JP2000153277A - Reduced water generator and generating method - Google Patents
Reduced water generator and generating methodInfo
- Publication number
- JP2000153277A JP2000153277A JP10326857A JP32685798A JP2000153277A JP 2000153277 A JP2000153277 A JP 2000153277A JP 10326857 A JP10326857 A JP 10326857A JP 32685798 A JP32685798 A JP 32685798A JP 2000153277 A JP2000153277 A JP 2000153277A
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- JP
- Japan
- Prior art keywords
- anode
- catalyst
- cathode
- water
- reduced water
- Prior art date
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- Water Treatment By Electricity Or Magnetism (AREA)
- Catalysts (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、還元水を簡単且つ
効率的に生成する還元水生成装置及び生成方法に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a reduced water generating apparatus and method for generating reduced water simply and efficiently.
【０００２】[0002]
【従来の技術】近年、病気等に優れた効力があることか
ら、還元水（アルカリ水）が注目されている。通常一般
に普及しているのは、アルカリイオン水生成器が広く普
及している。このアルカリイオン水生成器は、陽極及び
陰極を有し、水道水を電気分解して、酸性水とアルカリ
水とを作りだし、アルカリ水のみを利用するものであ
る。このアルカリ水中には、ＯＨ-（ヒドロキシイオ
ン）が多く存在し、また相手を還元する力を持ったＨ2
（水素分子）が水に溶け込むため、アルカリイオン水を
アルカリ還元水と称することもある。2. Description of the Related Art In recent years, reduced water (alkaline water) has attracted attention because of its excellent efficacy against diseases and the like. Generally, alkali ion water generators are widely used. This alkaline ionized water generator has an anode and a cathode, and electrolyzes tap water to produce acidic water and alkaline water, and uses only alkaline water. The alkaline water, OH - H 2 (hydroxy ion) many exist, also with a force to reduce the opponent
Since (hydrogen molecules) dissolve in water, alkaline ionized water is sometimes referred to as alkaline reduced water.
【０００３】[0003]
【発明が解決しようとする課題】ところで、上述のよう
な還元水（アルカリイオン水）生成装置は、高い還元
力、すなわちＨ2（水素分子）を多く得ようとすると、
その分ＯＨ-（ヒドロキシイオン）が多く水に溶け込
み、飲用に不適なｐＨ１０以上のアルカリ性水となって
しまう。逆に飲用に適しているといわれるｐＨ９．５以
下では十分な還元力が得られない。また、多くの還元水
（アルカリ水）を生成しようとすると、多くの酸化水が
発生し、効率良く還元水が得られない問題点も派生す
る。By the way, the above-mentioned reduced water (alkali ion water) generating apparatus is intended to obtain a high reducing power, that is, a large amount of H 2 (hydrogen molecules).
Correspondingly OH - (hydroxy ions) dissolved into many water becomes unsuitable pH10 or more alkaline water for drinking. Conversely, at a pH of 9.5 or less, which is said to be suitable for drinking, a sufficient reducing power cannot be obtained. In addition, when attempting to generate a large amount of reduced water (alkaline water), a large amount of oxidized water is generated, which causes a problem that reduced water cannot be obtained efficiently.
【０００４】本発明は上述の問題点を解決するために案
出されたもので、還元水を簡単且つ効率的に生成する還
元水生成装置及び生成方法を提供することを目的とす
る。[0004] The present invention has been devised in order to solve the above-mentioned problems, and an object of the present invention is to provide a reduced water generating apparatus and method for generating reduced water easily and efficiently.
【０００５】[0005]
【課題を解決するための手段】上記目的を達成するため
に請求項１記載の発明の装置は、陰極と、触媒を配した
陽極とで構成される電解槽であって、前記触媒には、水
酸化物イオンＯＨ-を選択的に通過させる隔膜を配する
ことを特徴とする。According to a first aspect of the present invention, there is provided an electrolysis cell comprising a cathode and an anode provided with a catalyst, wherein the catalyst comprises: hydroxide ions OH - and wherein placing the selective membrane to pass.
【０００６】請求項２記載の発明は、請求項１記載の還
元水生成装置において、前記隔膜は、テフロン，セロハ
ン又はイオン交換膜のいずれかであることを特徴とす
る。According to a second aspect of the present invention, in the reduced water generating apparatus according to the first aspect, the diaphragm is any one of Teflon, cellophane and an ion exchange membrane.
【０００７】請求項３記載の発明は、請求項１又は２記
載の還元水生成装置において、前記陽極は、前記電解槽
を２空間領域に隔てる電極であって、前記陰極は、前記
２空間のうちいずれか一方の空間領域に配置され、前記
触媒は、前記陰極が配された空間領域側に配されている
ことを特徴とする。According to a third aspect of the present invention, in the reduced water generating apparatus according to the first or second aspect, the anode is an electrode for separating the electrolytic cell into two space regions, and the cathode is an electrode for the two space regions. The catalyst is arranged in any one of the space regions, and the catalyst is arranged on the space region side where the cathode is arranged.
【０００８】請求項４記載の発明は、請求項３記載の還
元水生成装置において、前記触媒は、二酸化マンガン，
カーボン，白金クラスター、あるいはそれらの複合物で
あることを特徴とする。According to a fourth aspect of the present invention, in the reduced water producing apparatus according to the third aspect, the catalyst comprises manganese dioxide,
It is characterized by being carbon, platinum clusters, or a composite thereof.
【０００９】請求項５記載の発明は、請求項１又は２記
載の還元水生成装置において、前記隔膜は前記触媒と密
着して配されており、かつ前記触媒は前記陽極に密着し
て配されていることを特徴とする。According to a fifth aspect of the present invention, in the reduced water generating apparatus according to the first or second aspect, the diaphragm is disposed in close contact with the catalyst, and the catalyst is disposed in close contact with the anode. It is characterized by having.
【００１０】請求項６記載の発明の方法は、陰極と、陽
極と、前記陽極に配された触媒と、前記触媒に配された
水酸化物イオン（ＯＨ-）を選択的に通過させる隔膜と
により構成される電解槽中に、水（Ｈ2Ｏ）を満たし、
前記陰極と前記陽極に所望の電圧を付加することを特徴
とする。The method of the invention according to Claim 6, cathode and the anode, and a catalyst disposed in the anode, the catalyst provided a hydroxide ion (OH -) and the membrane which selectively passes Is filled with water (H 2 O)
A desired voltage is applied to the cathode and the anode.
【００１１】請求項７記載の発明は、請求項６記載の還
元水生成方法において、前記隔膜は、テフロン，セロハ
ン又はイオン交換膜のいずれかであることを特徴とす
る。The invention according to claim 7 is the method for producing reduced water according to claim 6, wherein the diaphragm is any one of Teflon, cellophane and an ion exchange membrane.
【００１２】請求項８記載の発明は、請求項６記載の還
元水生成方法において、前記触媒は、二酸化マンガン，
カーボン，白金クラスター、あるいはそれらの複合物で
あることを特徴とする。The invention according to claim 8 is the method for producing reduced water according to claim 6, wherein the catalyst is manganese dioxide,
It is characterized by being carbon, platinum clusters, or a composite thereof.
【００１３】請求項９記載の発明の方法は、陰極と、陽
極と、前記陰極と陽極とを仕切る水素イオン（Ｈ+）又
は水酸化物イオン（ＯＨ-）を選択的に通過させる隔膜
と、により構成される電解槽中に、水（Ｈ2Ｏ）を満た
し、前記陰極と陽極とに所望の電圧を付加することを特
徴とする。The method of the invention of claim 9, wherein comprises a cathode, anode and the hydrogen ions separating the cathode and the anode (H +) or hydroxide ions - and the membrane for selectively passing a, (OH) Is filled with water (H 2 O), and a desired voltage is applied to the cathode and the anode.
【００１４】請求項１０記載の発明は、請求項９記載の
還元水生成方法において、前記隔膜は、陰イオン交換膜
又は陽イオン交換膜であることを特徴とする。According to a tenth aspect of the present invention, in the method for producing reduced water according to the ninth aspect, the diaphragm is an anion exchange membrane or a cation exchange membrane.
【００１５】請求項１１記載の発明は、請求項９又は１
０記載の還元水生成方法において、前記陰イオン交換膜
または陽イオン交換膜は、フィルム状の膜であることを
特徴とする。The invention according to claim 11 is the invention according to claim 9 or 1
0, wherein the anion exchange membrane or the cation exchange membrane is a film-like membrane.
【００１６】[0016]
【作用】請求項１〜８記載の発明では、電解槽内に水を
入れた場合、水が電気分解されて、陰極ではＨ2とＯＨ-
が発生する。そして部分的に発生した活性な水素
（Ｈ2）は、水中に溶存している酸素と結合してＨ2Ｏと
なり、水中の溶存酸素を減らす。また、過剰に発生した
水素（Ｈ2）は水中に溶存し、相手を還元する力を水に
付与する。電気分解された水酸化物イオンＯＨ-は隔
膜、詳しくは、テフロン，セロハン又はイオン交換膜を
通過して触媒と反応し、酸素ガス（Ｏ2）と水（Ｈ2Ｏ）
になる。そのため、陰極側の生成水のｐＨは変化せず、
電解槽内に入れた水のｐＨとほぼ同じになる。ゆえに、
生成した還元水は中性で、化１の反応に由来する酸化還
元電位を有することになる。According to the present invention, when water is put into the electrolytic cell, the water is electrolyzed, and H 2 and OH − are collected at the cathode.
Occurs. The partially generated active hydrogen (H 2 ) combines with the oxygen dissolved in the water to form H 2 O, thereby reducing the dissolved oxygen in the water. In addition, the excessively generated hydrogen (H 2 ) is dissolved in the water, and gives the water the power to reduce the partner. Electrolyzed hydroxide ions OH - are diaphragm, details, Teflon, through the cellophane or ion-exchange membrane react with the catalyst, oxygen gas (O 2) and water (H 2 O)
become. Therefore, the pH of the generated water on the cathode side does not change,
It becomes almost the same as the pH of the water put in the electrolytic cell. therefore,
The generated reduced water is neutral and has an oxidation-reduction potential derived from the reaction of Chemical Formula 1.
【化１】 Embedded image
【００１７】請求項９〜１１記載の発明では、電解槽内
に水を入れた場合、水が電気分解されて、陰極では次の
反応が行われＨ2とＯＨ-が発生する。 ４Ｈ2Ｏ＋４ｅ-→４ＯＨ-＋２Ｈ2 そして部分的に発生した活性な水素（Ｈ2）は、水中に
溶存している酸素と結合してＨ2Ｏとなり、水中の溶存
酸素を減らす。また、陽極では、次の反応が行われ酸素
ガス（Ｏ2）とＨ+が発生する。 ２Ｈ2Ｏ→４Ｈ+＋Ｏ2＋４ｅ- そしてＨ+はフィルム状のイオン交換膜を通過して陰極
側から陽極側へ移動してきたＯＨ-と結合して再度Ｈ2Ｏ
となる。そのため陰極側及び陽極側で生成水のｐＨは変
化せず、電解槽内に入れた水のｐＨとほぼ同じになる。
ゆえに、酸化還元電位を有する還元水を得ることができ
る。According to the present invention, when water is introduced into the electrolytic cell, the water is electrolyzed, and the following reaction takes place at the cathode to generate H 2 and OH − . 4H 2 O + 4e − → 4OH − + 2H 2 and partially generated active hydrogen (H 2 ) combines with oxygen dissolved in water to form H 2 O and reduces dissolved oxygen in water. At the anode, the following reaction takes place to generate oxygen gas (O 2 ) and H + . 2H 2 O → 4H + + O 2 + 4e − and H + are combined with OH − that has passed from the cathode side to the anode side through the film-like ion exchange membrane to form H 2 O again.
Becomes Therefore, the pH of the produced water does not change on the cathode side and the anode side, and becomes almost the same as the pH of the water put in the electrolytic cell.
Therefore, reduced water having an oxidation-reduction potential can be obtained.
【００１８】[0018]
【発明の実施の形態】以下、本発明に好適な実施の形態
を図面を用いて詳細に説明する。図１は本発明の第１実
施例における還元水生成装置の模式図である。図１に示
すように、符号１は電解槽である。該電解槽１の両側に
は、陰極２及び陽極３が設けられており、それぞれ図示
しない電源に接続されている。さらに前記陽極３には触
媒４が密着してもうけられている。前記触媒４は、二酸
化マンガン，カーボン，白金クラスター、あるいはそれ
らの複合物であり、酸化性の高いものとする。さらに該
触媒４と密着するように隔膜５が設けられており、隔膜
５，触媒４，陽極３の順に配置されている。ここで、前
記隔膜５は、フィルム状のテフロン，セロハン又はイオ
ン交換膜で、特定のイオン，この場合は水酸化物イオン
ＯＨ-のみを通過させるものである。DESCRIPTION OF THE PREFERRED EMBODIMENTS Preferred embodiments of the present invention will be described below in detail with reference to the drawings. FIG. 1 is a schematic diagram of a reduced water generating apparatus according to a first embodiment of the present invention. As shown in FIG. 1, reference numeral 1 denotes an electrolytic cell. On both sides of the electrolytic cell 1, a cathode 2 and an anode 3 are provided, each of which is connected to a power source (not shown). Further, a catalyst 4 is provided in close contact with the anode 3. The catalyst 4 is manganese dioxide, carbon, platinum clusters, or a composite thereof, and has high oxidizability. Further, a diaphragm 5 is provided in close contact with the catalyst 4, and the diaphragm 5, the catalyst 4, and the anode 3 are arranged in this order. Here, the diaphragm 5, a film-like Teflon, cellophane or ion-exchange membrane, specific ions, in this case the hydroxide ion OH - is intended to pass only.
【００１９】次に上述した電解槽１に所要量の水道水を
入れ、陰極２及び陽極３に２０〜８０Ｖの電圧を付加す
る。すると水道水（Ｈ2Ｏ）は電解槽１内にて電気分解
する。詳しくは、陰極２付近の電気二重層Ｒ内で積極的
に電気分解し、Ｈ2とＯＨ-が発生する。そして部分的に
発生した活性な水素（Ｈ2）は、水中に溶存している酸
素と結合してＨ2Ｏとなり、水中の溶存酸素を減らす。
また、電気分解された水酸化物イオンＯＨ-は隔膜５、
具体的には、テフロン，セロハン又はイオン交換膜を通
過して触媒４と反応して酸化され、酸素ガス（Ｏ2）と
水（Ｈ2Ｏ）になる。そのため、電気分解されたＨ2とＯ
Ｈ-はそれぞれ中性の水（Ｈ2Ｏ）となるため、生成水の
ｐＨは変化せず、電解槽１内に入れた水のｐＨとほぼ同
じになる。ゆえに、生成した還元水は中性で、化１の反
応に由来する酸化還元電位を有することになる。Next, a required amount of tap water is poured into the electrolytic cell 1 described above, and a voltage of 20 to 80 V is applied to the cathode 2 and the anode 3. Then, tap water (H 2 O) is electrolyzed in the electrolytic cell 1. Specifically, electrolysis is actively performed in the electric double layer R near the cathode 2 to generate H 2 and OH − . The partially generated active hydrogen (H 2 ) combines with the oxygen dissolved in the water to form H 2 O, thereby reducing the dissolved oxygen in the water.
The electrolyzed hydroxide ions OH - are separated from the diaphragm 5,
Specifically, it passes through Teflon, cellophane or an ion exchange membrane and reacts with the catalyst 4 to be oxidized to oxygen gas (O 2 ) and water (H 2 O). Therefore, the electrolyzed H 2 and O
Since each H - is neutral water (H 2 O), the pH of the generated water does not change, and becomes almost the same as the pH of the water put in the electrolytic cell 1. Therefore, the generated reduced water is neutral and has an oxidation-reduction potential derived from the reaction of Chemical Formula 1.
【化１】 Embedded image
【００２０】次に本発明の第２実施例を図２の模式図を
用いて説明する。なお、同一部材には同一符号を付して
その説明を省略する。図２に示すように、電解槽１の両
側には陰極２と陽極３とが設けられている。そして前記
電解槽１のほぼ中央で、陰極２と陽極３とを隔てるよう
に隔膜４を設ける。この隔膜４はフィルム状の陰イオン
交換膜または陽イオン交換膜である。そしてこの隔膜４
を配することで、結果として電解槽１を陰極室と陽極室
とに隔てるようになる。Next, a second embodiment of the present invention will be described with reference to the schematic diagram of FIG. The same members are denoted by the same reference numerals, and description thereof will be omitted. As shown in FIG. 2, a cathode 2 and an anode 3 are provided on both sides of the electrolytic cell 1. A diaphragm 4 is provided substantially at the center of the electrolytic cell 1 so as to separate the cathode 2 and the anode 3. The diaphragm 4 is a film-like anion exchange membrane or cation exchange membrane. And this diaphragm 4
As a result, the electrolytic cell 1 is separated between the cathode chamber and the anode chamber.
【００２１】次に上述した電解槽１に所要量の水道水を
入れ、陰極２及び陽極３に２０〜８０Ｖの電圧を付加し
て水道水（Ｈ2Ｏ）を電解槽１内にて電気分解する。陰
極２側では、電気二重層内Ｒにて次の反応が行われＨ2
とＯＨ-が発生する。４Ｈ2Ｏ＋４ｅ-→４ＯＨ-＋２Ｈ2
そして部分的に発生した活性な水素（Ｈ2）は、水中に
溶存している酸素と結合してＨ2Ｏとなり、水中の溶存
酸素を減らす。また、陽極では、電気二重層Ｒ’内にて
次の反応が行われ酸素ガス（Ｏ2）とＨ+が発生する。 ２Ｈ2Ｏ→４Ｈ+＋Ｏ2＋４ｅ- そしてＨ+は隔膜４を通過して陰極室から陽極室へ移動
してきたＯＨ-と結合して再度Ｈ2Ｏとなる。そのため陰
極室及び陽極室で生成水のｐＨは変化せず、電解槽１内
に入れた水のｐＨとほぼ同じになる。ゆえに、陰極２側
で生成した還元水は中性で、化１の反応に由来する酸化
還元電位を有することになる。Next, a required amount of tap water is poured into the above-mentioned electrolytic cell 1, and a voltage of 20 to 80 V is applied to the cathode 2 and the anode 3 to electrolyze the tap water (H 2 O) in the electrolytic cell 1. I do. On the cathode 2 side, the following reaction takes place in R in the electric double layer, and H 2
It occurs - OH with. 4H 2 O + 4e − → 4OH − + 2H 2
The partially generated active hydrogen (H 2 ) combines with the oxygen dissolved in the water to form H 2 O, thereby reducing the dissolved oxygen in the water. Further, in the anode, an electric double layer R 'following reaction is performed in an oxygen (O 2) gas and H + is generated. 2H 2 O → 4H + + O 2 + 4e − and H + are combined with OH − that has passed through the diaphragm 4 and moved from the cathode chamber to the anode chamber to become H 2 O again. Therefore, the pH of the generated water does not change in the cathode chamber and the anode chamber, and becomes almost the same as the pH of the water put in the electrolytic cell 1. Therefore, the reduced water generated on the cathode 2 side is neutral and has an oxidation-reduction potential derived from the reaction of Chemical formula 1.
【化１】 Embedded image
【００２２】[0022]
【発明の効果】以上説明したように、本発明によれば、
水を電気分解するだけで中性の還元水のみを得ることが
できる。As described above, according to the present invention,
Only neutral reduced water can be obtained only by electrolyzing water.
【図１】本発明の第１実施例における電解槽の模式図FIG. 1 is a schematic view of an electrolytic cell according to a first embodiment of the present invention.
【図２】本発明の第２実施例における電解槽の模式図FIG. 2 is a schematic view of an electrolytic cell according to a second embodiment of the present invention.
１ 電解槽 ２ 陰極 ３ 陽極 ４ 隔膜 ５ 触媒 DESCRIPTION OF SYMBOLS 1 Electrolyzer 2 Cathode 3 Anode 4 Diaphragm 5 Catalyst
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 4D006 GA17 HA41 JA42A JA42C MA03 MA13 MA14 MC11 MC30 PB06 PC80 4D061 DA03 DB08 EA02 EB12 EB13 EB19 EB26 FA16 GA22 4G069 AA02 BA08A BA08B BB02A BB02B BC75A BC75B CB02 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4D006 GA17 HA41 JA42A JA42C MA03 MA13 MA14 MC11 MC30 PB06 PC80 4D061 DA03 DB08 EA02 EB12 EB13 EB19 EB26 FA16 GA22 4G069 AA02 BA08A BA08B BB02A BB02B BC75A BC75B CB02
Claims (11)
る電解槽であって、 前記触媒には、水酸化物イオンＯＨ-を選択的に通過さ
せる隔膜を配することを特徴とする還元水生成装置。And 1. A cathode, an electrolytic cell composed of an anode which arranged catalyst, the catalyst is a hydroxide ion OH -, characterized in that placing a selectively membrane passing Reduced water generator.
オン交換膜のいずれかであることを特徴とする請求項１
記載の還元水生成装置。2. The method according to claim 1, wherein the diaphragm is one of Teflon, cellophane and an ion exchange membrane.
The reduced water generator according to the above.
隔てる電極であって、 前記陰極は、前記２空間のうちいずれか一方の空間領域
に配置され、 前記触媒は、前記陰極が配された空間領域側に配されて
いることを特徴とする請求項１又は２に記載の還元水生
成装置。3. The anode is an electrode for separating the electrolytic cell into two space regions, the cathode is disposed in one of the two space regions, and the catalyst is disposed in the cathode region. The reduced water generation device according to claim 1, wherein the reduced water generation device is arranged on the side of the space region provided.
ン，白金クラスター、あるいはそれらの複合物であるこ
とを特徴とする請求項３記載の還元水生成装置。4. The reduced water generator according to claim 3, wherein the catalyst is manganese dioxide, carbon, platinum cluster, or a composite thereof.
おり、かつ前記触媒は前記陽極に密着して配されている
ことを特徴とする請求項１又は２に記載の還元水生成装
置。5. The apparatus for producing reduced water according to claim 1, wherein the diaphragm is arranged in close contact with the catalyst, and the catalyst is arranged in close contact with the anode. .
媒と、前記触媒に配された水酸化物イオン（ＯＨ-）を
選択的に通過させる隔膜とにより構成される電解槽中
に、水（Ｈ2Ｏ）を満たし、前記陰極と前記陽極に所望
の電圧を付加することを特徴とする還元水生成方法。6. An electrolytic cell comprising a cathode, an anode, a catalyst disposed on the anode, and a diaphragm selectively passing hydroxide ions (OH − ) disposed on the catalyst. And water (H 2 O), and applying a desired voltage to the cathode and the anode.
オン交換膜のいずれかであることを特徴とする請求項６
記載の還元水生成方法。7. The membrane according to claim 6, wherein the membrane is one of Teflon, cellophane and an ion exchange membrane.
The method for producing reduced water as described above.
ン，白金クラスター、あるいはそれらの複合物であるこ
とを特徴とする請求項６記載の還元水生成方法。8. The method according to claim 6, wherein the catalyst is manganese dioxide, carbon, platinum cluster, or a composite thereof.
切る水素イオン（Ｈ+）又は水酸化物イオン（ＯＨ-）を
選択的に通過させる隔膜と、により構成される電解槽中
に、水（Ｈ2Ｏ）を満たし、前記陰極と陽極とに所望の
電圧を付加することを特徴とする還元水生成方法。9. An electrolytic cell comprising a cathode, an anode, and a diaphragm selectively passing hydrogen ions (H + ) or hydroxide ions (OH − ) separating the cathode and the anode. And water (H 2 O), and applying a desired voltage to the cathode and the anode.
オン交換膜であることを特徴とする請求項９記載の還元
水生成方法。10. The method according to claim 9, wherein the diaphragm is an anion exchange membrane or a cation exchange membrane.
換膜は、フィルム状の膜であることを特徴とする請求項
９または１０に記載の還元水生成方法。11. The method for producing reduced water according to claim 9, wherein the anion exchange membrane or the cation exchange membrane is a film-like membrane.
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|---|---|---|---|
| JP32685798A JP3790054B2 (en) | 1998-11-17 | 1998-11-17 | Reduced water generating apparatus and generating method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32685798A JP3790054B2 (en) | 1998-11-17 | 1998-11-17 | Reduced water generating apparatus and generating method |
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| Publication Number | Publication Date |
|---|---|
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| JP3790054B2 JP3790054B2 (en) | 2006-06-28 |
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ID=18192505
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|---|---|---|---|
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006016564A1 (en) * | 2004-08-11 | 2006-02-16 | Miz Co., Ltd. | Performance maintaining method in electrolysis functional water producing device |
| JP2011125844A (en) * | 2009-12-15 | 2011-06-30 | Ind Technol Res Inst | Water body self-generating electrolytic reduction module |
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|---|---|---|---|---|
| JPH05239671A (en) * | 1992-02-27 | 1993-09-17 | Nishihara Eisei Kogyosho:Kk | Anticorrosion method and device for piping device |
| JPH09155350A (en) * | 1995-12-13 | 1997-06-17 | Tookemi:Kk | Production of electrolytic ion water |
| JPH09299953A (en) * | 1996-05-14 | 1997-11-25 | Matsushita Refrig Co Ltd | Electrolytic water generator |
| JPH101794A (en) * | 1996-06-13 | 1998-01-06 | Permelec Electrode Ltd | Electrolytic cell and electrolyzing method |
-
1998
- 1998-11-17 JP JP32685798A patent/JP3790054B2/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05239671A (en) * | 1992-02-27 | 1993-09-17 | Nishihara Eisei Kogyosho:Kk | Anticorrosion method and device for piping device |
| JPH09155350A (en) * | 1995-12-13 | 1997-06-17 | Tookemi:Kk | Production of electrolytic ion water |
| JPH09299953A (en) * | 1996-05-14 | 1997-11-25 | Matsushita Refrig Co Ltd | Electrolytic water generator |
| JPH101794A (en) * | 1996-06-13 | 1998-01-06 | Permelec Electrode Ltd | Electrolytic cell and electrolyzing method |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006016564A1 (en) * | 2004-08-11 | 2006-02-16 | Miz Co., Ltd. | Performance maintaining method in electrolysis functional water producing device |
| EP1803687A1 (en) * | 2004-08-11 | 2007-07-04 | MIZ Co., Ltd. | Performance maintaining method in electrolysis functional water producing device |
| EP1803687A4 (en) * | 2004-08-11 | 2010-02-17 | Miz Co Ltd | Performance maintaining method in electrolysis functional water producing device |
| JP2011125844A (en) * | 2009-12-15 | 2011-06-30 | Ind Technol Res Inst | Water body self-generating electrolytic reduction module |
| KR101212867B1 (en) | 2009-12-15 | 2012-12-14 | 인더스트리얼 테크놀로지 리서치 인스티튜트 | Self-generating electrolytic reduction module for electrolytic-reducing water body |
| US8366885B2 (en) | 2009-12-15 | 2013-02-05 | Industrial Technology Research Institute | Water body self-generating electrolytic reduction module |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3790054B2 (en) | 2006-06-28 |
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