JP2000011701A - Chemical illuminant and emission means using it - Google Patents

Abstract

PROBLEM TO BE SOLVED: To prevent the generation of a non-emission zone and emit light securely and comfortably in a uniform condition by installing a bubble catching means in a translucent resin container body enclosing a solution to generate a chemical luminescence reaction and thereby blocking the movement of bubbles toward one side. SOLUTION: A body 2a of a translucent resin container 2 is filled with a first solution 4, and an ampul 3 in which a second solution 5 is stored is inserted into it and the container is held with the end of its one side 2b oriented downward. A fitted-in body 7 is arranged in the first solution 4 through an opening of the other side 2c of the container body 2a. A through hole 7b having a predetermined diameter is bored in a partitioning body 7a to partition the first solution 4 of the fitted-in body 7. Bubbles 6 in the first solution 4 are moved from the through hole 7b to the side of a lid 8 to remove them by vibrating the container body 2a with a finger or the like. Thereafter, the one side 2b is stood upside-down, and thus, the ampul 3 is broken with external force to mix both the solutions, so that a chemical luminescence reaction is generated to emit light without reverse flow of the bubbles 6 from the through hole 7b.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a chemiluminescent body and a light emitting device using the chemiluminescent body.

[0002]

2. Description of the Related Art Conventionally, as a chemiluminescent substance utilizing a chemiluminescence reaction, for example, there is one shown in FIG. In the chemiluminescent body 1, a glass solution ampule 3 filled with a second solution 5 is housed in a cylindrical translucent resin container 2 filled with a first solution 4. Of the first solution 4 and the second solution 5 flowing out of the destroyed solution ampoule 3 cause a chemiluminescence reaction. When the resin solution is used, the inner solution is bent by bending the resin container body 2a. By breaking the ampoule 3 and mixing the respective solutions 4 and 5, the chemiluminescent body 1 can emit light without generating any heat, and the fluorescent substance in the solutions 4 and 5 to be filled is prepared. Thus, light can be emitted in various colors.

[0003]

However, the chemiluminescent body having the above structure has the following problems when used.

[0004] That is, the chemiluminescent body having the above-mentioned structure is prepared such that one side 2b is closed and the other side 2c is manufactured beforehand.
Cylindrical resin container body molded to open side
The resin container main body 2a is held in an inverted state with the other 2c facing upward with the other 2c side facing upward, and then the first solution 4 and the solution ampule 3 are filled into the resin container main body 2a, and then the other 2c side is sealed. Lid 8 (The sealing lid is not necessarily required, and the other end of 2c is melted and the first solution 4 and the solution ampoule 3 are transferred to the resin container body.
It may be sealed in 2a. ) Is produced by sealing.

[0005] Therefore, the chemiluminescent body whose end of the other side 2c is sealed as described above seals each of the solution ampules 3 in which the first solution 4 and the second solution are filled in the resin container main body 2a. Although it is possible to do so, when the end of the other 2c is sealed, as shown in FIG. 9A, a small amount of air is simultaneously trapped in the resin container body 2a as bubbles 6.

As shown in FIG. 1B, the chemical luminous body having the above structure is used by attaching the end of the other side 2c to a predetermined place 9 of various luminaires or the like. However, in the resin container main body 2a, since the bubbles 6 are trapped at the time of sealing at the end side of the other 2c, when the one 2b side is turned upward during use, it is trapped. The bubbles 6 move upward in the first solution 4 in the resin container main body 2a, that is, toward the one 2b side of the resin container main body 2a, and the bubbles 6 are formed at one end 2b end of the resin container main body 2a. It will accumulate.

Therefore, in this state, the internal solution ampule 3 is broken by bending the resin container main body 2a, and the second solution 5 flowing out from the damaged portion 3a is mixed with the first solution 4 to generate no heat. Although the chemiluminescent body 1 can emit light without causing it, anyway, since the bubbles 6 accumulate at one end 2b of the resin container body 2a, the solutions 4 and 5 cannot be mixed at the one 2b end. Therefore, a non-luminous zone (arrow F) which does not emit light is generated at one end 2b of the resin container main body 2a, and some users complain of discomfort. Therefore, some immediate solution is desired. I was

However, the present invention has been made to solve the above-mentioned problems. For example, when air bubbles are slightly generated during sealing, the air bubbles are trapped in a resin container main body or a solution ampule when a chemiluminescent substance is produced. Not only in the case where a slight amount of carbon dioxide gas is generated during mixing of the solution, but also in any case where one of the resin container It is an object of the present invention to provide an extremely excellent chemiluminescent substance which can surely and comfortably emit light in a uniform state without causing any non-luminous zone at an end, and a light emitting device using the chemiluminescent substance. It is an issue.

[0009]

The present invention has developed a completely new chemiluminescent body and a light emitting device using the chemiluminescent body, and has taken the following technical measures.

As a first technical means, the present invention is based on the fact that a bubble capturing means is provided in the translucent resin container main body 2a of a chemiluminescent body in which a solution for causing a chemiluminescence reaction is sealed. During the production of a chemiluminescent body, air bubbles due to some air are trapped in the resin container body 2a when the resin container body is sealed, or bubbles are trapped in the solution ampule when the solution ampule 3 is sealed. Not only in the case where a slight carbon dioxide gas is generated at the time of mixing the solution, but also in any case where one of the resin container main body 2a positioned above at the time of chemiluminescence of the resin container main body occurs. There is an advantage that the resin container main body 2a can be used by emitting light comfortably in a uniform state without causing any non-emission zone at the end.

Further, as a second technical means, the present invention provides:
The translucent resin container main body 2a is formed in a cylindrical shape, and the bubble trapping means prevents only the movement of the air bubbles 6 moving in the translucent resin container main body 2a to the one 2b side at a predetermined position. Therefore, during production or use of the chemiluminescent body, even if some air bubbles 6 such as air and carbon dioxide are trapped in the resin container main body 2a or generated, the resin container main body 2a
In the case where the chemiluminescent body is used by emitting light with the one 2b end positioned upward, the resin container main body 2a positioned above
There is an advantage in use that the resin container main body 2a can uniformly and comfortably emit light without generating any non-emission zone at one end 2b.

Further, as a third technical means, the present invention provides:
In order to prevent the bubble trapping means from moving the solution ampule 3 housed in the translucent resin container main body 2a, a partition 7a provided in the main body 2a and a through hole 7b formed in the partition 7a. Or, since it is composed of the through groove 7c, the transparent resin container body
The partition wall 7a does not cause a major change in the structure of 2a.
It is possible to capture a bubble 6 taken out through the through hole 7b or the through groove 7c through the partition wall 7a, thereby producing a chemiluminescent body having a simple structure in which an increase in cost is minimized. There is an advantage that can be.

Further, as a fourth technical means, the present invention is directed to a partition 7a provided with a through-hole 7b or a through-groove 7c, in which a bubble 6 in the main body 2a is moved to the other main body 2c side opposite to the solution ampoule 3. Since the tapered surface portion 7d tapered toward the other 2c side is provided to guide and pass through the through hole 7b or the through groove 7c, all the bubbles 6 existing on the one 2b side where the solution ampule 3 is stored are removed. In addition to being able to easily guide and collect to the through hole 7b or the through groove 7c, there is an advantage that the collected bubbles 6 can be more smoothly moved from the through hole 7b or the through groove 7c to the other 2c side. .

Further, as a fifth technical means, the present invention provides:
Since the bubble trapping means is formed of a porous partition wall 7a provided in the main body 2a in order to prevent movement of the solution ampule 3 stored in the transparent resin container main body 2a, the solution ampule 3 is stored. The bubbles 6 present on the one side 2b can be instantaneously moved from the many holes provided in the partition wall 7a to the other side 2c only by applying vibration or impact to the light transmitting resin container main body 2a. There are advantages that can be done.

Further, as a sixth technical means, the present invention provides:
Since the porous partition wall 7a is formed of a mesh, the bubbles 6 existing on the one 2b side where the solution ampule 3 is stored are removed.
There is an advantage that the translucent resin container main body 2a can be instantaneously moved from between the meshes to the other 2c side only by applying vibration or impact to the translucent resin container main body 2a.

Further, as a seventh technical means, the present invention is directed to a method for producing air bubbles by means of the bubble trapping means, wherein one side 2b of the light-transmitting resin container body 2a is inclined downward, or By applying an impact, the air bubbles 6 present on one side 2b of the container main body 2a are guided to the other 2c side of the container main body 2a, and the air bubbles 6 guided to the other 2c side are prevented from returning. Solution ampoule 3 by performing a very simple operation immediately before the chemiluminescent substance emits light.
Can be moved from the partition 7a to the other 2c side while the bubble 6 present on the one 2b side in which the is stored, and in use, no light is emitted at one end 2b of the resin container body 2a located above. There is an advantage in use that the resin container main body 2a can emit light comfortably in a uniform state without any zone.

Further, as an eighth technical means, the present invention provides:
When the light emitting device is obtained by forming the tip inner space 10 and the tip outer periphery 11 on the one 2b side of the translucent resin container main body 2a of the chemiluminescent body having any of the above configurations to be tapered. When the light emitting device is used, one 2b of the resin container body 2a positioned above is used.
The shape of the tip inner space 10 and the tip outer periphery 11 on the one 2b side of the chemiluminescent body, which enables the resin container main body 2a to emit light comfortably in a uniform state without any non-emission zone at the end, is tapered. It is possible to obtain the luminous state and amount of light of an atmosphere like a lit candle, thereby prohibiting the use of a fire in a place where it is suitable to use a candle. By actively using it in such places as, for example, in the wooden temple (with restrictions on the use of lighting using candles), etc., it is extremely safe and the atmosphere of the place is maximized. There are merchandise advantages that can be.

Further, as a ninth technical means, the present invention provides:
Since the light-emitting device 12 is configured to be detachably attached to the light-emitting device holder 9a via attachment / detachment means, the tip inner space 10 on the one 2b side of the translucent resin container main body 2a of the chemical light emitter and The light emitting device 12 that can obtain the light emitting state and light amount of an atmosphere like a lit candle at the time of light emission by mounting the light emitting device 12 to the light emitting device holding body 9a by forming the shape of the tip side outer periphery 11 to be tapered. By making it detachable, only the light emitting device 12
For example, it is possible to supply artificial candles to the market as consumable parts, which is extremely useful not only in various buildings where the use of lit candles is prohibited but also in households with elderly people. Not only can it be used safely and positively, but also various kinds of light emission in which the amounts of the first solution 4 and the second solution 5 in the solution ampule 3 filled in the translucent resin container body 2a are adjusted respectively. By supplying the light emitting devices 12 to the market, the light emitting time of each light emitting device 12 can be set more finely, so that the light emitting device 12 having the light emitting time suitable for the purpose of use and the use time can be appropriately selected according to the user's intention. There is an advantage that it can be used.

[0019]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS <First Embodiment> One embodiment of a chemiluminescent substance according to the present invention will be described below with reference to the drawings. In the structure of such a chemiluminescent body, description of the same portions as those described in the related art will be omitted.

In FIG. 1, reference numeral 1 (a) denotes a chemiluminescent substance, and 7 denotes an opening of the other side 2c of the container main body 2a to prevent the solution ampule 3 stored in the translucent resin container main body 2a from moving. 5 shows a cylindrical fitting body fitted into the main body 2a from a portion.

A partition 7a is provided at one end of the insert 7 so that the interior of the container body 2a can be divided into two when the insert 7 is inserted. In
A through hole 7b having a predetermined diameter is formed.

The diameter of the through hole 7b is such that the insertion member 7 is inserted through the opening of the other side 2c of the container body 2a,
The opening of the other 2c of the container body 2a is sealed with the sealing lid 8 (here, the case where the lid 8 is used separately from the container body 2a will be described. However, even if the opening itself is melted and the opening of the other 2c of the container body 2a is sealed. Of course, it does not matter.)
As shown in FIG. 3 (b), the air bubble 6 made of air trapped through the container body 2a is gripped in an inverted state with one finger, and then one side 2b of the container body 2a is inserted through the other finger. When a vibration or impact is applied to the container body 2a by flipping (arrow B) or the like, the first solution 4 is allowed to escape from the partition 7a of the insertion body 7 to the sealing lid 8 side to the other side 2c side. A size that can be moved upward (arrow C) by buoyancy (that is, the first solution 4 and the bubble 6 can be exchanged via the through-hole 7b when the container body 2a is subjected to vibration or impact). This diameter is previously tested based on the viscosity of the first solution 4 and the thickness of the partition wall 7a, and is set in advance to the best diameter.

Therefore, as described above, the translucent resin container main body 2a
The one 2b side of the container body 2a is inclined downward (not shown) or the container body 2a is turned upside down to apply vibration or impact to the one 2b side of the container body 2a via the partition wall 7a of the insertion body 7. The existing bubbles 6 can be guided to the other side 2c of the container body 2a by replacing the first solution 4 with the first solution 4. However, once the bubbles 6 have passed through the through holes 7b of the partition wall 7a, they are shown in FIG. ), Even when the container body 2a is rotated so that the one 2b side of the container body 2a faces upward and the other 2c is positioned below, a new vibration is applied to the container body 2a. Alternatively, as long as no impact is given, the partition wall 7a is captured by the partition wall 7a without returning to the through hole 7b.

Therefore, since the partition wall 7a functions as a bubble capturing means, the resin container main body 2a is bent in this state to break the internal solution ampule 3, and the second solution 5 flowing out from the damaged portion 3a is removed from the container main body. By mixing with the first solution 4 in 2a, the chemiluminescent body 1 can be made to emit light without generating any heat. Since the trapped air bubbles 6 are all captured by the partition wall 7a, there is no air bubble 6 at one end 2b of the resin container main body 2a, and therefore, the resin container main body 2a located above
Thus, the entire resin container main body can emit light uniformly and comfortably without causing any non-emission zone at one end 2b.

Further, a partition 7a as a bubble trapping means is provided.
The air bubbles 6 existing on one side 2b of the container main body 2a by inclining one side 2b of the translucent resin container main body 2a downward or applying vibration or impact with the container main body 2a in an inverted state.
To the other 2c side of the container body 2a, and then the container body 2a
Even if the one 2b side is rotated and positioned upward, the bubble 6 once guided to the other 2c side of the container body 2a
The solution ampoule 3 is stored by performing the above-mentioned very simple operation just before the chemiluminescent substance emits light, since the reversion is prevented while the impact and vibration are not applied again to the container body 2a. On the other hand, there is an advantage in handling that the bubble 6 present on the side 2b can be moved from the partition 7a to the side 2c to maintain the trapped state.

<Second Embodiment> In the above embodiment,
At the approximate center of the partition wall 7a, when the bubbles 6 trapped in the container body 2a are subjected to vibration or impact on the container body 2a,
A through-hole 7b having a diameter capable of moving the partition 7a of the insertion member 7 upward by its own buoyancy is formed as shown in FIG. 2A, but is not limited to this. For example, as shown in FIG. 2 (b), the bubble trapping means may be a porous 7b-shaped partition wall 7a provided in the main body 2a. The bubble 6 present on the 2b side is simply removed by applying shock or vibration to the container body 2a.
It is possible to instantly move upward from the many holes 7b provided in 7a to the other 2c side, and therefore, as described in the first embodiment, in a shorter time than in the case of one through hole 7b. In addition, there is an operational advantage that it can be moved instantaneously.

Furthermore, it is not necessary to be limited to the through hole 7b,
For example, as shown in FIG. 3 (c), the partition wall 7a may be provided with a through groove 7c, and even in this case, the air bubbles 6 existing on the one 2b side are transferred to the container main body 2a in the same manner as described above. The other side from the through groove 7c provided in the partition wall 7a only by giving a shock or vibration
Instantly move to the 2c side, and again,
It is possible to easily obtain a bubble capturing means that the bubbles 6 can be captured by the partition wall 7a as long as vibrations or shocks are not applied to the 2a. There is an advantage in manufacturing that a chemiluminescent substance can be produced with minimal increase in cost without causing any increase.

Further, by making the partition wall 7a porous, the bubble 6 existing on one side 2b can be instantaneously moved to the other 2c side in a shorter time than one through hole 7b. As shown in FIG. 3 (d), the partition wall 7a may be formed by a net. In this case, the bubble 6 existing on the one side 2b in which the solution ampule 3 is stored by one vibration or impact.
Is instantaneously and more reliably between all meshes
There is an operational advantage that can be raised at a stroke to the 2c side, and even in this case, the bubble 6 is captured by the partition wall 7a unless vibration or impact is applied to the container body 2a again. There is an advantage that can be maintained.

<Third Embodiment> Further, as shown in FIG. 3A, a part of the substantially central portion of one side of the partition wall 7a, or as shown in FIG. The partition body provided with, for example, a through hole 7b or a through groove 7c (not shown)
7a, a tapered surface portion 7d tapering toward the other 2c side so that the bubbles 6 in the main body 2a can be easily guided and passed through the through hole 7b or the through groove 7c to the other main body 2c side opposite to the solution ampoule 3.
Therefore, in this case, all of the bubbles 6 present on the one 2b side in which the solution ampule 3 is stored can be easily guided to the through hole 7b or the through groove 7c and collected. In addition, there is an advantage that the collected bubbles 6 can be more smoothly moved from the through hole 7b or the through groove 7c to the other 2c side.

<Fourth Embodiment> Next, a case of providing a completely new light emitting device 12 using a chemiluminescent substance having the above advantages will be described.

As shown in FIG. 4A, the shape of the tip inner space 10 and the tip outer periphery 11 on the one 2b side of the translucent resin container main body 2a of the chemiluminescent body 1 having the above-described structure is tapered ( At this time, the entire shape of the container body 2a may be made into an entasis shape so as to make it resemble the shape of a candlelight, but it is not particularly necessary to expand the central portion.) Then, as described in the above embodiment. The light emitting device 12 is produced in a similar process.

Thereafter, the trapped bubbles 6 are moved upward to the other side 2c of the container body 2a by applying vibration or impact to the container body 2a, and then, as shown in FIG. The container body 2a is rotated so that the one 2b side of the 2a faces upward and the other 2c is positioned below.In this case, the bubbles that have moved to the other 2c unless the container body 2a is subjected to vibration or impact. 6 maintains the state captured by the partition 7a without returning to the through hole 7b of the partition 7a.

Therefore, when the partition 7a is trapping the bubbles 6, the resin container main body 2a is bent to break the internal solution ampule 3, and the second solution 5 flowing out from the damaged portion 3a is transferred to the container main body 2a. By mixing with the first solution 4 in the inside, the resin container main body 2a does not generate heat at all, and does not generate any non-emission zone at one end 2b of the resin container main body 2a located above. It is possible to emit light comfortably in a uniform state. At this time, the shape of the tip inner space 10 and the tip outer periphery 11 on the one 2b side of the container body 2a of the chemiluminescent body is tapered.

Accordingly, it is possible to obtain the light emission state and light amount of an atmosphere like a lit candle, so that it is prohibited to use a fire in a place where the candle is suitable for use. By using it actively in lighting places such as wooden wooden placards (there are restrictions on the use of lighting with candles), etc., it is extremely safe and to maximize the atmosphere of the place. There is an advantage in the product that can be.

Further, as described above, the shape of the tip inner space 10 and the tip outer periphery 11 on the one side 2b side of the container body 2a is tapered, so that the light emitting state and light amount of an atmosphere like a lit candle can be reduced. As shown in FIG. 5, the light emitting device 12 that can be obtained may be detachably attached to a light emitting device holder 9a that resembles a candle body, for example.

That is, as shown in FIG.
The attaching / detaching means for attaching and detaching the light emitting device 12 to and from the light emitting device holder 9a is provided with a ring-shaped bulging portion 1a on the peripheral surface of the light emitting device 12 on the other side 2c of the resin container main body 2a, and 9a, a concave portion 9b into which the bulging portion 1a can be inserted and removed is provided on the inner peripheral surface of the light-emitting device insertion concave portion, and the light-emitting device holder 9a is inserted into the light-emitting device holder 9a as shown in FIG. A structure in which a projection 9c is provided on the inner peripheral surface of the concave portion to press and hold the peripheral surface of the resin container main body 2a of the light emitting device 12, and further, as shown in FIG. A recessed space in the sealed portion on the other side 2c
1b, and a protrusion formed at the end of the light emitting device holder 9a.
The light-emitting device 12 and the light-emitting device holder 9a may be configured to be detachable by press-fitting into the 9d.

Therefore, the light emitting device 12 which can obtain the light emitting state and light amount of an atmosphere like a lit candle can be detachably attached to the light emitting device holder 9a via various attaching / detaching means. Thereby, it becomes possible to supply only the light emitting device 12 to the market, for example, as a consumable part of a pseudo candle,
Therefore, it can be used not only in various buildings where it is prohibited to actually use lit candles, but also in memorial services at homes with elderly people, etc. The first filling in the translucent resin container body 2a
By supplying various types of luminous devices 12 in which the amounts of the solution 4 and the second solution 5 in the solution ampule 3 are adjusted to the market, the luminous time and luminous color of each luminous device 12 can be set more finely. Therefore, a product that can be widely used as a next-generation candle as a completely new product that can be used by appropriately selecting and using a light-emitting device 12 with a light-emitting time that matches the purpose of use and the time of use. There are strategic advantages.

It should be noted that the light emitting device 12 is connected to the light emitting device holder 9a as described above.
The attachment / detachment means for making the attachment / detachment detachable from the device is not limited to the above-described configuration. Various attachment / detachment means that can be attached and detached by an elastic body such as rubber or a resilient body such as a spring provided on at least one of a screw-in type, or a specific configuration of the attachment / detachment means may also be used. It is needless to say that the present invention is not limited in any way, and that the attaching / detaching means is not an essential requirement of the light emitting device using the chemiluminescent body of the present invention.

It should be noted that in the above embodiment, the bubble trapping means is the solution ampoule 3 contained in the translucent resin container main body 2a.
Partition 7a provided in the main body 2a to prevent the movement of
In the above description, the through hole 7b or the through groove 7c is provided. Alternatively, in the case of the through-groove 7c, it is possible to produce a chemiluminescent body with a minimum increase in cost without causing a major change in the structure of the translucent resin container main body 2a. There are advantages.

Further, in the above-described embodiment, the bubble trapping means sets the translucent resin container main body 2a in an inverted state, and then applies vibration or impact to the container main body 2a, so that the air bubbles 6 in the container main body 2a are removed. Although the case of moving upward from the side 2b to the other side 2c through the through-hole 7b provided in the partition wall 7a has been described, the present invention is not necessarily limited to this. For example, as shown in FIG. The tapered surface of the partition wall 7a formed in a tapered state from one side 2b to the other side 2c of the container body 2a
A tapered surface portion substantially similar to 7d is formed on the back surface side (the other side) of the partition wall body 7a.
2c) may be formed along the tapered surface portion 7d, and the through-hole 7b may be provided with a hole diameter that facilitates replacement of the bubbles 6 with the first solution 4. In this case, the container body 2a The bubble 6 is transferred from the through hole 7b to the other side 2c of the container main body 2a along the tapered surface portion 7d of the partition wall 7a without giving any vibration or impact to the container main body 2a just by turning the container into an inverted state. As shown in FIG. 13B, the ascending movement can be easily performed.

Therefore, as shown in FIG.
After the bubbles 6 have all moved to the other side 2c of the container body 2a,
As shown in FIG. 4D, even when the partition wall 7a is returned to the original state, a tapered surface portion (bubble 6) formed on the back surface side (the other side 2c) of the partition wall 7a along the tapered surface portion 7d of the partition wall 7a. Functioning as a catching unit for guiding and collecting the air bubbles), it is possible to catch all the bubbles 6 rising through the container body 2a. Bubble 6 without any impact or shock
The bubble 6 that has not only been easily moved from one side 2b of the 2a to the other side 2c, but has once moved to the other side 2c.
Means that the container body 2a can be returned to its original state,
There is an advantage that even if a shock or vibration is applied to the horn, it is possible to surely capture it via the partition 7a without returning to the one side 2b.

Further, in each of the above-described embodiments, only the air trapped in the resin container main body 2a at the time of sealing the resin container main body 2a is described as the air bubbles 6 trapped by the bubble trapping means. The present invention is not necessarily limited to this. For example, as shown in FIG. 6, some air or carbon dioxide gas generated at the time of chemiluminescence existing in the solution ampoule 3 housed in the resin container main body 2a. Air bubbles 6
Can be captured via the bubble capturing means.

That is, as shown in FIG.
2a with the air bubble 6 in the container body 2a in the inverted state,
When or after moving the container, the solution ampule 3 housed in the container body 2a is broken by breaking it by pressing the container body 2a firmly or pressurizing or bending it. Bubbles 6 consisting of a small amount of air existing in the solution ampoule 3 from 3a may be moved upward to the other side 2c, or a broken portion 3a
After the bubble 6 made of carbon dioxide gas generated when the second solution 5 flowing out of the container and the first solution 4 filled in the container main body 2 emits chemiluminescence is moved upward to the other side 2c, the same figure (d) In this case, the air bubbles 6 that have once moved to the other side 2c may be captured via the partition wall 7a.
There is an advantage that even when the container 2a is returned to the original state or when the container body 2a is given an impact or vibration, it can be reliably captured via the partition wall 7a without returning to the one side 2b.

Further, in each of the above embodiments, the case where the bubble trapping means is provided with the partition 7a in the container main body 2a has been described. However, the bubble trapping means of the present invention is not limited to the partition 7a. For example, as shown in FIG. 7 (a), at least one side 2b (may be provided on the other side 2c) in the light emitting device (container main body) 12 has a bag-like shape provided with water absorption by capillary action. May be housed as bubble trapping means. In this case, in use, when the one side 2b of the light emitting device 12 is positioned upward, the air bubbles 6 in the light emitting device 12 are removed from the felt body 13. It is possible to capture the light inside the light emitting device 12 as shown in FIG.
The solution ampule 3 in the inside is destroyed, and bubbles 6 made of carbon dioxide gas or the like generated at the time of chemiluminescence due to mixing of a small amount of air or solution existing in the solution ampule 3 from the broken portion 3a.
Can be moved upward to one side 2b to be captured inside the felt body 13.

Therefore, when the light emitting device 12 emits light while the air bubbles 6 are captured inside the felt body 13 as described above,
The bag-like felt body 13 itself having water absorption by capillary action emits light, and thus the light emitting device located above
The light emitting device 12 can comfortably emit light in a uniform state without generating a no light emitting zone at one end 2b of the light emitting device 12.

Further, in the above embodiment, the bubble trapping means is provided by the opening on the other side 2c of the container body 2a.
The case where the partition body 7a and the felt body 13 provided at the end of the insertion body 7 housed in the case are described, but the present invention is not necessarily limited to this, and it is essential to cause a chemiluminescence reaction. By having bubble trapping means in the translucent resin container main body 2a of the chemiluminescent body in which the solution is sealed, bubbles 6 such as air and carbon dioxide gas are generated during the production and use of the chemiluminescent body. Even if the chemiluminescent substance is made to emit light in the state where it is present in the inside, any bubble capturing means that can be used by making the resin container main body 2a emit light in a uniform state without generating any non-emission zone. If
It goes without saying that the specific structure, formation location and the like of the bubble trapping means are not limited at all.

In each of the above embodiments, the case where the container body of the chemiluminescent body is formed in a cylindrical shape or a tapered shape having a predetermined overall length has been described, but the container body is not necessarily limited to a cylindrical shape or a tapered shape. There is no necessity, for example, the entire shape of the container body may be formed in a prismatic shape, a crescent shape, or various character goods, and the point is that some air or carbon dioxide gas is contained in the container body of the chemiluminescent body or in the solution ampule. Even when the chemiluminescent body is caused to emit light in a state where bubbles 6 are present, a bubble trapping means which allows the resin container main body 2a to emit light in a uniform state without using any non-emission zone Is provided in the container body of the chemiluminescent body, the specific shape and size of the container body and the solution ampoule constituting the chemiluminescent body are not limited at all.

Further, the chemiluminescent substance used in the present invention also uses a so-called chemiluminescent reaction utilizing a so-called chemiluminescence reaction, which emits light without generating any heat by mixing two solutions. Needless to say, the specific type and reaction rate of the solution that causes the chemiluminescence reaction are not limited as long as it is a chemiluminescent substance using a chemiluminescence reaction to emit light without generating any heat.
In addition, the chemical luminous body may be used alone in various fields, or the chemical luminous body may be processed into various shapes or attached to other members to be used as any kind of light emitting device. It goes without saying that the specific shape, structure, field of use, etc. of the luminous body and the luminous device using the chemical luminous body are not limited at all.

[0049]

As described above, the present invention comprises a bubble trapping means in a translucent resin container body of a chemiluminescent body in which a solution for causing a chemiluminescence reaction is sealed. However, not only when bubbles due to some air are sealed in the resin container body or the solution ampule when producing the chemiluminescent substance at the time of sealing, but also a little carbon dioxide gas is generated at the time of mixing the solution. In any case where such a situation occurs, the resin container body is securely formed without causing any non-emission zone at one end of the resin container body located above at the time of chemiluminescence of the resin container body, and It can be used by emitting light comfortably in a uniform state.

Further, the light-transmitting resin container main body is formed in a cylindrical shape, and the bubble catching means prevents only the movement of the air bubbles moving in the light-transmitting resin container body to one side at a predetermined position. Therefore, when producing or using the chemiluminescent body, some air bubbles such as air and carbon dioxide gas are trapped in the resin container main body, and in a state where it is generated, one end of the resin container main body is positioned upward. Even when the chemiluminescent body is used to emit light, the resin container main body can emit light uniformly and comfortably without causing any non-emission zone at one end of the resin container main body located above.

Accordingly, the front end of one side of the chemiluminescent body, which makes it possible to uniformly and comfortably emit light in the resin container main body without generating any non-emission zone at one end of the resin container main body located above. By forming the inner space portion and the outer peripheral shape on the distal end side to be tapered, it is possible to provide a light emitting device capable of obtaining a light emitting state and a light amount of an atmosphere like a lit candle. The use of fire in places where it is appropriate to use it is prohibited, for example, by actively using it for lighting at a wooden wooden temple, etc. There is an effect at the time of use that can excite the atmosphere of the maximum.

Further, when the light emitting device capable of obtaining the light emitting state and light amount of an atmosphere like a lit candle can be detachably attached to the light emitting device holder through the attaching / detaching means, Can be supplied to the market, for example, as a consumable part of a pseudo candle, so that not only in various buildings where the use of a lit candle is prohibited, but also in households with elderly people, etc. A variety of light-emitting devices that can not only be used extremely safely and positively, but also adjust the amounts of the first solution and the second solution in the solution ampule to be filled in the translucent resin container body, respectively. By supplying to the market, the luminous time and luminous color of each luminous device can be set more finely, so that the luminous device having the luminous time and luminous color suitable for the purpose and use time can be selected according to the user's intention. Select as appropriate There is a large effect on the items that can also be spread as widely the general public to the next generation of candle as a completely new product that can be used.

Therefore, according to the chemiluminescent body of the present invention and the light emitting device using the chemiluminescent body, conventionally, the use of the chemiluminescent body at a concert hall, various event halls, and the like is not easy to use. A wide variety of uses, including not only shrines, temples and temples, but also general ceremonies and memorial services at home, various restaurants, bars, hotels, and lounges that emphasize the atmosphere, as well as masses and ceremonial occasions at churches The use of such a chemiluminescent substance and a chemiluminescent substance having a completely new effect of being able to enliven the atmosphere of the field as a totally new chemiluminescent substance and a light emitting device using the chemiluminescent substance. It has an extraordinary effect that it is possible to provide an improved light emitting device.

[Brief description of the drawings]

FIG. 1 shows a first embodiment of a chemiluminescent body according to the present invention, in which (a) and (b) are partial cross-sectional front views, and (c) a main part cross-sectional front view at the time of light emission.

2A and 2B show a partition body, wherein FIG. 2A is a sectional view taken along line AA of FIG. 1A, and FIGS. 2B, 2C and 2D are plan views showing another embodiment of FIG. .

FIGS. 3A and 3B show another embodiment of a partition body, and FIGS.
FIG.

4A and 4B show a light emitting device using a chemiluminescent body, wherein FIG. 4A is a cross-sectional front view of a main part, and FIG.

FIG. 5 shows another embodiment of the light emitting device of the present invention,
(A), (b), and (c) are cross-sectional views of a main part, partially omitted.

FIG. 6 shows another embodiment of the bubble capturing means of the light emitting device according to the present invention, in which (a), (b), (c), and (d) are cross-sectional views of a principal part with a part omitted.

7A and 7B show another embodiment of the bubble capturing means of the light emitting device according to the present invention, wherein FIG. 7A is a partially sectional perspective view, and FIG.

FIG. 8 is a perspective view showing a conventional chemiluminescent body.

9A and 9B show a conventional chemiluminescent body, wherein FIG. 9A is a partially omitted front view, and FIG.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 ... Chemiluminescent body 2 ... Translucent resin container 2a ... Translucent resin container main body 3 ... Solution ampoule 4 ... 1st solution 5 ... 2nd solution 6 ... Bubbles 7 ... Insert body

 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Nobuchi Kaneko 823-2, Sawamatsu, Hiromi-cho, Kita-wa-gun, Ehime Prefecture F-term (reference) 2C150 CA18 CA22 DA21 DC03 DC25 DK17 EA07 EB41 EB51 EC38 EE07 EF07 EH16 FB22

Claims (9)

[Claims] 1. A chemiluminescent body characterized in that it has bubble trapping means in a translucent resin container body (2a) in which a solution for causing a chemiluminescence reaction is sealed. 2. The translucent resin container main body (2a) is formed in a cylindrical shape, and the bubble trapping means is provided in the translucent resin container main body (2a).
2. The chemiluminescent substance according to claim 1, wherein only the movement of the air bubble (6) moving in the inside to one side (2b) is blocked at a predetermined position. 3. The light-transmissive resin container body according to claim 1, wherein
In order to prevent the solution ampule (3) stored in (2a) from moving, the partition (7a) provided in the main body (2a) and the partition (7) are provided.
3. The chemiluminescent body according to claim 1, comprising a through hole (7b) or a through groove (7c) formed in a). In the partition (7a) provided with the through hole (7b) or the through groove (7c), the air bubbles (6) in the main body (2a) are filled with the other main body opposite to the solution ampule (3). 4. The chemiluminescent body according to claim 3, wherein a tapered surface portion (7d) tapering toward the other side is provided so as to guide and pass to the side 2c). 5. The light-transmissive resin container body according to claim 1, wherein
3. The device according to claim 1, further comprising a porous partition (7a) provided in said main body (2a) to prevent movement of the solution ampule (3) stored in (2a). A chemiluminescent body as described. 6. The chemiluminescent body according to claim 5, wherein said porous partition wall (7a) is formed by a net. 7. The air bubble capturing means may incline one side (2b) of the translucent resin container main body (2a) downward or apply vibration or impact with the container main body (2a) in an inverted state. Thus, the air bubbles (6) existing on one (2b) side of the container body (2a) are guided to the other (2c) side of the container body (2a), and the air bubbles (6) guided to the other (2c) side. Bubbles)
The chemiluminescent substance according to any one of claims 1 to 6, wherein (6) is captured. 8. The chemiluminescent substance according to claim 1, wherein:
(1) The chemiluminescent body, wherein the shape of the tip inner space (10) and the tip outer periphery (11) on one (2b) side of the translucent resin container body (2a) is tapered. Light emitting device using. 9. The light-emitting device according to claim 8, wherein the light-emitting device (12) is configured to be detachably attached to the light-emitting device holder (9a) via attachment / detachment means.