JP2000308864A - Solid material obtained using carbonized scrap wood - Google Patents

Solid material obtained using carbonized scrap wood

Info

Publication number
JP2000308864A
JP2000308864A JP11780599A JP11780599A JP2000308864A JP 2000308864 A JP2000308864 A JP 2000308864A JP 11780599 A JP11780599 A JP 11780599A JP 11780599 A JP11780599 A JP 11780599A JP 2000308864 A JP2000308864 A JP 2000308864A
Authority
JP
Japan
Prior art keywords
waste
solid material
water
waste material
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11780599A
Other languages
Japanese (ja)
Inventor
Naoyoshi Kayama
直義 嘉山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP11780599A priority Critical patent/JP2000308864A/en
Publication of JP2000308864A publication Critical patent/JP2000308864A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/58Construction or demolition [C&D] waste
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/78Recycling of wood or furniture waste

Landscapes

  • Biological Treatment Of Waste Water (AREA)
  • Processing Of Solid Wastes (AREA)
  • Drying Of Gases (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)
  • Road Paving Structures (AREA)
  • Treating Waste Gases (AREA)

Abstract

PROBLEM TO BE SOLVED: To reuse waste materials such as used paper, wooden chips and glass bottles to be disposed as the waste. SOLUTION: Pulverized glass waste materials being noninflammable ones are kneaded with carbonized scrap obtained by incinerating inflammable waste and subjected to the heat treatment at high temperature to form porous powdery solids. As an alternative method, cement powder is mixed with the carbonized scrap and subjected to the steam treatment at a low temperature in a zero- slumped state to form water-permeable solids.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は、土木建築或いは
日用品として使用される材料の素材として使用される固
形物材料であって、特に産業廃棄物からなる炭化物を混
入した固形物材料に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a solid material used as a material of a material used for civil engineering construction or daily necessities, and more particularly to a solid material mixed with carbides made of industrial waste. .

【0002】[0002]

【従来の技術】現在では、家庭廃棄物又は産業廃棄物を
問わず、自治体はその処理に苦慮しており、重金属や陶
磁器片等の不燃物と、その分別収集を含む完全無公害処
理の困難性からゴミ資源は増える一方であり、我が国の
埋立て処分地は、後数年の余裕しかないと言われてい
る。
2. Description of the Related Art At present, municipalities are struggling to dispose of domestic and industrial wastes, and it is difficult to completely treat non-combustible materials such as heavy metals and ceramic pieces, including their separate collection. It is said that garbage resources are increasing due to their nature, and landfill sites in Japan can only afford a few years.

【0003】そこで、有害物質を流出しない特殊な溶液
とセメントで焼却灰を固化し、資源の再利用を図るため
「焼却灰等無害化固化法」が開発されている。この方法
は、焼却灰とガラスや陶器類を含む陶磁器を砂状に粉砕
し、前記特殊溶液とセメントで固化して各種のコンクリ
−ト製品を製造するものであるが、このようなリサイク
ル製品を完成するには、焼却灰と灰の中に含まれる不燃
物を取り除いたり、不燃物の中から陶磁器類や金属類の
選別作業が必要であり、出願人は、前記に関する選別作
業用装置の開発を完了し、既に特許出願を行っている。
また、古紙に関しても多量の廃棄物が有効利用されない
まま焼却廃棄されているのが現状である。
[0003] Therefore, a "solidification method for detoxifying incinerated ash etc." has been developed to solidify incinerated ash with a special solution and cement that do not allow harmful substances to flow out and to reuse resources. In this method, incinerated ash and ceramics including glass and ceramics are pulverized into sand and solidified with the special solution and cement to produce various concrete products. In order to complete it, it is necessary to remove incombustible substances contained in incinerated ash and ash, or to sort out ceramics and metals from incombustible substances, and the applicant has developed a device for sorting work related to the above. Has been completed and a patent application has already been filed.
At present, waste paper is incinerated and discarded without a large amount of waste being effectively used.

【0004】[0004]

【発明が解決しようとする課題】この発明は廃棄物とし
て処分されている古紙や木片、ガラスびん等の廃材を再
利用して有効な固形物材料を提供するものであって、可
燃廃棄物を焼却処分して生成された廃材炭化物とガラス
びん等の不燃物廃材を有効に利用して土木建築用素材を
得ることができる。
SUMMARY OF THE INVENTION The present invention provides an effective solid material by reusing waste materials such as waste paper, wood chips, glass bottles and the like disposed of as waste. The material for civil engineering and construction can be obtained by effectively utilizing the waste material carbonized by incineration and the incombustible waste material such as glass bottles.

【0005】[0005]

【課題を解決するための手段】この発明は、可燃廃棄物
を焼却処理して生成された廃材炭化物に不燃物廃材であ
るガラス製廃材を粉末にしたものを混練し高温加熱処理
して多孔性粒状固形物を形成し、或いは廃材炭化物にセ
メント粉を混入しゼロスランプ状態で低温水蒸気処理を
行い多孔性の透水性固形物を形成し、これらの固形物材
料を素材のまま使用し、或いはこれらを加工し、利用し
て土木建築用のシ−ト材又はブロック材を得るものであ
る。
SUMMARY OF THE INVENTION The present invention relates to a porous material which is obtained by kneading powdery glass ingot, which is incombustible waste, into carbonized waste material produced by incineration of combustible waste and heating the mixture to a high temperature. Form a granular solid, or mix cement powder into waste carbonized material, perform low-temperature steam treatment in a zero slump state to form a porous water-permeable solid, and use these solid materials as raw materials, or Is used to obtain a sheet material or a block material for civil engineering and construction.

【0006】[0006]

【発明の実施の形態】以下、この発明の実施の形態を実
施例に基づき図面を参照して説明すると、図1は、この
発明の第1の実施例の多孔性粒状固形物の部分断面外観
図で、表面は無数の細孔を有する比較的滑らかな表面部
分を有する多孔性粒状固形物を構成している。1は表面
部分、2は断面部分を示している。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the present invention will be described below with reference to the drawings based on embodiments. FIG. 1 is a partial cross-sectional view of a porous granular solid according to a first embodiment of the present invention. In the figure, the surface constitutes a porous granular solid having a relatively smooth surface portion with numerous pores. 1 indicates a surface portion, and 2 indicates a cross-sectional portion.

【0007】簡単に製造方法を述べると、廃材炭化物は
屑炭や木片や可燃物の屑ゴミ、貝殻やビ−ル粕、或いは
街路樹の切り落とした枝や落ち葉や芝等の清掃廃材を利
用し、廃材ガラス粉末は、廃棄処分されたガラスびんや
他のガラス製品の破片を粉砕して利用する。
[0007] Briefly, the manufacturing method is as follows. Carbonized waste materials are made of waste charcoal, wood chips and flammable waste, shells and bee meal, or cleaning waste materials such as cut off branches, fallen leaves and turf of street trees. Waste glass powder is used to crush pieces of glass bottles and other glass products that have been disposed of.

【0008】先ず、廃材炭化物を粉砕し粉末状にしたも
のと廃材ガラス粉末を混練し、これを約800℃前後の
高温で加熱処理するとガラスが溶融し、発泡現象による
微細な気孔が無数に形成された独立気泡性の粒状固形物
を形成する。したがって、溶融ガラスに炭化物が混入し
た独立気泡を有するる多孔性粒状固形物が形成されるの
である。この多孔性粒状固形物の大きさは、直径0.0
1ミリ〜3ミリ程度が好ましい。
[0008] First, the waste carbonized material is pulverized into powder and the waste glass powder is kneaded, and the mixture is heated at a high temperature of about 800 ° C, whereby the glass is melted and numerous pores are formed due to a foaming phenomenon. To form a closed, cellular, solid material. Therefore, a porous granular solid having closed cells in which carbide is mixed in the molten glass is formed. The size of this porous granular solid has a diameter of 0.0
About 1 to 3 mm is preferable.

【0009】なお、形成された粒状固形物の大きさや形
状、炭素粉とガラス粉末との混合比については、粒状固
形物の使用目的や強度の点を考慮して、必要に応じて調
整することができる。
The size and shape of the formed granular solid and the mixing ratio between the carbon powder and the glass powder are adjusted as necessary in consideration of the purpose of use and strength of the granular solid. Can be.

【0010】この多孔性粒状固形物は、活性炭と同様な
吸着作用に優れているので、活性炭と同様な使用手段を
有する。また、この粒状固形物は独立気泡性のため、軽
くて表面が滑らかであるから、扱い勝手がよく、安眠枕
の詰め物やクッションの詰め物、または保温材として使
用してもよく、ペットの床砂として用いた場合には、使
用後は粉砕して花壇の肥料として再利用することもでき
る。
[0010] Since the porous granular solid has the same adsorptive action as activated carbon, it has the same means of use as activated carbon. In addition, since this granular solid is closed-celled, it is light and has a smooth surface, so it is easy to handle and may be used as a pillow for sleeping pillows, a pad for cushions, or a heat insulator, and pet floor sand. When used, it can be crushed after use and reused as fertilizer for flower beds.

【0011】図2はこの発明の第2の実施例の外観斜視
図で、廃材炭化物とセメント粉末だけを使用した透水性
固形物を示している。これは廃材炭化物の粉砕粉末又は
粒状物とセメント粉末を混合し、型に入れて固定し、ゼ
ロスランプ状態で、つまり加水しない状態で、低温蒸気
処理(100°以下が好ましい。)を施すことによりセ
メントを多孔性状態で固化させることができるので、優
れた多孔性の透水性固形物を得ることがきる。炭化物の
大きさは必ずしも粉末状である必要はなく、直径10ミ
リ程度までの適当な大きさの粒状物が使用されるが、使
用目的に応じて任意に選択することが出来る。
FIG. 2 is an external perspective view of a second embodiment of the present invention, showing a water-permeable solid using only waste carbide and cement powder. This is achieved by mixing the ground powder or granular material of the waste material carbide and the cement powder, fixing them in a mold, and applying a low-temperature steam treatment (preferably 100 ° or less) in a zero slump state, that is, without adding water. Since the cement can be solidified in a porous state, an excellent porous water-permeable solid can be obtained. The size of the carbide is not necessarily required to be in the form of powder, and granules having an appropriate size of up to about 10 mm in diameter are used, but can be arbitrarily selected according to the purpose of use.

【0012】また、廃材炭化物に廃材ガラス片粉砕砂と
廃材溶融スラグ等の廃材粉末粒状物を混入し、これにセ
メント粉を混入してもよい。特に、廃材粉末粒状物とし
て火山灰または火山の噴火石の使用はセメント材の節約
と火山噴火のもたらす公害材料の有効利用に役立つもの
である。
Further, it is also possible to mix waste material powder granular material such as waste material glass crushed sand and waste material molten slag into the waste material carbonized material, and then mix cement powder into the waste material powder. In particular, the use of volcanic ash or volcanic eruption rock as waste powder granules helps to save cement material and effectively use the polluting materials resulting from the volcanic eruption.

【0013】図3はこの発明の第3の実施例を示す外観
斜視図で、図1で説明した多孔性粒状固形物を、図2に
おける透水性固形物を製造する際の廃材炭化物粉末の代
わりに使用したもので、多孔性で透水性に優れた軽量の
固形物を得ることができる。これらの透水性固形物は、
街路樹の周りの舗装ブロックとして使用することによ
り、雨水を通過させるので自然に優しい街つくりができ
る。
FIG. 3 is an external perspective view showing a third embodiment of the present invention. The porous granular solid described in FIG. 1 is used instead of the waste carbon powder in producing the water-permeable solid in FIG. And a light-weight solid material that is porous and excellent in water permeability can be obtained. These permeable solids are
By using it as a pavement block around a street tree, it allows rainwater to pass through, making it possible to create a town that is friendly to nature.

【0014】また、これらの炭化物混入の多孔性ブロッ
クは、地域のゴミ収集場のブロック塀や、家畜小屋の周
り等のブロック塀に使用することにより優れた脱臭、防
臭効果を発揮できる。そして、使用後に再び不要となっ
て廃棄するような時には、破砕して砂状にして土に混ぜ
ることにより路盤材として土に帰すことができる。
[0014] These porous blocks mixed with carbides can exert excellent deodorizing and deodorizing effects by being used for block walls at local garbage collection sites and block walls around livestock huts. Then, when it becomes unnecessary again after use and is discarded, it can be returned to the soil as a roadbed material by crushing it into sand and mixing it with the soil.

【0015】また、透水性固形物から形成したシ−トや
ブロックにヒバ油と木酢液を浸み込ませることにより、
吸湿効果を有すると共にカビ等の微生物の発生を抑制す
るので建造物の床下調湿材として優れた効果を発揮でき
る。
[0015] In addition, by impregnating Hiba oil and wood vinegar in a sheet or block formed from a water-permeable solid,
Since it has a moisture absorbing effect and suppresses the generation of microorganisms such as mold, it can exhibit an excellent effect as a floor-based humidity control material for buildings.

【0016】更に、バクテリア等の微生物を培養した水
槽に浸漬して乾燥させた多孔性の透水性固形物を鑑賞魚
の水槽や浴槽に沈めておくことにより、水の腐敗や汚染
を防止できるので、水質浄化材としての利用も大いに期
待できる。
Further, by immersing the porous permeable solids immersed and dried in a water tank in which microorganisms such as bacteria are cultured in a water tank or a bath for appreciation fish, it is possible to prevent water decay and contamination. It can also be expected to be used as a water purification material.

【0017】[0017]

【発明の効果】この発明によれば、処理に困っている可
燃性の廃材炭化物と不燃性の廃材ガラス製品を再利用す
ることにより、廃材処理を兼ねた優れた土木建築用の素
材を提供できる効果を有する。
According to the present invention, an excellent material for civil engineering and construction which also serves as a waste material treatment can be provided by reusing a combustible waste material carbide and a non-combustible waste material glass product which are difficult to treat. Has an effect.

【図面の簡単な説明】[Brief description of the drawings]

【図1】この発明の第1の実施例の物の部分断面外観図
である。
FIG. 1 is a partial cross-sectional external view of a product according to a first embodiment of the present invention.

【図2】この発明の第2の実施例の外観斜視図である。FIG. 2 is an external perspective view of a second embodiment of the present invention.

【図3】他の実施例の外観斜視図である。FIG. 3 is an external perspective view of another embodiment.

【符号の説明】[Explanation of symbols]

1・・・表面分 2・・・断面分 1 ... surface 2 ... section

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C02F 3/10 C04B 38/00 303Z 4G019 C04B 38/00 301 E01C 5/22 303 B01D 53/34 116A E01C 5/22 B09B 3/00 301S 303D Fターム(参考) 2D051 AA02 AD07 AE05 AF06 AG07 DA01 4D002 AB02 AC10 BA03 BA04 CA07 CA20 DA19 DA41 DA66 DA70 EA06 GA01 GB08 GB11 GB12 4D003 AA01 DA28 EA01 EA19 EA20 EA21 EA22 EA23 EA24 EA25 EA38 EA40 FA06 4D004 AA16 AA18 AA43 AA50 BA02 CA15 CA22 CC03 CC07 CC11 CC13 CC15 4D052 AA08 AA09 CA02 CA09 GB12 GB14 GB17 HA00 HA05 HA21 4G019 DA04 FA02 FA12 FA15 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C02F 3/10 C04B 38/00 303Z 4G019 C04B 38/00 301 E01C 5/22 303 B01D 53/34 116A E01C 5 / 22 B09B 3/00 301S 303D F term (reference) 2D051 AA02 AD07 AE05 AF06 AG07 DA01 4D002 AB02 AC10 BA03 BA04 CA07 CA20 DA19 DA41 DA66 DA70 EA06 GA01 GB08 GB11 GB12 4D003 AA01 DA28 EA01 EA19 EA20 EA20 EA20 EA20 4D004 AA16 AA18 AA43 AA50 BA02 CA15 CA22 CC03 CC07 CC11 CC13 CC15 4D052 AA08 AA09 CA02 CA09 GB12 GB14 GB17 HA00 HA05 HA21 4G019 DA04 FA02 FA12 FA15

Claims (8)

【特許請求の範囲】[Claims] 【請求項1】廃材炭化物と廃材ガラス粉末を混練し、高
温加熱処理したことを特徴とする多孔性粒状固形物材
料。
1. A porous granular solid material obtained by kneading waste material carbide and waste material glass powder and subjecting them to high-temperature heat treatment.
【請求項2】廃材炭化物にセメント粉を混入し、ゼロス
ランプ状態で低温水蒸気処理を行ったとを特徴とする透
水性固形物材料。
2. A water-permeable solid material obtained by mixing cement powder into a waste carbonized material and performing low-temperature steam treatment in a zero slump state.
【請求項3】廃材炭化物と廃材ガラス粉末を混練し、高
温加熱処理した多孔性粒状固形物材料にセメント粉を混
入し、ゼロスランプ状態で低温水蒸気処理を行ったとを
特徴とする透水性固形物材料。
3. A water-permeable solid material obtained by kneading a waste material carbide and a waste material glass powder, mixing a cement powder into a porous granular solid material subjected to a high-temperature heat treatment, and performing a low-temperature steam treatment in a zero slump state. material.
【請求項4】廃材炭化物とガラス片粉砕砂と廃材溶融ス
ラグ等の廃材粉末粒状物にセメント粉を混入し、ゼロス
ランプ状態で、低温水蒸気処理を行ったとを特徴とする
透水性固形物材料。
4. A water-permeable solid material obtained by mixing a cement powder into a waste material powder such as a waste material carbide, a glass piece crushed sand and a waste material molten slag, and performing a low-temperature steam treatment in a zero slump state.
【請求項5】廃材溶融灰等の廃材粉末粒状物の代わり
に、火山灰又は噴火石の粉末粒状物を使用したことを特
徴とする請求項4記載の透水性固形物材料。
5. The water-permeable solid material according to claim 4, wherein a granular material of volcanic ash or eruptive rock is used instead of a granular material of waste material such as molten ash of waste material.
【請求項6】微生物を含浸添加したことを特徴とする請
求項2、3、4、又は5のいずれかに記載の透水性固形
物材料。
6. The water-permeable solid material according to claim 2, wherein the material is impregnated with a microorganism.
【請求項7】ヒバ油及び木酢液を含浸させたことを特徴
とする請求項2、3、4又は5のいずれかに記載の透水
性固形物材料。
7. The water-permeable solid material according to claim 2, wherein the material is impregnated with hiba oil and wood vinegar.
【請求項8】シ−ト状、またはブロック状に形成したこ
とを特徴とする請求項1、2、3、4、5、6、又は7
のいずれかに記載の透水性固形物材料。
8. The method according to claim 1, wherein the sheet is formed in a sheet shape or a block shape.
A permeable solid material according to any one of the above.
JP11780599A 1999-04-26 1999-04-26 Solid material obtained using carbonized scrap wood Pending JP2000308864A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11780599A JP2000308864A (en) 1999-04-26 1999-04-26 Solid material obtained using carbonized scrap wood

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11780599A JP2000308864A (en) 1999-04-26 1999-04-26 Solid material obtained using carbonized scrap wood

Publications (1)

Publication Number Publication Date
JP2000308864A true JP2000308864A (en) 2000-11-07

Family

ID=14720723

Family Applications (1)

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Cited By (9)

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JP2006315914A (en) * 2005-05-13 2006-11-24 Torimu:Kk Porous light weight material and method of manufacturing the same
JP2007238336A (en) * 2006-03-03 2007-09-20 Kitakyushu Foundation For The Advancement Of Industry Science & Technology Carbon-containing porous glass ceramic and its manufacturing process
JP2008173558A (en) * 2007-01-17 2008-07-31 Petroleum Energy Center Water-permeable purifying wall and purification treatment method of polluted underground water
JP2009095738A (en) * 2007-10-16 2009-05-07 Aoyama Eco System:Kk Molding for water purification and manufacturing method of the same
CN103408129A (en) * 2013-08-19 2013-11-27 中国水产科学研究院渔业机械仪器研究所 Degradable bio-compatible water treatment filler and preparation method thereof
CN106082733A (en) * 2016-06-13 2016-11-09 曹树梁 Pb-Zn dust slag ceramic aggregate and manufacture method thereof
CN106082735A (en) * 2016-06-13 2016-11-09 曹树梁 Acid-washing stainless steel mud ceramic aggregate and manufacture method thereof
CN106082732A (en) * 2016-06-13 2016-11-09 曹树梁 Hydrargyrum slag ceramic aggregate and manufacture method thereof
CN106082736A (en) * 2016-06-13 2016-11-09 曹树梁 Barium slag ceramic aggregate and manufacture method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006315914A (en) * 2005-05-13 2006-11-24 Torimu:Kk Porous light weight material and method of manufacturing the same
JP2007238336A (en) * 2006-03-03 2007-09-20 Kitakyushu Foundation For The Advancement Of Industry Science & Technology Carbon-containing porous glass ceramic and its manufacturing process
JP2008173558A (en) * 2007-01-17 2008-07-31 Petroleum Energy Center Water-permeable purifying wall and purification treatment method of polluted underground water
JP2009095738A (en) * 2007-10-16 2009-05-07 Aoyama Eco System:Kk Molding for water purification and manufacturing method of the same
CN103408129A (en) * 2013-08-19 2013-11-27 中国水产科学研究院渔业机械仪器研究所 Degradable bio-compatible water treatment filler and preparation method thereof
CN103408129B (en) * 2013-08-19 2015-12-23 中国水产科学研究院渔业机械仪器研究所 Degradable biological affinity water treatment filling and preparation method thereof
CN106082733A (en) * 2016-06-13 2016-11-09 曹树梁 Pb-Zn dust slag ceramic aggregate and manufacture method thereof
CN106082735A (en) * 2016-06-13 2016-11-09 曹树梁 Acid-washing stainless steel mud ceramic aggregate and manufacture method thereof
CN106082732A (en) * 2016-06-13 2016-11-09 曹树梁 Hydrargyrum slag ceramic aggregate and manufacture method thereof
CN106082736A (en) * 2016-06-13 2016-11-09 曹树梁 Barium slag ceramic aggregate and manufacture method thereof

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