JP2000202482A - Cleaning method and device for waste water - Google Patents

Cleaning method and device for waste water

Info

Publication number
JP2000202482A
JP2000202482A JP11008251A JP825199A JP2000202482A JP 2000202482 A JP2000202482 A JP 2000202482A JP 11008251 A JP11008251 A JP 11008251A JP 825199 A JP825199 A JP 825199A JP 2000202482 A JP2000202482 A JP 2000202482A
Authority
JP
Japan
Prior art keywords
adsorbent
purified water
wastewater
treatment tank
tank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11008251A
Other languages
Japanese (ja)
Inventor
Masakata Hirai
正名 平井
Koji Doi
公司 土居
Hitoshi Kuno
斉 久野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denso Corp
Original Assignee
Denso Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denso Corp filed Critical Denso Corp
Priority to JP11008251A priority Critical patent/JP2000202482A/en
Publication of JP2000202482A publication Critical patent/JP2000202482A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Biological Treatment Of Waste Water (AREA)

Abstract

PROBLEM TO BE SOLVED: To elongate service life of an adsorbent material and to apply the material to waste water containing high concn. sludge substance. SOLUTION: The cleaning method is constituted with the purifying stage in which the adsorbent material such as activated carbon 4 having a precipitating property under water is filled in a treating tank 1 and purified water is produced by adsorbing the sludge substance in the waste water flowing into the treating tank 1 to the adsorbent material, and the regenerating stage in which the adsorbed sludge substance is decomposed by the microorganism propagated in the treating tank 1. At the regenerating stage, the adsorbent material is fluidized by providing the space 40 to which the adsorbent material is movable at the upper part of the treating tank 1 and supplying oxygen-containing gas and the purified water at the lower part. And the waste water is cleaned by providing the space to which the adsorbent material is movable at the lower part of the treating tank and supplying oxygen-containing gas and the treated water at the upper part by using the adsorbent material having a floating property under water.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【技術分野】本発明は,汚濁物質を含む排水を浄化する
ための浄化方法および浄化装置に関するものである。
TECHNICAL FIELD The present invention relates to a purification method and a purification device for purifying wastewater containing pollutants.

【0002】[0002]

【従来技術】吸着材を利用した排水の浄化技術として,
従来,接触曝気方式等の既存の排水浄化技術で処理した
汚濁濃度の低い排水を活性炭層を通過させることによっ
て残留汚濁物質を吸着除去し高度に浄化する処理が行わ
れている。この技術では,活性炭が汚濁物質の吸着によ
って飽和吸着状態となり,吸着能力を喪失するという欠
点があった。飽和吸着状態となった活性炭は処理槽内に
充填した状態では再生処理が困難であるため,飽和吸着
状態に達した段階で,活性炭を交換する必要があった。
このため,汚濁濃度が高い排水について,活性炭を用い
る上記技術を適用した場合,飽和吸着に至るまでの時間
が短く,活性炭の交換を頻繁に行う必要がある。そのた
め,上記従来の技術の適用対象は,既存の排水浄化技術
で処理した排水のように汚濁濃度が低い排水に限定され
ていた。
2. Description of the Related Art As a purification technology of wastewater using an adsorbent,
2. Description of the Related Art Conventionally, a process of adsorbing and removing residual pollutants and purifying the water to a high degree has been performed by passing wastewater having a low pollutant concentration, which has been treated by an existing wastewater purification technique such as a contact aeration method, through an activated carbon layer. This technique has a drawback that activated carbon is brought into a saturated adsorption state by the adsorption of pollutants, and the adsorption capacity is lost. Since activated carbon in the saturated adsorption state is difficult to regenerate when filled in the treatment tank, it was necessary to replace the activated carbon when the state reached the saturated adsorption state.
For this reason, when the above-mentioned technology using activated carbon is applied to wastewater having a high concentration of pollutants, the time until saturation adsorption is short, and the activated carbon needs to be frequently replaced. For this reason, the application of the above-mentioned conventional technology has been limited to wastewater having a low pollutant concentration, such as wastewater treated by existing wastewater purification technology.

【0003】[0003]

【解決しようとする課題】本発明はかかる従来の問題点
に鑑み,吸着材の使用期間の長期化を図り,高濃度の汚
濁物質を含む排水に対しても優れた浄化性能を発揮でき
る,排水の浄化方法および浄化装置を提供しようとする
ものである。
SUMMARY OF THE INVENTION In view of the above-mentioned problems, the present invention aims to prolong the period of use of an adsorbent and exhibit excellent purification performance even for wastewater containing high-concentration pollutants. It is an object of the present invention to provide a purification method and a purification device.

【0004】[0004]

【課題の解決手段】上記課題を解決するため,吸着材の
処理槽内における吸着能力の再生方法について鋭意研究
を行った結果,本発明の排水の浄化方法および浄化装置
を開発するに至った。すなわち,請求項1記載のよう
に,水中で沈降性を有する吸着材を処理槽内に充填し,
該処理槽内に流入した排水中の汚濁物質を吸着材に吸着
せしめて浄化水を生成する浄化工程と,吸着した汚濁物
質を処理槽内に繁殖させた微生物によって分解する再生
工程とからなり,上記再生工程において,上記処理槽の
上部に吸着材が移動可能な空間を設け,処理槽の下方か
ら吸着材に酸素含有気体と浄化水とを供給することによ
って吸着材を流動床化することを特徴とする排水の浄化
方法がある。
In order to solve the above-mentioned problems, as a result of intensive research on a method for regenerating the adsorption capacity of an adsorbent in a treatment tank, the method and apparatus for purifying wastewater of the present invention have been developed. That is, as described in claim 1, an adsorbent having sedimentation in water is filled in the treatment tank,
A purification step of generating purified water by adsorbing pollutants in the wastewater flowing into the treatment tank to an adsorbent, and a regeneration step of decomposing the adsorbed pollutants by microorganisms propagated in the treatment tank; In the regeneration step, a space in which the adsorbent can move is provided above the treatment tank, and the adsorbent is made into a fluidized bed by supplying oxygen-containing gas and purified water to the adsorbent from below the treatment tank. There is a characteristic method of purifying wastewater.

【0005】本発明において最も注目すべきことは,排
水中の汚濁物質を吸着材に吸着させて排水を浄化する浄
化工程に,吸着材に吸着した汚濁物質を処理槽内の微生
物によって分解して吸着材の吸着能力を再生する再生工
程を追加していることである。
[0005] Most notably, in the present invention, in the purification step of adsorbing pollutants in wastewater to an adsorbent to purify wastewater, the pollutants adsorbed to the adsorbent are decomposed by microorganisms in a treatment tank. That is, a regeneration step for regenerating the adsorption capacity of the adsorbent is added.

【0006】上記汚濁物質の吸着を行う浄化工程と,吸
着材の吸着能力を再生する再生工程とを繰り返すことに
より,吸着材の吸着飽和を避け吸着材の使用期間を長期
化することができる。
[0006] By repeating the purification step of adsorbing the pollutants and the regeneration step of regenerating the adsorption capacity of the adsorbent, adsorption saturation of the adsorbent can be avoided to prolong the service period of the adsorbent.

【0007】即ち,まず,浄化工程において,水中の汚
濁物質に対して吸着能力を有する吸着材を処理槽内に充
填し,ここに汚濁物質を含んだ排水を流入させると,汚
濁物質は吸着材に吸着され,排水中の汚濁物質濃度を低
下させることができる。
That is, first, in a purification step, an adsorbent capable of adsorbing pollutants in water is filled in a treatment tank, and a wastewater containing the pollutants flows into the treatment tank. To reduce the concentration of pollutants in wastewater.

【0008】次に,再生工程において,吸着材の再生に
は微生物を利用し,吸着した汚濁物質を分解することに
より除去している。ここで用いる微生物は排水中に含ま
れる微生物が吸着材で自然繁殖したものを利用すること
もできるし,あらかじめ培養した汚濁分解能力の高い微
生物を吸着材に供給し繁殖したものを利用することもで
きる。
Next, in the regeneration step, microorganisms are used to regenerate the adsorbent, and the adsorbed pollutants are removed by decomposition. The microorganisms used here can be those in which the microorganisms contained in the wastewater are naturally propagated on the adsorbent, or those in which microorganisms with high pollutant decomposition ability that have been pre-cultured are supplied to the adsorbent and propagated. it can.

【0009】また,再生工程においては,吸着材が移動
可能な空間の存在下で,酸素含有気体と浄化水とを処理
槽の下方から,沈降性を有する吸着材に供給することに
よって,吸着材を流動床化している。ここで,吸着材の
流動床化とは,水中で吸着材が下方から供給された酸素
含有気体及び浄化水により押し上げられて,排水を導入
した処理槽の上部に舞い上がり,処理槽の壁面では上方
から下方に移動し,処理槽の下方では壁面から内部へ移
動していく現象をいう。
In the regeneration step, the oxygen-containing gas and the purified water are supplied to the sedimentary adsorbent from below the treatment tank in the presence of a space in which the adsorbent can move, so that the adsorbent is removed. Is fluidized bed. Here, fluidization of the adsorbent means that the adsorbent in water is pushed up by the oxygen-containing gas and purified water supplied from below and rises above the treatment tank into which the wastewater is introduced. This refers to the phenomenon of moving downward from the wall and moving inward from the wall below the processing tank.

【0010】吸着材の流動床化は,吸着材として水中で
沈降性を有する吸着材により生じる。ここで「沈降性」
とは,処理槽の水中において底部付近に吸着材が沈み下
がる性質をいい,吸着材の比重が水よりも重いことによ
り得られる。一方,水中で浮遊する性質をもつ吸着材を
用いる場合には,下方より酸素含有気体と水を供給して
も,下部の吸着材のみが流動床化し,上部での吸着材は
流動しない。また,処理槽に吸着材が移動可能な空間が
ない場合には,流動床化は起こらない。
[0010] Fluidized bed of an adsorbent is caused by an adsorbent which has sedimentation in water as an adsorbent. Here "settling"
The term "adsorbent" means that the adsorbent sinks near the bottom in the water of the treatment tank, and is obtained because the specific gravity of the adsorbent is heavier than water. On the other hand, when an adsorbent having the property of floating in water is used, even if oxygen-containing gas and water are supplied from below, only the lower adsorbent becomes a fluidized bed and the upper adsorbent does not flow. Also, if there is no space in the treatment tank where the adsorbent can move, fluidized bed does not occur.

【0011】かかる吸着材の流動床化は,以下の,
の効果をもたらす。 吸着材の細孔径は一般に微生物よりも小さく微生物
が侵入しにくいため,微生物が細孔内に吸着された汚濁
物質を分解除去することは困難である。しかし,かかる
微小な細孔内に吸着された汚濁物質は,上記吸着材の流
動床化により,吸着材の細孔内の水の拡散が促進され,
汚濁物質の濃度勾配が形成されやすくなる。この濃度勾
配に応じて汚濁物質の離脱,拡散が進行しやすくなる。
細孔内に吸着されていた汚濁物質も細孔外に拡散され,
処理槽内の微生物によって分解可能な状態になる。これ
により,吸着材の吸着能力の再生率が著しく向上する。
[0011] The fluidized bed of the adsorbent is as follows.
Bring the effect. Since the pore diameter of the adsorbent is generally smaller than that of the microorganisms, it is difficult for the microorganisms to invade, and it is difficult for the microorganisms to decompose and remove the pollutants adsorbed in the pores. However, the contaminants adsorbed in these fine pores promote the diffusion of water in the pores of the adsorbent due to the fluidized bed of the adsorbent.
A concentration gradient of pollutants is easily formed. The detachment and diffusion of the pollutant are facilitated in accordance with the concentration gradient.
The pollutants adsorbed in the pores are also diffused out of the pores,
The state can be decomposed by microorganisms in the processing tank. As a result, the regeneration rate of the adsorption capacity of the adsorbent is significantly improved.

【0012】 上記流動床化によって,吸着材の固化
の防止及び吸着飽和の防止が可能となり,高い吸着浄化
性能を長期間維持することができる。これに対して,酸
素含有気体及び浄化水の供給は行うが,吸着材が移動可
能な空間をなくし,流動床化を行わない条件で汚濁物質
の吸着工程と吸着材の再生工程とを繰り返すと,吸着材
に過剰繁殖した微生物によって,吸着材が固化した状態
となり,目詰まりが発生し,浄化性能が著しく低下す
る。
[0012] The fluidized bed makes it possible to prevent the adsorbent from solidifying and prevent adsorption saturation, and to maintain high adsorption purification performance for a long period of time. On the other hand, when the oxygen-containing gas and purified water are supplied, the space where the adsorbent can move is eliminated, and the pollutant adsorption process and the adsorbent regeneration process are repeated under the condition that the fluidized bed is not used. In addition, the adsorbent becomes a solidified state due to the microorganisms that have excessively propagated in the adsorbent, causing clogging and significantly reducing the purification performance.

【0013】また,酸素含有気体を吸着材に供給するこ
とによって,吸着材に繁殖した微生物による酸素の消費
に起因した嫌気化を防止し,吸着材を好気的な条件に保
つことが可能となる。これによって微生物による汚濁物
質の分解活性を高く保つことができ,吸着材から離脱し
た汚濁物質をすみやかに分解し,吸着材からの汚濁物質
の離脱を一層促進させることができる。
Further, by supplying an oxygen-containing gas to the adsorbent, it is possible to prevent anaerobicity caused by consumption of oxygen by microorganisms propagated on the adsorbent and to keep the adsorbent under aerobic conditions. Become. As a result, the activity of decomposing pollutants by microorganisms can be kept high, and the pollutants released from the adsorbent can be immediately decomposed to further promote the release of the pollutants from the adsorbent.

【0014】次に,再度の浄化工程において,下方より
酸素含有気体の供給を停止することによって,吸着材の
流動床化を停止させる。流動床化の停止により,吸着材
は直ちに沈降し密な充填状態をとる。ここに排水を流入
させると,吸着材の充填状態が密である分,高い効率で
吸着材への汚濁物質の吸着が起こり,高い浄化性能が得
られる。これに対して,水中で浮遊する性質をもつ吸着
材を用いた場合には,密な充填状態をとることができ
ず,吸着効率が低い。
Next, in the purification step again, the supply of the oxygen-containing gas from below is stopped to stop the formation of the fluidized bed of the adsorbent. When the fluidized bed is stopped, the adsorbent immediately sediments and assumes a densely packed state. When the wastewater flows in, the pollutant is adsorbed on the adsorbent with high efficiency because the packed state of the adsorbent is dense, and high purification performance is obtained. On the other hand, when an adsorbent having the property of floating in water is used, a densely packed state cannot be obtained, and the adsorption efficiency is low.

【0015】以上のように本発明によれば,吸着材の吸
着能力を処理槽内で再生することが可能となり,吸着材
の使用期間の長期化が図れると共に,高濃度の汚濁物質
を含む排水に対しても適用可能な排水の浄化方法を提供
することができる。
As described above, according to the present invention, the adsorbing capacity of the adsorbent can be regenerated in the treatment tank, the service life of the adsorbent can be prolonged, and wastewater containing high-concentration pollutants can be obtained. It is possible to provide a method of purifying wastewater which can be applied to wastewater.

【0016】次に,請求項3記載のように,上記再生工
程において,上記処理槽から排出された浄化水を処理槽
外に設けた浄化水貯留槽に導き,過剰に繁殖した微生物
や水難溶性の粒状物を浄化水貯留槽に沈降させて浄化水
から除去した後,該浄化水を上記処理槽に還流すること
が好ましい。
Next, in the regeneration step, the purified water discharged from the treatment tank is guided to a purified water storage tank provided outside the treatment tank in the regeneration step, and the microorganisms and the poorly water-soluble water that have excessively propagated are regenerated. It is preferable that the particulate matter is settled in the purified water storage tank and removed from the purified water, and then the purified water is returned to the treatment tank.

【0017】これにより,流動床化によって吸着材から
剥離させた微生物を処理槽から取り除くことができ,吸
着材への微生物の過剰な蓄積に起因した浄化性能の低下
を防止することができる。また,吸着材に捕捉された汚
濁物質も同時に除去可能であることから,汚濁物質濃度
の高い排水に対しても優れた浄化性能を発揮できる。
Thus, the microorganisms separated from the adsorbent by the fluidized bed can be removed from the treatment tank, and a decrease in purification performance due to excessive accumulation of microorganisms on the adsorbent can be prevented. In addition, since pollutants trapped by the adsorbent can be removed at the same time, excellent purification performance can be exhibited even for wastewater with a high concentration of pollutants.

【0018】処理槽の上部に吸着材が移動可能な空間を
形成し,処理槽の下方より酸素含有気体及び浄化水を供
給すると,吸着材の流動床化がおこる。一方,上記空間
をなくすことにより,吸着材の流動床化が停止する。
When a space in which the adsorbent can move is formed in the upper part of the treatment tank, and the oxygen-containing gas and the purified water are supplied from below the treatment tank, the adsorbent becomes a fluidized bed. On the other hand, elimination of the space stops fluidization of the adsorbent.

【0019】この空間を形成するためには,例えば吸着
材を上部流出防止部材及び下部流出部材により挟持する
構造において,上部流動防止部材を上方に移動させる。
一方,上記空間をなくすためには,上記挟持構造におい
て,上部流動防止部材を下方に移動させる。
In order to form this space, for example, in a structure in which the adsorbent is sandwiched between the upper outflow prevention member and the lower outflow member, the upper flow prevention member is moved upward.
On the other hand, in order to eliminate the space, the upper flow prevention member is moved downward in the sandwiching structure.

【0020】上記空間は,少なくとも吸着材の再生工程
の際には形成されている必要があり,浄化工程の際には
消滅している必要がある。再生工程及び浄化工程を行わ
ない場合には,空間の有無は問わない。
The space needs to be formed at least at the time of the regeneration step of the adsorbent, and must be eliminated at the time of the purification step. When the regeneration step and the purification step are not performed, the presence or absence of a space does not matter.

【0021】ここで,請求項4記載のように,上記吸着
材が移動可能な空間の有無を調節することによって,上
記吸着材の流動床化を間欠的に行うことが好ましい。こ
れにより,吸着材の摩耗による劣化を防止し,吸着材の
使用期間を長期化することができる。
Here, it is preferable that the adsorbent is intermittently made into a fluidized bed by adjusting the presence or absence of a space in which the adsorbent can move. As a result, deterioration of the adsorbent due to wear can be prevented, and the service period of the adsorbent can be extended.

【0022】本発明に用いる吸着材は,排水中の汚濁物
質濃度に応じて汚濁物質を吸着脱離する性質を有し,か
つ水中で沈降性のあるものであれば,どのようなもので
もよい。このような吸着材として,最も好ましい材料
は,請求項5記載のように,活性炭であり,本発明にお
いて有利に使用できる。上記酸素含有気体は,たとえ
ば,空気などがある。
The adsorbent used in the present invention may be of any type as long as it has the property of adsorbing and desorbing pollutants in accordance with the concentration of pollutants in wastewater and has the property of settling in water. . The most preferred material for such an adsorbent is activated carbon, which can be advantageously used in the present invention. The oxygen-containing gas is, for example, air.

【0023】本発明の浄化方法は,請求項7記載のよう
に,たとえば,家庭の厨房排水の浄化に適用できるほ
か,業務用の厨房排水,風呂排水などの浄化にも適用で
きる。
The purification method of the present invention can be applied, for example, to the purification of domestic kitchen drainage, as well as to the purification of commercial kitchen drainage and bath drainage.

【0024】次に,請求項8記載のように,水中で沈降
性を有する吸着材を充填した処理槽と,該処理槽の上部
及び下部に設けた,吸着材の流出を防止するための上部
流出防止部材及び下部流出防止部材と,上記処理槽の下
部に酸素含有気体を供給する酸素含有気体供給手段と,
処理槽の下部に排水又は浄化水を流入させる流入管と,
上記処理槽の上部から浄化水を流出させる流出管と,上
記流出管から排出された浄化水を一時貯留し上記流入管
を通じて処理槽に還流するための浄化水貯留槽とを有す
るとともに,上記処理槽内に排水を流入させ排水中の汚
濁物質を吸着材に吸着させて浄化水を生成し該浄化水を
流出管から排出する浄化工程と,上記浄化水貯留槽から
上記処理槽に浄化水を還流しつつ上記酸素含有気体供給
手段により酸素含有気体を処理槽に供給しながら,上記
上部流出防止部材の上方への移動によって処理槽の上部
に吸着材が移動可能な空間を確保して,吸着材の流動床
を形成させる再生工程とを繰り返す機構を備えることを
特徴とする排水の浄化装置がある。
Next, as set forth in claim 8, a treatment tank filled with an adsorbent having sedimentability in water, and an upper part provided at the upper and lower parts of the treatment tank for preventing the adsorbent from flowing out. An outflow preventing member and a lower outflow preventing member, an oxygen-containing gas supply means for supplying an oxygen-containing gas to a lower portion of the processing tank,
An inflow pipe through which wastewater or purified water flows into the lower part of the treatment tank;
An outlet pipe for discharging purified water from an upper portion of the treatment tank; a purified water storage tank for temporarily storing purified water discharged from the outlet pipe and returning the purified water to the treatment tank through the inlet pipe; A purifying step of flowing wastewater into the tank, adsorbing pollutants in the wastewater with an adsorbent to generate purified water, and discharging the purified water from an outflow pipe, and purifying purified water from the purified water storage tank to the treatment tank. While supplying the oxygen-containing gas to the treatment tank by the oxygen-containing gas supply means while refluxing, a space in which the adsorbent can move is secured above the treatment tank by moving the upper outflow prevention member upward, thereby adsorbing. There is an apparatus for purifying wastewater, which comprises a mechanism for repeating a regeneration step for forming a fluidized bed of material.

【0025】上記浄化装置は,以上に説明した排水の浄
化方法を実現するための装置である。浄化装置は,浄化
を行う処理槽と,浄化水を一旦貯留し処理槽に還流する
浄化水貯留槽とからなり,これらは排水の浄化を行う浄
化工程と,浄化水の還流及び酸素含有気体の供給による
吸着材の再生を行う再生工程とを繰り返し行える機構を
有する。
The above-mentioned purifying apparatus is an apparatus for realizing the above-described method for purifying wastewater. The purification device is composed of a treatment tank for purification and a purified water storage tank for temporarily storing purified water and returning it to the treatment tank. A mechanism capable of repeating a regeneration step of regenerating the adsorbent by supply.

【0026】排水の汚濁物質の吸着により汚れた吸着材
は,再生工程で流動床化により汚濁物質を水中に拡散,
脱離させ微生物でこれを分解し再生される。このため,
本浄化装置によれば,吸着材が適宜再生を受け,長期間
吸着能力を保持できる。また,高濃度の汚濁物質を含む
排水に対しても優れた浄化性能を発揮できる。
The adsorbent contaminated by the adsorption of the pollutants in the wastewater diffuses the pollutants into the water by fluidization in the regeneration step.
It is detached and decomposed by microorganisms to be regenerated. For this reason,
According to the present purification device, the adsorbent is appropriately regenerated, and the adsorption capacity can be maintained for a long time. In addition, it can exhibit excellent purification performance even for wastewater containing high concentrations of pollutants.

【0027】請求項10記載のように,水中で沈降性を
有する吸着材は,たとえば活性炭である。また,本浄化
装置は,請求項12記載のように家庭の厨房排水や風呂
排水の浄化に用いることができる。
[0027] As described in claim 10, the adsorbent having sedimentation in water is, for example, activated carbon. Further, the purifying apparatus can be used for purifying domestic kitchen drainage and bath drainage.

【0028】また,水中で浮上性を有する吸着材を用い
ても本願の課題を解決できる。すなわち,請求項2記載
のように,水中で浮上性を有する吸着材を処理槽内に充
填し,該処理槽内に流入した排水中の汚濁物質を吸着材
に吸着せしめて浄化水を生成する浄化工程と,吸着した
汚濁物質を処理槽内に繁殖させた微生物によって分解す
る再生工程とからなり,上記再生工程において,上記処
理槽の下部に吸着材が移動可能な空間を設け,処理槽の
上方から吸着材に酸素含有気体と浄化水とを供給するこ
とによって吸着材を流動浮上化することを特徴とする排
水の浄化方法がある。
The problem of the present invention can be solved by using an adsorbent having a floating property in water. That is, as described in claim 2, an adsorbent having a floating property in water is filled in a treatment tank, and pollutants in wastewater flowing into the treatment tank are adsorbed by the adsorbent to generate purified water. A purification step and a regeneration step in which the adsorbed pollutants are decomposed by microorganisms propagated in the treatment tank. In the regeneration step, a space in which the adsorbent can move is provided below the treatment tank. There is a method for purifying wastewater, wherein an adsorbent is fluidized and floated by supplying an oxygen-containing gas and purified water to the adsorbent from above.

【0029】この浄化方法は,浮上性を有する吸着材を
用いている点,吸着材が移動可能な空間を処理槽の下部
に設ける点,酸素含有気体を処理槽の上方から供給する
点で,上記水中で沈降性を有する吸着材を用いる浄化方
法と相違する。
This purification method is characterized in that a floating adsorbent is used, a space in which the adsorbent can move is provided below the processing tank, and an oxygen-containing gas is supplied from above the processing tank. This is different from the purification method using an adsorbent having sedimentation in water.

【0030】この浄化方法の再生工程において,水中で
浮上性を有する吸着材に,吸着材が移動可能な空間の存
在下で,酸素含有気体と浄化水とを処理槽の上方から供
給することによって,吸着材を流動浮上化している。
In the regeneration step of this purification method, an oxygen-containing gas and purified water are supplied to the adsorbent having a floating property in water from above the treatment tank in the presence of a space in which the adsorbent can move. In addition, the adsorbent is fluidized and floated.

【0031】上記流動浮上化とは,水中で吸着材が,上
方から供給された酸素含有気体及び浄化水により押し下
げられて,処理槽の上部から下方に舞い沈み,処理槽の
壁面では下方から上方に移動し,処理槽の上方では壁面
から内部へ移動していく現象をいう。流動浮上化と上記
流動床化とは,水中における吸着材の流れが逆の関係に
ある。かかる吸着材の流動浮上化は,上記流動床化と同
様の優れた再生効果をもたらす。
The above-mentioned flow flotation means that the adsorbent is depressed in water by the oxygen-containing gas and purified water supplied from above, so that it sinks downward from the upper part of the processing tank, and sinks from below on the wall surface of the processing tank. , And above the processing tank, from the wall to the inside. Fluid levitation and the above fluidized bed have the opposite relationship of the flow of adsorbent in water. The fluidized floating of the adsorbent provides the same excellent regenerating effect as the fluidized bed.

【0032】次に,再度の浄化工程において,上方より
酸素含有気体の供給を停止することにより,吸着材の流
動浮上化が停止させる。すると,吸着材は直ちに浮上し
密な充填状態をとる。ここに排水を流入させると,充填
状態が密である分,高効率で吸着材への水中汚濁物質の
吸着が起こり,高い浄化性能が得られる。以上のよう
に,水中で浮上性を有する吸着材を用いても,水中で沈
降性を有する吸着材と同様に優れた再生力を有し,長期
間の使用が可能となり,また高効率での吸着性能を発揮
できる。請求項6記載のように,上記水中で浮上性を有
する吸着材としては,ポリウレタンフォームを用いるこ
とが好ましい。
Next, in the purification step again, the supply of the oxygen-containing gas from above is stopped, so that the flow floating of the adsorbent is stopped. Then, the adsorbent immediately floats and assumes a densely packed state. When the wastewater is introduced into the tank, the polluted substances in the water are adsorbed to the adsorbent with high efficiency because the packing state is dense, and high purification performance is obtained. As described above, even when an adsorbent having a floating property in water is used, it has excellent regenerative power as well as an adsorbent having sedimentation in water, and can be used for a long period of time. Adsorption performance can be demonstrated. As described in claim 6, it is preferable to use a polyurethane foam as the adsorbent having a floating property in water.

【0033】また,上記水中で浮上性を有する吸着材を
用いる浄化方法を実現するための装置としては,請求項
9記載のように,水中で浮上性を有する吸着材を充填し
た処理槽と,該処理槽の上部及び下部に設けた,吸着材
の流出を防止するための上部流出防止部材及び下部流出
防止部材と,上記処理槽の上部に酸素含有気体を供給す
る酸素含有気体供給手段と,処理槽の上部に排水又は浄
化水を流入させる流入管と,上記処理槽の下部から浄化
水を流出させる流出管と,上記流出管から排出された浄
化水を一時貯留し上記流入管を通じて処理槽に還流する
ための浄化水貯留槽とを有するとともに,上記処理槽内
に排水を流入させ排水中の汚濁物質を吸着材に吸着させ
て浄化水を生成し該浄化水を流出管から排出する浄化工
程と,上記浄化水貯留槽から上記処理槽に浄化水を還流
しつつ上記酸素含有気体供給手段により酸素含有気体を
処理槽に供給しながら,上記下部流出防止部材の下方へ
の移動によって処理槽の下部に吸着材が移動可能な空間
を確保して,吸着材の流動浮上を形成させる再生工程と
を繰り返す機構を備えることを特徴とする排水の浄化装
置がある。
Further, as an apparatus for realizing the purification method using the adsorbent having a floating property in water, there are provided a treatment tank filled with an adsorbent having a floating property in water, An upper outflow prevention member and a lower outflow prevention member provided at an upper portion and a lower portion of the processing tank for preventing the adsorbent from flowing out; an oxygen-containing gas supply means for supplying an oxygen-containing gas to the upper portion of the processing tank; An inflow pipe through which drainage or purified water flows into the upper part of the treatment tank, an outflow pipe through which purified water flows out from the lower part of the treatment tank, and a purification tank through which the purified water discharged from the outflow pipe is temporarily stored and the inflow pipe flows And a purified water storage tank for returning purified water to the treatment tank. The wastewater flows into the treatment tank, pollutants in the wastewater are adsorbed by an adsorbent to generate purified water, and the purified water is discharged from an outlet pipe. Process and the above purified water While supplying purified oxygen from the detention tank to the treatment tank and supplying oxygen-containing gas to the treatment tank by the oxygen-containing gas supply means, the adsorbent is moved to the lower part of the treatment tank by the downward movement of the lower outflow prevention member. There is an apparatus for purifying wastewater, which is provided with a mechanism for repeating a regeneration step for securing a movable space and forming a floating flow of an adsorbent.

【0034】上記浄化装置は,浮上性を有する吸着材を
用いている点,酸素含有気体供給手段を処理槽の上部に
設けている点,排水又は浄化水を流入させる流入管を処
理槽の上部に設けている点,浄化水を流出させる流出管
を処理槽の下部に設けている点で,上記水中で沈降性を
有する吸着材を用いる浄化装置と相違する。
The above-mentioned purifying apparatus is characterized in that a floating adsorbent is used, an oxygen-containing gas supply means is provided in the upper part of the processing tank, and an inflow pipe for flowing waste water or purified water is provided in the upper part of the processing tank. And a purification apparatus using an adsorbent having sedimentation in water, in that an outflow pipe for allowing purified water to flow out is provided below the treatment tank.

【0035】排水の汚濁物質を吸着した吸着材は,再生
工程で流動浮上化により汚濁物質を水中に拡散,脱離さ
せ微生物でこれを分解し再生される。このため,本浄化
装置によれば,上記沈降性を有する吸着材を用いる浄化
装置と同様の優れた浄化性能を発揮できる。
The adsorbent that has adsorbed the pollutants in the wastewater is regenerated by diffusing and desorbing the pollutants into the water by flowing and floating in the regeneration step, decomposing the pollutants with microorganisms, and regenerating. For this reason, according to the present purification apparatus, the same excellent purification performance as the purification apparatus using the adsorbent having sedimentation can be exhibited.

【0036】請求項11記載のように,上記水中で浮上
性を有する吸着材はポリウレタンフォームであることが
好ましい。上記水中で浮上性を有する吸着材を用いる浄
化方法及び浄化装置のそのほかの点は,上記沈降性を有
する吸着材を用いる浄化方法及び浄化装置と同様であ
る。
As described in the eleventh aspect, the adsorbent having a floating property in water is preferably a polyurethane foam. Other aspects of the purification method and the purification apparatus using the adsorbent having a floating property in water are the same as those of the purification method and the purification apparatus using the adsorbent having the sedimentation property.

【0037】[0037]

【発明の実施の形態】実施形態例1 本発明の実施形態に係る浄化装置及び浄化方法につい
て,図1〜図4を用いて説明する。本例の浄化装置は,
図1に示すごとく,活性炭4を充填した処理槽1と,処
理槽1の上部及び下部に設けた,活性炭4の流出を防止
するための上部流出防止部材31及び下部流出防止部材
32と,処理槽1の下部に空気を供給するための散気管
7と,処理槽1の下部に排水又は浄化水を流入するため
の流入管5と,処理槽1の上部から浄化水を排出するた
めの流出管6と,流出管6を通じて排出された浄化水を
一時貯留し適宜流入管5を通じて処理槽1に還流するた
めの浄化水貯留槽14とを有する。活性炭4は,水中で
沈降性を有する吸着材である。
DESCRIPTION OF THE PREFERRED EMBODIMENTS First Embodiment A purifying apparatus and a purifying method according to an embodiment of the present invention will be described with reference to FIGS. The purification device of this example is
As shown in FIG. 1, a treatment tank 1 filled with activated carbon 4, an upper outflow prevention member 31 and a lower outflow prevention member 32 provided at the upper and lower portions of the treatment tank 1 for preventing the activated carbon 4 from flowing out, A diffuser pipe 7 for supplying air to the lower part of the tank 1, an inflow pipe 5 for flowing waste water or purified water into the lower part of the processing tank 1, and an outflow for discharging purified water from the upper part of the processing tank 1. It has a pipe 6 and a purified water storage tank 14 for temporarily storing purified water discharged through the outflow pipe 6 and appropriately returning the purified water to the treatment tank 1 through the inflow pipe 5. Activated carbon 4 is an adsorbent having sedimentation in water.

【0038】浄化装置は,処理槽1内に排水を流入させ
排水中の汚濁物質を吸着材に吸着させて浄化水を生成し
浄化水を流出管6から排出する浄化工程と,浄化水貯留
槽14から流入管5を通じて処理槽1に浄化水を還流し
つつ散気管7より空気を活性炭4に供給しながら,上部
流出防止部材31の上方への移動によって処理槽1の上
部に活性炭が移動可能な空間40を確保し,活性炭4の
流動床を間欠的に形成させる再生工程とを繰り返す機構
を備える。
The purifying device includes a purifying step of flowing wastewater into the treatment tank 1, adsorbing pollutants in the wastewater with an adsorbent to generate purified water, and discharging the purified water from the outflow pipe 6. The activated carbon can be moved to the upper part of the processing tank 1 by moving the upper outflow prevention member 31 upward while supplying air from the diffuser pipe 7 to the activated carbon 4 while circulating purified water from the inlet pipe 14 to the processing tank 1 through the inflow pipe 5. And a regeneration process for intermittently forming a fluidized bed of the activated carbon 4.

【0039】処理槽1の内部には上部流出防止部材31
及び下部流出防止部材32を配してあり,この間に活性
炭4が充填されている。上部流出防止部材31及び下部
流出防止部材32は,活性炭の流出を防止し,かつ排水
及び浄化水は透過させる材料,具体的には,ステンレス
製のネットを用いている。上部流出防止部材31は,モ
ータ15により上下移動可能に取付けられている。処理
槽1の下部には,空気供給用の散気管7が配されてい
る。散気管7には,ブロワ8により電磁弁9を経て空気
が供給されるようにしてある。
An upper outflow prevention member 31 is provided inside the processing tank 1.
And a lower outflow prevention member 32, between which the activated carbon 4 is filled. The upper outflow prevention member 31 and the lower outflow prevention member 32 use a material that prevents the outflow of activated carbon and allows the drainage and purified water to permeate, specifically, a stainless steel net. The upper outflow prevention member 31 is mounted to be vertically movable by the motor 15. A diffuser 7 for supplying air is disposed below the processing tank 1. Air is supplied to the air diffuser 7 through a solenoid valve 9 by a blower 8.

【0040】また,処理槽1の下部には流入管5が接続
されている。流入管5は,処理槽1の下部と三方電磁弁
12との間を連結しており,その途中にはポンプ13が
設けられている。
An inflow pipe 5 is connected to a lower portion of the processing tank 1. The inflow pipe 5 connects the lower part of the processing tank 1 and the three-way solenoid valve 12, and a pump 13 is provided in the middle thereof.

【0041】三方電磁弁12は,流入管5と,浄化水貯
留槽14と連結した浄化水供給管55と,排水貯留槽1
1と連結した排水供給管50と連結している。三方電磁
弁12は,浄化水貯留槽14から浄化水供給管55を経
て流出する浄化水と排水送入管50より流入する排水と
を適宜選択して,流入管5に流すように構成されてい
る。
The three-way solenoid valve 12 includes an inflow pipe 5, a purified water supply pipe 55 connected to the purified water storage tank 14, and a drainage storage tank 1.
It is connected to a drainage supply pipe 50 connected to 1. The three-way solenoid valve 12 is configured to appropriately select purified water flowing out of the purified water storage tank 14 via the purified water supply pipe 55 and drainage flowing from the drainage inlet pipe 50 and flow the same to the inflow pipe 5. I have.

【0042】排水供給管50は,排水貯留槽11と連結
している。排水貯留槽11には,水流検知センサ10が
配されている。排水貯留槽11は,排水送入管56より
排水が外部から送入されるように構成されている。水流
検知センサ10は,排水貯留槽11の中での水流の有無
の情報を,三方電磁弁12及び電磁弁9に送信する。
The drainage supply pipe 50 is connected to the drainage storage tank 11. The drainage storage tank 11 is provided with a water flow detection sensor 10. The drainage storage tank 11 is configured so that drainage is supplied from the outside through a drainage inlet pipe 56. The water flow detection sensor 10 transmits information on the presence or absence of a water flow in the drainage storage tank 11 to the three-way solenoid valve 12 and the solenoid valve 9.

【0043】また,処理槽1の上部は,流出管6を介し
て,浄化水貯留槽14と連結している。浄化水貯留槽1
4は,流入した浄化水を適宜取出すための浄化水送出管
60と連結している。
The upper part of the treatment tank 1 is connected to a purified water storage tank 14 through an outflow pipe 6. Purified water storage tank 1
Numeral 4 is connected to a purified water delivery pipe 60 for appropriately taking in the purified water that has flowed in.

【0044】次に,本浄化装置の作用機構を説明する。
排水貯留槽11の中の水流検知センサ10が水流を検出
した場合には,三方電磁弁12を動かして,排水供給管
50と流入管5とを接続して,排水を,排水貯留槽11
及び流入管5を経て,処理槽1の下部に供給する。する
と,図1,図2(a)に示すごとく,排水は,処理槽中
の活性炭4により汚濁物質の吸着除去を受け浄化水とな
る。浄化水は,流出管6から浄化水貯留槽14を経て,
浄化水として排出される。
Next, the operation mechanism of the present purification device will be described.
When the water flow detection sensor 10 in the drainage storage tank 11 detects a water flow, the three-way solenoid valve 12 is operated to connect the drainage supply pipe 50 and the inflow pipe 5, and the drainage is discharged to the drainage storage tank 11.
Then, it is supplied to the lower part of the processing tank 1 through the inflow pipe 5. Then, as shown in FIG. 1 and FIG. 2 (a), the wastewater is converted into purified water by absorbing and removing pollutants by the activated carbon 4 in the treatment tank. Purified water flows from the outflow pipe 6 through the purified water storage tank 14,
Discharged as purified water.

【0045】この時,電磁弁9は水流検知センサ10の
信号により閉じた状態とし,処理槽1に空気が供給され
ないようにする。これにより,活性炭4を通過する排水
の水流を空気の通過によって乱すことを防止でき,活性
炭4の汚濁物質吸着効率を高めることが可能となる。
At this time, the solenoid valve 9 is closed by a signal from the water flow detection sensor 10 so that air is not supplied to the processing tank 1. Thereby, the water flow of the wastewater passing through the activated carbon 4 can be prevented from being disturbed by the passage of air, and the pollutant adsorption efficiency of the activated carbon 4 can be increased.

【0046】また,このとき,上部流出防止部材31
は,モータ15により下方に移動させ,活性炭4の移動
可能な空間を設けないでおく。これにより,活性炭4の
高濃度の充填状態となり,ここに,排水が流入すると,
活性炭4の充填状態が密である分,高効率で活性炭への
汚濁物質の吸着が起こり,高い浄化性能が得られる。
At this time, the upper outflow prevention member 31
Is moved downward by the motor 15 without leaving a space in which the activated carbon 4 can move. As a result, the activated carbon 4 is filled with high concentration, and when wastewater flows into it,
Since the activated carbon 4 is densely packed, pollutants are adsorbed on the activated carbon with high efficiency, and high purification performance is obtained.

【0047】次に,水流検知センサ10が水流を検知し
ない場合は,流入管5は三方電磁弁12によって,排水
貯留槽11側ではなく,浄化水貯留槽14側に連結す
る。すると,浄化水貯留槽14に貯留されている浄化水
が,浄化水供給管55及び流入管5を通じて処理槽1に
供給される。この時,図1,図2(b)に示すごとく,
電磁弁9は開いた状態に制御し,処理槽1に空気を供給
する。これにより処理槽1中の微生物の繁殖が促進され
て活性炭4に吸着した汚濁物質を分解し,活性炭4の吸
着能力が再生される。
Next, when the water flow detecting sensor 10 does not detect a water flow, the inflow pipe 5 is connected to the purified water storage tank 14 side by the three-way solenoid valve 12 instead of the drain water storage tank 11 side. Then, the purified water stored in the purified water storage tank 14 is supplied to the treatment tank 1 through the purified water supply pipe 55 and the inflow pipe 5. At this time, as shown in FIGS. 1 and 2 (b),
The solenoid valve 9 is controlled to be open and supplies air to the processing tank 1. This promotes the growth of microorganisms in the treatment tank 1, decomposes pollutants adsorbed on the activated carbon 4, and regenerates the adsorption capacity of the activated carbon 4.

【0048】この状態において,図2(b)に示すごと
く,モータ15により上部流出防止部材31を上方向に
移動し,上部流出防止部材31と活性炭4との間に空間
40を形成する。すると,散気管7から供給される空気
と流入管5から供給される浄化水とによって活性炭4が
流動床化される。
In this state, as shown in FIG. 2B, the upper outflow preventing member 31 is moved upward by the motor 15 to form a space 40 between the upper outflow preventing member 31 and the activated carbon 4. Then, the activated carbon 4 is made into a fluidized bed by the air supplied from the air diffuser 7 and the purified water supplied from the inlet pipe 5.

【0049】この流動床化によって,活性炭4に付着し
た汚濁物質の脱離,拡散が起こり,処理槽1内の微生物
により分解が行われ,活性炭4の吸着能力の再生が促進
される。また,過剰繁殖した微生物による活性炭4の目
詰まりを防止しかつ浄化性能の低下を防止することが可
能となる。
By this fluidized bed, the pollutants adhering to the activated carbon 4 are desorbed and diffused, the microorganisms in the treatment tank 1 are decomposed, and the regeneration of the adsorption capacity of the activated carbon 4 is promoted. In addition, it is possible to prevent the activated carbon 4 from being clogged by the overgrown microorganisms and to prevent the purification performance from lowering.

【0050】次に,上部流出防止部材31を下方向に移
動し,上部流出防止部材31と活性炭4との間の空間を
設けなくすると,活性炭4の流動床化は停止し,流動床
化に伴う活性炭4の摩耗による劣化を防止することが可
能となる。また,三方電磁弁12を動かして,排水供給
管50と流入管5とを接続して,排水を処理槽1に供給
すると,活性炭4により排水の浄化が再度開始される。
Next, if the upper outflow prevention member 31 is moved downward to provide no space between the upper outflow prevention member 31 and the activated carbon 4, the fluidized bed of the activated carbon 4 is stopped, and the fluidized bed is activated. Thus, it is possible to prevent the activated carbon 4 from being deteriorated due to abrasion. Further, when the three-way solenoid valve 12 is operated to connect the drainage supply pipe 50 and the inflow pipe 5 and supply the wastewater to the treatment tank 1, the purification of the wastewater by the activated carbon 4 is started again.

【0051】次に,上記浄化装置を用いて一般家庭の厨
房排水に対して浄化処理を行った。処理槽1は,直径1
1.2cm,高さ60cmの円筒型で,この中に石炭系
の活性炭5リットルを充填した。この処理槽1を8個用
い,一つの処理槽から排出された浄化水が次の処理槽に
入るように1順次連結した。
Next, using the above-mentioned purification device, purification treatment was performed on kitchen wastewater of ordinary households. Processing tank 1 has a diameter of 1
The cylinder was 1.2 cm in height and 60 cm in height, and was filled with 5 liters of coal-based activated carbon. Eight treatment tanks 1 were used and connected one by one so that purified water discharged from one treatment tank entered the next treatment tank.

【0052】水流検知センサ10により水流が認められ
る場合は,排水貯留槽11に溜まった排水を流速2リッ
トル/分で処理槽1に供給した。水流が認められない場
合は,浄化水貯留槽14に溜まった浄化水を流速2リッ
トル/分で処理槽1に供給し,水が閉じた系内を循環す
るようにした。この間,散気管7より空気を流速2リッ
トル/分で導入した。夜間の水流が認められないとき
に,処理槽1の上部流出防止部材31を上方向に移動
し,活性炭の流動床化を合計1時間行った。このように
して,排水貯留槽11に溜まった排水と浄化水貯留槽1
4から排出される浄化水とを適宜サンプリングし,これ
らのBODを測定した結果を図3に示した。図3及び後
述の図4において,○は排水中のBOD,□は浄化水中
のBODを示す。測定結果より,本発明の浄化処理によ
って,排水基準を大幅に下回るBODが低下した浄化水
が長期間にわたり生成され,この間活性炭の交換を行う
必要はなかった。
When a water flow was detected by the water flow detection sensor 10, the wastewater stored in the wastewater storage tank 11 was supplied to the treatment tank 1 at a flow rate of 2 liter / min. When no water flow was observed, the purified water stored in the purified water storage tank 14 was supplied to the treatment tank 1 at a flow rate of 2 liter / min, so that the water circulated in the closed system. During this time, air was introduced from the air diffuser 7 at a flow rate of 2 L / min. When no water flow at night was observed, the upper outflow prevention member 31 of the treatment tank 1 was moved upward, and the activated carbon was made into a fluidized bed for a total of 1 hour. In this way, the wastewater accumulated in the wastewater storage tank 11 and the purified water storage tank 1
FIG. 3 shows the results obtained by appropriately sampling purified water discharged from Sample No. 4 and measuring their BOD. In FIG. 3 and FIG. 4 described below, ○ indicates BOD in wastewater, and □ indicates BOD in purified water. From the measurement results, it was found that the purification treatment of the present invention produced purified water having a BOD lowered significantly below the effluent standard for a long period of time, during which time it was not necessary to exchange activated carbon.

【0053】これに対して,上部流動防止部材を下方に
移動させておき流動床化を行わなかった場合(比較例)
についても同様の試験を行い,その結果を図4に示し
た。この場合には,10日前後を経過すると排水が活性
炭を通過する際の圧力損失が増加すると共に,浄化性能
の大幅な低下が認められるようになった。この原因は,
微生物の過剰繁殖による活性炭層の目詰まりと考えられ
る。以上より,活性炭層の目詰まりを防止するために,
活性炭の流動床化が極めて有効に作用していることがわ
かる。
On the other hand, the case where the upper flow preventing member was moved downward and the fluidized bed was not formed (comparative example)
A similar test was conducted for the test results, and the results are shown in FIG. In this case, after about 10 days had passed, the pressure loss when the wastewater passed through the activated carbon increased, and a significant decrease in purification performance was observed. This is because
It is considered that the activated carbon layer was clogged due to overgrowth of microorganisms. From the above, to prevent clogging of the activated carbon layer,
It can be seen that the fluidized bed of activated carbon works extremely effectively.

【0054】本例の浄化方法および浄化装置で排水を処
理することによって,次のような効果が得られる。 1.活性炭の使用期限を大幅に延長することができる。 2.汚濁物質濃度の高い排水の処理が可能になった。B
ODが600ppm程度の汚濁物質濃度が高い排水につ
いても,これを排水基準値以下に浄化することができ
る。 3.処理装置の大幅な小型化が可能になった。処理槽本
体のみ比較すると,槽容積を接触曝気方式の1/25に
できる。
The following effects can be obtained by treating wastewater with the purification method and the purification device of the present embodiment. 1. The expiration date of activated carbon can be greatly extended. 2. It is possible to treat wastewater with a high concentration of pollutants. B
Even wastewater with a high pollutant concentration of about 600 ppm OD can be purified to a wastewater standard value or less. 3. The processing apparatus can be significantly reduced in size. Comparing only the processing tank body, the tank volume can be reduced to 1/25 of the contact aeration method.

【図面の簡単な説明】[Brief description of the drawings]

【図1】実施形態例1の浄化装置を示す模式図。FIG. 1 is a schematic view showing a purification device according to a first embodiment.

【図2】実施形態例1の浄化方法の,浄化工程(a)及
び再生工程(b)を示す模式図。
FIG. 2 is a schematic view showing a purification step (a) and a regeneration step (b) of the purification method according to the first embodiment.

【図3】実施形態例1の浄化装置により浄化された浄化
水のBODを示す特性図。
FIG. 3 is a characteristic diagram showing a BOD of purified water purified by the purification device of the first embodiment.

【図4】比較例の浄化装置により浄化された浄化水のB
ODを示す特性図。
FIG. 4 shows purified water B purified by a purification device of a comparative example.
FIG. 4 is a characteristic diagram showing OD.

【符号の説明】[Explanation of symbols]

1...処理槽, 10...水流検知センサ, 11...排水貯留槽, 12...三方電磁弁, 13...ポンプ, 14...浄化水貯留槽, 15...モータ, 31...上部流出防止部材, 32...下部流出防止部材, 4...活性炭, 40...空間, 5...流入管, 6...流出管, 7...散気管, 8...ブロワ, 81...空気, 9...電磁弁, 1. . . Processing tank, 10. . . 10. water flow detection sensor, . . 11. drainage storage tank, . . 12. three-way solenoid valve; . . Pump, 14. . . 14. Purified water storage tank, . . Motor, 31. . . Upper outflow prevention member, 32. . . Lower outflow prevention member, 4. . . Activated carbon, 40. . . Space, 5. . . 5. Inflow pipe, . . Outflow pipe, 7. . . 7. diffuser tube; . . Blower, 81. . . Air, 9. . . solenoid valve,

───────────────────────────────────────────────────── フロントページの続き (72)発明者 久野 斉 愛知県刈谷市昭和町1丁目1番地 株式会 社デンソー内 Fターム(参考) 4D003 AA01 AB02 AB08 DA08 DA09 DA14 DA15 DA18 DA21 DA29 DA30 EA19 EA25 EA30 FA01 FA05 FA06  ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Hitoshi Kuno 1-1-1, Showa-cho, Kariya-shi, Aichi F-term in DENSO Corporation (reference) 4D003 AA01 AB02 AB08 DA08 DA09 DA14 DA15 DA18 DA21 DA29 DA30 EA19 EA25 EA30 FA01 FA05 FA06

Claims (12)

【特許請求の範囲】[Claims] 【請求項1】 水中で沈降性を有する吸着材を処理槽内
に充填し,該処理槽内に流入した排水中の汚濁物質を吸
着材に吸着せしめて浄化水を生成する浄化工程と,吸着
した汚濁物質を処理槽内に繁殖させた微生物によって分
解する再生工程とからなり,上記再生工程において,上
記処理槽の上部に吸着材が移動可能な空間を設け,処理
槽の下方から吸着材に酸素含有気体と浄化水とを供給す
ることによって吸着材を流動床化することを特徴とする
排水の浄化方法。
A purification step of filling a treatment tank with an adsorbent having sedimentation property in water and adsorbing pollutants in wastewater flowing into the treatment tank to the adsorbent to produce purified water; A regeneration step in which the contaminated substances are decomposed by microorganisms propagated in the treatment tank. In the regeneration step, a space in which the adsorbent can move is provided above the treatment tank, and the adsorbent is supplied from below the treatment tank. A method for purifying wastewater, comprising forming an adsorbent into a fluidized bed by supplying an oxygen-containing gas and purified water.
【請求項2】 水中で浮上性を有する吸着材を処理槽内
に充填し,該処理槽内に流入した排水中の汚濁物質を吸
着材に吸着せしめて浄化水を生成する浄化工程と,吸着
した汚濁物質を処理槽内に繁殖させた微生物によって分
解する再生工程とからなり,上記再生工程において,上
記処理槽の下部に吸着材が移動可能な空間を設け,処理
槽の上方から吸着材に酸素含有気体と浄化水とを供給す
ることによって吸着材を流動浮上化することを特徴とす
る排水の浄化方法。
2. A purification step of filling a treatment tank with an adsorbent having buoyancy in water and adsorbing pollutants in wastewater flowing into the treatment tank to the adsorbent to produce purified water. A regeneration step in which the contaminated substances are decomposed by microorganisms propagated in the treatment tank. In the regeneration step, a space is provided below the treatment tank where the adsorbent can move, and the adsorbent is transferred from above the treatment tank to the adsorbent. A method for purifying wastewater, comprising supplying an oxygen-containing gas and purified water to fluidize and float an adsorbent.
【請求項3】 請求項1又は2において,上記再生工程
において,上記処理槽から排出された浄化水を処理槽外
に設けた浄化水貯留槽に導き,過剰に繁殖した微生物や
水難溶性の粒状物を浄化水貯留槽に沈降させて浄化水か
ら除去した後,該浄化水を上記処理槽に還流することを
特徴とする排水の浄化方法。
3. The method according to claim 1, wherein in the regeneration step, purified water discharged from the treatment tank is guided to a purified water storage tank provided outside the treatment tank, and excessively propagated microorganisms and hardly water-soluble particulates are collected. A method for purifying wastewater, comprising: causing a substance to settle in a purified water storage tank and removing it from the purified water, and then returning the purified water to the treatment tank.
【請求項4】 請求項1又は2において,上記吸着材が
移動可能な空間の有無を調節することによって,上記吸
着材の流動床化を間欠的に行うことを特徴とする排水の
浄化方法。
4. The method for purifying wastewater according to claim 1, wherein the adsorbent is intermittently made into a fluidized bed by adjusting the presence or absence of a space in which the adsorbent can move.
【請求項5】請求項1において,上記水中で沈降性を有
する吸着材は活性炭であることを特徴とする排水の浄化
方法。
5. A method according to claim 1, wherein the adsorbent having sedimentation in water is activated carbon.
【請求項6】 請求項2において,上記水中で浮上性を
有する吸着材はポリウレタンフォームであることを特徴
とする排水の浄化方法。
6. The method according to claim 2, wherein the adsorbent having a floating property in water is a polyurethane foam.
【請求項7】 請求項1〜5のいずれか1項において,
上記排水は,家庭の厨房排水または/及び風呂排水であ
ることを特徴とする排水の浄化方法。
7. The method according to claim 1, wherein:
A method for purifying wastewater, wherein the wastewater is domestic kitchen wastewater and / or bath wastewater.
【請求項8】 水中で沈降性を有する吸着材を充填した
処理槽と,該処理槽の上部及び下部に設けた,吸着材の
流出を防止するための上部流出防止部材及び下部流出防
止部材と,上記処理槽の下部に酸素含有気体を供給する
酸素含有気体供給手段と,処理槽の下部に排水又は浄化
水を流入させる流入管と,上記処理槽の上部から浄化水
を流出させる流出管と,上記流出管から排出された浄化
水を一時貯留し上記流入管を通じて処理槽に還流するた
めの浄化水貯留槽とを有するとともに,上記処理槽内に
排水を流入させ排水中の汚濁物質を吸着材に吸着させて
浄化水を生成し該浄化水を流出管から排出する浄化工程
と,上記浄化水貯留槽から上記処理槽に浄化水を還流し
つつ上記酸素含有気体供給手段により酸素含有気体を処
理槽に供給しながら,上記上部流出防止部材の上方への
移動によって処理槽の上部に吸着材が移動可能な空間を
確保して,吸着材の流動床を形成させる再生工程とを繰
り返す機構を備えることを特徴とする排水の浄化装置。
8. A treatment tank filled with an adsorbent having sedimentation in water, and an upper outflow prevention member and a lower outflow prevention member provided at an upper portion and a lower portion of the treatment bath for preventing outflow of the adsorbent. An oxygen-containing gas supply means for supplying an oxygen-containing gas to a lower portion of the processing tank, an inflow pipe for flowing wastewater or purified water to a lower part of the processing tank, and an outflow pipe for flowing purified water from the upper part of the processing tank. A purified water storage tank for temporarily storing purified water discharged from the outflow pipe and returning the purified water to the processing tank through the inflow pipe, and injecting wastewater into the processing tank to adsorb pollutants in the wastewater. A purification step of producing purified water by adsorbing the purified water and discharging the purified water from an outlet pipe; and supplying oxygen-containing gas by the oxygen-containing gas supply means while refluxing purified water from the purified water storage tank to the treatment tank. While supplying to the processing tank And a mechanism for repeating a regeneration step of forming a fluidized bed of the adsorbent by securing a space in which the adsorbent can move above the treatment tank by moving the upper outflow prevention member upward. Wastewater purification equipment.
【請求項9】 水中で浮上性を有する吸着材を充填した
処理槽と,該処理槽の上部及び下部に設けた,吸着材の
流出を防止するための上部流出防止部材及び下部流出防
止部材と,上記処理槽の上部に酸素含有気体を供給する
酸素含有気体供給手段と,処理槽の上部に排水又は浄化
水を流入させる流入管と,上記処理槽の下部から浄化水
を流出させる流出管と,上記流出管から排出された浄化
水を一時貯留し上記流入管を通じて処理槽に還流するた
めの浄化水貯留槽とを有するとともに,上記処理槽内に
排水を流入させ排水中の汚濁物質を吸着材に吸着させて
浄化水を生成し該浄化水を流出管から排出する浄化工程
と,上記浄化水貯留槽から上記処理槽に浄化水を還流し
つつ上記酸素含有気体供給手段により酸素含有気体を処
理槽に供給しながら,上記下部流出防止部材の下方への
移動によって処理槽の下部に吸着材が移動可能な空間を
確保して,吸着材の流動浮上を形成させる再生工程とを
繰り返す機構を備えることを特徴とする排水の浄化装
置。
9. A treatment tank filled with an adsorbent having a floating property in water, and an upper outflow prevention member and a lower outflow prevention member provided at an upper part and a lower part of the treatment tank for preventing outflow of the adsorbent. An oxygen-containing gas supply means for supplying an oxygen-containing gas to the upper part of the processing tank, an inflow pipe for flowing waste water or purified water into the upper part of the processing tank, and an outlet pipe for discharging purified water from the lower part of the processing tank. A purified water storage tank for temporarily storing purified water discharged from the outflow pipe and returning the purified water to the processing tank through the inflow pipe, and injecting wastewater into the processing tank to adsorb pollutants in the wastewater. A purification step of producing purified water by adsorbing the purified water and discharging the purified water from an outlet pipe; and supplying oxygen-containing gas by the oxygen-containing gas supply means while refluxing purified water from the purified water storage tank to the treatment tank. While supplying to the processing tank A mechanism for securing a space in which the adsorbent can move below the treatment tank by moving the lower outflow prevention member downward, and repeating a regeneration process for forming a floating flow of the adsorbent. Wastewater purification equipment.
【請求項10】 請求項8において,上記水中で沈降性
を有する吸着材は活性炭であることを特徴とする排水の
浄化装置。
10. The waste water purifying apparatus according to claim 8, wherein the adsorbent having sedimentation in water is activated carbon.
【請求項11】 請求項9において,上記水中で浮上性
を有する吸着材はポリウレタンフォームであることを特
徴とする排水の浄化装置。
11. An apparatus according to claim 9, wherein said adsorbent having a floating property in water is a polyurethane foam.
【請求項12】 請求項8又は9において,上記排水
は,家庭の厨房排水又は/風呂排水であることを特徴と
する排水の浄化装置。
12. The wastewater purifying apparatus according to claim 8, wherein the wastewater is domestic kitchen wastewater and / or bath wastewater.
JP11008251A 1999-01-14 1999-01-14 Cleaning method and device for waste water Pending JP2000202482A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11008251A JP2000202482A (en) 1999-01-14 1999-01-14 Cleaning method and device for waste water

Publications (1)

Publication Number Publication Date
JP2000202482A true JP2000202482A (en) 2000-07-25

Family

ID=11687928

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2000202482A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012528716A (en) * 2009-06-03 2012-11-15 バイオウォーター テクノロジー エーエス Method and reactor for biological purification of wastewater
JP2017064587A (en) * 2015-09-28 2017-04-06 王子ホールディングス株式会社 Carrier for water treatment and water treatment method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012528716A (en) * 2009-06-03 2012-11-15 バイオウォーター テクノロジー エーエス Method and reactor for biological purification of wastewater
JP2015145006A (en) * 2009-06-03 2015-08-13 バイオウォーター テクノロジー エーエス Method for biological purification of waste water and reactor
US9758402B2 (en) 2009-06-03 2017-09-12 Biowater Technology AS Method and reactor for biological purification of waste water
JP2017064587A (en) * 2015-09-28 2017-04-06 王子ホールディングス株式会社 Carrier for water treatment and water treatment method

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