JP2000264024A - Spike pin for spike tire - Google Patents

Spike pin for spike tire

Info

Publication number
JP2000264024A
JP2000264024A JP11070084A JP7008499A JP2000264024A JP 2000264024 A JP2000264024 A JP 2000264024A JP 11070084 A JP11070084 A JP 11070084A JP 7008499 A JP7008499 A JP 7008499A JP 2000264024 A JP2000264024 A JP 2000264024A
Authority
JP
Japan
Prior art keywords
spike
spike pin
vickers hardness
pin
tire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11070084A
Other languages
Japanese (ja)
Other versions
JP4124534B2 (en
Inventor
Yoichi Yamaguchi
洋一 山口
Shigeru Shinoda
茂 篠田
Kazuo Horikirigawa
一男 堀切川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yokohama Rubber Co Ltd
Original Assignee
Yokohama Rubber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yokohama Rubber Co Ltd filed Critical Yokohama Rubber Co Ltd
Priority to JP07008499A priority Critical patent/JP4124534B2/en
Publication of JP2000264024A publication Critical patent/JP2000264024A/en
Application granted granted Critical
Publication of JP4124534B2 publication Critical patent/JP4124534B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Tires In General (AREA)
  • Ceramic Products (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

PROBLEM TO BE SOLVED: To improve the performance of a tire with its spike pin on ice by forming a hardened porous carbon material having the specific Vickers hardness in which chipped vegetable raw materials are impregnated in a thermosetting resin and heat treated at high temperature into carbonize to obtain the spike pins for a spike tire. SOLUTION: A hardened porous carbon material in which chipped vegetable raw materials such as rice bran and chipped wooden materials are impregnated in a thermosetting resin, and heat treated at high temperature into carbon, is formed to obtain a spike pin of 30-1500 in Vickers hardness. This spike pin is lower in hardness than an asphalt road surface of 1000-1500 in Vickers hardness, but higher in hardness than ice of 30 or under in Vickers hardness so that brake performance on an icy road surface can be improved. Though the braking performance on ice is equivalent to that of a conventional metal spike pin formed of steel or iron, the durability is equivalent to and larger than that of the metal spike pin due to the excellent wear resistance of the hardened porous carbon material.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明はスパイクタイヤ用ス
パイクピンに関し、更に詳しくは氷路面上でのタイヤ性
能が良好で走行時の粉塵発生を抑制し、そして耐摩耗性
及び耐久性に優れたスパイクタイヤ用スパイクピンに関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a spike pin for a spike tire, and more particularly, to a spike pin having good tire performance on an icy road surface, suppressing generation of dust during running, and having excellent wear resistance and durability. The present invention relates to a spike pin for a tire.

【0002】[0002]

【従来の技術】従来スパイクタイヤ用スパイクピンとし
ては、金属、超硬合金、粉塵、硬質プラスチックなどが
使用されているが、金属を使用した場合には走行時に路
面が削られて粉塵を発生させるという問題があり、また
プラスチックの場合には耐久性に難点があるという問題
があった。
2. Description of the Related Art Metals, cemented carbides, dust, hard plastics and the like are conventionally used as spike pins for spiked tires. However, when metal is used, the road surface is shaved during traveling to generate dust. In the case of plastic, there is a problem that durability is difficult.

【0003】[0003]

【発明が解決しようとする課題】従って、本発明の目的
は、前記した従来技術の問題点を克服し、氷上でのタイ
ヤ性能が良好で、走行時の粉塵発生を抑制し、そして耐
摩耗性及び耐久性に優れたスパイクタイヤ用スパイクピ
ンを提供することにある。
SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to overcome the above-mentioned problems of the prior art, to provide good tire performance on ice, to suppress generation of dust during running, and to improve wear resistance. Another object of the present invention is to provide a spike pin for a spike tire having excellent durability.

【0004】[0004]

【課題を解決するための手段】本発明に従えば、細分し
た植物系原料に熱硬化性樹脂を含浸し、高温で熱処理を
して炭素化させて得られるビッカース硬度が30〜15
00の硬質多孔性炭素材料を成型して成るスパイクタイ
ヤ用スパイクピンが提供される。
According to the present invention, a Vickers hardness obtained by impregnating a finely divided plant material with a thermosetting resin and heat-treating it at a high temperature to carbonize it is 30 to 15%.
No. 00 is provided.

【0005】[0005]

【発明の実施の形態】本発明者らは、細分した植物系原
料、たとえば米ぬかや細分した木質材料などに熱硬化性
樹脂を含浸し、高温で熱処理して炭素化させた硬質多孔
性炭素材料を成型したスパイクピンは、熱硬化性樹脂の
配合量及び処理温度によりピンの硬さを広範囲に亘って
調整することができることを見い出した。更に、本発明
で用いる植物系原料は、細分した状態、例えば、粉状、
細片状で用いるため、スパイクピンの成型に際し、金型
に入れて成型したり、押出し、切削、研磨などの加工に
よる製造が極めて容易に行えるため、様々な形状のスパ
イクピンを容易に製造することができる。
BEST MODE FOR CARRYING OUT THE INVENTION The present inventors have developed a hard porous carbon material obtained by impregnating a plant material such as rice bran or wood material which has been finely divided with a thermosetting resin and heat-treating it at a high temperature to carbonize it. Was found that the hardness of the spike pin can be adjusted over a wide range depending on the blending amount of the thermosetting resin and the processing temperature. Furthermore, the plant-based raw material used in the present invention is in a finely divided state, for example, powdery,
Since it is used in the form of strips, spike pins can be molded in a mold, extruded, cut, polished, etc., so that spike pins of various shapes can be easily manufactured. be able to.

【0006】本発明に従った植物系原料によるスパイク
ピンはビッカース硬度1000〜1500のアスファル
ト路面よりも硬度が低く、ビッカース硬度が30以下の
氷よりは硬度が高いために、タイヤ走行時に粉塵を発生
させることなく、氷路面上での制動性能を改善すること
ができる。一方、氷上での制動性能は従来の鋼鉄などの
金属製スパイクピンと同等であるが、耐久性は植物系原
料から得られる硬質多孔性炭素材料の優れた耐摩耗性に
より金属製スパイクピンと同等以上である。
[0006] The spike pin made of a plant-based material according to the present invention has a lower hardness than an asphalt road surface having a Vickers hardness of 1000 to 1500, and has a higher hardness than ice having a Vickers hardness of 30 or less. It is possible to improve the braking performance on an icy road without causing the braking. On the other hand, braking performance on ice is equivalent to that of conventional metal spike pins such as steel, but durability is equal to or higher than that of metal spike pins due to the excellent wear resistance of hard porous carbon materials obtained from plant-based materials. is there.

【0007】本発明によれば、使用する熱硬化性樹脂の
配合量と熱処理温度(焼成温度)を調整することでビッ
カース硬度を、アスファルト路面より柔らかく、氷路面
より硬い硬度である、30〜1500の広い範囲、好ま
しくは200〜1000で調整することができる。しか
も本発明に従ってスパイクピン用の材料は75重量%程
度は天然素材であるため、人体などの環境への影響が従
来の金属やプラスチック性スパイクピンより少ないエコ
マテリアルであるという特長も有する。
According to the present invention, by adjusting the amount of the thermosetting resin used and the heat treatment temperature (firing temperature), the Vickers hardness is 30 to 1500, which is softer than the asphalt road surface and harder than the icy road surface. Can be adjusted in a wide range, preferably 200 to 1000. In addition, according to the present invention, since about 75% by weight of the spike pin material is a natural material, the spike pin is also an eco-material that has less influence on the environment such as the human body than conventional metal or plastic spike pins.

【0008】本発明に係るスパイクピンの成型に使用さ
れる特定のビッカース硬度を有する硬質多孔性炭素材料
は、例えば脱脂した米ぬかや木材粉をフェノール樹脂、
ユリア樹脂、メラミン樹脂などの熱硬化性樹脂を含浸さ
せた後、高温で焼成して炭素化させることによって得ら
れるもので、例えばフェノール樹脂を含浸させたものは
窒素雰囲気下で700〜1100℃で焼成することによ
り硬質の多孔質炭化粒子を得ることができる。好ましい
硬質多孔性炭素材料の代表平均粒径は50〜500μm
で、硬度はビッカース硬さで平均30〜1500、好ま
しくは200〜1000である。
[0008] The hard porous carbon material having a specific Vickers hardness used for molding the spike pin according to the present invention includes, for example, defatted rice bran or wood powder,
After being impregnated with a thermosetting resin such as urea resin or melamine resin, it is obtained by firing at a high temperature and carbonizing. For example, a resin impregnated with a phenol resin is heated at 700 to 1100 ° C. under a nitrogen atmosphere. By firing, hard porous carbonized particles can be obtained. The typical average particle size of the preferred hard porous carbon material is 50 to 500 μm.
The average hardness of the Vickers hardness is 30 to 1500, preferably 200 to 1000.

【0009】本発明に従ったスパイクピンは従前のスパ
イクピンと同様にしてタイヤトレッド部に装着すること
ができ、粉塵の発生を効果的に防止することができると
共に耐久性に優れるという効果を得ることができる。
[0009] The spike pin according to the present invention can be mounted on the tire tread in the same manner as the conventional spike pin, and it is possible to effectively prevent the generation of dust and obtain the effect of having excellent durability. Can be.

【0010】[0010]

【実施例】以下、実施例によって本発明を更に説明する
が、本発明の範囲をこれらの実施例に限定するものでな
いことは言うまでもない。
EXAMPLES The present invention will be further described with reference to the following examples, but it goes without saying that the scope of the present invention is not limited to these examples.

【0011】実施例1及び比較例1〜3 表Iに示すように、本発明に従った硬度の硬質多孔性材
料であるRBセラミックスを用いたスパイクピン(実施
例1)と、従来の超硬質合金を用いたスパイクピン(比
較例1)並びに本発明で用いるのと同じ材料であるがビ
ッカース硬度の値が本発明の範囲外の材料を用いたスパ
イクピン(比較例2及び3)とを常法に従って作製し、
タイヤトレッド部に取り付けて、以下の方法で、その路
面の摩耗性、氷上制動性能及びピンの寿命について評価
した。結果を表Iに示す。
Example 1 and Comparative Examples 1 to 3 As shown in Table I, a spike pin (Example 1) using RB ceramics, which is a hard porous material having a hardness according to the present invention, and a conventional super hard A spike pin using an alloy (Comparative Example 1) and a spike pin using the same material as used in the present invention but having a Vickers hardness value outside the range of the present invention (Comparative Examples 2 and 3) were always used. Made according to the method,
Attached to the tire tread portion, the following methods were used to evaluate the wear property of the road surface, braking performance on ice, and the life of the pin. The results are shown in Table I.

【0012】評価方法 1)路面の摩耗…乾燥アスファルト路面上を滑らせ、粉
塵発生量が金属スパイクピン程度の場合を×とし、粉塵
発生量の減少により順に△、○とした。 2)氷上性能…初速度40km/hrでロック制動し、制動
距離が金属スパイク程度の場合を○、制動距離の増加に
より順に△、×とした。 3)ピンの寿命…一定距離(2000km)を走行し、初
期のピン長さからの変化の小さいものを○とし、ピンの
摩耗の増加に従い順に△、×とした。
Evaluation method 1) Abrasion of the road surface: Slip on the dry asphalt road surface, and the case where the amount of dust generation was about metal spike pins was evaluated as x, and the decrease in the amount of generated dust was evaluated as Δ and ○ in order. 2) Performance on ice: Lock braking was performed at an initial speed of 40 km / hr, and when the braking distance was about a metal spike, ○ was given, and Δ and × were given in order of increasing braking distance. 3) Pin life: The vehicle traveled for a fixed distance (2000 km), and the one with a small change from the initial pin length was marked with ○, and Δ and × were sequentially determined according to the increase in pin wear.

【0013】[0013]

【表1】 [Table 1]

【0014】[0014]

【発明の効果】表Iに示した結果からも明らかな通り、
本発明に従えば、米ぬかや木材粉などの細分した植物系
原料に熱硬化性樹脂を含浸し、熱処理した硬質多孔性炭
素材料を用いてタイヤ用スパイクピンを構成するので、
スパイクピンの硬度を広範囲で制御することができ、ス
パイクピンの氷上でのタイヤ性能を改善し、粉塵発生を
抑制することができ、更に耐久性、寿命を向上させるこ
とができる。
As is clear from the results shown in Table I,
According to the present invention, a thermosetting resin is impregnated into a finely divided plant material such as rice bran or wood powder, and a spike pin for a tire is formed using a heat-treated hard porous carbon material.
The hardness of the spike pin can be controlled in a wide range, the tire performance of the spike pin on ice can be improved, the generation of dust can be suppressed, and the durability and life can be further improved.

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4G032 AA12 BA00 GA09 GA11 4G046 CA00 CB02 CB05 CB08 CC01 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4G032 AA12 BA00 GA09 GA11 4G046 CA00 CB02 CB05 CB08 CC01

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 細分した植物系原料に熱硬化性樹脂を含
浸し、高温で熱処理をして炭素化させて得られるビッカ
ース硬度が30〜1500の硬質多孔性炭素材料を成型
して成るスパイクタイヤ用スパイクピン。
1. A spike tire formed by impregnating a thermosetting resin into a finely divided plant-based material and heat-treating it at a high temperature to carbonize, thereby forming a hard porous carbon material having a Vickers hardness of 30 to 1500. For spike pins.
JP07008499A 1999-03-16 1999-03-16 Spike pin for spike tire Expired - Fee Related JP4124534B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP07008499A JP4124534B2 (en) 1999-03-16 1999-03-16 Spike pin for spike tire

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP07008499A JP4124534B2 (en) 1999-03-16 1999-03-16 Spike pin for spike tire

Publications (2)

Publication Number Publication Date
JP2000264024A true JP2000264024A (en) 2000-09-26
JP4124534B2 JP4124534B2 (en) 2008-07-23

Family

ID=13421332

Family Applications (1)

Application Number Title Priority Date Filing Date
JP07008499A Expired - Fee Related JP4124534B2 (en) 1999-03-16 1999-03-16 Spike pin for spike tire

Country Status (1)

Country Link
JP (1) JP4124534B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014214269A (en) * 2013-04-26 2014-11-17 旭化成ケミカルズ株式会社 Composition of modified conjugated diene polymer

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014214269A (en) * 2013-04-26 2014-11-17 旭化成ケミカルズ株式会社 Composition of modified conjugated diene polymer

Also Published As

Publication number Publication date
JP4124534B2 (en) 2008-07-23

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