JP2000226419A5 - - Google Patents
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- JP2000226419A5 JP2000226419A5 JP1999289351A JP28935199A JP2000226419A5 JP 2000226419 A5 JP2000226419 A5 JP 2000226419A5 JP 1999289351 A JP1999289351 A JP 1999289351A JP 28935199 A JP28935199 A JP 28935199A JP 2000226419 A5 JP2000226419 A5 JP 2000226419A5
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- JP
- Japan
- Prior art keywords
- group
- polyoxyethylene
- general formula
- polymer
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920000642 polymer Polymers 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 230000003699 hair surface Effects 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- -1 polyoxyethylene group Polymers 0.000 description 19
- 125000000217 alkyl group Chemical group 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 125000002252 acyl group Chemical group 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 2
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
Description
【００１１】
（２）本発明の高分子に使用される一般式（ＩＩ）に表される化合物
本発明の高分子は、一般式（ＩＩ）に表される化合物を構成モノマーとして含有することを特徴とする。 ここで、式中Ｒ３は水素原子又は炭素数１〜４のアルキル基を表し、Ｒ４はアルキルオキシ基、アシロキシ基又は水酸基を有していても良い、炭素数２〜４のアルキル基を表し、Ｒ５は水素原子、芳香族乃至は脂肪族の炭素数１〜８の炭化水素基又はアシル基を表し、ｎは１〜４０の数値を表す。Ｒ３としては、水素原子又はメチル基であることが特に好ましい。これは、高分子などで汎用されているアクリル酸或いはメタクリル酸の構造であり、安全性などが多くのものについて既に確認されているし、原料として、市販品も多く入手がた易いためである。Ｒ４はポリオキシエチレン基、ポリオキシプロピレン基、ポリオキシブテン基、ポリオキシ（ヒドロキシプロピレン）基、その１部又は全部のアシル化物、アルキルエーテル等が例示できる。アシル基としてはアセチル基、ベンゾイル基、ステアロイル基、オレオイル基等の炭素数１〜２０のものが好ましく例示でき、アルキル基としては炭素数１〜４のアルキル基が好ましく例示できる。これらの中では、ポリオキシエチレン基であることが好ましい。この末端の水酸基はフリーのままでも良いし、アシル基やアルキル基で封鎖することも可能である。この様なアシル基としては、アセチル基、ベンゾイル基、アクリロイル基、メタクリロイル基等が好ましく例示でき、アルキル基としては炭素数１〜４のものが好ましく例示できる。好ましいＲ４の基としてはメチルポリオキシエチレン（９）基、メチルポリオキシエチレン（２３）基、メトキシエチル基、３−メトキシブチル基、エチルポリオキシエチレン（２）基、フェノキシチル基、フェニルポリオキシエチレン（２）基、メチルポリオキシエチレン（３）基、アクリルポリオキシエチレン（４）基、アクリルポリオキシプロピレン（３）基、アクリルポリオキシプロピレン（７）基等が好ましく例示できる。この様な一般式（ＩＩ）に表される化合物としては、一般式（ＩＶ）に表されるものが特に好ましい。本発明の高分子中に構成モノマーとして一般式（ＩＩ）に表される化合物が含有される割合は、１分子中の総量の平均重量百分率で、３０〜９０．５重量％、更に好ましくは４０〜９０．１重量％
である。これは、本発明の高分子の水への溶解性が、この一般式（ＩＩ）に表される構成部分によるため、少なすぎると高分子の水への溶解性が阻害されることがあり、多すぎると形成された被膜の耐水性が損なわれることがあるためである。[0011]
(2) Compound Represented by General Formula (II) Used in Polymer of the Present Invention The polymer of the present invention is characterized by containing the compound represented by General Formula (II) as a constituent monomer. . Here, in the formula, R 3 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R 4 represents an alkyl group having 2 to 4 carbon atoms which may have an alkyloxy group, an acyloxy group or a hydroxyl group, R5 represents a hydrogen atom, an aromatic to aliphatic hydrocarbon group having 1 to 8 carbon atoms, or an acyl group, and n represents a numerical value of 1 to 40. As R 3, a hydrogen atom or a methyl group is particularly preferable. This is the structure of acrylic acid or methacrylic acid that is widely used for polymers etc., and safety has been confirmed for many things, and many commercial products are easily obtained as raw materials. . R4 can be exemplified by a polyoxyethylene group, a polyoxypropylene group, a polyoxybutene group, a polyoxy (hydroxypropylene) group, an acylated product of one part or all thereof, an alkyl ether and the like. Preferred examples of the acyl group include those having 1 to 20 carbon atoms such as acetyl, benzoyl, stearoyl and oleoyl groups, and preferred examples of the alkyl group include alkyl groups having 1 to 4 carbons. Among these, a polyoxyethylene group is preferable. The terminal hydroxyl group may remain free or may be blocked with an acyl group or an alkyl group. As such an acyl group, an acetyl group, a benzoyl group, an acryloyl group, a methacryloyl group etc. can be illustrated preferably, and a C1-C4 thing can preferably be illustrated as an alkyl group. Preferred groups of R 4 are methyl polyoxyethylene (9) group, methyl polyoxyethylene (23) group, methoxyethyl group, 3-methoxybutyl group, ethyl polyoxyethylene (2) group, phenoxyl group, phenyl polyoxy Preferred examples are ethylene (2) group, methyl polyoxyethylene (3) group, acryl polyoxyethylene (4) group, acryl polyoxypropylene (3) group, acryl polyoxypropylene (7) group and the like. As a compound represented by such general formula (II), what is represented by general formula (IV) is especially preferable. Ratio of the compound represented by the general formula (II) as a constituent monomer in the polymer of the present invention is contained in an average weight percentage of the total amount in one molecule, from 30 to 90.5 wt%, more preferably 40 90.1% by weight
It is. This is because the solubility of the polymer of the present invention in water is due to the component represented by the general formula (II), so too little of the solubility of the polymer in water may be inhibited. If the amount is too large, the water resistance of the formed film may be impaired.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11289351A JP2000226419A (en) | 1998-11-30 | 1999-10-12 | Copolymer for surface modification |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10-355377 | 1998-11-30 | ||
| JP35537798 | 1998-11-30 | ||
| JP11289351A JP2000226419A (en) | 1998-11-30 | 1999-10-12 | Copolymer for surface modification |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000226419A JP2000226419A (en) | 2000-08-15 |
| JP2000226419A5 true JP2000226419A5 (en) | 2004-11-04 |
Family
ID=26557569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11289351A Withdrawn JP2000226419A (en) | 1998-11-30 | 1999-10-12 | Copolymer for surface modification |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000226419A (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100413800B1 (en) | 2001-10-17 | 2004-01-03 | 삼성에스디아이 주식회사 | Fluoride copolymer, polymer electrolyte comprising the same and lithium battery employing the polymer electrolyte |
| JP4238164B2 (en) * | 2004-03-22 | 2009-03-11 | ポーラ化成工業株式会社 | Cosmetics |
| WO2007016105A2 (en) * | 2005-07-26 | 2007-02-08 | Rhodia Inc. | Polymers with pendant poly(alkyleneoxy) substituent groups and their use in personal care applications |
| JP2007269642A (en) * | 2006-03-30 | 2007-10-18 | Daikin Ind Ltd | Cosmetic containing fluoroacrylate polymer |
| ES2546275T3 (en) * | 2008-03-31 | 2015-09-22 | Daikin Industries, Ltd. | Fluorine-containing copolymer, paper processing agent, and coating film forming agent for cosmetic preparation |
| MX2011006738A (en) * | 2008-12-23 | 2011-07-13 | Du Pont | (meth)acrylic esters of poly(trimethylene ether) glycol and uses thereof. |
| JP2011032207A (en) * | 2009-07-31 | 2011-02-17 | Miyoshi Kasei Inc | Cosmetic preparation in which fluorine-containing copolymer is blended |
| JP6061520B2 (en) * | 2012-06-29 | 2017-01-18 | ポーラ化成工業株式会社 | Water-soluble copolymer |
| KR102260329B1 (en) * | 2019-08-05 | 2021-06-02 | 주식회사 엘지생활건강 | Film-forming Polymer Having Excellent Water- and Oil-repellent Properties, and Long Wear Cosmetic Composition Comprising the Same |
-
1999
- 1999-10-12 JP JP11289351A patent/JP2000226419A/en not_active Withdrawn
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