JP2000093495A - Aromatic carbon sintered compact - Google Patents
Aromatic carbon sintered compactInfo
- Publication number
- JP2000093495A JP2000093495A JP10309574A JP30957498A JP2000093495A JP 2000093495 A JP2000093495 A JP 2000093495A JP 10309574 A JP10309574 A JP 10309574A JP 30957498 A JP30957498 A JP 30957498A JP 2000093495 A JP2000093495 A JP 2000093495A
- Authority
- JP
- Japan
- Prior art keywords
- perfume
- carbon
- sintered body
- porous carbon
- porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 32
- 125000003118 aryl group Chemical group 0.000 title claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 239000011148 porous material Substances 0.000 claims abstract description 4
- 239000003205 fragrance Substances 0.000 claims description 19
- 239000003575 carbonaceous material Substances 0.000 abstract description 11
- 238000000465 moulding Methods 0.000 abstract description 7
- 239000002304 perfume Substances 0.000 abstract description 7
- 238000010304 firing Methods 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 239000011230 binding agent Substances 0.000 abstract description 2
- 239000000571 coke Substances 0.000 abstract description 2
- 229910002804 graphite Inorganic materials 0.000 abstract description 2
- 239000010439 graphite Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 229920001187 thermosetting polymer Polymers 0.000 abstract description 2
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 230000002706 hydrostatic effect Effects 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000005416 organic matter Substances 0.000 abstract 1
- 238000012856 packing Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000009834 vaporization Methods 0.000 abstract 1
- 230000008016 vaporization Effects 0.000 abstract 1
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical compound CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000007088 Archimedes method Methods 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 230000037237 body shape Effects 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000009694 cold isostatic pressing Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229940073505 ethyl vanillin Drugs 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】この発明は、芳香性炭素焼結
体に関する。The present invention relates to an aromatic carbon sintered body.
【０００２】[0002]
【発明が解決しようとする課題】香水等をはじめとする
香料を、芳香性を維持しつつ所定期間保持するために従
来は布や綿などに香料をしみこませていた。しかし、香
料による布のシミや傷み或いは皮膚等に接触することに
より皮膚荒れの原因となる等の問題があった。また揮発
性の固形材に香料を混ぜる方法が芳香剤などにおいて用
いられているが、専用の容器が必要であり、皮膚に触れ
た場合には皮膚荒れなど生ずる問題があった。更にプラ
スチックに香料を含有させることも行われているが、芳
香性が弱いこと、含有する香料の種類に制限があるこ
と、プラスチック自体が環境による変化を受けやすいこ
と等の問題があり、所定期間芳香性を維持でき、且つ人
体などの害を及ぼすことのない安定した芳香性材料の開
発が望まれていた。本発明は上記要望に応えるべくなさ
れたもので、従来の欠点を改善した芳香性材料を提供す
ることを目的とする。Conventionally, perfume such as perfume is soaked in cloth, cotton, or the like in order to maintain the fragrance for a predetermined period of time. However, there has been a problem that the fragrance causes the skin to become rough due to contact with the stains or damage of the cloth or the skin. In addition, a method of mixing a fragrance with a volatile solid material is used for a fragrance or the like. However, a special container is required, and there is a problem that the skin becomes rough when touching the skin. Furthermore, plastics are also made to contain fragrances. However, there are problems such as low aromaticity, restrictions on the types of fragrances contained, and the plastic itself being susceptible to environmental changes. There has been a demand for the development of a stable aromatic material that can maintain the aromaticity and does not cause harm to the human body or the like. The present invention has been made to meet the above-mentioned demands, and an object of the present invention is to provide an aromatic material in which the conventional disadvantages are improved.
【０００３】[0003]
【課題を解決するための手段】上記目的を達成するため
に本発明は、炭素焼結体の開気孔に液状の香料を充填し
たことを特徴とする。該炭素焼結体の開気孔率は３ｖｏ
ｌ％〜５０ｖｏｌ％が望ましく、またショア硬さ１００
〜１３０の硬質性を有することが望ましい。該炭素焼結
体は種々の形に成形可能であり、例えば球体や、片、
棒、板等の形状とすることが可能である。該炭素焼結体
は、炭素を所定の形状に成形して焼成して焼結体とし、
該焼結体を脱気した後液状の香料を加圧含浸することが
望ましい。In order to achieve the above object, the present invention is characterized in that the open pores of the carbon sintered body are filled with a liquid fragrance. The open porosity of the carbon sintered body is 3 vol.
1% to 50% by volume, and a Shore hardness of 100
It is desirable to have a hardness of ~ 130. The carbon sintered body can be formed into various shapes, for example, a sphere, a piece,
It can be in the shape of a bar, a plate or the like. The carbon sintered body is formed by molding carbon into a predetermined shape and firing to form a sintered body,
It is preferable that the sintered body be degassed and then impregnated with a liquid fragrance under pressure.
【０００４】[0004]
【発明の実施の形態】以下本発明の実施の形態を説明す
る。この炭素焼結体は高強度を有する有機炭素物を出発
原料とする。有機炭素物とはピッチ、熱硬化性樹脂を結
合材とし、骨材にコークス、カーボンブラック、黒鉛を
用いた混練物の粉砕品または自己焼結性を有する炭素質
粉末を云う。その有機炭素物をプレス成形、冷間静水圧
成形等の通常の成形方法で所望の形状に成形する。この
時の成形圧は、成形体形状を保ち、カサ比重の低い成形
体を得るため０．３t/cm2から２．０t/cm2が良い。Embodiments of the present invention will be described below. This carbon sintered body uses an organic carbon material having high strength as a starting material. The organic carbon material refers to a pulverized kneaded product using coke, carbon black, or graphite as an aggregate, using a pitch or a thermosetting resin as a binder, or a carbonaceous powder having self-sintering properties. The organic carbon material is formed into a desired shape by a normal forming method such as press forming or cold isostatic pressing. Molding pressure at this time, maintaining the green body shape, good 2.0 t / cm 2 from 0.3 t / cm 2 to obtain a molded article having low bulk specific gravity.
【０００５】次にこの成形体を非酸化性雰囲気下で焼成
し、含有する有機物を重合、分解、気化させ、所望の開
気孔率を有する多孔質炭素物を得る。この時の焼成温度
は有機炭素物が重合、分解、気化する温度である８００
℃以上が良い。これによって開気孔率３vol％〜５０vol
％の多孔質炭素物を得る。[0005] Next, the molded body is fired in a non-oxidizing atmosphere to polymerize, decompose and vaporize an organic substance contained therein to obtain a porous carbon material having a desired open porosity. The firing temperature at this time is 800 at which the organic carbon material is polymerized, decomposed, and vaporized.
C or higher is good. This results in an open porosity of 3 vol% to 50 vol.
% Of the porous carbon material is obtained.
【０００６】開気孔率３vol％以下では香料が殆ど充填
されていず、また開気孔率５０vol％以上では炭素物の
強度が得られないため、３vol％〜５０vol％の範囲が適
当である。When the open porosity is 3 vol% or less, almost no fragrance is filled, and when the open porosity is 50 vol% or more, the strength of the carbonaceous material cannot be obtained. Therefore, the range of 3 vol% to 50 vol% is appropriate.
【０００７】この多孔質炭素物を更に研磨加工等により
光沢を有する多孔質炭素球に仕上げる。球体とするのは
一例であって形状は任意であり、片状、板状、棒状等種
々の形状が可能である。[0007] The porous carbon material is further polished to a glossy porous carbon sphere. The shape of the sphere is merely an example, and the shape is arbitrary, and various shapes such as a piece, a plate, and a bar are possible.
【０００８】次に、該多孔質炭素球を真空中で脱気し、
液状にした香料を多孔質炭素球に満たした後、大気圧に
戻し多孔質内部に香料を充填させる。さらに高圧含浸装
置を用い、高い圧力をかけて香料を更に充填する方が良
い。これにより炭素球の多孔質部分には、十分な香料が
充填される。Next, the porous carbon sphere is degassed in a vacuum,
After filling the porous carbon spheres with the liquefied fragrance, the pressure is returned to the atmospheric pressure, and the fragrance is filled inside the porous material. It is better to use a high-pressure impregnating device and further apply a high pressure to further fill the fragrance. Thus, the porous portion of the carbon sphere is filled with a sufficient fragrance.
【０００９】この時使用する香料は、液状であるならば
特に指定はない。また固形香料でも溶媒に溶かして使用
することも可能である。The fragrance used at this time is not particularly specified as long as it is liquid. It is also possible to use a solid fragrance dissolved in a solvent.
【００１０】＜実施例＞平均粒径２０μｍのメソフェー
スカーボン（呉羽化学工業製ＭＨ−１Ｐ）を所定の形状
の型を用いて、成形圧０．６t/cm2で加圧成形し、４mm
の球状成形体を得た。その成形体を非酸化性雰囲気中
で、1000℃１時間焼成し、球状焼結体を得た。得られた
焼結体に対し、アルキメデス法により開気孔率を測定し
た結果、１２vol％であった。次に、球状多孔質焼結体
を研磨加工で仕上げ、光沢を有する多孔質炭素球を得
た。その多孔質炭素球を真空含浸装置で脱気後、液状香
料（塩野香料製エチルバニリン）に浸漬し、さらに高圧
含浸装置で加圧含浸して、芳香性炭素球を得た。その芳
香性炭素球は、３週間以上空気中に放置しても変質する
ことなく光沢を保ち、芳香性を持ち続けた。<Example> A mesophase carbon having an average particle diameter of 20 μm (MH-1P manufactured by Kureha Chemical Industry Co., Ltd.) was press-formed at a molding pressure of 0.6 t / cm 2 using a mold having a predetermined shape, and 4 mm in diameter.
Was obtained. The compact was fired in a non-oxidizing atmosphere at 1000 ° C. for 1 hour to obtain a spherical sintered body. The open porosity of the obtained sintered body measured by the Archimedes method was 12 vol%. Next, the spherical porous sintered body was finished by polishing to obtain a glossy porous carbon sphere. After degassing the porous carbon spheres with a vacuum impregnating device, the porous carbon spheres were immersed in a liquid fragrance (ethyl vanillin manufactured by Shiono Perfume Co., Ltd.), and further impregnated with pressure by a high pressure impregnating device to obtain aromatic carbon spheres. The aromatic carbon spheres remained glossy and did not deteriorate even after being left in the air for three weeks or more, and maintained their aromatic character.
【００１１】[0011]
【発明の効果】以上説明したように本発明の芳香性炭素
焼結体にれば、芳香性を所定期間維持しつつ、香料を安
定して保持できる。また、環境による変化もなく、人体
に対しても害を与えることがない。更に炭素焼結体を研
磨することにより光沢を与えることができ、外見上も好
ましいなどの効果がある。As described above, according to the aromatic carbon sintered body of the present invention, the fragrance can be stably retained while maintaining the aromaticity for a predetermined period. In addition, there is no change due to the environment and no harm to human body. Further, polishing the carbon sintered body can impart gloss, and has effects such as appearance.
フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ１１Ｂ 9/00 Ｃ０４Ｂ 35/52 Ｚ Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat II (reference) C11B 9/00 C04B 35/52 Z
Claims (4)
した、 ことを特徴とする芳香性炭素焼結体。1. An aromatic carbon sintered body, characterized in that a liquid fragrance is filled in open pores of the carbon sintered body.
０ｖｏｌ％である、 請求項１に記載の芳香性炭素焼結体。2. The open porosity of the carbon sintered body is 3 vol% to 5 vol.
The aromatic carbon sintered body according to claim 1, wherein the content is 0 vol%.
である、 請求項１又は２に記載の芳香性炭素焼結体。3. The carbon sintered body has a Shore hardness of 100 to 130.
The aromatic carbon sintered body according to claim 1 or 2.
結体とし、 該焼結体を脱気した後液状の香料を加圧含浸した、 ことを特徴とする芳香性炭素焼結体。4. An aromatic carbon sinter, wherein carbon is formed into a predetermined shape and fired to form a sintered body, and the sintered body is degassed and then impregnated with a liquid fragrance under pressure. body.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10309574A JP2000093495A (en) | 1998-09-18 | 1998-09-18 | Aromatic carbon sintered compact |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10309574A JP2000093495A (en) | 1998-09-18 | 1998-09-18 | Aromatic carbon sintered compact |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000093495A true JP2000093495A (en) | 2000-04-04 |
Family
ID=17994676
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10309574A Pending JP2000093495A (en) | 1998-09-18 | 1998-09-18 | Aromatic carbon sintered compact |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000093495A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011123723A1 (en) | 2010-03-31 | 2011-10-06 | Enviroscent, Inc. | Methods, compositions and articles for olfactory-active substances |
| US9694097B2 (en) | 2014-09-29 | 2017-07-04 | Enviroscent, Inc. | Coating providing modulated release of volatile compositions |
| US10286098B2 (en) | 2004-06-24 | 2019-05-14 | Enviroscent, Inc. | Scent devices and methods |
| US10596290B2 (en) | 2015-06-09 | 2020-03-24 | Enviroscent, Inc. | Formed three-dimensional matrix and associated coating providing modulated release of volatile compositions |
| US10953125B2 (en) | 2016-09-30 | 2021-03-23 | Enviroscent, Inc. | Articles formed of pulp base materials with modulated scent release |
-
1998
- 1998-09-18 JP JP10309574A patent/JP2000093495A/en active Pending
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10286098B2 (en) | 2004-06-24 | 2019-05-14 | Enviroscent, Inc. | Scent devices and methods |
| US10987445B2 (en) | 2010-03-31 | 2021-04-27 | Enviroscent, Inc. | Methods, compositions and articles for olfactory-active substances |
| JP2013526906A (en) * | 2010-03-31 | 2013-06-27 | エンバイロセント，インコーポレイテッド | Methods, compositions and articles for olfactory actives |
| EP2552499A4 (en) * | 2010-03-31 | 2016-06-15 | Enviroscent Inc | Methods, compositions and articles for olfactory-active substances |
| WO2011123723A1 (en) | 2010-03-31 | 2011-10-06 | Enviroscent, Inc. | Methods, compositions and articles for olfactory-active substances |
| US9694096B2 (en) | 2010-03-31 | 2017-07-04 | Enviroscent, Inc. | Methods compositions and articles for olfactory-active substances |
| US11167055B2 (en) | 2010-03-31 | 2021-11-09 | Enviroscent, Inc. | Methods, compositions and articles for olfactory-active substances |
| US9694097B2 (en) | 2014-09-29 | 2017-07-04 | Enviroscent, Inc. | Coating providing modulated release of volatile compositions |
| US10647868B2 (en) | 2014-09-29 | 2020-05-12 | Enviroscent, Inc. | Coating providing modulated release of volatile compositions |
| US11498095B2 (en) | 2014-09-29 | 2022-11-15 | Enviroscent, Inc. | Coating providing modulated release of volatile compositions |
| US10596290B2 (en) | 2015-06-09 | 2020-03-24 | Enviroscent, Inc. | Formed three-dimensional matrix and associated coating providing modulated release of volatile compositions |
| US11241514B2 (en) | 2015-06-09 | 2022-02-08 | Enviroscent, Inc. | Formed three-dimensional matrix and associated coating providing modulated release of volatile compositions |
| US10953125B2 (en) | 2016-09-30 | 2021-03-23 | Enviroscent, Inc. | Articles formed of pulp base materials with modulated scent release |
| US11458222B2 (en) | 2016-09-30 | 2022-10-04 | Enviroscent, Inc. | Articles formed of pulp base materials with modulated scent release |
| US11931487B2 (en) | 2016-09-30 | 2024-03-19 | Enviroscent, Inc. | Articles formed of pulp base materials with modulated scent release |
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