JP2000210669A - Treatment of car washing waste water and device - Google Patents

Treatment of car washing waste water and device

Info

Publication number
JP2000210669A
JP2000210669A JP11014182A JP1418299A JP2000210669A JP 2000210669 A JP2000210669 A JP 2000210669A JP 11014182 A JP11014182 A JP 11014182A JP 1418299 A JP1418299 A JP 1418299A JP 2000210669 A JP2000210669 A JP 2000210669A
Authority
JP
Japan
Prior art keywords
water
wastewater
electrode reaction
waste water
car wash
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11014182A
Other languages
Japanese (ja)
Inventor
Masaru Onoda
勝 小野田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KYOWA SENPAKU KOGYO KK
Original Assignee
KYOWA SENPAKU KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KYOWA SENPAKU KOGYO KK filed Critical KYOWA SENPAKU KOGYO KK
Priority to JP11014182A priority Critical patent/JP2000210669A/en
Publication of JP2000210669A publication Critical patent/JP2000210669A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide a treating method and its inexpensive device for car wash ing water which is capable of purifying the water to the degree capable of being reused as car washing water, and which is expected to be used widely by a gasoline stations, etc. SOLUTION: The earth and sand in the car washing water is settled and separated in a settling and separating tank 1, then the waste water is sent to an electrolytic cell 5. Electrode reaction at the interface between an anode, a cathode and the waste water as well as the secondary reaction in which the product by the electrode reaction is allowed to react with the component in the waste water are executed compositely. The component in the waste water is oxidized, reduced, decomposed and settled by the electrode reaction. The settling, adsorption, condensation and floatation of the component in the waste water occurs in the secondary reaction. The treated water from which a suspended substance is separated and removed is subjected to filtering to separate the suspended substance by a precision filter device 8 and sent to a water storage tank 11.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明が属する技術分野】本発明は、洗車廃水の処理方
法および装置に関するものである。
The present invention relates to a method and an apparatus for treating car wash wastewater.

【0002】[0002]

【従来の技術】一般に、ガソリンスタンドなどでは門型
装置による洗車・高圧水噴射・ブラシかけおよびワック
スかけ等の作業が自動連続して行われている。また、コ
イン洗車場などにおいても上記洗車作業などが手作業で
行われている。これらの洗車作業により、大量の洗車廃
水が発生する。従来、洗車廃水はそのまま下水道に排水
されていたり、例えば、浮上分離方式のオイルトラップ
などの簡易な処理装置により廃水中の油脂分や土砂と水
を分離してから、下水などに排水されていた。
2. Description of the Related Art Generally, at a gas station or the like, operations such as car washing, high-pressure water injection, brushing, and waxing by a portal type device are automatically and continuously performed. Also, in a coin car wash, etc., the above car wash work and the like are performed manually. These car wash operations generate a large amount of car wash wastewater. Conventionally, car wash wastewater has been drained to the sewer as it is, or, for example, after separating oil and fat and soil and sand from wastewater by a simple treatment device such as a floating separation type oil trap, and then drained to sewage. .

【0003】しかしながら、近年の環境保護重視の時代
においては、そのままの排水は当然のこと、オイルトラ
ップなどによる処理でも浄化が不十分であり、排水基準
を十分に満足し得るものではなかった。また、洗車廃水
中には、上記油脂分や土砂の他に合成洗剤(界面活性
剤)なども含まれており、上記従来の装置では除去が不
可能であり、特に、浄化水を再利用しようとすると泡立
ってしまうなど、その改良が要請されていた。さらに、
上記従来の装置は、大型で場所をとるだけでなく高価
で、ガソリンスタンド等に広く普及できない等の問題点
もあった。
[0003] However, in the recent era of emphasis on environmental protection, the wastewater is naturally drained, and the purification by the oil trap or the like is insufficient, so that the wastewater standard cannot be sufficiently satisfied. In addition, the car wash wastewater contains synthetic detergents (surfactants) in addition to the oils and fats and the earth and sand, and cannot be removed by the above-described conventional apparatus. If so, foaming would be required, and improvement was requested. further,
The conventional apparatus described above has problems that it is not only large and occupied but also expensive and cannot be widely used in gas stations and the like.

【0004】[0004]

【発明が解決しようとする課題】本発明は、上記従来の
問題点を解決し、また、上記要請に応えるためになされ
たもので、その目的とするところは、洗車水として再利
用が可能な程度にまで浄化することができ、安価でガソ
リンスタンド等に普及し易い洗車廃水の処理方法および
装置を提供することにある。
SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned conventional problems, and has been made to meet the above-mentioned demands. It is an object of the present invention to provide a method and an apparatus for treating car wash wastewater, which can be purified to a certain extent, are inexpensive, and easily spread to gas stations and the like.

【0005】[0005]

【課題を解決するための手段】本発明の洗車廃水の処理
方法は、洗車廃水を電極反応せしめてその成分を酸化、
還元、分解、析出せしめると共に、上記電極反応による
生成物と廃水中の成分との二次反応により該成分を沈
降、吸着、凝縮、浮上せしめて廃水中から分離・除去
し、分離・除去後の処理水中の浮遊物質を精密濾過装置
により分離・除去することを特徴とする。土砂を沈降分
離してから上記電極反応せしめることも特徴とする。
SUMMARY OF THE INVENTION The method for treating car wash wastewater of the present invention comprises subjecting the car wash wastewater to an electrode reaction to oxidize the components thereof.
In addition to reducing, decomposing and precipitating, the secondary reaction between the product of the above-mentioned electrode reaction and the components in the wastewater causes the components to settle, adsorb, condense, float and separate and remove from the wastewater. It is characterized in that suspended substances in the treated water are separated and removed by a microfiltration device. It is also characterized in that the above-mentioned electrode reaction is performed after sedimentation of sediment.

【0006】また、本発明の洗車廃水の処理装置は、内
部に電極を設置して洗車廃水を電極反応せしめてその成
分を酸化、還元、分解、析出せしめると共に上記電極反
応による生成物と廃水中の成分との二次反応により該成
分を沈降、吸着、凝縮、浮上せしめて廃水中から分離・
除去する電解槽と、該電解槽からの処理水を精密濾過す
る精密濾過装置から構成されることを特徴とする。上記
電解槽の前に、土砂を沈殿分離する沈殿分離槽を設ける
ことも特徴とする。
Further, in the apparatus for treating car wash wastewater according to the present invention, an electrode is installed inside the carwash wastewater to cause an electrode reaction of the carwash wastewater to oxidize, reduce, decompose, and precipitate the components, and the product of the above-mentioned electrode reaction and the wastewater. Settle, adsorb, condense and float by secondary reaction with the component
It is characterized by comprising an electrolytic cell to be removed and a microfiltration device for microfiltering the treated water from the electrolytic cell. It is also characterized in that a sedimentation separation tank for sedimentation and separation of earth and sand is provided in front of the electrolytic cell.

【0007】[0007]

【実施例】図1は、本発明装置の1実施例を示す説明図
であり、1は沈殿分離槽であって、流入管2から流入す
る洗車廃水中の土砂を沈殿させる。土砂を沈殿分離した
後の廃水は、主として水に鉱物油やワックスなどの油脂
分やABS(アルキルベンゼンスルフォン酸塩)系合成
洗剤などの洗剤の小滴、あるいは浮遊物質(SS)など
の懸濁粒子が含まれたエマルジョンである。
1 is an explanatory view showing one embodiment of the apparatus of the present invention. Reference numeral 1 denotes a sedimentation / separation tank for sedimenting earth and sand in car wash wastewater flowing from an inflow pipe 2. Wastewater after sedimentation of sediment is mainly composed of water, oil and fats such as mineral oil and wax, small droplets of detergents such as ABS (alkyl benzene sulfonate) synthetic detergents, and suspended particles such as suspended solids (SS). Is contained in the emulsion.

【0008】上記沈殿分離槽1中の廃水は、送水管3を
通して送水ポンプ4により電解槽5に送られる。なお、
上記沈殿分離槽1が上記電解槽5より上方に位置してい
る場合には、送水ポンプ4を省略してもよい。
The wastewater in the sedimentation separation tank 1 is sent to an electrolytic tank 5 by a water supply pump 4 through a water supply pipe 3. In addition,
When the sedimentation separation tank 1 is located above the electrolysis tank 5, the water supply pump 4 may be omitted.

【0009】上記電解槽5は、水平隔板5aにより電解
室5bと沈殿室5cに分けられている。本実施例では、
上記電解室5bは、隔壁5dにより区画されている。電
解室5bと沈殿室5cは、上記床板5aに開設された開
口部5a′により連通している。なお、上記水平隔板5
aや隔壁5dに多数の開口部を開設して透水性を高めた
り、あるいは省略してもよい。
The electrolytic cell 5 is divided into an electrolytic chamber 5b and a sedimentation chamber 5c by a horizontal partition plate 5a. In this embodiment,
The electrolytic chamber 5b is partitioned by a partition 5d. The electrolysis chamber 5b and the precipitation chamber 5c communicate with each other through an opening 5a 'formed in the floor plate 5a. The horizontal partition 5
a or a large number of openings may be formed in the partition wall 5d to increase the water permeability, or may be omitted.

【0010】上記電解槽5の電解室5b内には、図2に
示すような、電極6が設置されている。該電極6は、陽
極板6aと陰極板6bを一対(本実施例では3対)とし
て交互に平行に配置されていて、連結ボルト6cにより
一体的に構成されている。連結ボルト6cと各電極板
(6a、6b)は電気的に絶縁されている。6dは陽極
ボルトであって、図2(B)に示すように、上記陽極板
6aとは電気的に接続され、陰極板6bとは絶縁管6f
により絶縁されている。陰極ボルト6eも同様に陰極板
6bにのみ接続されている。これらの陽極ボルト6dと
陰極ボルト6e間には、例えば6〜12Vの直流が印加
される。商用の交流電力を利用する場合には、適当な整
流器および変圧器(図示せず)を介して印加される。な
お、上記電極板6a、6bの材質としては、アルミニウ
ム、チタン、鉄など従来公知の材料のいずれでもよい。
An electrode 6 as shown in FIG. 2 is provided in the electrolytic chamber 5b of the electrolytic cell 5. The electrodes 6 are arranged alternately in parallel with a pair of anode plates 6a and cathode plates 6b (three pairs in this embodiment), and are integrally formed by connecting bolts 6c. The connection bolt 6c and each electrode plate (6a, 6b) are electrically insulated. An anode bolt 6d is electrically connected to the anode plate 6a and is electrically connected to the cathode plate 6b as shown in FIG. 2 (B).
Insulated by Similarly, the cathode bolt 6e is connected only to the cathode plate 6b. For example, a direct current of 6 to 12 V is applied between the anode bolt 6d and the cathode bolt 6e. When using commercial AC power, it is applied via a suitable rectifier and transformer (not shown). The material of the electrode plates 6a and 6b may be any of conventionally known materials such as aluminum, titanium and iron.

【0011】上記電解室5b内に流入した上記廃水中に
直流を流すと、上記陽極6aや陰極6bと廃水間の界面
における電極反応と、この電極反応による生成物が廃水
中の成分と反応する二次反応が複合的に行われる。上記
電極反応により廃水中の成分が酸化、還元、分解、析出
される。また、上記二次反応により廃水中の成分の沈
降、吸着、凝縮、浮上が行われる。
When a direct current is passed through the wastewater flowing into the electrolytic chamber 5b, an electrode reaction at the interface between the anode 6a or the cathode 6b and the wastewater, and a product of the electrode reaction reacts with a component in the wastewater. The secondary reaction is performed in a complex manner. The components in the wastewater are oxidized, reduced, decomposed, and precipitated by the electrode reaction. Further, the components in the wastewater are settled, adsorbed, condensed, and floated by the secondary reaction.

【0012】上記電極反応において、廃水中のエマルジ
ョンや金属イオンは、上記電極6間に起こる電子反応
(電場)によりイオン的中和(分解)がなされて分離
し、油分は浮上する。また、金属イオンは水酸イオンと
結合して不溶化する。
In the above-mentioned electrode reaction, the emulsion and metal ions in the wastewater undergo ionic neutralization (decomposition) by an electron reaction (electric field) occurring between the above-mentioned electrodes 6 and are separated, and the oil floats. Further, the metal ions are insoluble by binding to the hydroxide ions.

【0013】特に、上記陽極6aから酸素ガスが、一
方、上記陰極6bから水素ガスが、それぞれ発生して上
昇し、廃水中の油分を浮上させると共に、浮遊物質(S
S)に付着してこれを水面に浮上させる。浮上した油分
や浮遊物質などは、吸着材(図示せず)などに吸着させ
たり、適当な掻取り手段などにより、除去する。
In particular, oxygen gas is generated from the anode 6a, and hydrogen gas is generated and raised from the cathode 6b, respectively, to raise the oil content in the wastewater, and to cause the floating substance (S
S) and floats on the water surface. The floating oil and suspended substances are adsorbed by an adsorbent (not shown) or the like, or removed by a suitable scraping means or the like.

【0014】浮遊物質が分離・除去された処理水は、送
水管7を通して精密濾過装置8に送られる。9は送水ポ
ンプである。上記精密濾過装置8は、例えば、図3に示
すように、密封容器8a内に、天然繊維などの濾材によ
り成形された円盤を多数積層して全体として円筒状に構
成されたフィルター8bを収容して、上記電解槽5にお
いて除去し切れなかった浮遊物質を濾過分離する。濾過
装置としては上記装置8に限定するものではなく、微細
な懸濁状物質やコロイド状物質を分離除去できるもので
あればいずれでもよい。
The treated water from which the suspended substances have been separated and removed is sent to a microfiltration device 8 through a water pipe 7. 9 is a water pump. For example, as shown in FIG. 3, the microfiltration device 8 accommodates a filter 8b, which is formed by laminating a large number of disks formed of a filter material such as natural fiber and formed into a cylindrical shape, in a sealed container 8a. Then, the suspended matter that cannot be completely removed in the electrolytic cell 5 is separated by filtration. The filtration device is not limited to the above-mentioned device 8, but may be any device capable of separating and removing fine suspended substances and colloidal substances.

【0015】上記精密濾過装置8により濾過された浄化
水は、送水管10を通して貯水槽11に送られて、必要
に応じて洗浄水として再利用される。
The purified water filtered by the microfiltration device 8 is sent to a water storage tank 11 through a water pipe 10 and reused as washing water as required.

【0016】[0016]

【発明の効果】本発明方法により、洗車水として再利用
が可能な程度にまで十分浄化することができ、また、安
価でガソリンスタンド等に普及し易い装置とすることが
できる。
According to the method of the present invention, it is possible to sufficiently purify the water to such an extent that it can be reused as car wash water, and it is possible to provide an apparatus which is inexpensive and easily spread to gas stations and the like.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の洗車廃水の処理装置の一実施例を示す
説明図である。
FIG. 1 is an explanatory view showing one embodiment of a device for treating car wash wastewater of the present invention.

【図2】電極の構成例を示す斜視図である。FIG. 2 is a perspective view showing a configuration example of an electrode.

【図3】濾過装置の実施例を示す断面図である。FIG. 3 is a cross-sectional view illustrating an embodiment of the filtration device.

【符号の説明】[Explanation of symbols]

1 沈殿分離槽 2 流入管 3 送水管 4 送水ポンプ 5 電解槽 5a 水平隔板 5b 電解室 5c 沈殿室 5d 隔壁 5d′切欠部 6 電極 6a 陽極板 6b 陰極板 6c 連結ボルト 6d 陽極ボルト 6e 陰極ボルト 6f 絶縁管 7 送水管 8 精密濾過装置 8a 密封容器 8b フィルター 9 送水ポンプ 10 送水管 11 貯留槽 DESCRIPTION OF SYMBOLS 1 Precipitation separation tank 2 Inflow pipe 3 Water supply pipe 4 Water supply pump 5 Electrolysis tank 5a Horizontal partition plate 5b Electrolysis chamber 5c Precipitation chamber 5d Partition wall 5d 'Notch 6 Electrode 6a Anode plate 6b Cathode plate 6c Connection bolt 6d Anode bolt 6e Cathode bolt 6f Insulation pipe 7 Water supply pipe 8 Microfiltration device 8a Sealed container 8b Filter 9 Water supply pump 10 Water supply pipe 11 Storage tank

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4D061 DA08 DB15 DB19 DC01 DC02 DC09 DC11 EA03 EA04 EA07 EA08 EB04 EB11 EB17 EB18 EB20 EB27 EB28 EB30 FA09 FA14 4D062 BA19 BB01 CA10 EA32 FA13 FA17 FA22 FA24  ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4D061 DA08 DB15 DB19 DC01 DC02 DC09 DC11 EA03 EA04 EA07 EA08 EB04 EB11 EB17 EB18 EB20 EB27 EB28 EB30 FA09 FA14 4D062 BA19 BB01 CA10 EA32 FA13 FA17 FA22 FA24

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 洗車廃水を電極反応せしめてその成分を
酸化、還元、分解、析出せしめると共に、上記電極反応
による生成物と廃水中の成分との二次反応により該成分
を沈降、吸着、凝縮、浮上せしめて廃水中から分離・除
去し、分離・除去後の処理水中の浮遊物質を精密濾過装
置により分離・除去することを特徴とする洗車廃水の処
理方法。
1. An electrode reaction of car wash wastewater to oxidize, reduce, decompose, and precipitate its components, and sedimentation, adsorption, and condensation of the components by a secondary reaction between the product of the electrode reaction and components in the wastewater. A method for treating car wash wastewater, comprising separating and removing the suspended matter in the treated water after separation and removal using a microfiltration device.
【請求項2】 土砂を沈降分離してから上記電極反応せ
しめることを特徴とする請求項1に記載の洗車廃水の処
理方法。
2. The method for treating car wash wastewater according to claim 1, wherein said electrode reaction is carried out after sedimentation of sediment.
【請求項3】 内部に電極を設置して洗車廃水を電極反
応せしめてその成分を酸化、還元、分解、析出せしめる
と共に上記電極反応による生成物と廃水中の成分との二
次反応により該成分を沈降、吸着、凝縮、浮上せしめて
廃水中から分離・除去する電解槽と、該電解槽からの処
理水を精密濾過する精密濾過装置から構成されることを
特徴とする洗車廃水の処理装置。
3. An electrode is installed in the interior to cause car wash wastewater to undergo an electrode reaction to oxidize, reduce, decompose, and precipitate the components, and a secondary reaction between a product of the electrode reaction and a component in the wastewater causes the components to react. An electrolytic cell for separating and removing water from wastewater by settling, adsorbing, condensing, and floating water, and a microfiltration device for microfiltrating the treated water from the electrolytic cell, a car washing wastewater treatment apparatus.
【請求項4】 上記電解槽の前に、土砂を沈殿分離する
沈殿分離槽を設けることを特徴とする請求項3に記載の
洗車廃水の処理装置。
4. The apparatus for treating car wash wastewater according to claim 3, wherein a sedimentation separation tank for sedimenting and separating earth and sand is provided before the electrolytic cell.
JP11014182A 1999-01-22 1999-01-22 Treatment of car washing waste water and device Pending JP2000210669A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11014182A JP2000210669A (en) 1999-01-22 1999-01-22 Treatment of car washing waste water and device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11014182A JP2000210669A (en) 1999-01-22 1999-01-22 Treatment of car washing waste water and device

Publications (1)

Publication Number Publication Date
JP2000210669A true JP2000210669A (en) 2000-08-02

Family

ID=11854005

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11014182A Pending JP2000210669A (en) 1999-01-22 1999-01-22 Treatment of car washing waste water and device

Country Status (1)

Country Link
JP (1) JP2000210669A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102557304A (en) * 2010-12-16 2012-07-11 张建平 Water treatment device for treating waste bathing and washing water
CN107792970A (en) * 2016-08-31 2018-03-13 福瑞莱环保科技(深圳)股份有限公司 A kind of wastewater from car washer advanced treating and reuse technology
CN113853245A (en) * 2019-09-19 2021-12-28 株式会社Lg化学 Neutralization/water separation tank for esterification product and neutralization/water separation method for esterification product

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102557304A (en) * 2010-12-16 2012-07-11 张建平 Water treatment device for treating waste bathing and washing water
CN107792970A (en) * 2016-08-31 2018-03-13 福瑞莱环保科技(深圳)股份有限公司 A kind of wastewater from car washer advanced treating and reuse technology
CN113853245A (en) * 2019-09-19 2021-12-28 株式会社Lg化学 Neutralization/water separation tank for esterification product and neutralization/water separation method for esterification product

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