JP2000206293A - Method for treating ion exchange resin in decontamination work - Google Patents

Method for treating ion exchange resin in decontamination work

Info

Publication number
JP2000206293A
JP2000206293A JP11010066A JP1006699A JP2000206293A JP 2000206293 A JP2000206293 A JP 2000206293A JP 11010066 A JP11010066 A JP 11010066A JP 1006699 A JP1006699 A JP 1006699A JP 2000206293 A JP2000206293 A JP 2000206293A
Authority
JP
Japan
Prior art keywords
resin
exchange resin
decontamination
ion exchange
ion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11010066A
Other languages
Japanese (ja)
Inventor
Takeshi Kanezaki
健 金崎
Hitoshi Kajinuma
仁志 梶沼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Engineering Corp
Toshiba Corp
Original Assignee
Toshiba Engineering Corp
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Engineering Corp, Toshiba Corp filed Critical Toshiba Engineering Corp
Priority to JP11010066A priority Critical patent/JP2000206293A/en
Publication of JP2000206293A publication Critical patent/JP2000206293A/en
Pending legal-status Critical Current

Links

Landscapes

  • Treatment Of Water By Ion Exchange (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a method for treating an ion exchange resin in chemical decontamination that needs the fewest possible ion exchange resin towers and makes it possible to locate them in a small space, shorten preparation and restoration work and reduce the exposure dose of radiation. SOLUTION: In a method for treating an ion exchange resin by which chemical decontamination treatment is conducted for pipes or equipment of nuclear power plant facilities by passing a decontamination liquid through an object 15 to be decontaminated and metal ions dissolved by the decontamination liquid and involving radioactive contamination are recovered by an ion exchange resin tower 45 or 46, a resin exhaust nozzle 49 is placed in the ion exchange resin tower 45 or 46 and a used ion exchange resin is transferred from the resin exhaust nozzle 49 through a resin exhaust line 51 to a resin storage tank 64 during decontamination work.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、原子力発電所内設
備の配管および機器を化学除染対象物とする除染作業時
のイオン交換樹脂の処理方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for treating an ion-exchange resin in a decontamination operation in which piping and equipment of facilities in a nuclear power plant are subjected to chemical decontamination.

【0002】[0002]

【従来の技術】原子力発電所内設備の配管および機器等
を化学除染対象物とした除染作業において、化学薬品に
より溶解除去した放射能汚染を伴う酸化皮膜の金属イオ
ンおよび化学薬品は、イオン交換樹脂を充填したイオン
交換樹脂塔に回収される。
2. Description of the Related Art In a decontamination work in which piping and equipment of a facility in a nuclear power plant are subjected to chemical decontamination, metal ions and chemicals of oxide films accompanied by radioactive contamination dissolved and removed by chemicals are subjected to ion exchange. It is collected in an ion-exchange resin tower filled with resin.

【0003】イオン交換樹脂量は溶解除去される酸化皮
膜量により決定され、全ての酸化皮膜量を回収可能なイ
オン交換樹脂量を充填した数基のイオン交換樹脂塔を除
染系統内に配置し除染を行う。酸化皮膜を回収した使用
済イオン交換樹脂は、除染終了後、イオン交換樹脂塔に
充填された状態で貯蔵保管を行っている。
[0003] The amount of ion-exchange resin is determined by the amount of oxide film to be dissolved and removed, and several ion-exchange resin towers filled with the amount of ion-exchange resin capable of recovering the entire amount of oxide film are arranged in a decontamination system. Perform decontamination. The spent ion-exchange resin from which the oxide film has been recovered is stored and stored in a state filled with the ion-exchange resin tower after the completion of decontamination.

【0004】つぎに図11により従来のイオン交換樹脂塔
(以下、樹脂塔と記す)の構造を説明する。図11は従来
の樹脂塔を一部側面で示す縦断面図で、図11中、符号1
は円筒形状樹脂塔本体で、上端開口部に上蓋2を有し、
下端開口部に底板3を有している。上蓋2の下面に大径
円板状上部スクリーン4が設けられており、底板3の上
面に複数の小径円板状下部スクリーン5が設けられてい
る。樹脂塔本体1内にはイオン交換樹脂(以下、樹脂と
記す)が充填された樹脂層6が収容されている。
Next, the structure of a conventional ion exchange resin tower (hereinafter, referred to as a resin tower) will be described with reference to FIG. FIG. 11 is a longitudinal sectional view showing a part of a conventional resin tower in a side view.
Is a cylindrical resin tower main body, having an upper lid 2 at an upper end opening,
A bottom plate 3 is provided at the lower end opening. A large-diameter disk-shaped upper screen 4 is provided on the lower surface of the upper lid 2, and a plurality of small-diameter disk-shaped lower screens 5 are provided on the upper surface of the bottom plate 3. A resin layer 6 filled with an ion exchange resin (hereinafter, referred to as resin) is accommodated in the resin tower main body 1.

【0005】上蓋2に上方から上蓋2を貫通する入口ノ
ズル7が取付けられ、入口ノズル7に入口弁8が接続さ
れている。底板3に下部スクリーン5に対向する出口ノ
ズル9が取付けられ、出口ノズル9に出口弁10が取付け
られている。樹脂塔本体1,上蓋2,底板3および出口
ノズル9は遮へい容器11内に収容される。
An inlet nozzle 7 penetrating the upper cover 2 from above is attached to the upper cover 2, and an inlet valve 8 is connected to the inlet nozzle 7. An outlet nozzle 9 facing the lower screen 5 is mounted on the bottom plate 3, and an outlet valve 10 is mounted on the outlet nozzle 9. The resin tower body 1, the top lid 2, the bottom plate 3 and the outlet nozzle 9 are accommodated in a shielding container 11.

【0006】なお、図11中、符号12は遮へい容器11の遮
へい蓋で、積層体で構成されている、符号13は遮へい容
器11の底板である。樹脂塔1の底板3と遮へい容器11の
底板13との間は出口ノズル9のノズル挿入孔14を有し出
口ノズル9が挿入される空間領域となっている。
In FIG. 11, reference numeral 12 denotes a shielding cover of the shielding container 11, which is constituted by a laminated body, and reference numeral 13 denotes a bottom plate of the shielding container 11. The space between the bottom plate 3 of the resin tower 1 and the bottom plate 13 of the shielding vessel 11 is a space region having a nozzle insertion hole 14 for the outlet nozzle 9 and into which the outlet nozzle 9 is inserted.

【0007】ここで、化学除染作業時の除染水は入口ノ
ズル7から樹脂塔本体1内に流入し、上部スクリーン4
および樹脂層6を通過する。これにより除染水中の金属
イオンは回収される。樹脂層6を通過した処理水は下部
スクリーン5から出口ノズル9を通り流出して除染対象
物への洗浄水として使用される。なお、除染作業中の放
射線被曝低減のため、樹脂塔本体1は遮へい容器11に収
納される。
Here, the decontamination water during the chemical decontamination work flows into the resin tower main body 1 from the inlet nozzle 7 and the upper screen 4
And the resin layer 6. Thereby, the metal ions in the decontaminated water are recovered. The treated water that has passed through the resin layer 6 flows out of the lower screen 5 through the outlet nozzle 9 and is used as washing water for the object to be decontaminated. The resin tower main body 1 is stored in a shielding container 11 to reduce radiation exposure during decontamination work.

【0008】[0008]

【発明が解決しようとする課題】従来の化学除染では、
除染対象物全ての酸化皮膜量を回収可能な複数基の樹脂
塔を除染系統内に配置して除染作業を行うため、炉内化
学除染などのように除染対象物が広範囲で除去酸化皮膜
量が多い場合は、10数基以上の樹脂塔が必要となる。し
たがって、遮へい容器11を含めた10数トンの重量物の樹
脂塔を設置する場所の確保が困難という課題がある。
In the conventional chemical decontamination,
Since the decontamination work is performed by arranging multiple resin towers in the decontamination system that can collect the oxide film amount of all the decontamination target, the decontamination target covers a wide range such as chemical decontamination in the furnace. When the amount of the removed oxide film is large, ten or more resin towers are required. Therefore, there is a problem that it is difficult to secure a place for installing a resin tower having a weight of more than 10 tons including the shielding container 11.

【0009】また、樹脂塔は除染作業終了まで高放射能
を有する酸化皮膜を樹脂塔内部に保有することにより、
遮へい容器11の表面の線量当量率が上昇するため、樹脂
塔設置エリアの雰囲気線量の上昇により工事従事者の被
曝量が増加する等の課題がある。
Further, the resin tower has an oxide film having high radioactivity inside the resin tower until the decontamination work is completed,
Since the dose equivalent rate on the surface of the shielding container 11 increases, there are problems such as an increase in the exposure of construction workers due to an increase in the atmospheric dose in the resin tower installation area.

【0010】さらに、除染中に酸化皮膜を回収する際は
除染剤も樹脂塔内を循環するため、樹脂塔内には除染剤
である化学薬品も含まれる。シュウ酸などの化学薬品は
キレート剤であり、キレートを含んだ使用済イオン交換
樹脂を将来埋設処分する際に問題となる課題がある。
Furthermore, when the oxide film is recovered during the decontamination, the decontamination agent also circulates in the resin tower, so that the resin tower also contains a chemical as a decontamination agent. A chemical such as oxalic acid is a chelating agent, and there is a problem that will cause a problem when a used ion exchange resin containing a chelate is to be disposed of in the future.

【0011】本発明は上記課題を解決するためになされ
たもので、樹脂塔の使用基数を必要最小限にし、少ない
スペースで樹脂塔を設置でき、準備,復旧作業時間を短
縮でき、かつ化学除染作業の雰囲気線量当量率低減によ
り作業員の放射線被曝量を低減できる化学除染における
樹脂の処理方法を提供することにある。また、本発明は
使用済樹脂の将来の埋設処分も問題なく実施できるイオ
ン交換樹脂の処理方法を提供することにある。
SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and the number of resin towers to be used can be minimized, the resin tower can be installed in a small space, the preparation and restoration work time can be shortened, and chemical removal can be achieved. An object of the present invention is to provide a method for treating a resin in chemical decontamination in which the radiation exposure dose of an operator can be reduced by reducing the ambient dose equivalent rate of the dyeing operation. Another object of the present invention is to provide a method for treating an ion-exchange resin in which the future disposal of used resin can be carried out without any problem.

【0012】[0012]

【課題を解決するための手段】請求項1の発明は、原子
力発電所内設備の配管または機器を対象とした除染対象
物に除染液を流して化学除染処理する化学除染作業時の
樹脂の処理方法において、前記化学除染作業時の除染液
で溶解した放射能汚染を伴う金属イオンを回収する樹脂
塔に樹脂排出ノズルを設け、この樹脂排出ノズルから除
染作業中に使用済イオン交換樹脂を排出することを特徴
とする。
Means for Solving the Problems The first aspect of the present invention relates to a chemical decontamination operation in which a decontamination liquid is supplied to a decontamination object for piping or equipment in a nuclear power plant and a chemical decontamination process is performed. In the resin treatment method, a resin discharge nozzle is provided in a resin tower for collecting metal ions accompanying radioactive contamination dissolved in the decontamination solution during the chemical decontamination work, and the resin discharge nozzle is used during the decontamination work. It is characterized by discharging the ion exchange resin.

【0013】請求項1の発明によれば、原子力発電所内
設備の配管および機器を対象とした化学除染における、
シュウ酸などの化学薬品で溶解した放射能汚染を伴う酸
化皮膜の金属イオンを回収する樹脂において、樹脂塔を
排出可能型にして、除染の最中に使用済樹脂を排出する
ことにより、樹脂塔の使用基数を低減することができ
る。
According to the first aspect of the present invention, in chemical decontamination for piping and equipment of facilities in a nuclear power plant,
In the resin that collects metal ions of the oxide film accompanied by radioactive contamination dissolved by chemicals such as oxalic acid, the resin tower is made dischargeable and the used resin is discharged during decontamination. The number of bases used in the tower can be reduced.

【0014】請求項2の発明は、前記樹脂塔を少なくと
も2基除染ラインに設置して、一方の樹脂塔内の使用済
樹脂を樹脂排出ノズルから排出する作業を行う際に、他
方の樹脂塔により前記除染ラインの除染作業を継続する
ことを特徴とする。
According to a second aspect of the present invention, at least two resin towers are installed in a decontamination line, and when the used resin in one resin tower is discharged from a resin discharge nozzle, the other resin tower is used. The decontamination work of the decontamination line is continued by a tower.

【0015】請求項2の発明によれば、樹脂塔を2基以
上用意することにより、一方の樹脂塔で使用済樹脂を排
出する作業を行う際にも、他方の樹脂塔を使用すること
により化学除染作業を継続できる。
According to the second aspect of the present invention, by preparing two or more resin towers, it is possible to use one of the resin towers to discharge the spent resin while using the other resin tower. Chemical decontamination work can be continued.

【0016】請求項3の発明は、原子力発電所内に設置
されている樹脂貯蔵タンク、廃樹脂貯蔵設備等の貯蔵設
備で前記使用済樹脂を仮貯蔵することを特徴とする。
According to a third aspect of the present invention, the used resin is temporarily stored in a storage facility such as a resin storage tank and a waste resin storage facility installed in a nuclear power plant.

【0017】請求項3の発明によれば、原子力発電所内
の既存の樹脂貯蔵タンク,廃樹脂貯蔵設備等の貯蔵設備
において化学除染で発生した使用済樹脂を仮貯蔵するこ
とにより樹脂塔設置エリアの雰囲気線量当量率が低減で
きる。
According to the third aspect of the present invention, a resin tower installation area is provided by temporarily storing used resin generated by chemical decontamination in existing resin storage tanks, waste resin storage facilities, and other storage facilities in a nuclear power plant. Ambient dose equivalent rate can be reduced.

【0018】請求項4の発明は、前記樹脂塔に使用済樹
脂の排出ノズル、樹脂押出しノズルおよび新樹脂の充填
ノズルを設けてなることを特徴とする。請求項4の発明
によれば、化学除染の最中に排出ノズルからの使用済イ
オン交換樹脂の排出および充填ノズルからの新樹脂の充
填を容易に行うことができる。
The invention of claim 4 is characterized in that the resin tower is provided with a used resin discharge nozzle, a resin extrusion nozzle and a new resin filling nozzle. According to the invention of claim 4, it is possible to easily discharge the used ion exchange resin from the discharge nozzle and fill the new resin from the filling nozzle during the chemical decontamination.

【0019】請求項5の発明は、前記樹脂塔に仮設配管
またはホースを接続して水および圧縮空気で前記樹脂塔
内の樹脂を移送することを特徴とする。請求項5の発明
によれば、仮設配管またはホースを用いて水および圧縮
空気で樹脂を移送することにより短時間でかつ作業被曝
を少なく効率よく樹脂移送作業ができる。
A fifth aspect of the present invention is characterized in that a temporary pipe or a hose is connected to the resin tower, and the resin in the resin tower is transferred by water and compressed air. According to the fifth aspect of the present invention, by transferring the resin with water and compressed air using a temporary pipe or a hose, the resin transfer operation can be performed efficiently in a short time with less work exposure.

【0020】請求項6の発明は、前記樹脂を移送する際
に放射線モニタを仮設配管またはホース表面あるいはそ
の近傍に設置し樹脂の移送状況を確認することを特徴と
する。請求項6の発明によれば、放射線モニタにより線
量当量率の上昇により樹脂の移送状況を確認することが
でき、万一樹脂が閉塞した場合の閉塞箇所を把握でき、
樹脂移送時の作業員の放射線被曝を低減できる。
A sixth aspect of the present invention is characterized in that when transferring the resin, a radiation monitor is installed on the surface of a temporary pipe or a hose or in the vicinity thereof to check the transfer state of the resin. According to the invention of claim 6, it is possible to confirm the transfer status of the resin by the increase in the dose equivalent rate by the radiation monitor, and to grasp the blockage position in the event that the resin is blocked,
Radiation exposure of workers during resin transfer can be reduced.

【0021】請求項7の発明は、前記樹脂を移送する際
に仮設配管またはホースの全部または一部に遮へいを取
付けることを特徴とする。請求項7の発明によれば、樹
脂移送の際に仮設配管またはホースの全部または一部に
遮へいを取付けることにより樹脂移送時の作業員の放射
線被曝を低減できる。
The invention of claim 7 is characterized in that a shield is attached to all or a part of the temporary pipe or hose when transferring the resin. According to the invention of claim 7, it is possible to reduce the radiation exposure of the worker at the time of transferring the resin by attaching a shield to all or a part of the temporary pipe or the hose at the time of transferring the resin.

【0022】請求項8の発明は、除染中に可搬式の遮へ
い付き樹脂保管容器に樹脂を排出して一時保管し、除染
作業終了後に前記樹脂保管容器を移送しやすい場所に移
動して仮設配管またはホースなどを介し、水および圧縮
空気などを使用して樹脂貯蔵設備に樹脂を排出すること
を特徴とする。請求項8の発明によれば、遮へい付き樹
脂保管容器に樹脂を排出することにより、樹脂塔の使用
基数を減らすことができる。
According to the invention of claim 8, the resin is discharged to a portable shielded resin storage container during decontamination and temporarily stored, and after the decontamination work is completed, the resin storage container is moved to a place where it can be easily transferred. The resin is discharged to a resin storage facility using water, compressed air, or the like via a temporary pipe or a hose. According to the eighth aspect of the present invention, the number of used resin towers can be reduced by discharging the resin into the shielded resin storage container.

【0023】請求項9の発明は、カチオン樹脂とアニオ
ン樹脂を使用する化学除染作業時の樹脂の処理方法にお
いて、前記何れか一方の樹脂を使用後、他方の樹脂に切
替えて使用する際に元の樹脂を貯蔵設備に移送し、樹脂
塔で除染作業を実施することを特徴とする。請求項9の
発明によれば、1つの樹脂塔でカチオン樹脂とアニオン
樹脂のように異なった樹脂を切替えて使用することによ
り、樹脂塔の使用基数を減らすことができる。
According to a ninth aspect of the present invention, there is provided a method for treating a resin during a chemical decontamination operation using a cationic resin and an anionic resin, the method comprising the steps of: The original resin is transferred to a storage facility, and decontamination work is performed in a resin tower. According to the ninth aspect, by switching and using different resins such as a cationic resin and an anionic resin in one resin tower, the number of bases used in the resin tower can be reduced.

【0024】請求項10の発明は、前記使用済樹脂を樹脂
貯蔵設備に移送する前に前記樹脂塔内の化学除染剤を除
染系統浄化水,系統外の脱塩水または復水で置換するこ
とを特徴とする。請求項10の発明によれば、樹脂塔内の
化学除染剤を除染系統浄化水,系統外の脱塩水または復
水で置換することにより、キレート剤を含まない使用済
イオン交換樹脂を問題なく埋設処分することができる。
According to a tenth aspect of the present invention, before transferring the used resin to the resin storage facility, the chemical decontamination agent in the resin tower is replaced with decontamination system purified water, demineralized water or condensate water outside the system. It is characterized by the following. According to the invention of claim 10, by replacing the chemical decontamination agent in the resin tower with decontamination system purified water, demineralized water or condensate water outside the system, a problem arises in the use of a used ion exchange resin containing no chelating agent. Can be buried without disposal.

【0025】[0025]

【発明の実施の形態】図1から図3により本発明に係る
化学除染における樹脂の処理方法の第1の実施の形態を
説明する。図1は本実施の形態を説明するための系統図
で、図1中、符号15は除染対象物である。除染対象物15
には除染液流入配管16と除染液流出配管17が着脱自在に
接続する。除染液流入配管16の上流側には電気ヒータ装
置18の出口側からの除染液供給ライン19と樹脂塔1A,
1Bからの洗浄水供給ライン20が弁21を介して接続して
いる。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A first embodiment of a method for treating a resin in chemical decontamination according to the present invention will be described with reference to FIGS. FIG. 1 is a system diagram for explaining the present embodiment. In FIG. 1, reference numeral 15 denotes an object to be decontaminated. Object to be decontaminated 15
A decontamination liquid inflow pipe 16 and a decontamination liquid outflow pipe 17 are detachably connected. On the upstream side of the decontamination liquid inflow pipe 16, a decontamination liquid supply line 19 from the outlet side of the electric heater device 18 and the resin tower 1A,
A washing water supply line 20 from 1B is connected via a valve 21.

【0026】電気ヒータ装置18の上流側はポンプ出口弁
22,循環ポンプ23,ポンプ入口弁24,タンク出口弁25お
よび除染液容量調整タンク26が順次接続している。除染
液容量調整タンク26のほぼ上部側面には薬液注入装置2
7,薬液出口弁28,薬液ポンプ29,ポンプ出口弁30が接
続している。薬液ポンプ29と出口弁30との間には薬液注
入装置27に接続する戻り管31が止め弁32を介して接続し
ている。
The upstream side of the electric heater device 18 is a pump outlet valve.
22, a circulation pump 23, a pump inlet valve 24, a tank outlet valve 25, and a decontamination liquid capacity adjusting tank 26 are sequentially connected. The chemical injection device 2 is provided on the almost upper side of the decontamination liquid volume adjustment tank 26.
7. A chemical outlet valve 28, a chemical pump 29, and a pump outlet valve 30 are connected. A return pipe 31 connected to the chemical liquid injector 27 is connected between the chemical liquid pump 29 and the outlet valve 30 via a stop valve 32.

【0027】除染液容量調整タンク26の頂部には排気管
33が接続し、排気管33には局所排風機34が接続してい
る。また、除染液容量調整タンク26と除染液流出配管17
との間には弁35,,37を介して調整液配管36が接続して
いる。弁37の入口側および出口側には紫外線照射装置38
が入口弁39,出口弁40を介して照射ループ配管41により
接続している。
An exhaust pipe is provided at the top of the tank 26 for adjusting the volume of the decontamination liquid.
33 is connected, and a local exhaust fan 34 is connected to the exhaust pipe 33. In addition, the decontamination liquid capacity adjustment tank 26 and the decontamination liquid outflow pipe 17
The adjustment liquid piping 36 is connected between the valves and via valves 35 and 37. An ultraviolet irradiation device 38 is provided on the inlet and outlet sides of the valve 37.
Are connected by an irradiation loop pipe 41 via an inlet valve 39 and an outlet valve 40.

【0028】除染液容量調整タンク26のタンク出口弁25
と洗浄水供給ライン20との間には除染ライン42が接続し
ている。この除染ライン42と洗浄水供給ライン20との間
には補助ポンプ入口弁43,補助ポンプ44が接続するとと
もに、補助ポンプ44の吐出側には第1の樹脂塔45と第2
の樹脂塔46がそれぞれ入口弁8および出口弁10を介して
並列接続している。
The tank outlet valve 25 of the decontamination liquid volume adjusting tank 26
A decontamination line 42 is connected between and the cleaning water supply line 20. An auxiliary pump inlet valve 43 and an auxiliary pump 44 are connected between the decontamination line 42 and the washing water supply line 20, and a first resin tower 45 and a second resin tower 45 are provided on the discharge side of the auxiliary pump 44.
Are connected in parallel via an inlet valve 8 and an outlet valve 10, respectively.

【0029】それぞれの入口弁8と出口弁10を接続する
除染ラインには第1の弁47,第2の弁48が設けられてい
る。第1の樹脂塔45と第2の樹脂塔46には樹脂排出ノズ
ル49が接続しており、樹脂排出ノズル49は樹脂出口弁50
を介して樹脂排出ライン51に接続している。
A first valve 47 and a second valve 48 are provided in a decontamination line connecting each of the inlet valves 8 and the outlet valve 10. A resin discharge nozzle 49 is connected to the first resin tower 45 and the second resin tower 46, and the resin discharge nozzle 49 is connected to a resin outlet valve 50.
Is connected to the resin discharge line 51 via the.

【0030】第1の樹脂塔45と第2の樹脂塔46の構造を
図2により説明する。なお、図2中、図11と同一部分に
は同一符号を付して重複する部分の説明は省略する。第
1および第2の樹脂塔45,46が図11に示した従来例と異
なる第1の点は、上蓋2の中央部に新樹脂充填ノズル52
を設け、この新樹脂充填ノズル52を包囲して大径円筒状
流出管53を設け、この流出管53に入口ノズル7を接続す
るとともに、流出管53の下端部に複数の小径上部スクリ
ーン54を設けたことにある。
The structure of the first resin tower 45 and the second resin tower 46 will be described with reference to FIG. In FIG. 2, the same portions as those in FIG. 11 are denoted by the same reference numerals, and the description of the overlapping portions will be omitted. A first difference between the first and second resin towers 45 and 46 from the conventional example shown in FIG.
A large-diameter cylindrical outflow pipe 53 is provided surrounding the new resin filling nozzle 52, the inlet nozzle 7 is connected to the outflow pipe 53, and a plurality of small-diameter upper screens 54 are provided at the lower end of the outflow pipe 53. It has been provided.

【0031】第2の点は樹脂塔本体1内の底部にほぼV
字状下部スクリーン55を設け、このV字状下部スクリー
ン55の下端部に樹脂排出ノズル49を接続したことにあ
る。なお、入口ノズル7には分岐して注水ノズル56が接
続しており、新樹脂充填ノズル52,樹脂排出ノズル49お
よび注水ノズル56にはそれぞれ弁57,58,50が設けられ
ている。処理前の除染系統水は入口ノズル7から樹脂塔
本体1内に流入し、樹脂層6を通過することにより金属
イオンを回収する。
The second point is that approximately V
The V-shaped lower screen 55 is provided, and the resin discharge nozzle 49 is connected to the lower end of the V-shaped lower screen 55. The inlet nozzle 7 is branched and connected to a water injection nozzle 56. The new resin filling nozzle 52, the resin discharge nozzle 49 and the water injection nozzle 56 are provided with valves 57, 58 and 50, respectively. The decontamination system water before the treatment flows from the inlet nozzle 7 into the resin tower main body 1 and passes through the resin layer 6 to collect metal ions.

【0032】図1および図2において、除染対象物15に
循環ポンプ23,電気ヒータ装置18,紫外線照射装置38,
薬液注入装置27,除染液容量調整タンク26,局所排風機
34,補助ポンプ44および第1および第2の樹脂塔45,46
から構成される除染装置を接続して、除染対象物15内の
化学除染を行う。
In FIGS. 1 and 2, a circulation pump 23, an electric heater device 18, an ultraviolet irradiation device 38,
Chemical solution injection device 27, decontamination solution volume adjustment tank 26, local exhaust fan
34, auxiliary pump 44 and first and second resin towers 45, 46
The decontamination device composed of is connected to perform chemical decontamination in the object 15 to be decontaminated.

【0033】除染対象物15に付着していた放射線汚染を
伴う金属イオンは化学薬品で溶解され、第1および第2
の樹脂塔45,46で回収される。金属イオンを回収した使
用済樹脂は除染の最中に原子力発電所に設置されている
樹脂貯蔵タンクまたは廃樹脂貯蔵設備へ排出する。
The metal ions accompanying the radiation contamination attached to the object 15 to be decontaminated are dissolved by a chemical, and the first and second metal ions are dissolved.
Are collected in the resin towers 45 and 46 of the refrigeration system. The spent resin from which the metal ions have been recovered is discharged to a resin storage tank or waste resin storage facility installed in a nuclear power plant during decontamination.

【0034】図3(a)から(c)は樹脂塔として第1
および第2の樹脂塔45,46を除染系統に2基設置してこ
れらを切換えて除染を行う例を説明する。なお、第1の
樹脂塔45をA塔,第2の樹脂塔46をB塔と称す。
FIGS. 3A to 3C show the first resin tower.
An example will be described in which two second resin towers 45 and 46 are installed in a decontamination system and these are switched to perform decontamination. The first resin tower 45 is referred to as tower A, and the second resin tower 46 is referred to as tower B.

【0035】図3(a)はA塔に除染系統から通水し,
B塔を待機した状態を示し、図3(b)はA塔の樹脂を
排出し,B等に通水している状態を示し、図3(c)は
A塔に新樹脂を充填し,B等に通水している状態を示し
ている。
FIG. 3A shows that water is passed from the decontamination system to the tower A,
FIG. 3B shows a state in which the resin in Tower A is discharged and water is passed through B and the like, and FIG. 3C shows a state in which the resin in Tower A is filled with new resin. B shows a state in which water is flowing.

【0036】すなわち、図3(a)に示すように除染ラ
イン42と洗浄水供給ライン20との間にA塔とB塔を2基
並列接続する。このうち、除染開始時はA塔1基のみに
通水し、除染中、樹脂が金属を回収し使用済となった時
点で、図3(b)に示すようにA塔,B塔の入口弁8,
出口弁10を切換えてB塔に通水する。
That is, as shown in FIG. 3 (a), two towers A and B are connected in parallel between the decontamination line 42 and the washing water supply line 20. Of these, at the start of decontamination, water was passed through only one of the towers A. During the decontamination, when the resin was recovered and the metal was used, as shown in FIG. Inlet valve 8,
The outlet valve 10 is switched to allow water to flow through the tower B.

【0037】A塔の樹脂はこの間に使用済樹脂を排出
し、図3(c)に示すように排出後、新樹脂をA塔に充
填し、次の使用に備えることにより除染作業を中断する
ことなく、樹脂の交換作業を行うことができる。
During the period, the resin in the tower A discharges the used resin, and after discharging as shown in FIG. 3 (c), the new resin is filled in the tower A, and the decontamination work is interrupted by preparing for the next use. The replacement of the resin can be performed without the need for the replacement.

【0038】図4は図2に示した第1の樹脂塔45または
第2の樹脂塔46の他の例を示したもので、図2と異なる
点は樹脂塔本体1内に下端部が底板3の上部近傍に開口
し、上端部が上蓋2を貫通して上蓋2を突出する長さを
有する樹脂排出ノズル49aを設け、このノズル49aの上
端部に樹脂出口弁50を設けたことにある。この例によれ
ば、V字状下部スクリーン55を設ける必要がなく、構造
を簡単にすることができる。
FIG. 4 shows another example of the first resin tower 45 or the second resin tower 46 shown in FIG. 2. The difference from FIG. 2 is that the lower end of the resin tower main body 1 has a bottom plate. 3, a resin discharge nozzle 49a having a length such that the upper end thereof penetrates the upper cover 2 and projects the upper cover 2, and a resin outlet valve 50 is provided at the upper end of the nozzle 49a. . According to this example, there is no need to provide the V-shaped lower screen 55, and the structure can be simplified.

【0039】つぎに図5から図7により本発明の第2の
実施の形態を説明する。本実施の形態は第1または第2
の樹脂塔45,46から使用済樹脂6aを樹脂貯蔵タンクま
たは廃樹脂貯蔵設備へ移送する方法に関する。
Next, a second embodiment of the present invention will be described with reference to FIGS. This embodiment is the first or second embodiment.
Of transferring the used resin 6a from the resin towers 45 and 46 to a resin storage tank or a waste resin storage facility.

【0040】図5において、樹脂塔本体1に接続した入
口ノズル7に圧縮空気ライン59と水供給ライン60がそれ
ぞれ止め弁61,62を介して分岐接続している。また、樹
脂排出ノズル49に仮設配管63の一端を接続し、この仮設
配管63の他端を樹脂貯蔵タンク64に接続する。なお、樹
脂貯蔵タンク64は廃樹脂貯蔵設備に代えることもでき
る。樹脂貯蔵タンク64または廃樹脂貯蔵設備は放射線遮
へい壁65により区隔されている。
In FIG. 5, a compressed air line 59 and a water supply line 60 are branched and connected to the inlet nozzle 7 connected to the resin tower main body 1 via stop valves 61 and 62, respectively. Further, one end of a temporary pipe 63 is connected to the resin discharge nozzle 49, and the other end of the temporary pipe 63 is connected to a resin storage tank 64. Note that the resin storage tank 64 can be replaced with waste resin storage equipment. The resin storage tank 64 or the waste resin storage equipment is separated by a radiation shielding wall 65.

【0041】第1の樹脂塔45または第2の樹脂塔46から
原子力発電所に設置されている樹脂貯蔵タンク64へ使用
済樹脂6aを排出する場合には、樹脂排出ノズル49と樹
脂貯蔵タンク64との間を仮設配管63で接続する。そし
て、樹脂塔本体1内に水を注入し、樹脂塔本体1内を加
圧し、水とともに使用済樹脂6aを排出する。使用済樹
脂6aを排出後、入口ノズル7から圧縮空気を流入する
ことにより、樹脂塔本体1内に残留した使用済樹脂を排
出することができる。
When the used resin 6a is discharged from the first resin tower 45 or the second resin tower 46 to the resin storage tank 64 installed in the nuclear power plant, the resin discharge nozzle 49 and the resin storage tank 64 Are connected by a temporary pipe 63. Then, water is injected into the resin tower main body 1, the inside of the resin tower main body 1 is pressurized, and the used resin 6a is discharged together with the water. After the spent resin 6a is discharged, the compressed resin flows from the inlet nozzle 7 so that the spent resin remaining in the resin tower main body 1 can be discharged.

【0042】図6は図5において、放射線遮へい壁65の
内外における仮設配管63にそれぞれ放射線モニタ66を設
けて使用済樹脂6aの排出移送状態を確認することにあ
る。すなわち、使用済樹脂6aを樹脂貯蔵タンク64へ移
送する仮設配管63に放射線モニタ66を設けることによ
り、使用済樹脂6aの移送中は線量当量率が上昇し、使
用済樹脂6aの移送後は線量当量率が低下することか
ら、使用済樹脂6aの移送状態を確認することができ
る。
FIG. 6 shows that a radiation monitor 66 is provided on each of the temporary pipes 63 inside and outside the radiation shielding wall 65 in FIG. 5 to check the discharge and transfer state of the used resin 6a. That is, by providing the radiation monitor 66 in the temporary pipe 63 for transferring the used resin 6a to the resin storage tank 64, the dose equivalent rate increases during the transfer of the used resin 6a, and the dose equivalent rate increases after the used resin 6a is transferred. Since the equivalent ratio decreases, the transfer state of the used resin 6a can be confirmed.

【0043】図7は、図5において放射線遮へい壁65の
内外における仮設配管63の表面全体、または一部に放射
線遮へい体67を設けたことにある。これにより、使用済
樹脂6aの移送時の雰囲気線量当量率を低下させて、作
業員の放射線被曝を低減させることができる。
FIG. 7 shows that a radiation shield 67 is provided on the entire surface or a part of the temporary pipe 63 inside and outside the radiation shield wall 65 in FIG. Thereby, the ambient dose equivalent rate at the time of transfer of the used resin 6a can be reduced, and the radiation exposure of the worker can be reduced.

【0044】つぎに図8により本発明の第3の実施の形
態を説明する。本実施の形態は除染中に可搬式遮へい付
き樹脂保管装置68に第1の樹脂塔45または第2の樹脂塔
46内の使用済樹脂6aを排出して一時保管し、除染作業
終了後に前記保管容器68を放射性廃棄物処理(ラド)建
屋に移動して仮設配管63を接続して樹脂貯蔵タンク64に
排出することにある。図8中、符号69は運搬用台車,70
はベント管,71は注水ノズルである。
Next, a third embodiment of the present invention will be described with reference to FIG. In the present embodiment, the first resin tower 45 or the second resin tower is installed in the resin storage device 68 having a portable shield during decontamination.
The used resin 6a in 46 is discharged and temporarily stored, and after the decontamination work is completed, the storage container 68 is moved to a radioactive waste treatment (Rad) building, a temporary pipe 63 is connected and discharged to a resin storage tank 64. Is to do. In FIG. 8, reference numeral 69 denotes a transport trolley, 70
Is a vent pipe, and 71 is a water injection nozzle.

【0045】すなわち、本実施の形態は樹脂塔から直接
原子力発電所に設置されている樹脂貯蔵タンク64に使用
済樹脂6aを直接排出できない場合の樹脂廃棄方法に好
適している。化学除染中は使用済樹脂6aを一旦前記保
管容器68内に排出して保管し、除染作業終了後に前記保
管容器68を樹脂貯蔵タンク64の移送し易い場所まで運搬
用台車69に載せて移動する。そして、その場所で樹脂排
出ノズル49と樹脂貯蔵タンク64とを仮設配管63により移
動する。その後、前記保管容器68に接続した注水ノズル
71から水および圧縮空気を流して使用済樹脂6aを排出
する。
That is, the present embodiment is suitable for a resin disposal method when the used resin 6a cannot be directly discharged from the resin tower to the resin storage tank 64 installed in the nuclear power plant. During the chemical decontamination, the used resin 6a is once discharged into the storage container 68 and stored, and after the decontamination work is completed, the storage container 68 is placed on the transport trolley 69 to a place where the resin storage tank 64 can be easily transferred. Moving. Then, the resin discharge nozzle 49 and the resin storage tank 64 are moved by the temporary piping 63 at that location. Then, the water injection nozzle connected to the storage container 68
Water and compressed air flow from 71 to discharge the used resin 6a.

【0046】つぎに図9により本発明の第4の実施の形
態を説明する。本実施の形態はイオン交換樹脂にカチオ
ン樹脂とアニオン樹脂を使用する化学除染時の樹脂の処
理方法において、前記何れか一方の樹脂を使用後、他方
の樹脂に切換えて使用する際に、元の樹脂を貯蔵設備に
移送し限られた樹脂塔で遅滞なく除染作業を行うことに
ある。
Next, a fourth embodiment of the present invention will be described with reference to FIG. This embodiment is a method of treating a resin during chemical decontamination using a cationic resin and an anionic resin as an ion exchange resin. In the method of using one of the above resins, when switching to the other resin, the original resin is used. Is transferred to a storage facility and decontamination work is performed without delay in a limited resin tower.

【0047】すなわち、図9に示したように、A塔とB
塔を使用して、カチオン樹脂とアニオン樹脂など種類の
異なる樹脂を入れ替えることにより、同一の塔で異なる
樹脂を使用する。この場合、まず最初にA塔のカチオン
樹脂を使用して通水(ステップ1)した後、他方のB塔
の通水中にA塔の使用済カチオン樹脂を排出する(ステ
ップ2)。次に新アニオン樹脂をA塔に充填(ステップ
2)し、アニオン塔として使用することができる(ステ
ップ3)。よって、本実施の形態によれば、樹脂塔の基
数を低減することができる。
That is, as shown in FIG.
Different resins are used in the same tower by replacing different kinds of resins such as a cationic resin and an anionic resin using a tower. In this case, first, water is passed through the cation resin in the tower A (step 1), and then the spent cation resin in the tower A is discharged into the water passed in the other tower B (step 2). Next, the tower A is filled with the new anion resin (step 2) and can be used as an anion tower (step 3). Therefore, according to the present embodiment, the number of bases of the resin tower can be reduced.

【0048】つぎに図10により本発明の第5の実施の形
態を説明する。本実施の形態は使用済樹脂6aを排出す
る前の樹脂塔(A塔,B塔)内の置換方法に関するもの
で、図10に示したように、使用済樹脂6aを樹脂貯蔵設
備に移送する前に樹脂塔内の化学除染剤を除染ライン42
からの除染系浄化水,系統外の入口ノズル7に分岐接続
した脱塩水または復水または復水注入ノズル73からの脱
塩水または復水で置換することにある。
Next, a fifth embodiment of the present invention will be described with reference to FIG. The present embodiment relates to a method of replacing the inside of the resin tower (tower A, tower B) before discharging the used resin 6a, and transfers the used resin 6a to a resin storage facility as shown in FIG. Before the chemical decontamination agent in the resin tower is decontaminated line 42
And demineralized water or condensed water condensed from condensate or condensate injection nozzle 73 branched and connected to inlet nozzle 7 outside the system.

【0049】すなわち、図10に示したように、A塔の使
用済樹脂排出前に、除染系統が浄化中であれば除染系統
の浄化水を、除染中であれば系統外の脱塩水または復水
を樹脂塔内に通水し、樹脂塔内の高濃度の化学薬品を置
換する。B塔の使用済樹脂6aの排出時も同様に樹脂塔
内を置換する。これによりA,B塔内はキレートを含ま
ない水で置換されるため、使用済樹脂6aを問題なく埋
設処分することができる。
That is, as shown in FIG. 10, before the spent resin is discharged from the tower A, if the decontamination system is purifying, the purified water of the decontamination system is discharged. Brine or condensate is passed through the resin tower to replace high concentrations of chemicals in the resin tower. When the used resin 6a is discharged from the tower B, the inside of the resin tower is similarly replaced. This replaces the inside of the towers A and B with water containing no chelate, so that the used resin 6a can be buried and disposed without any problem.

【0050】[0050]

【発明の効果】本発明によれば、化学除染中に使用済樹
脂を排出することにより、樹脂塔を必要最小限の樹脂塔
基数で除染を行うことができる。これに伴い、作業員の
被曝低減を図ることができ、樹脂塔基数低減により高線
量雑固体廃棄物の低減を図ることができる。
According to the present invention, by discharging used resin during chemical decontamination, the resin tower can be decontaminated with the minimum necessary number of resin towers. Along with this, it is possible to reduce the exposure of workers, and it is possible to reduce high-dose miscellaneous solid waste by reducing the number of resin towers.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の第1の実施の形態を説明するためのシ
ステム系統図。
FIG. 1 is a system diagram for explaining a first embodiment of the present invention.

【図2】図1における樹脂塔の第1の例を示す縦断面
図。
FIG. 2 is a longitudinal sectional view showing a first example of the resin tower in FIG.

【図3】(a)は図1における樹脂塔Aに樹脂塔Bを待
機させた状態を示す系統図、(b)は同じく樹脂塔Aの
樹脂を排出し,樹脂塔Bに通水した状態を示す系統図、
(c)は樹脂塔Aに樹脂を充填し,樹脂塔Bに通水した
状態を示す系統図。
3A is a system diagram showing a state in which the resin tower B is made to stand by in the resin tower A in FIG. 1, and FIG. 3B is a state in which the resin in the resin tower A is discharged and water is passed through the resin tower B. A system diagram showing
(C) is a system diagram showing a state in which resin is filled in resin tower A and water is passed through resin tower B.

【図4】図1における樹脂塔の第2の例を示す縦断面
図。
FIG. 4 is a longitudinal sectional view showing a second example of the resin tower in FIG.

【図5】本発明の第2の実施の形態を説明するための系
統図。
FIG. 5 is a system diagram for explaining a second embodiment of the present invention.

【図6】図5において、仮設配管に放射線モニタを取付
けた例を示す系統図。
FIG. 6 is a system diagram showing an example in which a radiation monitor is attached to a temporary pipe in FIG.

【図7】図5において、仮設配管に遮へいを取付けた例
を示す系統図。
FIG. 7 is a system diagram showing an example in which a shield is attached to a temporary pipe in FIG. 5;

【図8】本発明の第3の実施の形態を説明するための系
統図。
FIG. 8 is a system diagram for explaining a third embodiment of the present invention.

【図9】本発明の第4の実施の形態を説明するための工
程図。
FIG. 9 is a process chart for explaining a fourth embodiment of the present invention.

【図10】本発明の第5の実施の形態を説明するための
系統図。
FIG. 10 is a system diagram for explaining a fifth embodiment of the present invention.

【図11】従来のイオン交換樹脂塔を一部側面で示す縦
断面図。
FIG. 11 is a longitudinal sectional view showing a part of a conventional ion exchange resin tower in a side view.

【符号の説明】[Explanation of symbols]

1,1A,1B…樹脂塔本体、2…上蓋、3…底板、4
…上部スクリーン、5…下部スクリーン、6…樹脂層、
6a…使用済樹脂、7…入口ノズル、8…入口弁、9…
出口ノズル、10…出口弁、11…遮へい容器、12…遮へい
蓋、13…底板、14…ノズル挿入孔、15…除染対象物、16
…除染流入配管、17…除染流出配管、18…電気ヒータ装
置、19…除染液供給ライン、20…洗浄水供給ライン、21
…弁、22…ポンプ出口弁、23…循環ポンプ、24…ポンプ
入口弁、25…タンク出口弁、26…除染液容量調整タン
ク、27…薬液注入装置、28…薬液出口弁、29…薬液ポン
プ、30…ポンプ出口弁、31…戻り管、32…止め弁、33…
排気管、34…局所排風機、35,37…弁、36…調整液配
管、38…紫外線照射装置、39…入口弁、40…出口弁、41
…照射ループ配管、42…除染ライン、43…補助ポンプ入
口弁、44…補助ポンプ、45…第1の樹脂塔、46…第2の
樹脂塔、47…第1の弁、48…第2の弁、49…樹脂排出ノ
ズル、50…樹脂出口弁、51…樹脂排出ライン、52…新樹
脂充填ノズル、53…流出管、54…小径上部スクリーン、
55…V字状下部スクリーン、56…注水ノズル、57,58…
弁、59…圧縮空気ライン、60…水供給ライン、61,62…
止め弁、63…仮設配管、64…樹脂貯蔵タンク、65…放射
線遮へい壁、66…放射線モニタ、67…放射線遮へい体、
68…可搬式遮へい付き保管容器、69…運搬用台車、70…
ベント管、71…注水ノズル、72…脱塩水または復水注入
ノズル、73…注入弁。
1, 1A, 1B ... resin tower body, 2 ... top lid, 3 ... bottom plate, 4
... upper screen, 5 ... lower screen, 6 ... resin layer,
6a: Used resin, 7: Inlet nozzle, 8: Inlet valve, 9 ...
Outlet nozzle, 10 ... Outlet valve, 11 ... Shielding container, 12 ... Shielding lid, 13 ... Bottom plate, 14 ... Nozzle insertion hole, 15 ... Object to be decontaminated, 16
... decontamination inflow pipe, 17 ... decontamination outflow pipe, 18 ... electric heater device, 19 ... decontamination liquid supply line, 20 ... washing water supply line, 21
… Valve, 22… Pump outlet valve, 23… Circulation pump, 24… Pump inlet valve, 25… Tank outlet valve, 26… Decontamination liquid capacity adjusting tank, 27… Chemical liquid injector, 28… Chemical liquid outlet valve, 29… Chemical liquid Pump, 30 ... Pump outlet valve, 31 ... Return pipe, 32 ... Stop valve, 33 ...
Exhaust pipe, 34… Local exhaust fan, 35, 37… Valve, 36… Adjustment liquid piping, 38… Ultraviolet irradiation device, 39… Inlet valve, 40… Outlet valve, 41
... irradiation loop piping, 42 ... decontamination line, 43 ... auxiliary pump inlet valve, 44 ... auxiliary pump, 45 ... first resin tower, 46 ... second resin tower, 47 ... first valve, 48 ... second No. 49, Resin discharge nozzle, 50: Resin outlet valve, 51: Resin discharge line, 52: New resin filling nozzle, 53: Outflow pipe, 54: Small diameter upper screen,
55 ... V-shaped lower screen, 56 ... water injection nozzle, 57, 58 ...
Valve, 59… Compressed air line, 60… Water supply line, 61,62…
Stop valve, 63: Temporary piping, 64: Resin storage tank, 65: Radiation shielding wall, 66: Radiation monitor, 67: Radiation shielding body,
68… Portable storage container with shielding, 69… Transportation trolley, 70…
Vent pipe, 71 ... water injection nozzle, 72 ... deionized water or condensate injection nozzle, 73 ... injection valve.

Claims (10)

【特許請求の範囲】[Claims] 【請求項1】 原子力発電所内設備の配管または機器を
対象とした除染対象物に除染液を流して化学除染処理す
る化学除染作業時のイオン交換樹脂の処理方法におい
て、前記化学除染作業時の除染液で溶解した放射能汚染
を伴う金属イオンを回収するイオン交換樹脂塔に樹脂排
出ノズルを設け、この樹脂排出ノズルから除染作業中に
使用済イオン交換樹脂を排出することを特徴とする除染
作業時のイオン交換樹脂の処理方法。
1. A method for treating an ion-exchange resin in a chemical decontamination operation in which a decontamination liquid is flown to a decontamination target for piping or equipment in a facility in a nuclear power plant and a chemical decontamination treatment is performed. Install a resin discharge nozzle in the ion exchange resin tower that collects metal ions with radioactive contamination dissolved in the decontamination solution during the dyeing work, and discharge the used ion exchange resin from the resin discharge nozzle during the decontamination work A method for treating an ion-exchange resin during decontamination work.
【請求項2】 前記イオン交換樹脂塔を少なくとも2基
除染ラインに設置して、一方のイオン交換樹脂塔内の使
用済イオン交換樹脂を前記樹脂排出ノズルから排出する
作業を行う際に、他方のイオン交換樹脂塔により前記除
染ラインの除染作業を継続することを特徴とする請求項
1記載の除染作業時のイオン交換樹脂の処理方法。
2. The method according to claim 1, wherein the ion-exchange resin tower is installed in at least two decontamination lines, and when the used ion-exchange resin in one ion-exchange resin tower is discharged from the resin discharge nozzle, the other is used. The method for treating an ion-exchange resin during decontamination according to claim 1, wherein the decontamination operation of the decontamination line is continued by the ion-exchange resin tower.
【請求項3】 前記原子力発電所内に設置されている樹
脂貯蔵タンク、廃樹脂貯蔵設備等の貯蔵設備で前記使用
済イオン交換樹脂を仮貯蔵することを特徴とする請求項
1記載の除染作業時のイオン交換樹脂の処理方法。
3. The decontamination work according to claim 1, wherein the used ion exchange resin is temporarily stored in a storage facility such as a resin storage tank and a waste resin storage facility installed in the nuclear power plant. Method of ion exchange resin at the time.
【請求項4】 前記イオン交換樹脂塔に使用済イオン交
換樹脂の排出ノズル、樹脂押出しノズルおよび新樹脂の
充填ノズルを設けてなることを特徴とする請求項1記載
の除染作業時のイオン交換樹脂の処理方法。
4. The ion exchange during decontamination work according to claim 1, wherein the ion exchange resin tower is provided with a discharge nozzle for used ion exchange resin, a resin extrusion nozzle, and a nozzle for charging new resin. Resin treatment method.
【請求項5】 前記イオン交換樹脂塔に仮設配管または
ホースを接続して水および圧縮空気で前記イオン交換樹
脂塔内のイオン交換樹脂を移送することを特徴とする請
求項1記載の除染作業時のイオン交換樹脂の処理方法。
5. The decontamination work according to claim 1, wherein a temporary pipe or a hose is connected to the ion exchange resin tower, and the ion exchange resin in the ion exchange resin tower is transferred by water and compressed air. Method of ion exchange resin at the time.
【請求項6】 前記イオン交換樹脂を移送する際に放射
線モニタを仮設配管またはホース表面あるいはその近傍
に設置しイオン交換樹脂の移送状況を確認することを特
徴とする請求項5記載の除染作業時のイオン交換樹脂の
処理方法。
6. The decontamination work according to claim 5, wherein a radiation monitor is installed on or near a temporary pipe or a hose surface when transferring the ion-exchange resin to check the transfer status of the ion-exchange resin. Method of ion exchange resin at the time.
【請求項7】 前記イオン交換樹脂を移送する際に仮設
配管またはホースの全部または一部に遮へいを取付ける
ことを特徴とする請求項5記載の除染作業時のイオン交
換樹脂の処理方法。
7. The method for treating an ion-exchange resin during decontamination according to claim 5, wherein a shield is attached to all or part of the temporary pipe or hose when transferring the ion-exchange resin.
【請求項8】 除染中に可搬式の遮へい付きイオン交換
樹脂保管容器にイオン交換樹脂を排出して一時保管し、
除染作業終了後に前記イオン交換樹脂保管容器を移送し
やすい場所に移動して仮設配管またはホースなどを介
し、水および圧縮空気などを使用してイオン交換樹脂貯
蔵設備にイオン交換樹脂を排出することを特徴とする除
染作業時のイオン交換樹脂の処理方法。
8. The ion exchange resin is discharged into a portable shielded ion exchange resin storage container during decontamination and temporarily stored therein.
After completion of the decontamination work, move the ion exchange resin storage container to a place where it can be easily transferred, and discharge the ion exchange resin to the ion exchange resin storage facility using water, compressed air, or the like via a temporary pipe or a hose. A method for treating an ion-exchange resin during decontamination work.
【請求項9】 カチオン樹脂とアニオン樹脂を使用する
化学除染作業時のイオン交換樹脂の処理方法において、
前記何れか一方の樹脂を使用後、他方の樹脂に切替えて
使用する際に元の樹脂を貯蔵設備に移送し、イオン交換
樹脂塔で除染作業を実施することを特徴とする除染作業
時のイオン交換樹脂の処理方法。
9. A method for treating an ion exchange resin during a chemical decontamination operation using a cationic resin and an anionic resin,
At the time of decontamination work characterized in that after using any one of the above resins, the original resin is transferred to a storage facility when used by switching to the other resin, and decontamination work is performed in an ion exchange resin tower. Method of treating ion exchange resin.
【請求項10】 前記使用済イオン交換樹脂を樹脂貯蔵
設備に移送する前に前記イオン交換樹脂塔内の化学除染
剤を除染系統浄化水,系統外の脱塩水または復水で置換
することを特徴とする請求項1ないし9記載の除染作業
時のイオン交換樹脂の処理方法。
10. The chemical decontamination agent in the ion exchange resin tower is replaced with decontamination system purified water, demineralized water or condensate outside the system before transferring the used ion exchange resin to a resin storage facility. The method for treating an ion-exchange resin during the decontamination work according to claim 1, wherein:
JP11010066A 1999-01-19 1999-01-19 Method for treating ion exchange resin in decontamination work Pending JP2000206293A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11010066A JP2000206293A (en) 1999-01-19 1999-01-19 Method for treating ion exchange resin in decontamination work

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11010066A JP2000206293A (en) 1999-01-19 1999-01-19 Method for treating ion exchange resin in decontamination work

Publications (1)

Publication Number Publication Date
JP2000206293A true JP2000206293A (en) 2000-07-28

Family

ID=11740018

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11010066A Pending JP2000206293A (en) 1999-01-19 1999-01-19 Method for treating ion exchange resin in decontamination work

Country Status (1)

Country Link
JP (1) JP2000206293A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019196956A (en) * 2018-05-09 2019-11-14 太平電業株式会社 Storage method of radioactive granular waste resin to shielding container

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019196956A (en) * 2018-05-09 2019-11-14 太平電業株式会社 Storage method of radioactive granular waste resin to shielding container

Similar Documents

Publication Publication Date Title
JP6270880B2 (en) Chemical decontamination method
EP1298677A2 (en) A method of decontaminating by ozone and a device therefor
JP2004520586A (en) Radiation decontamination method and apparatus for a surface located inside a hollow object
JPH04276596A (en) Method and apparatus for chemical decontamination of primary system of atomic reactor
JP3172127B2 (en) Chemical decontamination method for facilities in nuclear power plants
US4963293A (en) Flow control method for decontaminating radioactively contaminated nuclear steam generator
JP2000206293A (en) Method for treating ion exchange resin in decontamination work
EP0404428A1 (en) Water filled tanks for temporary shielding of reactor vessel internals and method of assembly
US5171519A (en) Outside of containment chemical decontamination system for nuclear reactor primary systems
JPS6317196B2 (en)
JP2006313134A (en) Drum conceal type ion-exchange resin column
EP3491652A1 (en) Tank closure cesium removal
RU194177U1 (en) Filter container for cleaning solutions from radionuclides
KR20040013784A (en) Chemical decontamination device for contaminated equipment by radioactive substance
US6907891B2 (en) Radioactive substance decontamination method and apparatus
TWI814091B (en) Chemical decontamination method
JP2714134B2 (en) Radioactive waste treatment system
KR20050010734A (en) Chemical decontamination device for contaminated equipment by radioactive substance
KR100323352B1 (en) A Movable Tritium Eliminate Device
Steinkuhler et al. Experience in chemical decontamination of PWR systems and components
US20030052063A1 (en) Decontamination method and apparatus
JP2006184045A (en) Ion-exchange resin tower for chemical decontamination
US5491732A (en) Nuclear reactor primary system chemical decontamination clean-up system component arrangement
Brooksbank et al. Post-Accident Cleanup of Radioactivity at the Three Mile Island Nuclear Power Station
JP5912886B2 (en) Chemical decontamination method

Legal Events

Date Code Title Description
A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A712

Effective date: 20040319

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20040611

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20060511

RD02 Notification of acceptance of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7422

Effective date: 20070315

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20070821

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20071015

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20080401

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20080528

A911 Transfer of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20080604

A912 Removal of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A912

Effective date: 20080627