JP2000143683A - Iron compound of tannin - Google Patents
Iron compound of tanninInfo
- Publication number
- JP2000143683A JP2000143683A JP35067798A JP35067798A JP2000143683A JP 2000143683 A JP2000143683 A JP 2000143683A JP 35067798 A JP35067798 A JP 35067798A JP 35067798 A JP35067798 A JP 35067798A JP 2000143683 A JP2000143683 A JP 2000143683A
- Authority
- JP
- Japan
- Prior art keywords
- tannin
- coloring
- fiber
- powder
- polyphenol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001864 tannin Polymers 0.000 title claims abstract description 11
- 235000018553 tannin Nutrition 0.000 title claims abstract description 11
- 239000001648 tannin Substances 0.000 title claims abstract description 11
- 150000002506 iron compounds Chemical class 0.000 title claims description 6
- 239000000835 fiber Substances 0.000 claims abstract description 7
- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 7
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 7
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 4
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001447 ferric ion Inorganic materials 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims abstract 2
- 229910001448 ferrous ion Inorganic materials 0.000 claims description 3
- 239000000976 ink Substances 0.000 abstract description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
- 238000004040 coloring Methods 0.000 abstract description 5
- 229910052742 iron Inorganic materials 0.000 abstract description 4
- 235000015523 tannic acid Nutrition 0.000 abstract description 4
- 229920002258 tannic acid Polymers 0.000 abstract description 4
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 abstract description 3
- 239000001263 FEMA 3042 Substances 0.000 abstract description 3
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 3
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 abstract description 3
- 229940033123 tannic acid Drugs 0.000 abstract description 3
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 abstract description 2
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 abstract description 2
- 235000005487 catechin Nutrition 0.000 abstract description 2
- 229950001002 cianidanol Drugs 0.000 abstract description 2
- 239000000975 dye Substances 0.000 abstract description 2
- -1 iron ions Chemical class 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 3
- 235000003891 ferrous sulphate Nutrition 0.000 description 3
- 239000011790 ferrous sulphate Substances 0.000 description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 235000010215 titanium dioxide Nutrition 0.000 description 3
- WMBWREPUVVBILR-WIYYLYMNSA-N (-)-Epigallocatechin-3-o-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=C(O)C=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-WIYYLYMNSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000003738 black carbon Substances 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Coloring (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】 ［産業上の利用分野］従来、水性インク又は油性インク
は着色金属化合物、タール色素などを水又は油に微細分
散させて使用してきた。特に使用頻度の高い青色、黒色
などは鉄のシアン化合物を使用するが生態系に問題があ
り、今後改善の必要が有る。本発明のタンニン類の鉄化
合物は極めて生分解されやすく、生態系に何等の問題を
生ぜず耐光性も従来のインクに勝るとも劣らず、優れた
品質のものが得られる。又、粉体又は繊維に形成された
タンニン類の鉄化合物は各種粉体又は各種繊維に極めて
強固に結合吸着し、耐光性も優れており、色調も良く着
色粉体は化粧品に安全な着色体として広範に利用され得
る。又、繊維製品への利用は安全で優れた染色が可能と
なる。DETAILED DESCRIPTION OF THE INVENTION [Industrial application] Conventionally, aqueous inks or oil-based inks have been used by finely dispersing a colored metal compound, a tar dye or the like in water or oil. Particularly, blue and black, which are frequently used, use a cyanide compound of iron. However, there is a problem in the ecosystem, and there is a need for improvement in the future. The iron compound of the tannins of the present invention is extremely easily biodegradable, does not cause any problems in ecosystems, and has light resistance equal to that of conventional inks, and excellent quality can be obtained. In addition, iron compounds of tannins formed in powders or fibers are extremely strongly bonded and adsorbed to various powders or fibers, and have excellent light resistance, good color tone and colored powders which are safe for cosmetics. Can be used widely. Moreover, the use for textile products enables safe and excellent dyeing.
［従来の技術及び発明が解決しようとする課題］前項で
説明したごとく、印刷に大量に使用される生分解性と生
態系に問題の多い現在のインクは改善されなければなら
ない。又化粧品に広く利用されるタール系の青色色素及
び黒色のカーボンブラックは共に人体安全面、着色利用
面に問題がある。これらの問題点を解決するべく研究
し、生体利用安全性、生態系安全性、光安定性、着色
性、調色性の各要素を総合的に満足する鉄のタンニン類
（ポリフェノール）化合物を見出だし本発明になった。[Problems to be Solved by the Related Art] As described in the preceding paragraph, the present inks, which are used in large quantities for printing and are biodegradable and ecologically problematic, must be improved. In addition, both tar-based blue pigments and black carbon black, which are widely used in cosmetics, have problems in terms of human body safety and color utilization. We researched to solve these problems and found that iron tannins (polyphenols) compounds satisfying all factors of bioavailability, ecosystem safety, photostability, coloring and toning. The present invention has begun.
［課題を解決する為の手段］発明者は先にタンニン酸類
（ポリフェノール）が鉄錆と常温で反応し、水に不溶性
の青色又は黒色の錯体を作る事を見出だし「給水配管の
鉄錆による赤水の防止剤」を出願している（特願平９−
３２１９１５）。この錯体の光安定性、水中及び油中の
分散・着色性などを研究し、第一鉄イオン又は第二鉄イ
オンとタンニン類ポリフェノールであるタンニン酸又は
カテキンとの反応化合物が本目的に適う事を見出だし解
決に至った。[Means for Solving the Problems] The inventor has previously found that tannic acids (polyphenols) react with iron rust at room temperature to form a water-insoluble blue or black complex. Of Red Water Prevention Agent (Japanese Patent Application No. 9-
321915). By studying the photostability, dispersibility and colorability of this complex in water and oil, the reaction compound of ferrous ion or ferric ion with the tannin polyphenols tannic acid or catechin is suitable for this purpose. And found a solution.
［実施例］ 実施例１．繊維の着色 木綿、絹、アクリルの繊維
片をそれぞれ０．１％の茶カテキンの水溶液に５分間浸
漬する。この布片を溶液から取りだし、軽く絞りこれに
０．２％の硫酸第一鉄水溶液を布にひたひたに加え３０
分間放置する。それぞれの布片を絞り、水で良く洗う。
これを乾燥する時それぞれの布片は美しい青黒色に染色
されている。秋晴れの日の直射日光に１０日間、日光照
射しても殆ど退色が見られなかった。[Example] Example 1 Fiber coloring Cotton, silk and acrylic fiber pieces are each immersed in a 0.1% aqueous solution of tea catechin for 5 minutes. The cloth piece was taken out of the solution, squeezed gently, and a 0.2% aqueous ferrous sulfate solution was added to the cloth, followed by adding 30%.
Leave for a minute. Squeeze each piece of cloth and wash well with water.
When dried, each piece of fabric is dyed a beautiful blue-black color. Almost no fading was observed even in direct sunlight for 10 days on a sunny autumn day.
実施例２．青色インク １％の硫酸第一鉄水溶液に
界面活性剤０．０１％相当量を溶解し、これにタンニン
酸の１％水溶液を攪拌混合し反応させる。１０分後、こ
れを遠心分離器にかけて青色色素を沈殿させる。水洗浄
を３，４回行い低温で乾燥させる時、美麗な青色有機顔
料を得る。これに少量の高Ｈ．ＬＢ界面活性剤を加え水
中に分散させ又は低Ｈ．Ｌ．Ｂ界面活性剤を加え、油中
に分散させる時それぞれ水性青色インク及び油性青色イ
ンクが得られる。Embodiment 2. FIG. A blue ink is prepared by dissolving 0.01% of a surfactant in a 1% aqueous ferrous sulfate solution, and mixing and reacting a 1% aqueous solution of tannic acid with stirring. After 10 minutes, this is centrifuged to precipitate the blue dye. When washed three or four times with water and dried at a low temperature, a beautiful blue organic pigment is obtained. A small amount of high H. Add LB surfactant and disperse in water. L. When the surfactant B is added and dispersed in oil, an aqueous blue ink and an oily blue ink are obtained, respectively.
実施例３．チタン白（酸化チタン）の染色 チタン白１
０ｇを０．３％の茶カテキン水溶液１００ｍｌに分散さ
せる。これに硫酸第一鉄の０．５％水溶液１００ｍｌを
かきまぜながら加える。１０分間軽くかきまぜた後に遠
心分離器で水層を分離し、水洗を繰り返し黒紫色に染ま
ったチタン白を得る。これを蒸気シリコン処理した後油
に分散させる。メークアップ化粧品用の顔料が得られ
る。Embodiment 3 FIG. Dyeing titanium white (titanium oxide) titanium white 1
0 g is dispersed in 100 ml of a 0.3% aqueous solution of tea catechin. To this, 100 ml of a 0.5% aqueous solution of ferrous sulfate is added with stirring. After gently stirring for 10 minutes, the aqueous layer is separated by a centrifugal separator and washed repeatedly to obtain titanium white stained in black purple. This is dispersed in oil after steam siliconization. A pigment for make-up cosmetics is obtained.
Claims (2)
に、第一鉄イオン又は第二鉄イオンを含む液を加え混合
する事により生成するタンニン類の鉄化合物1. An iron compound of tannins formed by adding a solution containing ferrous ions or ferric ions to a solution containing tannins (polyphenol) and mixing them.
にタンニン類（ポリフェノール）を含む液を含浸させ、
続いて第一鉄イオン又は第二鉄イオンを加える事によ
り、［請求項１］のタンニン類の鉄化合物をこれら粉体
又は繊維の表面及び又はその内部構造に形成する事を特
徴とするタンニン類（ポリフェノール）の鉄化合物2. The surface of powder or fiber and / or its internal structure is impregnated with a liquid containing tannins (polyphenol),
Subsequently, ferrous ions or ferric ions are added to form the iron compound of the tannin of claim 1 on the surface of the powder or fiber and / or the internal structure thereof. (Polyphenol) iron compounds
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP35067798A JP2000143683A (en) | 1998-11-04 | 1998-11-04 | Iron compound of tannin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP35067798A JP2000143683A (en) | 1998-11-04 | 1998-11-04 | Iron compound of tannin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000143683A true JP2000143683A (en) | 2000-05-26 |
Family
ID=18412110
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP35067798A Pending JP2000143683A (en) | 1998-11-04 | 1998-11-04 | Iron compound of tannin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000143683A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005047592A1 (en) * | 2003-11-12 | 2005-05-26 | Kurashiki Boseki Kabushiki Kaisha | Method for coloring cellulose fiber and colored cellulose fiber obtained by such method |
| WO2005047591A1 (en) | 2003-11-12 | 2005-05-26 | Kurashiki Boseki Kabushiki Kaisha | Method for coloring corporeal substance having polyamide bond and corporeal substance colored by such method |
| JP2007077337A (en) * | 2005-09-15 | 2007-03-29 | Takahiro Doihara | Color material composition, and color material, ink, and dyestuff using same, and manufacturing method of ink |
| JP2008197212A (en) * | 2007-02-09 | 2008-08-28 | Hubei Dinglong Chemical Co Ltd | Charge control agent and toner |
| WO2009078017A3 (en) * | 2007-12-17 | 2009-11-19 | S.O.S Color Ltd. | Agents, compositions and devices for temporary coloring local hair areas |
| KR20100094370A (en) * | 2009-02-18 | 2010-08-26 | 엘브이엠에이취 러쉐르쉐 | Coloring material and its uses, in particular in the field of cosmetics, especially for making up the skin and superficial body growths |
| US8152859B2 (en) | 2008-12-05 | 2012-04-10 | Conopco, Inc. | Colouring of keratinous fibers using a pretreatment comprising an iron salt and a colour developer comprising hydrolysable tannin |
| KR101475672B1 (en) * | 2013-11-29 | 2014-12-31 | 주식회사 화수목 | Method for manufacturing vegetable pigment using tannin |
| JP2017165960A (en) * | 2016-03-11 | 2017-09-21 | 満由美 菰田 | Method for separating components in Aji stone, a method for producing a stain using Aji stone, Blue light cut glass containing Aji stone as a raw material |
| CN115337251A (en) * | 2022-08-19 | 2022-11-15 | 南京斯拜科生物科技股份有限公司 | Continuous preparation method of natural plant melanin nano powder |
-
1998
- 1998-11-04 JP JP35067798A patent/JP2000143683A/en active Pending
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005047591A1 (en) | 2003-11-12 | 2005-05-26 | Kurashiki Boseki Kabushiki Kaisha | Method for coloring corporeal substance having polyamide bond and corporeal substance colored by such method |
| US7476263B2 (en) | 2003-11-12 | 2009-01-13 | Kurashiki Boseki Kabushiki Kaisha | Coloring method of tangible matter having polyamide bond and tangible matter colored by such method |
| US7481848B2 (en) | 2003-11-12 | 2009-01-27 | Kurashiki Boseki Kabushiki Kaisha | Method for coloring cellulose fiber and colored cellulose fiber obtained thereby |
| WO2005047592A1 (en) * | 2003-11-12 | 2005-05-26 | Kurashiki Boseki Kabushiki Kaisha | Method for coloring cellulose fiber and colored cellulose fiber obtained by such method |
| CN101035948B (en) * | 2003-11-12 | 2011-11-23 | 仓敷纺绩株式会社 | Method for coloring tangibles having polyamide bonds and tangibles colored by the method |
| JP2007077337A (en) * | 2005-09-15 | 2007-03-29 | Takahiro Doihara | Color material composition, and color material, ink, and dyestuff using same, and manufacturing method of ink |
| JP2008197212A (en) * | 2007-02-09 | 2008-08-28 | Hubei Dinglong Chemical Co Ltd | Charge control agent and toner |
| WO2009078017A3 (en) * | 2007-12-17 | 2009-11-19 | S.O.S Color Ltd. | Agents, compositions and devices for temporary coloring local hair areas |
| RU2500317C2 (en) * | 2007-12-17 | 2013-12-10 | С.О.С Колор Лтд. | Agents, compositions and devices for temporary dyeing of local sites of hair |
| US8152859B2 (en) | 2008-12-05 | 2012-04-10 | Conopco, Inc. | Colouring of keratinous fibers using a pretreatment comprising an iron salt and a colour developer comprising hydrolysable tannin |
| JP2010195780A (en) * | 2009-02-18 | 2010-09-09 | Lvmh Recherche | Coloring material and use thereof, in particular in field of cosmetic, especially for making up skin and superficial body growth |
| KR20100094370A (en) * | 2009-02-18 | 2010-08-26 | 엘브이엠에이취 러쉐르쉐 | Coloring material and its uses, in particular in the field of cosmetics, especially for making up the skin and superficial body growths |
| KR101746119B1 (en) * | 2009-02-18 | 2017-06-12 | 엘브이엠에이취 러쉐르쉐 | Coloring material and its uses, in particular in the field of cosmetics, especially for making up the skin and superficial body growths |
| KR101475672B1 (en) * | 2013-11-29 | 2014-12-31 | 주식회사 화수목 | Method for manufacturing vegetable pigment using tannin |
| JP2017165960A (en) * | 2016-03-11 | 2017-09-21 | 満由美 菰田 | Method for separating components in Aji stone, a method for producing a stain using Aji stone, Blue light cut glass containing Aji stone as a raw material |
| CN115337251A (en) * | 2022-08-19 | 2022-11-15 | 南京斯拜科生物科技股份有限公司 | Continuous preparation method of natural plant melanin nano powder |
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