L ₃ represent a methine group, and n represents an integer of 0, 1 or 2.

Hereinafter, specific examples of the compound represented by formula (4) will be shown, but the present invention is not limited thereto.

[0099]

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[0100]

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[0101]

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The compound represented by the general formula (4) is preferably used in an amount of 1 to 2000 mg, more preferably 50 to 500 mg per m ² .

In the general formula (5), A represents an acidic nucleus residue, L ₁ , L ₂ and L ₃ represent a methine group, n represents 0, 1 or 2, and Z represents Represents a group of nonmetallic atoms necessary for forming a heterocyclic residue by bonding to the nitrogen atom, and Y represents a substituent or a heterocyclic residue represented by the general formula (a). In the general formula (a), R ₁ and R ₂ represent an alkyl group, which may be bonded to each other to form a ring. R ₃ is a hydrogen atom or Hammett
Represents an electron-withdrawing group having a σ _p value of 0.3 or more. However, the compound represented by the general formula (5) has at least one carboxyl group or alkylsulfonamide group in the aromatic ring portion in the molecular structure.

In the general formula (5), examples of the acidic nucleus of the acidic nucleus residue represented by A include 2-pyrazolin-5-one, pyrazolidinedione, barbituric acid, thiobarbituric acid, rhodanine, Examples thereof include hydantoin, thiohydantoin, oxazolone, isoxazolone, indandione, hydroxypyridone, and pyrazolopyridone, and preferably 2-pyrazolin-5-one. These acidic nuclei may have a substituent. Examples of the substituent include an alkyl group (for example, a methyl group, an ethyl group,
Hexyl group, etc.), cycloalkyl group (eg, cyclohexyl group, cyclopentyl group, etc.), aryl group (eg, phenyl group, tolyl group, 4-hydroxyphenyl group, 4-
Carboxyphenyl group, aralkyl group (eg, benzyl group, phenethyl group, etc.), alkoxy group (eg, methoxy group, ethoxy group, tert-butoxy group, etc.), aryloxy group (eg, phenoxy group, 4-methylphenoxy group, etc.) A heterocyclic group (for example, a pyridyl group, a furyl group,
A thienyl group, etc.), a substituted or unsubstituted amino group (eg, dimethylamino group, diethylamino group, anilino group, etc.), an alkylthio group (eg, methylthio group, etc.), an acyl group (eg, acetyl group, pivaloyl group, benzoyl group, etc.), An alkoxycarbonyl group (eg, methoxycarbonyl group, ethoxycarbonyl group, 2-hydroxyethoxycarbonyl group, etc.), a carbamoyl group (eg, carbamoyl group, methylcarbamoyl group, ethylcarbamoyl group, 2-hydroxyethylcarbamoyl group, dimethylcarbamoyl group, Carboxyphenylcarbamoyl group), cyano group and the like. It is well known to those skilled in the art that the position of the acidic nucleus bonded to L _{1 in} the general formula (5) and the compound represented by the general formula (5) has a function as a dye, It can also be confirmed by experiments.

Further, L ₁ , L ₂ and L _{3 in the} general formula (5)
The methine group represented by includes those having a substituent, and examples of the substituent are the same as those described above as the substituent of the acidic nucleus residue A.

In the general formula (5), examples of the heterocyclic ring formed by Z together with a nitrogen atom include pyrrole, pyrazole,
Examples include imidazole, triazole, and tetrazole. The heterocyclic ring may be condensed with a benzene ring,
Examples of such heterocycles include indole, indazole, benzimidazole. The heterocyclic ring includes those having a substituent, and examples of the substituent include a halogen atom in addition to those described above as the substituent for the acidic nucleus residue A.

In the general formula (5), Y represents a substituent or a heterocyclic residue represented by the general formula (a). As the heterocyclic residue, pyrrole, imidazole, pyrazole,
Heterocyclic residues derived from pyridine, pyrimidine, thiophene, quinoline, benzimidazole, indole, benzthiazole, sulfolane, thiacyclohexane-1,1-dioxide, butyrolactone, pyran, morpholine, piperidine and the like. The heterocyclic residue includes those having a substituent, and examples of the substituent include a halogen atom in addition to those described above as the substituent for the acidic nucleus residue A.

In the general formula (a), R ₁ and R ₂ represent an alkyl group, examples of which include a methyl group, an ethyl group, an isopropyl group, a butyl group, a neopentyl group and an octyl group. Group. Also R
₁ and R ₂ may combine with each other to form a ring, and examples thereof include cyclohexane, cyclopentane, cyclohexene, and cyclohexanone. The alkyl group and the ring formed include those having a substituent, and examples of the substituent include a halogen atom in addition to those described above as the substituent for the acidic nucleus residue A.

In the general formula (5), R ₃ is a hydrogen atom or a σ _p value of a substituent constant Hammett (edited by Toshio Fujita,
“Chemical domain special issue No. 122 Structure-activity relationship of drugs”, 9
Pages 6 to 103 (1979), Nankodo and the like. ) Represents a group of 0.3 or more, for example, a cyano group, an alkoxycarbonyl group (eg, a methoxycarbonyl group, an ethoxycarbonyl group, a butoxycarbonyl group, an octyloxycarbonyl group, etc.), an aryloxycarbonyl group (eg, a phenoxycarbonyl group, -Hydroxyphenoxycarbonyl group), carbamoyl group (for example, carbamoyl group, methylcarbamoyl group, ethylcarbamoyl group, butylcarbamoyl group, dimethylcarbamoyl group,
Phenylcarbamoyl group, 4-carboxyphenylcarbamoyl group, etc.), acyl group (eg, methylcarbonyl group, ethylcarbonyl group, butylcarbonyl group, phenylcarbonyl group, 4-ethylsulfonamidophenylcarbonyl group, etc.), alkylsulfonyl group (eg, methyl A sulfonyl group, an ethylsulfonyl group, a butylsulfonyl group, an octylsulfonyl group, an arylsulfonyl group (eg, a phenylsulfonyl group, a 4-chlorosulfonyl group, etc.), and the like. Examples include a fluoromethyl group and a cyano group.

As described above, the compound represented by the general formula (5) has at least one carboxyl group or alkylsulfonylamino group in the aromatic ring portion in the molecule, and an example of the alkylsulfonylamino group is methylsulfonylamino. Examples include an amino group and an ethylsulfonylamino group. A carboxyl group or a methylsulfonylamino group is preferred, and a carboxyl group is particularly preferred.

Specific examples of the compound represented by formula (5) of the present invention are shown below, but the present invention is not limited to these.

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The above compounds are described, for example, in JP-A-52-927.
No. 16, No. 55-120030, No. 55-15535
Nos. 0, 55-155351, 56-12639
No. 63-197943, JP-A-2-1838,
No. 2-1839, World Patent No. 88 / 04,794,
U.S. Pat. Nos. 4,861,700 and 4,950,586
And European Patent No. 489,973.

The dye of the present invention is added to a hydrophilic colloid solution as a solid fine particle dispersion. A method for producing a solid particulate dispersion is disclosed in Japanese Patent Application Laid-Open No. 52-92716.
No. 55-155350, No. 55-155351
No. 63-197943, JP-A-3-182743.
And the methods described in World Patent No. 88 / 04,794. Specifically, it can be prepared using a surfactant and a fine dispersing machine such as a ball mill, a vibration mill, a planetary mill, a sand mill, a roller mill, a jet mill, and a disk impeller mill. Further, after dissolving the dye in a weakly alkaline aqueous solution, a method of precipitating fine solid particles by lowering the pH to weakly acidic, or a weakly alkaline solution of the dye and an acidic aqueous solution, p
A dispersion of a dye can be obtained by a method in which H is adjusted and mixed at the same time to produce fine solid particles. The dyes may be used alone or as a mixture of two or more. When two or more kinds are used as a mixture, they may be dispersed individually and then mixed, or they may be dispersed simultaneously.

The particle diameter of the solid fine particles preferably used in the present invention is represented by a so-called equivalent spherical diameter. As a specific particle size measuring method, it can be measured by a system 4700 manufactured by Malvern Instrument. The smaller the particle size of the dye fine particles, the larger the absorbance per coating amount of the dye. However, if the particle size is too fine, when the fine particles are dispersed in a solution of gelatin or the like, they may cause a problem such as aggregation. When the particle size of the dye fine particles is large, the effective concentration of the layer constituting the photosensitive material to which the fine particle dispersion is added as an optical filter decreases, and the dissolution and outflow speed of the dye from the photosensitive material during the development processing is also low. In addition, it may adversely affect the exposure light shielding effect and the flatness of the photosensitive layer. The dye dispersed in the form of solid fine particles preferably used in the present invention is preferably dispersed such that the average particle diameter is 0.4 μm or less, more preferably 0.01 μm to 0.3 μm, and particularly preferably. 0.
It is 10 μm to 0.25 μm.

In the invention of claim 6 of the present invention, the effect of the present invention is exerted when at least one of the photographic constituent layers contains the compound represented by the general formula (7).

In the general formula (7), R ₃₁ is a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group,
From the viewpoint of light and fading, a hydrogen atom, an alkyl group, and an alkoxy group are more preferable.

In order for the organic groups represented by R ₂₉ , R ₃₀ and R ₃₁ to be liquid at room temperature, at least one is preferably an alkyl group, and more preferably at least two are alkyl groups. It is preferred that

The alkyl group represented by R ₂₉ , R ₃₀ and R ₃₁ may be any alkyl group, but at least one is preferably a tertiary alkyl group or a secondary alkyl group. In particular, it is preferable that at least one of the alkyl groups represented by R ₂₉ and R ₃₀ is a tertiary alkyl group or a secondary alkyl group. Further, the total number of carbon atoms in the alkyl portion of the alkyl group is preferably 12 or more.

Hereinafter, specific examples of the compound represented by formula (7) will be shown.

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In the present invention, the ultraviolet absorbent represented by the general formula (7) can be contained in a photographic component layer as long as the ultraviolet absorbent is in a liquid state at room temperature, or as needed. Using a low-boiling solvent such as ethyl acetate or the like, finely disperse as an oil-in-water dispersion using a surfactant in a hydrophilic binder such as an aqueous gelatin solution using a surfactant, and then adding this dispersion to the target layer. Good.

When these ultraviolet absorbents are in a solid state at room temperature or in a liquid state, they may be used with a high boiling point organic solvent and, if necessary, with a low boiling point solvent. , Finely dispersed as described above,
Can be added in the layer.

In the invention of claim 7 of the present invention, the effects of the present invention are exhibited by including a high-boiling organic solvent dispersion in at least one of the photographic constituent layers.

In the present invention, the high-boiling organic solvent dispersion is obtained by dispersing a high-boiling organic solvent in oil droplets in water.
A high boiling organic solvent widely used in the field of silver halide color photographic light-sensitive materials can be used.

As the high-boiling organic solvent preferred in the present invention, the compounds represented by the above-mentioned general formulas (A) to (E) are preferable in that the effects of the present invention can be further exhibited.

The compound represented by formula (A), (B), (C), (D) or (E) will be described.

In the general formulas (A) and (B), R _a ,
R _b , R _c , and R _d each represent a linear or branched alkyl group having 4 to 10 carbon atoms, and examples of these alkyl groups include a butyl group, an iso-butyl group, and a 2-ethylhexyl group. Octyl group, tert-octyl group, se
c-octyl group, nonyl group, iso-nonyl group, decyl group, iso-decyl group and the like.

In the general formula (A), m is 2 to 10
And more preferably an integer of 4 to 8.

In the general formula (B), n is 2 to 10
And more preferably an integer of 2 to 4.

In the general formula (B), -OO
The _{C (C n H 2n-2} ) dibasic acid residue represented by COO-, for example, malonic acid, fumaric acid, itaconic acid, citraconic acid, mesaconic acid, 2-Pentenin acid, 2-hexenoic diacid , 3-hexenedioic acid and the like.

In the general formula (C), R _e and R _f are
It represents a linear or branched alkyl group having 3 to 24 carbon atoms, and it is more preferable that R _e and R _f have 4 to 10 carbon atoms.

Examples of the linear or branched alkyl group having 3 to 24 carbon atoms represented by R _e and R _f include, for example, propyl, butyl, iso-butyl, pentyl, heptyl, 2- Ethylhexyl group, octyl group, decyl group,
Examples include a nonyl group, an iso-nonyl group, a pentadecyl group, and a tetracosyl group.

In formula (D), examples of the alkyl group represented by R _g include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, an iso-pentyl group,
Examples include a 2-ethyl-hexyl group, an octyl group, and a decyl group.

In formula (D), examples of the alkenyl group represented by R _g include a 2-propenyl group and a 3-alkenyl group.
Butenyl, 1-methyl-3-propenyl, 3-pentenyl, 1-methyl-3-butenyl, 4-hexenyl and the like.

In formula (D), the alkyl group or alkenyl group represented by R _g may further have a substituent.

R _h and R _i each represent a hydrogen atom or a group represented by R _g , but preferably at least one is a hydrogen atom, and more preferably both are hydrogen atoms.

In the general formula (E), 5 to 5 represented by X
Examples of the seven-membered saturated hydrocarbon include cyclopentane, cyclohexane, and cycloheptane.
Cyclohexane is more preferred.

Q is an integer of 0 to 2, preferably 0 to 1, and r is an integer of 1 to 3, preferably 1 to 2.

The linear or branched alkyl group represented by R _j has 4 to 16 carbon atoms, but preferably 4 to 12 carbon atoms. The linear or branched alkyl group represented by R _j, for example, butyl, iso- butyl group, a pentyl group, a hexyl group, a heptyl group, 1-ethylpentyl group, octyl group, nonyl group, iso- nonyl Group, decyl group, iso-decyl group, undecyl group, dodecyl group, hexadecyl group and the like.

The following are typical specific examples of these compounds, but are not limited thereto.

A-1 Dibutyl adipate A-2 Di-iso-butyl adipate A-3 Di- (2-ethylhexyl) adipate A-4 Dioctyl adipate A-5 Acetate (octyl) decyl A-6 Adipine (2-ethylhexyl) decyl acid A-7-iso-dinonyl adipate A-8 di- (2-ethylhexyl) azelate A-9 dinonyl azelate A-10 dibutyl sebacate A-11 di-sebacate di- (2- A-12 Dioctyl sebacate B-1 Dibutyl maleate B-2 Di- (2-ethylhexyl) maleate B-3 Di-iso-nonyl maleate B-4 Dibutyl fumarate B-5 Di-fumarate 2-ethylhexyl) B-6 dibutyl itaconate B-7 di-itaconate Le)

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With respect to the added layer of the compound represented by the general formula (A), (B), (C), (D) or (E), the photographic constituent layer, that is, the photosensitive layer containing photosensitive silver halide Layer, non-photosensitive layer (antihalation layer, filter layer,
It may be added to at least one of an intermediate layer, an ultraviolet absorbing layer, a protective layer, and the like, and is preferably added to a plurality of layers.

The wax dispersion according to the eighth aspect of the present invention is a dispersion in which waxes are dispersed in oil droplets in water.
Those widely used for reducing friction can be used. Among them, paraffins, liquid paraffin, natural carnauba wax, beeswax, etc. have a great effect of the present invention,
preferable.

The wax dispersion is not particularly restricted but includes, for example, silicone oils such as polysiloxanes disclosed in JP-B-53-292 and those disclosed in US Pat. No. 4,275,146. Fine powders of higher fatty acid amides, polyethylene, polytetrafluoroethylene, etc., higher fatty acid metal salts or higher fatty acids as disclosed in US Pat. No. 3,933,516;
JP-B-58-33541, UK Patent No. 927,446
Or JP-A-55-126238 and JP-A-58-90.
No. 633, higher fatty acid esters as disclosed in US Pat.
Examples include aqueous dispersions of higher fatty acid derivatives, fluorocarbons and the like. These can be used alone or as a mixture.

In the tenth aspect of the present invention, the coating weight ratio (O / G) of the oil droplet containing the compound represented by the general formula (1) or (2) to the hydrophilic binder is 0.1.
When it is 2 to 0.6 or less, the effect of the present invention is exhibited.

In the ninth aspect of the present invention, the effects of the present invention are exerted when the photographic constituent layer is hardened with the hardener represented by the general formula (8).

In the general formula (8), A is at least 1
Represents an n-valent group having one hydroxy group or an amide group, and n represents 2, 3 or 4. A in the general formula (8)
As an n-valent acyclic hydrocarbon group having 1 to 10 carbon atoms (preferably an alkylene group having 1 to 8 carbon atoms); a 5- or 6-membered heterocyclic ring having a nitrogen, oxygen or sulfur atom; Or an aralkylene group having 7 to 10 carbon atoms. These may be substituted with an alkoxy group (such as a methoxy group or an ethoxy group), an alkyl group having 1 to 4 carbon atoms, a halogen atom, or an acetoxy group.

Hereinafter, specific examples of the hardener represented by the general formula (8) are shown, but the present invention is not limited to these.

VS-1 CH ₂ ＣＨCHSO ₂ CH ₂ CH (OH) CH ₂ SO ₂ CH =
_{CH 2 VS-2 CH 2 =} CHSO 2 CH 2 C (OH) HC (OH) HCH 2
_{SO 2 CH = CH 2 VS-} 3 CH 2 = CHSO 2 CH 2 C (OH) HCH 2 C (OH) H
_{CH 2 SO 2 CH = CH 2} VS-4 (CH 2 = CHSO 2 CH 2 C (OH) HCH 2) 2 CO VS-5 (CH 2 = CHSO 2 CH 2 C (OH) HCH 2) 3 CCH 3 VS _{-6 (CH 2 = CHSO 2 CH} 2 C (OH) HCH 2) 2 O VS-7 (CH 2 = CHSO 2 CH 2 C (OH) HCH 2) 2 NH

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These hardeners are disclosed in US Pat.
It can be obtained by referring to the method described in 3,481 or the like. Further, it is used in an amount of about 1 to 50 mg, preferably 2 to 40 mg per 1 g of gelatin.

Specific examples of the vinyl sulfone type hardener having an amide group are shown below, but the present invention is not limited thereto.

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In the tenth aspect of the present invention, the compound represented by the general formula (1) or (2) is treated with the high-boiling organic solvent represented by the general formulas (A) to (E) to form the same oil droplet. The effect of the present invention is exhibited by being dispersed.

According to the eleventh aspect of the present invention, the effect of the present invention is obtained by containing the compound represented by the general formula (1) or (2) and the compound represented by the general formula (9). Demonstrate.

In the general formula (9), R ₅ and R ₆ each represent a hydrogen atom, an alkyl group or an acyl group, X represents —CO— or —COO—, m is an integer of 1 to 5, n is an integer of 1 to 4. p is an integer of 1 to 4. Details of the groups represented by R ₅ and R ₆ of the benzophenone-based ultraviolet absorber represented by the general formula (9) are disclosed in
No. 8-30493 (U.S. Pat. No. 3,698,907)
And No. 48-31255.

Examples of the substituent that can be substituted on the group in the general formula (9) include a hydroxyl group, a halogen atom, (for example, a fluorine atom,
A chlorine atom, a bromine atom), an alkyl group having 1 to 12 carbon atoms (eg, methyl, ethyl, butyl, trifluoromethyl, hydroxyoctyl, epoxymethyl), and a carbon atom of 1
To 18 alkoxy groups (e.g., methoxy, ethoxy,
Butoxy, cyclohexyloxy, benzyloxy),
An aryl group having 6 to 18 carbon atoms (eg, phenyl, 4-methylphenyl), an aryloxy group having 6 to 18 carbon atoms (eg, phenoxy, m-methylphenoxy), an alkoxycarbonyl group (eg, ethoxycarbonyl,
-Methoxyethoxycarbonyl), an aryloxycarbonyl group (eg, phenoxycarbonyl, p-methylphenoxycarbonyl), an alkylthio group having 1 to 18 carbon atoms (eg, methylthio, butylthio), a carbamoyl group (eg, methylcarbamoyl, butylcarbamoyl) Is mentioned.

The specific compounds represented by the general formula (9) are shown below, but the invention is not restricted thereto.

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In the present invention, the reference development processing refers to a standard development processing of a color negative film on the market, and specifically, The Annual of the Brit.
ish Journal of Photograph
y, p. 161 to 162 (1994), a development process C- for a color negative film manufactured by Eastman Kodak Company.
Say 41. Also, Konica Corporation's CNK-4 and Fuji Photo Film's CN1 have been developed as color negative films of other manufacturers that can exhibit substantially the same performance.
6, etc. can also be used.

As the silver halide emulsion used for the silver halide photographic light-sensitive material of the present invention, those described in Research Disclosure (referred to as RD) 308119 can be used. The places to be described are shown below.

[Item] [Page of RD308119] Iodine structure Item 993IA-A Manufacturing method 993IA-A and 994E Crystal habit Normal crystal 994E Crystal habit Twin crystal 994E section Epitaxial 994E Halogen composition uniform 993I Item -B Halogen composition Non-uniform 993I-B Item Halogen conversion 994I-C Item Halogen substitution 994I-C Item Metal-containing 990I-D Item Monodispersion 990I-F Solvent addition 999I-F Item Latent image forming surface Surface 990I-G Item Latent image formation position Inner surface Item 995I-G Applicable photosensitive material Negative 995I-H Applicable photosensitive material Positive (including internal fogging particles) Item 995I-H Item Emulsion mixed and used Item 995I-J Item Desalting Item 995II-A In the above, use a silver halide emulsion which has been subjected to physical ripening, chemical ripening and spectral sensitization. . The additives used in such a process are RD17643, 1871
6 and 308119. The places to be described are shown below.

[Items] [Page of RD308119] [RD17643] [RD18716] Chemical sensitizer 996 III-A Section 23 648 Spectral sensitizer 996 IV-AA, B, C, D, H, I, J section 23-24 648-9 Supersensitizer 996 IV-AE, J section 23-24 648-9 Antifogging agent 998 VI 24-25 649 Stabilizer 998 VI 24-25 649 The halogenation of the present invention Known photographic additives used in the silver emulsion layer are also described in the above RD. The relevant sections are described below.

[Items] [Page of RD308119] [RD17643] [RD18716] Anti-turbidity agent 1002 VII-I 25 650 Dye image stabilizer 1001 VII-J 25 Brightener 998 V 24 UV absorber 1003 VIII -C, XIIIC section 25 to 26 Light absorber 1003 VIII 25 to 26 Light scattering agent 1003 VIII Filter dye 1003 VIII 25 to 26 Binder 1003 IX 26 651 Static inhibitor 1006 XIII 27 650 Hardener 1004 X 26 651 Plasticizer 1006 XII 27 650 Lubricant 1006 XII 27 650 Matting agent 1007 XVI Developer 1011 XXB (contained in the light-sensitive material) Various couplers can be used in the silver halide emulsion layer. Has been described. The relevant sections are described below.

[Items] [Page of RD308119] [RD17643] [RD18716] Yellow coupler 1001 VII-D VIIC-G Magenta coupler 1001 VII-D VIIC-G Cyan coupler 1001 VII-D VIIC-G Item Colored coupler 1002 VII-G Section VIIG DIR coupler 1001 VII-F VIIF Section BAR coupler 1002 VII-F Other useful residue releasing coupler 1001 VII-F Alkali-soluble coupler 1001 VII-E The present invention Additives for silver halide color photographic light-sensitive materials can be added by a dispersion method described in RD308119XIV or the like.

The silver halide color photographic light-sensitive material of the present invention may be provided with an auxiliary layer such as a filter layer or an intermediate layer described in the aforementioned RD308119VII-K.

The silver halide color photographic light-sensitive material of the present invention can have various layers and constitutions such as a forward layer, a reverse layer, and a unit constitution described in RD308119VII-K.

The silver halide color photographic light-sensitive material of the present invention is described in RD17643, pp. 28-29, RD18716.
Development can be carried out by a usual method described on page 647 and XIX of RD308119.

[0186]

EXAMPLES The present invention will be described below in detail with reference to examples, but embodiments of the present invention are not limited thereto.

Example 1 A multilayer color photographic light-sensitive material sample 101 was prepared by sequentially forming layers having the following compositions on a triacetyl cellulose film support provided with an undercoat layer from the support side.

[0188] The addition amount is expressed in grams per 1 m ^2.
However, silver halide and colloidal silver were converted to the amount of silver, and sensitizing dyes (indicated by SD) were shown in moles per mole of silver.

First Layer (Antihalation Layer) Black Colloidal Silver 0.16 UV-a 0.30 CM-1 0.123 CC-1 0.044 OIL-1 0.17 Gelatin 1.33 Second Layer (Intermediate) Layer) AS-1 0.160 OIL-1 0.20 Gelatin 0.69 Third layer (low-sensitivity red-sensitive layer) Silver iodobromide a 0.20 Silver iodobromide b 0.29 SD-12 37 × 10 ^-5 SD-2 1.2 × 10 ^-4 SD-3 2.4 × 10 ^-4 SD-4 2.4 × 10 ^-6 C-1 0.20 CC-1 0.038 OIL- 2 0.28 AS-2 0.002 Gelatin 0.73 Fourth layer (medium-speed red-sensitive layer) Silver iodobromide c 0.10 Silver iodobromide d 0.86 SD-1 4.5 × 10 ^{-5 SD-2 2.3 × 10 -4} SD-3 4.5 × 10 -4 C-1 0.52 CC-1 0.06 DI-1 0.047 O L-2 0.46 AS-2 0.004 Gelatin 1.30 Fifth layer (high-sensitivity red-sensitive layer) Silver iodobromide c 0.13 Silver iodobromide d 1.18 SD-1 3.0 × 10 ^-5 SD-2 1.5 × 10 ^-4 SD-3 3.0 × 10 ^-4 C-1 0.138 CC-1 0.036 DI-1 0.024 OIL-2 0.27 AS- 2 0.006 Gelatin 1.28 6th layer (intermediate layer) OIL-1 0.29 AS-1 0.23 Gelatin 1.00 7th layer (low-sensitive green color-sensitive layer) Silver iodobromide a. 19 Silver iodobromide b 0.062 SD-4 3.6 × 10 ^-4 SD-5 3.6 × 10 ^-4 M-1 0.14 CM-1 0.033 OIL-1 0.22 AS-2 0.002 Gelatin 0.61 8th layer (intermediate layer) OIL-1 0.26 AS-1 0.054 Gelatin 0.80 9th layer (medium-sensitive green color sensitivity) Layer) Silver iodobromide e 0.54 iodobromide f 0.54 SD-6 1.6 × 10 -4 SD-7 1.7 × 10 -4 SD-8 1.6 × 10 -4 M- 1 0.40 CM-1 0.024 CM-2 0.029 DI-2 0.024 DI-3 0.005 OIL-1 0.73 AS-2 0.003 Gelatin 1.80 10th layer (high sensitivity Green color sensitive layer) Silver iodobromide f 1.19 SD-6 1.7 × 10 ^-4 SD-7 1.8 × 10 ^-4 SD-8 1.7 × 10 ^-4 M-1 0.075 CM-2 0.026 CM-1 0.022 DI-3 0.003 DI-2 0.003 OIL-1 0.19 OIL-2 0.43 AS-2 0.014 Gelatin 1.23 11th layer ( Yellow filter layer) Yellow colloidal silver 0.05 OIL-1 0.18 AS-1 0.16 Gelatin 1.00 12th layer ( Low-sensitivity blue-sensitive layer) Silver iodobromide b 0.22 Silver iodobromide a 0.08 Silver iodobromide h 0.09 SD-9 6.5 × 10 ^-4 SD-10 2.5 × 10 ^-4 Y-1 0.77 DI-4 0.017 OIL-1 0.31 AS-2 0.002 Gelatin 1.29 13th layer (high-sensitivity blue-sensitive layer) Silver iodobromide h 0.41 Silver iodobromide i 0.61 SD-9 4.4 × 10 ^-4 SD-10 1.5 × 10 ^-4 Y-2 0.23 OIL-1 0.10 AS-2 0.004 Gelatin 1.20 14th layer (first protective layer) Silver iodobromide j 0.30 UV-a 0.055 Fa 0.110 OIL-2 0.30 gelatin 1.59 15th layer (second protective layer) PM- 1 0.15 PM-2 0.04 WAX-1 0.02 D-1 0.001 Gelatin 0.69 The characteristics of the above silver iodobromide are shown below. The particle size side length of the same volume of the cube).

Emulsion No. Average grain size (μm) Average AgI amount (mol%) Diameter / thickness ratio Silver iodobromide a 0.30 2.0 1.0 b 0.40 4.0 1.4 c 0.60 3.5 3.5. 1d 0.74 3.5 5.0 e 0.60 4.0 4.1 f 0.65 6.5 7.2 h 0.65 4.2 1.4 i 1.00 3.5 7.5. 0 j 0.05 2.0 1.0 In addition to the above composition, coating aids SU-1 and SU-
2, SU-3, dispersion aid SU-4, viscosity modifier V-1,
Stabilizers ST-1, ST-2, antifoggant AF-1, A
F-2, inhibitor AF-3, hardeners H-1, H-2 and preservative Ase-1 were added. As for the hardener, H-1 was 1 g of gelatin based on the total gelatin in the photographic constituent layer.
20mg / g, H-2 is 10mg / g of gelatin
And added separately in the second layer and the fifteenth layer.

The structures of the compounds used in the above samples are shown below.

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Samples 102 to 110 were prepared by changing the ultraviolet absorber, the high boiling point organic solvent, and the gelatin among the constitutions of the 14th and 15th layers of Sample 101 as follows.

[0202]

[Table 1]

For each of the samples obtained as described above, the influence of the ultraviolet absorber on the properties of the coating film and the static mark resistance under the forced deterioration conditions were evaluated.

<1> Situation of sweating precipitation Each sample was left in an atmosphere of 70 ° C. and 60% relative humidity for 3 days, returned to room temperature, and subjected to the following standard development processing without exposure, and the coating surface was measured with a loupe. Was observed with transmitted light to investigate the sweat precipitation phenomenon.

；: No abnormalities were observed.

Δ: Slight turbidity is observed.

C: Turbidity was observed, and sweating was precipitated on the surface.

<2> Static Mark Resistance In a dark room, the protective layer side of the sample was rubbed 20 times with a rubber roller in the vicinity of ± 0 in the charging line, and then subjected to the following standard development processing without exposure. The occurrence of static marks on each sample after the development processing was observed and examined with a loupe.

A: No static mark is observed at all.

B: Generation of static marks is slightly observed.

C: A state in which the generation of a static mark is considerably recognized, which causes a problem as a product.

<< Standard development processing >> Processing step Processing time Processing temperature Replenishment amount * Color development 3 minutes and 15 seconds 38 ± 0.3 ° C. 780 cc Bleaching 45 seconds 38 ± 2.0 ° C. 150 cc Settlement 1 minute and 30 seconds 38 ± 2 .0 ℃ 830cc Stabilizing 60 seconds 38 ± 5.0 ℃ 830cc drying 1 min 55 ± 5.0 ℃ - * the replenishing amount is a value per photosensitive material 1 m ^2.

The following color developing solutions, bleaching solutions, fixing solutions, stabilizing solutions and replenishers were used.

Color developer Water 800 cc Potassium carbonate 30 g Sodium bicarbonate 2.5 g Potassium sulfite 3.0 g Sodium bromide 1.3 g Potassium iodide 1.2 mg Hydroxylamine sulfate 2.5 g Sodium chloride 0.6 g 4-amino- 3-methyl-N-ethyl-N- (β-hydroxylethyl) aniline sulfate 4.5 g Diethylenetriaminepentaacetic acid 3.0 g Potassium hydroxide 1.2 g Add water to make 1 liter, and add potassium hydroxide or 20
The pH is adjusted to 10.06 with% sulfuric acid.

Color developing replenisher Water 800 cc Potassium carbonate 35 g Sodium bicarbonate 3 g Potassium sulfite 5 g Sodium bromide 0.4 g Hydroxylamine sulfate 3.1 g 4-Amino-methyl-N-ethyl-N- (β-hydroxylethyl) Aniline sulfate 6.3 g Potassium hydroxide 2 g Diethylenetriaminepentaacetic acid 3.0 g Add water to make 1 liter, and add potassium hydroxide or 20
The pH is adjusted to 10.18 with% sulfuric acid.

Bleaching solution Water 700 cc Ammonium iron (III) 1,3-diaminopropanetetraacetate 125 g Ethylenediaminetetraacetic acid 2 g Sodium nitrate 40 g Ammonium bromide 150 g Glacial acetic acid 40 g Add water to make 1 liter, and use aqueous ammonia or glacial acetic acid. And adjust to pH 4.4.

Bleach replenisher Water 700 cc 1,3-Diaminopropanetetraacetic acid iron (III) ammonium 175 g Ethylenediaminetetraacetic acid 2 g Sodium nitrate 50 g Ammonium bromide 200 g Glacial acetic acid 56 g After adjusting to pH 4.4 using aqueous ammonia or glacial acetic acid Add water to make 1 liter.

Fixing solution Water 800 cc Ammonium thiocyanate 120 g Ammonium thiosulfate 150 g Sodium sulfite 15 g Ethylenediaminetetraacetic acid 2 g After adjusting the pH to 6.2 using aqueous ammonia or glacial acetic acid, add water to make 1 liter.

Fixing replenisher Water 800 cc Ammonium thiocyanate 150 g Ammonium thiosulfate 180 g Sodium sulfite 20 g Ethylenediaminetetraacetic acid 2 g After adjusting the pH to 6.5 using aqueous ammonia or glacial acetic acid, add water to make 1 liter.

Stabilizing Solution and Stabilizing Replenisher Water 900 cc paraoctylphenyl polyoxyethylene ether (n = 10) 2.0 g dimethylolurea 0.5 g hexamethylenetetramine 0.2 g 1,2-benzoisothiazolin-3-one 0.1 g Siloxane (UCC L-77) 0.1 g Ammonia water 0.5 cc Add water to make 1 liter, then add ammonia water or 5
Adjust to pH 8.5 with 0% sulfuric acid.

The results for each sample are shown below.

[0222]

[Table 2]

As is clear from the above results, even under the condition that the protective layer is thinned, the constitution of the present invention has a sufficient function and does not affect the physical properties of the coating film of the photosensitive material. Understand.

Example 2 Among the structures of the first and second layers of the sample 101, an ultraviolet absorber,
Samples 201 to 210 were prepared by changing the high boiling point organic solvent and gelatin as follows.

[0225]

[Table 3]

For each of the samples obtained as described above, the influence of the ultraviolet absorber on the coating film adhesion under the forced deterioration condition and the static mark resistance similar to that of Example 1 were evaluated.

<3> Coating Adhesion In order to evaluate the coating adhesion when wet, each sample was immersed in the color developing solution (38 ° C.) for the standard development treatment for 3 minutes, and then placed on the coating surface. Lattice-like cuts were made at 5 mm intervals with a cutter knife, and rubbed with a finger with a constant force to evaluate the adhesion of the coating film by the residual ratio.

Rank a: 80% or more Rank b: 50 to 80% Rank c: less than 50%.

<4> Evaluation of coating film strength Next, in order to evaluate the coating film strength when wet, the following operation was performed using a scratch strength tester (manufactured by Shinto Kagaku).

Each sample was cut into a rectangle having a width of 3.5 cm and a length of 12 cm, and a color developing solution (38 ° C.) for the standard developing process was used.
After immersion for 3 minutes, the tip diameter 0.5 mm on the coating film surface
The sapphire needle is placed vertically and the load (g) on the needle is continuously changed while moving at a constant speed of 5 mm / sec.
The load at which the failure of the coating reached the support was recorded. 3
The measurements were repeated and the arithmetic mean was determined.

[0231]

[Table 4]

As is clear from the above results, even when the undercoat layer is made thinner, the sample containing the ultraviolet absorbent of the present invention has the effect of the present invention sufficiently, It can be seen that physical properties are not affected.

Example 3 In the sample 101 of Example 1, the first and second layers
The sample 206 of No. 14 was used for the 14th and 15th layers, and the sample 301 of the sample 103 of Example 1 was used for the 3rd to 13th layers, and the gelatin coating amount of each layer was reduced by 30%. Further, in the sample 301, the ultraviolet absorbers of the first and the 14th layers were changed, and the silver halide emulsions f of the ninth and tenth layers were further replaced with E described in Examples of JP-A-11-2877.
The following samples 302 to 306 were produced by replacing the same silver equivalent amount with m-3 (aspect ratio 7.0, with dislocation lines).

[0234]

[Table 5]

For each sample, a scratch strength tester (manufactured by Shinto Kagaku) was used to evaluate the effect of pressure on photographic characteristics.
The following operation was performed using. Each sample was 3.5 cm wide,
It was cut into a rectangle having a length of 12 cm, and a diamond needle having a tip diameter of 0.025 mm was placed vertically on the surface of the coating film under an atmosphere of 23 ° C. and a relative humidity of 55% so that a load of 5 g was applied and 5 mm / sec. It moved at the same speed. After that, a step wedge exposure for sensitometry was applied so as to be perpendicular to the scanning line by the needle, and the above-described reference development processing was performed. The density change of the applied portion of the obtained processed sample at the point of the minimum transmission density of the magenta image (measured with green light) +0.40 was measured by a microdensitometer, and the absolute value of the density difference was measured. Pressure tolerance was evaluated by the value (ΔD). The smaller the numerical value, the smaller the change due to the pressure and the better.

Sample No. Pressure resistance (ΔD) 101 0.09 301 0.16 302 0.13 303 0.06 304 0.12 305 0.04 306 0.05 As is clear from the above results, the photographic constituent layer It can be seen that, even under the condition where is thinned, the sample in which the ultraviolet absorber of the present invention and the tabular silver halide are combined has excellent pressure resistance.

Example 4 <Preparation of Ultraviolet Absorber Dispersion; Dispersion for Sample 101 of Example 1> 236 g of ultraviolet absorber UV-a and Compound F
-A was mixed with 472 g, and 544 ml of ethyl acetate was added.
130 g of il-2 was added and dissolved by heating. (Oil-based liquid) Next, 264 g of gelatin, 2650 ml of ion-exchanged water, and 10 parts of sodium p-dodecylbenzenesulfonate surfactant were added.
539 mL of a weight% aqueous solution was added and dissolved by heating. (Water-based liquid) The oil-based liquid and the water-based liquid are mixed, and the liquid temperature is 50 to 60 ° C.
The mixture was dispersed at 3500 rpm for 40 minutes using a high-speed stirring blade dissolver while removing ethyl acetate in a reduced pressure atmosphere. After the dispersion was completed, an aqueous gelatin solution comprising 380 g of gelatin and 5000 ml of ion-exchanged water was added to obtain an ultraviolet absorbent dispersion.

<Evaluation of Stability of Ultraviolet Absorbent Dispersion> The average particle size and viscosity of the dispersed particles immediately after the dispersion were measured were 0.25 μm and 22 cp (measured with a B-type viscometer). . Thereafter, the mixture was left at 38 ° C. for 50 hours while stirring slowly, and then the average particle diameter and viscosity of the dispersed particles were measured again.

In the dispersion for Sample 101, dispersions 401 to 405 were prepared by changing the ultraviolet absorber and the compound in the same molar amount as follows, and the evaluation was performed in the same manner.

Dispersion No. UV absorber Compound 101 UV-a F-a 401 UV-a F-2 402 UV-20 F-a 403 UV-1 F-2 404 UV-18 F-2 405 UV-20F -2 <6> Evaluation of stability of dispersed particle size LL: coarse particles with a maximum of about 3 μm are observed.

L: Coarse particles having a maximum size of about 1 μm are observed.

M: coarse particles having a maximum size of about 0.5 μm are observed.

<7> Evaluation of stability of dispersion viscosity A: within ± 2 cp B: increase of 3 to 5 cp C: increase of 6 cp or more

[0244]

[Table 6]

As is clear from the above results, the sample of the present invention is excellent in production stability and does not affect the physical properties of the coating film of the photosensitive material.

Example 5 Sample 501 was prepared by changing colloidal silver in the eleventh layer to the following yellow dye and changing the ultraviolet absorber in the fourteenth layer to the following molar amounts in the same manner as in sample 101 of Example 1 as follows. ~ 5
07 was produced.

[0247]

[Table 7]

<Evaluation of Storage Stability> Each sample was left to stand in an atmosphere of 40 ° C. and 70% relative humidity for 3 days for forced deterioration treatment, and then subjected to sensitometric exposure together with the sample not subjected to forced deterioration treatment. The reference development processing was performed. The photographic performance storage stability of the blue photosensitive layer (yellow image forming layer) was examined. The increase in fog and the change in sensitivity are shown as relative values to the sample without the forced deterioration treatment. However, as for the sharpness, a sample which was equivalent to a sample which was not subjected to a forced deterioration treatment was visually evaluated as 、, and a sample which showed deterioration was evaluated as △.

[0249]

[Table 8]

As is clear from the above results, it is understood that the sample of the present invention has excellent photographic characteristics stability during storage of the photographic material.

Example 6 Samples 601 to 605 were prepared by changing the sample 101 of Example 1 in the following manner in the same molar amount as the ultraviolet absorber UV-a in the fourteenth layer.

[0252]

[Table 9]

For each sample, the following dispersion progress was evaluated, and after the dispersion was completed, the stability of the dispersion particle diameter and the sweating out property of the light-sensitive material were evaluated.

<9> Evaluation of Dispersion Progress After the start of dispersion, the relationship between time and average particle size was checked, and the target particle size was 0.25 μm.
The dispersion progression was evaluated by the time required to reach the dispersed particle size. The shorter the time, the better the dispersion progress.

A: reached at 25 minutes after the start of dispersion B: reached at 30 minutes after the start of dispersion C: reached at 40 minutes after the start of dispersion Sample number Dispersion progress Dispersion stability Sweating precipitation 101 BL 601 BM 602 AM 603 AM 604 AM 605 AM As can be seen from the above results, the sample of the present invention in combination with a specific ultraviolet absorber is stable in production. It can be seen that the film has excellent properties and does not affect the physical properties of the coating film of the photosensitive material.

Example 7 In Samples 107 and 108 of Example 1, a dispersion of a high-boiling organic solvent or a dispersion of wax was added to the tenth layer as described below, and the coating amount was 0.22 g / samples 701 to 710 were prepared as a m ^2.

Sample number Sample used Sample UV absorber in 14th layer 10th layer 107-UV-a not added 108-UV-1 not added 701 107 UV-a A-10 702 107 UV-a Liquid paraffin 703 108 UV-1 A-10 704 108 UV-1 Liquid paraffin 705 108 UV-1 Carnauba wax 706 108 UV-1 A-7 707 108 UV-1 B-2 708 108 UV-1 C-2 709 108 UV-1 D-2 710 108 UV-1 E-7 Each sample was evaluated for resistance to pressure.

<10> Evaluation of pressure resistance In the evaluation of pressure resistance in Example 3, except that the evaluation part was changed to the point of minimum transmission density +1.4, the same measurement was performed, and the absolute value of the density difference (ΔD ) Was used to evaluate the pressure resistance.

Sample No. Pressure resistance (ΔD) 107 0.24 108 0.23 701 0.19 702 0.18 703 0.13 704 0.10 705 0.12 706 0.11 707 0.12 708 0.12 709 0.11 710 0.13 As is clear from the above results, even under the condition where the photographic constituent layer is thinned, the use of a specific dispersion significantly improves the pressure resistance of the sample of the present invention. It is understood that it is done.

Example 8 In the samples 103 and 104 of Example 1, the hardening agent H-1 was used.
Was changed as follows in the same molar amount, and samples 801 to 80
No. 6 was produced. However, H-2 was not changed.

Sample No. Sample Used Sample Ultraviolet absorber in 14th layer Hardener 103--H-1 104--H-1 801 103 UV-a VS-3 802 103 UV-a VS-1 803 103 UV -A VSA-3 804 104 UV-1 VS-3 805 104 UV-1 VS-1 806 104 UV-1 VSA-3 For each sample, sweat-depositing property as in Example 1, and also as in Example 2. The coating film strength was evaluated.

Sample No. Coating film strength Sweating precipitation 103 90 × 104 90 ○ 801 88 △ 802 90 △ 803 91 △ 804 91 ○ 805 92 ○ 806 92 ○ As is clear from the above results, the sample of the present invention is a photosensitive material. It can be seen that the film has excellent physical properties.

Example 9 In the ultraviolet absorbent dispersion of the fourteenth layer of Example 1, the high boiling organic solvent was changed as follows, and the dispersion progress and dispersion stability of each dispersion were examined.

Dispersion number UV absorber High boiling point organic solvent Dispersion progress Dispersion viscosity stability 901 UV-a OIL-1 BB 902 UV-a OIL-2 BB 903 UV-a A-7 A B 904 UV -20 OIL-2 BA 905 UV-20 A-7 A A906 UV-20 A-10 AA907 UV-20 B-2 AA 908 UV-20 C-2 AA909 UV-20 D-2 AA 910 UV-20 E-7 AA 911 UV-18 A-7 AA 912 UV-18 A-10 AA 913 UV-1 B-2 AA 914 UV-1 C-2 AA 915 UV- 1 D-2 AA 916 UV-1 E-7 AA As is clear from the above results, it is understood that the sample of the present invention has excellent production stability.

Example 10 Samples 1001 to 1005 were prepared by changing the sample 101 of Example 1 in the following manner in the same molar amount as the ultraviolet absorber UV-a in the fourteenth layer.

[0266]

[Table 10]

For each sample, the following dispersion progress was evaluated. Further, after the dispersion was completed, the stability of the dispersion particle diameter, the stability of the dispersion liquid viscosity, and the sweating out property of the photosensitive material were evaluated.

Sample No. Dispersion progression Stability of dispersed particle size Stability of dispersion viscosity Sweating precipitation 101 BLA △ 1001 BMA △ 1002 AMA 1003 AMA 1004 AMA 1005 AM A ○ As is clear from the above results, it can be understood that the constitution of the present invention has sufficient production stability and does not affect the physical properties of the coating film of the photosensitive material.

[0269]

As demonstrated in the examples, the silver halide color photographic light-sensitive material according to the present invention has an excellent effect on ultraviolet absorption without deteriorating photographic characteristics, coating film properties and production stability.

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁷ Identification symbol FI Theme coat ゛ (Reference) G03C 7/00 510 G03C 7/00 510

Claims (11)

[Claims] 1. A support comprising, on one side on a support, a photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer, respectively. In a silver halide color photographic light-sensitive material having at least one non-photosensitive protective layer on the side farthest from the photosensitive layer furthest from the silver halide, the protective layer is represented by the following general formula (1) or (2). A silver halide color photographic light-sensitive material containing a compound and having a total dry film thickness of the protective layer of 1.5 to 2.0 [mu] m. Embedded image [Wherein, R ₁ and R ₂ each represent a substituent. Where R ₁
And at least one of R ₂ represents an alkoxy group, an aryloxy group or an amide group. X ₁ and X ₂ each represent a halogen atom. m, n, p and q each represent an integer of 0-4. However, the sum of m and n and the sum of p and q are each an integer of 0 to 4, and both m and n are not 0. or,
When m, n, p or q is 2 or more, a plurality of R ₁ , R ₂ , X ₁
Or, X ₂ may be the same or different. [Chemical formula 2] Wherein R ₁₁ and R ₁₂ each represent an alkyl group, an aryl group,
R ₁₃ represents an alkoxy group or an aryloxy group, and R ₁₃ represents an alkoxy group or an aryloxy group. ] 2. A support having, on one side on a support, a photographic component layer having at least two red-sensitive layers, green-sensitive layers, blue-sensitive layers and non-light-sensitive layers, respectively. In a silver halide color photographic light-sensitive material having at least one non-photosensitive undercoat layer on the side closer to the photosensitive layer closest to the above, the undercoat layer is represented by the general formula (1) or (2). A silver halide color photographic light-sensitive material containing a compound and having a total dry film thickness of the undercoat layer of 1.80 μm to 2.0 μm. 3. A silver halide color photograph having a photographic component layer having at least two red-sensitive layers, green-sensitive layers, blue-sensitive layers and non-light-sensitive layers on one side on a support. In a photosensitive material, at least one of the photographic constituent layers contains the compound represented by the formula (1) or (2), and at least one of the photosensitive layers contains 70% of the total projected area. The above contains a silver halide emulsion having tabular silver halide grains having an aspect ratio of 5 or more having 20 or more dislocation lines per grain, and the total of the dry film thicknesses of the photographic constituent layers is 12 μm to 20 μm. A silver halide color photographic light-sensitive material, characterized in that: 4. A silver halide color photograph having a photographic component layer having at least two red-sensitive layers, green-sensitive layers, blue-sensitive layers and non-light-sensitive layers on one side on a support. In the photographic material, at least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and at least one of the photographic constituent layers has the following general formula (3). A silver halide color photographic light-sensitive material comprising the compound represented by the formula: Embedded image [Wherein, R ₁ and R ₂ each represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group, and R ₁ and R ₂ may form a heterocyclic ring. G
-COOR _3, -SO ₂ R ₃ is, -COR _3, -CONR ₃
R ₄ , —SO ₂ NR ₃ R ₄ , and —CN, and R ₃ and R ₄ each represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group. n is 1 or 2
Represents an integer. ] 5. A silver halide color photograph having a photographic component layer having at least two red-sensitive layers, green-sensitive layers, blue-sensitive layers and non-light-sensitive layers on one side on a support. In a photographic material, at least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and at least one of the photographic constituent layers has the following general formula (4) or A silver halide color photographic light-sensitive material comprising the compound represented by (5). Embedded image [Wherein, R ³ and R ⁴ each represent an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group. X is ^{-CN, -COOR 5, -CONR 5 R} 6, -S
O ₂ NR ⁵ R ⁶ , —COR ^5, —SO ₂ R ⁵ or —CF ₃ , wherein R ⁵ and R ⁶ each represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group . L _{1 to} L ₃ represent a methine group, and n represents an integer of 0 or 2. [Chemical formula 5] [In the formula, A represents an acidic nucleus residue, L ₁ , L ₂ and L ₃ represent a methine group, n represents 0, 1 or 2, and Z is bonded to the nitrogen atom shown in the formula. A nonmetallic atom group necessary for forming a heterocyclic residue is represented, and Y represents a substituent or a heterocyclic residue represented by the general formula (a). In the general formula (a), R ₁ and R ₂ represent an alkyl group, which may be bonded to each other to form a ring. R ₃ represents a hydrogen atom or an electron-withdrawing group having a Hammett's σ _p value of 0.3 or more. However, the compound represented by the general formula (5) has at least one carboxyl group or alkylsulfonamide group in the aromatic ring portion in the molecular structure. ] 6. A silver halide color photograph having a photographic component layer having at least two red-sensitive layers, a green-sensitive layer, a blue-sensitive layer and a non-light-sensitive layer on one side on a support. In the photographic material, at least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and at least one of the photographic constituent layers has the following general formula (7). A silver halide color photographic light-sensitive material comprising the compound represented by the formula: Embedded image Wherein R ₃₁ is a hydrogen atom, a halogen atom, an alkyl group,
It is an alkoxy group. R ₂₉ , R ₃₀ and R ₃₁ represent an organic group, at least one of which is an alkyl group. ] 7. A silver halide color photograph having a photographic component layer having at least two red-sensitive layers, green-sensitive layers, blue-sensitive layers and non-light-sensitive layers on one side on a support. In a photographic material, at least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and a high-boiling organic solvent dispersion is contained in at least one of the photographic constituent layers. A silver halide color photographic light-sensitive material characterized by comprising: 8. A silver halide color photograph having a photographic component layer having at least two red-sensitive layers, green-sensitive layers, blue-sensitive layers and non-light-sensitive layers on one side on a support. In a photographic material, at least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and at least one of the photographic constituent layers contains a wax dispersion. A silver halide color photographic light-sensitive material comprising: 9. A silver halide color photograph having a photographic component layer having at least two red-sensitive layers, green-sensitive layers, blue-sensitive layers and non-light-sensitive layers on one side on a support. In a photographic material, at least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and the photographic constituent layer is a hardener represented by the following general formula (8) A silver halide color photographic light-sensitive material characterized by being hardened by: Formula (8) (CH ₂ ＣＨCHSO ₂ ) _n A wherein A represents an n-valent group having at least one hydroxy group or amide group, and n represents 2, 3 or 4. A represents an n-valent acyclic hydrocarbon group having 1 to 10 carbon atoms (preferably an alkylene group having 1 to 8 carbon atoms), a 5- or 6-membered heterocyclic ring having a nitrogen, oxygen or sulfur atom, 5 or 6 Alicyclic group or aralkylene group having 7 to 10 carbon atoms. These may be substituted with an alkoxy group (such as a methoxy group or an ethoxy group), an alkyl group having 1 to 4 carbon atoms, a halogen atom, or an acetoxy group, and are bonded to each other via the hetero atom, carbonyl group, or carbamide group. You may. ] 10. A silver halide color photograph having a photographic component layer having at least two red-sensitive layers, green-sensitive layers, blue-sensitive layers and non-light-sensitive layers on one side on a support. In the photographic material, at least one of the photographic constituent layers contains the compound represented by the general formula (1) or (2), and the compound is represented by the following general formula (A) or (A).
(E) A silver halide color photographic light-sensitive material characterized by being dispersed in oil droplets by a high-boiling organic solvent shown in (E). Formula (A) in _{R a OOC (CH 2) m} COOR b [wherein, R _a, R _b each represent a linear or branched alkyl group having 4 to 10 carbon atoms. m represents an integer of 2 to 10. ] Formula _{(B) R c OOC (C} n H 2n-2) in COOR _d [wherein, R _c, R _d each represent a linear or branched alkyl group having 4 to 10 carbon atoms. n represents an integer of 2 to 10. ] Formula _{(C) R e COO (CH} 2) in _p OCOR _f [wherein, R _e, R _f represents a linear or branched alkyl group having 3 to 24 carbon atoms. p represents an integer of 2 to 10. General formula (D) C (R _g ) (R _h ) (R _i ) (OH) wherein R _g represents an alkyl group or an alkenyl group.
R _h and R _i each represent a hydrogen atom or a group represented by R _g . However, the total number of carbon atoms of the groups represented by R _g , R _h , and R _i is at least 10 or more. General formula (E) X-((CH ₂ ) _q —O (CO) R _j ) _r wherein X represents a 5- to 7-membered saturated hydrocarbon, and q represents 0
Represents an integer of 2 to 2, and r represents an integer of 1 to 3. R _j represents a linear or branched alkyl group having 4 to 16 carbon atoms. ] 11. A silver halide color photograph having a photographic component layer having at least two red-sensitive layers, green-sensitive layers, blue-sensitive layers and non-light-sensitive layers on one side on a support. In a photographic material, at least one of the photographic constituent layers contains a compound represented by the general formula (1) or (2) and a compound represented by the following general formula (9). Silver color photographic light-sensitive material. Embedded image [Wherein, R ₅ and R ₆ each represent a hydrogen atom, an alkyl group or an acyl group, and X represents —CO— or —COO—
And m is an integer of 1 to 5, and n is an integer of 1 to 4. p is an integer of 1 to 4. ]