JP2000169908A - Electric furnace provided with device for blowing gas to hearth - Google Patents

Electric furnace provided with device for blowing gas to hearth

Info

Publication number
JP2000169908A
JP2000169908A JP10343030A JP34303098A JP2000169908A JP 2000169908 A JP2000169908 A JP 2000169908A JP 10343030 A JP10343030 A JP 10343030A JP 34303098 A JP34303098 A JP 34303098A JP 2000169908 A JP2000169908 A JP 2000169908A
Authority
JP
Japan
Prior art keywords
gas
metal
electric furnace
plate
melting point
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10343030A
Other languages
Japanese (ja)
Inventor
Naohiko Ogino
荻野直彦
Akitaka Ikefuchi
池淵明孝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shinagawa Refractories Co Ltd
Original Assignee
Shinagawa Refractories Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shinagawa Refractories Co Ltd filed Critical Shinagawa Refractories Co Ltd
Priority to JP10343030A priority Critical patent/JP2000169908A/en
Publication of JP2000169908A publication Critical patent/JP2000169908A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Vertical, Hearth, Or Arc Furnaces (AREA)

Abstract

PROBLEM TO BE SOLVED: To prevent a pipe for gas ejection from being clogged, and to easily and inexpensively recover a metal of low melting point by installing a metallic plate having a plurality of gas holes and provided with a plurality of hole to recover the metal of low melting point in its periphery on a hearth plate so as to cover an opening formed in the hearth of an electric furnace. SOLUTION: A hearth of an electric furnace is provided with an opening 10a for blowing the stirring gas and discharging the metal of low melting point such as lead contained in a molten metal. A stirring gas blowing device 12 provided with a gas inlet pipe 12a to be communicated with the opening, and a low melting point metallic trap 13 integrated therewith are fitted to the outside of the opening 10a, and a semi- spherical metallic plate 11 is installed on an electric furnace hearth plate 10 so as to cover the trap inside thereof. A plurality of gas holes 11a to eject the stirring gas is formed in the metallic plate 11, a plurality of holes 11b to recover the metal of low melting point are formed in the periphery thereof, and a stamp material 15 is filled between the metallic plate 11 and the hearth plate 10. The periphery of the gas holes 11a, and the periphery of the holes 11b are filled with a gas permeable stamp material, and a gas non-permeable and dense stamp material respectively.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は炉底、炉床を介して
金属溶湯中に撹拌用ガスを吹き込む装置を備えた電気炉
に関わり、特に金属溶湯中に含まれる鉛等の低融点金属
及びそれらの合金(以下、低融点金属)を炉外に回収で
きるようにした電気炉に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an electric furnace provided with a device for blowing a stirring gas into a molten metal through a furnace bottom and a hearth, and more particularly to a low melting point metal such as lead contained in the molten metal. The present invention relates to an electric furnace capable of recovering those alloys (hereinafter, low melting point metals) outside the furnace.

【0002】[0002]

【従来の技術】電気炉による製鋼では炉床あるいは炉底
のガス吹き込み口から溶鋼中に不活性ガスを吹き込んで
溶鋼を撹拌し、不純物を除去して溶鋼を均質化し、さら
に冶金反応を促進するようにしている。このような電気
炉に用いられるガス吹き込み装置の概略を図5により説
明すると、図5(a)に示すように、炉床1を形成する
永久ライニング3を設けない領域を形成し、この部分の
炉底板2の直上に直接、例えば渦巻き状のガス噴出用パ
イプ6を配置し,その上にラミング材(スタンプ材)を
充填して消耗ライニング4を形成する。図5(b)に示
すように、ガス噴出用パイプ6は所定の径を有する一巻
き、あるいは複数巻きのもので、複数のガス噴出口6a
が設けられている。このパイプは炉底に通常複数箇所に
設置される。ガス供給管5より供給されたガスはガス噴
出用パイプ6のガス噴出口6aから噴出し、消耗ライニ
ング4の中を通って溶鋼中を泡状になって上昇し、溶鋼
を撹拌する。
2. Description of the Related Art In steelmaking by an electric furnace, an inert gas is blown into molten steel from a hearth or a gas inlet at the bottom of the furnace to stir the molten steel, remove impurities, homogenize the molten steel, and further promote a metallurgical reaction. Like that. The outline of the gas blowing device used in such an electric furnace will be described with reference to FIG. 5. As shown in FIG. 5A, a region where the permanent lining 3 forming the hearth 1 is not formed is formed. A spiral gas ejection pipe 6 is disposed directly above the furnace bottom plate 2, for example, and a consumable lining 4 is formed by filling a ramming material (stamp material) thereon. As shown in FIG. 5 (b), the gas ejection pipe 6 has a single diameter or a plurality of diameters having a predetermined diameter.
Is provided. This pipe is usually installed at a plurality of places in the furnace bottom. The gas supplied from the gas supply pipe 5 is spouted from the gas spout 6 a of the gas spouting pipe 6, passes through the consumable lining 4, rises in the molten steel in a foamy state, and stirs the molten steel.

【0003】しかし、このようなガス吹き込み装置で
は、パイプの周辺に低融点金属蒸気が高濃度に浮遊し、
これがパイプに触れて冷却されると凝固し、供給パイプ
内に低融点金属が詰まって、パイプの閉塞状態を起こし
やすい。そこで本出願人は、ガス噴出用パイプの周囲に
冷却フィンを配置して冷却媒体を供給することにより低
融点金属を凝固させ、また冷却媒体の流量をコントロー
ルして温度を上昇させ、凝固した金属を解かして回収す
るようにしたものを提案している(特開平9ー2363
87号公報)。また、特表平6ー503873号公報の
図3には、開口の上に複数のガス孔を設けた箱状のガス
分配装置を用いた実施例が開示されている。
However, in such a gas blowing device, a low-melting metal vapor floats at a high concentration around the pipe,
When this is cooled by touching the pipe, it solidifies, and the low melting point metal is clogged in the supply pipe, and the pipe is easily clogged. Therefore, the present applicant arranges cooling fins around the gas ejection pipe and supplies a cooling medium to solidify the low-melting-point metal, and also controls the flow rate of the cooling medium to raise the temperature and increase the temperature of the solidified metal. Is proposed to solve the problem (Japanese Patent Laid-Open No. 9-2363).
No. 87). FIG. 3 of JP-T-6-503873 discloses an embodiment using a box-shaped gas distribution device provided with a plurality of gas holes above an opening.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、従来の
炉底ガス吹き込み装置を備えた電気炉においては、低融
点金属の凝縮によりガス噴出用パイプが閉塞しやすく、
これを回避すべく冷却フィンを設けたものは形状、構造
が複雑となり、そのためコストアップとなって普及しに
くいという問題があった。また、特表平6ー50387
3号公報の形態においても、低融点金属が分配装置上で
凝固し、ガス孔をふさぐ恐れがあり、また低融点金属を
除去、回収するためには炉底耐火物を解体する必要があ
る。
However, in a conventional electric furnace equipped with a bottom gas injection device, the gas ejection pipe is liable to be clogged due to condensation of the low melting point metal,
In order to avoid this, a device provided with cooling fins has a problem in that the shape and structure are complicated, which increases the cost and makes it difficult to spread the device. In addition, Japanese Patent Translation No. Hei 6-50387
Also in the form of JP-A No. 3 (KOKAI), the low-melting point metal may be solidified on the distribution device and block the gas holes, and it is necessary to disassemble the furnace bottom refractory to remove and recover the low-melting point metal.

【0005】本発明は上記課題を解決するためのもの
で、ガス噴出用パイプの閉塞を防止し、かつ構成が簡単
で安価であり、低融点金属の回収を行える炉底ガス吹き
込み装置を備えた電気炉を提供することを目的とする。
SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and has a furnace bottom gas blowing device capable of preventing blockage of a gas discharge pipe, having a simple structure and being inexpensive, and capable of recovering a low melting point metal. It is intended to provide an electric furnace.

【0006】[0006]

【課題を解決するための手段】請求項1の発明は、炉底
に撹拌用ガス吹き込みと低融点金属排出用の開口が形成
された電気炉において、複数のガス孔が形成され、周囲
に複数の低融点金属抜き孔が形成された金属板を前記開
口を覆うように炉底板上に設置したことを特徴とする。
請求項2の発明は、前記開口上に吹き込むガスの流れの
向きを変える偏向板を設置したことを特徴とする。請求
項3の発明は、金属板と炉底板との間にスタンプ材を充
填したことを特徴とする。請求項4の発明は、金属板外
側に充填されるスタンプ材は、ガス孔が形成された部分
の周囲はガス透過性のよいスタンプ材、低融点金属抜き
孔が形成された部分の周囲は、ガスが透過しにい緻密な
スタンプ材であることを特徴とする。
According to a first aspect of the present invention, there is provided an electric furnace having an opening for blowing a stirring gas and discharging a low-melting-point metal at the bottom of the furnace. The metal plate in which the low melting point metal hole is formed is set on the furnace bottom plate so as to cover the opening.
The invention according to claim 2 is characterized in that a deflection plate for changing the direction of the flow of the gas blown onto the opening is provided. The invention according to claim 3 is characterized in that a stamp material is filled between the metal plate and the furnace bottom plate. According to a fourth aspect of the present invention, in the stamp material filled on the outside of the metal plate, the periphery of the portion where the gas hole is formed is a stamp material having good gas permeability, and the periphery of the portion where the low melting point metal hole is formed is: It is characterized by being a dense stamp material that is difficult for gas to permeate.

【0007】[0007]

【発明の実施の形態】以下、本発明の実施の形態につい
て説明する。図1は本発明の電気炉底部のガス吹き込み
部を説明する図で、図1(a)は断面図、図1(b)は
本発明で使用する半球状金属板の平面図である。図1
(a)において、炉底板10には、ガスを吹き込むとと
もに、鉛等の低融点金属を排出させるための開口10a
が形成され、炉底板の外部には開口10aを囲むように
不活性ガスを導入するためのガス導入管12aを備えた
ガス吹き込み装置12が取付けられている。ガス吹き込
み装置12の下側には、排出された鉛等の低融点金属を
捕捉するための低融点金属トラップ13が取り付けられ
ている。
Embodiments of the present invention will be described below. FIG. 1 is a view for explaining a gas blowing portion at the bottom of an electric furnace according to the present invention. FIG. 1A is a sectional view, and FIG. 1B is a plan view of a hemispherical metal plate used in the present invention. FIG.
1A, an opening 10a through which gas is blown into a furnace bottom plate 10 and a low melting point metal such as lead is discharged.
A gas blowing device 12 having a gas introduction pipe 12a for introducing an inert gas is attached to the outside of the furnace bottom plate so as to surround the opening 10a. A low-melting-point metal trap 13 for capturing discharged low-melting-point metals such as lead is attached to the lower side of the gas blowing device 12.

【0008】炉内には、開口10aを覆うように半球状
金属板11が設けられる。半球状金属板11は所定の曲
率を有していて、図1(b)に示すように、ガスを噴出
するための複数のガス孔11aが設けられ、周囲には低
融点金属を回収するための抜き孔11bが形成されてい
る。これは、例えば、鉛の場合、融点が327.4℃、
沸点1750℃、比重11.34で、炉底に高濃度で蒸
気として浮遊しており、これがガスで冷却された半球状
金属板11に触れると凝縮し、その表面を伝わって流下
し、抜き孔11bを通って半球状金属板11内に入るよ
うにするためである。半球状金属板11は還元性雰囲気
の中で利用されるため、ステンレスでなくても普通の鉄
板で十分であり、これに所定の孔を開けただけの簡単な
構成であるため、製作が容易でありコストダウンが図れ
る。なお、半球状金属板11の形状としては、表面を低
融点金属が流下できれは任意の形状でよいが、電気炉中
には電界が存在するため、尖った部分を有する形状のも
のは電界集中が起こるため避けることが望ましい。
A hemispherical metal plate 11 is provided in the furnace so as to cover the opening 10a. The hemispherical metal plate 11 has a predetermined curvature, and as shown in FIG. 1 (b), is provided with a plurality of gas holes 11a for ejecting a gas, and the surroundings are for collecting a low melting point metal. Is formed. This is because, for example, in the case of lead, the melting point is 327.4 ° C.,
It has a boiling point of 1750 ° C. and a specific gravity of 11.34, and floats at a high concentration in the furnace bottom as a vapor. When the vapor comes into contact with the gas-cooled hemispherical metal plate 11, it condenses, flows down the surface, and flows down. This is for the purpose of entering into the hemispherical metal plate 11 through 11b. Since the hemispherical metal plate 11 is used in a reducing atmosphere, a normal iron plate is sufficient even if it is not made of stainless steel. Therefore, cost can be reduced. The shape of the hemispherical metal plate 11 may be any shape as long as the low-melting-point metal can flow down the surface, but an electric furnace has an electric field. It is desirable to avoid concentration.

【0009】半球状金属板11の外側にはスタンプ材が
充填されているが、抜き孔11bの周囲はガスが透過し
にくい緻密なスタンプ材14として抜き孔11bを通し
て撹拌用ガスが噴出しないようにし、一方、ガス孔11
aの周囲は比較的ガス透過性の良いスタンプ材15を充
填する。
The outside of the hemispherical metal plate 11 is filled with a stamp material, but the periphery of the perforated hole 11b is formed as a dense stamp material 14 which is difficult for gas to permeate so that a stirring gas is not ejected through the perforated hole 11b. , On the other hand,
The periphery of a is filled with a stamp material 15 having relatively good gas permeability.

【0010】このような構成において、ガス導入管12
a、開口10aからガスを導入して半球状金属板11の
ガス孔11aからスタンプ材15中へガスを噴出する。
一方、溶鋼中の鉛や亜鉛等の低融点金属は、ガスで冷却
されている半球状金属板11に触れて凝縮し、その表面
を流れて抜き孔11bを通して半球状金属板11内に流
れ込み、開口10aを通して低融点金属トラップ13内
に捕捉される。
In such a configuration, the gas introduction pipe 12
a, A gas is introduced from the opening 10a and the gas is ejected into the stamp material 15 from the gas holes 11a of the hemispherical metal plate 11.
On the other hand, the low melting point metal such as lead and zinc in the molten steel touches the gas-cooled hemispherical metal plate 11, condenses, flows on the surface thereof, flows into the hemispherical metal plate 11 through the hole 11b, It is trapped in the low melting point metal trap 13 through the opening 10a.

【0011】図2は本発明の他の例を示す図である。こ
の例においては、図1の装置に、さらに開口10a上に
支柱21で炉底板10との間に所定の間隔をもって偏向
板20を取り付けるようにしたものである。図2(b)
に示すように、偏向板20は数箇所で支柱21で支持さ
れ、偏向板20と炉底板20との間から導入ガスが周囲
に噴出する。そのためガスの流れを四方八方に向けるこ
とができる。なお、図では、偏向板を1つだけ設けるよ
うにしたが、1つの半球状金属板内に開口を複数箇所開
けてそれぞれに偏向板を設けるようにしてもよい。
FIG. 2 is a diagram showing another example of the present invention. In this example, a deflection plate 20 is attached to the apparatus shown in FIG. 1 at a predetermined interval between the furnace bottom plate 10 and a support 21 on the opening 10a. FIG. 2 (b)
As shown in (1), the deflection plate 20 is supported by the columns 21 at several places, and the introduced gas is blown out from between the deflection plate 20 and the furnace bottom plate 20 to the surroundings. Therefore, the gas flow can be directed in all directions. Although only one deflection plate is provided in the drawing, a plurality of openings may be opened in one hemispherical metal plate, and a deflection plate may be provided for each.

【0012】図3は本発明の他の例を示す図である。こ
の例においては、半球状金属板11内に通気性の良いス
タンプ材15を充填したものである。もちろんスタンプ
材15に代えてポーラスな焼結体等を充填しても良い。
FIG. 3 is a diagram showing another example of the present invention. In this example, the stamp material 15 having good air permeability is filled in the hemispherical metal plate 11. Of course, instead of the stamp material 15, a porous sintered body or the like may be filled.

【0013】図4は本発明の他の例を示す図である。こ
の例においては、ガス吹き込み装置12および低融点金
属トラップ13を保温材30で覆うようにしている。こ
のように保温材30を設けることにより、炉底板10の
温度を鉛等の低融点金属の融点以上に保持し、これの流
出を促すことができる。保温材としてはガラスウール、
セラミックウール等の耐熱性ウールを用いるのが好まし
い。
FIG. 4 is a diagram showing another example of the present invention. In this example, the gas blowing device 12 and the low melting point metal trap 13 are covered with a heat insulating material 30. By providing the heat insulating material 30 in this manner, the temperature of the furnace bottom plate 10 can be maintained at a temperature equal to or higher than the melting point of a low melting point metal such as lead, and the outflow thereof can be promoted. Glass wool as a heat insulator,
It is preferable to use heat-resistant wool such as ceramic wool.

【0014】なお、上記の例においては半球状金属板を
1つ設ける例について説明したが、本発明はこれに限定
されるものではなく、半球状金属板複数設置し、各半球
状金属板で炉底板に形成した1つまたは複数の開口を覆
うようにしてもよい。
In the above example, an example in which one hemispherical metal plate is provided has been described. However, the present invention is not limited to this. A plurality of hemispherical metal plates are provided, and each hemispherical metal plate is provided. One or more openings formed in the furnace bottom plate may be covered.

【0015】[0015]

【発明の効果】以上のように本発明によれば、炉底板の
開口を覆うように複数のガス孔が形成され、周囲に複数
の低融点金属抜き孔が形成された金属板を設置すること
により、ガス孔からガスを噴出させるとともに、金属板
表面で低融点金属を析出させ、金属板の表面を流下させ
て回収することができるので、低融点金属がガス孔を塞
ぐことを防止でき、継続してガスの導入が可能となり、
これにより1次溶解から直ちに2次精錬を促すことがで
き、安定した品質の鋼を生産することが可能とある。ま
た、ガスを噴出させて低融点金属を回収する装置が、単
に金属板に孔を開けただけの簡単な構成で設置が容易で
あるので、コストダウンを図り、その普及を図ることが
期待される。
As described above, according to the present invention, a metal plate having a plurality of gas holes formed so as to cover the opening of the furnace bottom plate and a plurality of low melting point metal holes formed around the metal plate is provided. By causing the gas to be ejected from the gas holes, the low-melting-point metal is precipitated on the surface of the metal plate and can be collected by flowing down the surface of the metal plate, so that the low-melting-point metal can be prevented from blocking the gas holes, Gas can be introduced continuously,
Thereby, secondary refining can be promoted immediately after primary melting, and it is possible to produce steel of stable quality. In addition, since a device for ejecting gas to recover a low-melting-point metal is easy to install with a simple configuration in which a metal plate is simply opened, it is expected that cost reduction and widespread use will be achieved. You.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 本発明の電気炉底部のガス導入を説明する図
である。
FIG. 1 is a view for explaining gas introduction into the bottom of an electric furnace according to the present invention.

【図2】 本発明の他の例を示す図である。FIG. 2 is a diagram showing another example of the present invention.

【図3】 本発明の他の例を示す図である。FIG. 3 is a diagram showing another example of the present invention.

【図4】 本発明の他の例を示す図である。FIG. 4 is a diagram showing another example of the present invention.

【図5】 従来の電気炉に用いられるガス吹き込み装置
の概略図である。
FIG. 5 is a schematic view of a gas blowing device used in a conventional electric furnace.

【符号の説明】[Explanation of symbols]

10…電気炉底板、10a…開口、11…半球状金属
板、11a…ガス孔、11b…抜き孔、12…ガス吹き
込み装置、13…低融点金属トラップ、14,15…ス
タンプ材、20…偏向板、21…支柱、30…保温材。
DESCRIPTION OF SYMBOLS 10 ... Electric furnace bottom plate, 10a ... Opening, 11 ... Hemispherical metal plate, 11a ... Gas hole, 11b ... Punch hole, 12 ... Gas blowing device, 13 ... Low melting point metal trap, 14,15 ... Stamp material, 20 ... Deflection Board, 21 ... pillar, 30 ... insulation material.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 炉底に撹拌用ガス吹き込みと低融点金属
排出用の開口が形成された電気炉において、複数のガス
孔が形成され、周囲に複数の低融点金属抜き孔が形成さ
れた金属板を前記開口を覆うように炉底板上に設置した
ことを特徴とする炉底ガス吹き込み装置を備えた電気
炉。
1. An electric furnace having an opening for blowing a stirring gas and discharging a low-melting-point metal in a furnace bottom, wherein a plurality of gas holes are formed and a plurality of low-melting-point metal holes are formed around the metal furnace. An electric furnace equipped with a furnace bottom gas blowing device, wherein a plate is placed on a furnace bottom plate so as to cover the opening.
【請求項2】 前記開口上に吹き込むガスの流れの向き
を変える偏向板を設置したことを特徴とする請求項1記
載の電気炉。
2. The electric furnace according to claim 1, further comprising a deflection plate for changing a direction of a flow of gas blown onto the opening.
【請求項3】 前記金属板と炉底板との間にスタンプ材
を充填したことを特徴とする請求項1記載の電気炉
3. The electric furnace according to claim 1, wherein a stamp material is filled between the metal plate and the furnace bottom plate.
【請求項4】 金属板外側に充填されるスタンプ材は、
ガス孔が形成された部分の周囲はガス透過性のよいスタ
ンプ材、低融点金属抜き孔が形成された部分の周囲は、
ガスが透過しにい緻密なスタンプ材であることを特徴と
する請求項1記載の電気炉。
4. The stamp material filled on the outside of the metal plate is:
Around the portion where the gas hole is formed is a stamp material having good gas permeability, and around the portion where the low melting point metal hole is formed,
2. The electric furnace according to claim 1, wherein the electric furnace is a dense stamp material through which gas is hardly permeated.
JP10343030A 1998-12-02 1998-12-02 Electric furnace provided with device for blowing gas to hearth Pending JP2000169908A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10343030A JP2000169908A (en) 1998-12-02 1998-12-02 Electric furnace provided with device for blowing gas to hearth

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10343030A JP2000169908A (en) 1998-12-02 1998-12-02 Electric furnace provided with device for blowing gas to hearth

Publications (1)

Publication Number Publication Date
JP2000169908A true JP2000169908A (en) 2000-06-20

Family

ID=18358401

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10343030A Pending JP2000169908A (en) 1998-12-02 1998-12-02 Electric furnace provided with device for blowing gas to hearth

Country Status (1)

Country Link
JP (1) JP2000169908A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002364982A (en) * 2001-06-11 2002-12-18 Nippon Soda Co Ltd Oxygen blowing nozzle

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002364982A (en) * 2001-06-11 2002-12-18 Nippon Soda Co Ltd Oxygen blowing nozzle

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