JP2000265173A - Method and system for dry distillation-type cracking - Google Patents

Method and system for dry distillation-type cracking

Info

Publication number
JP2000265173A
JP2000265173A JP6556499A JP6556499A JP2000265173A JP 2000265173 A JP2000265173 A JP 2000265173A JP 6556499 A JP6556499 A JP 6556499A JP 6556499 A JP6556499 A JP 6556499A JP 2000265173 A JP2000265173 A JP 2000265173A
Authority
JP
Japan
Prior art keywords
temperature
heating
gas
raw material
dry distillation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6556499A
Other languages
Japanese (ja)
Other versions
JP4038925B2 (en
Inventor
Hiromichi Noma
弘道 野間
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IHI Corp
Original Assignee
IHI Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IHI Corp filed Critical IHI Corp
Priority to JP6556499A priority Critical patent/JP4038925B2/en
Publication of JP2000265173A publication Critical patent/JP2000265173A/en
Application granted granted Critical
Publication of JP4038925B2 publication Critical patent/JP4038925B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/143Feedstock the feedstock being recycled material, e.g. plastics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Abstract

PROBLEM TO BE SOLVED: To provide the subject method and system therefor, enabling feedstocks to be treated efficiently in a short time and separated into a gas component and solid component in a stable condition. SOLUTION: This method for dry distillation-type cracking which is intended for thermally cracking a feedstock R comprising petroleum-based compounds in a substantially closed space to separate it into a solid component and a gas component, has a conveyance process for conveying a feedstock charged in the front step A of the above closed space toward the rear step B and a heating process for heating the above closed space to thermally crack the feedstock during conveyance operation; wherein the heating process has a temperature-raising stage for heating the feedstock at the front step of the closed space to such a temperature as to enable it to be cracked and a separation stage for thermal insulation at such a temperature as to enable the gas component to be separated until the gas component is nearly entirely separated from the solid component at the rear step of the closed space; in this case, the temperature-raising stage is designed to set heating energy per unit time to be greater than that in the separation stage.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、廃プラスチックや
塩化ビニル品等の石油系化合物からなる原料を熱分解し
固形成分と気体成分とに分離する乾留式分解方法および
装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a dry distillation cracking method and apparatus for pyrolyzing a raw material composed of petroleum compounds such as waste plastics and vinyl chloride products to separate them into solid components and gas components.

【0002】[0002]

【従来の技術】近年、廃タイヤ、廃プラスチックおよび
塩化ビニル品等の石油系化合物からなる廃棄物は、その
まま焼却処理するとダイオキシン等の有毒物質を発生さ
せてしまうため、乾留式で廃棄物を熱分解し、石油系資
源として再利用可能な固形成分と塩素成分等の有毒ガス
を含む気体成分とに分離して処理する手段が研究されて
いる。
2. Description of the Related Art In recent years, wastes made of petroleum compounds such as waste tires, waste plastics and vinyl chloride products generate toxic substances such as dioxin when incinerated as they are. Means for decomposing and separating into solid components that can be reused as petroleum resources and gas components containing toxic gases such as chlorine components for treatment are being studied.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、上記従
来の熱分解手段では、以下のような課題が残されてい
る。すなわち、廃タイヤ等の石油系化合物からなる原料
を熱分解し始めた後に、気体成分を固形成分から完全に
分離させるために、高温状態で十分な滞留時間を確保す
る必要があり、全体の処理時間を短縮するためには、で
きるだけ初期の熱分解に要する加熱時間を短縮すること
が要望されている。
However, the above-mentioned conventional thermal decomposition means has the following problems. That is, it is necessary to secure sufficient residence time in a high temperature state in order to completely separate the gas component from the solid component after starting to crack the raw material composed of petroleum compounds such as waste tires. In order to reduce the time, it is desired to reduce the heating time required for the initial thermal decomposition as much as possible.

【0004】一方、従来は、単一の熱媒を用いて加熱処
理を行っているが、分解加熱後、気体成分の分離に必要
な滞留時間にも同一の熱媒で加熱を継続させた場合、温
度が安定せず気体成分の分離に必要な温度を大きく越え
てしまい暴走反応を起こすおそれもある。この場合、固
形成分がさらに分解されて再利用可能な燃料としての価
値が下がってしまう不都合があった。
[0004] On the other hand, conventionally, heat treatment is performed using a single heat medium. However, after heating by decomposition, heating is continued with the same heat medium during the residence time required for separation of gas components. However, the temperature may not be stable and may greatly exceed the temperature required for separating gas components, causing a runaway reaction. In this case, there is an inconvenience that the solid component is further decomposed and its value as a reusable fuel is reduced.

【0005】本発明は、前述の課題に鑑みてなされたも
ので、短時間で効率的に処理でき、さらに、安定した状
態で気体成分と固形成分との分離ができる乾留式分解方
法および装置を提供することを目的とする。
The present invention has been made in view of the above-mentioned problems, and provides a dry distillation method and apparatus capable of efficiently treating in a short time and separating gas components and solid components in a stable state. The purpose is to provide.

【0006】[0006]

【課題を解決するための手段】本発明は、前記課題を解
決するため、以下の構成を採用した。すなわち、請求項
1記載の乾留式分解方法では、石油系化合物からなる原
料を略密閉空間で熱分解させて固形成分と気体成分とに
分離する乾留式分解方法において、前記略密閉空間の前
段に投入された前記原料を前段から後段に向けて粉砕し
ながら移送する移送工程と、該移送工程中に前記略密閉
空間を加熱して前記原料を熱分解させる加熱工程とを備
え、該加熱工程は、前記略密閉空間の前段で前記原料を
分解可能な温度まで加熱する昇温工程と、前記略密閉空
間の後段で前記気体成分が前記固形成分からほぼ完全に
分離するまで気体成分の分離可能な温度で保温する分離
工程とを備え、該昇温工程は、前記分離工程に比べて単
位時間当たりの加熱量を大きく設定している技術が採用
される。
The present invention has the following features to attain the object mentioned above. That is, in the dry distillation cracking method according to claim 1, in the dry distillation cracking method in which a raw material composed of a petroleum compound is thermally decomposed in a substantially closed space to separate it into a solid component and a gas component, A transfer step of transferring the input raw material while pulverizing it from the former stage to the latter stage, and a heating step of heating the substantially enclosed space to thermally decompose the raw material during the transfer step, the heating step comprising: A heating step in which the raw material is heated to a temperature at which the raw material can be decomposed at a stage preceding the substantially enclosed space, and a gas component can be separated until the gas component is substantially completely separated from the solid component at a stage subsequent to the substantially enclosed space. A separation step of keeping the temperature at a temperature, and in the temperature raising step, a technique in which a heating amount per unit time is set to be larger than that in the separation step is adopted.

【0007】また、請求項7記載の乾留式分解装置で
は、石油系化合物からなる原料を内部が略密閉な筒状本
体内で熱分解させて固形成分と気体成分とに分離する乾
留式分解装置において、前記筒状本体内の前段に投入さ
れた前記原料を前段から後段に向けて移送する移送機構
と、前記筒状本体内を加熱して前記原料を熱分解させる
加熱機構とを備え、前記加熱機構は、前記筒状本体内の
前段で前記原料を分解可能な温度まで加熱する昇温手段
と、前記筒状本体内の後段で前記気体成分が前記固形成
分からほぼ完全に分離するまで気体成分の分離可能な温
度で保温する分離手段とを備え、前記昇温手段は、前記
分離手段に比べて単位時間当たりの加熱量が大きく設定
されている技術が採用される。
Further, in the dry distillation cracking apparatus according to the present invention, a raw material comprising a petroleum compound is thermally decomposed in a substantially closed cylindrical main body to separate into a solid component and a gas component. In the, comprises a transfer mechanism for transferring the raw material charged to the previous stage in the cylindrical body from the previous stage to the subsequent stage, and a heating mechanism for heating the cylindrical body and thermally decomposing the raw material, The heating mechanism includes a heating unit that heats the raw material to a temperature at which the raw material can be decomposed at a preceding stage in the tubular main body, and a gas until the gas component is almost completely separated from the solid component at a subsequent stage in the tubular main body. A separating means for keeping the temperature at a temperature at which the components can be separated, wherein a technique is employed in which the heating means has a larger heating amount per unit time than the separating means.

【0008】これらの乾留式分解方法および装置では、
原料を昇温する際に、気体成分の分離を行うときに比べ
て、単位時間当たりの加熱量が大きく設定されているの
で、短時間で原料を分解温度に到達させることができ
る。
In these dry distillation cracking methods and apparatuses,
When the temperature of the raw material is increased, the amount of heating per unit time is set to be larger than when the gas component is separated, so that the raw material can reach the decomposition temperature in a short time.

【0009】請求項2記載の乾留式分解方法では、請求
項1記載の乾留式分解方法において、前記昇温工程は、
前記略密閉空間の前段の周囲に前記原料を分解可能な温
度以上に加熱された高温油を流通させる技術が採用され
る。
[0009] In the carbonization cracking method according to claim 2, in the carbonization cracking method according to claim 1, the heating step includes
A technique is adopted in which high-temperature oil heated to a temperature at which the raw material can be decomposed or higher is circulated around the former stage of the substantially enclosed space.

【0010】また、請求項8記載の乾留式分解装置で
は、請求項7記載の乾留式分解装置において、前記昇温
手段は、前記筒状本体の前段の周壁に前記原料を分解可
能な温度以上に加熱された高温油を流通させる高温油流
路を備えている技術が採用される。
[0010] In the dry distillation apparatus according to the present invention, the temperature raising means may be at a temperature higher than a temperature at which the raw material can be decomposed on a peripheral wall in a preceding stage of the tubular main body. A technology having a high-temperature oil flow path for flowing the high-temperature oil heated to a high temperature is adopted.

【0011】これらの乾留式分解方法および装置では、
原料の分解温度までの昇温を行う部分の周囲に前記分解
可能な温度以上に加熱された高温油を流通させるので、
該高温油が高い熱伝導度を有していることから短時間で
原料を分解温度に到達させることができる。
In these dry distillation cracking methods and apparatuses,
Since high-temperature oil heated to a temperature above the decomposable temperature is allowed to flow around the portion where the temperature is raised to the decomposition temperature of the raw material,
Since the high-temperature oil has a high thermal conductivity, the raw material can reach the decomposition temperature in a short time.

【0012】請求項3記載の乾留式分解方法では、請求
項1記載の乾留式分解方法において、前記昇温工程は、
前記略密閉空間の前段の周囲に配した電気ヒータにより
前記原料の成分および量に応じて加熱量を調整しながら
加熱する技術が採用される。
[0012] In the carbonization cracking method according to the third aspect, in the carbonization cracking method according to the first aspect, the temperature-raising step includes:
A technique is employed in which heating is performed while adjusting the amount of heating according to the components and amounts of the raw materials by an electric heater disposed around the former stage of the substantially enclosed space.

【0013】また、請求項9記載の乾留式分解装置で
は、請求項7記載の乾留式分解装置において、前記昇温
手段は、前記筒状本体の前段の周壁に前記原料の成分お
よび量に応じて加熱量が調整可能な電気ヒータを備えて
いる技術が採用される。
[0013] In the dry distillation apparatus according to the ninth aspect, in the dry distillation apparatus according to the seventh aspect, the temperature raising means may be provided on a peripheral wall at a preceding stage of the cylindrical main body in accordance with a component and an amount of the raw material. A technology having an electric heater whose heating amount can be adjusted by using an electric heater is adopted.

【0014】これらの乾留式分解方法および装置では、
原料の分解温度までの昇温を行う部分の周囲に配した電
気ヒータにより、原料の成分および量に応じて加熱量を
調整しながら加熱を行うので、効率的にかつ細かな温度
コントロールを行うことができ、必要十分な加熱量で短
時間に原料を分解温度に到達させることができる。
In these dry distillation cracking methods and apparatuses,
Heating is performed by adjusting the amount of heating according to the components and amount of the raw material using an electric heater arranged around the part where the temperature rises to the decomposition temperature of the raw material, so efficient and fine temperature control can be performed The raw material can reach the decomposition temperature in a short time with a necessary and sufficient heating amount.

【0015】請求項4記載の乾留式分解方法では、請求
項1から3のいずれかに記載の乾留式分解方法におい
て、前記分離工程は、前記略密閉空間の後段の周囲に前
記気体成分の分離可能な温度以上に加熱された加熱ガス
を流通させる技術が採用される。
According to a fourth aspect of the present invention, in the dry distillation method according to any one of the first to third aspects, the separation step includes a step of separating the gas component around a rear stage of the substantially closed space. A technique of flowing a heated gas heated to a temperature higher than a possible temperature is adopted.

【0016】また、請求項10記載の乾留式分解装置で
は、請求項7から9のいずれかに記載の乾留式分解装置
において、前記分離手段は、前記筒状本体の後段の周壁
に前記気体成分の分離可能な温度以上に加熱された加熱
ガスを流通させるガス流路を備えている技術が採用され
る。
According to a tenth aspect of the present invention, in the dry distillation apparatus according to any one of the seventh to ninth aspects, the separation means includes a gas component on a rear peripheral wall of the tubular main body. A technology having a gas flow path through which a heated gas heated to a temperature equal to or higher than the releasable temperature is allowed to flow is adopted.

【0017】これらの乾留式分解方法および装置では、
気体成分の分離を行う部分の周囲に気体成分の分離可能
な温度以上に加熱された加熱ガスを流通させるので、分
解反応を行う部分とは別の熱媒、すなわち熱伝導度の低
い加熱ガスによって適度な保温状態(緩やかに温度が上
昇する状態も含む)を維持でき、暴走反応が防止され
る。したがって、気体成分の分離を行う部分は分解温度
までの昇温を行う部分に比べて大きな熱量が不要である
ことから、異なる2種類の熱媒を別々に用いることによ
り、分離のための滞留時間における無駄な加熱量を低減
することができる。
In these dry distillation cracking methods and apparatuses,
Since a heating gas heated to a temperature higher than the temperature at which the gas component can be separated flows around the portion where the gas component is separated, a heating medium different from the portion performing the decomposition reaction, that is, a heating gas having a low thermal conductivity, is used. An appropriate heat-retaining state (including a state where the temperature rises slowly) can be maintained, and a runaway reaction is prevented. Therefore, since the portion for separating the gas component does not require a large amount of heat as compared with the portion for raising the temperature to the decomposition temperature, the residence time for the separation is determined by separately using two different types of heat medium. In this case, the amount of unnecessary heating can be reduced.

【0018】請求項5記載の乾留式分解方法では、請求
項4記載の乾留式分解方法において、前記分離工程で分
離した前記気体成分を再加熱して含まれる塩素成分を分
解除去する高温処理工程を備え、前記分離工程は、前記
高温処理工程後の前記気体成分を前記加熱ガスにする技
術が採用される。
According to a fifth aspect of the present invention, there is provided a dry distillation method according to the fourth aspect, wherein the gas component separated in the separation step is reheated to decompose and remove a chlorine component contained in the gas component. And the separation step employs a technique in which the gas component after the high-temperature treatment step is converted into the heating gas.

【0019】また、請求項11記載の乾留式分解装置で
は、請求項10記載の乾留式分解装置において、前記加
熱手段で分離した前記気体成分を再加熱して含まれる塩
素成分を分解除去する高温処理手段を備え、前記分離手
段は、前記高温処理手段で再加熱された前記気体成分を
前記加熱ガスにして前記ガス流路に流通させる技術が採
用される。
[0019] In the dry distillation apparatus according to the eleventh aspect, in the dry distillation apparatus according to the tenth aspect, the gas component separated by the heating means is reheated to decompose and remove the chlorine component contained therein. A processing means is provided, and the separation means adopts a technique in which the gas component reheated by the high-temperature processing means is converted into the heating gas and passed through the gas flow path.

【0020】これらの乾留式分解方法および装置では、
高温処理後の気体成分を前記加熱ガスにするので、分離
され高温となった気体成分を分離用の熱媒として再利用
でき、別個に加熱ガスの供給源を設置する必要もなくな
り、簡便な構成で加熱ガスを流通させることが可能とな
る。
In these dry distillation cracking methods and apparatuses,
Since the gas component after the high-temperature treatment is used as the heating gas, the gas component separated and heated to a high temperature can be reused as a heat medium for separation, and there is no need to separately install a heating gas supply source. Makes it possible to distribute the heating gas.

【0021】請求項6記載の乾留式分解方法では、請求
項4記載の乾留式分解方法において、前記昇温工程で使
用する前記高温油または前記分離工程で分離した前記気
体成分を、加熱炉内で燃焼ガスで加熱する工程を備え、
前記分離工程は、前記加熱炉の燃焼ガスを前記加熱ガス
にする技術が採用される。
In the carbonization cracking method according to a sixth aspect, in the carbonization cracking method according to the fourth aspect, the high-temperature oil used in the temperature raising step or the gas component separated in the separation step is supplied into a heating furnace. Equipped with a step of heating with combustion gas,
The separation step employs a technique in which the combustion gas of the heating furnace is changed to the heating gas.

【0022】また、請求項12記載の乾留式分解装置で
は、請求項10記載の乾留式分解装置において、前記昇
温手段で使用する前記高温油または前記分離手段で分離
した前記気体成分を燃焼ガスで加熱する加熱炉を備え、
前記分離手段は、前記加熱炉の燃焼ガスを前記加熱ガス
にして前記ガス流路に流通させる技術が採用される。
In the carbonization cracking apparatus according to the twelfth aspect, in the carbonization cracking apparatus according to the tenth aspect, the high-temperature oil used in the temperature raising means or the gas component separated by the separation means may be used as a combustion gas. Equipped with a heating furnace for heating with
The separation unit employs a technique in which the combustion gas of the heating furnace is converted into the heating gas and circulated through the gas passage.

【0023】これらの乾留式分解方法および装置では、
加熱炉の燃焼ガスを前記加熱ガスにするので、高温の燃
焼ガスを分離用の熱媒として再利用でき、別個に加熱ガ
スの供給源を設置する必要もなくなり、簡便な構成で加
熱ガスを流通させることが可能となる。
In these dry distillation cracking methods and apparatuses,
Since the combustion gas of the heating furnace is used as the heating gas, the high-temperature combustion gas can be reused as a heat medium for separation, and there is no need to separately provide a heating gas supply source. It is possible to do.

【0024】[0024]

【発明の実施の形態】以下、本発明に係る乾留式分解方
法および装置の第1実施形態を、図1および図2を参照
しながら説明する。これらの図において、1は乾留式分
解装置、2は筒状本体、3は移送機構、4は加熱機構で
ある。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A first embodiment of a carbonization cracking method and apparatus according to the present invention will be described below with reference to FIGS. In these figures, reference numeral 1 denotes a dry distillation decomposition apparatus, 2 denotes a cylindrical main body, 3 denotes a transfer mechanism, and 4 denotes a heating mechanism.

【0025】本実施形態の乾留式分解装置1は、図1に
示すように、廃タイヤ、廃プラスチックおよび塩化ビニ
ル品等の石油系化合物からなる原料Rを略密閉空間内で
移送するキルン式を採用したものであり、熱分解によっ
て原料Rを気体成分および固体成分に分離して回収する
ものである。
As shown in FIG. 1, the dry distillation cracking apparatus 1 of the present embodiment employs a kiln type in which a raw material R composed of petroleum compounds such as waste tires, waste plastics and vinyl chloride products is transferred in a substantially closed space. The raw material R is separated into gaseous components and solid components by thermal decomposition and recovered.

【0026】この乾留式分解装置1は、内部が略密閉な
筒状本体2と、該筒状本体2内の前段である昇温領域A
に投入口2aから投入された原料Rを昇温領域Aから後
段の分離領域Bに向けて移送する移送機構3と、筒状本
体2内を加熱して原料Rを熱分解させる加熱機構4とを
備えている。該加熱機構4は、昇温領域Aで原料Rを分
解可能な温度(本実施形態では、約320℃)まで加熱
する昇温手段5と、分離領域Bで気体成分が固形成分か
らほぼ完全に分離するまで気体成分の分離可能な温度
(本実施形態では、約320℃近傍)で保温(緩やかに
温度が上昇する状態も含む)する分離手段6とを備えて
いる。
The dry distillation cracking apparatus 1 includes a cylindrical body 2 having a substantially closed interior, and a heating zone A, which is a front stage in the cylindrical body 2.
A transfer mechanism 3 for transferring the raw material R supplied from the charging port 2a to the separation area B at the subsequent stage from the heating area A, and a heating mechanism 4 for heating the inside of the cylindrical main body 2 to thermally decompose the raw material R. It has. The heating mechanism 4 includes a heating means 5 for heating the raw material R to a temperature at which the raw material R can be decomposed (about 320 ° C. in this embodiment) in the heating area A, and a gas component almost completely from the solid component in the separation area B. Separation means 6 is provided which keeps the temperature (including a state where the temperature rises slowly) at a temperature at which the gas component can be separated (in the present embodiment, about 320 ° C.) until separation.

【0027】前記移送機構3は、筒状本体2の軸線に沿
って回転可能に軸支されたスクリューコンベア7と、筒
状本体2の前段側端部から突出したスクリューコンベア
7の一端部に回転軸が接続された駆動モータ8とを備え
ている。すなわち、この駆動モータ8によりスクリュー
コンベア7を回転駆動すると、昇温領域Aに投入された
原料Rがスクリューコンベア7の回転で分離領域Bへと
徐々に移送されるようになっている。
The transfer mechanism 3 includes a screw conveyor 7 rotatably supported along the axis of the cylindrical main body 2 and one end of the screw conveyor 7 protruding from the front end of the cylindrical main body 2. And a drive motor 8 to which a shaft is connected. That is, when the screw conveyor 7 is rotationally driven by the drive motor 8, the raw material R charged into the temperature raising area A is gradually transferred to the separation area B by the rotation of the screw conveyor 7.

【0028】前記筒状本体2は、分離領域Bの後端部に
おける上部および下部に、分離した気体成分を回収する
ための気体成分排出口2bおよび分離した固形成分を回
収するための固形成分排出口2cがそれぞれ設けられ、
気体成分排出口2bおよび固体成分排出口2cには、そ
れぞれの排出管路である気体成分排出ライン9および固
体成分排出ライン10が接続されている。
The cylindrical main body 2 has a gas component outlet 2b for collecting separated gas components and a solid component discharging port for collecting separated solid components at an upper portion and a lower portion at the rear end of the separation region B. Outlets 2c are respectively provided,
A gas component discharge line 9 and a solid component discharge line 10, which are discharge pipes, are connected to the gas component discharge port 2b and the solid component discharge port 2c.

【0029】前記昇温手段5は、筒状本体1の昇温領域
A周囲に位置する周壁に、原料Rを分解可能な温度以上
(本実施形態では、約380℃)に加熱されたホットオ
イル(高温油)Hを内部に流通可能なオイル用ジャケッ
ト(高温油流路)11を備えている。
The heating means 5 includes a hot oil heated to a temperature above the temperature at which the raw material R can be decomposed (about 380 ° C. in this embodiment) on a peripheral wall located around the heating area A of the cylindrical main body 1. An oil jacket (high-temperature oil passage) 11 through which (high-temperature oil) H can flow is provided.

【0030】該オイル用ジャケット11には、ホットオ
イルHの供給管路であるオイル供給ライン12と排出管
路であるオイル排出ライン13とが接続され、オイル供
給ライン12とオイル排出ライン13とは、ホットオイ
ルHを循環させるポンプ14で接続されている。また、
オイル供給ライン12の途中には、ホットオイルHを加
熱するためのオイル用加熱炉15が設置され、オイル供
給ライン12内を流通するホットオイルHはオイル用加
熱炉15内で燃焼ガス(加熱ガス)Gによって所定温度
(約380度)まで加熱される。
The oil jacket 11 is connected to an oil supply line 12 which is a supply line for hot oil H and an oil discharge line 13 which is a discharge line. The oil supply line 12 and the oil discharge line 13 are connected to each other. , Hot oil H is circulated. Also,
An oil heating furnace 15 for heating hot oil H is installed in the middle of the oil supply line 12, and the hot oil H flowing through the oil supply line 12 is subjected to combustion gas (heating gas) in the oil heating furnace 15. ) Heated to a predetermined temperature (about 380 degrees) by G.

【0031】前記分離手段6は、筒状本体1の分離領域
B周囲に位置する周壁に、気体成分の分離可能な温度以
上に加熱された燃焼ガス(加熱ガス)Gを内部に流通可
能なガス用ジャケット(ガス流路)16を備えている。
該ガス用ジャケット16には、燃焼ガスGの供給管路で
あるガス供給ライン17と排出管路であるガス排出ライ
ン18とが接続されている。
The separating means 6 is provided on a peripheral wall located around the separation area B of the cylindrical main body 1 with a gas capable of flowing a combustion gas (heated gas) G heated to a temperature higher than a temperature at which a gas component can be separated. A jacket (gas flow path) 16 is provided.
The gas jacket 16 is connected to a gas supply line 17 which is a supply line of the combustion gas G and a gas discharge line 18 which is a discharge line.

【0032】前記気体成分排出ライン9の途中には、気
体成分を再加熱するための高温処理用加熱炉19が設置
され、気体成分排出ライン9内を流通する気体成分は、
高温処理用加熱炉19内で塩素成分が分解可能な温度で
燃焼ガスGによって高温処理される。また、気体成分排
出ライン9は、高温処理用加熱炉19の下流側で冷却装
置20に接続されている。すなわち、高温処理された高
温状態のままで気体成分を大気に放出してしまうとダイ
オキシン等が発生するおそれがあるため、冷却装置20
内で水冷等によって気体成分を300℃以下に急冷処理
するものである。
A heating furnace 19 for high-temperature treatment for reheating the gas component is installed in the gas component discharge line 9, and the gas component flowing through the gas component discharge line 9 is:
High temperature processing is performed by the combustion gas G at a temperature at which the chlorine component can be decomposed in the high temperature processing heating furnace 19. The gas component discharge line 9 is connected to a cooling device 20 on the downstream side of the high-temperature processing heating furnace 19. That is, if the gas component is released to the atmosphere in the high temperature state after the high temperature treatment, dioxin or the like may be generated.
Inside, the gas component is rapidly cooled to 300 ° C. or less by water cooling or the like.

【0033】前記オイル用加熱炉15および前記高温処
理用加熱炉19には、それぞれ使用された燃焼ガスGの
排出管路である燃焼ガス排出ライン15a、19aが接
続され、これらの燃焼ガス排出ライン15a、19a
は、ガス供給ライン17に接続されている。すなわち、
オイル用加熱炉15および高温処理用加熱炉19におい
て使用した燃焼ガスGは、それぞれ燃焼ガス排出ライン
15a、19aによってガス供給ライン17に送られ、
ガス用ジャケット16内に供給させる。
The heating furnace 15 for oil and the heating furnace 19 for high-temperature treatment are connected to combustion gas discharge lines 15a and 19a, respectively, which are discharge pipes of the used combustion gas G. 15a, 19a
Are connected to a gas supply line 17. That is,
The combustion gas G used in the oil heating furnace 15 and the high-temperature processing heating furnace 19 is sent to the gas supply line 17 by combustion gas discharge lines 15a and 19a, respectively.
The gas is supplied into the gas jacket 16.

【0034】次に、本実施形態の乾留式分解装置1にお
いて、原料Rを固形成分と気体成分とに分離する方法に
ついて、図2を参照して説明する。
Next, a method of separating the raw material R into a solid component and a gas component in the dry distillation cracking apparatus 1 of the present embodiment will be described with reference to FIG.

【0035】〔昇温工程〕まず、原料Rを投入口2aか
ら筒状本体2内の昇温領域Aに投入する。この投入され
た原料Rは、スクリューコンベア7で徐々に分離領域B
側へと移送される。このとき、オイル用ジャケット11
内を流通する高温状態のホットオイルHを熱媒として、
図2に示すように、原料Rは、昇温領域Aの後端部で
は、約320℃まで加熱され、投入後約15分から30
分程度の短時間で気体成分と固形成分の分解可能な温度
に到達する。
[Temperature Raising Step] First, the raw material R is charged into the temperature raising area A in the cylindrical main body 2 from the charging port 2a. The charged raw material R is gradually separated by a screw conveyor 7 into a separation area B.
Transferred to the side. At this time, the oil jacket 11
Using hot oil H in a high temperature flowing through the inside as a heat medium,
As shown in FIG. 2, the raw material R is heated to about 320 ° C. at the rear end of the heating area A, and about 15 minutes to 30 minutes after being charged.
The temperature reaches a temperature at which the gas component and the solid component can be decomposed in a short time of about one minute.

【0036】〔分離工程〕気体成分と固形成分との分解
温度に達した原料Rは、スクリューコンベア7によって
昇温領域Aから分離領域Bへと移されると、ガス用ジャ
ケット16内を流通する燃焼ガスGを熱媒として昇温領
域Aの最終的な温度である約320℃近傍で保温されな
がら、後端部へと徐々に移送される。
[Separation Step] When the raw material R which has reached the decomposition temperature of the gas component and the solid component is transferred from the temperature raising region A to the separation region B by the screw conveyor 7, the combustion R flowing through the gas jacket 16 The gas G is gradually transferred to the rear end while keeping the temperature at about 320 ° C., which is the final temperature of the temperature rising area A, using the gas G as a heat medium.

【0037】このとき、スクリューコンベア7によって
固形成分が撹拌されるとともに、上記の保温効果によっ
て気体成分が固形成分から上方に分離していく。気体成
分を完全に固形成分から分離するには、高温で十分な滞
留時間を与える必要があるため、固形成分は分離領域B
の後端部まで、滞留時間をかけて移送され、気体成分と
完全に分離される。
At this time, the solid components are agitated by the screw conveyor 7 and the gas components are separated upward from the solid components by the above-mentioned heat retaining effect. In order to completely separate the gas component from the solid component, it is necessary to provide a sufficient residence time at a high temperature.
To the rear end over a residence time and is completely separated from the gaseous components.

【0038】なお、分離領域Bにおいて、昇温領域Aと
同様に、ホットオイルHを熱媒とした場合、図2の点線
に示すように、温度が急速に上昇して暴走反応を生じて
しまうおそれがあるが、本実施形態では、熱伝導性が低
い別の熱媒である燃焼ガスGを分離領域Bに使用してい
るので、図2の実線に示すように、温度上昇が非常に緩
やかになり、ほぼ一定の温度で保温することができる。
When hot oil H is used as the heat medium in the separation region B, as in the temperature rising region A, the temperature rises rapidly and a runaway reaction occurs as shown by the dotted line in FIG. Although there is a possibility that the combustion gas G, which is another heat medium having low thermal conductivity, is used in the separation region B in the present embodiment, the temperature rise is very gentle as shown by the solid line in FIG. , And can be kept at a substantially constant temperature.

【0039】この分離領域Bで熱媒として使用される燃
焼ガスGは、オイル用加熱炉15および高温処理用加熱
炉19で使用された燃焼ガスGをガス用ジャケット16
内に導入させたものであり、オイル用ジャケット11内
を流通して筒状本体2内を加熱した後、ガス排出ライン
18に排出される。
The combustion gas G used as a heat medium in the separation region B is obtained by converting the combustion gas G used in the oil heating furnace 15 and the high-temperature processing heating furnace 19 into a gas jacket 16.
After flowing through the oil jacket 11 to heat the inside of the tubular main body 2, it is discharged to the gas discharge line 18.

【0040】〔回収工程〕分離領域Bの後端部で完全に
気体成分が分離された固形成分は、固形成分排出口2c
から固形成分排出ライン10を介して取り出され、再資
源として活用される。一方、分離した気体成分は、気体
成分排出口2bから気体成分排出ライン9を介して取り
出され、高温処理用加熱炉19で高温処理されて有害な
塩素成分が分解除去されるとともに、さらに冷却装置2
0において急冷された状態で大気に放出される。
[Recovery Step] The solid component from which the gaseous component has been completely separated at the rear end of the separation area B is supplied to the solid component outlet 2c.
From the waste through the solid component discharge line 10 and utilized as a resource. On the other hand, the separated gas component is taken out from the gas component discharge port 2b through the gas component discharge line 9 and is subjected to high temperature treatment in the high-temperature treatment heating furnace 19 to decompose and remove harmful chlorine components, and further to a cooling device. 2
At 0, it is released to the atmosphere in a quenched state.

【0041】このように、本実施形態の乾留式分解装置
1では、原料Rを昇温する際に、気体成分の分離を行う
ときに比べて単位時間当たりの加熱量を大きくするた
め、原料Rを分解温度に到達させる部分の周囲に、原料
Rが分解可能な温度以上に加熱されたホットオイルHを
流通させるので、該ホットオイルHが高い熱伝導度を有
していることから短時間で原料Rを分解温度に到達させ
ることができる。
As described above, in the dry distillation cracking apparatus 1 of the present embodiment, when the temperature of the raw material R is increased, the amount of heating per unit time is increased as compared with the case where the gas component is separated. The hot oil H heated to a temperature higher than the temperature at which the raw material R can be decomposed is circulated around the portion where the raw oil R reaches the decomposition temperature, so that the hot oil H has a high thermal conductivity, The raw material R can reach the decomposition temperature.

【0042】また、気体成分の分離を行う部分(分離領
域B)の周囲に、気体成分の分離可能な温度以上に加熱
された燃焼ガスGを流通させるので、分解温度までの昇
温を行う部分とは別の熱媒、すなわち熱伝導度の低い加
熱ガスによって適度な保温状態を維持でき、暴走反応が
防止される。したがって、分離領域Bは昇温領域Aに比
べて大きな熱量が不要であることから、異なる2種類の
熱媒(ホットオイルHと燃焼ガスG)を別々に用いるこ
とにより、分離のための滞留時間における無駄な熱量を
低減することができる。
Further, since the combustion gas G heated to a temperature higher than the temperature at which the gas component can be separated flows around the portion where the gas component is separated (separation region B), the temperature is raised to the decomposition temperature. An appropriate heat retaining state can be maintained by another heat medium, that is, a heating gas having low thermal conductivity, and a runaway reaction is prevented. Therefore, since the separation area B does not require a large amount of heat as compared with the temperature raising area A, the residence time for separation can be increased by separately using two different heat media (hot oil H and combustion gas G). In this case, the amount of waste heat can be reduced.

【0043】さらに、オイル用加熱炉15および高温処
理用加熱炉19の燃焼ガスGを分離領域Bの熱媒に用い
るので、使用済みの燃焼ガスGを気体成分の分離用とし
て再利用でき、別個に熱媒用加熱ガスの供給源を設置す
る必要もなくなり、簡便な構成でガス熱媒をガス用ジャ
ケット16内に流通させることが可能となる。
Further, since the combustion gas G of the oil heating furnace 15 and the high-temperature processing heating furnace 19 is used as the heating medium in the separation region B, the used combustion gas G can be reused for separating gas components, and can be used separately. There is no need to provide a heating medium supply source for the heating medium, and the gas heating medium can be circulated in the gas jacket 16 with a simple configuration.

【0044】次に、本発明に係る乾留式分解方法および
装置の第2実施形態を、図3および図4を参照しながら
説明する。
Next, a second embodiment of the dry distillation method and apparatus according to the present invention will be described with reference to FIGS.

【0045】第2実施形態と第1実施形態との異なる点
は、第1実施形態では昇温手段5がホットオイルHを熱
媒として流通させるオイル用ジャケット11を備えてい
るのに対し、第2実施形態の乾留式分解装置21では、
図3に示すように、昇温手段22が、筒状本体2の昇温
領域Aの周壁に原料Rの成分および量に応じて加熱量が
調整可能な電気ヒータ23と該電気ヒータ23に電流を
供給するとともに制御する電源24とを備えている点で
異なる。
The difference between the second embodiment and the first embodiment is that in the first embodiment, the temperature raising means 5 has an oil jacket 11 for flowing hot oil H as a heat medium, In the dry distillation cracker 21 of the second embodiment,
As shown in FIG. 3, an electric heater 23 capable of adjusting a heating amount in accordance with a component and an amount of a raw material R is provided on a peripheral wall of a heating area A of the cylindrical main body 2 and a current is supplied to the electric heater 23. And a power supply 24 for supplying and controlling the power supply.

【0046】すなわち、原料Rを分解温度に到達させる
部分の周囲に配した電気ヒータ23により、図4に示す
ように、原料Rの成分および量に応じて加熱量を調整し
ながら加熱を行うので、投入された原料Rの分解に必要
な温度に確実に到達させることができる。したがって、
ホットオイルでは細かな温度制御が困難であるのに対
し、本実施形態では、電気ヒータ23によって効率的に
かつ細かな温度コントロールを行うことができ、必要十
分な加熱量で短時間に原料を分解温度に到達させること
ができる。
That is, as shown in FIG. 4, the heating is performed by adjusting the heating amount according to the component and the amount of the raw material R by the electric heater 23 disposed around the portion where the raw material R reaches the decomposition temperature. Thus, the temperature required for decomposition of the charged raw material R can be reliably reached. Therefore,
While it is difficult to perform fine temperature control with hot oil, in the present embodiment, the electric heater 23 can perform efficient and fine temperature control, and the raw material can be decomposed in a short time with a necessary and sufficient heating amount. Temperature can be reached.

【0047】また、第1実施形態では、分離手段6にお
いて燃焼ガスGを熱媒として流通させるガス用ジャケッ
ト16を備えているのに対し、第2実施形態では、分離
手段25において高温処理用加熱炉19で高温処理され
た高温の気体成分を熱媒として流通させるガス用ジャケ
ット26を備えている。
In the first embodiment, the separating means 6 is provided with a gas jacket 16 through which the combustion gas G flows as a heat medium, whereas in the second embodiment, the separating means 25 is provided with a heating means for high-temperature processing. A gas jacket 26 is provided for passing a high-temperature gas component that has been subjected to high-temperature processing in the furnace 19 as a heat medium.

【0048】すなわち、気体成分排出ライン9は、高温
処理用加熱炉19の下流側でガス供給ライン17に接続
され、ガス用ジャケット26内に導入されるようになっ
ている。さらに、ガス用ジャケット26を流通して分離
領域Bを加熱保温した気体成分は、ガス排出ライン18
から排出されるとともに冷却装置20へと送られ、30
0℃以下に急冷された後に大気に放出されるようになっ
ている。
That is, the gas component discharge line 9 is connected to the gas supply line 17 on the downstream side of the high-temperature processing heating furnace 19 and is introduced into the gas jacket 26. Further, the gas component which flows through the gas jacket 26 and heats and maintains the separation area B is supplied to the gas discharge line 18.
From the cooling device 20 and
After being quenched to 0 ° C. or less, it is released to the atmosphere.

【0049】したがって、本実施形態では、高温処理後
の気体成分を分離領域Bの熱媒用の加熱ガスにするの
で、分離された気体成分を再利用でき、別個に熱媒用の
加熱ガス供給源を設置する必要もなくなり、簡便な構成
で分離領域Bの保温が可能となる。
Therefore, in the present embodiment, the gas component after the high-temperature treatment is used as the heating gas for the heating medium in the separation region B, so that the separated gas component can be reused and the heating gas for the heating medium is separately supplied. There is no need to install a source, and the separation region B can be kept warm with a simple configuration.

【0050】なお、本発明は、次のような実施形態をも
含むものである。 (1)上記各実施形態では、分離領域Bの熱媒として加
熱炉からの燃焼ガスGまたは高温処理後の気体成分を用
いたが、別個の供給源からの加熱ガスを採用しても構わ
ない。しかしながら、この場合は上述したように、加熱
ガス用の供給源設備を別個に設置する必要が生じるた
め、上記各実施形態のように、燃焼ガスGおよび気体成
分を再利用する方が設備コストおよび稼働コストを低減
することができる。
The present invention also includes the following embodiments. (1) In each of the above embodiments, the combustion gas G from the heating furnace or the gas component after the high-temperature treatment is used as the heating medium in the separation region B, but a heating gas from a separate supply source may be used. . However, in this case, as described above, since it is necessary to separately install a supply source equipment for the heating gas, it is more expensive to reuse the combustion gas G and the gas component as in the above embodiments. Operating costs can be reduced.

【0051】(2)第1実施形態では、分離領域B用の
熱媒としてオイル用加熱炉15および高温処理用加熱炉
19の両方からの燃焼ガスGを採用したが、いずれか一
方の燃焼ガスだけを用いても構わない。
(2) In the first embodiment, the combustion gas G from both the oil heating furnace 15 and the high-temperature processing heating furnace 19 is employed as the heating medium for the separation region B. May be used alone.

【0052】(3)第1実施形態の昇温手段5と第2実
施形態の分離手段25とを組み合わせたものや、第1実
施形態の分離手段6と第2実施形態の昇温手段22とを
組み合わせたもの(この場合は、ガス用ジャケットに送
られる燃焼ガスGは高温処理用加熱炉のもののみ)を分
解装置に採用しても構わない。
(3) A combination of the temperature raising means 5 of the first embodiment and the separation means 25 of the second embodiment, the separation means 6 of the first embodiment and the temperature raising means 22 of the second embodiment, (In this case, only the combustion gas G sent to the gas jacket is from the heating furnace for high-temperature treatment) may be adopted as the decomposition device.

【0053】(4)第1実施形態では、オイル用加熱炉
15および高温処理用加熱炉19を別々に設置したが、
一つの加熱炉をホットオイル加熱用および気体成分高温
処理用として兼用して使用しても構わない。この場合、
加熱炉の単一化により設備コストを低減することができ
る。なお、燃焼ガスを分離領域の熱媒として用いない場
合には、ホットオイルの加熱および気体成分の高温処理
は、加熱炉以外の他の加熱手段(電気ヒータ等)によっ
ても構わない。
(4) In the first embodiment, the heating furnace 15 for oil and the heating furnace 19 for high-temperature treatment are separately installed.
One heating furnace may be used for both hot oil heating and gas component high temperature treatment. in this case,
Equipment costs can be reduced by using a single heating furnace. When the combustion gas is not used as the heat medium in the separation region, the heating of the hot oil and the high-temperature treatment of the gas components may be performed by other heating means (such as an electric heater) other than the heating furnace.

【0054】[0054]

【発明の効果】本発明によれば、以下の効果を奏する。 (1)請求項1記載の乾留式分解方法および請求項7記
載の乾留式分解装置では、原料を昇温する際に、気体成
分の分離を行うときに比べて、単位時間当たりの加熱量
が大きく設定されているので、短時間で原料を分解温度
に到達させることができ、全体の処理時間を短縮するこ
とができる。
According to the present invention, the following effects can be obtained. (1) In the carbonization cracking method according to the first aspect and the carbonization cracking apparatus according to the seventh aspect, when the temperature of the raw material is increased, the amount of heating per unit time is higher than when the gas component is separated. Since it is set to be large, the raw material can reach the decomposition temperature in a short time, and the overall processing time can be shortened.

【0055】(2)請求項2記載の乾留式分解方法およ
び請求項8記載の乾留式分解装置では、原料の分解温度
までの昇温を行う部分の周囲に前記分解可能な温度以上
に加熱された高温油を流通させるので、該高温油が高い
熱伝導度を有していることから短時間で原料を分解温度
に到達させることができ、処理時間全体および装置全長
を短縮することができる。
(2) In the dry distillation method according to the second aspect and the dry distillation apparatus according to the eighth aspect, the raw material is heated to a temperature higher than the decomposable temperature around the portion where the temperature is raised to the decomposition temperature of the raw material. Since the high-temperature oil is circulated, the raw material can reach the decomposition temperature in a short time because the high-temperature oil has a high thermal conductivity, and the entire processing time and the overall length of the apparatus can be shortened.

【0056】(3)請求項3記載の乾留式分解方法およ
び請求項9記載の乾留式分解装置では、原料の分解温度
までの昇温を行う部分の周囲に配した電気ヒータによ
り、原料の成分および量に応じて加熱量を調整しながら
加熱を行うので、効率的にかつ細かな温度コントロール
を行うことができ、投入原料に対して必要十分な加熱量
で短時間に原料を分解温度に到達させることができる。
したがって、処理時間全体および装置全長を短縮できる
だけでなく、稼働コストの低減を図ることもできる。
(3) In the dry distillation method according to the third aspect and the dry distillation apparatus according to the ninth aspect, the components of the raw material are controlled by an electric heater disposed around a portion for raising the temperature to the decomposition temperature of the raw material. Heating is performed while adjusting the heating amount according to the amount and amount, so that efficient and fine temperature control can be performed, and the raw material reaches the decomposition temperature in a short time with the necessary and sufficient heating amount for the input raw material Can be done.
Therefore, not only the entire processing time and the overall length of the apparatus can be reduced, but also the operating cost can be reduced.

【0057】(4)請求項4記載の乾留式分解方法およ
び請求項10記載の乾留式分解装置では、気体成分の分
離を行う部分の周囲に気体成分の分離可能な温度以上に
加熱された加熱ガスを流通させるので、熱伝導性の異な
る2種類の熱媒により安定かつ適度な保温状態を維持で
き、暴走反応を防止することができるとともに、固形成
分からのガス分離率を高めることができる。したがっ
て、分離処理において無駄な加熱量を低減して効率的な
稼働が可能となる。
(4) In the dry distillation method according to the fourth aspect and the dry distillation apparatus according to the tenth aspect, the heating is performed at a temperature higher than the temperature at which the gas component can be separated around the portion where the gas component is separated. Since the gas is circulated, a stable and appropriate heat retaining state can be maintained by two kinds of heat mediums having different thermal conductivities, a runaway reaction can be prevented, and a gas separation rate from a solid component can be increased. Therefore, efficient operation can be achieved by reducing the amount of unnecessary heating in the separation process.

【0058】(5)請求項5記載の乾留式分解方法およ
び請求項11記載の乾留式分解装置では、高温処理後の
気体成分を前記加熱ガスにするので、気体成分をガス分
離用の熱媒として再利用できるとともに、別個の加熱ガ
スの供給源を不要にでき、設備コストおよび稼働コスト
の低減を図ることができる。
(5) In the dry distillation method according to the fifth aspect and the dry distillation apparatus according to the eleventh aspect, since the gas component after the high temperature treatment is used as the heating gas, the gas component is converted into a heat medium for gas separation. And a separate heating gas supply source can be dispensed with, and equipment and operating costs can be reduced.

【0059】(6)請求項6記載の乾留式分解方法およ
び請求項12記載の乾留式分解装置では、加熱炉の燃焼
ガスを前記加熱ガスにするので、使用済みの燃焼ガスを
ガス分離用の熱媒として再利用できるとともに、別個の
加熱ガスの供給源を不要にでき、設備コストおよび稼働
コストの低減を図ることができる。
(6) In the dry distillation method according to the sixth aspect and the dry distillation apparatus according to the twelfth aspect, since the combustion gas in the heating furnace is the heating gas, the used combustion gas is separated for gas separation. It can be reused as a heat medium, and a separate heating gas supply source can be dispensed with, so that equipment costs and operating costs can be reduced.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 本発明に係る乾留式分解方法および装置の第
1実施形態を示す乾留式分解装置の全体構成図である。
FIG. 1 is an overall configuration diagram of a dry distillation apparatus showing a first embodiment of a dry distillation method and apparatus according to the present invention.

【図2】 本発明に係る乾留式分解方法および装置の第
1実施形態における筒状本体内の温度分布を示すグラフ
図である。
FIG. 2 is a graph showing a temperature distribution in a cylindrical main body in the first embodiment of the dry distillation method and apparatus according to the present invention.

【図3】 本発明に係る乾留式分解方法および装置の第
2実施形態を示す乾留式分解装置の全体構成図である。
FIG. 3 is an overall configuration diagram of a dry distillation apparatus showing a second embodiment of a dry distillation method and apparatus according to the present invention.

【図4】 本発明に係る乾留式分解方法および装置の第
2実施形態において、電気ヒータによる加熱量を変えた
場合の筒状本体内の温度分布を示すグラフ図である。
FIG. 4 is a graph showing a temperature distribution in a cylindrical main body when a heating amount by an electric heater is changed in a second embodiment of the dry distillation method and apparatus according to the present invention.

【符号の説明】[Explanation of symbols]

1、21 乾留式分解装置 2 筒状本体 3 移送機構 4 加熱機構 5、22 昇温手段 6、25 分離手段 7 スクリューコンベア 8 駆動モータ 11 オイル用ジャケット(高温油流路) 15 オイル用加熱炉 16、26 ガス用ジャケット(ガス流路) 19 高温処理用加熱炉(高温処理手段) 23 電気ヒータ A 昇温領域(略密閉空間の前段) B 分離領域(略密閉空間の後段) G 燃焼ガス(加熱ガス) H ホットオイル(高温油) R 原料 DESCRIPTION OF SYMBOLS 1, 21 Dry distillation type decomposition apparatus 2 Cylindrical main body 3 Transfer mechanism 4 Heating mechanism 5, 22 Heating means 6, 25 Separation means 7 Screw conveyor 8 Drive motor 11 Oil jacket (high-temperature oil flow path) 15 Oil heating furnace 16 , 26 Gas jacket (gas flow path) 19 Heating furnace for high-temperature processing (high-temperature processing means) 23 Electric heater A Heating area (previous to substantially enclosed space) B Separation area (subsequent to substantially enclosed space) G Combustion gas (heating) Gas) H Hot oil (High temperature oil) R Raw material

Claims (12)

【特許請求の範囲】[Claims] 【請求項1】 石油系化合物からなる原料(R)を略密
閉空間で熱分解させて固形成分と気体成分とに分離する
乾留式分解方法において、 前記略密閉空間の前段(A)に投入された前記原料を前
段から後段(B)に向けて粉砕しながら移送する移送工
程と、 該移送工程中に前記略密閉空間を加熱して前記原料を熱
分解させる加熱工程とを備え、 該加熱工程は、前記略密閉空間の前段で前記原料を分解
可能な温度まで加熱する昇温工程と、 前記略密閉空間の後段で前記気体成分が前記固形成分か
らほぼ完全に分離するまで気体成分の分離可能な温度で
保温する分離工程とを備え、 該昇温工程は、前記分離工程に比べて単位時間当たりの
加熱量を大きく設定していることを特徴とする乾留式分
解方法。
In a dry distillation cracking method in which a raw material (R) composed of a petroleum compound is thermally decomposed in a substantially closed space to separate it into a solid component and a gas component, the raw material (R) is introduced into the former stage (A) of the substantially closed space. A transfer step of transferring the raw material while pulverizing the raw material from the former stage to the latter stage (B); and a heating step of heating the substantially enclosed space to thermally decompose the raw material during the transfer step. A heating step in which the raw material is heated to a temperature at which the raw material can be decomposed at a stage preceding the substantially enclosed space; and a gas component can be separated at a stage subsequent to the substantially enclosed space until the gas component is almost completely separated from the solid component. A separation step of keeping the temperature at a suitable temperature, wherein the heating step sets a larger amount of heating per unit time than the separation step.
【請求項2】 請求項1記載の乾留式分解方法におい
て、 前記昇温工程は、前記略密閉空間の前段の周囲に前記原
料を分解可能な温度以上に加熱された高温油(H)を流
通させることを特徴とする乾留式分解方法。
2. The dry distillation method according to claim 1, wherein in the heating step, high-temperature oil (H) heated to a temperature at which the raw material can be decomposed or higher is distributed around a front stage of the substantially enclosed space. A carbonization-type decomposition method characterized in that:
【請求項3】 請求項1記載の乾留式分解方法におい
て、 前記昇温工程は、前記略密閉空間の前段の周囲に配した
電気ヒータ(23)により前記原料の成分および量に応
じて加熱量を調整しながら加熱することを特徴とする乾
留式分解方法。
3. The dry distillation method according to claim 1, wherein in the heating step, an electric heater (23) arranged around a front stage of the substantially enclosed space heats the heat according to the component and amount of the raw material. A carbonization-type decomposition method characterized by heating while adjusting the temperature.
【請求項4】 請求項1から3のいずれかに記載の乾留
式分解方法において、 前記分離工程は、前記略密閉空間の後段(B)の周囲に
前記気体成分の分離可能な温度以上に加熱された加熱ガ
ス(G)を流通させることを特徴とする乾留式分解方
法。
4. The dry distillation method according to claim 1, wherein the separation step comprises heating the gas component around a rear stage (B) of the substantially enclosed space to a temperature at which the gas component can be separated. A dry distillation cracking method characterized by flowing a heated gas (G).
【請求項5】 請求項4記載の乾留式分解方法におい
て、 前記分離工程で分離した前記気体成分を再加熱して含ま
れる塩素成分を分解除去する高温処理工程を備え、 前記分離工程は、前記高温処理工程後の前記気体成分を
前記加熱ガスにすることを特徴とする乾留式分解方法。
5. The dry distillation method according to claim 4, further comprising a high-temperature treatment step of reheating the gas component separated in the separation step to decompose and remove a chlorine component contained therein. A dry distillation decomposition method, wherein the gas component after the high-temperature treatment step is used as the heating gas.
【請求項6】 請求項4記載の乾留式分解方法におい
て、 前記昇温工程で使用する前記高温油(H)または前記分
離工程で分離した前記気体成分を、加熱炉内で燃焼ガス
(G)で加熱する工程を備え、 前記分離工程は、前記加熱炉の燃焼ガスを前記加熱ガス
にすることを特徴とする乾留式分解方法。
6. The dry distillation method according to claim 4, wherein the high-temperature oil (H) used in the heating step or the gas component separated in the separation step is subjected to combustion gas (G) in a heating furnace. Wherein the separation step comprises using the combustion gas of the heating furnace as the heating gas.
【請求項7】 石油系化合物からなる原料(R)を内部
が略密閉な筒状本体(2)内で熱分解させて固形成分と
気体成分とに分離する乾留式分解装置(1)において、 前記筒状本体内の前段(A)に投入された前記原料を前
段から後段(B)に向けて移送する移送機構(3)と、 前記筒状本体内を加熱して前記原料を熱分解させる加熱
機構(4)とを備え、 前記加熱機構は、前記筒状本体内の前段で前記原料を分
解可能な温度まで加熱する昇温手段(5)と、 前記筒状本体内の後段で前記気体成分が前記固形成分か
らほぼ完全に分離するまで気体成分の分離可能な温度で
保温する分離手段(6)とを備え、 前記昇温手段は、前記分離手段に比べて単位時間当たり
の加熱量が大きく設定されていることを特徴とする乾留
式分解装置。
7. A dry distillation cracker (1) for thermally decomposing a raw material (R) made of a petroleum compound in a substantially closed cylindrical body (2) to separate it into a solid component and a gas component. A transfer mechanism (3) for transferring the raw material supplied to the former stage (A) in the tubular main body from the former stage to the latter stage (B); and heating the inside of the cylindrical main body to thermally decompose the raw material. A heating mechanism (5) for heating the raw material to a temperature at which the raw material can be decomposed at a preceding stage in the tubular main body; and a gas at a subsequent stage in the tubular main body. Separating means (6) for keeping the temperature of the gas component at a temperature at which the gas component can be separated until the component is substantially completely separated from the solid component, wherein the heating means has a heating amount per unit time compared to the separating means. A dry distillation cracker characterized by being set large.
【請求項8】 請求項7記載の乾留式分解装置におい
て、 前記昇温手段は、前記筒状本体の前段の周壁に前記原料
を分解可能な温度以上に加熱された高温油(H)を流通
させる高温油流路(11)を備えていることを特徴とす
る乾留式分解装置。
8. The dry distillation apparatus according to claim 7, wherein the heating means distributes high-temperature oil (H) heated to a temperature at which the raw material can be decomposed or more to a peripheral wall in a preceding stage of the tubular main body. A dry distillation cracking device comprising a high-temperature oil flow path (11) for causing a cracking.
【請求項9】 請求項7記載の乾留式分解装置におい
て、 前記昇温手段は、前記筒状本体の前段の周壁に前記原料
の成分および量に応じて加熱量が調整可能な電気ヒータ
(23)を備えていることを特徴とする乾留式分解装
置。
9. The dry distillation apparatus according to claim 7, wherein the temperature raising means comprises an electric heater (23) having a heating amount adjustable on a peripheral wall at a preceding stage of the cylindrical main body in accordance with a component and an amount of the raw material. ).
【請求項10】 請求項7から9のいずれかに記載の乾
留式分解装置において、 前記分離手段は、前記筒状本体の後段(B)の周壁に前
記気体成分の分離可能な温度以上に加熱された加熱ガス
(G)を流通させるガス流路(16、26)を備えてい
ることを特徴とする乾留式分解装置。
10. The dry distillation apparatus according to any one of claims 7 to 9, wherein the separation means heats the peripheral wall of a rear stage (B) of the tubular main body to a temperature higher than a temperature at which the gas component can be separated. A dry distillation cracking device comprising a gas flow path (16, 26) for flowing the heated gas (G).
【請求項11】 請求項10記載の乾留式分解装置にお
いて、 前記加熱手段で分離した前記気体成分を再加熱して含ま
れる塩素成分を分解除去する高温処理手段(19)を備
え、 前記分離手段は、前記高温処理手段で再加熱された前記
気体成分を前記加熱ガスにして前記ガス流路(26)に
流通させることを特徴とする乾留式分解装置。
11. The dry distillation apparatus according to claim 10, further comprising a high-temperature processing unit (19) for reheating the gas component separated by the heating unit to decompose and remove a chlorine component contained therein, and the separation unit. Wherein the gas component reheated by the high-temperature processing means is converted into the heating gas and passed through the gas flow path (26).
【請求項12】 請求項10記載の乾留式分解装置にお
いて、 前記昇温手段(5)で使用する前記高温油(H)または
前記分離手段(6)で分離した前記気体成分を燃焼ガス
(G)で加熱する加熱炉(15、19)を備え、 前記分離手段は、前記加熱炉の燃焼ガスを前記加熱ガス
にして前記ガス流路(16)に流通させることを特徴と
する乾留式分解装置。
12. The dry distillation cracking apparatus according to claim 10, wherein the high-temperature oil (H) used in the temperature raising means (5) or the gas component separated by the separation means (6) is subjected to combustion gas (G). ), Wherein the separating means converts the combustion gas of the heating furnace into the heating gas and circulates the gas through the gas flow path (16). .
JP6556499A 1999-03-11 1999-03-11 Dry distillation type decomposition method and apparatus Expired - Fee Related JP4038925B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6556499A JP4038925B2 (en) 1999-03-11 1999-03-11 Dry distillation type decomposition method and apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6556499A JP4038925B2 (en) 1999-03-11 1999-03-11 Dry distillation type decomposition method and apparatus

Publications (2)

Publication Number Publication Date
JP2000265173A true JP2000265173A (en) 2000-09-26
JP4038925B2 JP4038925B2 (en) 2008-01-30

Family

ID=13290646

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6556499A Expired - Fee Related JP4038925B2 (en) 1999-03-11 1999-03-11 Dry distillation type decomposition method and apparatus

Country Status (1)

Country Link
JP (1) JP4038925B2 (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4840879A (en) * 1971-09-27 1973-06-15
JPS4875680A (en) * 1972-01-12 1973-10-12
JPS60113351U (en) * 1974-05-06 1985-07-31 レツドカー‐ヤング プロセシズ、インコーポレーテツド Carbonization equipment for organic waste materials
JPH05245463A (en) * 1991-10-18 1993-09-24 Agency Of Ind Science & Technol Treatment of mixed plastic waste and device therefor
JPH06116564A (en) * 1992-10-08 1994-04-26 Shin Meiwa Ind Co Ltd Method for carbonization and apparatus for carbonization
JPH08104880A (en) * 1994-09-12 1996-04-23 Seisei Kogyo Kk Treating method for dry distillation for reaped lawn grass and treating device therefor

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4840879A (en) * 1971-09-27 1973-06-15
JPS4875680A (en) * 1972-01-12 1973-10-12
JPS60113351U (en) * 1974-05-06 1985-07-31 レツドカー‐ヤング プロセシズ、インコーポレーテツド Carbonization equipment for organic waste materials
JPS6321544Y2 (en) * 1974-05-06 1988-06-14
JPH05245463A (en) * 1991-10-18 1993-09-24 Agency Of Ind Science & Technol Treatment of mixed plastic waste and device therefor
JPH06116564A (en) * 1992-10-08 1994-04-26 Shin Meiwa Ind Co Ltd Method for carbonization and apparatus for carbonization
JPH08104880A (en) * 1994-09-12 1996-04-23 Seisei Kogyo Kk Treating method for dry distillation for reaped lawn grass and treating device therefor

Also Published As

Publication number Publication date
JP4038925B2 (en) 2008-01-30

Similar Documents

Publication Publication Date Title
EP2059575B1 (en) Reactor and apparatus for pyrolyzing waste, especially tyre
JPH03291331A (en) Scrap iron preheating method by recovering all of energy of resinous residue contained in scrap iron and by thermally decomposing said resinous residue while improving steel producing cycle
EP1799792A2 (en) Pyrolysis machine
CN104923556B (en) For the thermal desorption firing equipment that oil-contaminated soil is repaired
US20220034505A1 (en) Pyrolysis system and method of use
WO2017209638A1 (en) Method and installation for thermochemical conversion of raw material containing organic compounds
JP2001300497A (en) Apparatus and method for treating waste
JP2001200093A (en) Waste plastic treating equipment
JP2000265173A (en) Method and system for dry distillation-type cracking
JPH0913045A (en) Liquefaction apparatus for plastic waste
JP3096448B2 (en) Waste plastic decomposition equipment
JP4633216B2 (en) Carbonization method with screw-type carbonization furnace
WO2019033202A1 (en) Hybrid processing of waste material
JP2005103437A (en) Processing method of organic material containing water and its facility
JPH06256769A (en) Continuous apparatus for converting rubber-plastic waste into oil
JP2003262315A (en) Heat treatment method and facility for water containing organic matter
JP4352596B2 (en) Indirect heat treatment method for workpieces
JP2001201026A (en) Thermal cracking furnace device
JPH1129774A (en) Pyrolysis reactor for waste plastic
JPH08208210A (en) Production of graphite powder and production unit therefor
JP3110018B2 (en) Continuous waste treatment equipment
JP2002001285A (en) Method, apparatus and equipment for heat-treating matter to be treated containing combustible component
JPH04256485A (en) Method for continuous melting of residual substance
WO2024048618A1 (en) Pyrolyzer
CN114907868B (en) Thermal decomposition method and thermal decomposition device

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20060222

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20070706

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20070717

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20070918

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20071016

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20071029

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20101116

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20101116

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111116

Year of fee payment: 4

LAPS Cancellation because of no payment of annual fees