JP2000318319A5 - - Google Patents
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- JP2000318319A5 JP2000318319A5 JP1999301060A JP30106099A JP2000318319A5 JP 2000318319 A5 JP2000318319 A5 JP 2000318319A5 JP 1999301060 A JP1999301060 A JP 1999301060A JP 30106099 A JP30106099 A JP 30106099A JP 2000318319 A5 JP2000318319 A5 JP 2000318319A5
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- Prior art keywords
- recording material
- information recording
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- 239000010410 layer Substances 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 38
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 125000002091 cationic group Chemical group 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive Effects 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000008119 colloidal silica Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 229920000126 Latex Polymers 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L Magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 claims description 2
- MHCAFGMQMCSRGH-UHFFFAOYSA-N aluminum;hydrate Chemical compound O.[Al] MHCAFGMQMCSRGH-UHFFFAOYSA-N 0.000 claims description 2
- 239000011436 cob Substances 0.000 claims description 2
- -1 isocyanate compound Chemical class 0.000 claims description 2
- 239000004816 latex Substances 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- 239000011776 magnesium carbonate Substances 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 239000011241 protective layer Substances 0.000 claims description 2
- 229910002029 synthetic silica gel Inorganic materials 0.000 claims description 2
- 229920003169 water-soluble polymer Polymers 0.000 claims description 2
- 239000000376 reactant Substances 0.000 claims 4
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000000976 ink Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 239000004840 adhesive resin Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000003287 optical Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000000980 acid dye Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000989 food dye Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative Effects 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Description
【００１０】
２．上記の発明１において、共反応体がイソシアナート化合物である情報記録材料である。0010
2. In the above invention 1 , the information recording material in which the copolymer is an isocyanate compound.
【００１１】
３．上記の発明１、２のいずれかにおいて、該インクジェット適性を有する面が、５％イソプロピルアルコール水溶液で測定した３０秒コッブ吸水度が、７ｇ／ｍ2以上４２ｇ／ｍ2以下であることを特徴とする情報記録材料である。0011
3. 3. In any of the above inventions 1 and 2, the surface having inkjet suitability is characterized in that the 30-second Cobb water absorption measured with a 5% isopropyl alcohol aqueous solution is 7 g / m 2 or more and 42 g / m 2 or less. It is an information recording material to be used.
【００１２】
４．上記の発明１〜３のいずれかにおいて、該インクジェット適性を有する面が、カチオン性樹脂を含有することを特徴とする情報記録材料である。0012
4. In any of the above inventions 1 to 3, the surface having inkjet suitability is an information recording material characterized by containing a cationic resin.
【００１３】
５．上記の発明１、２のいずれかにおいて、支持体の他方の面に、インクジェット適性を有するインク受理層を設けたことを特徴とする情報記録材料である。0013
5. In any of the above inventions 1 and 2 , the information recording material is characterized in that an ink receiving layer having inkjet suitability is provided on the other surface of the support.
【００１４】
６．上記の発明５において、該インク受理層が、顔料と接着剤を含有する層であることを特徴とする情報記録材料である。0014.
6. The information recording material according to the above invention 5 , wherein the ink receiving layer is a layer containing a pigment and an adhesive.
【００１５】
７．上記の発明６において、該顔料が多孔性合成非晶質シリカ、コロイダルシリカ、多孔性炭酸マグネシウム、多孔性アルミニウム水和物から選ばれた少なくとも１種である情報記録材料である。0015.
7. In the above invention 6 , the information recording material in which the pigment is at least one selected from porous synthetic amorphous silica, colloidal silica, porous magnesium carbonate, and porous aluminum hydrate.
【００１６】
８．上記の発明５〜７のいずれかにおいて、該インク受理層が、カチオン性樹脂を含有することを特徴とする情報記録材料である。0016.
8. The information recording material according to any one of the above inventions 5 to 7 , wherein the ink receiving layer contains a cationic resin.
【００１７】
９．上記の発明１，２或いは５において、支持体と感熱記録層との間に一層以上の中間層を設けたことを特徴とする情報記録材料である。[0017]
9. In the above inventions 1, 2 or 5 , the information recording material is characterized in that one or more intermediate layers are provided between the support and the heat-sensitive recording layer.
【００１８】
１０．上記の発明９において、該中間層の少なくとも一層が溶剤不透過層であることを特徴とする情報記録材料である。0018
10. In the above invention 9 , at least one layer of the intermediate layer is a solvent-impermeable layer, which is an information recording material.
【００１９】
１１．上記の発明１０において、該溶剤不透過層が水溶性高分子またはラテックス類のいずれか１種を含有することを特徴とする情報記録材料である。0019
11. In the above invention 10 , the information recording material is characterized in that the solvent impermeable layer contains any one of a water-soluble polymer and latex.
【００２０】
１２．上記の発明５において、該インク受理層を設けた支持体と感熱記録層を設けた支持体を貼り合わせることで一体化してなることを特徴とする情報記録材料である。0020
12. In the invention 5 above, an information recording material characterized by being integrated by bonding a support provided with support and the heat-sensitive recording layer provided with the ink-receiving layer.
【００２１】
１３．上記の発明１，５，９或いは１２において、該感熱記録層の上に、保護層を設けたことを特徴とする情報記録材料である。0021.
13. In the above invention 1, 5 and 9 or 12, on the said heat-sensitive recording layer, an information recording material, characterized in that a protective layer.
【００２２】
１４．上記の発明１，５，９，１２或いは１３において、該記録材料の不透明度が８０％以上であることを特徴とする情報記録材料である。0022.
14. In the above inventions 1 , 5, 9, 12 or 13, the information recording material is characterized in that the opacity of the recording material is 80% or more.
【００９３】
接着樹脂の塗布形状も有機溶剤系、水溶液系、エマルジョン系、無溶剤系、反応硬化系、あるいはホットメルトタイプであってもさしつかえない。接着樹脂の硬化方法は自然硬化、酸化硬化、加熱硬化、付加重合、縮合重合、加熱乾燥、２液硬化、あるいは放射線硬化であってもさしつかえないが、感熱記録層あるいはインク受理層を劣化させるものであってはならない。[093]
The coating shape of the adhesive resin may be an organic solvent type, an aqueous solution type, an emulsion type, a solventless type, a reaction curing type, or a hot melt type. The method of curing the adhesive resin may be natural curing, oxidative curing, heat curing, addition polymerization, condensation polymerization, heat drying, two-component curing, or radiation curing, but it deteriorates the heat-sensitive recording layer or the ink receiving layer. Must not be.
【００９７】
水性インクは、着色剤、液媒体、その他の添加剤からなる記録液体が挙げられる。着色剤としては、直接染料、酸性染料、塩基性染料、反応性染料或いは食品用色素等の水溶性染料の他、有色顔料も用いることができる。[097]
Water-based inks include recording liquids consisting of colorants, liquid media, and other additives. As the colorant, in addition to water-soluble dyes such as direct dyes, acid dyes, basic dyes, reactive dyes and food dyes, colored pigments can also be used.
【０１０６】
実施例５
実施例４で作製された本発明の情報記録材料において、実施例４で用いたインク受理層の代わりに下記のインク受理層を設けること以外は、実施例４と同様にして、実施例５の情報記録材料を製造した。
すなわち、インク受理層組成物として、超微粒子無機顔料としてコロイダルシリカ１００部、接着剤としてポリビニルアルコール１０部を調液し、固形分濃度３０％とした。調製したインク受理層塗液を用いて、エアーナイフコータにより塗工量７ｇ／ｍ 2 となるように塗工、乾燥すること以外は、実施例４と同様にして、実施例５の情報記録材料を製造した。[0106]
Example 5
In the information recording material of the present invention produced in Example 4, the same as in Example 4 except that the following ink receiving layer is provided in place of the ink receiving layer used in Example 4, Manufactured information recording material.
That is, as the ink receiving layer composition, 100 parts of colloidal silica as an ultrafine particle inorganic pigment and 10 parts of polyvinyl alcohol as an adhesive were prepared to obtain a solid content concentration of 30%. The information recording material of Example 5 in the same manner as in Example 4 except that the prepared ink receiving layer coating liquid is applied and dried with an air knife coater so as to have a coating amount of 7 g / m 2. Manufactured.
【０１１２】
実施例１１
実施例７で作製された本発明の情報記録材料において、支持体の作製において、紙支持体の坪量を４３ｇ／ｍ2とし、感熱記録層と支持体の間に、下記の中間層を設けること以外は、実施例７と同様にして、実施例１１の情報記録材料を製造した。
すなわち、中間層組成物として、１０％ポリビニルアルコール１００部、２０％シリカ（水澤化学製、ミズカシルＰ５２７）５０部を、エアーナイフコータにより塗工量３ｇ／ｍ2となるように塗工、乾燥すること以外は、実施例７と同様になお、情報記録材料の不透明度は８０％であった。[0112]
Example 11
In the information recording material of the present invention produced in Example 7, in the production of the support, the basis weight of the paper support is set to 43 g / m 2, and the following intermediate layer is provided between the heat-sensitive recording layer and the support. Except for this, the information recording material of Example 11 was produced in the same manner as in Example 7.
That is, as an intermediate layer composition, 100 parts of 10% polyvinyl alcohol and 50 parts of 20% silica ( Mizukasil P527 manufactured by Mizusawa Industrial Chemicals Co., Ltd.) are coated and dried with an air knife coater so that the coating amount is 3 g / m 2. Except for this, the opacity of the information recording material was still 80% as in Example 7.
【０１２０】
＜感熱記録適性評価＞
（１）感熱記録画像濃度
実施例１〜１５および比較例１〜３で作製した情報記録材料の感熱記録層が設けられている方の面に、抵抗値１６４５Ωのサーマルヘッドを装着した大倉電気製感熱ファクシミリ印字試験装置を用いてドット密度８ドット／ｍｍ、印加電圧２１Ｖ、パルス幅１．２ｍｓの条件で印字したところ、いずれの実施例、比較例からも発色画像を得た。画像の光学濃度をマクベスＲＤ９１８（ビジュアルフィルター）にて測定したところ、いずれも１．２以上の光学濃度を示し、実施例、比較例ともに感熱記録が可能であった。[0120]
<Evaluation of thermal recording aptitude>
(1) Thermally Recorded Image Concentration Okura Electric Co., Ltd. equipped with a thermal head having a resistance value of 1645Ω on the side where the thermal recording layer of the information recording material produced in Examples 1 to 15 and Comparative Examples 1 to 3 is provided. When printing was performed using a thermal facsimile printing test apparatus under the conditions of a dot density of 8 dots / mm, an applied voltage of 21 V, and a pulse width of 1.2 ms, color-developed images were obtained from all the examples and comparative examples. When the optical density of the image was measured with Macbeth RD918 (visual filter), all showed an optical density of 1.2 or more, and heat-sensitive recording was possible in both Examples and Comparative Examples.
【０１２５】
（４）画像濃度
実施例１〜１０および比較例１〜２で作製した情報記録材料の感熱記録層を設けていない面に、インクジェットプリンタ（ＢＪＣ−４２０Ｊ：キヤノン株式会社製）を用いて、ブラック、シアン、マゼンタ、イエローのベタ印刷部をそれぞれに印刷する。このとき、各色のベタ印刷部を、反射濃度計（マクベスＲＤ９１８、マクベス社製）を用いて測定した。その結果を表１にまとめた。評価は５段階であり、３点以上であれば実用レベルである。[0125]
(4) Image Density Black using an inkjet printer (BJC-420J: manufactured by Canon Inc.) on the surface of the information recording material produced in Examples 1 to 10 and Comparative Examples 1 and 2 on which the heat-sensitive recording layer is not provided. , Cyan, magenta, and yellow solid prints are printed on each. At this time, the solid printing portion of each color was measured using a reflection densitometer (Macbeth RD918, manufactured by Macbeth Co., Ltd.). The results are summarized in Table 1. The evaluation is on a 5-point scale, and a score of 3 or higher is a practical level.
【０１２７】
（５）耐水性
実施例１〜１０および比較例１〜２で作製した情報記録材料の感熱記録層を設けていない面に、インクジェットプリンタ（ＢＪＣ−４２０Ｊ：キヤノン株式会社製）を用いて、ブラック、シアン、マゼンタ、イエローのベタ印刷部をそれぞれに印刷する。このとき、各色のベタ印刷部を、流水中に１０分間浸し、残存率（残存率＝処理後の反射濃度／原画像の反射濃度）を測定した。その結果を表１にまとめた。評価は５段階であり、３点以上は実用レベルである。[0127]
(5) Water resistance Black using an inkjet printer (BJC-420J: manufactured by Canon Inc.) on the surface of the information recording material produced in Examples 1 to 10 and Comparative Examples 1 and 2 on which the heat-sensitive recording layer is not provided. , Cyan, magenta, and yellow solid printing parts are printed on each. At this time, the solid printing portion of each color was immersed in running water for 10 minutes, and the residual rate (residual rate = reflection density after processing / reflection density of the original image) was measured. The results are summarized in Table 1. The evaluation is on a 5-point scale, with a score of 3 or higher being a practical level.
Claims (14)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11301060A JP2000318319A (en) | 1998-12-02 | 1999-10-22 | Information recording material |
| DE1999158095 DE19958095A1 (en) | 1998-12-02 | 1999-12-02 | Data recording medium, useful e.g. for tickets, ballot papers and securities, has thermographic coat on one side of base and accepts ink-jet printing on other side |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10-343112 | 1998-12-02 | ||
| JP34311298 | 1998-12-02 | ||
| JP11301060A JP2000318319A (en) | 1998-12-02 | 1999-10-22 | Information recording material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000318319A JP2000318319A (en) | 2000-11-21 |
| JP2000318319A5 true JP2000318319A5 (en) | 2004-09-24 |
Family
ID=26562547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11301060A Pending JP2000318319A (en) | 1998-12-02 | 1999-10-22 | Information recording material |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP2000318319A (en) |
| DE (1) | DE19958095A1 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4496654B2 (en) * | 2001-02-08 | 2010-07-07 | コニカミノルタホールディングス株式会社 | Inkjet recording material and image recording method |
| EP1543984B1 (en) * | 2003-12-18 | 2009-02-25 | Mitsubishi Hitec Paper Flensburg GmbH | Heat-sensitive recording material for double-sided printing |
| JP4584663B2 (en) * | 2004-09-29 | 2010-11-24 | 日本製紙株式会社 | Thermal recording material |
| JP4530006B2 (en) * | 2007-07-31 | 2010-08-25 | 王子製紙株式会社 | Double-sided recording medium and method for manufacturing double-sided recording medium |
| JP2010094988A (en) * | 2008-09-17 | 2010-04-30 | Ricoh Co Ltd | Thermosensitive recording medium |
| WO2010056342A2 (en) * | 2008-11-14 | 2010-05-20 | Kanzaki Specialty Papers, Inc. | A multi-layer sheet material |
| JP2011245786A (en) * | 2010-05-28 | 2011-12-08 | Nakagawa Seisakusho:Kk | Confidential document paper and method for producing confidential document using the paper |
| DE102011114129A1 (en) * | 2011-09-23 | 2013-03-28 | Mitsubishi Hitec Paper Europe Gmbh | Recording material for offset printing |
| JP7327882B2 (en) * | 2018-03-23 | 2023-08-16 | 大阪シーリング印刷株式会社 | Thermal recording medium |
| DE102018113022A1 (en) * | 2018-05-30 | 2019-12-05 | Mitsubishi Hitec Paper Europe Gmbh | Heat-sensitive recording material with glossy and printable back and method for producing a heat-sensitive recording material |
-
1999
- 1999-10-22 JP JP11301060A patent/JP2000318319A/en active Pending
- 1999-12-02 DE DE1999158095 patent/DE19958095A1/en not_active Ceased
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