JP2000072578A - Production of organic fertilizer of shellfishes fouled in cooling water channel or the like of condenser - Google Patents

Production of organic fertilizer of shellfishes fouled in cooling water channel or the like of condenser

Info

Publication number
JP2000072578A
JP2000072578A JP10249724A JP24972498A JP2000072578A JP 2000072578 A JP2000072578 A JP 2000072578A JP 10249724 A JP10249724 A JP 10249724A JP 24972498 A JP24972498 A JP 24972498A JP 2000072578 A JP2000072578 A JP 2000072578A
Authority
JP
Japan
Prior art keywords
shellfish
organic fertilizer
shell
fermentation
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10249724A
Other languages
Japanese (ja)
Inventor
Mikio Aoki
幹夫 青木
Tsuneo Sato
常夫 佐藤
Ten Ando
天 安藤
Hideo Tsuchida
秀夫 土田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AOKI KANKYO JIGYO KK
Tohoku Electric Power Co Inc
Original Assignee
AOKI KANKYO JIGYO KK
Tohoku Electric Power Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by AOKI KANKYO JIGYO KK, Tohoku Electric Power Co Inc filed Critical AOKI KANKYO JIGYO KK
Priority to JP10249724A priority Critical patent/JP2000072578A/en
Publication of JP2000072578A publication Critical patent/JP2000072578A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F1/00Fertilisers made from animal corpses, or parts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin

Landscapes

  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a method for producing an organic fertilizer by which shellfishes such as Mytilus edulis thickly growing in a seawater intake channel, etc., of various kinds of plants such as power stations can simply be converted into a fertilizer at a low cost. SOLUTION: An operation to remove shellfishes in a water intake channel →a step for grading shells and shell fleshes (vibrating type or rotating type grading) → a step for dehydrating treatment with a centrifugal separator to a pulverizing step with a shell pulverizer are performed in the spot. An organic fertilizer is then produced by a step for fermentation treatment with a primary fermenting machine → a step for secondary fermentation treatment in a room →a step for pelletizing. The pulverized shells or shell fleshes, etc., are blended with an organic fertilizer raw material for promoting the fermentation such as poultry manures, coffee bean pulps or organic sludges to thereby recycle most of the shells, algae, sludges, etc., collected from the water intake channel to the organic fertilizer. The cost can remarkably be reduced by the treatment on the spot.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明はプラント取水路など
に付着する貝類の有機肥料製造方法に係り、特に、火力
発電所や原子力発電所等の復水器などに使用する冷却水
路や、あるいは船底などに付着する貝類の肥料化に好適
な復水器冷却水路等の付着貝類の有機肥料製造方法に関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing an organic fertilizer for shellfish attached to a plant intake channel, and more particularly to a cooling channel or a ship bottom used for a condenser in a thermal power plant or a nuclear power plant. The present invention relates to a method for producing an organic fertilizer of attached shellfish such as a condenser cooling water channel suitable for converting the shellfish attached to the fertilizer into fertilizer.

【0002】[0002]

【従来の技術】火力発電所や原子力発電所の復水器冷却
水路などに付着するムラサキイガイを主とする大量の貝
類は、水路から除去した後、一般廃棄物あるいは産業廃
棄物として埋め立て処分を行っているのが現状である。
しかし、将来、埋立処分場の不足も懸念されることに加
え、地球環境保護の観点から、社会的に肥料化などの有
効利用が求められている。
2. Description of the Related Art A large amount of mussels, mainly mussels, attached to condenser cooling channels of thermal power plants and nuclear power plants, are removed from the channels and disposed of as landfill or industrial waste. That is the current situation.
However, in the future, there is a concern that there will be a shortage of landfill sites, and from the viewpoint of protecting the global environment, there is a demand for socially effective use of fertilizers.

【0003】電力各社とも当該貝類の肥料化に積極的に
取り組んでいるものの、処理装置の価格が莫大であると
ともに、その処理過程において大量の熱源および動力を
必要とすることに加え、専用の運転員を配して運転する
必要があるなどのため、商業ベースに乗らないのが現状
である。さらに、せっかく肥料化を行っても、その成分
から土壌改良剤等の用途が限られるため、肥料会社に有
償で引き取ってもらったり、埋立処分を行っているとこ
ろも多い。
[0003] Although electric power companies are actively working on the conversion of the shellfish into fertilizer, the price of the processing equipment is enormous, and in addition to requiring a large amount of heat source and power in the processing process, a special operation is required. At present, they do not get on a commercial base because of the need to operate with staff. Furthermore, even if fertilizer is used, the use of the soil conditioner and the like is limited due to its components, so there are many places where fertilizer companies have to pay for it or landfill it.

【0004】火力発電所や原子力発電所などの冷却水路
付着貝類の肥料化については、圧搾、粉砕後、モンモリ
ロナイトを混合して有機肥料とする方法(特開昭27−
200280号公報参照)、貝類に酸化カルシウムを加
えた後、加熱乾燥させて肥料とする方法(特開昭59−
156989号公報参照)、および、貝類を水洗後、5
00〜900℃で焼却して炭酸カルシウムとし、これを
脱水乾燥して肥料やセメント等の原料とする方法(特開
平4−346882号公報参照)などがある。
[0004] For the fertilization of shellfish attached to cooling water channels in thermal power plants and nuclear power plants, squeezing, pulverization, and mixing with montmorillonite to produce organic fertilizer (Japanese Patent Application Laid-Open No.
200280), a method in which calcium oxide is added to shellfish and then heated and dried to obtain a fertilizer (JP-A-59-1984).
No. 156989) and after washing the shellfish with water, 5
There is a method in which calcium carbonate is incinerated at 00 to 900 ° C. to obtain calcium carbonate, which is dehydrated and dried to be used as a raw material for fertilizers and cement (see JP-A-4-346882).

【0005】[0005]

【発明が解決しようとする課題】しかしながら、これら
の従来技術における肥料製造方法は、製造するための設
備が大規模であることに加え、装置価格も数億円以上の
ものであり、コストが高価なため、商業ベースに乗らな
かったり、肥料化してもせいぜい土壌改良剤などに限ら
れたものであり、市場性に乏しく、殆ど有効利用がなさ
れていない。このような従来の問題を解決するための課
題を次に示す。
However, these conventional methods of producing fertilizer in the prior art require large-scale production equipment, a cost of several hundred million yen or more, and a high cost. For this reason, they are not commercially available, and even when fertilized, they are limited to soil amendments at best, and they have poor marketability and are hardly used effectively. Problems for solving such a conventional problem will be described below.

【0006】 低廉な処理コスト 従来技術のように、大規模で高価な設備を使用するので
はなく、現在、既に発電所などで使用している低廉な装
置や、廃棄物処理業者が用いている機器等を組み合わせ
るとともに、短期間で肥料化できるような技術の開発が
必要である。また、工程等の処理装置を可搬式とするな
ど、肥料製造場所を任意にすることにより、コストが最
も低廉な製造場所を選択できるような技術を開発する必
要がある。
Inexpensive treatment cost Rather than using large-scale and expensive equipment as in the prior art, inexpensive equipment already used in power plants and the like, and waste disposal companies are currently using it. It is necessary to develop equipment that can be used as a fertilizer in a short period of time while combining equipment. In addition, it is necessary to develop a technology that can select a production site with the lowest cost by making a fertilizer production site arbitrary, such as making a processing device such as a process portable.

【0007】一方、発酵処理工程においては、従来技術
のように、特殊な発酵菌を使用することなく、鶏糞等の
肥料原料が有している発酵菌により発酵させることによ
って、特殊発酵菌の技術開発費等の価格転嫁がないよう
にして、低廉な処理コストにする必要がある。また、特
殊な発酵菌による貝類の発酵処理では、発酵菌の中種と
して米糠等の栄養剤を約50%程度添加して処理する必
要があり、処理コスト増の一因となっている。
[0007] On the other hand, in the fermentation treatment step, fermentation by fermentation bacteria contained in fertilizer raw materials such as chicken manure is carried out without using special fermentation bacteria as in the prior art. It is necessary to keep processing costs low so as not to pass on development costs. Further, in the fermentation treatment of shellfish by a special fermentation bacterium, it is necessary to add about 50% of a nutrient such as rice bran as a fermentation bacterium, which is one of the causes, which contributes to an increase in treatment cost.

【0008】 広い用途 貝類単独の肥料では、土壌改良剤等の用途に限られるこ
とが懸念されるため、例えば他の有機物と混合すること
によって、一般の有機肥料より有益なものを製造し商業
ベースにのせる必要がある。
[0008] There is a concern that the use of fertilizers solely for shellfish is limited to applications such as soil amendments. For example, by mixing with other organic substances, a more beneficial product is produced than a general organic fertilizer, and commercial use is possible. It is necessary to put on.

【0009】本発明の目的は、上述した状況を踏まえ、
発電所等の各種プラントの海水取水路などに密生するム
ラサキイガイ等の貝類を、簡易にしかも低コストで肥料
化する有機肥料製造方法を提供することである。
[0009] The object of the present invention is based on the situation described above,
An object of the present invention is to provide a method for producing an organic fertilizer for easily and at low cost making fertilizer into shellfish such as mussels densely growing in seawater intake channels of various plants such as power plants.

【0010】[0010]

【課題を解決するための手段】上記目的を達成するため
に、本発明の復水器冷却水路等の付着貝類の有機肥料製
造方法は、火力または原子力発電所の復水器冷却水路等
のプラント取水路に付着する貝類から有機肥料を製造す
る方法において、前記プラント取水路から採取されるム
ラサキイガイなどの貝類およびその他の藻類を、前記プ
ラント取水路のある現地で貝殻と貝肉とに選別し、選別
後、粉砕し、これらの貝殻粉および貝肉およびその他の
藻類を混ぜ合わせ、発酵させて有機肥料を製造すること
を特徴とするものである。そのため、現地で貝類を粉砕
し、さらに選別・脱水処理まで行うと、採取した貝類の
運搬量が、当初の採取量の10分の1以下に激減し、コ
ストの低下が著しい。しかも採取した貝類は有機物が豊
富であり、発酵させて有機肥料として有効利用できる。
In order to achieve the above object, the present invention relates to a method for producing organic fertilizer for attached shellfish such as a condenser cooling water channel, which comprises a method of manufacturing a condenser cooling water channel of a thermal or nuclear power plant. In a method of producing organic fertilizer from shellfish attached to an intake channel, shellfish and other algae such as mussels collected from the plant intake channel, are sorted into shells and shell meat at the site where the plant intake channel is located, After sorting, the mixture is ground, and the shell powder, shell meat and other algae are mixed and fermented to produce an organic fertilizer. For this reason, if shellfish is crushed on site, and further sorting and dewatering processes are performed, the transported amount of the collected shellfish is drastically reduced to one-tenth or less of the originally collected amount, and the cost is remarkably reduced. Moreover, the collected shellfish are rich in organic matter, and can be fermented and effectively used as an organic fertilizer.

【0011】以下、具体的な手段を述べると、本発明
は、火力発電所および原子力発電所の復水器冷却水路な
どに付着するムラサキイガイを主とする貝殻と貝肉を利
用して、下記に示す機器の組み合わせと工程で、有機肥
料を製造する方法である。 (a)貝殻選別機による貝殻とその他のものの選別工程 貝類を水洗と振動作用あるいは回転作用による貝殻選別
機によりフルイにかけ、フルイ上部に貝殻、フルイ下部
に貝肉・水洗排水とを選別する。貝類を粉砕すると大量
の水分が発生すると共に、貝肉も粉砕され排水中に溶け
込み排水水質の悪化を来す。そこで、予め貝殻と貝肉に
分離することにより、それぞれ有機肥料原料とすること
ができる。なお、貝殻選別機への貝類導入方式は、振動
式ではバックホン、回転式では真空吸引とする。
In the following, specific means are described. The present invention utilizes the shells and shell meats of mussels mainly attached to condenser cooling water channels of thermal power plants and nuclear power plants, as follows. It is a method of producing organic fertilizer by the combination of equipment and process shown. (A) Step of Sorting Shells and Others Using a Shell Sorting Machine Shells are washed with water and sieved with a shell sorting machine by vibrating or rotating action to sort shells on the upper part of the sieve and shellfish and washing drainage on the lower part of the sieve. When crushing shellfish, a large amount of water is generated, and the shell meat is also crushed and dissolved in the wastewater, resulting in deterioration of the quality of the wastewater. Then, by separating the shell and the shell meat in advance, each can be used as an organic fertilizer raw material. In addition, as for the method of introducing shellfish into the shell sorter, a backphone is used for the vibration type, and vacuum suction is used for the rotary type.

【0012】(b)遠心分離機による脱水処理工程 選別された貝肉・水洗排水に、例えばカチオン系および
アニオン系の凝集剤を添加して、移動式遠心脱水機にて
脱水処理し、貝肉等の固形分と水に分離して、分離され
た貝肉等の固形分は肥料原料とする。この際、凝集剤の
添加量は極力少量で脱水効果を上げるようにし、脱水後
の貝肉等が粘度状にならないようにする。 (c)貝がら粉砕機による粉砕工程 選別工程で選別された貝殻は、粉砕機により径が5mm
以下まで粉砕し、容積の減少化による移送効率の向上を
図り肥料原料とする。
(B) Dehydration step by centrifuge A cation-type and anion-type flocculant is added to the selected shellfish and washing wastewater, and the shellfish is dehydrated by a mobile centrifugal dehydrator. The solids such as shellfish and the like are separated into water and the separated solids are used as fertilizer raw materials. At this time, the amount of the coagulant added is as small as possible to enhance the dewatering effect, so that the dehydrated shellfish and the like do not become viscous. (C) Crushing process by shell crusher The shells selected in the sorting process have a diameter of 5 mm by the crusher.
Grind to the following, and improve the transfer efficiency by reducing the volume and use it as a fertilizer raw material.

【0013】(d)一次発酵機による発酵処理工程 貝類の発酵処理方法としては、好気性発酵および嫌気性
発酵に大別されるが、共に発酵菌に発酵処理装置との適
切な組み合わせを要する中にあって、大量に発生する貝
類を余すところなく採取し、効率よく処理するために
は、大規模な処理装置を要する。そこで、市場性ニーズ
に合致し安価な処理方法として、好気性発酵に基ずき、
粉砕した貝殻および脱水処理した貝肉等の発酵を促進す
るために、鶏糞、コーヒ豆かす、有機汚泥等の有機肥料
原料とともに、加圧しながら混合し10分程度の滞留時
間で50〜60℃まで昇温する一次発酵処理を行う。
(D) Fermentation process using a primary fermenter Fermentation methods for shellfish are roughly classified into aerobic fermentation and anaerobic fermentation. Therefore, a large-scale processing device is required to collect and treat the shellfishes generated in large quantities without exhaustion. Therefore, as an inexpensive treatment method that meets market needs, based on aerobic fermentation,
In order to promote fermentation of crushed shells and dehydrated shell meat, etc., it is mixed with organic fertilizer raw materials such as chicken manure, coffee grounds, and organic sludge while applying pressure to a temperature of 50 to 60 ° C. with a residence time of about 10 minutes. A primary fermentation process is performed to raise the temperature.

【0014】(e)室内での二次発酵処理工程 一次発酵させたものを室内に山積みにし、下部から空気
をフロアーで吹き込みながら二次発酵させる。このと
き、山積みにしたものを適時切り返しを行うことによ
り、さらに発酵を促進させ短時間で有機肥料を製造す
る。本発明は、鶏糞等の有機肥料原料を発酵菌を兼ねて
使用するので、中種添加の必要がないため、処理コスト
が低減できる。
(E) Secondary fermentation treatment step in the room The primary fermentation is piled up in the room, and the secondary fermentation is performed while blowing air from below on the floor. At this time, the piled material is appropriately turned back to further promote fermentation and produce the organic fertilizer in a short time. Since the present invention uses an organic fertilizer raw material such as chicken dung also as a fermentation bacterium, there is no need to add a sponge so that the processing cost can be reduced.

【0015】[0015]

【発明の実施の形態】以下、本発明の実施の形態を、図
面を参照して詳細に説明する。図1は、本発明の有機肥
料製造方法の一実施形態を示す工程図である。 (A)取水路の貝類除去作業 まず、バキューム車を取水路のある現地に運行し、取水
路に密生するムラサキイガイ等の貝類や、藻類あるいは
汚泥などを吸引する。
Embodiments of the present invention will be described below in detail with reference to the drawings. FIG. 1 is a process chart showing one embodiment of the method for producing an organic fertilizer of the present invention. (A) Shellfish removal work in the intake channel First, a vacuum truck is operated to the site where the intake channel is located, and the shellfish such as mussels and algae or sludge which are densely grown in the intake channel are sucked.

【0016】(B)貝殻とその他のものの選別工程 現地において、バキューム車に連結した貝殻選別機によ
って、吸引して破砕された貝類や藻類あるいは汚泥など
を、貝殻と、貝肉や藻類あるいは汚泥などとに選別す
る。選別は以下の方式を適宜採用する。 (a)振動式選別 取水路から吸い上げた貝類その他のものを、バックホン
等により貝殻選別機に投入する。貝殻選別機では、水に
よりシャワーリングしながら水洗すると同時に、振動作
用によるフルイ(目開き約7mm)にかけ、フルイ上部
に貝殻を選別し、フルイ下部に貝殻から外れた貝肉や藻
類その他のもの、および水洗排水とに選別する。 (b)回転式選別 取水路から貝類その他のものをバキュームカーにより吸
引し、貝殻選別機に投入する。貝殻選別機では、水をシ
ャワーリングしながら水洗すると同時に、回転作用によ
るフルイ(目開き約7mm)にかけ、フルイ上部に貝殻
を選別し、フルイ下部に貝殻から外れたもの、すなわ
ち、貝肉・藻類・汚泥等(以下、貝肉類等という)およ
び水洗排水を選別する。フルイ上部に選別された貝殻
は、回転式かき寄せ機で排出され、貝肉類等および水洗
排水は、次のバキュームカーに吸引される。
(B) Step of sorting shells and other materials On the spot, shells, algae or sludge sucked and crushed by a shell sorting machine connected to a vacuum truck are used to remove shells, shell meat, algae or sludge. And to sort. The following method is appropriately adopted for the selection. (A) Vibratory sorting The shellfish and other things sucked up from the intake channel are put into a shell sorter using a backphone or the like. In the shell sorter, it is washed while showering with water, and at the same time, it is sieved by a vibrating action (opening about 7 mm), and the shell is sorted on the upper part of the screen. And washing and drainage. (B) Rotary sorter Shellfish and other things are sucked from the intake channel by a vacuum car and put into a shell sorter. In the shell sorter, the water is washed while showering water, and at the same time, it is sieved by a rotating action (opening about 7 mm), the shell is sorted on the upper part of the screen, and the shells are separated from the shell below the screen, that is, shell meat and algae.・ Sludge etc. (hereinafter referred to as shellfish etc.) and washing wastewater are sorted out. The shells selected at the upper part of the screen are discharged by a rotary scraper, and the shell meat and the washing water are sucked into the next vacuum car.

【0017】(C)遠心分離機による脱水処理工程 脱水処理工程に用いる遠心分離機車は、駆動部・薬液部
・給泥部・脱水部・排水部からなる移動式である。この
遠心分離機車を取水路のある現地に運行する。選別機で
選別された貝殻以外の貝肉類等および水洗排水は、吸引
ポンプで吸引され、あらかじめ溶解した凝集剤をライン
ミキサー(混合撹拌機)内に添加して、貝肉類・洗浄排
水内の固形分を大きな粒子に凝集し、バスケット型遠心
分離機に導入し、高速回転による遠心作用を受け、貝肉
類等の固形分はバスケットの壁面に蓄積する。この間、
分離された水分はバスケットの上部からオーバーフロー
し、やがて排水ポンプで系外に排出される。バスケット
内の固形分は、一定量となると回転は下がり、かき寄せ
機で下部にかき落とされて、ベルトコンベアで系外に排
出され、肥料原料となる。この際、脱水効果を高めるた
め凝集沈殿剤を添加するが、その添加量は極力少くし、
脱水処理されたものが粘土状にならないようにすること
が望ましい。
(C) Dehydration process by centrifugal separator The centrifuge vehicle used in the dehydration process is a mobile type including a drive unit, a chemical solution unit, a mud supply unit, a dehydration unit, and a drainage unit. The centrifuge vehicle will be operated on site with a water channel. The shell meat other than the shells and the washing wastewater sorted by the sorter are sucked by the suction pump, and the coagulant dissolved in advance is added to the line mixer (mixing stirrer), and the solid matter in the shellfish and washing wastewater is added. The solids are aggregated into large particles, introduced into a basket-type centrifuge, and subjected to centrifugal action by high-speed rotation, so that solids such as shellfish accumulate on the wall surface of the basket. During this time,
The separated water overflows from the upper part of the basket, and is eventually discharged out of the system by the drainage pump. When the solid content in the basket reaches a certain amount, the rotation decreases, and the solid content is scraped down by a scraper, discharged out of the system by a belt conveyor, and becomes a fertilizer raw material. At this time, a coagulating sedimentation agent is added to enhance the dehydration effect, but the amount of addition is minimized,
It is desirable that the dehydrated material does not become clay-like.

【0018】(D)貝殻粉砕機による粉砕工程 選別された貝殻は、ホッパー・スクリュウコンベア・粉
砕機・ベルトコンベアからなる粉砕機により、約5mm
以下まで粉砕し、容積の減少による輸送効率の効率化を
図ると共に肥料原料とする。粉砕部は、ホッパーから供
給された貝殻を、穴径10mmからなる鋼性ダイスと、
間隙3〜5mmの羽根カッター間に供給し、貝殻を約5
mm以下まで粉砕し、ダイス穴からベルトコンベアを経
て系外に排出し肥料原料とする。
(D) Pulverizing step by shell crusher The selected shells are crushed by a crusher comprising a hopper, a screw conveyor, a crusher and a belt conveyor to a size of about 5 mm.
Pulverize to the following to improve the transport efficiency by reducing the volume and use it as a fertilizer raw material. The pulverizing unit converts the shell supplied from the hopper into a steel die having a hole diameter of 10 mm,
Feed between blade cutters with a gap of 3 to 5 mm,
mm or less and discharged out of the system via a belt conveyor from the die hole to obtain a fertilizer raw material.

【0019】(E)一次発酵機による発酵処理工程 粉砕した貝殻および脱水処理した貝肉類等の固形分は、
鶏糞、コーヒー豆かす、有機汚泥等の発酵を促進させる
有機肥料原料とともに一次発酵機に投入する。一次発酵
機は、原料ホッパー・スクリュウコンベア・円筒型加圧
シリンダーからなる。原料ホッパーから供給された肥料
原料は、粉砕貝殻および脱水貝肉類等の容積1に対し、
コーヒー豆かすおよび鶏糞等の有機肥料原料が容積3の
混合比となるように、スクリュウコンベアで加圧シリン
ダーに導入する。加圧シリンダーに導入された各原料
は、2列からなる変形羽根の回転およびシリンダー内に
設置されたゲート間を10分程度で渦状に移動する。こ
の際、高圧力、そして激振動を受けながら混合・移動す
るため、圧縮摩擦熱を受け、ほとんど外気の影響を受け
ずに急激に温度が50〜60℃に上昇し、一次発酵工程
が終了する。この高圧力・激振動を得るためには、出口
ゲートの開度を出口の肥料状態を見ながら調整し、最適
条件を見出すものである。急激な温度上昇を図ることに
より、肥料化に悪影響を及ぼす低温菌・中温菌を死滅さ
せ、高温菌を活性化させるため、二次発酵における高温
菌の発芽を促進することができるものである。
(E) Fermentation step by primary fermenter The solid content of the crushed shell and dehydrated shellfish is as follows:
It is fed into the primary fermenter together with raw materials for organic fertilizer that promote fermentation of chicken manure, coffee grounds, and organic sludge. The primary fermenter consists of a raw material hopper, screw conveyor, and cylindrical pressure cylinder. The fertilizer raw material supplied from the raw material hopper has a volume of 1, such as crushed shells and dehydrated shellfish,
The organic fertilizer raw materials such as coffee grounds and chicken dung are introduced into a pressurized cylinder by a screw conveyor so as to have a mixing ratio of 3 volumes. Each raw material introduced into the pressurized cylinder spirally moves in about 10 minutes between the rotation of the two rows of deformed blades and the gates installed in the cylinder. At this time, the mixture undergoes high pressure and violent vibration while mixing and moving, so it receives compression friction heat, and the temperature rises rapidly to 50 to 60 ° C. almost without being affected by the outside air, ending the primary fermentation step. . In order to obtain this high pressure and severe vibration, the opening degree of the exit gate is adjusted while observing the state of fertilizer at the exit, and optimum conditions are found. By rapidly increasing the temperature, psychrotrophic and mesophilic bacteria that have an adverse effect on fertilization are killed and thermophilic bacteria are activated, so that germination of thermophilic bacteria in secondary fermentation can be promoted.

【0020】(F)室内での二次発酵処理工程 一次発酵させたものを室内に山積みにし、下部から空気
をブロアーで吹き込むことにより、好気性発酵が促進し
二次発酵させる。この二次発酵においては、一次発酵で
50〜60℃まで温度が上がったものが、移動に際し大
気に触れ、一時的に温度が下がるものの、室内で山積み
にすることにより、高温菌の働きで徐々に温度が上昇
し、発酵とともに水分の除去も進む。この際、適時切り
返しを行うことにより、発酵は促進され、短期間で有機
肥料を製造することができる。
(F) Secondary fermentation treatment step in the room The primary fermentation is piled up in the room, and air is blown from the lower part with a blower to promote aerobic fermentation and secondary fermentation. In this secondary fermentation, the temperature of the primary fermentation, which has risen to 50-60 ° C, comes into contact with the atmosphere when moving, and the temperature temporarily decreases. The temperature rises and the removal of water proceeds with fermentation. In this case, the fermentation is promoted by appropriately turning over, and an organic fertilizer can be produced in a short period of time.

【0021】(G)ペレット化工程 二次発酵の終了した有機肥料を、ある一定の粒度に揃え
るためにペレット化を行い、施肥作業の簡素化に役立て
る。
(G) Pelletizing step The organic fertilizer after the secondary fermentation is pelletized in order to make it a certain particle size, which is useful for simplifying the fertilizing operation.

【0022】〈本実施形態での肥料評価〉 a.有機肥料成分 本実施形態における有機肥料の成分を表1に示す。な
お、有機肥料成分は貝殻・貝肉類等・発酵促進用の一般
有機肥料原料などの混合割合によって、任意に調整でき
るので、下記成分に制約されるものではない。また、表
2は、吸引採取したムラサキイガイを主とする貝類(貝
殻と貝肉)の成分分析表である。吸引作業により、海草
などの藻類や泥砂などの混入状態により異なるが、カル
シウム分が豊富に含まれている。
<Evaluation of fertilizer in this embodiment> a. Organic fertilizer components Table 1 shows the components of the organic fertilizer in the present embodiment. The organic fertilizer component can be arbitrarily adjusted according to the mixing ratio of shells, shellfish and the like, and general organic fertilizer raw materials for promoting fermentation, and is not limited to the following components. Table 2 is a component analysis table of shellfishes (shells and shell meat) mainly containing mussels collected by suction. Depending on the state of algae such as seaweed and mud and sand mixed by suction work, calcium content is abundant.

【0023】[0023]

【表1】 [Table 1]

【0024】[0024]

【表2】 [Table 2]

【0025】b.幼植物試験 本実施形態における有機肥料の施肥によって、小松菜の
発芽および発芽後の生育への支障の有無、およびその程
度を調査するため、幼植物試験を実施した。その結果、
発芽は3日後に開始し、発芽後の生育も順調に推移し、
試験生育期間中、有害物質と考えられる異常生育は認め
られなかった。
B. Young plant test A young plant test was carried out to investigate whether or not the fertilization of the organic fertilizer in the present embodiment impedes germination of Komatsuna and growth after germination, and the degree thereof. as a result,
Germination starts after 3 days, growth after germination is also going well,
During the test growth period, no abnormal growth considered to be a harmful substance was observed.

【0026】本実施形態による有機肥料製造方法は、低
廉な処理コストと広い用途とを持っている。すなわち、
従来の技術のように大規模で高価な設備を使用するので
はなく、既に使用されている貝殻選別機、廃棄物処理業
者が有している移動式遠心分離機、低廉な一次発酵機、
および廃棄物処理業者が有しているペレット化装置の組
み合わせにより、処理期間は1ユニット1回あたり30
日間程度の短期間で低廉な有機肥料の製造ができる。ま
た、各工程毎の機器の設置個所は、特定な場所に限定す
る必要はなく、処理コストが最も低廉な場所を任意に選
択できる方法である。
The method for producing an organic fertilizer according to the present embodiment has low processing cost and wide application. That is,
Rather than using large-scale and expensive equipment as in the prior art, shell sorters already used, mobile centrifuges owned by waste disposal companies, inexpensive primary fermenters,
Depending on the combination of the pelletizer and the waste treatment company, the treatment period is 30 units per unit.
Inexpensive organic fertilizer can be manufactured in a short period of time, such as about a day. Further, it is not necessary to limit the installation place of the equipment for each process to a specific place, and it is a method that can arbitrarily select a place where the processing cost is the lowest.

【0027】さらに、特殊な発酵菌による貝類の発酵処
理では、発酵菌の中種として米糠等の栄養剤を約50%
程度添加して処理する必要があり、処理コスト増の一因
となっているが、本実施形態では鶏糞等の有機肥料原料
を発酵菌を兼ねて使用するので、中種添加の必要がない
ため、処理コストを大幅に低減できる。これらのことか
ら、本実施形態による処理コストの試算結果では、某電
力会社の火力発電所で試算されたものと比較して、10
分の1程度まで低減できるものである。また、貝類単独
の肥料では、土壌改良剤等の用途にかぎられることが懸
念されるため、鶏糞・コーヒー豆かす等と混合すること
によって、有機肥料として使用範囲が広くなり、商業ベ
ースに乗せることができる。
Further, in the fermentation treatment of shellfish by a special fermenting bacterium, a nutrient such as rice bran is added as a middle species of the fermenting bacterium by about 50%.
Although it is necessary to add and treat to a certain extent, this is one of the causes of an increase in the processing cost.However, in the present embodiment, since an organic fertilizer material such as chicken dung is used also as a fermentation bacterium, it is not necessary to add a medium seed In addition, processing costs can be significantly reduced. From these facts, the results of the trial calculation of the processing cost according to the present embodiment show that, compared with the trial calculation at the thermal power plant of a certain power company,
This can be reduced to about one-half. In addition, it is feared that shellfish alone fertilizers are limited to applications such as soil conditioners, so by mixing with chicken dung, coffee beans grounds, etc., the range of use as organic fertilizers can be widened and put on commercial base Can be.

【0028】次に、本実施形態の特徴の一つである現地
処理用の車両について、その一例を説明する。図2は、
貝殻選別を自動的に行う装置を搭載した車両の側面図で
ある。この車両には、タンク1、ロータリースクリーン
2、排出2段ダンパ3、連結・ドレンバルブ4、吸引バ
ルブ5、連結バルブ6、制御盤7、操作盤8などを備え
ている。この車両をバキューム車と共に、貝類を採取す
る取水路のある現地に運行する。
Next, an example of a vehicle for on-site processing, which is one of the features of the present embodiment, will be described. FIG.
It is a side view of the vehicle carrying the device which performs shell sorting automatically. This vehicle includes a tank 1, a rotary screen 2, a discharge two-stage damper 3, a connection / drain valve 4, a suction valve 5, a connection valve 6, a control panel 7, an operation panel 8, and the like. This vehicle will be transported along with the vacuum truck to a site where there is an intake channel for collecting shellfish.

【0029】図において、吸引バルブ5にバキューム車
(不示図)を連結する。バキューム車で吸引採取された
貝類や藻類および汚泥などは、強力な強制的吸引作用に
より破砕され、吸引バルブ5からタンク1のロータリー
スクリーン2内に入る。ここで、貝殻と貝肉類や泥水と
に分離され、貝殻は回転中に洗浄され、排出2段ダンパ
3を通過して排出口から排出される。貝殻から分離され
た貝肉類や泥水は、ロータリースクリーン2から落ち、
連結・ドレンバルブ4に連結した吸引車へと吸引され
る。このように、取水路のある現地で、あらかじめ効率
的に作業を実施し、次の運搬工程の省力化を図ることが
できる。
In the figure, a vacuum wheel (not shown) is connected to the suction valve 5. Shellfish, algae, sludge, etc. sucked and collected by the vacuum truck are crushed by a strong forced suction action and enter the rotary screen 2 of the tank 1 from the suction valve 5. Here, the shells are separated into shellfish and muddy water, and the shells are washed while rotating, pass through the discharge two-stage damper 3, and are discharged from the discharge port. Shell meat and muddy water separated from the shell fall off the rotary screen 2,
It is sucked into the suction wheel connected to the connection / drain valve 4. In this way, work can be efficiently carried out in advance at the site where the intake channel is located, and labor saving in the next transportation process can be achieved.

【0030】上述のとおり、上記実施形態によれば、従
来技術のように莫大な装置価格、非常に高いランニング
コスト、および商業ベースに乗らない等の欠点を解決し
た有機肥料製造方法であり、具体的効果を次に示す。 a.低廉な装置 本実施形態の有機肥料製造方法に供される装置は、市販
されているもののなかでも低廉なコストのものである。 b.低廉な発酵方法 従来の技術では、特殊な発酵菌を使用するため、特殊発
酵菌の技術開発費や栄養剤として米糠等の中種を添加す
る必要があるため、発酵処理費が高くなる。これに対し
て、本実施形態における発酵菌は、一般の有機肥料原料
(鶏糞やコーヒー豆かす等)を使用するため低廉なコス
トになる。
As described above, according to the above-described embodiment, there is provided a method for producing an organic fertilizer which has solved the drawbacks such as the huge equipment cost, extremely high running cost, and the lack of commercial use as in the prior art. The effects are shown below. a. Inexpensive Apparatus The apparatus provided for the method for producing an organic fertilizer of the present embodiment has a low cost among commercially available ones. b. Inexpensive fermentation method In the conventional technology, special fermentation bacteria are used, and therefore, it is necessary to add technical seeds for the special fermentation bacteria and to add medium seeds such as rice bran as a nutrient, so that the fermentation treatment cost increases. On the other hand, the fermentation bacterium in the present embodiment uses a general organic fertilizer raw material (chicken dung, coffee grounds, and the like), so that the cost is low.

【0031】c.任意な処理場所 従来の技術では、大規模な処理装置を発電所構内等に設
置して、専用の運転員によって肥料化を行っている。一
方、本実施形態における貝殻選別機、遠心分離機および
粉砕機は、いずれも可搬式であるため、処理コストの最
も低廉な処理場所を任意に選択できる。 d.低廉な処理コスト 従来技術での肥料化では、他社の火力電力発電所構内の
発酵処理方法の場合、1m3約40万円の処理コストと
されているが、本実施形態における試算では、その10
分の1程度のコストで有機肥料が製造できる。
C. Arbitrary treatment place In the conventional technology, a large-scale treatment device is installed in a power plant premises or the like, and fertilizer is made by a dedicated operator. On the other hand, since the shell sorter, the centrifuge, and the crusher in the present embodiment are all portable types, the processing place with the lowest processing cost can be arbitrarily selected. d. Inexpensive treatment cost In the case of fertilizer using the conventional technology, in the case of a fermentation treatment method at a thermal power plant premises of another company, a treatment cost of about 400,000 yen per m 3 is assumed.
Organic fertilizer can be manufactured at a cost of about one-half.

【0032】e.商業ベース 本実施形態による有機肥料は、市場のニーズに応じた肥
料成分に調整できるとともに、貝殻主成分である炭酸カ
ルシウムによる稲等の倒伏防止効果があり、肥料として
も最適であり、さらに、ペレット化により粒度を揃えた
商品であるため、十分商業ベースに乗せることができ
る。
E. Commercial base The organic fertilizer according to the present embodiment can be adjusted to fertilizer components according to the needs of the market, and has an effect of preventing lodging of rice and the like by calcium carbonate which is a shell main component, and is most suitable as a fertilizer. Since the product has a uniform particle size due to the development, it can be put on a commercial base.

【0033】[0033]

【発明の効果】以上説明したように、本発明の有機肥料
製造方法によれば、発電所等の各種プラントの海水取水
路などに密生するムラサキイガイ等の貝類を、簡易にし
かも低コストで肥料化することがてきる。
As described above, according to the method for producing organic fertilizer of the present invention, shellfish such as mussels that grow densely in seawater intake channels of various plants such as power plants can be easily and inexpensively converted into fertilizer. I can do it.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の有機肥料製造方法の一実施形態を示す
工程図である。
FIG. 1 is a process chart showing one embodiment of a method for producing an organic fertilizer of the present invention.

【図2】本発明における貝殻選別を自動的に行う装置を
搭載した車両の側面図である。
FIG. 2 is a side view of a vehicle equipped with an apparatus for automatically performing shell sorting according to the present invention.

【符号の説明】[Explanation of symbols]

1 タンク 2 ロータリースクリーン 3 排出2段ダンパ 4 連結・ドレンバルブ 5 吸引バルブ 6 連結バルブ 7 制御盤 8 操作盤 DESCRIPTION OF SYMBOLS 1 Tank 2 Rotary screen 3 Discharge 2-stage damper 4 Connection / drain valve 5 Suction valve 6 Connection valve 7 Control panel 8 Operation panel

───────────────────────────────────────────────────── フロントページの続き (72)発明者 佐藤 常夫 新潟県北蒲原郡聖籠町東港一丁目1番地 115号 東北電力株式会社東新潟火力発電 所内 (72)発明者 安藤 天 新潟県北蒲原郡聖籠町東港一丁目1番地 115号 東北電力株式会社東新潟火力発電 所内 (72)発明者 土田 秀夫 新潟県北蒲原郡聖籠町東港一丁目1番地 115号 東北電力株式会社東新潟火力発電 所内 Fターム(参考) 4H061 AA02 CC01 CC04 CC31 CC41 CC51 DD20 EE51 EE61 EE65 EE66 GG13 GG41 GG48 GG49 GG52 GG70  ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Tsuneo Sato 1-11-1 Higashiko, Seirocho, Kitakanbara-gun, Niigata Prefecture Inside the Higashi-Niigata Thermal Power Station, Tohoku Electric Power Co., Inc. 1-Chome 1-1 115 Higashi-Niigata Thermal Power Station Tohoku Electric Power Co., Inc. (72) Inventor Hideo Tsuchida 1-1-1 115 Higashi-ko, Seiro-cho, Kitakanbara-gun, Niigata Prefecture F-term in Higashi-Niigata Thermal Power Station (Reference) 4H061 AA02 CC01 CC04 CC31 CC41 CC51 DD20 EE51 EE61 EE65 EE66 GG13 GG41 GG48 GG49 GG52 GG70

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 火力または原子力発電所の復水器冷却水
路等のプラント取水路に付着する貝類から有機肥料を製
造する方法において、 前記プラント取水路から採取されるムラサキイガイなど
の貝類およびその他の藻類を、前記プラント取水路のあ
る現地で貝殻と貝肉とに選別し、選別後、粉砕し、これ
らの貝殻粉および貝肉およびその他の藻類を混ぜ合わ
せ、発酵させて有機肥料を製造することを特徴とする復
水器冷却水路等の付着貝類の有機肥料製造方法。
1. A method of producing organic fertilizer from shellfish attached to a plant intake channel such as a condenser cooling channel of a thermal or nuclear power plant, wherein shellfish such as mussels and other algae collected from the plant intake channel. Is classified into shells and shell meat at the site where the plant water intake is located, crushed, crushed, mixed with these shell powder and shell meat and other algae, and fermented to produce an organic fertilizer. Characteristic method for producing organic fertilizer for attached shellfish such as condenser cooling water channels.
【請求項2】 火力または原子力発電所の復水器冷却水
路等のプラント取水路に付着する貝類から有機肥料を製
造する方法において、(1)前記取水路から、ムラサキ
イガイなどの貝類およびその他の藻類などを、バキュー
ム装置で吸引し採取する工程と、(2)前記バキューム
装置で吸引採取した貝類などを、振動式バックホンまた
は回転式真空吸引法による貝殻選別機に導入し、水洗と
振動作用あるいは回転作用によりフルイにかけ、フルイ
上部の貝殻と、フルイ下部の貝肉類および水洗排水とに
選別する工程と、(3)前記フルイ下部の貝肉類および
水洗排水に凝集沈殿剤を添加して、脱水処理機により脱
水処理する工程と、(4)前記フルイ上部の貝殻を粉砕
機により粉砕したものと、前記脱水処理した貝肉類と、
発酵促進材とを一次発酵機に投入し、加圧混合して所定
の滞留時間で一次発酵させる工程と、(5)前記一次発
酵させたものに、空気をブロワで吹き込み二次発酵させ
る工程と、からなることを特徴とする復水器冷却水路等
の付着貝類の有機肥料製造方法。
2. A method for producing organic fertilizer from shellfish attached to a plant intake channel such as a condenser cooling channel of a thermal or nuclear power plant, comprising: (1) shellfish such as mussels and other algae from the intake channel; And (2) introducing shellfish etc. sucked and collected by the vacuum device into a vibrating backphone or a shell sorter using a rotary vacuum suction method, and washing with water and vibrating or rotating. (3) adding a coagulating sedimentation agent to the shellfish below the sieve and the washing wastewater, adding a flocculant to the shells above the sieve and the shellfish below the sieve and washing wastewater. (4) crushing the shell above the sieve with a crusher, and the dehydrated shell meat;
A step of introducing the fermentation promoting material into a primary fermenter, mixing under pressure and performing primary fermentation for a predetermined residence time, and (5) a step of blowing air with a blower to the primary fermented to perform secondary fermentation. A method for producing an organic fertilizer of attached shellfish such as a condenser cooling water channel, comprising:
【請求項3】 前記発酵を促進させる材料として、鶏糞
等の有機肥料原料、コーヒーの豆かす、有機汚泥等の有
機物、もしくは好気性発酵菌、等の発酵促進材を加える
ことを特徴とする請求項1または2に記載の有機肥料製
造方法。
3. A fermentation promoting material such as an organic fertilizer material such as chicken dung, an organic matter such as coffee bean cake and organic sludge, or an aerobic fermentation bacterium is added as a material for promoting the fermentation. Item 3. The method for producing an organic fertilizer according to Item 1 or 2.
【請求項4】 前記貝類などと共に採取された泥質分
も、脱水処理して前記藻類などと共に混ぜ合わせること
を特徴とする請求項1、2または3に記載の有機肥料製
造方法。
4. The method for producing an organic fertilizer according to claim 1, wherein the muddy material collected together with the shellfish and the like is dehydrated and mixed with the algae and the like.
【請求項5】 前記取水路からムラサキイガイ等の貝類
などを吸引するバキューム装置と、吸引採取した貝類を
貝殻と貝肉などに選別する貝殻選別機と、貝殻を粉砕す
る粉砕機と、選別した貝肉などを脱水処理する脱水処理
機とを、車両に適宜搭載して取水路のある現地に運行
し、前記吸引・選別・粉砕・脱水の各処理を現地で実施
することを特徴とする請求項1ないし4のうちいずれか
に記載の有機肥料製造方法。
5. A vacuum device for sucking shellfish such as mussels from the intake channel, a shell sorter for sorting shellfish and shellfish, etc., the shellfish collected by suction, a crusher for crushing shells, and a shellfish for sorting shellfish. A dehydration processing machine for dehydrating meat and the like, suitably mounted on a vehicle, operating at a site with an intake channel, and performing each of the suction, sorting, crushing, and dehydrating processes locally. 5. The method for producing an organic fertilizer according to any one of 1 to 4.
JP10249724A 1998-09-03 1998-09-03 Production of organic fertilizer of shellfishes fouled in cooling water channel or the like of condenser Pending JP2000072578A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10249724A JP2000072578A (en) 1998-09-03 1998-09-03 Production of organic fertilizer of shellfishes fouled in cooling water channel or the like of condenser

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10249724A JP2000072578A (en) 1998-09-03 1998-09-03 Production of organic fertilizer of shellfishes fouled in cooling water channel or the like of condenser

Publications (1)

Publication Number Publication Date
JP2000072578A true JP2000072578A (en) 2000-03-07

Family

ID=17197265

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10249724A Pending JP2000072578A (en) 1998-09-03 1998-09-03 Production of organic fertilizer of shellfishes fouled in cooling water channel or the like of condenser

Country Status (1)

Country Link
JP (1) JP2000072578A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010084999A (en) * 2001-07-10 2001-09-07 박성식 The product method of granular calcium fertilizer using shells
JP2002004206A (en) * 2000-06-26 2002-01-09 Tohoku Regional Construction Bureau Sanrik Natl Highway Const Office Moc Pavement method, pavement material producing system and pavement material
WO2018169253A1 (en) * 2017-03-14 2018-09-20 왕영성 Organic slow-acting fertilizer using plantaginis semen husk and manufacturing method therefor

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002004206A (en) * 2000-06-26 2002-01-09 Tohoku Regional Construction Bureau Sanrik Natl Highway Const Office Moc Pavement method, pavement material producing system and pavement material
KR20010084999A (en) * 2001-07-10 2001-09-07 박성식 The product method of granular calcium fertilizer using shells
WO2018169253A1 (en) * 2017-03-14 2018-09-20 왕영성 Organic slow-acting fertilizer using plantaginis semen husk and manufacturing method therefor
JP2020510600A (en) * 2017-03-14 2020-04-09 ワン,ヨンソン Organic slow-release fertilizer using carskin and its production method
US11130716B2 (en) 2017-03-14 2021-09-28 Youngsung WANG Organic slow-acting fertilizer using plantaginis semen husk and manufacturing method therefor
JP7012738B2 (en) 2017-03-14 2022-01-28 ワン,ヨンソン Organic slow-release fertilizer using plantain skin and its manufacturing method

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