JP2000127298A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2000127298A5 JP2000127298A5 JP1998304479A JP30447998A JP2000127298A5 JP 2000127298 A5 JP2000127298 A5 JP 2000127298A5 JP 1998304479 A JP1998304479 A JP 1998304479A JP 30447998 A JP30447998 A JP 30447998A JP 2000127298 A5 JP2000127298 A5 JP 2000127298A5
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- weight
- nbr
- fkm
- carboxyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001971 elastomer Polymers 0.000 claims description 57
- 239000005060 rubber Substances 0.000 claims description 57
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 11
- 229920000768 polyamine Polymers 0.000 claims description 8
- 229920001973 fluoroelastomer Polymers 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 6
- 229920000459 Nitrile rubber Polymers 0.000 description 19
- 239000000203 mixture Substances 0.000 description 19
- 239000003795 chemical substances by application Substances 0.000 description 16
- 229920002449 FKM Polymers 0.000 description 13
- 239000000853 adhesive Substances 0.000 description 12
- 230000001070 adhesive Effects 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 238000009472 formulation Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000004073 vulcanization Methods 0.000 description 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 239000000292 calcium oxide Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 238000007719 peel strength test Methods 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- -1 polyol compound Chemical class 0.000 description 3
- 230000003014 reinforcing Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 210000000188 Diaphragm Anatomy 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- OQMIRQSWHKCKNJ-UHFFFAOYSA-N 1,1-difluoroethene;1,1,2,3,3,3-hexafluoroprop-1-ene Chemical compound FC(F)=C.FC(F)=C(F)C(F)(F)F OQMIRQSWHKCKNJ-UHFFFAOYSA-N 0.000 description 1
- XHGMOUXCWNPJHF-UHFFFAOYSA-N 1,1-difluoroethene;1,1,2,3,3,3-hexafluoroprop-1-ene;1,1,2,2-tetrafluoroethene Chemical group FC(F)=C.FC(F)=C(F)F.FC(F)=C(F)C(F)(F)F XHGMOUXCWNPJHF-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 210000003491 Skin Anatomy 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003712 anti-aging Effects 0.000 description 1
- JXXZKEBTQSQDJX-UHFFFAOYSA-N carbamic acid;hexane-1,6-diamine Chemical compound NC(O)=O.NCCCCCCN JXXZKEBTQSQDJX-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxyl anion Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000001105 regulatory Effects 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
Description
【０００２】
【従来の技術】
ＦＫＭは、耐熱性、耐薬品性、耐老化性等の諸物性に優れ、また各種のオイル、ガソリン等にも優れた耐性を有しているため、燃料ホースやダイヤフラム、耐薬品ホース・パッキン等の素材に使用されている。
しかし、ＦＫＭは優れた性能を有する反面、ＮＢＲ、ＮＶ等の他のゴムに比べ１０〜２０倍と高価であり、そのため、一般ゴムと積層しＦＫＭの特徴を有する材料が注目されている。ＦＫＭと接着するポリマーとして、例えば、アクリロニトリル−ブタジエン共重合ゴム（以下ＮＢＲと略す）や、ＮＢＲとポリ塩化ビニル（ＰＶＣ）の複合体であるＮＶが挙げられる。
ＮＢＲやＮＶを用いた場合、通常の方法では加硫接着しないか、接着しても接着力が非常に弱く、接着力の優れた積層体は得られない。このため、ＮＢＲの場合は、金属化合物、シリカ系充填剤及びエポキシ樹脂と更にカルボン酸−１．８−ジアザビシクロ［５．４．０］ウンデセン−７を含有させる方法（特開昭５８−１６２３３５号）、ＮＢＲに特定の有機ホスホニユウム塩を含有させる方法（特開昭６３−２５２７３６号）も提案されている。しかし、いずれの方法においても、接着力を上げる為には、ＮＢＲにシリカを配合する必要があり、その場合、燃料ホース等では、電気抵抗が大きくなり、帯電するという問題が発生する。その為、使用が困難であった。また、低温特性の改良等から可塑剤を多く添加する場合、接着力が低くなり実用的でなかった。また、ＮＢＲ単独では、耐候性が劣ることから、光やオゾンと触れる外皮に使用するには制限があった。ＮＢＲに代えて、耐候性、低温性の良いＮＶの使用が望まれているが、これに他成分を配合するに際してＮＢＲに対する上記技術を使用した場合には、接着力が得られなかったり、耐候性、低温特性が劣るという問題があった。
0002.
[Conventional technology]
FKM has excellent physical properties such as heat resistance, chemical resistance, and aging resistance, and also has excellent resistance to various oils, gasoline, etc., so fuel hoses, diaphragms, chemical resistant hoses, packing, etc. It is used for the material of.
However, while FKM has excellent performance, it is 10 to 20 times more expensive than other rubbers such as NBR and NV, and therefore, a material laminated with general rubber and having the characteristics of FKM is attracting attention. As the polymer to adhere the FKM, for example, acrylonitrile - (hereinafter referred to as NBR) butadiene copolymer rubber and, NV can be mentioned a composite of NBR and polyvinyl chloride (PVC).
When NBR or NV is used, vulcanization adhesion is not performed by a usual method, or even if adhesion is performed, the adhesive strength is very weak, and a laminate having excellent adhesive strength cannot be obtained. Therefore, in the case of NBR, a method of further containing a metal compound, a silica-based filler, an epoxy resin, and a carboxylic acid-1.8-diazabicyclo [5.4.0] undecene-7 (Japanese Patent Laid-Open No. 58-162335). ), A method of incorporating a specific organic phosphonium salt into NBR (Japanese Patent Laid-Open No. 63-252736) has also been proposed. However, in either method, it is necessary to add silica to the NBR in order to increase the adhesive strength, and in that case, the fuel hose or the like has a problem that the electric resistance becomes large and the fuel is charged. Therefore, it was difficult to use. In addition, when a large amount of plasticizer is added due to improvement of low temperature characteristics, the adhesive strength becomes low and it is not practical. In addition, since NBR alone is inferior in weather resistance, its use on the exodermis that comes into contact with light or ozone is limited. It is desired to use NV having good weather resistance and low temperature resistance instead of NBR, but when the above technique for NBR is used when blending other components with this , adhesive strength cannot be obtained or weather resistance is not obtained. sex, there is a problem that the low temperature properties are inferior.
【０００３】
【発明が解決しようとする課題】
本発明の目的は、ＮＢＲのシリカ配合以外のカーボン等の配合で、低温特性の良好な、また、ＮＶの特徴である耐候性と低温特性を維持し、良好なＦＫＭとの接着性を示す積層体を提供することにある。
0003
[Problems to be Solved by the Invention]
An object of the present invention, the formulation of carbon other than the silica compounding of NBR, good low temperature properties, also maintaining weather resistance and low temperature properties which are characteristic of NV, laminated showing adhesion with good FKM To provide the body.
【０００４】
【発明を解決するための手段】
本発明は以上のような事情に基づいてなされたものである。即ち、本発明のゴム積層体は、（Ａ）フッ素ゴム以外のカルボキシル基を含有するゴムにポリアミン化合物を含有させてなる未加硫ゴム層と、（Ｂ）フッ素ゴムを主成分とした未加硫ゴム層とを重ね合わせて加硫したことを特徴とするものである。
0004
[Means for Solving the Invention]
The present invention has been made based on the above circumstances. That is, the rubber laminate of the present invention, (A) and the rubber formed by incorporating the polyamine compound to the unvulcanized rubber layer containing a carboxyl group other than fluorine rubber, unvulcanized mainly composed of (B) fluorine rubber It is characterized in that it is vulcanized by superimposing a vulcanized rubber layer.
本発明のＦＫＭに用いられるフッ素ゴム組成物としては、ビニリデンフルオライド−ヘキサフルオロプロペンの二元共重合体や、ビニリデンフルオライド−ヘキサフルオロプロペン−テトラフルオロエチレンの三元共重合体の合成ゴムなどであり、公知の加硫系や金属の酸化物、水酸化物、充填剤などの副資材が配合され、架橋剤としてポリオール化合物などが用いられるフッ素ゴム組成物を使用し、特に限定されない。 Examples of the fluororubber composition used in the FKM of the present invention include a binary copolymer of vinylidene fluoride-hexafluoropropene and a synthetic rubber of a ternary copolymer of vinylidene fluoride-hexafluoropropene-tetrafluoroethylene. , and the oxides of the known vulcanizing or metal hydroxides, auxiliary materials such as fillers are blended, using a fluororubber composition polyol compound and the like are used as the crosslinking agent is not particularly limited.
本発明に用いられるフッ素ゴム以外のカルボキシル基を含有するゴム（以下、カルボキシル基含有ゴムともいう。）としては、数平均分子量が１，０００以上のオリゴマーを含む高分子化合物であるゴム自体にカルボキシル基を含有しているゴムであり、また、カルボキシル基を含有しないゴムとのブレンド物であってもよい。 Rubber containing a carboxyl group other than fluorine rubber used in the present invention (hereinafter, also referred to as a carboxyl group-containing rubber.) The carboxyl number average molecular weight of the rubber itself is a polymer compound containing 1, 000 or more oligomers It is a rubber containing a group, and may be a blended product with a rubber containing no carboxyl group.
本発明に用いられるフッ素ゴム以外のカルボキシ基を含有するゴムの組成としては、ＳＢＲ、ＥＰＤＭ、ＥＰＭ、ＮＢＲ、ＮＶ、水素化ＮＢＲ等があり、好ましくはＮＢＲ、ＮＶ、水素化ＮＢＲ等である。接着に対しては、特に制約はなく通常の市販されている材料が使用出来る。耐候性、耐油性とかの要求性能に合わせて材料の選定を行う事が出来る。 The composition of the rubber containing a carboxy group other than the fluororubber used in the present invention includes SBR, EPDM, EPM, NBR, NV, hydrogenated NBR and the like, and preferably NBR, NV, hydrogenated NBR and the like. There are no particular restrictions on the adhesion, and ordinary commercially available materials can be used. The material can be selected according to the required performance such as weather resistance and oil resistance.
使用されるカルボキシル基含有ゴムとしては、カルボキシル化ＮＢＲ、液状のポリブタジエンをカルボキシル化した共重合体等を用いる。ゴム中のカルボキシル基量としては、ゴム中に０．１重量％〜１５重量％のカルボキシル基を含有していればよく、好ましくは、１重量％〜１０重量％が良い。各々のゴムの特徴が維持されれば、ゴム中のカルボキシル基量が規制されるものではないが、０．１重量％未満であれば、希望する接着力が得られない。 As the carboxyl group-containing rubber used, a carboxylated NBR, a copolymer obtained by carboxylating liquid polybutadiene, or the like is used. The amount of carboxyl groups in the rubber may be 0.1% by weight to 15% by weight, preferably 1% by weight to 10% by weight, as long as the rubber contains 0.1% by weight to 15% by weight of carboxyl groups. If the characteristics of each rubber are maintained , the amount of carboxyl groups in the rubber is not regulated, but if it is less than 0.1% by weight, the desired adhesive force cannot be obtained.
本発明で配合剤として用いられるポリアミン化合物としては、ヘキサメチレンジアミンカーバメート、Ｎ，Ｎ−ジシナミリジン−１，６−ヘキサンジアミン等があり、使用量としては、ゴム１００重量部に対して、好ましくは０．３〜１０重量部、さらに好ましくは１〜５重量部用いる。０．３重量部未満であれば、希望する接着力が得られず、１０重量部を超えると、加硫物性に悪影響が生じ、また、配合剤の価格が高価となり積層によるコスト低下が得られず好ましくない。 Examples of the polyamine compound used as a compounding agent in the present invention include hexamethylenediamine carbamate, N, N-disinamilidine-1,6 - hexanediamine, etc., and the amount used is preferably 0 with respect to 100 parts by weight of rubber. .3 to 10 parts by weight, more preferably 1 to 5 parts by weight. If it is less than 0.3 parts by weight, the desired adhesive force cannot be obtained, and if it exceeds 10 parts by weight, the vulcanized physical properties are adversely affected , the price of the compounding agent becomes high, and the cost due to lamination can be reduced. Not preferable.
本発明の加硫に用いられる加硫剤としては、特に限定されず通常ゴム工業で使用されているものでよい。硫黄及び／または硫黄化合物を主体とした加硫系や、有機過酸化物による架橋剤など、ゴムの加硫に用いられる加硫剤、加硫助剤、加硫促進剤が使用できる。また、加硫剤と共にカルシウムの酸化物、水酸化物を併用してもよい。 The vulcanizing agent used for the vulcanization of the present invention is not particularly limited and may be one usually used in the rubber industry. Vulcanizing agents, vulcanization aids, and vulcanization accelerators used for vulcanization of rubber, such as vulcanization systems mainly composed of sulfur and / or sulfur compounds, and cross-linking agents using organic peroxides, can be used. Further, a calcium oxide and a hydroxide may be used in combination with the vulcanizing agent.
本発明のゴムに配合される配合剤としては、それぞれの目的に応じて公知の添加剤、例えば、カーボンブラック等の補強剤、シリカ系補強剤、充填剤、可塑剤、老化防止剤、加工助剤などを使用することが出来る。本発明のゴム組成物は、前記のカルボキシル基含有ゴム及び加硫剤等をロール、ニーダー、バンバリーなどで混練りすることにより製造される。ゴム積層体にするには、これらゴム組成物を適当な厚みのシートに成形する。 The compounding agent to be blended in the rubber of the present invention includes known additives according to the respective purposes, for example, reinforcing agents such as carbon black, silica-based reinforcing agents, fillers, plasticizers, antiaging agents, and processing aids. it can be used, such as agent. The rubber composition of the present invention is produced by kneading the above-mentioned carboxyl group-containing rubber, vulcanizing agent, etc. with a roll, kneader, Banbury, or the like. To form a rubber laminate, these rubber compositions are molded into a sheet of appropriate thickness.
本発明のＦＫＭ材に用いられる配合剤としては、それぞれの目的に応じて公知の架橋剤（ポリオール化合物、パーオキサイド化合物、アミン化合物等）、架橋助剤、添加剤（例えば、カーボンブラック、シリカ系補強剤、充填剤、可塑剤）などを使用することが出来る。ＦＫＭ材のゴム組成物は、ロール、ニーダー、バンバリーなどで混練りすることにより製造される。ゴム積層体にするには、これらゴム組成物を適当な厚みのシートに成形する。 The blending agent used in FKM material of the present invention, known crosslinking agents in accordance with the respective purposes (the polyol compound, Paoki side compound, amine compound, etc.), crosslinking aid, additives (e.g., carbon black, silica Reinforcing agents, fillers, plasticizing agents ) and the like can be used. The rubber composition of the FKM material is produced by kneading with a roll, a kneader, a Banbury or the like. To form a rubber laminate, these rubber compositions are molded into a sheet of appropriate thickness.
カルボキシル基含有ゴム及びポリアミン化合物を含む未加硫ゴムと、ＦＫＭを主体とした未加硫ゴムをシートに成形後、両シートを未加硫の状態で接触させ、ホットプレス又は、加硫缶を用い加圧、加硫を行い、両ゴムシートを加硫接着させる。また、２層押出し法により積層チューブに成形後、加硫缶を用い加圧、加硫をさせる方法でもよい。ホットプレスの条件としては、温度１４０〜２００℃程度で加圧し約５分〜６０分程度加硫する。加硫缶を用い場合は、温度１３０〜１８０℃程度で約１０分〜１２０分程度加硫させる。 After molding the unvulcanized rubber containing a carboxyl group-containing rubber and the polyamine compound and the unvulcanized rubber mainly composed of FKM into a sheet, both sheets are brought into contact with each other in an unvulcanized state, and a hot press or a vulcanized can is formed. Pressurize and vulcanize, and vulcanize and bond both rubber sheets. Alternatively, a method may be used in which a laminated tube is formed by a two-layer extrusion method and then pressurized and vulcanized using a vulcanizing can. As the conditions for hot pressing, pressure is applied at a temperature of about 140 to 200 ° C. and vulcanization is performed for about 5 to 60 minutes. When a vulcanizing can is used, it is vulcanized at a temperature of about 130 to 180 ° C. for about 10 to 120 minutes.
なお、実施例中の％及び部は、特に断らない限り、重量基準である。また、実施例および比較例の接着力の測定は、下記の方法により行った。以下の例で用いた、ＮＢＲ、ＮＶ配合物層を形成する配合処方は、下記表１、表２の如くである。以下の例で用いた、ＦＫＭ配合物層を形成する配合処方は、下記表３の如くである。ＦＫＭ配合物は、ロールで混練りし、約２ｍｍの均一な厚みのシートを作成した。ＮＢＲ、ＮＶ配合物は、加硫系剤、ＣａＯ、及びポリアミン化合物以外を、バンバリーで混練りし、その後、加硫系剤、ＣａＯ、及びポリアミン化合物をロールにて添加した。その後、約２ｍｍの均一な厚みのシートを作成した。剥離強度の試験片は、ＦＫＭ、ＮＢＲ、ＮＶの各配合物シートを６ｃｍ×１５ｃｍの短冊型に切った後貼り合わせ、１５５℃の加硫缶で３０分加硫し、室温に２４時間以上放置後試験を行った。なお、剥離試験のチャックに掴む部分のため、予めセロハンで両シートの一部が互いに接着されないようにした。次に、この試験片について、ＪＩＳ Ｋ ６３０１に準じて、引張り速度５０ｍｍ／ｍｉｎの条件で剥離試験を行った。 Unless otherwise specified,% and parts in the examples are based on weight. In addition, the adhesive strength of Examples and Comparative Examples was measured by the following method. The compounding formulations used in the following examples to form the NBR and NV compounding layers are as shown in Tables 1 and 2 below. The formulation used to form the FKM formulation layer used in the following examples is as shown in Table 3 below. The FKM formulation was kneaded with a roll to prepare a sheet having a uniform thickness of about 2 mm. For the NBR and NV formulations, other than the vulcanizing agent, CaO, and the polyamine compound were kneaded with Banbury, and then the vulcanizing agent, CaO, and the polyamine compound were added by roll. Then, a sheet having a uniform thickness of about 2 mm was prepared. The peel strength test piece is obtained by cutting FKM, NBR, and NV compound sheets into strips of 6 cm x 15 cm, pasting them together, vulcanizing them in a vulcanization can at 155 ° C for 30 minutes, and leaving them at room temperature for 24 hours or more. A post-test was performed. Since it is a part to be gripped by the chuck of the peeling test, a part of both sheets was prevented from being adhered to each other in advance with cellophane. Next, this test piece was subjected to a peeling test under the condition of a tensile speed of 50 mm / min according to JIS K 6301.
実施例
表１に記載した配合処方の配合番号１〜５のゴムと表３のフッ素ゴムとを加硫接着させてなるゴム積層体の剥離強度試験結果を表４に示す。表４に示す通り、配合番号１〜５のゴムを用いた場合には、高い剥離強度とゴム破壊を示している。
Examples Table 4 shows the peel strength test results of a rubber laminate obtained by vulcanizing and adhering the rubbers of formulation numbers 1 to 5 of the formulation shown in Table 1 and the fluororubber of Table 3. As shown in Table 4, when the rubbers of Formulation Nos. 1 to 5 are used, high peel strength and rubber breakage are shown.
比較例
表２に記載した配合処方の配合番号６〜１１のゴムと表３のフッ素ゴムとを加硫接着させてなるゴム積層体の剥離強度試験結果を表４に示す。表４に示す通り、配合番号６〜１１のゴムを用いた場合には、剥離強度が低く実用に耐えない。
Comparative Example Table 4 shows the peel strength test results of a rubber laminate obtained by vulcanizing and adhering the rubbers of the compounding formulations Nos. 6 to 11 shown in Table 2 and the fluororubber of Table 3. As shown in Table 4, when the rubbers of Formulation Nos. 6 to 11 are used, the peel strength is low and they cannot be put into practical use.
【００２４】
【発明の効果】
本発明のフッ素ゴム以外のカルボキシル基を含有するゴム及びポリアミン化合物を含有した未加硫ゴム層と、ＦＫＭを主成分とした未加硫ゴム層とを重ね合わせ加硫したゴム積層体は、両者の剥離強度が大きく、燃料ホースやダイヤフラム、耐薬品ホース・パッキン等の素材の外皮に使用される。
0024
【Effect of the invention】
Unvulcanized rubber layer containing a rubber and a polyamine compound containing a carboxyl group other than fluorine rubber of the present invention, the rubber laminate vulcanized superposing the unvulcanized rubber layer composed mainly of FKM are both It has a high peeling strength and is used for the outer skin of materials such as fuel hoses, diaphragms, chemical resistant hoses and packing.
以下に本発明の効果を列挙する。
接着体の剥離試験結果が、高い接着力を示し、剥離が凝集破壊である。可塑剤を多く使用しても接着力の低下が少ない。接着力を得る為のシリカの使用が必要でなく、配合設計上の制約を受けない。架橋形態の幅が広く配合の自由度が広がった。
The effects of the present invention are listed below.
The peeling test result of the adhesive shows high adhesive strength, and the peeling is cohesive fracture. Even if a large amount of plasticizer is used, there is little decrease in adhesive strength. There is no need to use silica to obtain adhesive strength, and there are no restrictions on compounding design. The range of cross-linked forms is wide and the degree of freedom of compounding is widened.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10304479A JP2000127298A (en) | 1998-10-26 | 1998-10-26 | Rubber laminate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10304479A JP2000127298A (en) | 1998-10-26 | 1998-10-26 | Rubber laminate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000127298A JP2000127298A (en) | 2000-05-09 |
| JP2000127298A5 true JP2000127298A5 (en) | 2005-10-27 |
Family
ID=17933529
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10304479A Pending JP2000127298A (en) | 1998-10-26 | 1998-10-26 | Rubber laminate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000127298A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5644485B2 (en) * | 2010-12-27 | 2014-12-24 | 日本ゼオン株式会社 | Rubber laminate |
-
1998
- 1998-10-26 JP JP10304479A patent/JP2000127298A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4876581B2 (en) | Method for producing thermoplastic elastomer / rubber laminate with improved weather resistance and pneumatic tire using the same | |
| WO2005030479A1 (en) | Laminate and pneumatic tires made by using the same | |
| WO2006121140A1 (en) | Multilayer body and pneumatic tire using same | |
| WO2007043497A1 (en) | Thermoplastic elastomer composition/pressure-sensitive adhesive/diene rubber composition laminate and pneumatic tires made by using the same | |
| JPH10323953A (en) | Composite material comprising forming material with base of polyamide on one side, and vulcanizable fluorine-elastomer on other side | |
| JP2010042669A (en) | Fluororubber lamination and its production process | |
| WO2010119685A1 (en) | Adhesive composition, bonding method, laminate and tire | |
| CA2181925A1 (en) | Laminate of vulcanizable rubber composition layers, process for producing rubber laminate, and rubber laminate | |
| JP2583444B2 (en) | Manufacturing method of rubber laminate | |
| JPS63205217A (en) | Manufacture of vinylidene fluoride resin laminate | |
| JP2583442B2 (en) | Manufacturing method of rubber laminate | |
| JP4677823B2 (en) | Thermoplastic elastomer laminate | |
| JP5218277B2 (en) | Laminated hose of thermoplastic resin composition and rubber composition | |
| JP2000127298A5 (en) | ||
| JP2000006317A (en) | Rubber laminate and hose | |
| JP2001162722A (en) | Polyamide/rubber composite | |
| JP3582112B2 (en) | Bonding composition and laminate using the bonding composition | |
| JP2000273241A (en) | Rubber composition, rubber laminate, hose and its production | |
| JP2000127298A (en) | Rubber laminate | |
| JPH085970B2 (en) | Manufacturing method of rubber laminate | |
| JP4778160B2 (en) | Adhesive primer composition, waterproof sheet adhesive method using the composition, and damaged part repair method for the same | |
| TW201840424A (en) | Laminate | |
| JP7432820B2 (en) | Laminate and its manufacturing method | |
| JP2699579B2 (en) | Rubber laminate | |
| JPH0822585B2 (en) | Manufacturing method of rubber laminate |