JP2000043495A - Manufacture of decorative body - Google Patents

Manufacture of decorative body

Info

Publication number
JP2000043495A
JP2000043495A JP10227576A JP22757698A JP2000043495A JP 2000043495 A JP2000043495 A JP 2000043495A JP 10227576 A JP10227576 A JP 10227576A JP 22757698 A JP22757698 A JP 22757698A JP 2000043495 A JP2000043495 A JP 2000043495A
Authority
JP
Japan
Prior art keywords
masking layer
layer
pattern
base
sand
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10227576A
Other languages
Japanese (ja)
Inventor
Hidetoshi Kodama
英俊 小玉
Tsuruo Nakayama
鶴雄 中山
Masaki Shigemori
正樹 重盛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pentel Co Ltd
Original Assignee
Pentel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pentel Co Ltd filed Critical Pentel Co Ltd
Priority to JP10227576A priority Critical patent/JP2000043495A/en
Publication of JP2000043495A publication Critical patent/JP2000043495A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To form a pattern through roughing a surface regardless of the shape of a base by partially removing a masking layer using a laser and applying a surface roughing process to the surface of the base after the removal of the masking layer and further removing the remaining masking layer. SOLUTION: A coating obtained by diluting a mixture of an acrylic adhesive 1022 and carbon black with a mixed solvent of toluene and MEK is sprayed on a glass sphere with about 20 mm dia. to form a peelable adhesive layer 2. Next an elastic urethane coating GM-808C loaded with a specified curing agent and a thinner is sprayed to form a masking layer 4. Further, the masking layer 4 on the entire face of a base 1 is removed in a patternlike fashion using a YAG laser marking device and then the base 1 is sand-blasted. In this case, the sand-blasting process uses about 2-3 kg/cm2 air pressure and about 50 mesh sand. This process is applied to the entire periphery of the glass sphere for about 120 sec. while the glass sphere is rotated. After that, the masking layer 4 is peeled following the knack of peeling a pressure-sensitive adhesive tape.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、プラスチックス、
ガラス等のセラミックス、アルマイト皮膜、金属または
木材などの基材を、部分的に粗面化することによりパタ
−ンを形成した装飾体の製造方法に関するものである。
The present invention relates to plastics,
The present invention relates to a method for manufacturing a decorative body in which a pattern is formed by partially roughening a base material such as a ceramic such as glass, an alumite film, a metal or wood.

【0002】[0002]

【従来の技術】従来、基材上に粗面化したパタ−ンを形
成するには、粗面化する部分以外をマスキングし、基材
が露出した部分を粗面化処理し、その後マスキングを取
り除くことにより行っていた。マスキング層の形成に
は、基材上にマスキング用のペ−ストを筆などによりパ
タ−ン状に塗布する方法、粘着テ−プを張り付けてカッ
タ−等でパタ−ン状にテ−プを取り除く方法、スクリ−
ン印刷などの印刷によりネガパタ−ンを形成する方法、
感光性樹脂を塗布し部分的に樹脂を硬化させ、非硬化部
分を除去する方法、紙まはた金属などのマスクを密着さ
せる方法などが用いられていた。またマスキング層は、
形状に限定されることなく基材に形成でき、粗面化処理
中に摩耗や剥離がなく、さらに基材形状に限定されない
で微細パタ−ンが形成でき、パタ−ン形成後に簡単に剥
離できる特性が必要であり、これらを全て満足する材料
および形成方法がないのが現状であった。
2. Description of the Related Art Conventionally, in order to form a roughened pattern on a substrate, a portion other than the surface to be roughened is masked, a portion where the substrate is exposed is roughened, and then the masking is performed. I was going by removing it. The masking layer is formed by applying a masking paste on the base material in a pattern with a brush or the like, or by sticking an adhesive tape and forming the pattern in a pattern with a cutter or the like. How to remove, screen
A method for forming a negative pattern by printing such as
A method of applying a photosensitive resin and partially curing the resin to remove an uncured portion, a method of closely attaching a mask such as paper or metal, and the like have been used. The masking layer is
It can be formed on a substrate without being limited to a shape, does not wear or peel off during the surface roughening treatment, and can form a fine pattern without being limited to the shape of the substrate, and can be easily peeled off after pattern formation. At present, properties are required, and there is no material and a forming method that satisfy all of these properties.

【0003】具体的な先行技術としては、特開昭54−
152294号公報および特公昭57−12665号公
報が上げられるが、これらは、弾性を有するマスキング
インキを用いて基材上に直接印刷し、非印刷部をブラス
トにより処理し、その後マスキング層を剥離する方法で
あるが、これらに用いられている弾性を有するマスキン
グインキは、一部のプラスチックスを除き基材との密着
性が十分得られなく、ブラスト中にマスキングのエッジ
部分が剥離したり、マスキング部分の面積が小さいとマ
スキング自体が簡単に剥離してしまい、パタ−ン形成が
できないことが確認された。また、マスキング層の形成
は、印刷法を使用しているため平板状または円筒状など
の印刷可能な形状に限定され、パタ−ン精度も数百μm
程度に限定されていた。さらに、特公昭57−1266
5号公報のマスキング層の剥離は、専用の水洗装置が必
要となりその後の廃液処理が必要となる。また特開昭5
4−152294号公報のマスキング層は、サンドブラ
ストの耐性が数秒しかなく、深く彫刻することが不可能
であるため、マスキング層のサンドブラスト耐性を向上
させるべく、マスキング層上に微細樹脂粉末をふりかけ
付着させているが、微細粉末がパタ−ンエッジ部に付着
し、特に、微細パタ−ンを形成する場合、パタ−ンがつ
ぶれたり、線が細くなったり、ラインの鮮明さがなくな
る等の不具合を有していた。
A specific prior art is disclosed in
No. 152294 and Japanese Patent Publication No. 57-12665, which are directly printed on a base material using an elastic masking ink, the non-printed portion is treated by blasting, and then the masking layer is peeled off. However, the elastic masking inks used in these methods, except for some plastics, do not provide sufficient adhesiveness to the base material, and the edge of the masking peels off during blasting or masking. It was confirmed that when the area of the portion was small, the masking itself was easily peeled off, so that the pattern could not be formed. Further, since the masking layer is formed by a printing method, the masking layer is limited to a printable shape such as a flat plate or a cylinder, and the pattern accuracy is several hundred μm.
Was limited to a degree. Furthermore, Japanese Patent Publication No. 57-1266
The peeling of the masking layer disclosed in JP-A No. 5 (1993) -205 requires a dedicated rinsing device and subsequent waste liquid treatment. See also
The masking layer disclosed in Japanese Patent Application Laid-Open No. 4-152294 has a sandblast resistance of only a few seconds, and cannot be deeply engraved. However, when the fine powder adheres to the pattern edge portion, and particularly when a fine pattern is formed, there is a problem that the pattern is crushed, the line becomes thin, and the line becomes unclear. Was.

【0004】[0004]

【発明が解決しようとする課題】以上のように、粗面化
パタ−ン形成用のマスキング層は、耐衝撃摩耗性を有
し、さらに、粗面化処理中は基材に強固に接着している
が、該処理後は簡単に剥離できる特性が必要であるが、
この特性を満足するマスキング材料がないことが問題点
であった。さらに、球状物や凹部を有する基材に粗面化
によるパタ−ン形成を行わんとした場合、マスキング層
が従来技術では形成できないという問題点があった。
As described above, the masking layer for forming a roughened pattern has impact wear resistance, and furthermore, adheres firmly to the substrate during the roughening treatment. However, it is necessary to have a property that can be easily peeled after the treatment.
The problem is that there is no masking material satisfying this property. Further, when a pattern is formed on a substrate having a spherical body or a concave portion by roughening, there is a problem that a masking layer cannot be formed by the conventional technique.

【0005】[0005]

【課題を解決するための手段】本発明は、上記問題点を
解決するため鋭意研究を重ねた結果、得られたもので、
基材上に密着する接着層とブラストの衝撃を吸収し、か
つ、摩耗しにくい弾性を有する樹脂層を積層することに
より、従来満足し得なかった特性を有するマスキング層
が得られることを見い出し、さらに、レ−ザ−によりマ
スキング層を除去しパタ−ニングを行うことにより、基
材形状に限定されることなく、粗面化処理によるパタ−
ン形成ができることを見い出し本発明を完成したもので
あり、基材上に、剥離性を有する接着層と弾性を有する
樹脂層を順次形成してマスキング層となし、該マスキン
グ層をレ−ザ−により部分的に除去し、次いで、マスキ
ング層を除去した基材表面を粗面化処理した後、残りの
マスキング層を除去した装飾体の製造方法を要旨とする
ものである。
Means for Solving the Problems The present invention has been obtained as a result of intensive studies to solve the above problems.
By absorbing the impact of the blast and the adhesive layer that adheres to the base material, and by laminating a resin layer having elasticity that is hard to wear, it has been found that a masking layer having characteristics that could not be satisfied conventionally can be obtained, Further, by removing the masking layer with a laser and performing patterning, the patterning by the surface roughening treatment is not limited to the substrate shape.
The present invention has been completed, and a masking layer is formed by sequentially forming a peelable adhesive layer and an elastic resin layer on a base material, and forming the masking layer with a laser. The present invention provides a method for manufacturing a decorative body in which a base material surface from which a masking layer has been removed is roughened, and then the remaining masking layer is removed.

【0006】以下図面に基づき本発明を詳細に説明す
る。参照符号1は、基材であり、該基材1の材質は、特
に限定されず、プラスチックス、ガラス等のセラミック
ス、アルマイト皮膜、金属または木材など通常装飾体の
製造に使用されている公知の材料が使用される。また、
基材上に塗装法や印刷法で樹脂層を形成したもの、めっ
き法や物理蒸着法により金属またはその化合物を形成し
たもの、溶射法などによりセラミックス皮膜を形成した
ものを用いてもよい。
Hereinafter, the present invention will be described in detail with reference to the drawings. Reference numeral 1 denotes a base material, and the material of the base material 1 is not particularly limited, and is a known material usually used for manufacturing a decorative body such as ceramics such as plastics and glass, an alumite film, metal or wood. Materials are used. Also,
A material in which a resin layer is formed on a base material by a coating method or a printing method, a material in which a metal or a compound thereof is formed by a plating method or a physical vapor deposition method, or a material in which a ceramic film is formed by a thermal spraying method or the like may be used.

【0007】参照符号2は剥離性を有する接着剤層、参
照符号3は弾性を有する樹脂層であり、この接着剤層2
と弾性を有する樹脂層3とによってマスキング層4を構
成している。接着剤層2は、マスキング層4を最後に除
去するため、剥離性を有するものを用いるが、具体的に
は、ゴム系、アクリル系、ポリイソブチレン系、シリコ
−ン系、ポリウレタン系、ポリエステル系、ポリビニル
エ−テル系などの粘着性を有する樹脂材料を含むものが
挙げられる。粘着力としては、室温において100〜
4,000g/25mm範囲が好ましい。その理由は、
粘着力が100g/25mm未満だと基材に対する接着
強さが弱いため剥離しやすく、また、4,000g/2
5mmを超えると基材に対する接着強さが強すぎ剥離で
きないことがあるからである。
Reference numeral 2 denotes an adhesive layer having releasability, and reference numeral 3 denotes a resin layer having elasticity.
The masking layer 4 is composed of the resin layer 3 having elasticity. As the adhesive layer 2, a material having releasability is used to remove the masking layer 4 last. Specifically, a rubber-based, acrylic, polyisobutylene-based, silicone-based, polyurethane-based, or polyester-based adhesive layer is used. And a resin containing an adhesive resin material such as polyvinyl ether. The adhesive strength is 100 ~ at room temperature.
A range of 4,000 g / 25 mm is preferred. The reason is,
When the adhesive strength is less than 100 g / 25 mm, the adhesive strength to the substrate is weak, so that the adhesive is easily peeled off.
This is because if it exceeds 5 mm, the adhesive strength to the substrate may be too strong to be peeled off.

【0008】弾性を有する樹脂層3は、粗面化処理され
ることから、耐衝撃摩耗や耐薬品性を有する材料を用い
る必要があ、また、マスキング層4を除去するときに接
着層を剥ぎ取るための基材となることから、接着層との
接着力が大きく、かつ、引き裂き強度が大きい必要があ
る。特に、層の形成のし易さ、衝撃吸収性、取り扱い性
を考慮するとポリウレタン系の材料が好ましい。マスキ
ング層4を形成する前記剥離性を有する接着剤層2並び
に弾性を有する樹脂層3を形成する材料は、特に、基材
1の形状が複雑であったり、球状であるような場合、性
状は溶剤に溶解しているものや粉体状のものが好まし
く、また、形成方法は塗装法が好ましい。その理由は、
形状を選ばず均一に形成できるからである。さらに、後
述するレ−ザ−による除去性を向上させるため、カ−ボ
ンブラック等の黒色顔料を含む材料を用いることが好ま
しい。これは、レ−ザ−の吸収効率が向上することと、
顔料を含むことによりマスキング層の強度の向上が期待
できるからである。
Since the resin layer 3 having elasticity is subjected to a surface roughening treatment, it is necessary to use a material having impact resistance and chemical resistance, and when removing the masking layer 4, the adhesive layer is peeled off. Since it becomes a base material to be removed, it is necessary that the adhesive strength to the adhesive layer is large and the tear strength is large. In particular, a polyurethane-based material is preferable in consideration of ease of forming a layer, shock absorption, and handling. The material for forming the adhesive layer 2 having releasability and the resin layer 3 having elasticity for forming the masking layer 4 has properties particularly when the shape of the substrate 1 is complicated or spherical. A substance dissolved in a solvent or a powdery substance is preferable, and a forming method is preferably a coating method. The reason is,
This is because they can be formed uniformly regardless of the shape. Further, it is preferable to use a material containing a black pigment such as carbon black in order to improve the removability by a laser described later. This means that the absorption efficiency of the laser is improved,
This is because the inclusion of the pigment can improve the strength of the masking layer.

【0009】参照符号5は、レ−ザ−によりマスキング
層4を部分的に除去した部分である。マスキング層4の
除去は、市販のYAGまたは炭酸ガスレ−ザ−装置を用
いて行えばよい。参照符号6は、粗面化処理面である。
粗面化処理は、市販の薬品、装置を用いて行えばよく特
に限定されるものではない。粗面化は、化学的または物
理的エッチング法やブラスト処理により行う。化学的エ
ッチング処理は、素材を溶解する薬品とその他添加剤よ
りなる溶液中に浸漬して行う。基材の材質により処理溶
液を適宜選択して使用する。物理的エッチング処理は、
ガスプラズマ等を用いて基材表面を微細に粗面化する方
法であり、ブラスト処理は、砂やガラスまたは樹脂ビ−
ズを高圧のエア−をキャリア−として基材に吹き付ける
方法である。これらの方法の中で、特に、粗面化処理の
設備とコストの問題から化学的エッチングまたはブラス
ト処理が好ましい。粗面化表面の粗さおよび深さは、処
理液、材質、処理時間などにより適宜処理条件を選択し
調整すればよい。粗面化処理しないマスキング層4は、
粘着テ−プを剥がす要領で簡単に手で剥離することがで
きる。また、接着剤層2が強粘着性を有する場合は、お
湯の中に浸漬することにより簡単に剥離することができ
る。
Reference numeral 5 denotes a portion where the masking layer 4 is partially removed by a laser. The removal of the masking layer 4 may be performed using a commercially available YAG or carbon dioxide gas laser device. Reference numeral 6 denotes a roughened surface.
The surface roughening treatment may be performed using commercially available chemicals and equipment, and is not particularly limited. The roughening is performed by a chemical or physical etching method or a blast treatment. The chemical etching treatment is performed by immersing in a solution containing a chemical for dissolving the material and other additives. A treatment solution is appropriately selected and used depending on the material of the base material. The physical etching process is
This is a method of finely roughening the surface of a substrate using gas plasma or the like, and blasting is performed by sand, glass or resin beads.
In this method, high pressure air is blown onto a substrate as a carrier. Among these methods, chemical etching or blasting is particularly preferable from the viewpoint of equipment for roughening treatment and cost. The roughness and depth of the roughened surface may be adjusted by appropriately selecting processing conditions depending on the processing solution, material, processing time, and the like. The masking layer 4 not subjected to the surface roughening treatment
The adhesive tape can be easily peeled off by hand in the same manner. When the adhesive layer 2 has strong tackiness, it can be easily peeled off by immersing it in hot water.

【0010】[0010]

【作用】本発明の装飾体の製造方法は、プラスチック
ス、ガラス等のセラミックス、アルマイト皮膜、金属ま
たは木材などの基材上に、剥離性を有する接着層と弾性
を有する樹脂層を順次形成したものをマスキング層とし
たので、粗面化処理によりマスキング層が剥離したり、
摩耗することがなく所望のパタ−ンが得られ、さらに、
レ−ザ−によりマスキング層を部分的に除去し、パタ−
ニングを行うため基材形状に限定されることなく精度の
高いパタ−ン形成ができ、そして接着層の粘着力を適切
にすることにより、粗面化処理中はマスキング層が剥離
することなく、粗面化処理後のマスキング層の除去は、
粘着テ−プを剥離するのと同様の要領で剥離することが
できる。
According to the method of manufacturing a decorative body of the present invention, a peelable adhesive layer and an elastic resin layer are sequentially formed on a ceramic such as plastics or glass, an alumite film, or a base material such as metal or wood. Since the thing was a masking layer, the masking layer peeled off due to the surface roughening treatment,
The desired pattern can be obtained without abrasion.
The masking layer is partially removed with a laser, and the pattern is removed.
The patterning can be performed with high accuracy without being limited to the shape of the base material, and by appropriately adjusting the adhesive force of the adhesive layer, the masking layer does not peel off during the surface roughening treatment. Removal of the masking layer after the surface roughening treatment
The adhesive tape can be peeled in the same manner as the tape.

【0011】[0011]

【実施例】次に実施例に基づき本発明を説明する。 〈実施例1〉直径20mmのガラス製の球に、市販のア
クリル系接着剤1022(SKダイン、綜研化学(株)
製)を用いてカ−ボンブラックを混合し、トルエン、M
EKの混合溶剤で希釈しスプレ−塗装で剥離性を有する
接着剤層を形成した。その後、市販の弾性ウレタン塗料
GM−808C(ハニソフトン黒色、ハニ−化成(株)
製)を用いて所定の硬化剤、シンナ−を添加しスプレ−
塗装しマスキング層を形成した。その後、YAGレ−ザ
−マ−キング装置で基材全面をパタ−ン状にマスキング
層を除去し、サンドブラスト処理を行った。サンドブラ
ストは、2〜3kg/cm2のエア−圧、50メッシュ
の砂を用いて、120秒間球を回しながら全周に行っ
た。その後、マスキング層を粘着テ−プを剥離する要領
で剥離した。ガラス球の全面に凹みが深く表面粗さが大
きい彫刻状のパタ−ンが形成できた。
Next, the present invention will be described based on examples. Example 1 A commercially available acrylic adhesive 1022 (SK Dyne, Soken Chemical Co., Ltd.) was placed on a glass sphere having a diameter of 20 mm.
Was mixed with carbon black using toluene, M
After dilution with a mixed solvent of EK, an adhesive layer having releasability was formed by spray coating. Then, a commercially available elastic urethane paint GM-808C (Hanisofton black, Hani Kasei Co., Ltd.)
And a predetermined hardening agent and thinner are added thereto and sprayed.
Painting was performed to form a masking layer. Thereafter, the masking layer was removed in a pattern over the entire surface of the substrate with a YAG laser marking device, and sandblasting was performed. Sand blasting was performed on the entire circumference using an air pressure of 2-3 kg / cm 2 and sand of 50 mesh while rotating the ball for 120 seconds. Thereafter, the masking layer was peeled off in a manner to peel off the adhesive tape. A sculpture-like pattern having a large dent and a large surface roughness was formed on the entire surface of the glass sphere.

【0012】〈実施例2〉直径30mmの樹脂製の凹レ
ンズに、市販のゴム系接着剤RB810(JSR製)を
用いてカ−ボンブラックを混合し、トルエン、MEKの
混合溶剤で希釈しスプレ−塗装で剥離性を有する接着剤
層を形成した。その後、市販の弾性ウレタン塗料SF−
6(ファンタスコ−ト黒色、オリジン電気(株)製)を
用いて所定の硬化剤、シンナ−を添加しスプレ−塗装し
マスキング層を形成した。その後、炭酸ガスレ−ザ−マ
−キング装置で一部分をパタ−ン状にマスキング層を除
去し、サンドブラスト処理を行った。サンドブラスト
は、2〜3kg/cm2のエア−圧、200メッシュの
砂を用いて10秒間行った。その後、マスキング層を粘
着テ−プを剥離する要領で剥離した。樹脂製の凹レンズ
の一部に凹みが浅く表面粗さの小さい彫刻状のパタ−ン
が形成できた。
Example 2 Carbon black was mixed with a resin-made concave lens having a diameter of 30 mm using a commercially available rubber-based adhesive RB810 (manufactured by JSR), diluted with a mixed solvent of toluene and MEK, and sprayed. An adhesive layer having releasability was formed by painting. Then, commercially available elastic urethane paint SF-
6 (Fantascot black, manufactured by Origin Electric Co., Ltd.), a predetermined hardener and a thinner were added and spray-coated to form a masking layer. Thereafter, the masking layer was partially removed in a pattern using a carbon dioxide laser marking device, and sandblasting was performed. Sand blasting was performed for 10 seconds using 200 mesh sand with an air pressure of 2-3 kg / cm 2 . Thereafter, the masking layer was peeled off in a manner to peel off the adhesive tape. An engraved pattern having a shallow dent and a small surface roughness was formed on a part of the resin concave lens.

【0013】〈実施例3〉直径10mm、長さ100m
mの円筒形のアルミ軸をアルマイト処理した。アルマイ
ト処理したアルミ軸に市販のシリコ−ン系接着剤KR1
01−10(シリコ−ンワニス、信越化学工業(株)
製)を用いてカ−ボンブラックを混合し、トルエン、M
EKの混合溶剤で希釈しスプレ−塗装で剥離性を有する
接着剤層を形成した。その後、市販の弾性ウレタン塗料
ラビ(S)(黒色、大橋化学工業(株)製)を用いて所
定の硬化剤、シンナ−を添加しスプレ−塗装しマスキン
グ層を形成した。その後、YAGレ−ザ−マ−キング装
置で基材全面をパタ−ン状にマスキング層を除去し、サ
ンドブラスト処理を行った。サンドブラストは、2〜3
kg/cm2のエア−圧、100メッシュの砂を用い
て、30秒間軸を回しながら全周に行った。その後、軸
をお湯の中に浸漬しマスキング層を剥離した。アルマイ
ト軸の全面に凹みが深く表面粗さががやや大きい彫刻状
のパタ−ンが形成できた。
<Embodiment 3> Diameter 10 mm, length 100 m
The anodized aluminum shaft of m was processed. Commercially available silicone-based adhesive KR1 on anodized aluminum shaft
01-10 (Silicon Varnish, Shin-Etsu Chemical Co., Ltd.)
Was mixed with carbon black using toluene, M
After dilution with a mixed solvent of EK, an adhesive layer having releasability was formed by spray coating. Thereafter, using a commercially available elastic urethane paint Rabi (S) (black, manufactured by Ohashi Chemical Industry Co., Ltd.), a predetermined curing agent and thinner were added and spray-coated to form a masking layer. Thereafter, the masking layer was removed in a pattern over the entire surface of the substrate with a YAG laser marking device, and sandblasting was performed. Sandblasting is 2-3
The test was performed on the entire circumference using an air pressure of kg / cm 2 and sand of 100 mesh while rotating the shaft for 30 seconds. Thereafter, the shaft was immersed in hot water to remove the masking layer. A sculpture pattern was formed on the entire surface of the alumite shaft, which was deeply recessed and had a slightly large surface roughness.

【0014】〈実施例4〉直径10mm、長さ100m
mの円筒形の真鍮軸に市販のポリウレタン系接着剤ニッ
ポラン3222(日本ポリウレタン工業(株)製)を用
いてカ−ボンブラックを混合し、トルエン、MEKの混
合溶剤で希釈しスプレ−塗装で剥離性を有する接着剤層
を形成した。その後、市販の弾性ウレタン塗料V−7
X−8550(黒色、長島ペイント(株)製)を用いて
所定の硬化剤、シンナ−を添加しスプレ−塗装しマスキ
ング層を形成した。その後、炭酸ガスレ−ザ−マ−キン
グ装置で基材全面をパタ−ン状にマスキング層を除去
し、サンドブラスト処理を行った。サンドブラストは、
2〜3kg/cm2のエア−圧、50メッシュの砂を用
いて、60秒間軸を回しながら全周に行った。その後、
軸を水の中に浸漬しマスキング層を剥離した。真鍮軸の
全面に凹みが深く表面粗さが大きい彫刻状のパタ−ンが
形成できた。
<Embodiment 4> Diameter 10 mm, length 100 m
Carbon black is mixed with a commercially available polyurethane adhesive Nipporan 3222 (manufactured by Nippon Polyurethane Industry Co., Ltd.) on a cylindrical brass shaft of m, diluted with a mixed solvent of toluene and MEK, and peeled off by spray coating. An adhesive layer having properties was formed. Then, commercially available elastic urethane paint V-7
Using X-8550 (black, manufactured by Nagashima Paint Co., Ltd.), a predetermined hardener and thinner were added and spray-coated to form a masking layer. Thereafter, the masking layer was removed in a pattern from the entire surface of the base material using a carbon dioxide laser marking device, and sandblasting was performed. Sandblasting
The test was performed on the entire circumference using an air pressure of 2-3 kg / cm 2 and sand of 50 mesh while rotating the shaft for 60 seconds. afterwards,
The shaft was immersed in water to remove the masking layer. A sculpture-like pattern having a large dent and a large surface roughness was formed on the entire surface of the brass shaft.

【0015】〈比較例1〉直径20mmのガラス製の球
に、市販の弾性ウレタン塗料GM−808C(ハニソフ
トン黒色、ハニ−化成(株)製)を用いて所定の硬化
剤、シンナ−を添加しスプレ−塗装しマスキング層を形
成した。その後、YAGレ−ザ−マ−キング装置で基材
全面をパタ−ン状にマスキング層を除去し、サンドブラ
スト処理を行った。サンドブラストは、2〜3kg/c
2のエア−圧、50メッシュの砂を用いて、10秒間
球を回しながら全周に行った。その後、マスキング層を
粘着テ−プを剥離する要領で剥離した。マスキング層が
剥離したり、一部浮いてしまいパタ−ン形成ができなか
った。
Comparative Example 1 A predetermined hardening agent and thinner were added to a glass ball having a diameter of 20 mm using a commercially available elastic urethane paint GM-808C (Hanisofton black, manufactured by Hani Kasei Co., Ltd.). Spray-painted to form a masking layer. Thereafter, the masking layer was removed in a pattern over the entire surface of the substrate with a YAG laser marking device, and sandblasting was performed. Sandblasting is 2-3kg / c
m 2 of air - pressure, with a 50-mesh sand was performed the entire circumference while turning the 10 seconds sphere. Thereafter, the masking layer was peeled off in a manner to peel off the adhesive tape. The masking layer peeled off or partially floated, and the pattern could not be formed.

【0016】〈比較例2〉直径20mmのガラス製の球
に、市販のアクリル系接着剤材1022(SKダイン、
綜研化学(株)製)を用いて、トルエン、MEKの混合
溶剤で希釈しスプレ−塗装で接着剤層(マスキング層)
を形成した。その後、YAGレ−ザ−マ−キング装置で
基材全面をパタ−ン状にマスキング層を除去し、サンド
ブラスト処理を行った。サンドブラストは、2〜3kg
/cm2のエア−圧、50メッシュの砂を用いて、30
秒間球を回しながら全周に行った。その後、マスキング
層を粘着テ−プを剥離する要領で剥離した。接着剤層に
ゴミ等が付着しレ−ザ−でパタ−ニングができない部分
があった。またブラストの砂が接着剤層に付着しパタ−
ンエッジが鮮明にならなかった。
Comparative Example 2 A commercially available acrylic adhesive material 1022 (SK Dyne,
Using Soken Chemical Co., Ltd.), dilute with a mixed solvent of toluene and MEK, and spray-coat the adhesive layer (masking layer).
Was formed. Thereafter, the masking layer was removed in a pattern over the entire surface of the substrate with a YAG laser marking device, and sandblasting was performed. Sandblast is 2-3kg
/ Cm 2 air pressure, 50 mesh sand, 30
It went all round while turning the ball for seconds. Thereafter, the masking layer was peeled off in a manner to peel off the adhesive tape. Dust and the like adhered to the adhesive layer, and there were portions where patterning was impossible with a laser. Also, blast sand adheres to the adhesive layer and
The edge was not sharp.

【0017】[0017]

【発明の効果】本発明によれば、実施例、比較例の結果
が示すように、任意の彫刻の深さおよび精度のパタ−ン
を基材形状に限定されることなく再現性良く粗面化パタ
−ンが形成できるものである。
According to the present invention, as shown by the results of the examples and the comparative examples, the pattern of arbitrary depth and accuracy of the engraving is not limited to the shape of the base material and the reproducibility of the rough surface is good. Can be formed.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の処理工程説明図。FIG. 1 is an explanatory view of a processing step of the present invention.

【符号の説明】[Explanation of symbols]

1 基材 2 剥離性を有する接着層 3 弾性を有する樹脂層 4 マスキング層 5 レーザーにより除去した部分 6 粗面化処理面 Reference Signs List 1 base material 2 adhesive layer having releasability 3 resin layer having elasticity 4 masking layer 5 portion removed by laser 6 roughened surface

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】基材上に、剥離性を有する接着層と弾性を
有する樹脂層を順次形成してマスキング層となし、該マ
スキング層をレ−ザ−により部分的に除去し、次いで、
マスキング層を除去した基材表面を粗面化処理した後、
残りのマスキング層を除去した装飾体の製造方法。
An adhesive layer having releasability and a resin layer having elasticity are sequentially formed on a substrate to form a masking layer, and the masking layer is partially removed with a laser.
After roughening the substrate surface from which the masking layer has been removed,
A method for producing a decorative body from which the remaining masking layer has been removed.
JP10227576A 1998-07-28 1998-07-28 Manufacture of decorative body Pending JP2000043495A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10227576A JP2000043495A (en) 1998-07-28 1998-07-28 Manufacture of decorative body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10227576A JP2000043495A (en) 1998-07-28 1998-07-28 Manufacture of decorative body

Publications (1)

Publication Number Publication Date
JP2000043495A true JP2000043495A (en) 2000-02-15

Family

ID=16863089

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10227576A Pending JP2000043495A (en) 1998-07-28 1998-07-28 Manufacture of decorative body

Country Status (1)

Country Link
JP (1) JP2000043495A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1197351A1 (en) * 2000-10-13 2002-04-17 Kissel & Wolf GmbH Process for applying a pattern on a substrat
JP2005063780A (en) * 2003-08-11 2005-03-10 Nordson Corp Electrolyte membrane. electrolyte membrane complex, manufacturing method of electrolyte membrane complex, electrolyte membrane/electrode assembly for fuel cell, manufacturing method of electrolyte membrane/electrode assembly for fuel cell, and fuel cell
US8272187B2 (en) 2004-12-23 2012-09-25 Flooring Industries Limited, Sarl Floor panel, as well as method, device and accessories for manufacturing such floor panel
KR101190589B1 (en) * 2010-11-26 2012-10-12 황재우 Masking Sheet and Complex Masking Sheet For Sand Blast and Thereof Manufacturing Method
WO2014061523A1 (en) * 2012-10-19 2014-04-24 株式会社ミマキエンジニアリング Sandblasting method

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1197351A1 (en) * 2000-10-13 2002-04-17 Kissel & Wolf GmbH Process for applying a pattern on a substrat
JP2005063780A (en) * 2003-08-11 2005-03-10 Nordson Corp Electrolyte membrane. electrolyte membrane complex, manufacturing method of electrolyte membrane complex, electrolyte membrane/electrode assembly for fuel cell, manufacturing method of electrolyte membrane/electrode assembly for fuel cell, and fuel cell
US8272187B2 (en) 2004-12-23 2012-09-25 Flooring Industries Limited, Sarl Floor panel, as well as method, device and accessories for manufacturing such floor panel
US8499519B2 (en) 2004-12-23 2013-08-06 Flooring Industries Ltd Floor panel, as well as method, device and accessories for manufacturing such floor panel
US9249580B2 (en) 2004-12-23 2016-02-02 Flooring Industries Limited, Sarl Floor panel, as well as method, device and accessories for manufacturing such floor panel
US9611657B2 (en) 2004-12-23 2017-04-04 Flooring Industries Limited, Sarl Floor panel, as well as method, device and accessories for manufacturing such floor panel
US10000936B2 (en) 2004-12-23 2018-06-19 Flooring Industries Limited, Sarl Floor panel, as well as method, device and accessories for manufacturing such floor panel
US10415257B2 (en) 2004-12-23 2019-09-17 Flooring Industries Limited, Sarl Floor panel, as well as method, device and accessories for manufacturing such floor panel
US11208813B2 (en) 2004-12-23 2021-12-28 Flooring Industries Limited, Sarl Floor panel, as well as method, device and accessories for manufacturing such floor panel
KR101190589B1 (en) * 2010-11-26 2012-10-12 황재우 Masking Sheet and Complex Masking Sheet For Sand Blast and Thereof Manufacturing Method
WO2014061523A1 (en) * 2012-10-19 2014-04-24 株式会社ミマキエンジニアリング Sandblasting method
JP2014083607A (en) * 2012-10-19 2014-05-12 Mimaki Engineering Co Ltd Sand blast method

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